Time Allooed:3 Hours] [Max.

Marks: 70
General Instructions: See Sanmple Question Paper -1.
SECTIONA
Note: Very Short Answer Questions of 1 mark each.
.1 What is meant by ammonolysis of alkyl halide ?
Or
Write the structure ofN, N-dimethylmethanamine.
0.2 Write the structure of 1-chloro-4-ethylcyclohexane.
Or
Name two halogen compounds of industrial importance.
03. The bond angle 2COH in alcohols is slightly less than the tetrahedral angle. Why ?
Or
Write the structure of picric acid.
Q4. Whattype of addition reactions are given by aldehydes and ketones?
Or
(CH)C-CHOdoes not give aldol condensation. Why?
Q.5. Namethe following compound according to IUPAC system?
CH3-C=C-CHOH
CH3 Br

Q.6. What is meant by the statement "like dissolves like ?

97. Howis quaternary ammonium salt obtained?
Q.8. Write the products formed when methanol reacts with sodium bromide and sulphuric acid.
99. Give the product of reaction between benzene diazonium chloride with aniine.
Q.10. What do we observe when we preform Tollen's reagent test ?
In question numbers 11 to 15, two statements are given - one labelled Assertion (A) and the
other labelled Reason (R). Select the correct answer to these questions from the codes (a), (6), (c)
and (d) as given below:
(a) Both Assertion (A) and Reason (R) are correct statements, and Reason (R) is the correct explanation of
the Assertion (A).
 (b) Both Assertton (A) and Reason (R) are correct statements, but Reason (R) is not the correct explanation
of the Assertion (A).
(c) Assertion (A) 1s Correct, but Reason (R) is incorrect statement.
(d) Assertion (A) is incorrect, but Reason (R) is correct statement.
Q.11. Assertion (A) : For ideal solutions, Amix H= 0 and Anix V= 0.
Reason (R) :When a solution does not obey Raoult's law over the whole concentration range.
it is called non-ideal solution.
Or
Assertion A) : We observe a negative deviation in the solution of acetone and chloroform.
Reason (R) Hydrogen of chloroform
forms a hydrogen bond with oxygen of
Q.12. Assertion (A) For a chemical reaction with rise of temperature by 10°, the rate constant is
acetone
nearly
doubled.
Reason (R) :Decomposition of N,05 to give 2NO2 +O is a first order reaction.
Q.13. Assertion (A) : Second and third transition series shows similar radii.
Reason (R :There is an increase in ionisation enthalpy along each series of transition elements
from left to right.
Q.14. Assertion (A) Aniline is a resonance hybrid of five resonating structures.
Reason (R) :Amino group in amine has to be protected by acetylation before carrying out
nitration.
Q.15. Assertion A) : Sulphanilic acid also occurs as zwitter ion.
Reason (R :
Carbylamine reaction is used a test for primary amine.
SECTIONB
Questions 16 to 23 are multiple choice questions. Each question has been provided by four
possible options as the answer. Select the most appropriate option out of these four.
Q.16. The relation between ATp W and w is given by
X 1000
(a) AT= Ky
Wz x K x W2 x 100
(b) AT; =
M2 X W1 M2 x W1

() AT Ky X W X 1000 (d) AT = K X W X 1000

M2 X W2 M XW1
Or
Osmotic pressure of a solution
depends upon
(a) molality of the solution. (b) molarity of the solution.
(c)nature of the solute (d) melting point of the solute.
Q.17. Carboxylic acids exist as dimers in
(a) vapour state, (b) in a protic solvent.
(c) all solvents,
(d) in vapour state and
Or
a protic solvent.
Carboxy acids react with NaHCO, solution and evolve
(a) O2 (b) CO () HS (d) SO
O.18. Acidified KMnO, reacts with KI to liberate
(a) H2 gas (b) 12 gas (c) HO
Or
(d) O2 gas
Which of the following is not a lanthanoid ?
(a) La (b) Sc (c) Ce
(d) Pr
626 U-LIKE Chemistry-XIl
0.19. In the equation k A eal Ki, the
=

quantity A is called
(a) Arrhenius factor
(b) Frequency factor
(c) Pre-exponential factor
(d) All the above
0.20. Freon-12 is manufactured from
(a) Wurtz reaction
tetrachloromethane by
(b) Finkelstein reaction
(c) Sandmeyer's reaction
(d) Swarts reaction
Q.21. Relative ease of dehydration of alcohols is
(a) tertiary > secondary >
primary (6) tertiary > primary > secondary
()secondary > tertiary primary >
(d) secondary > primary > tertiary
0.22. Tertiary butyl alcohol can be
(a) HSOg at 443 K
dehydrated in the presence of
() 85% HPO, at 440 K
(6) HSO, at 413 K
Q.23. Aliphatic amines on treatment with (d) 20% H,PO at 358 K
(a) nitro compound HNO, form
(b) alcohol
(c) nitrite (d) no effect
Questions 24 to 26 are Case Study Based
carries 1 mark. questions and are compulsory. Each sub-part of a
question
Q.24. Read the passage
given below and answer the following
Life ispossible due to the coordination of various questions:
example is the digestion of food, chemical reactions in
of energy. This absorption of appropriate molecules and living organisms. An
process involves
under very mild conditions.
a
sequence of reactions and all these reactions ultimately
production
This occurs with the occur in the
Almost all the help of certain biocatalysts called body
enzymes are
globular proteins. enzymes.
particular substrate. They are generallyEnzymes
and for a are
very specific for a
named after the particular reaction
upon which they work. For
example, the enzyme that catalyses compound or class of
compounds
is named as maltase. hydrolysis of maltose into glucose
CpHa2O11 Maltase 2CH1206
Maltose Glucose
Sometimes enzymes are also named after the reaction, where
enzymes which catalyse the oxidation of one substrate with
they are used. For example,
the
substrate are named as oxidoreductase simultaneous reduction of another
enzymes. The ending of the name of an
The enzyme is
following questions are multiple choice questions. Choose -ase.

G) Almost all the enzymes are the most appropriate answer

(a) globular proteins (b) fibrous proteins
(c) peptides (d) carbohydrates
(i) The enzyme that catalyses the
hydrolysis of sucrose into glucose and zymase is
(a) maltase (b) zymase () lactase (d) sucrase
(in) To carry out a biochemical reaction, needed in
enzymes are
(a) milligrams (b) grams (c) decagrams (d) kilograms
(D) The action of enzymes can be explained on the basis of
(a) reduction of activation energy.
(b) raising of activation energy.
(c) performing without change in activation energy.
(d) none of these
 Or
Which other element does cysteine contain besides carbon, hydrogen, nitrogen and oxygen ?
(a) selemium (b) sulphur ()phosphorus (d) silicon
Q.25. Read the passage given below and answer the following questions :
1he magnitude of conductivity varies a great deal and depends on the nature of the material. It
also depends on the temperature and pressure at which the measurements are made. Materials are
classified into conductors, insulators and semiconductors depending on the magnitude of their
conductivity. Metals and their alloys have very large conductivity and are known as conductors.
Certain non-metals like carbon-black, graphite and some organic polymers are also electronically
conducting. Substances like glass, ceramics, etc., having very low conductivity are known as
insulators. Substances like silicon, doped silicon and gallium arsenide having conductivity
between conductors and insulators are called semiconductors and are important electronic
materials. Certain materials called superconductors by definition have zero resistivity or infinite
conductivity. Earlier, only metals and their alloys at very low temperatures (0 to 15 K) were known
to behave as superconductors, but nowadays a number of ceramic materials and mixed oxides are
also knowm to show superconductivity at temperatures as high as 150 K.
In these questions, a statement of assertion followed by a statement of reason is given. Choose
the correct answer out of the following choices:
(@) Assertion and reasonm both are correct statements and reason is correct explanation for assertion.
(6) Assertion and reasom both are correct statements but reason is not correct explanation for assertion.
(c) Assertion is correct statement but reason is wrong statement.
(d) Assertion is wrong statement but reason is correct statement.
) Assertion (A): Cuprous oxide is a conductorwith conductivity of 1x107 S m
:Magnitude of conductivity varies with the nature of the material.
Reason (R)
() Assertion (A): In terms of conductivity, materials can be divided into conductors,
semiconductors and insulators.
Reason (R) :Graphite is a non-metallic conductor.
(Gii) Assertion (A): Glass and ceramic containers can be used in microwave oven.
Reason R) :Pure water is a non-conductor of
electricity.
i ) Assertion (A) : Superconductors are substances that show zero resistivity or infinite
conductivity.
Reason (R :Copper,silver and gold show a low value of electrical conductivity.
Or
Assertion (A): Now-a-days superconductors have been developed that can work at 150 K.
Reason (R) :Electronic conductance depends upon the number of valence electrons per
atom.
O.26. Read the passage given below and answer the following questions:
Henry's law finds several applications in industry and explains some biological phenomena.
Notable among these are:
.To increase the solubility of CO, in soft drinks and soda water, the bottle is sealed under hign
pressure.
Scuba divers must cope with high concentrations of dissolved gases while breathing air at
high pressure underwater, Increased pressure increases the solubility of atmospheric gases in

blood. When the divers come towards surface, the pressure gradually decreases. This releases
the dissolved gases and leads to the formation of bubbles of nitrogen in the blood. This block

capillaries and creates a medical condition known as bends, which are painful and dangerou

u HIKE Chemistry-XII
 to life. To avoid bends, as well as, the toxic effects of high concentrations of nitrogen in the
blood, the tanks used by scuba divers are filled with air diluted with helium (11.7% helium,
56.2% nitrogen and 32.1% oxygen).
.At high altitudes the partial pressure of oxygen is less than that at the ground level. Thisleads
to low concentrations of oxygen in the blood and tissues of people living at high altitudes
or climbers. Low blood oxygen causes climbers to become weak and unable to think clearly,
anoxia.
symptoms of a condition known as

The following questions are multiple choice questions. Choose themost appropriate answer:
T o increase the solubility of CO, in soft drinks and soda water, we use
(a) Boyle's law (b) Charles law
() Avogadro's law (d) Henry's law
() A medical condition 'bends' is caused in scuba divers because of formation of bubbles
of
(a) hydrogen (b) oxygen (c) nitrogen (d) helium
(oin) Low partial pressure of oxygen at high altitude causes the medical condition.
(a) cephalalgia 6) conjuctivitis (c) anoxia (d) bends
(io) Solubility of a
gas in a
liquid
(a) decreases with increase of temperature for exothermic
proceses.
b) increases with increase of temperature for endothermic
proceses.
(c) decreases with increase of pressure.
(d) change of temperature makes no
difference
Or
If the vapour
pressures of pure hexane and heptane at a particular
and 400 mm. The vapour temperature are 500 mm
pressure of a solution of hexane and heptane with equal mole
fraction of both will be
(a) 300 mm (b) 350 mm (c) 400 mm (d) 450 mm
SECTIONC
Note: Short Answer Questions of 2 marks each.
Q.27. How will you convert
) Propene to propan-2-ol
() Methyl magnesium bromide to 2-methylpropan-2-ol ?
Or
Give reason for higher boiling point of ethanol in
comparison to methoxymethane.
Q.28. Write the formulae of the
following coordination compounds:
0) Tetraamminediaquacobalt (I) chloride
() Potassium tetracyanonickelate (11)
Or
Indicate the type of isomerism exhibited by the following complexes and draw the structurec e
these isomers.
0 1Co(NH,)s(NO,)J(NO}2
(di) [Pt(NH(H,O)Cl
.29. A first order gas reaction
Apb, (8) 2A (8) + 25 (g) at the
temperature 400 °C has the rate
constant k=2.0 x 10s, What percentage of A,B, is decomposed on heating for 900 seconds?
.30, To what extent the electronic configuration decide the stability of oxidation states in the first
of
series
transition elements. Illustrate your answer with example.
 SECTION D
Note: Long Answer Questions of 3 marks each.
.31. WVhat
may be the stable oxidation state of the transition elements with the following d-electron
configuration in the ground state of their atoms ?
3d, 3d and 3d
Or
) What is lanthanoid contraction ?
(i) What are the consequences of lanthanoid contraction ?
Q.32. Classify the following as monosaccharide and disaccharide
Ribose, 2-deoxyribose, maltose, galactose, fructose and lactose.
Or
How are vitamins classified ? Name the vitamin
responsible for coagulation of blood.
Q.33. The rate constant for the
decomposition of N,O; at various temperatures is given below:
T/°C 20 40 60 80
10xk/s1 0.787 1.70 25.7 178 2140
Draw a
graph between In k and 1/T and calculate the values of A and E. Predict the rate constant
at 30 °C and 50 °C.
Q.34. The treatment of
alkyl chlorides with aqueous KOH leads to the formation of alcohols but in the
presence of alcoholic KOH, alkenes are major products. Explain.
SECTIONE
Note: Long Answer Questions of 5 marks each.
Q.35. ) Zn rod is dipped in 0.1 M
solution of ZnSO4. The salt is 90% dissociated at this
298 K. Calculate the electrode
dilution at
potential.
(i) Write two factors that influence the
conductivity of the electrolytes.
Or
Calculate the standard cell
potential of galvanic cell in which the
2Cr (s) +3Cd* (aq) - 2Cr3* (ag) +3Cd
following reaction takes place:

[Given F3t/Cr -0.74 V, Eca2+ /Ch -

0.04 V]
(i) Explain how rusting of iron is envisaged as
setting up of an electrochemical cell.
Q.36. () Explain the following terms giving an
example
(a) Cyanohydrin
(b) Aldol
(c) Schiffs base
(ii) Convert each of the following to benzoic acid
(a) Acetophenone
(b) Phenylethene
Or
i) Name the following according to IUPAC system.
(a) (CH3),CCH,COOH
(b) CH-CH=CH-CHO
(c) CH,COCH,COCH,
 (i) Which of the following will undergo aldol condensation and which Cannizzaro's reaction
Write the products.
(a) 2-Methylpentanal (b) Benzaldehyde
Q.37. (a) 0 What type of isomerism is shown by the complex [Co(NH;)5(SCN)J* ?
(i) Why is [NiCl,] paramagnetic while [Ni(CN),12is diamagnetic? [At. No. of Ni ==28]
(ii) Why are low spin tetrahedral complexes rarely observed ?
(b) Using the valence bond approach, deduce the shape and magnetic character or ICOUNlg/6l S*.

[Atomic number of Co =
27]
Or
(a) () For the complex [Fe(H,O),1, write the hybridisation, magnetic character and spin of the
Complex. [At. number: Fe = 26]

(7) Draw one of the geometrical isomers of the complex [Pt(en),Cl,]* which is optically
inactive.
(b) Deduce the shape and magnetic behaviour of the complex ion [Co(NH3),NO,l
[Atomic number of Co = 27]