CHEMISTRY THEORY (043) - SET 1

Max. Marks:70 Time: 3 hours

General Instructions:
Read the following instructions carefully.
a. There are 33 questions in this question paper with internal choice.
b. SECTION A consists of 16 multiple-choice questions carrying 1 mark each.
c. SECTION B consists of 5 short answer questions carrying 2 marks each.
d. SECTION C consists of 7 short answer questions carrying 3 marks each.
e. SECTION D consists of 2 case —based questions carrying 4 marks each.
SECTION E consists of 3 long answer questions carrying 5 marks each.
g. All questions are compulsory.
h. Use of log tables and calculators is not allowed.

SECTION A
The following questions are multiple-choice questions with one correct
answer. Each question carries 1 mark. There is no internal choice in this
section.
Which of the following aqueous solution will have highest boiling point?
1 1
a.1.OMKCl b,1.OMK2S04 c. 2.0M KCI d. 2.0 M K2S04
Kohlrausch gave the following relation for strong electrolyte:

Which of the following equality holds true?

2 a. 1

c.

Why is the increase in radii happening towards the end of graph?

12

a.due to increase in Ionization enthalpy b.due to decrease in atomic radii

c.due to decrease in enthalpy of atomization d.due to pairing of electrons
Which of the following tests/reactions is given by aldehydes as well as ketones?
4
a.Fehling's test b.Tollen's test c.2,4 DNP test d.Cannizzaro reaction 1
The major product of acid catalyzed dehydration of I-methylcyclohexanol is:
5 a. I -methylcyclohexane b. 1-methylcyclohexene
1
c. 1-cyclohexylmethanol d. I -methylenecyclohexane

The number of ions formed on dissolving one molecule of

6 in water is 1
a.3 c.5 d.6
The oxidation of toluene to benzaldehyde by chromyl chloride is called
7 a,Etard reaction b.Riemer-Tiemann reaction 1
c.Stephen's reaction d.Cannizzaro's reaction

1
 The best reagent for converting 2-phenylpropanamide into 2-phenylpropanamine is

8
a.excess b.Br2 in aqueous NaOH
c.iodine in the presence of red phosphorus d.LiAIH4 in ether
Which of the following reaction confirms the presence of carbonyl group
(>C-O) in glucose?
9 1
a.Reaction with HI b.Reaction with hydroxylamine
c.Reaction with HCN d.Both (b) and (c)
Deficiency of Vitamin B causes:
10 a.rickets b.muscular weakness c.scurvy d.beri-beri
During protein synthesis in cells, amino acids condense (in the presence of
enzymes) through the formation of the amide link (-CONH-), or peptide bond, to
form a polypeptide chain, which then folds to form a biologically active protein.
The equation below shows the fortnation of a dipeptide, Ala-Gly, formed by
condensation of the two amino acids, alanine and glycine in a test tube.
CH30 H
o Il
H2N—C—
OH OH
I
11 1
Peptide •Ala +
Ala Gly
bond

Which of the statements is/are true for the above reaction?

(i)A dipeptide Gly-ala is equally likely to be formed by condensation of alanine
and glycine.
(ii)Water is eliminated in the above condensation reaction.
(iii)Oxygen and hydrogen is released as gases in the above condensation reaction.
a.(i) only b.(i) and (ii) only c.(ii) and (iii) only d.all (i), (ii) and (iii)
40%H2S04 Isomerisation
CH3- C CH A C1-13—
C—CH3
1%HgS04
O
12 Structure of 'A' and type of isomerism in the above reaction are respectively. 1

a.prop- I -en-2-ol, metamerism b.Prop- 1-en- I -01, tautomerism

c.Prop-2-en-2-ol,geometrieal isomerism d.Prop-l -en-2-oI, tautomerism
Assertion (A):When NaCl is added to water a depression in freezing point is
observed.
Reason (R): The lowering of vapour pressure of a solution causes depression in
the freezing point. 1
13
a.Both A and R are true and R is the correct explanation of A.
b.Both A and R are true but R is not the correct explanation of A.
C.Ais true but R is false.
d.A is false but R is true.
Assertion (A): Current stops flowing when Ecell= 0
Reason (R): Equilibrium of the cell reaction is attained.
a.Both A and R are true and R is the correct explanation of A.
14 b.Both A and R are true but R is not the correct explanation of A. 1
C.Ais true but R is false.
d.A is false but R is true.
Assertion (A): Fe acts as a reducing agent.
Reason (R): Fe state is stable due to 3d5 configuration.
a.Both A and R are true and R is the correct explanation of A.
15 b.Both A and R are true but R is not the correct explanation of A.
C.Ais true but R is false.
d.A is false but R is true.

2
 Assertion (A): Nitration of chlorobenzene
leads to the formation of m-
nitrochlorobenzene.
Reason (R): -N02 group is a m-directing group.
16 a.Both A and R are true and R is the correct explanation of A.
1
b.Both A and R are true but R is not the correct explanation of
A.
C.A is true but R is false.
d.A is false but R is true.

SECTION B
This section contains 5 questions with internal choice in one question. The
followingquestions are very short answer type and carry 2 marks each.
(i)Write the reactions happening is Leclanche cell.
(ii)Tarnished silver contains Ags. Can this tarnish be removed by placing
tarnished silver ware in an aluminium pan containing an inert electrolytic
17
solution such as NaCl.The standard electrode potential for half reaction: 2
Ag2S(s)+ 2e- 2Ag(s) + S 2- is - 0.71 V
3
and for A1 + + is -1.66V
Represent the cell in which the following reaction takes place. The value of EO
18 for the cell is 1.260V. What is the value of Ecell?
2
2Al(S) + M) 3Cd(S) -+-2A13+ (0.01M)
2-bromo-octanereacts with a\queous NaOH to give octan-2-ol as shown below.
C6H13
El—C —Br + NaOH HO —C —H + NaBr
CH3
19
2-bromo-octane 2-octanol(±) 2
a.ldentify the type of substitution reaction mechanism. Justify your answer.
b.What effect will it have on the rate of the reaction if:
(i) the concentration ofNaOH is reduced by half?
(ii) the concentration ,of2-bromo-2-methyloctane is reduced by half?
a.Write the mechanism of the following reaction:

CFL— CH2 —OH CFL = Cl-12 + 1-120

443k
b.Write the equation of the reaction för the preparation of phenol from
cumene.
(OR)
a.Complete the following reactions:
20 CH3 2
C 1-13— C — O — C 1--13+ HI

CE13

O O
Il NaBH4 H3+o
(ii) [AJ ——..>
[B]

Arrange the following:

(i)ln increasing order of basic strength:
21 a.Aniline, p-nitroaniline and p-toluidine
2
(ii)ln increasing order of boiling point:
C2H50H, (CH3)2NH, C2H5NH2

3
 SECTION C
This section contains 7 questions with internal choice in one question.
The
followingquestions are short answer type and carry 3 marks each.
(i)On the basis of EOvalues identify which amongst
the following is the
strongest oxidising agent.
C12(g) + 2e-
, EO=+l.36 V,
Mn0ö + se- + ; +1.51 V,
+ + 6 2Cr3+ + 71-120 ; EO= +1.33 V,

(ii)The following figure 2, represents variation of (Am)

vs for an electrolyte.
I-lere Am is the molar conductivity and c is the concentration
of the
electrolyte.

149 0
22
3

1470

00 0 OOS 0015 0020 0025 0030

c i(moiLF
a.ldentify the nature of electrolyte on the basis of the above plot. Justify your
answer.
O
b.Determine the value of Am for the electrolyte.
C.How is for CH3COOHcalculated?

a.Radioactive decay follows first —order kinetics. The initial amount of two
radioactive elements X and Y is I gm each. What will be the ratio of X and Y
after two days if their half—lives are 12 hours and 16 hours respectively?
23 b.The hypothetical reaction P + Q R is half order w.r.t. 'p' and first order 3
w.r.t 'Q'. What is the unit of rate constant for this reaction?
c. What is the difference between molecularity and order?
(i) When a coordination compound NiC12.6H20is mixed with AgN03 solution,
2 moles of AgCl are precipitated per mole of the compound. Write the
structural formula of the complex and secondary valency for Nickel ion.
24 (ii)Write IUPAC name of the ionisation isomer of 3
(iii)Using Valence Bond Theory, predict the geometry and magnetic nature of:

[Atomic number: Ni = 281

Give reasons:
a.Low spin tetrahedral complexes are not formed.
25 b. is an inner orbital complex whereas is an outer
3
orbital complex.
c.Give an example of co-ordination isomer pair.

4
 a.What happens when bromobenzene is treated with Mg in the presence of dry
ether?
26 b.Write the equations for the preparation of I-idodobutane from. 3
I. 1-chlorobutane
2.But-l-ene.
How do you convert the following: (Any three)
(i)Phenol to picric acid (ii)Propanone to 2-Methylpropan-2-ol
27 (iii)Phenol to anisole (iv)Propene to Propan- I -01 3

The image below shows the effect of acid and base on the aqueous ethylamine.
Fishy amine Fishy amine
smell smell

28 1 2 3 4 5
3
Solution of Add dilute Temperature Add excess Smell of
ethylamine With hydrochloric nses. smell sodium amine
charactenstic smell acid disappears hydroxide returns

a.What evidence is there for a chemical reaction between ethylamine and

hydrochloric acid?
b.Why does the smell of ethylamine disappear when hydrochloric acid is
added?
c.Why does the smell of ethylamine reappear when sodium hydroxide is added?
(Justify your answer with equations)

SECTION D
The following questions are case-based questions. Each question has an
internal choice and carries 4(1+1+1+1) marks each. Read the passage
carefully and answer the questions that follow.
PASSAGE-I
The rate of reaction in concerned with decrease in concentration of reactants or
increase in the concentration of products per unit time. It can be expressed as
instantaneous rate at a particular instant of time and average rate over a large
interval of time. Mathematical representation of rate of reaction is give by rate
law. Rate constant and order of a reaction can be determined from rate law or
its integrated rate equation.
I.What is average rate of reaction?
29 2.Write two factors that affect the rate of reaction. 4
3.(i)What happens to rate of reaction for zero order reaction?
(ii)What is the unit of k for zero order reaction?
4.Define pseudo first order reaction with an example.

(OR)

5
 PASSAGE-2
Temperaturehas a marked effect on the rate of reaction. For most of the
reactions, the rate of reaction becomes nearly double for every 10 degree rise in
temperature. The effect of temperature is usually expressed in terms of
temperature coeficient. The quantitative dependence of reaction rate on
temperature was first explained by Swante Arrhenius. Arrhenius proposed a
simple equation known as Arrhenius equation.
k=Ae-Ea/RT
This equation provides a relationship between the rate constant (k) of a reaction
and the temperature of the system. A is the Arrhenius factor or pre-exponential
factor, Ea is the activation energy and R is the gas constant.
1.The plot of log k vs X is linear with slope -Ea/2.303R.What is X?
2.What is the fraction of molecules having energy greater than activation
energy, Ea?
3.Can a reaction have zero activation energy? Justify.
4.How does a catalyst affect the rate of reaction? Explain with respect to
Arrhenius equation.
PASSAGE-I
Living systems are made up of various complex biomolecule, like
carbohydrates, proteins, nucleic acids, lipids, etc. Carbohydrates are optically
active polyhydroxy aldehydes or ketones or molecules which provide such units
on hydrolysis. They are broadly classified into three groups
monosaccharides, oligosaccharides and polysaccharides. Monosaccharides are
held together by glycosidic linkages to form disaccharides like sucrose, maltose
or polysaccharides like starch and cellulose.
Another biomolecule: proteins are polymers of u - amino acids which are
linked by peptide bonds. Ten amino acids are called essential amino acids.
Structure and shape of proteins can be studied at four different levels i.e.,
primary, secondary, tertiary and quaternary, each level being more complex
than the previous one.
Answer the following questions:
I. What is the difference between a glycosidic linkage and peptide linkage?
2.Which amino acids are called essential amino acids?
3. What are the common types of secondary structures of proteins? Write any
two forces which-stabilise the secondary and tertiary structures of protein.
4.When we cook food, do you think there is loss of nutrition. Give your
comments for or against the statement and justify your views. 4
30 (OR)
PASSAGE-2
The efficacy of Sudanese camel dromedary's raw milk on insulin doses, fasting
and post prandial blood sugars and glycated heamoglobin(HbAlc) in 30 type I
diabetic patients were evaluated for 12 months. 15 patients of control group
were given medical care, diet exercise, insulin and other group was given camel
milk which caused significant reduction in doses of insulin that was consumed
twice 250 mL per day in morning and evening. Camel milk caused reduction of
insulin dose to obtain euglycemia by 46%, fasting blood sugar was reduced by
67%, HbAlc was reduced by 37%. In conclusion, study proved that camel milk
works well in regulation of blood sugar and improvement of carbohydrate
metabolism.
Answer the following questions:
I. Which sugar is present in camel milk? Is it a monosaccharideor
oligosaccharide?
2.The deficiency of which hormone causes diabetes?
3.1s lactose optically active or not? Give reason.
4.Do you think eating more of sweets leads to be diabetic. Give your comments
for or a ainst the statement and •ustif our views.

6
 SECTION E
The following
questions are long answer type and carry 5 marks each. All
questions have an
internal choice.
a. What is the effect
of temperature on the solubility of glucose in water?
b.lbrahim collected a 10mL each of fresh water and ocean water. He observed
that one sample labelled "P" froze at OOCwhile the other "Q" at -I .30C.
Ibrahim forgot which of the two, "P" or "Q" was ocean water. Help him
identify which container contains ocean water, giving rationization for your
answer.
c.Calculate Van't Hoff factor for an aqueous solution of if the
degree of dissociation (u) is 0.85. What will be boiling point of this solution if
31 5
its concentration is 2 molal? (Kb=0.52 K Kg/mol)
(OR)
a.What type of deviation from Roult's Law is expected when CHC13and
CH3COCH3are mixed with each other? What change in the net volume of the
mixture is expected? Graphically represent the deviation.
b.The vapour pressure of pure water at a certain temperature is 23.50 mm Hg.
If I mole of a non-volatile non-electrolytic solute is dissolved in 100g water,
calculate the resultant vapour pressure of the solution.
32 a.Account for the following:
(i)Zr resembles with Hf.
(ii)Zn, Cd, Hg are not considered as transition metal.
(iii)Why is Co(ll) easily oxidised in presence of strong ligands?
b. (i)Why is d l configuration unstable in ions?
(ii)What are lanthanoids?Write their general configuration.
(OR) 5
a.Which bivalent cation in 5d transition series is most paramagnetic and why?
b.Why is Cr2+ a good reducing agent?
c.Why is Cu a colourless whereas Cu2+ blue?
d.Complete and balance the following reaction:(Acid medium)
(i) I- + Mn04—
(ii) H2S +
33 a. An organic compound A on treatment with ethyl alcohol gives a
carboxylic acid B and compound C. Hydrolysis of C under acidified
conditions gives B and D. Oxidation of D with KMn04 also gives B. B
on heating with Ca OH)2gives E having molecular formula C3H60. E
does not give Tollen's test and does not reduce Fehling solution but
forms a 2, 4-dinitrophenylhydrazone, Identify A, B, C, D and E.
b. Why is CH3CHO more reactive than C6H5CHOtowards reaction with HCN?
c.Why is CH3COOHless acidic than HCOOH?
(OR)
5
a.Write the products formed when acetone (Propanone) reacts with the
following reagents:
(i)CH3MgBr and then H30+
(ii)NH2-NH2/ethylene glycol + KOH
(iii)C6H5CHO in presence of conc.NaOH.
b.How will you distinguish between
(i)Benzoic acid and Benzaldehyde
(ii)EthanaI and Butan-2-one?

** End of Paper **