Intro to OChem

Ood
O O
pop Dodo O
O O
O
g Of alkene
alcohol

cyclo

Vitamin A is aromatic as it contains a

bonds
system of
conjugated pi

D
ester
amine

O .

T
'
ester ✓
cyclohexane phenyl

3)

÷:*
:* ÷.÷i:ai÷*
i:*:
-
'Est
low
.
ii. i÷÷÷: ⇐
't 's

He
fits -
et if
y
Est
'

it
H Hs
 Conformer
4) -
when
ring flips
axial becomes equat
1 OH

at

¥I
1
a) Z

y
b) No diaster - m e r
possible
-

-
-
-

(2)
.

i
c) E

i it
µ
'

l"
.

i
(2)

6) a
) identical

9H3 fH3
LL
c

FEB b)
" " '
" H enantiomers x same
(3)
e k
CHS
µ)
-

I - -
→

Hzc -

Hzc d H 'll

c) identical
-

R l" R Coote ,

d) enantiomers

•
•

SS → RS

diastercorners

No it will not be active b/c

biological
-

, systems are

chiral t chiral molecules have different behaviour

1) Determine the # of
sigma
and
pi bonds in the
following
molecules

state atoms
the
geometry at the carbon

7- 5 3
Sigma Sigma Sigma
O pi bonds I pi - bond 2 pi - bonds

70 , 0 50 I it
30 21T
it , ,

tetrahedral C 's C 's linear

C 's
trigonal planar
= =
=

2)

3) Identify the molecular

geometry
of the carbon atoms numbered

I -

6 in the structure below :

5
CH
a) I tetrahedral
#
.

2
,
CHZ
j tetrahedral
2 .

I ✓ \3
Hsc c
3 .

trigonal planar
(I 4 .
linear

(
H2 5 .
linear
6

6 .

trigonal planar

it :-O
:@It :
"

d
1. tetrahedral

b) CHZCOOH z
y it
2. trigonal pla .

c- -
y - -
/ T o
( E .
? :
C to
'
-

-
H -
C *
'
'
' '
H H
H
H
4) Indicate numbered heteroatom 's
the electronic
geometry at each

Rec #
N'H2
→

I
:
? :-O

I - tetrahedral 2.
trigonal planar
3 . tetrahedral 4.
trigonal planar

5) Which of the
following compounds is an alcohol ?
A .
Cz Hy -

alkane

b . Cz Hs OH -

alcohol

C .

CHZCOZH -

aldehyde
d .

cHzCOzCHz -
ester

e. CH z -
O -

city - ether

6 Which of the
following sets of compounds contain ether
one
,
.

one alcohol and one ketone

a)
Twats , cygnets ,
Mats
ether

ester ketone

b)
✓ Mats ,
florets ,
Mats
ether
peroxide ketone

/¥cHz
c) I /°✓cH3 Mcas
,

ether ketone

alcohol
7 Use nomenclature to the systematic
.
rules
give name

of this compound :

↳ 5 -

methyl hexanone b/c of ketone

8) Name this
compound :

\
methyl propyl amine

~,
9) Name this compound i

I
\ -
tert-butyl cyclopentane

↳
or

1,1 -

dimethyl ethyl cyclopentane

)
10 Name this compound i

I
3 -
chloro propyl ethy ether

✓ #
O

linear tetra O
- tetra
O
a .

I I
# 4 ethyl 5-
methyl 2- hexyne
-
-

T O
tetrahedral a- letrahedrol
o

b
tetrahedral o

① trigonal planar
.

O o

# He pentanal
 O tetrahedral
O

¥f¥%
C .

2,4 -

dimethyl 3 -

pentane)

) #
a.
alkyne

b I electronic geometry of O :
trigonal
#
.

planar
II ketone
:O :

°¥③
C .

electronic Ni tetrahedral
geometry of

,
amide Oi
trigonal planar

Naming) Drawing Alkenes and

Alkynes

1
1,3 butadiene 2
µ
.

8,8 -

dimethy 4 -

nonyne
3 .

4 2 methyl 2 pentane
-

I -

hexene

5 .

⇐ ÷ .