EJECTIVE CHEMISTRY-XIIB ORGANIC COMPOUNDS CONTAINING NITROGEN

B
4LEVEL 1
st,
EXERCISE -I
and Nitrobenzene
Steam distillation method is useful for the purification of
1) Nitrobenzene 2) Benzene
ene 3) Aniline 4) Both Nitrobenzene and Aniline
NitroBenzene is reduced with LiAIH. The product is
ne 1) AzoBenzene 2) HydrazoBenzene
ent. 3) N-Phenyl hydroxylamine 4) Aniline
ate Among the following which is less reactive towards electrophilic substitution, reactions
1) Benzene 2) NitroBenzene 3) Aniline 4) Toluene
rm
The following is used in the preparation of floor polishes
1) Nitrobenzene 2) Aniline
xyl
3) Benzene diazonium chloride 4) Phenyl hydroxyl amine
um 5. NitroBenzene is used as a solvent,in
1) Wurtz's reaction 2) The preparation of Grignard reagent
sily 3) Friedel - Craft's reaction 4) Diazotisation reaction
2at 6. Which is used as a cheap perfume
1) Aniline 2) Ethyl alcohol 3) Acetone 4) NitroBenzene
and Amines General
lled IUPAC name of (CH),C.NH, is
1) trimethyl amine 2) 2-methyl butanamine-1
mo 4) 2-methyl propanamine-1
3) 2-methyl propanamine-2
8. Which of the following is not a tertiary anmine ?
1) triethylamine 2) trimethylamine
rate
3) 2-methyl propanamine-2 4) N-ethyl-N-methyl propanamine-1
9. Which of the following shows optical activity?
1) butanamine-1 2) butanamine-2 3) isopropyl amine 4) ethyl methyl amine
hol
10. IUPAC name of C,H,),C-NH, is
1) 3-ethyl propanamine-1 2) 3-ethyl pentanamine-2
3) 3-ethyl pentanamine-3 4) 2-ethyl pentanamine-3
ange
1, Number of saturated isomerie primary amines possible for the molecular formula C.H,N is
um, 1) zero 2) 3 3) 2 4) 4

12. Chemical formula of Hinsberg's reagent is

ence, 1) C.H SO,H 2) CH NHSO,CH, 3) CHSO,Ci 4) CH NHCOC,H,
For carbylamine reaction, we need alcoholic KOH and (CBSE PMT 92)
the 2) aromatic primary amine and chloroform
) any primary amine and chloroform
4) any amine and chloroform
3) aliphatic primary amine and chloroform
nts
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 a OBJECTIVECHEMISTRY.XIe0ECTIVE CHEMISTRY-X e
ORGANIC cOMPOUNDSs cONTAINING NITROGEN ORGANICc cOMPOUNDs cONTAINING
The substance with offensive NITROGEN
14. Aniline on acetylation
gives (Roorkee'93)
4) benzene 1) C.HCN
odour
2) CH NO,
1) phenol 2) acetamide 3) acetanilide 3) CH NH, 4) C.HNC
0. Aniline doesn't react with
15. Treatment of ammonia with excess alky1 halide gives (AIIMS'94) 1) dil. HCI
1) triethyl amine
quaternary ammonium salt 2) dil.NaOH 3) CH. CHO 4) Br,water
3) diethyl amine 4) ethyl amine
Nitrobenzene on reduction with Hydrogen in presence of Nickel
gives
1) Azobenzene
l6. Aniline on reaction with con.H.SO, gives N. If N is heated. the prduet is (AIIMS'94) 2) Hydrazobenzene 3) Phenyl hydroxyl amine 4) Aniline
1) sulphanilic acid )sulphonamide Aniline is soluble in
3) benzene sulphonyl chloride benzene sulphonic acid 1) dil.HCI
4) m-amino 2) dil.NaOH 3) Water 4) Na,CO, solution
17. Incorrect statement among the following is (MP PMT95)
33. Aniline is treated with excess of CH,I. The final product is
1) methanamine is more basic than ammonia 2) ammonia forms H-bonds
3) boiling point of ethyl amine is higher than propane 4) dimethyl amine is less basic than aniline
1) C.H,NHCH, 2) C,H,N(CH), 3) C.HNCH)I 4) CHI
18. 34. The reagent which reacts with benzene nucleus in aniline is
A primary amine on reaction with alc.KOH and dhloroform vields [AIEEE'02] 1) CHI
1) isocyanide 2) aldebyde 3) cyanide 4) alcohol 2) CH,COCi 3) CH,COC 4) Br
19. Primary amines have lower 35. Which of the following is not a property of aniline
boiling points than
1) corresponding alkanes 2) corresponding 2° and 30 amines 1) It is basic in nature 2) It gives carbylamine test
3) corresponding esters 4) corresponding alcohols 3) It can react with 3 moles of alkylhalide 4) It turns blue litmus red
20. Moiecular association is inhighest 36. Which of the following is a mixed 2° amine
1) n-propyl amine 2) trimethyl amine 3) ethyl methyl amine 4) equal in all 2) N - Methylaniline
1) Toludine 3) Dimethylamine 4) Methyldiethyl amine
21 Among isomeric amines possible for moiecular formula C.HN, corect order of basic strength is
37. The general formula of aliphatic amines is
given by
2) CHN 3) C.H N 4CH,
D propanamine-1 I) N-methyl ethanamine 1)CHN
38. The general formula of quaternary ammoniam salt is
II) N.N-dimethyl methanamine
1) RNH, 2) R,NH 3) R,N 4) RNX
1) II>I>I 2)I>I>II 3) I> II >>I 4) II >I> IV
Aniline: 39. Which of the following contains imino group NH
22. Aniline is less basic than 1) Aniline 2) 0 Toludine 3) Benzylamine 4) N methyl aniline
I mole of nitrobenzene to hydrazobenzene is
1) NH, 2) CH NH 3) N - methyl Aniline
4) All the above 40. The number of hydrogen atoms required to convert
23. Which of the following is a 1° amine 2) 1 3) 4 4) 8
1) 5
1) Tert. butylamine 2) dimethyl amine 41. Freshly prepared aniline is ?
3) N methylaniline 2) Brown 3) Yellow 4) Pale Yellow
4) N, N-dimethyl aniline 1) Colourless
24. Which functional group 42. Which of the following is true
responds to carbylamine test
basie than ammonia
1) -NH, 2) NH 1) aniline forms salts with aqueous alkali 2 aniline is more
3) -CONH, 4) N chloride with nitrie acid
25. Among the following which is more basic 3) aniline forms benzene diazonium
1) n - butyl amine 4) aniline less basic than ammonia
2) isobutylamine 3) Sec. butylamine 4) diethylamine water mainly gives
26. Impure Aniline is purified by 43. Bromination of Aniline with bromine
aniline
1) decantation tribromo aniline ) o- and p- Bromo
2) steam distilltation 1) Red precipitate of 2. 4, 6 6-tribromo aniline
4) White precipitate of 2. 4,
3) distillation under reduced pressure 4) fractional crystallisation 3) 2, 4 Dibromo aniline
-
it reacts with
7. Towards litmus, Aniline is 44. Aniline forms anilinium salt when 4) Benzoyl chloride
2) Acetyl chloride
3) Sulphuric acid
1) Acidic 2) Basic ) An alkyl halide'
3) Neutral 4) Bleaching agent
8. Which of the bonds is
following can react with an alkyl halide 45, The amine that does not fornm hydrogen 2) Neopentyl amine
1) 1° amine 2) 2° amine 1) Isopropyl amine
3) 3° amine 4) N. N- Dimethylaminoethane
4) All the above
84 3) Tertiary butyl amine 185
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 h9RGANIC cOMPOUNDs cONTAINING NITROGEN OBJECTiVE CHEMISTRY-XI OBJECTIVE CHEMISTRY-XI1B 6 ORGANIC COMPOUNDS
for
CONTAINING NITROGEN
46. The number possible the compound with 60. Which of the
of primary, secondary and tertiary amine isisomers following give(s) chloropicrin on chlorination.
formula CH,,N are
1) 4, 3, 1 2) 4. 3. 2 3) 3,2.1
4) 4, 2, 1
1) CH3-NO2 2) CH2-CH2-NO2
CH4
) , CH- NO, 4) CHa-CH2-CH2-NO2
47. In the diazotisation of aniline, the
reagent or reagents Useu CH4
1) HNO, HCI 2) NaNo.HCI at0-5°C 3) NaNO,, HNO, at 0--SC 4) HNO, only
NH2
Diazonium salts Introduction-Preparation methods:
48. In
Sn+HCI NaNO2 +HCI CuCl/ KCI
benzene diazonium chloride, the functional 61. B C The compound 'C" in the
group 1s
1)-N=N=Cl 4) -N=N NO2 0°C-5°C
2)-N=N-c 3)-N=N-C
49. Diazonium salts are formed above sequence is [C)
by
1) aliphatic primary amines CI
3) alicyclic primary amines
2) aromatic primary amines
NH2
4) heterocycli aromatic nitrogen compounds
50. Diazotisation
1) any prumary
means the conversion
amine into diazonium
of Do] NO2
salt
2) aromatic primary amine into diazonium salt
using NaNO,+HCl at ice cold temperature
using NaNO,+HCl at 60-70C 62. Which of the following will not give aniline:
3) aromatic primary amine into
diazonium salt using NaNO, +HCl at ice cold temperature
4) any prmary amine into diazonium salt using NaNO,+HCl at ice cold temperature NO2 NO
1DH+ Ele
51. Aniline can be converted into
Benzene by
Sn/HCI o] Vodilute H,SO4
1) diazotization
2) diazotization followed by treating withH,PO,
3) treating with HPO 4) diazotization followed by treating with steam NO2 NO2
LiAIH4 Fe/HC/steam
52. Which of the
1) Benzenamine
following does not give diazonium salt with nitrous acid
2) Benzyl amine
at 273K? AIH, [o
3) p-hydroxy aniline 4) o-hydroxy aniline 63. On reaction with NaNO,/HCI which of the following will give green coloured compound.
Properties-applications:
53. CH3
Which diazonium salt is stable at room
temperature
1) Benzene diazonium chloride
2) Benzene diazonium fluoroborate 1) CaHNH2 2)oNHCH,CH, 3)
CH
NH2
3) Benzene diazonium nitrate
4) Benzene diazonium bromide
54. Conversion of benzen 64. Which of the following reaction can be used to convert benzene diazoniumchloride to benzene ?
diazonium salt into chlorobenzne in presence of
1) Azocoupling reaction Cu,Cl, is called 1) SnCl2/HCI 2) CHCH2-OH 3) H20 4) HPO2
2) Sandmeyer reaction
3) Gattermann reaction
4) Shiemann reaction 65. Which of the following compound is most basic?
Action of HCI on Benzene diazonium
chloride in the presence of
1) p-chloro benzene diazonium chloride copper powder gives
3) Chloro benzene
2) o-chloro benzene diazonium
chloride 1) O2N- NH2 -CH-NH
4) o-dichloro benzene
56. One mole benzene diazonium
chloride is treated with
Now, HBr(excess) in the presence of CuBr.
volume
1) 11.2 lit.
of N, iberated at STP
2) 22.4 lit.
weighs NH
3) 5.6 lit.
57. Action of KI on Benzene 4) 44.8 lit.
diazonium chloride yields leads to carbon earbon double bond?
1) sym tri iodobenzene 2) p-di iodo benzene
66. Which of the following
3) o-di iodo benzene 4) both 2 and 3
4) iodo benzene 1) 1° amine +R -
CHO 2) 2° amine +RCO 3) 2° amine +RCHO
58. Benzene diazonium fluoro borate on heating to dryness
1) Fluoro benzene yields be prepared by Garbriel Method?
2) Benzene 67. Which of the following amine can
3) Aniline both 1 and 2
59. The compound which on reaction with aquoues nitrousacid
4) o-fluoro aniline 2) (CH)2CHNH2 3) (CH3)3CNH 4)
at low 1) CH3CH2NH2
nitrosoamine is temperature produces on oily
1) methyl amine 2) Ethylamine 68. In Garbriel synthesis the halide may be
3) Diethyl amine 4) Tertiary alkyl halide
4) triethyl amine 2) allyl halide 3) Both ofl and 2
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 OBJECTIVECHEMISTRY-XIIB ORGANIC COMPOUNDS CONTAINING NITROGEN
BJECTIVE CHEMISTRRY-XllB Primary amino group is absentin
ORGANICcOMPOUNDs cONTAINING NITROGEN alkaline solution
arter it has underon
rgoes 1) p-amino phenol 2) o-amino phenol 3) N-methyl ethanamine 4) phenyl amine
dissolve in
Which
of the following compound(s) will not N, N-dimethyl butanamine -2 is the functional isomer of
reaction with Hinsberg reagent? aniline 4) Both 1 and 2
10.
3) N, N -dimethyl 1) N-butanamine-2 2) N-methy1-2-ethyl butanamine-2
1) Diethyl amine 2) Isopropyl amine
3) trimethyl amine 4) triethyl amine
70. Which of the following statement is wrong
n-butyl amine and isobutyl amine are isomers
---
1) All amines are consider as Lewis bases 11. .
2) All primary amines exhibits functional group isomerism 1) optical 2) functional 3) chain 4) positional
3) All secondary amines exhibits functional isomerism 12. How many primary amine structural isomers are possible with the molecular formula C,H, N.
4) All tertiary amines exhibits functional isomerism 2) 2 3) 3 4) 4
1) 1
Aniline:
EXERCISE -II NHCH3
NitroBenzene HydrazoBenzene. Here the reagent is can react with a maximum of . . . . moles of CHI
3) Zn +NaOH 4) LiAIH 13
1) Sn +HCI 2) Zn +NH,4C
2) 3 3) 2 4) 1
NH 1) 4
protected by conversion into
2. In the reaction weight of NitroBenzene is 14. In the nitration of aniline the amino group is
O The equivalent
3) Diazonium salt 4) Acetyl derivative
1) Tribromo derivative 2) Isocyanide
from aniline, the reagent used is
1) M 4) 15. In the preparation of N-phenyl benzene sulphonamide
2) SOCL, 3) CHCI 4) CHSO Ci
1) HSO,
of different amines
respect to the order of basic
natures
Which of the following is correct with
3. R - N 0 and R-0-N =O are a pair of 16.
given below ?
1) Chain Isomers 2) Metamers 3) Functional Isomers 4) Tautomers
NHg > CHNH2 > (CH3}NH 24) CH3h NH>CHNH2>CGH,NH,>NH3
NH
< 1) CH NH2>
3) CHNH,>(CH3),NH>CH,NH, > NH3 CH3NH> CHNH2 >NH3>CgH NH2
Here the reagent is
is used to Aniline on large scale ?
17. Which of the following methods prepare
1) Zn + NHCI 2) Zn + NaOH 3) Sn +HCI 4) LiAIH,
A) CH NO, + 6(H) CHNH,+2H,O B) CH,NO +6(H) S HCLCHNH, + 2H,
NO
LiA Azobenzene ZnCl, D) CHCI+2NH, oar'c, C.HNH, +NH,C
5. C)CHOH,+NH, CHNH,+H,O
300c
+KOH Hyårazobenzene The ratio of the number of
hydrogen atoms required to get 1 mole of
1) A only 2) B or C 3) C only 4) A or D
azobenzene and 1 mole of hydrazobenzene Diazonium Salts:
1)4 5 of CuCN yields X. X on hydrolysis
2) 5:4 3) 1:1 18. Benzene diazonium chloride on reaction with KCN in the presence
4)2:3
yields Y. Now, Y can also be obatained from
6.
HNO HSO4 conc.
t h e main product of
the reaction 1) Toluene by the action of CI/PeCL 2) Toluene by oxidation by KMnO
100c nitration
4) Toluene by sulphonation
1) Nitrobenzene 2) o dinitrobenzene 3) 3) Toluene by
m -
dinitrobenzene 4) p -
dinitrobenzene correct statement is
1 Which of the X N, HCI where regarding X.
following staements is wrong 19. Ar.N,CIL + +
i) Shape of a Aliphatie amines is pyrmidal ii) All amines are Bronsted 1) dissolves in NaOH solution 2) it liberates H, with Na
ii) All primary amines exhibit functional isomerism iv) All bases 4) 1 and 2
1) i, i, ii, iv tertiary amines shows functional isomerism 3) it is stronger acid than acetic acid
2) i& i 3) i only is retained
4) ii only 20. During diazo coupling, the following group
Amines General
1) -N=N- 2)-N=N- 3) NH, 4) NHR
8 N,N-dimethyl butanamine-2 contains of electrophilic substitution?
1) six sp$ hybridised carbon atoms 21. Which of the following is an example
2) 2) Sandmayer reaction
3) two sp hybridised nitrogen atoms
seven sp' hybridised atoms 1) diazotisation
and 2 4) action of KCN on ArN,CI
188 4) are correct 3) diazo coupling
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 g 0BJECTIVECHEMISTRY-XI
OBJECTIVEGUEMISTRY-XIIBB6= ORGANIC COMPOUNDS CONTAINING NITROGEN
ORGANICcOMPOUNDScONTAININGNITROGEN of coupling with C
Which of the following compounds on reduction will not give primary amine
the order of ease
nicn ot following is the correct
3) Phenol
4) Chloro benzene 1) R- NO2 2)Ar NO2 3) R-CN 4) R - NC
1) Benzene 2) Nitro benzene 4) B> D>A>c be reduced in to
3) C>A>D>B
6
Nitrobenzene can
1)A>D>B>C 2) C>A>B>D
2) CH -N =N-CH, 3) CH,NHOH 4) All of these
23. Benzenediazonium salt on reaction with phenol gives 1) CH NO0
2) o hydroxyazobenzene
1) p- hydroxyazobenzene
4) p-aminoazobenzene
CH
3) m-hydroxyazobenzene
24. NN-dimethyl aniline on coupling with C.HN,CI yields
CH X' X is
1) 4-(N.N-dimethyl) amino azo benzene 2) 4-(N,N-dimethyl)
nitroso benzene
87 CH3
amino hydrazo benzene
3) 4-(N.N-dimethyl) amino azoxy benzene 4) 4-(N,N-dimethyl)
not exists
amines, intramolecular hydrogen bond does
2. In which of the
NH2
following
NH-CH3 N(CH)h CH CH CH CH3
»oJ 4)CH,-CH2- CH2 - NH
38. Hoffmann bromamide reaction involves the conversion of amides
lowing undergo fastest rate

in
under identical condtions.

to amines, which of the fol-

26. In the reaction PhSO.Cl+ EtNH, A NaOBEtherC, Then C Will be
CONH2 CONH2 CONH2
1) PhSO,NEt 4) None of these
2) PhSO NEt 3) PhSO,OH |
27. Which of the following reagents would be best for converting CgH5CONH2 to C6HsCHNH2 2o
1) LiAIH4 is ether 2) ) P2O5, heat, (ü) LiAlH4 is ether
CH3 OCH3
3) H2 & Pt catalyst 4) Aqueous NaOBr NO2
28. 39. Which compound has highest boiling point.
Following reaction is an examples of R--OH + HN, R - NH2 CH
1) Hofmann reaction 2) Curtius reaction 3) Schmidt reaction 4) Lossen reaction abi
29. Which nitroalkane will give ketone when boiled with dil HCI
N 3)
-
2
1) (CH)CHNO, 2) CH,CHNO, 3) (CH),C-CH, -NO, 4) (CH,), C-NO, H NH2
reaction with phenol.
30. Identify Z in the sequence
C,H,NH, NaNO, /HCx Cu,(CNhY
0°C O/HZ 40. Which of the following diazonium salts readily undergo diazo coupling
1) CHNH,COOH 2) CGH,cOoH N,CI NCI NO2 N,C
3) CH NHCH3 4) CH,CH,NH2 NCI
2) 3) 4)
31. Which of the 1) NO2
following will lead with cyclohexanone to give enamine? 0,N O,N O,N NO2
41. P - toluidine5 FH A, A is the above sequence.
1) (CH3) NH 2) 3) NH2 NH2 NH2
4) All the above NH,
Br Br Br Br
32. What is the end 3) 4)
product in the following sequence of reactions? 1) o 2 Br Br Br
HNO c
CH,NH CH CH3 CH CH
1) ethyl cyanide 2) Ethylamine 3) methylamine 4) acetamide 42. Identify (3) and (4) in the following series of reactions
33. In carbylamine reaction the reaction intermediate
is
1) carbocation 2) Carbanion 3) CCI CHNH,CKCsO A]AgO>B] >C]+[D]
4) CH2 CHI
34. Nitrobenzene can be converted into N phenyl hydroxylamine by 2) (CH,)C=CH,,CH,NH
1) LiALH4 1) (CH,),C-OH CH,NH2
2) NaBH4 3) Zn /
NH4Ct/H20 4) Fe / Steam
3) (CH ),N.CH,OH
4) (CH)C=CH,; CH,OH
190 APEX SERIES for Sli Ghaltanya CBSE XII 191
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 QRGANIC COMPOUNDSCONTAMNUNG NITROGEN
43. 1dentify the compound (1) in the following xiation reaction (A)-0tHs K,CO,+HSO
O
OH
NH2 OH

4) All the above

o
NH2 NH2 OH
44. Which of the following is the strongest base in SOluton.
aqueous
1) (CH)N 2) (CH,), NCH, -CH, -OH 3) CH,CH,CH,NHOH 4) (CH,),N-OH
CO
45 o N- H +
(Br2 + KOH) The product of the reaction
co O

COOH NH2
,NH2
»[o] NH2 2
COOH
3)
COOH
4)
o COOH

KEY SHEET (LEVEL 1)

EXERCISE -1
1) 4 2) 1 3)2 4) 1 5) 3 6)4 7)3 8) 3 9)2 10) 3
11) 4 12) 3 13) 1 14) 3 15) 2 16) 1 17)4 18)1 19)4 20) 1
21) 3 22) 4 23) 1 24) 1 25) 4 26) 2 27) 3 28)4 29) 4 30) 2
31) 4 32) 1 33) 3 34) 4 35) 4 36) 2 37) 3 38) 4 39) 4 40) 2
41) 1 42) 4 43) 4 44) 1 45) 4 46)1 47)2 48) 4 49) 2 50)3
51) 2 52) 2 53) 2 54) 2 55) 3 56) 2 57)4 58)1 59) 3 60)1
61) 3 62) 3 63) 3 64)4 65) 2 66) 4 67) 4
68) 3 69) 4 70) 4

EXERCISE -I
1)3 2) 4 3) 3 4) 3 5)1 6) 3 7)4 8)1 9) 3 10) 4
11)3 12) 4 13)3 14) 4 15) 4 16)4 17) 1 18)2 19) 4 20)1
21) 3 22) 4 23) 1 24) 1 25)3 26) 2 27)4 28)3 29) 1 30) 2
31) 4 32) 2 33) 3 34)3 35) 4 36)4 37)3 38) 4
41) 1 43) 4 44) 4
39) 3 40) 3
42)3 45) 3

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