1 Self-Evaluation Test

1 Which of the
following solutions will have the (c) breaking of protein into amino acids
highest conductivity at 298 K?
(a) 0.01 M HCI solution (d) denaturation of protein
(b) 0.1 M HCI solution 8. IUPAC name of product formed by reaction of
(c) 0.01 M CH,COOH solution methylamine with two moles of ethyl chloride is:
(d) 0.1 M CH,COOH solution 1
2. The major product of acid catalysed (a) N,N-Dimethyl ethanamine
of 1-methylcyclohexanol is:
dehydration (b) N,N-Diethyl methanamine
(a) 1-methylcyclohexane (c) N-Methyl ethanamine
(b) 1-methylcyclohexene (d) N-Ethyl-N-methyl ethanamine
(c) 1-cyclohexylmethanol 9. The CFSE of [CoCI]*- is 18000 cm,the CFSE
(d) 1-methylene cyclohexane for [CoCl,] will be:
(a) 18000 cm-l (b) 8000 cm-1
3. As per Henry's Law, Ky = plk, where 'p' is partial (c) 2000 cm-1
pressure, 'x is mole fraction of gas and Ky is (d) 16000 cm-l
Henry's Law constant. If, the concentration of 10. Which of the following statement is true? 1
N, gas in water at constant pressure increase (a) molecularity of reaction can be zero or a
fraction.
quadratically, how will the value of Ky change? 1
(a) increases linearly (b) molecularity has no meaning for complex
(b) decreases linearly reactions.
(c) remains same (c) molecularity of a reaction is an experimental
(d) decreases quadratically quantity
(d) reactions with the molecularity three are very
4. Major product obtained on reaction of 3-Phenyl rare but are fast.
propene with HBr in presence of organic peroxde In the following questions (Q. No. 11 -
12), a statement
of assertion followed by statement of a reason is given.
(a) 1-Bromo-3-phenylpropane Choose the correct answer out of the following choices.
(b) 1-Phenyl-3-bromopropane (a) Both A and R are true and R is the correct
(c) 1-Phenyl-2-bromopropane of A.
explanation
(d) 3-Phenyl-2-bromopropane (b) Both A and R are true but R is not the
correct
explanation of A.
5. A+ B dil NaOH -CH=CH- (c) A is true but R is false.
(d) A is false but R is true.
Identify A and B:
11. Assertion (A): During electrolysis of
ta) A = 1-phenylethanal, B = acetophenone aqueous copper
sulphate solution using copper electrodes hydrogen
(0) A = Benzophenone, B = formaldehyde
gas is released at the cathode.
(c) A = Benzaldehyde, B = Acetophenone Reason (R): The electrode potential of Cu+/Cu is
1

(a) A = Benzophenone, B = Acetophenone

O. KMn0, is coloured due to: 1 greater than that of H"/H,(g).
(a) d-d transitions 12. Assertion (A): Magnetic moment values of actinides
(6) charge transfer from ligandto metal are lesser than the theoretically predicted values. 1
(C) unpaired electrons in d orbital of Mn Reason (R): Actinide elements are strongly
(d) charge transfer from metal to ligand paramagnetic.
1 13. Convert:
I. Curdling of milk is an example of: 2
(a) Benzene to m-Nitro
(a) breaking of peptide linkage (b)
benzaldehyde
(6) hydrolysis of lactose Bromobenzene to benzoic acid
 14. The following results have been obtained during 21. (i) On the basis of E° values sidentify which
the kinetic studies of the reaction: 2 the following is the strongest oxidising amongst
agent. 5
P 2Q ’R 2S
Cl,(g) + 2e2CI E = +1.36 V
Initial InitialQ Init. Rate of Formation MnO, + 8H* + 5e’ Mn* + 4H.0
Exp. P(mol/L) (mol/L) of R (M min-) E° = +1.51 V
0.10 0.10 3.0 x 10o4 Cr,0; + 14H+ + 6e 2Cr+ + 7H,0
E° = +1.33 V
2 0.30 0.30 9.0 × 104
0.10 0.30 3.0 x 104
(ii) The following figure, represents variation of
(A,, ) vs Vc for an electrolyte. Here A. is the m
4 0.20 0.40 6.0 × 104 molar conductivity and c is the concentration of
the electrolyte.
Determine the rate law expression for the reaction. 150.0
15. A 5% solution of Na,SO,.10H,0(M.W. = 322) 149.8
is isotonic with 2% solution of non-electrolytic.
non-volatile substance X. Find out the molecular 149.4

weight of X. 2 mot
cm²
AS r 149.0
16. (i) Predict the geometry of [NiCN,. 1486
(ii) Calculate the spin only magnetic moment of
|Cu(NH,),* ion. 148.2
17. Explain the reason for the following: 3
147.8
(i) Transition metals and many of their compounds
are paramagnetic in nature. 147.4
(ü) Transition metals generally forms coloured
147.0
compound.
(iii) The enthalpies of atomisation of transition
metals are high. 0 .005 .010 .015 .020 .025 .030 .035
18. (a) Can we construct an electrochemical cellwith cmoL)13
two half-cells composed of ZnSO, solution (a) Define molar conductivity.
and zinc electrodes? Explain your answer.
(b) Calculate the for CI ion from the data (6) ldentify the nature of electrolyte on the basis
of the above plot. Justify your answer.
given below: (c) Determine the value of A, for the electrolyte.
A, MgCl, =258.6Scm'mol'andà Mg? =106 (d) Show how to calculate the value of A for the
Scm²moI
(c) The cell constant of a conductivity cell is electrolyte using the above graph.
0.146 cm. What is the conductivity of 0.01 M 22. (a) What happens when 5
solution of an electrolyte at 298 K, if the () Manganate ions (MnO?) undergoes
resistance of the cell is 1000 ohm? 3 disproportionation reaction in acidic
19. Give reasons for any 3 of the following observations: 3 medium?
(a) Aniline is acetylated before nitration reaction. (ü) Lanthanum is heated with Sulphur?
(b) pK; of aniline is lower than the m-nitroaniline. (b) Explain the following trends in the properties
(c) Primary amine on treatment with benzene of the members of the First series of transition
sulphonyl chloride forms a product which is elements:
soluble in NaOH however secondary amine () E°(M/M) value for copper is positive
gives product which is insoluble in NaOH. (+0.34 V) in contrast to the other
(d) Aniline does not react with methyl chloride members of the series.
in the presence of anhydrous AlCl, catalyst. (iü) C is reducing while Mn?t is oxidising,
20. Answer the following questions: 3 though both have d configuration.
(a) [Ni(H,O),}*(aq) is green in colourwhereas (iüi) The oxidising power in the series increases
in the order:
[Ni(H,0), (en)]*(aq)is blue in colour, give
reason in support of your answer. vOj < Cr,0% < Mn0,
(b) Write the formula and hybridization of the 23. Ahydrocarbon (A) with molecular formula C;Ho
following compound: on ozonolysis gives two products (B) and (C).
tris (ethane-1,2-diamine) cobalt(III) sulphate Both (B) and (C) give a yellow precipitate when
 heated with iodine in presence of NaOHwhile only
(B) give a silver mirror on reaction with Tollen's
reagent. 5 An efficient, aerobic catalytic system for
(a) Identify (A), (B) and (C).
(b) Write the reaction of B with Tollen's reagent.
(c) Write the equation for iodoform test for C.
(d) Write down the equation for aldol condensation
reaction of B and C.
24. Read the passage given below and answer the
following questions: 4 5% CuCl; 5% Phen; 2 equiv. K,CO,;
In spite of the predictions of stable noble gas
compounds since at least 1902, unsuccessful
attempts at their synthesis gave rise to the widely
held opinion that noble gases are not only noble
but also inert. It was not until 1962 that this dogma
was shattered when Bartlett in Canada published
the first stable noble gas compound XePtFs. This
discovery triggered a worldwide frenzy in this area,
and within a short time span many new xenon,
radon, and krypton compounds were prepared
and characterized. The recent discoveries show the
ability of xenon to act as a ligand. The discovery
by Seppelt's group that more than one xenon atom
can attach itself to a metal center which in the
case of gold leads to surprisingly stable Au-Xe
bonds. The bonding in [AuXe,]* involves 4 Xe
ligands attached by relatively strong bonds to a
single Au(I) center in asquareplanar arrangement
with aXe-Au bond length of about 274 pm This
discovery provides not only the first example of
multiple xenon ligands but also represents the
first strong metal xenon bond.
(Source: Christe, K.0. (2001). A renaissance in noble
gas chemistry. Angewandte Chemie International
Edition, 40(8), 1419-1421.)
(a) In the complex ion [AuXe,]*, what is ligand?
(b) What is hybridisation shown by Au in
[AuXe,j2+?
(c) What is denticityof Xe? What is coordination
number of Au?
Or
(c) Why do Xe can form complex compounds
where as other noble gases do not?
25. Read the passage given below and answer the
following questions: 4
the transformation of alcohols into carbonyl
compounds under mild conditions, copper-based
catalyst has been discovered. This copper-based
catalytic system utilizes oxygen or air as the
ultimate, stoichiometric oxidant, producing water
as the only by-product.
R! R'
ROH 5% ABAAH,; 0, Toluene; 70° to 90° C
H R2 2
1
A wide range of primary, secondary, allylic, and
benzylic alcohols can be smoothly oxidized to
the corresponding aldehydes or ketones in good
to excellent yields. Air can be conveniently used
instead of oxygen without affecting the efficiency
of the process. However, the use of air requires
slightly longer reaction times.
This process is not only economically viable and
applicable to large-scale reactions, but it is also
environmentally friendly.
(Reference:Ohkuma, I, Ooka, H, Ikariya, I, &
Noyori, R. (1995). Preferential hydrogenation of
aldehydes and ketones. Journal of the American
Chemical Society, 117741), 10417-10418.)
(a) Name the carbonyl compound formed when
ethanol gets oxidised using copper based catalyst
which can also be obtained by ozonolysis of
2-butene.
(b) Give one example of secondary allyl alcohol.
(c) Benzyl alcohol on treatment with this copper
based catalyst gives a compound A which
on reaction with KOH gives compounds B
and 'C. Compound B on oxidation with
KMnO,-KOH gives compound 'C. Identify
compounds 'A, 'B and 'C.
Or
(c) An organic compound X' with molecular
formula CH,0 on reaction with this copper
based catalyst gives compound Y which
reduces Tollen's reagent. Xon reaction with
sodium metal gives 'Z.What is the product of
reaction ofZ' with
2-chloro-2-methylpropane?