CARBONYL COMPOUNDS (OR)

(ALDEHYDES & KETONES)

3) Ethanol 4) Propanol
CONCEPTUAL - QUESTIONS 39. When propyne is treated with aqueous
sulphuric acid in presence of Mercuric
NOMENCLATURE & ISOMERISM
sulphate, the major product is
31. IUPAC name of
1) Propanal
CH3
| 2) Propyl Hydrogen Sulphate
CH 3  CH 2  C H  C H  CH 2  CH 3 3) Propanol
|
CHO
4) Propanone
1) 4-methyl hexanal-3 40. The final product obtained when toluene is
2) 3-ethyl-2-methyl pentanal subjected to side chain chlorination followed
3) 2-ethyl-3-methyl pentanal by hydrolysis at 737 K is
4) 4-methyl heptanal 1) Phenol 2) Benzaldehyde
32. General Formula of aldehyde, ketone is 3) Acetophenone 4) Chlorobenzene
1) CnH2nO2 2) CnH2nO 41. The product formed in Gattermann-Koch
3) CnH2n+1O 4) CnH2n+2O reaction from benzene is
33. CH3-CHO and CH2=CHOH are a pair of 1) Chlorobenzene 2) Benzol chlordie
1)Position isomers 2) Chain isomers 3) Benzaldehyde 4) Acetophenone
3) tautomers 4) metamers 42. When ethyl alcohol is pased over red hot
34. Hybridisation of the carbon atom of carbonyl copper at 3000 C the formula of the product
group is
formed is (Eamcet 1994)
1) sp 2) sp2 3) sp3 4) sp3d2
1) CH3CHO 2) CH3COCH3
PREPARATION
3) C 2 H 4 4) CH3COOH
35. Isobutyraldehyde is obtained by the 43. Which of the following reactions is called
oxidation of Rosenmund reaction?
1) 2-methyl propanoic acid 1) Aldehydes are reduced to alcohols
2) 2-methyl propanol 2) Acids are converted to acid chlorides
3) Propanoic acid 3) Alcohols are reduced to hydrocarbons
4) 2-methyl butanoic acid 4) Acid chloride are reduced to aldehydes
36. Compound formed when a mixture of
vapours of formic acid and acetic acid is PROPERTIES
passed over ‘MnO’ at 3000C is
1) Acetone 2) Acetaldehyde 44. On reduction with LiAIH4 a ketone gives
3) Acetic anhydride 4) Aldol 1) 1O alcohol 2) 2O alcohol
37. When a mixture of calcium acetate and O
3) 3 alcohol 4) alkane
calcium formate is heated, we get 45. PCC is
1) Acetone 2) Acetic acid
 
3) Acetaldehyde 4) Methanol 1) C H N H CrO Cl
5 5 3
38. Ethylidine chloride on hydrolysis gives the
following compound  
2) C H N H CrO Cl
1) Acetone 2) Acetaldehyde 6 5 3
 Jr Chemistry E/M
4) Potassium ammonium tartarate
 
3) C H N H CrO Cl 55. Methyl ketones are usually characterised
5 11 3
through

4) C H N H CrO Cl
 1) Tollen’s reagent 2) Schiff’s test
6 13 3 3) Iodoform test 4) Bromine test
46. Clemmenson reduction of aldehydes and
ketones produce 56. When acetaldehyde is heated with Fehling
1) Alkenes 2) Tertiary alcohols solution, it gives a red precipitate of
3) Alkanes 4) Primary alcohols 1) Cu 2) CuO
47. Haloform test is given by the compound 3) Cu2O 4) Cu+Cu2O+CuO
1) CH3COCH3 2) C2H5COOC2H5 57. Acetone gives test with
3) HCHO 4) CH3CH2Cl 1) Fehling’s solution 2) Schiff’s solution
48. Which shows aldol condensation? 3) 2,4-DNP 4) All the above
1) CH3COOH 2) HCOOH USES
3) CH3CHO 4) CCl3 CHO 58. Which of the following is used as solvent for
CH  CHO  OH  A. then IUPAC name
cellulose acetate, nail polish
49. 3 1) Acetadehyde 2) Ethyl alcohol
of ‘A’ is 3) Formalin 4) Acetone
1) Aldol 59. Cordite is smokeless powder explosive. It
2) Prop-1-ene-2 ol is manufactured from
3) 4-hydroxy-4methyl 2-pentanone 1) Acetaldehyde 2) Acetone
4) 3-hydroxy Butanal 3) Paraldehyde 4) Mesitylene
50. When acetone is treated with Ba(OH)2 it
gives KEY
1) Mesitylene 2) Diacetone alcohol
CONCEPTUAL-QUESTIONS
3) Urotropine 4) Mercaptol
51. Aldehydes and ketones form only addition 31) 3 32) 2 33) 3 34) 2 35) 2
compounds with 36) 2 37) 3 38) 2 39) 4 40) 2
1) NH2 - NHC6H5 2) NH2OH
41) 3 42) 1 43) 4 44) 2 45) 1
3) NH2-NH2 4) HCN
52. Aldol on heating gives 46) 3 47) 1 48) 3 49) 4 50) 2
1) Crotonaldehyde 2) Acetaldehyde 51) 4 52) 1 53) 3 54) 2 55) 3
3) Aceticacid 4) Phorone
56) 3 57) 3 58) 4 59) 2
TESTS
53. C 2 H 5CHO and CH3COCH3 can be CONCEPTUAL-QUESTIONS
distinguished from one another by testing HINTS
with
33. Tautomers are obtained by rearrangement
1) Phenyl hydrazine
CH 3 CHO
2) 2,4-dinitrophenyl hydrazine 35.
|

|
CH 3  CH  CH 2 OH  [O ]  CH 3  CH  CH 3
3) Fehling solution
4) Sodium bisulphite 36. MnO
HCOOH + CH3COOH  
300 C
54. Rochelle salt is
CH3CHO + CO2 + H2O
1) Sodium tartarate
37. Ca(CH 3 COO) 2 + Ca(HCOO) 2 
2) Sodium potassium tartarate  
3) Ammonium tartarate 2CH3CHO + 2CaCO3
2
 Jr Chemistry E/M
38. CH3CHCl2 
2KOH
 CH CHO + 2KCl + elimination of water molecule
3
H 2O 53. Fehling’s solution differs aldehydes and
H 2 SO4
Ketones because it reacts with aldehydes, but
39. CH 3 - C  CH + H 2O 
HgSO4
 not with Ketones.
OH
LEVEL - I
CH 3 - C = C H 2
NOMENCLATURE
CH 3 - CO - C H 3 80. IUPAC name of  ,   -dichloro diethyl
ketone is
40. CH3 C H C l2 CH O 1. 2, 5 - dichloro - 3 - pentanone
C l2 / h r H 2O 2. 2, 4 - dichloro - 3 - pentanone
37 3K
3. 1, 4 - dichloro - 2 - pentanone
CO , HCl
41. C6 H 6 
AlCl3 ,CH 2 Cl2
 C6 H 5CHO 4. 2, 5 - dichloro - 3 - hexanone
redhot
42. C2H5OH 
copper ,300 C
 CH3CHO + H2
PREPARATION
43. In Rosenmund’s reaction acid chlorides are
reduced to aldehydes. 81. CH 3C  N  CH 3CHO
Lindlar ' s Reagents useful for this conversion is
RCOCl + H2 
Catalyst
 RCHO + HCl
/ are
44. R - CO - R + 2[H] 
LiAlH 4
 R - CH(OH) - R 1. I) SnCl2  conc. HCl ; II ) H 3O 
(2° alcohol)
46. In the Clemmenson reduction. Aldehydes and 2. II) DIBAL - H; II) H 2O
Ketones are converted to Alkanes 3. dil. H 2 SO4
4. 1 & 2
O
47. CH3 - C - group containing compounds 82. An organic compound ‘X’ gives a red
precipitate on heating with Fehling’s
48. An aldehyde (or) ketone having alpha hydrogen solution. Which one of the following
participates in aldol condensation. reactions yields ‘X’ as major product
OH   i  CH 3 MgI
49. CH3CHO   CH3CH (OH) CH2CHO 1) HCHO   ii H 2 O

(A) 
3 - hydroxy butanal 2) C 2 H 5 Br  AgOH  
50. 2CH3COCH3 
3) 2C 2 H 5 Br  Ag 2 O  
OH 40%H 2 SO 4
4) C 2 H 2  H 2 O 
1%HgSO 4 ,60 0 C

Ba ( OH ) 2
  CH3 - C - CH2COCH3
83. Acetaldehyde on reaction with Grignard
CH3 reagent and subsequent hydrolysis yields
1) Tertiary alcohol
Diacetone alcohol (Ketol)
51. With HCN aldehydes and Ketones form only 2) Primary alcohol
addition compounds where as others form 3) Secondary alcohol
condensation product. 4) Both primary and secondary alcohol
52. Aldol on heating forms crotonaldehyde with the 84. The chemicals used for preparing
acetophenone are
3
 Jr Chemistry E/M
A) C6H6 B) CH3COOCH 3 1) CH3-CH2-OH 2) CH3COOH
3) CH3-CH3 4) C2H5I
C) CH 3COCl D) Anhydrous AlCl 3  O
LiAlH 4 H /170 C
93. CH3CHO   A  B
1) A,B,C 2) B,C,D
3) A,C,D 4) A,B,D excess
 HBr
 C. In the above series of reaction
85. 3-Hydroxybutanal is formed when(X) reacts ‘C’ is
with (Y) in dilute (Z) solution. What are X, Y 1) CH3-CH2-OH 2) CH2=CH2
and Z ? 3) CH3-CH2 Br 4) CO2
X Y Z 94. Identify Z in the series CH  CH
1 CH 3CHO (CH3)2CO, NaOH O
H 2 SO4  HgSO 4  60 C
2 CH3CHO CH3CHO NaCl    Z.
3. (CH3)2CO, (CH3)2CO, HCl 1) C2H5I 2) C2H5OH
4. CH3CHO, CH3CHO, NaOH 3) CHI3 4) CH3CHO
86. Which of the following is not a condensation HgSO
CH 3C  CH 
4
 B. Then ‘B’ is
95. H 2 SO4 600
product of acetone
1) meistyl oxide 2) diacetone ammonia 1) Acetone 2) Trichloroacetone
3) acetone oxime 4)acetone cyanohydrin 3) Acetaldehyde 4) Chloral
87. Which of the following reagents converts 96. Which of the following will undergo aldol
both acetaldehyde and acetone to alkanes? condensation (IIT1998)
1) Ni /H 2 2) LiAlH 4 I) acetaldehyde
II) Propionaldehyde
3) I 2 /NaOH 4) Zn  Hg /Con.HCl III) benzaldehyde
88. Iodoform test can be answered by IV) acetone
A) CH3CHO B) CH3COCH3 1) I, II IV only 2) III only
C) C2H5OH D) (CH3)2CHOH 3) IV only 4) I & IV only
1) A only 2) B only TESTS
3) B and C only 4) All A,B,C,D 97. Legal test for acetone involves
89. “Aldol condensation” can be answered by A) Sodium nitroprusside
A) HCHO B) CH3CHO B) NaOH
C) CCl3CHO D) C6H5CHO C) O-nitrobenzaldehyde
1) All A,B,C,D 2) A, C, D only 1) A & C only 2) A and B only
3) B only 4) A and D only 3) B and C only 4) all A, B, C
90. Diacetone alcohol is 98. Indigotest for acetone involves
1)  - hydroxy butyraldehyde A) Sodium nitro prusside
2) 4-hydroxy-4-methyl-2-pentanone B) KOH
3) but-2-en-1-al C) O-nitrobenzaldehyde
4) butan-2, 4-dione 1) A and C only 2) A and B only
91. Compound ‘A’ with formula C3H6O forms 3) B and C only 4) All A, B, C
phenyl hydrazone and gives negative 99. Tollen’s reagent is
Tollen’s test. Compound. ‘A’ on reduction 1) Alkaline solution containing complex of
gives propane. Then compund ‘A’ is copper nitrate
1) a primary alcohol 2) an aldehyde 2) Ammonical cuprous chloride solution
3) a ketone 4) a secondary alcohol 3) Ammonical AgNO3 solution
LiAlH 4 HI 4) Ammonical cupric chloride solution
92. CH 3  CHO   X   Z. Then
100. Acetone and acetaldehyde can be
‘Z’ is distinguished using
4
 Jr Chemistry E/M
1) Grignard reagent 2) NaHSO 3 one  hydrogen perform aldol condensation
  
3) Ammonical AgNO3 4) PCl 5 with dilute strong base   CH  C  . ||
|
 O 
CH3
|

90. CH3  C|  CH2  C||  CH3 (diacetone alcohol)

LEVEL-1 OH O

KEY 4-hydroxy-4-methyl pentan-2-

one(IUPAC)
80) 2 81) 4 82) 4 83) 3 84) 3
91. Ketone reacts with phenyl hydrazine to form
85) 4 86) 4 87) 4 88) 4 89) 3 phenyl hydrazone but gives negative Tollen’s test
90) 2 91) 3 92) 4 93) 3 94) 4 92. LiAlH4
CH3CHO  HI
 CH3 CH2OH   C2H5I
95) 1 96) 1 97) 2 98) 3 99) 3 LiAlH 4
93. CH 3 CHO  CH 3 CH 2 OH
100) 3  0
H /170 C
LEVEL-1 HINTS   CH2  CH2
H 2 SO 4  HgSO 4
40% H SO 94. CH  CH   CH2  CH  OH
82. C2H2 + H2O  2 4
1% HgSO4 ;60 C
 60 0 C

 CH 3 CHO

OH
CH 2 = C - H H 2 SO 4  HgSO 4
CH 3C HO (X) 95. CH3  CH  CH  60 0 C


 CH 3  C  CH 3
CH 3  C|  CH 2 
83. conceptual OH
||
O

Anhydrous
84. C6H6 + CH3COCl 
 C6H5.COCH3
AlCl3
96. Aldehyde or Ketone containing minimum 1
 hydrogen underoges aldol condensation
H H 100. Acetone and Acetaldehyde can be distinguished
85. CH3 - C = O + CH3 - C = O Na ( OH ) Z by Ammonical AgNO3 because it reacts with
 
Acetaldehyde and does not react with
(X) (Y) Acetone.
LEVEL-II
OH
PROPERTIES
CH 3 - C - CH 2 - CH O
128. Which of the following carbonyl compound
H on condensation gives an aromatic com-
3 - hydroxy butanal pound
86. Acetone cyanohydrin is an addition product 1) CH 3 CH O 2) HCHO
whereas the remaining are condensation products 3) CH 3 2 CO 4) CH 3 CH 2 CH O
87. CH3CHO  Zn  Hg / HCl
  CH3 - CH3 129. Identify t he product C in the series
O Na / C2 H5OH HNO2
CH3CN   A  B
Zn  Hg / HCl
CH 3 - C - CH 3   CH3CH2CH3
Cu / 573k
(propane)  C
1. CH 3COOH
88. Alcohols of CH3  CH2  OH and CH3  CH
OH
|

2. CH 3CH 2 NHOH
type; aldehydes and ketones of CH3  C|| 
O

type perform haloform test with I2  KOH

89. Aldehydes or Ketones containing minimum 5
 Jr Chemistry E/M
3. CH 3CONH 2 1) C2H5I
2) C2H5OH
4. CH 3CHO 3) CHI3
 4) CH3CHO
130. A  H CN

B 
H 3O
 lactic acid. Identify
137. In a cannizaro reaction, the intermediate
‘A’ that will be the best hydride donor is
1) HCHO 2) CH 3 CH O
3) C 6 H 5 C HO 4) CH 3 COC H 3
131. Methylethyl ketone can be reduced to n - 1) 2)
butane by
1) The Rosenmund reduction
2) The wolff - kishner reduction
3) 4)
3) Mg - Hg, H 2 O
4) All of the above 138. Which one of the following will most readily
132. Which one of the following undergoes reac- be dehydrated in acidic condition
tion with 50% sodium hydroxide solution to
give the corresponding alcohol and acid? 1) 2)
1. Butanal
2. Benzaldehyde
3. Phenol 3) 4)
4. Benzoic Acid
133. Which of the following is less reactive to 139. What is the final product of the following
warms nucleophilic addition reactions crossed aldol condensation
1) Proponal O O
2) Acetone || ||
CH 3  C  H + CH3  CH2  C  CH3
3) Benzaldehyde
4) Acetaldehyde 


OH
  
hydrolysis
134. CO2  CH3MgCl   O
||
 H C O O 2 C a 1) C H 3C H  C H C H 2 C C H 3
A  C
a ( O H )2
  B.  D
rydistillatio n
  C. Then
‘C’ is 2) CH 3CH 2 .C  CHCH 3
1) Acetaldehyde 2) Acetic acid |
CH 3
3) Acetone 4) Chloroform
(O) Ca (OH) 2
135. CH 3CHO  A   O
 C. Then ‘C’ is
B  3)
||
CH 3  CH  C  C  CH 3
|
1) CH3COOH CH 3

2) CH3CH2OH 4) CH 3 CH  CHCH  CHCH 3

3) CH3COCH3 140. In the reaction
4) CH2=CH2
Mg  Hg
136. Identify Z in the series CH 3COCH 3 
H 2O
 A, A is

PdCl2  H 2O  CuCl2 / H
CH 3CH  CH 2  

I / OH
Y 
2 Z.


6
 Jr Chemistry E/M

1) 2)
1.

3) 4)
2.
145. Which of the folloiwng compounds neither
forms semicarbazone nor oxime?
3. 1) H  C  H
||
O
2) CH 3  C  NH  CH 3
||
O
4. 3) C H 3  C  C H 2 Cl
||
O
141. Which is enolisable? 4) CH 3  CH  CH O
1) Benzophenone |
CH 3
2) 2, 4 - pentanedione

3) phenyl - t- butyl ketone 146. 2DCDO OH   X and Y are
e
4) All the above 1) DC OO  , D 2 CHOH
142. Which of the following alkenes on reductive
2) HCOO  , C H 3 OH
ozonolysis will gives only acetone
1) C H 3 CH  CHC H 3 3) HCOO  , C D 3 OH
2) C H 3 2 C  CHCH 3 4) DCOO  , CD 3 OH
147. In the sequence
CH 3
/ NH OH
A  
2  CH 3  CH  N  OH  Re
duction
  B
3) CH 3 2 C  C \
C2H 5 A & B are
1) CH 3 CH 2 OH.CH 3 CH 2 NH 2
4) CH 3 2 C  C CH 3 2
2) CH 3 C HO, C H 3  NH  C H 3
143. Which is incorrect conversion
3) CH 3 CHO , CH 3 C H 2 NH 2
4) CH 3 CH 2 OH , CH 3  N HC H 3
1) 2) 148. The order of susceptibility of nucleophilic
attack on aldehydes follows the order
1. 10  30  20
3) 4) 2. 10  20  30
3. 10  20  30
4. 20  30  10
144. . A is Ca  OH  2
149. HCOOH  Drydistillation
 A   B,
find B.
1. CH 3CHO
7
 Jr Chemistry E/M
2. HCHO
3. CH 3COCH 3 130.

4. CH 3COOH

NH 2 NH 2
131. Methyl ethyl ketone 
OH
 n-butane
CH 3

150. The compound CH 3 - C = CH - C H 3 on reac-

tion with NaIO4 in the presence of KMnO4 CHO CH2OH
50% NaOH
gives 132.
1. CH3COOH COO+Na-
+
2. CH3COCH3 + CH3COOH
3. CH3COCH3 + CH3CHO
Aldehydes having no α - hydrogen(s) undergo
4. CH3CHO + CO2
disproportionation in presence of strong concen-
151. Reaction of butanone with
trated alkali to form alcohol and acid.
methylmagnesium bromide followed by hy-
NaOH
drolysis gives 2C6 H 5 CHO 
 C 6 H 5 CH 2OH + C 6 H 5 COONa
alcohol sod. salt of acid
1. 2-methyl-2-butanol
2. 2-butanol 133. The carbon atom of the carbonyl group of
3. 3-methyl-2-butanol benzaldehyde is less electrophilic than carbon
4. 2,2-dimethyl-1-butanol atom of carbonyl group of other carbonyl com-
pounds given. The polarity of the carbonyl group
KEY is reduced in benzaldehyde due to resonance.
LEVEL-II Hence it is less reactive.
followed Ca OH
128. 3 129. 4 130. 2 131. 2 134. CO2  CH3MgCl 
byH O
CH3COOH 
2
 2

132. 2 133. 3 134. 1 135. 3  HCOO 2 Ca

136. 3 137. 3 138. 1 139. 3 dist.
 CH3COO 2 Ca   CH3 CHO
140. 1 141. 2 142. 4 143. 4
135. CH 3 CHO 
O
CH 3 COOH    
Ca OH
144. 1 145. 2 146. 4 147. 3  2

148. 2 149. 2 150. 2 151. 1  CH 3 CO O 2 Ca   CH 3 COCH 3

Wacker's
LEVEL-II HINTS 136. CH3  CH  CH2 
process
 CH3  C CH 3
O
||

I2

OH
 CHI 3
128. Acetone gives aromatic compound mesitylene 137. The methoxy group being electron - releasing
on condensation with conc. H 2SO 4 group makes the release of hydride group more
easy.
138. The compound
CH 3 COCH 2 C H OH  C H 3 ,  ,  - keto hydroxy
3 CH 3 COCH 3  conc.H
 2SO
 3H O
4
2
compound , will be the most readily dehydrated.
139. CH 3 C H O  H 2 CH.C H 2 CO CH 3 K 
OH


CH 3 C H  CHCH 2 .C OCH 3
141. 2, 4 - pentadiene contains   H  atom and
8
 Jr Chemistry E/M
therefore it is capable of showing tautomer-  NH 2  NH 2 heat

BaCO3
A   B   C  ,
ism. KOH

143. CH 3 CO OH is weak acid hence not suitable. Product (C) obtained is :

144. N aBH 4 / m ethanol - CHO is reduced to 1. CH 3  CH  CH  CH 2
 CH 2 OH
145. CH 3 CON HCH 3 compound neither forms semi
carbazone nor oxime because it is a substituted 2.
amide .... while other compounds have carbonyl
group hence, they form semi carbazone (or)
oxime.

146. 2DCDO OH


 DCOO  CD 3 OH 3.

147. CH 3  CHO  NH
  CH 3 CH  N  OH
2 OH
 H 2O


LiAlH 4
 CH 3CH 2 NH 2  H 2 O
CH3
150. CH3 - C = CH - CH3  KNaIO
 4
CH 3 COCH 3 + CH 3COOH 4.
M nO 4

151. Conceptual

169.Which of the following does not react with

LEVEL-III NaHSO3 (sodium bisulphite) :
PROPERTIES
165.In which of the following compounds the
methylenic hydrogens are the most acidic ?
1.
1. CH 3COCH 2CH 3
2. CH 3CH 2COOC2 H 5
3. CH 3CH 2CH  COOC2 H 5 2
2.
4. CH 3COCH 2CN
166.Which of the following gives iodoform test ?
1. CH 3COOH 2. C2 H 5CHO
3.
3.  CH 2OH  2 4. None of these
167.Which of the following pairs cannot be
differentiated by Tollen’s reagent ?
1. Benzaldehyde and benzyl alcohol
2. Hexanal and 2-hexanone 4.
3. 2-Hexanol and 2-hexanone
4. pentanal and diethyl ether
168.
170.

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2.

3.

Compound (C) can show geo

metrical isomersm.Product (E) of the

reaction will be : 4.

172.Arrange the following carbonyl compounds

in decreasing order of their reactivity in
1. nucleophilic addition reaction :

2.

3.

4.

171.

, End

1. ii>iii>i>iv 2. ii>i>iv>iii
product (C) of reaction will be : 3. iii>ii>i>iv 4. iii>i>iv>ii
1.

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173.

products,identify the product :

1.

; 2.

Product (E) is :

1. Nylon 6 2. Nylon 66
3. Styrene 4. Polystyrene 3.
174.
NH 2OH H 2 SO4
( A) 

( B )  

H 3O
(C )  ( D )  ( E )


CHCl3 4.
( E ) 
KOH / 
CH 3  N  C

SOCl2 ( i ) PhMgBr ( excess ) H

( D )   ( F )  ( ii ) H 
 (G )  (H )


177. , Product of

this Cannizaro reaction is :

CH 2 I 2
( H )   1. D  CO2  CH 2  CH 2 DOD
Zn / Cu

Molecular weight of compound (A) is :

1. 58 2. 120 3. 60 4. 182
10% NaOH
H2
175. CH 3CHO 
0  
    A :
5 C Ni
Product (A) of the reaction is :
1. Propanol 2. Ethanol
3. Butanol 4. Pentanol
176.The reaction
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2. H  CO2 D CO2
3. D  CO2  CH 2 DOH
4. D  CO2  CHD2OH
OH 
178. CH 3CH  CHCHO 
AldolCondensation


  A, A is :
1. CH 3  CH  CH 3 CHO

2. CH 3CH 2CH 2  CH  CH  2 CHO

3. CH 3  CH 2CH 2 3 CH  CH  CHO
4. none is correct 171.

KEY
LEVEL-III
166. 4 167. 3 168. 3 169. 3
170. 3 171. 1 172. 2 173. 1
174. 1 175. 3 176. 3 177. 3
178. 1
LEVEL-III-HINTS 174.  A  CH 3  CO  CH3
NaOI
166. CH 3  CH 2  OH    C  CH3  CO  NH  CH3
CH 3  CHO  NaOI 
 H CO2  CHI 3  D  CH 3  CO  O  H
167. Tollen’s is used to differentiad aldehyde  E  CH 3  NH 2  F  CH 3  CO  Cl
and ketone.

68.

169. NaHSO3 WILL REACT WITH ALDEHYDE AND

METHYLKETONE ONLY. NaOH
175. CH 3  CHO  CH 3  CH
H 2 / Ni
 CH  CHO 
170. CH 3 CH 2  CH 2  CH 2  OH
176. Intramolecular cinnizaro reaction

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