SECTION-A

1. Write short answers of any SIX. 6

i) Why Aniline is stronger base than Trinitro Aniline?
ii) What is INDUCTIVE EFFECT? Explain with example.
iii) What is meant by PYROLYSIS of ALKANES?
iv) What is meant by DECARBOXYLATION? Give Decarboxylation of Propanoic acid using soda lime.
v) Write Structural Formula of 3-Cyclobutyl Pentane.
o
vi) What product is obtained when Cyclo hexane reacts with H2 at 25 C in presence of Nickel?
vii) Give One Diel-Alder reaction to prepare Cyclo Alkane.
SECTION-B
2. a) Draw and discuss the structure of Cyclopropane. 4
b) i) Give preparation of Ethene through Pyrolysis of Ester. 2
ii) Give witting reaction to prepare an alkene. 2

3. a) Aniline on reaction with methyl chloride in presence of AℓCℓ3 produce O and þ-product whereas
nitrobenzene produces m-product. Why? 4
b) Complete the following reactions: 4
Fe Br3 H2So4 Br2
i) Benzene + Br2 ? ii) Benzene + HNO3 ? ?
Fe Br3
Fe Cℓ3 hv
iii) Toluene + Cℓ2 o ? iv) Benzene + Cℓ2 ?
25 C
4. a) Define the following Terms with example: 1,1,1,1
i) Intra Molecular Hydrogen Bonding ii) Keto-Enolic Tautomerism
iii) Resonance Energy iv) Conjugated System
b) i) Give Corey House Method to prepare Alkanes.
ii) Give Wurtz Reaction to prepare Alkanes. 2,2

5. a) Give a detailed note on R and S-Convention. 2,2

b) Give Clemmensen and Wolf-Kishuer’s reduction of Aldehydes and Ketones. 2,2

SECTION-C
6. a) Give preparation of Alcohols from: 1,1,1,1

i) Ethene ii) Ethyl Chloride

iii) Formaldehyde iv) Acetaldehyde
b) i) Give DOW’s Process to prepare Phenol.
ii) Give Formation of Iodoform from Acetaldehyde. 2, 2

7. a) What is AROMATICITY? Discuss Huckel Rule for Aromaticity. 1, 3

b) Give a comparison of SN1 and SN2 reactions. 4

8. a) Give preparation of Acetoacetic ester and Malonic Ester. 4

b) What compounds will be obtained as a reaction of following with propanoic acid: 1,1,1,1
i) NaOH ii) NaHCO3 iii) SoCℓ2 iv) NH3

9. a) Give Hofmann’s Method of preparation of Amines. 2

b) How can you prepare Propyl Amine from Nitro Propane? 2
c) Why þ-nitroaniline is a weaker base than aniline? 2
d) Give Acylation of Aniline. 2
*** B.A/B.Sc - I (13/A) vii ***