Single Digit Integer Type 1. The number of reactions among the following. as ‘writen, could deseribe clementary reaction. is () CL +CO> COKly r= KICLP? ICO} (ii) PCL, + Cl, + PC: (PCI) (Ch) (ii) 2NO+ Ty S NO+HLO INO} Hb iv) 2NO 10, > 2NOx: KINOF [03] (x) NO+ 0; NO;+ 03: r= K [NO] [O3) 2. The following mechanisms are proposed for the reaction CO + NO, > CO, + NO, at low temperature Mechanism 1 2NOy2N;0, (fast) N,0,+2CO+2C0;+3NO (slow) ‘Mechanism 2: 2NO, > NO; 1 NO (stow) NO,+CO+NO,+CO, (fast) Who hee ene ith tne obered tee rE = gu 3. Forthe reaction 3BrO~-> BrO,- + 2BF aqueous solution, the value of the se ste constant (1 BrO°) ne rte awe fon — \as found to be 0.06 M's !. The rate constant in M's. the rate law iswriten as+ 22600) Girl eee rarce isa M's and as+ ish M's dr value of (a +) x 1003s In a ccrtain polluted atmosphere con at a stoady:state coneentration of 2 x the hourly production of Oy by all sone wis estimated as 7.2 10° M. If only mechanism tor the destruction of O15 second order reaction, them the rate constant (in ml mots!) for the sestruction reaction is For the seaction 2NO(e) + Hula) > NsOl) + 1,049, the vatve of 32 was found to be 1.5 as Yor a pressure of 372 Pa for NO and 0.25 Pa fora pressure of 152 Pa for NO. the pressure of II, being constant. If pressure of NO was kept constant the vale of 4 yas found to be 1.60 Pas "fora pressure of 289 Pa for H, and 0.79 Pa ST yea presse af 14d Pa for Hi HF he omer of reaction with respect to NO and ITs are a and &, respectively, then the value of (a +) 18% ¥ 10, a. For « chemical resotion A = B-> Products, the confers one wilh respect to euch And B.'Lhe sum fof and yf the Fall nia ic as follows Rate IA BI tmel PS) (wot) tmot 110) 20 0.05) 040 . 9.05) sn oan ’ In the presonce of excess thioeyanate ion (SCN ) the following reaction is first-order in chzomium, (UD son, Cr™: the rate constant is 9.0% 107 = Cx'(ag) +SEN (ae) + Cr'SENF (aa) 180.0% reaction is requited to obtain a noticeable colour from the formation of the Cr{SCN)* ion. Useu ow anstay bcs ste exited? (la 5= 1.62) | he Teaction of thtoacetamide with water sshown Dy the equation below CH,CQNIL fag) +10 11,8009) = CII,C(O)NTI aa) ‘The sate of regetion i given by the sate lw Rate = K[H,O-TCH,C(S)NFA]. Consider 1 L of solution thot is 020 M in CH,C{S)NH, and 0.15 M ia HCL SC. For each af the changes listad hates, the number of changes thar decreases the rate of” reaction is (i) @ 40 g sample of NaWIL is added to the solution, (i) 500 ml of water is added to the solution. i) the 0.15 M HC solution is replaced by 0.15 M acetic acid sulution, (iv) the reaction is carried out at 38°C instead of 25 1f0.01¢ of a substance undergoing decomposition 4s consumed in | ms when the concentration 1s (0.02 M and in 0.25 ms when the concentration is 0.04 M. The order of reaction is Ethylene is produced us CyHy > 2C;Hy. The rate xs a will the molar ratio of tho etaylono to eyetobustane inthe venction mixture attain the-vahus 1.7 (hn 2 02.1 3= 1.10) A viral preparation was inactivated in 2 chemical bath, The inactivation process was found tobe fist constant is In what time Gin hows) 2 13. u 16, order ia virus concentration and at the beginning of the experiment, 2.0% of the virus was found to be inactivated per minute. If the rate constant for the inactivation process is K'min ', then the value of 400 Kis Hydrogen pevwside in aqueous solution decomposes by a fisi-onder reaction to water and oxygen. he rile constant lor this decomposition 7.50 = 104s | Wissk quay UL Mal Git J) is initially Libetated per second from2,0 Lof solution that is 0.02 M of H,0.7 Given dyif of HO.) = 187.0 k3/mol aad 9/17 11,01) = =257.0 kno. An oplically active drug has one chiral vente and only dex rorolslory isomer is elective, Moreover, it becomes ieffective when its optical activity is veduced to 404) of the otiginal. Ie was found that mutarotation of this drug was firstorder slots The reaction with rate constant —* BL expiration time ofthe drug (in yess) is (in 2=0.7, In3= 1.1. la5=1.6) For the reaction Aig) —» nB(g), tie rate eonstant is G93 10 5°, The seautiu i petfonused at coustant volume and temperature, starting. with pure A(g) If after 1000 sfrom the start of reaction, Ue pressure of system becomes 8 tie tt iii pressure the value of zis The acidic obs of ety acta in agusons solution infin order with expec to ety acetate Upen varying the pll of soltion, the fstorder rate constant aries as flies iW 7 Ko? ty 10 w 100 IF the onda of rection with respect to Hise and the value of tho rate constant {in M's) is.y, thon dhe value w! G9) 8 ‘The complex [Co(NIy)eL]** reocts with water os [CMNH,) FI + HO [CoiNH,),(H.O) ‘Theratz of reaction maybe givenasr=Kicomplex!" (IP. The reaction is acid catalysed and hens, THF] does uo eiuge doting Ute action, Thm the rate may be given as r= K'Tcomplex}* where = K(H*. The value of (a + b)i8 K lex} (H") fiath tyg(hd cM dorm i920 o2m mm osn. 19 20, IF fora reaction A + products the concentration OFA STE Ce Coy Cy gy woe ate ME interval 137 40 Wham aia constant and O ae 1, The order of reaction is Dissociation of salt A,B,(ag) in yater Follows firs- onder kinetics A,B(aq) 24™(aq) + 3B (aq). Stoctag fron (= 0, a Jelnive volun of sulativa is taken at different instant and its esmotie rise is measured, If the osmotic rise was ? mm at r= 0 10 min, then the value of © is, y whore 1 = osmotic pressure of solution (in Pascal) at (= 20 minutes and y= f,. of the dissociation reaction ((= min) [Civen: Density of finsl solution in each case = 1.0 gin. ¢ = 10 mvs) AA cuhatomer A. undergoes a mserion such thar its concentration at any time 1 (in seconds) can be 1 ord rate of disappearance of in 109M 54) at the concentration, [A]=0.2 Mis and 6 mm at 7 represented by the cquation [4]! = In onder to determine the otder of reaction Ae) = 2Kg), the vapour density of the system is ctcrmince at diffrent stagcs of reaction st constant temperature. The reaction is started with pure A(g). From the following data, the order of reaction is as fll. “Tine (ala) v.30 Vaponr density 2 sw a mM 25, In the reaction A > Products, the rate is doubled \when the concentcation of 3s quadrupled. IF 20s ff the reaction cerns in 84/7 by thea howe long. hours) would it take tor the completion of next 50% A gaseous compound ‘A’ decomposes Simwlliievusly lulu gaseous produsts“B', “Cau DY with the rate constants 3.x 10 $3 x 1 ST and 19330 107 1, respectively I only Ao) ‘ats present initially ad pressure oP 13,89 sim amid ‘the reaction is performed at constant volume and \emperature, the partial pressure (in uli) of Bla) Jn the reaction misture alter 100 § froma the star af action Consider two firstorder reactions [und IL. The Frequency factor of T iy 100 times that of Th, the activation energy of 1 is 4.606 keal higher tha Wal UF Le AF ube eatiy oF sate wuutstants for alae reactions [and IT is x: | at 227°C, then the value of xis If the activation enetgy of a seaction is 83.14 It role, the fraction of molecules at $00 K whieh have enough enargw to form produete is x» 10° The value of ()—x)is (lo 2x 10 =—20, In 4x 10° =10, In 4 10" = 40) A given sample of milk tums sour at room temperature @7°C) in Lo Im a reftigerator at 7°C. millecan be stored three times as long before it sours, How long (i it takes for milk 10 sourat 37°C (In Four Digit Integer Type 1 The sate constaat forthe decomposition of ozone following second-order Kinetics © 1" L mot! Tava certain temperature. The rate of reaction in terms ruber af molseles decomposed pot fl per minute. when ennceniraion af a7ane is BelO* Meist¥q= 6% 10) In thermal decomposition of CH{Br(E) 10 (CoHla) and HBr), the intial pressure chugs from 200 to 390 mm of Hg at the end of reaction. Percentage of Cyttsbr(y) undecomposed, when, the pnessiea of niet wots 3 5 mo of Hg, "The generation time of any substance athe time in which us concentration doubles. The growth of a certain byeteria follows GrsLorder kinetics 1P the population of bacteria triples in 96 h, then what is ‘he generation time (is h) for it? (og ? = 0.3.10 3 = 0.48) Nitric enide seasts with oxygen to give nits siioxide. 2NOig) +O14g) + 2NO4E) The mite haw is ~SPNOVA = AINOFIOY, wlieie the rate constant is 16% 10M «tat 327°C. vessel contains NO and Q, at 327°C. The initial ‘partial presses of NO ard Q, are 190) and 288 ‘ram Hg, reapoorively Tho initial rate of eeverace of partial pressure of NO (in mm Hg per seconel) is(R = 0.08 L-attayK-mol)A drop (0.05 ml) of solution eontains 3.» 10-7 moles ot H' I the ate constant of disappearance Af TT ie £3 197 mmol THe thes hese long Gn nin) Would i take for IT in drop to disappear? A substance is reduced to one third of its exiginal concentrition in 100 minutes by first-order Ikincties, The time (in ein) in i will be reduced 1g one ninth of its eriginal valus is A drug is known to be ineffective after it h decomposed 2052, The original vonventration of a sample way 300 units/ml. Whe analyse 20 mouths later the concentration was found to be 420 unityml. Assuming that the decomposition is frst order, what will be the expiration time (in month) of the drug? (In 2= 0.7. In $= 1.6, In 7= 19,mn3= 1.1) The devomposition of benzene dixconium chloride m ssjeous volubon os texeton of Is neler hin fencer ae Cql NCL CCT + Nig) certain solution of benzene diszonium chemo eantins nity an amount ofthis Snmponind hich givne RD em? af itm om connplte decomposition. Ii four tht 230°C, 40cm ol mlrogen are evolved m 40 minutes. How Ing in min) after the cart af the dornepositian vill 20cm’ of nitrogen have been evolved? ‘The decomposition of a compound “Pat tempersture 1) according tothe following equation 2P(g) +4Q(a) + Rie) + S10) isa first-order reaction. After 30 minutes. from the start of the decomposition is a closed vessel, the loul peste developed fs found Ws be 445 and after long tne, the total pressure is 625 mn ‘The vapour pressure of S(0) at this temperature 251mm, The iota pressure ser 60 minutes fy Ine half-life for the first-order decomposition of stent NENOMaq) >N,0(2) | HOM) ts 123 minutes at 27°C. Lf 200 nl of UZ ML NH,NO, solution is allowed to decompose. then hhow long (in min) must the renction proceed to peuce 3925 mat oF "WEE NgO|B) MeAsUTE! at 27°C and 785 mm Hg? The vapour pressure of vwatec at 27°C i 25 mm Hg. 1 M4 |. The reaction 2A +B C+D goes to vompletion and fotows the rate ow Al _ x pap). The sum of values of and inthe following data are Sex 4)K1M IRIX1PM Tle 1300 1 es su 6 * 2 5 20 4 wi ‘The gas phase decomposition of dimethy! ether Follows ist order kinetics CH,-O-CH, CH, (g) +H, (@) +004) ‘The eeaction is cartied out in ¢ constant volume container a¢ S00%C sud has a hells of 145 minutes Initially, only dimethyl ether i present fata pressure of 4.0 atmosphere. What is the total [pressure af the system (in atm) after 43.5 minuts? Assume ideal gas behaviout The fate of a first-order reaction is 04 mo! litre“! at 10 minutes and 0.03 mol litres at 22 minutes aftcr initiation. The halP-life of the reaction (in seconds) is (In 2=0.7, In 3= 1.1) An acid-catalysod hydrolysis of ester is carried out inthe presence of HCI. Small but same volume of reaction mixture were taken out at yrious instant lund were blrated wilh standard NuOH solution ‘The following data was obtained. “Tims in mind De Volume (nl) of NaOH solution needed for ration If the initial concentration of ester was 6.0 M, then ealeulate the value of aed, where sl Ls forthe hydoolysis.o ester (in minutes) ed = molar concentration of LICL used in the experiment, For the reaction Alg) > 2B{g) + Clg) the rate vonsiamt is 1.386 < U0" Ss The reaction ts performed at constant pressure and temperature starting with only :A’. The initial concentration of ‘N was 0.1 M. The concentration er A (i tmillinole per lite) after 500 s fro the start of reaction is16. A 18, 1». 2 ‘An optically active substance decomposes into ‘optically active substances ‘Band °C’ as follows A EtmMe 5 3B are 10 minutes and 15 minutes, respectively, the conceatration of C (in millimole pet lite) after 30 2. Torthe reversite rection Alaa) od which The specific rotations of A.B and C are +20°, +10° . wo 18 it and —30° per mole respectively. If intilly A and is Hisrondsr ia bom dtestions: B= sqq ti Chere yument and, Satara these, The uritonin sonsntatons wih Gime sows ‘lec which the ample beoimes opty inactne in the Fue a nselé la 25) In 20 7 inSe 16 in? 20 In 1325) ons tN Tora easton 2A + -¥ C+Date following dia is collected by experiments lah Bl x IA SM eM “Al | wo > 2 a aon i mW B) Fe - ; mf + Time nin Tne vane ot (a+ 9 +0 +a) “he sme miu) in whisk 29% of wow be concerted intB is in? 0.68 The gas phase decomposition of aoetic acid at 180K preccods by way of two poslllscections 22, At 25°C, a veaction is vomplete ia 4h va Approximately wat temperature fn °C) mist Be cancoe all, 6e sera eine acl abe cages 3 1 8? The temperature cocfficient of rong cH,coon — 14 HO. K-48 2%. The sate of decomposition for CHLNO. and The maximum percentage yield of the ketene CH,NO, can be given in terms of rate constant (CH,CO) ebainable nthe omportar ee er pars For overall action & + 2B +90 SED, the cation or thes eatin 152 30nd 171.3 ee ae a ‘Sa edhe eqn creas Han “ teas Oe op respecte The wemerae is °©) a hic retin) =2cureyap TN "ae conslant wl be same for both decoreposiion IF initially each of the reactant has concentrate resets BCR = 8.3. NR mL i W233) 19 M, calculate tharos of rion when the’. Thain Ong or viata w 140.4 concentration of C hocomes 0.7 M assuming ni D ‘mol and its pre-exponential factor is 5% 10" s ispresentat the star of thereatinn I the ates’ ‘AL wha (emperiture Gin K) wall the reaction hive Minin then the yale of (109s tule of Una? (n2-02, 32 LL kn ‘A mixture of two substances A ond B gives 20 ee 9, RS BALIN the same product C by (Wo parallel first-order 2, A hydrogenation reaction is curried out at 500 K. As CandB eS € IF the nial concentrations of A aud Bie 10 ud 0.8 M. respectively and their hallives, 7, and Tp Ifthe same ssaction actied out in the preseace of & catalyst at the siame rate, the temperatuse required is 400K, The activation energy of reaction lie ki/mol), i the catalyst lowers the activation energy by 20 kien. isSingle-digit integer Type LQ 20 36 46 Se 1.) 126) 1.) 146) 15.2 21. 8) 22 @) 23. (1) 24.(7) 25. a) Four-digit Integer Type 1. (7200) 2. (0025) 3. (0060) 6. (0200) 7, (0040) 8. (0120) 11, (0375) 12, (0011) 13, (1680) 16, (0300) 17. (0260) 18. (9000) 21, (0100) 22. (0085) 23. (0727) Single Digit Integer Type 1 iin 4 TEX A tanto a 3600 Smlmot s! 5. 6) 28 &£@) % 2) 1.@) 2) 17) 18) 19.) 2.) 250) 5. (1000) (0535) 10. (0123) (4003) 15, (0025) 393) 20. (1475) (0500) 25. (9100) o1_2¥005 0g Oaxy lr ce] _ 1 i = gta? 00-80 = 18% 10" we = 5 aes 1 .G) Addition of NaOIL will deeesaze 11,0"). Gi) Addition of water will decresse the concentration of bath, (Gl) Acetic acid is a weak acid amd benee, 1,0") will decraise (9) Increase in temperature increases the reaction rate,10. 2. 1B W r= KlesterlH*}® “Time for certain progress of reaction, [Ay]? 1x10 asx 16. (0 amole tr (@—x)mole uv. 18, |= For 24 reaction, we may assume that rate isalmost eonstant f= AALS (5 «LAs = 1A) = K=002 min" H0.(a—>#,00+ 04) an 100 K Uma 275% 104x022 3x 10° 3x 104 «(100 x 107) a O87) (187 Molos of H.0, reacted pers <2 Heat produced por see 9! as w 156 OD KSASS6NI $553 1536510 0.693, ms * 6.93K10~ 1000 se A — to ame ° 1100000 mote ws 2 3-0-5 K=K Ny Now yy === ® RUE 19 (222) spar oslo Conventrations sre in G.P. and bene, exder: AsBYag), —> 2A" (ag) +3 BP (ag) f=0 amole ° o min a oy aw 8 = total mole ah A > mole ja-s) mole From mass conservation. a My= (a+) x M, aMAchy 2B. TF ‘or f= 20 min, + Aye 1 —— Lele Peery [As K vals are same, the reaction is of erode = = 100 xen 21, r= KLAland 2r= isla n= 1 24 Fraction of molecules having scent energy in LAT "= [gl . 7 a 1 ; Next fp willbe. times of previous one and 28, Bs LE 1 on inks Ef 1 3 (aoa) ® Ka Pe ptkuekaek BB (1 1) Pay _ptkivkarko and int6= (1 2 Pe Rte 1 7 R (300 330. i 2x10 x . From (1) and (2) 1=4 bs 210? 1386 aes 2am 63x10 Four Digit Integer Type r= KOsP=5x 1042x1057 4. Aso = Kr. Pg -Py, and x10" mol Ps “ = 2x 10 6x 10 x 10 x 60 LOI atm st 7200 molecules mI! min (0.08 x 600)" 2. At = = Prot should be 400 mm, but as it is exit (ny ~28) ‘only 390 mm, some enreaetve gas shold also he aexa8 “C760) “Geo present inthe vesal Let Pocus = 24 mm then 7 Praacne 88 = (20 — Pa) ma, 250mm s GHBig) —> GHYe) + HB) 5% 0 oO f yas xox temo % From question, Py + Py +(200~ P,)=390 Sr2i9 and(Py — 3) tx x4 Q00— Py = MBS Skates + Percentage CH, Br undecomposed “ 1 jy TAL 1 yy Ml 00 gis Ego = 1=200 min