2021314412

Student # ________________________
진효엔
Name: _________________________

Assignment (Take-Home)
and it can be defined as

(You can answer either in English or Korean) Profein Es a natural Polymen

of
polyamide macro molecalecomposed
amino
bondss
1. Define a protein in polymer science language.
acid monomer connected with
pepfide 1
secondany
tertianytruturypeptede
It canform
,

though molecular forces

/
fnter
2. Compare step polymerization and chain polymerization in terms of growth mechanism,
monomer consumption, and formation of macromolecules, respectively?
연쇄중합과 단계중합을 아래 각 면에서 비교 서술하시오.
(a) 사슬성장 메커니즘; (b) 모노머 소비속도; (c) 고분자량 폴리머 생성.

10 1
sfep by
condensation sfepwise
sfepzchain slep < chain
:

닌
addifion of monomer to the V IV
chain : by
3. Fill the blanks: groving 애iy
) w 니 x 에
Dr can be very hagh

opa
6

chain
dente
.

plastics
1) Five major classifications of polymer industry are _______________, fibers
________________,
elastomers
___________________, _______________,
adhesives and _______________.
coatings
2) Two categories of plastics based on their thermal processing behavior are
Thermosefs
qhermoplasfics and ___________________.
____________________
3) Of the various methods of number average molecular weight determination based on
number average MW is most useful.
colligative properties, _______________________
Gel Permeafron Chomatography is by far the mostly widely used method of
4) _______________________________
determining molecular weight distribution.
5) The______________
Tacticify of a polymer describes regularity in the sequencing of asymmetric
isotactic
centers along the chain. Three possibility exist, called ____________ syndiotactic and
, _____________,
afacfic sequencing.
_________

4. Name and draw polymers whose intermolecular forces are principally (a) dispersion
(London) force, (b) dipole-dipole force, and (c) hydrogen bonding, respectively.

a) inn
xt c -

↓d
b)
갱요 - 3
올

t .

했
c)

Ti
1 * .

↓탄. 5

5. Most commercially important polyamides are aliphatic, whereas commercial polyesters

are mostly aromatic. Why is that?
-

polyamides have desirable ProPerfres I

highsfrangth , fhermal stability low moisture absorption
c ex ) nylon )
'

아마이드는 매우 주성을 띄고 분자간에수소결합이다는 강한 인력이 작용하므로 유연하고 무주성인 지방목과 배열될때 다양하게 널리 사용될 수있다 .

~
매우 단단하고

있다다
testers havedesiable properfies highstrength
.
, therm stablty V
; 사용이불편할수 서l

( PE 9 PBTS
.

배열될 때 mlTg 가높아져 사용될수있다 .

에스터는 강석기 극성을 띄지 않으므로mfTg 가낮아 사용이 본편할수았다 .따라서aomatic고리와 상업적으로잘
 [
chyyc . 내( ⇒

=에
+에

6. To improve processing properties, an equal weight of low molecular mass nylon 6

(degree of polymerization, n = 100) is blended with a molding grade nylon 6 (n = 500).
Assuming both materials are monodisperse, calculate the following:
가공성을 향상시키기 위해, 저분자량 Nylon 6 ( n = 100) 를 몰딩(molding) grade 의 고분자량
Nylon 6 (n = 500) 와 같은 중량비로 혼합하였다. 두 성분 고분자 모두 단분산 물질로
가정하고 다음을 계산하라.
2
하자 어개씩 있있다고 *

1) the weight-average molecular weight (Mw): 2

인
(

)113 ( 00 tn ( 13 50 48966 7
-
.

2
M
Mw - = .

) tn n .(
3000 (
( 110

2) the number-average molecular weight (Mn):

은 nn " β

Zll
3 . oot
i

33900
Mn = =
m

3) the polydispersity index (PDI) of the mixture:

마 %
M = 4890
,
-
1 44
.

.. .

7. The following viscosity data were obtained for a sample of poly(meythyl methacrylate),
PMMA, in acetone at 30 oC.
riscosity Y
cecafie n 차기울기
d
lnna
manh : C7 O ㆆ C
D04 0 . 9

[7 57 l
> 0 2n 5
ninh
0

yt
.

→ .

. ." . 어
566 . n4
=

0 . 0

쁜
.
8960

빠던
0

.
5446 ,
.
1990
531 %
1
.
.
때

For PMMA in acetone at 30 oC, [] = 5.83 x 10-5 (Mv)0.72. Determine [] and Mv for the
배융
패내
. t. a
0

sample.
.
⇒ tn = 0
5

,.
3
이며

( M) 5 일
=
1011149 =
크
=
K10 - 5
MV =
21878683 b ≈ =
la 2 × o

8. Explain how to synthesize high molecular weight PLA, poly(lactic acid) or polylactide, as a
representative biodegradable polymer, with their synthetic reaction scheme. (include two
alternative routes, i.e. direct polycondensation and ring-opening polymerization of lactide).

양 서 .
싱다 tni %
" 0

② . [서 없 %
"
매 ↑ >
- .

Comment on the stereochemistry involved in the PLA structure.

ㅇ

J 돼; -
"

넓없 . 이t .

.
.
.
. ( isotactia )
"

의 PLLA
.
"
그리고 L,D 가
섞인
[ "H

…
*대
)0 PLA 까지 합성능하다.
[
,용
+
- (
7
mfy.. . 의
Rconfiguration
'

PDLA tisotactill
0 sconfiigurationo
이

규칙적으로 섬이면 Syndiotactiy

불규칙점으로 섬이면 atactic polymev 가 합성된다
9. Answer about thermal transition temperatures of polymer, Tg and Tm:
Tg : amorpmous 한 고분자가 glassy state 에서 Vubben ) 상태로 바뀔서의 온도이다

1) Define Tg and Tm, respectively. Tm :

Erystabine 한 고분세가 Solid phase 에서 Kquiidphase 로바 i9 의 온도 이다

2) List the molecular factors that determine the Tg and explain the effect of each factor briefly.
forsional mobility 면작의 잘움직미제
가

7 torsional 해Cg가 높다.

"
hain 의
mobElity '
[
Mainsfiffness : 더 stiff 연
가높다
[g 가 높다
Volume 크다면
고 ] frpe Uolume : free 이

3) polar intaraction " 곡성인력이 크라면 Tg 가 높다 .

3
4) molecular weight : molecnlar veight 6 이 크다면 Cg가 높다.

3) What thermal instrumental technique would you use to determine Tg and Tm? Explain each
shortly.
T역을 dafermine 한다
PSC ; sample 이 어떤 온도어서 발열 는지를 측점하여 tg ,

Poly ( uiny ) aleohol ) 은

4) Account for the differences in Tg or Tm for the following pairs of polymers: 무소결합이란 ntermoleularpoar
한
아래 각 쌍의 고분자 간 Tg 또는 Tm 차이를 설명해 보라. forEe 가 작용하므로
후 작용지 않는 P
014 ( thyene oxide )
(a) Poly(ethylene oxide) of -67 oC and poly(vinyl alcohol) of 85 oC, 에비해 g 가높와
의
p 네 Mt monomer
(b) Poly(ethyl acrylate) of -24 oC and poly(methyl methacrylate) of 105 oC. →
branch 개꾸가잡막
PMMA 의 chain 이 PEA 보다
(c) Tm of poly(ethylene adipate): 54 oC and Tm of poly(ethylene terephthalate): 268 oC stiff 하므로 더
, PET의 반복구조가더 mob: ( 54 가 진 PolyLethylen adipate ) 는 반복구조가 유연해서 T 개이 Tg 가료다
a
.

Tm 이 높고 ,
~
달다
10. Define or briefly explain terms listed below:
groupol end reactive 한 Polymev 이다
1) Telechelic polymer ㅅ rubber Bhase 와
2) Thermoplastic elastomer → fhermoplastic Phense 를 응합친 Copol mer Styren butadienc block[ opolilmer 가 여비다 4 로 .

3) Hyper branched polymer branched polyme 중 branch 가 배우 많은 고분자로

→ dendrimer 라고도 한다 와

4) Polyelectrolytes 의 반복단위에 전해잘그룹을 갖는 고분자잉와

11. A student prepared a sample of poly(α-methyl styrene) and placed overnight in a vacuum
oven maintained at 120 ℃ to dry. Next morning, he found the sample disappeared
completely. What had happened to the polymer sample? Explain.
Ehain 의 공유 Volatilk 한 물질들은
높은 온도에서 Ponf 결합이 끊어지면서 열분해 되었을 것이다 또한 전공상태에서 건조 했으므로
mer .

증발하여 Oven 내의 samphe 과 진공공간의 압력 . 농도등을 평형상태로 만들고자 하는 자발적인 변화 5 일어났을 것이다 .

12. Elemental analysis of a copolymer of propylene and vinyl chloride showed that the polymer
contained 25.9% chlorine. What is the molar ratio of vinyl chloride to propylene in the
H - 서
copolymer? "

[ ] t J
'
i c
9
c
-
- -

↓↓ m .
35 45m = 136 087 62 46 f 42 o 3 n

니
. m 2
, m
,

CH 3
- 0 . 259
* 82 42 94 41 42 03 m
46 mt 03 n m = .

. ,

무
.

2
12 01 x 24 01 m
←

c'
← + s 6 03
12 0142
.
m . .
.
에

man = 1 , 1 . 713
H : 1 Xon = 3 mton
1 x 3 m t E 1 : 35 45 m
.

13. A sample of poly(ethylene terephthalate), PET, was dissolved in a solvent to give a series
of solutions of different concentrations (c). A membrane osmometer was used to measure
the corresponding osmotic pressures (p) at 25 oC. Given that a plot by p/c vs c gave an
intercept equivalent to 94.2 J/kg and the point specified by p/c = 141 J/kg and c = 8.70 x
10-3 kg/dm3 lies on the plot, evaluate (i) the second virial coefficient (A2), and (ii) the
average molecular weight (Mn) of PET molecule. (gas constant R = 8.314 J/mol·K)

은띠 +A
cP " ( 어 =
94 , 256kg (End)

ㅡ 삳
= 모 r~ 00 .g 이
. 미 4 fhud .

이
e +
재 -
다 . = 8

94 2 J/
,

Kg1

094
z5
/
o

dnpA
.

kg - 6 . 7 h 시 3( g/
46 .881kg
= 8
.
347mllx 296

)
문체
,

molfkkgr
.
C dm
A 2
= 2 9n
.
3

malfkg