Amines

(1+5=6)
For: PU Board 2023

MCQs
1. Amongst the following the strongest base in aqueous medium is
(a) CH3NH2 (b) (CH)3N (c) (CH3)2NH (d) C6H5NH2 (2023 m)
(5 MARKS)
1. a) i) Explain Hoffmann bromamide degradation for the preparation of Aniline (2014)
ii) Give the IUPAC name of
H3C-N-CH2-CH3
H
b) What is Hinsberg reagent? Between CH3NH2 and C6H5NH2 which is more basic?
2. a) identify the reagent ‘A’ in the following reaction: (2015)
A + 2R – X → R4N+X-
b) Explain Hoffmann’s bromamide degradation reaction for the preparation of methenamine.
c) Which is more basic among aqueous solutions of aniline and ammonia? Give one reason.
3. a) Explain carbylamine reaction
b) What is the action of bromine water on benzenamine (Aniline) at room temp?
c) The pkb value of ammonia methanamine and bezenamine (aniline) are 4.75, 3.38, and
9.38 respectively arrange them in the increasing order of their basic strength. (2016)
4. a) i) Explain the reduction of nitrocompounds to amines with an example.
ii) Why aromatic primary amines cannot be prepared by Gabriel synthesis?
b) How is aniline converted into phenyl isocyanide? Write the equation. (2016s)
5. a) Name the major product formed when nitrous acid is treated with
i) methylamine
ii) aniline at low temperature
b) Explain the Hoffmann’s bromide reaction
c) Write the IUPAC name of (CH3)2N- CH2-CH3 (2015s)
6. a) How primary amine is prepared by Hoffmann bromamide degradation reaction? Write
equation.
b) i) write IUPAC name of CH3CH2NH2.
ii) Arrange the following amines in the order of their increasing basic strength in aqueous
solution. (CH3)3N,(CH3)2NH,CH3NH2
iii) complete the following equation.
273−278 𝐾
C6H5NH2 + NaNO2 + 2HCl → (2017)
7. a) Explain Hoffmann broamide degradation reaction.
b) Name the major organic product formed in the following conversion
i. When nitrous acid is treated with methyl lamine.
ii. Benzene diazonium chloride is treated with KI.
c) Which is more basic among methyl amine and aniline? (2017s)
8. a) Explain carbyl amine reaction with equation.
b) How does nitrobenzene is reduced to aniline? Give equations.
c) Write the IUPAC name of
C6H5 – N – CH3
CH3 (2018)

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 Amines
(1+5=6)
For: PU Board 2023

9. a) How is methanamine prepared by Hoffmann bromamide degradation reaction? Give

equation.
b) How is aniline converted to Benzene diazonium chloride? Give equation.
c) Between ammonia and aniline, which is more basic? (2018s)
10. a) Between CH3NH2 and C6H5NH2 which is more base? Give reason.
b) i) Name the main product when aniline is heated with alcoholic KOH and chloroform.
ii) Give the IUPAC name of (CH3)2N-C2H5.
c) Complete the chemical equation.
𝐵𝑟2 /𝑁𝑎𝑂𝐻
CH3CONH2 → (2019)
11. a) How does Primary amine undergo carbyl amine reaction? Give chemical equations.
b) How aniline is prepared by Hoffmann bromamide degradation reaction? Give equation.
c) Write the general formula of diazonium salt (2019s)
12. a) How does Primary amine undergo carbyl amine reaction? Give chemical equations.
b) How aniline is prepared by Hoffmann bromamide degradation reaction? Give equation.
c) Write the general formula of diazonium salt
13. a) Mention the I.U.P.A.C name of (CH3)2 – N – CH3.
b) How is Aniline is prepared from nitro benzene?
c) Give the equation for the conversion of aniline to 4-Bromo aniline (2020)
14. a) Write the equation and IUPAC name of the product formed when aniline reacts with
bromine water at room temperature. (2021m)
b) Write the increasing order of basicity of the following amines in aqueous solution.
NH3, (C2H5)3N, C2H5NH2, (C2H5)2NH
c) How do you prepare primary amine by Gabriel’s phthalimide synthesis? Give equation.
15. a) How do you convert methyl cyanide into ethyl amine by reduction by catalytic
hydrogenation method?
b) When aniline is treated with HNO2 at 273K-278K, benzene diazonium chloride is formed.
c) Write the equation and name the reaction.
d) Give reason: Methyl amine is more basic than ammonia. (2021m)
16. a) Explain carbylamine reaction with suitable example
b) Write chemical equation for the conversion of Nitro-benzene to aniline
c) Why primary amines have higher boiling point than tertiary amines? (2023 m)

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