OBJECTIVE CHEMIST eCTIVECHEMISTRY-XIIC

with net
optical rota
a ne
CO-ORDINATION COMPOUNDS
mixture,
primary valency of 'Fe' in the
CO-ORDINATION CON
recemic
69. A 1: 1 equilibrium mixture of d- and
1-isomers
gives
a
5.
1) 2 2) 3
complex K,Fe(CN),J
f the following compounds
followin 3) 6
mir imapo the
o-superimposabla
of zero. I ney
arc
which ol
enantiomers.
In Iron has zero 4) 4
0. Optical isomers are called enantiomorphs
or
properties. 1)Fe(CO) 2) Fe,O oxidation state
and almost identical in physical and
chemical
is identifie 3) Fe0
analysISCu by deep bne The hybridisalion of metal ion in 4) Fe,O
in qualitative square planar
71. Complex formation is an importantfeature 1) dsp2 2)sp'd complexes is
complex. [Cu(NH) (H,0) The charge on Cobalt in [Co(CN),.is
3) d'sp
NH,
salts. 4) sp
Nesseler's reagent is used for detection of NH,
or
72. ess of KOH. Complex K,[Hgl,] is cole 2) +3
1)-3
3. Nesseler's reagent is a solution of K[Hgl,] complex in exC colour les,
etal ions idisationof Iron in
3)-6
+6
74. colour of hydrate
complexes,
respective metal can be
detecte 9.
The
1) dsp2 2) sp3
K,[Fe(CN),Iis
Depending upon the characters 1S purple. 3) d'sp
is pale green. [Cu( HO), * is blue and ['1I(H,0)," bidentate ligand is 4) d'sp
Ere HLO) in diute nypo solution de 10.
A
film is dissolved 2) thiocyanate
.
the to the 1) pyridine
. In photography the unreacted AgX on
3) ethylene diammine 4) water
formation of complex, Na,[Ag(S,0,)] Vhich of the llowing is
uniform coating in
electroplatine ae
I1.
a
polynuclear compound
/6. Metal complexes releases metal slowly and thus give a
1) [Co(NH,)4 CL] CI 2) NaFe[Fe(CN)J
metal. 3) [Cr(H,O)g CIj Ci,
because it provides Ag" slowly
4) [Co NH)O),IC,
11. In electroplating of silver, K [Ag(CN), ] is used
and thus gin One mole of the complex
compound Co(NH,),Cl, gives
3 moles of ions on
dissolution in water.
uniform coating One mole of the same complex reacts with two moles of
78. Ag and Au are extracted by use of complex formation. The metal Ag or Au 1s displaced from t. AgCI(s). The structure of the complex is AgNO, solution to yield two moles of
om te 1) [Co(NH),CIJCL (AIEEE 2003)
complex in the solution by using Zn. 2) [Co(NH)CI].2NH,
Fes* has 6 coordinate 3) [Co(NH,)4 Cl1.CL.NHB 4) [Co(NH),1Cl
79. Hemoglobin is the red pigment in the red-blood cells (erythrocytes). linkage 13. The coordination number of a central metal atom in a
80. The problem of C0' pollution is the formation of carboxy hemoglobin. The bonding of complex is determined by (AIEEE 2004)
wit Fe 1) The number of ligands around a metal ion bonded by sigma bonds
CO is very strong and is difficult to dissociate. CO prevents transport of and thus CO is O, toxi 2) the number of only anionic ligands bonded to the metal ion
81. Chlorophyll is the green pigment present in the leaves of the
plants. Chlorophyll has a
tetrapymole 3) the number of ligands around a metal ion bonded by sigma and pi-bonds both
ring structure with Mg" present in the centre.
4) the number of ligands around a metal ion bonded by pi-bonds
LEVEL -I Nomenclature &isomerism
14. In the IUPAC version, the ligand OH is named as
EXERCISE-1 1) hydroxide 2) hydroxyl 3) hydroxo 4) ol
Compler Compounds 15. The formula of
. Ligand in a metal carbonyl complex is 'nitrosyl' group
1) CO2 1) NO 2) NO* 3) NO 4) ONO
2) CO
3) CoCl 4) CO2 l0, Name of 'oxalate' in IUPAC version changes to
2. In complex compounds the metal atom acts asa
1) Lewis acid 1) Oxalite 2) Oxalato 3) Oxalito 4) Oxalide
2) Lewis base
3) Bronsted acid 4) Bronsted base
3. A ligand should contain (A): Structure of [Co(NH,),1*3 ion is octahedral
ion is 6
1) odd electrons T h e coordination number of the metal
2) even number of ) Both (A) and (R) are true and (R) is the correct explanation of (A)
3) lone pair of electrons to donate electrons
4) vacant orbital to Both (A) and (R) are true and (R) is not the correct explanation of(A)
4. The oxidation state of Iron in accept the lone pair
[Fe(CN) ion
1)+1 2)+2 3) (A) is true but (R) is false
3)+3
146 = 4) zero 4) (A) is false but (R) is true
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cBSE XII
 OBJECTIVE CHEMIST
STRY
VE CHEMISTRY-XIC
unpaired d-clectronsco-ORDINATION OMPOUNDS
ihe following has maximum
Which of number of
Co-ORDINATION COMPOUNDS chemical
svmbol.
2) Fet2
indicated by its I ) Zn
(BIT)
18. Metal-Isothiocyana is 2) M-SCN
3) Ni3
Applications
4) Cu
1) M-NCS 4) M - C S N
Hacnoglobin is made up of
3) M-CNS 21.
on
the ton
) 4 haeme units and one globular protein
P t Br Ci(NO,) (NH,)}I on ionisation gives 4) NO, 2) 4 haeme units
and four
3)F 3 )2 haeme nits and one globular protein globular protein
1) C 2) Br 4) 4 haeme units
and two
Formulae of ligand Globular protein in haemoglobin is de up of globular protein
20. IUPAC Name 28
A) CO two polypeptide chains
i) Bromno ) 2) four polypeptide chains
B) CHCOO0 polypeptide chain
3) one 4) eight polypeptide chains
ii) Carbonyl
H.O 0, Geometry of orbitals around the transition metal ion in haem of haemoglobin is
ii) Benzoato
iv) Aquo0
D) Br 1) square planar arrangement 2) tetrahedral arrangement
The corect match 1s 3) plane trigonal arragement 4) octahedral arrangement
ii of moles of KI required
111
i The number to
prepare one mole of K,[ Hgl,] is
D B A C. 1) 4 2) 3 3) 2
1) D A B C 2) 4) 1
A B
3) D AC B 4) D C a1 The protein part of the Haemoglobin and non protein part of Haemoglobin are coordinated through
formula
1) N of the pyrrole 2) N-of the Histidine
21. Fac and mer isomerism is associated with the general
3) MABCD 4) M(AA)3 3) N of 2,3-dimethyl Benzimidazole 4) N of the 5,6-dimethyl Benzimidazole
1) MA X 2) M(AA),
32. In metallurgy the metal used to displace silver from its cyano complex is
22. Which of the following is an example of ambidentate ligand
1) Zn 2) Au 3) F2 4) Cl
1) CO 2) CN 3) HO 4) SO
3. Which of the following releases metal slowly which gives uniform coating in electropiating
23. LIST-I LIST I
1) Metal salts 2) Double salts
A) Haber's process 1) Cu
3) Complex salts 4) Alums
B) Contact process 2) VO 34. The metal present in chlorophyll is
C) Hydrogenation of oils 3) Pt 3) Co 4) Zn
1) Fe 2) Mg
D) Ostwaid's process 4) Fe 35. Number of dative bonds around Mg* ion in chlorophyll is
5) Ni 3) 4 4) 6
1) 2 2) 3
The correct match is
EXERCISE-II
A BC D AB C D Complercompounds
1) 4 3 5 1 2) 4 23 5 transition metal ion in a complex compound [Cr(NH),Cl,CI
he primary valency of the central
3) 4 2 53 4) 3 15 2 3) 1 4) 0
1) 3 2) 2
24. Coordination isomerism is exhibited by
in aqueous solution is
2) [CrNHJ ICo(CN)J C number of ions given by [Co(NH,),Cl,1 4) zero
3) 3
3) [Cr(en),INO, 4) (Ni(NHJ BFJ 1)1 2) 2
[Co(NH,),1Cl,
metal ion in the complex
25. Which is not amphoteric Tprimary and secondary valencies of the central
(CPM
1) A3 2)Cr*3 respectively are and 66
3) Fet3 4) 3
4) Zn2
2) 6 and 6
3)3 and 3 149
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Udents
 OBJECTIVE CHEMST OBJECTIVE CHEMISTRY-X =
Co-ORDINATION COMPOUNDS precipitate
with AgNO,
tion is
solutio. 18. LIST I LIST II CO-ORDINATION COMPOUN
4. The complex compound which does not give
3) [Co(NH),CLjCI 4)[Co(NH,),Cl) A)TI* 1) Charge transfer
phenomenon
1) [Co(NH,),CI]C, 2) [Co(NH,),1Cl, B)MnO
2) Impurities
statement regarding the eleme
X' is 4s'3d.
The wrong X is 3) S-s transition
5. C COntiguration of an element exhibits
variable valency C)F
2) it 4) d-d transition
1) it forms complexes
form coloured salts D)Gems
4) It can
5) Excitation of electron
3) it forms paramagnetic ions only
b. The oxidation state of Cr in [Cr(NH;),CI,]Cl 4) 0
(AIEEE 2005 The correct match which 1s responsible for colour
1) +3 +2
3) +1 AB C D ABC D
solution the weight of
of AgU
,
precipitated jis 1) 4 1 2 5 2) 4 1 5 2
. of AgNO,
When 1 mole
of [Co(NH,),CJ is added to excess
3) zero 4) 54 3) 4 5 1 2 4) 5 2 3 4
1) 143.5g 2) 108 g
The primary valency of Iron in K,[Fe(CN), J is satistied by 19. LIST I LIST II
8.
Four K* ions 4) Two K* ions (Complex) (Charge on co-ord. sphere)
1) Six CN ions 2) Two CN ions 3)
A) CoCly.6NH, 1) +1
9. The secondary valency of Chromium in [Cr(en),]Cl, is
1) 6 3) 2 4) 4 B) CoCly SNH, 2) +2
2) 3
10. Which of the following is wrong with respect to [Co(NH,),CIJCi, C) CoCl4NH 3) +3
1) central metal ion is Co and the ligands are NH, and CF ion
D) CoCl.3NH 4) +4
2) oxidation number of Co is +2
5) 0
3) co-ordination number of Co is 6
4) the number of ions formed when 1 mole of the compound dissolves in water is 3 moles The correct match in terms of the charge on the complex
A B C D A BC D
11. The deep blue complex produced by adding of Ammonia to
excess
CuSO, solution is
1) 3 2 51 2) 3 1 2 5
1) [Cu(NH)* 2) [Cu(NH)4 3) [Cu(NH,),* 4) Cu2+ 4) 4 3 21
3) 3 2 1 5
12. A complex in which central atom carries zero oxidation state is 20. Prop. of transition element Reason
1) [Co (NH,),CII 2) PtCI,2NH 1) Colour of ion A) unpaired e in (n-1) d orbital
3) Ni(CO) 4) Na,[(Ni(CN))I
13. K,SO,Al,(SO,)j. 24H,0 is 2) Variable oxdn. states B) Same crystal structure
1) a complex salt C) d-d- transition
2) a double salt 3) formation of alloys
3) a complex salt & double salt charge
4) a basic salt 4) paramagnetic D) high magnitude of +ve
14. Number of dative bonds in the between ns & (n--1)d shells
complex CoCl,.5NH, is E) slight energy difference
1)5 2) 6 2) 1-C, 2-E, 3-B, 4-A
3) 3 1) 1-C, 2-E, 3-A, 4-B
4) 4
15. Coordination number and oxidation number 3) 1-C, 2-B, 3-E, 4-A 4) 1-B, 2-A, 3-E, 4-B
respectively for the
complex aqueous solutions of following complex
[Co(NH,),C,JCO4 increasing order of electrical conductivity of
1)6, +3 2) +6, +2 correct
3) 6, +1 the
16. The number of 1ons formed when 4) 4, +3 entities
Cupra ammonium (Co(NH),Cl, }CI IV) K,[Pt Cl,]
1)1 2) 2 sulphate is dissolved in water 1) [Pt(NH,),1Cl4 I) [Cr(NH),]Cl
n
3) 4 3) I < I < I V < I I 4) I<II<IV <II
17 A complex of Cot having 4) zero 1) I<IV <II<l 2) I V < l I < I l < I
ligands is
molecular en, superoxide
as
nroduced. The number of
formula CoCl.XNH, whien dissolved ns
number of Cr is 6.
A complex entity
with C,0,,
C 1ons
Satistying both
in water three frdination
1) 3 2) 1 primary and
secondary valencies is rCO), (en),(O2),]. The ratio
of x : y : z 15
4)2:1:1
3) 4 3)1:2:2
150 4) zero 1)1:1:2 2)1:1:1 151
APEX SERIES for Sri
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 E
CO-ORDINATION COMPOUNDS
OBJE
|Co(NH,),CI,1
AY-IRYAI JECTIVE CHEMISTRY-XIIC
OBJEC7 h
of CO
formula ands that
co-ORDINATIONCOME
with number
The can be
43. Pick up true statement about the complex compound
2) 5
attached to Fe(Z
1) 4 26) on the
=
1) The EAN of cobalt is 39
in
in which effective
which
3) 6 basis of EAN concept
2) The complex can exhibit fac and mer isomerisn ah Complex atomic number 4)110
is not
3) The complex can show optical isomerism 1) [Ni(CN),J 2) [Fe(CN),1 equal to atomic number
of the noble
4) The hybrid state of cobalt is dsp'
3) [Ni(CO),1 gas
17. Complex EAN value 4) [Co(NHJJP
I n Aqueous solution meta aluminate ion exists as
2) Cationic complex A) Fe(CO), i) 34
1) Neutral complex
4) Anionic complex B) Fe(CN), i) 35
3) Cationic double salt
25. In the the metal six there is no
M is and c) FeCN), ii) 36
complex MCI,.5H.0. the rdination number of molecul
the free chlorid.
of hydration. Then the volume of 0.1M AgNO, solution needed to precipitate de ions iv) 37
in 200ml of 0.01M solution of the complex is
The correct match is
1) 80 ml 3) 20 ml 4) 120 ml
2) 40 ml
1) A -iv, B-i, C-ii 2) A - i, B-ii, C-ii
3) A-ii, B-i, Ci
26. Ammonia forms the complex ion [Cu(NH,) with copper ions in alkaline solutions but noti 4) A-ii, B-i, C-ii
acidic solutions. What is the reason for it?
ot in 18. Stable complex based on EAN rule
1) In acidic solutions hydration protects copper 1ons i) K,[Fe(CN)J i) [Co(NH,)CHCi, ii) [Ni(CO)J iv) K_[Ni(CNJ
2) In acidic solutions protons coordinate with ammonia molecules forming 1) i only 2) i& i only
NH4 10ns and N 3) i, ii& i only 4) all
molecules are not available Nomenclature
3) In alkaline solutions insoluble is precipitated which is soluble in excess of any alkai
Cu(OH, 39. TUPAC name of Ni(cO), is
4) Copper hydroxide is an amphoteric substance.
27. Nickel combines with 1) tetracarbonylNickel(D 2) tetracarbonyINickel (O)
a
uninegative monodentate ligand X to form a paramagnetic complex [NiX,
The number of unpaired electron/s in the nickel and geometry of this complex 1on 3) tetracarbonylNickelate () 4) tetracarbonylNickelate (O)
are respectively
(ATEEE2000 40. Potassiumhexachloroplatinate (TV) is
1) two, square planar 2) one, tetrahedral 3) two, tetrahedral 4) one, square planar 1) P,IK(C)J 2) KP(CDJ 3) KTPt(CDJd 4) K P{C)J
28. How many EDTA molecules are
required to make an octahedral complex with a
Ca* ion? 41. TUPAC name of
K,[Al(C,OJI
1) Two 2) Six
(AIEEE2006 1) potassium alumino oxalte 2) potassium trioxalato aluminate ( )
3) Three 4) one
3) potassium aluminium oxalate (11) 4) potassium trioxalato aluminate (VD
29. Which of the following is neutral molecular
complex
1) CoCl,.3NH 2) Ni(CO) 3) Pt.Cl,2NH 42. TUPAC name of Li AlH, Jis
4) All
30. Neutral 2) Lithiumtetrahydridoaluminate[]
complex among the following 1) Lithiumaluminiumhydride
1) CuSO4NH, 2) [Co(NH3),JCl 3) Tetrahydridealuminiumlithionate 4) Aluminiumlithiumhydride
3) Ni(CO), 4) [Pt(NH,)h]Clh
31. Cationic complex is is best represented as
3. The neutral complex, diammine dibromo dichloro platinum(1V)
1) Potassium ferrocyanide
2) Cryolite 1) [Pt (NH,) Br, Cll 2) [Pt Cl, Br, (NH)
3) Cuprammonium () sulphate 4) Sodium argentothiosulphate 4) [Pt (NH Cl, Br]
32. The 3) [Pt Br, CI, (NH,)>
following complex representation violates IUPAC rule
44, TUPA name of Fe(CN),* is
1)[Cu(NH,),ISO, 2) K,Fe(CN),]
EAN 3)(Co(NH,)6 Cly 4) TICl,.6H,O 1) ferrocyanide
2) hexacyanoferate (1)
4) hexacyanoferrate (I)
33. Effective atomic number of Cobalt in
the
27
complex ion
[Co(en), CL,]* is 3) ferricyanide one mole of AgCl i
2) 36 3) 33 in to llit. of CoCl, x NH,solution,
is added
excess
34. Effective atomic number of 4) 35 When AgNO, solution
[Co(NH,)JCI, is formed. What is the value of x'
1) 24 2) 27 4) 4
3) 35 3)3
152 p APEX SERIES for STI Chaitanya cBSE XIIStuden
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153
 OBJECTIVE CHEMISTRYX
CO-ORDINATION COMPOUNDS= OBJECTIVEc
CHEMISTRY-XIC =
46.
Complex
A) COCl. 3NH
Type
i) Anionic complex
Geometrical isomerism in quare planar comple
1) Ma, type complex is given by Co-ORDINATION COMPOUNDSs
2) labcd type comple
B) Na,ZnCl i) Cationic complex 3) Ma,b, type complex
C) PtCI. 5NH 4) Mb type complex
ii) Neutral complex 2ath geometrical and optical isomerism was
Bo
The correct match is 5. shown by
C-ii 4) A-ii, B-ii, C-i ) [Pt (NH,)3clh] 2) [Pt(NH,),CLI
1) A - i, B-ii, C-i
2) A-ii, B-i, C-ii 3) A-ii, B-i, 3) Pt [(en),Cl
*(A): 1UPAC name of [Co(H,),CLICI. 2H,Ois tetraaquadichlorocobalt (l) chloride. 56. (A): A cis-is has a net dipole moment zero. 4) [Pt (en),]
before ts name cis- isomers
(R):AA cis- has two
represented by Arabic numerical
Water of crystallisation is ligands the same type
of
1) Both (A) and (R) are true and (R) is the correct explanation of (A) ) Both (A) and (R) are true and (R) is the
occupying adjacent positions.
correct explanation of
2) Both (A) and (R) are true and (R) is not the correct explanation or (A) Both (A) and (R) are true and
(A)
(R) is not the correct
3) (A) is true but (R) is false 4) (A) is false but (R) is true 3) (A) is true but (R) is false explanation of (A)
4) (A) is false but (R) is true
48. (A): IUPAC name of [Pt Br,(en), ]CI, is dibromobis (1, 2-ethane diamine) platinum ((V) 57, Optical isomerism is exhibited by a complex with
chlorid
R:(en) represents ethylenediamine and it is a ligand where prefix di- is already included in 1) coordination number 4, with a bidentate ligand
its
designation. 2) coordination number 4, with two bidentate
1) Both (A) and (R) ligands
are true and (R) is the correct explanation of (A) 3) coordination number 6, with a bidentate ligand
2) Both (A) and (R) and (R) is not the correct explanation of (A)
are true 4) coordination number 6, with three tridentate ligands
3) (A) is true but (R) is false
4) (A) is false but (R) is true
58. Ligands with which linkage isomerism is possible
49. (A):
[Co,(OH),(NH),JCL is an
example of polynuclear complex compound. A) NO, B) CN C) SCN
(R) : Compound in which the number of central
metal atoms is more 1) A only 2) A & B
compound.
than one is called polynuclear 3)B &C 4) A,B &C
1) Both (A) and (R) are true and 59. Optical isomers have
(R) is the correct explanation of (A)
2) Both (A) and (R) are true and A) property of chirality
(R) is not the correct
3) (A) is true but (R) is false explanation of (A) B) almost identical chemical properties
4) (A) is false but (R) is true
50. The IUPAC name of the coordination
C) almost identical physical properties
compound K,[Fe(CN)6] D) similar rotation of plane polarised light
1) Potassium hexacyanoferrate(1) (AIEEE 2005)
2) Potassium
3) Potassium hexacyanoiron () hexacyanoferrate (I) 1) A,B,C are correct 2) B,CD are correct 3) A,C,D are correct 4) A,B,D are correct
4) Tropotassium
51. The IUPAC name of the
hexacyano iron () 60. Tdentify the correct statements among the following
complex [Co(NO,)(NH),]Cl2 is
1) pentaammine (AIEEE 2006) C r in first series of d-block has highest oxidation state.
nitrito-N-cobalt(I) chloride
2) nitrito-N-pentaamminecobalt(I) chloride ) Colour of MnO is due to charge transfer phenomenon.
3) nitrito-N-pentaamminecobalt(1I) chloride m) Zn can show variable oxidation state.
4) pentaamminenitrito-N-cobalt(1I) chloride IV) Ferromagnetism disappears in the solution of Fe
Isomerism 1) All 2) I & I only 3) I&IV only 4)I&l only
52.Example showing ionisation isomerism W h a t is wrong about the following pair of compounds? [Cr(H.O),]ICI,
and [Cr(H,0),CI} Cl,.H,O
1) [Co(NO
2) [Co(NH
(NH,)]SO, & [Co(SO,)(NH,)INO, )They are hydration isomers 2) They have different colours
),CLICI & [CO(NH),CIjC, 3) Their 0.1M aqueous solutions have same molar conductivity
3)
[Cr(HLO),Cijc, H,O &
4) [PNH [Pt CII & [Cr(H,o),cljCL2H,0
4) They have different IUPAC name
53.
[PU(NH,),CM,Pt CJ Geometrical Isomerism is observed in
When two ligands of the same 1) Tetrahedral complex 2) Square planar complex
type occupy
polyhydron, the isomer is called opposite positions to 3) Tined complexes 4) planar triangle complexes
each other in (AJEBE 2005)
1) trans- 2) cis-
a
coordina 63 shows optical
isomerism?
3) fac- Whiech of the following compound
3) ICr(C,O,) 4) [Co(CN),
154 4) mer- 1) [Cu(NH,) 2 [Zn(C),F
APEX SERIES 155
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 98 OBJECIIVECREMISTR OBJECTIVE CHEM
TRY-XIC
CO-ORDINATION COMPOUNDS
4. M-L bonds in
MISTRY-XNC Tetrapyrrole structure has
co-ORDINAT NCOMPOUNDS
carbonyl compounds posses
2) only r
character
80.
1) Pyrrole rings 2) ethylene linkage
1) only o character above 3) Both 1 and 2
of the formalion of HbO, is
3) both a and r chracter 4) none
The 4) None of the
above
1) Oxidation
2) Reduciton
0. Which of the following comnpound is expected to
be 4) CuCl 3) Oxygenation
3) MgF2 82. FelH,O),1P* is 4) Disproportion action
1) Ag SO CuF
1) Pale green complex
electron
66. Which of the number of unpaired
following has the maxin 4) Fet2 3) Red coloured complex 2) Blue coloured
1) Mgt2 2) T3 3) 4) Violet colouredcomplex
83. D Chlorophyll is a magnesium porphyrin complex complex
67. Which has the largest radi
1) Crt3 2) Mnts 3) Fet3 4) Cot3 (MP PMT Ma atom forms two covalent bonds and
two dative bonds in
o8. Which of the following elements is alloyed with copper to form Drss 1) both are wrong 2) both
correct are chlorophyll
Pb 2) Bi 3)Zn 4) Sb (AFMC 84.
Which one of the
following complexes
3) only I is correct
will consume
4) only I is
wrong
69. The oxidation state of Fe in brown ring conmplex [Fe(H,0),NOJSO, 1Ss Ag(NO,)?
more
equivalents of aqueous solution
of
1) +1 4) +4 1) Na,[CrC] 2) [Cr(HO),Ccl, (2016)
+2 3) +3 3) [Cr(HO)C 4) Na[CClH,O)
70. TUPAC name of
K,[Fe CN),J is (Ker CETD Tdentify the correct trend given below :
[Atomic No =Ti :22. Cr :24 and Mo: 42) (2016)
1) potassiumhexacyanoferrate (ID 2) Potassiumhexacyanoferrate (II) Ae of [CrH,O)J*> [Mo(H,O)P* and e of [Ti(H,0)*>
3) hexacyanoferrate ( ) 4) potassiumferricyanide 2) Ae of [Cr(H,O)*> [Mo(H,0)P*
[HHO),
71.
KFeCN)J is a
and Ae of [Ti(H,OJP* < [THOF*
(AFMC) 3) Ae of and [Cr(H,O),* < [Mo(H,0),* and Ae of
1) double salt 2) complex compound 3) neutral molecule 4) none of these (mHO)*> [TiHLO)P*
72. The oxidation number of Pt in the complex
4) of and [Cr(H,O)1* < [Mo(H,O) and Ae of (TH,O)J* < [Ti(HO)
Ae
1) +1
[Pt(C,H,)CljF is -
(MLNR) 86. Which of the following is an example of homoleptic complex ?
2) +2 3) +3 4) +4 (2016)
73. The effective atomic number of Cr
(at. no. 24) in
[Cr(NH,),JCl, is
1) [Co(NH)JCI, 2)PUNH,),CL} 3) [Co(NHCi 4) [CoNHCHC,
1) 35 (BHU) 87. Which molecule/ion among the following cannot act ligand in
)27 3) 33 4) 3t
as a comples compounds ? (2015)
74. 1) CO
Among the following series of transition metal ions the one where all metal ions 2) 3) CH 4) Br
configuration is have 3d electronic
8. The correct statement on the isomerism associated with the following complex ions (2015)
1) Ti3, V+2, Cr3, Mnt4 Ti", V4, Cr, Mnt7
2)
(CBSE PMT
75. What is magnetic moment
3) Ti4, V4, Cr?, Mnt3 4) Tit2, V*3, Cr4, Mnt a) [Ni(H,O),NH,J* b) [Ni(H,O)4(NH), and c) NiHO,NH)J*
of [FeF]3 ? .
1) (a) and (b) show only geometrical isomerism
1) 6.92 BM 2) 5.92 BM
(Orissa PMT)
3) 7.62 BM 4) 3.14 BM 2) (a) and (b) show geometrical and optical isomerism
76.
[Co(NH,), SO, ]Br and [Co(NH,),Br]SO, are pair of -- a
isomers
3) (6) and (c) show geometrical and optical isomerism
1) Ionization 2) Ligand 4) (b) and (c) show only geometrical isomerism
3) Co-ordination 4) Hydrate
77. Which one of the following colour changes from reddish
pairs of complexes has the effective atomic 0 When concentrated HCl is added to an aqueous solution of CoCl, its
transition element ? number equal to 36 for tne
pink to deep blue.Which complex ion gives blue colour in this reaction ?(2015)
1) [Co(NH),1Cl,;K,[Fe(CN,] 3) [CoCL,1 4) [Co(H,O)
2) [Co(NH),Cl,:K,[Fe(CN),] 1) [CoCi 2) [CoCI
3) [Fe(CO),1:K,[Fe(CN) symmetrically filled in both t and
e
4) [Fe(CO),1:K,Fe(CN),1 W h i c h of the following complex ions has electrons that are
Applications (2015)
orbitals? 4) FeF P
78. Porphyrin complex of heme is made 3) ]Mn(CN),
up of 1) [COF 2) [Co(NH),12+
the highest CFSE, Aoas a ligand is (2014)
1) 2 pyrrole rings and 1 Fe(11) which causes
Among the followingspecies the
one
2) 4 4) CO
3) 4
pyrrole rings and 1 Fe(11) pyrrole rings and 2 Fe(11) ) CN 2) N
3) F
4) 4 pyrrole absorb visible light? (2014)
79. The rings and 4 92. Which will most likely
carboxylic acid group attached to Fe(11) C n one the following complexes
of the
one of
1) HCO0
porphyrin
blood is
of heme in 30)
2)-CH coo At no.s
Sc= 21, Ti = 22, V =23, Zn =
3) [VONH), P* 4) Zn(NHL,
156 3)-CH coo 4)-CH-CO0 1) [Sc(HL_O) 2) [Ti(NH,),14+
157
4APEX SERIES for Srl Chaitanya APEX SERIES XII Students
cBSE XII Stude ents
ESfor SrlChaltanyacesSE
 OBJECTIVE CHEMISTRYR
CO-ORDINATION COMPOUNDS
93. u Octahedral complex of Col+ is diamagnetic. The hybridisation invlolved in the formation of
SASC
the
complex is
4) dspd
(2014)
1) spd2 2) dsp 3) dsp3
94. The correct statément about the magnetic properties of [Fe(CN),Jand [FeF%
is: (Z 26
26) (2014
=
(2014)
1) Both are
paramagnetic 2) both are diamagnetic
3).[FeCN)3is diamagnetic, [FeFJ3- is paramagnetic
4) [Fe(CN)N is paramagnetic,
[FeF13- is diamagnetic
Consider the coordination compound |Co(NH,).ICI,. In the formation of this complex, the species
which acts asthe Lewis acid is (2014)
1) [Co(NH3+ 2) Cl 3) Co3* 4) NH
96.
96. Amongest the following identify the species with an atom in +6 oxidation state :
(2014)
1) [MnOl 2) [Cr(CN) 3) Cr,O 4) CrO,Cl
KEY SHEET (LEVEL 1)E -
EXERCISE -I
1) 2 2)1 3) 3 4) 3 5) 1 6)1 7) 1 8) 2 9) 3 10) 3
11) 4 12) 1 13) 1 14) 3 15) 1 16) 2 17) 1 18) 1 19) 3 20) 1
21) 1 22) 2 23) 3 24) 2 25) 3 26) 2 27) 1 28) 2 29) 4 30) 1
31) 2 32) 1 33) 3 34) 2 35) 1
EXERCISE - II
1) 1 2) 4
3)4 4) 4 5) 3 6) 1 7) 3 8) 2 9) 1 10) 2
11) 2 12) 3 13) 2 14) 2 15) 1 16) 2 17) 2 18) 2 19) 3 20) 2
21) 1 22) 1 23) 2 24) 4 25) 2 26) 2 27) 3 28) 4 29) 4
31) 3 32) 4 33) 2 30) 3
34) 4 35) 2 36) 1 37) 4 38) 3 39) 2 40) 3
41) 2 42) 2 43) 1 44) 2 45) 4 46) 2 47) 4 48) 1 49) 1
51) 1 52) 1 53) 1 54) 3 50) 2
55) 3 56) 4 57) 3 58) 4 59) 1 60) 3
61) 3 62) 2 63) 3 64) 3 65) 2 66) 4 67) 1 68) 3
69) 1
71) 2 72) 2 73) 3 74) 4 70) 2
75) 2 76) 1 77) 3 78) 3
81) 3 82) 1 83) 2 84) 3
79) 3 80) 3
85) 3
86) 1 87) 3 88) 4 89) 2 90) 4
91) 4 92) 2 93) 3 94) 3 95) 4 96) 4