CHEMISTRY

Daily Practice Problems

DPP. NO.-03
Q.1 Match the column :
Column I Column II
(Compound) (Number of carbons in selected carbon chain
for IUPAC nomenclature)
OH
|
(A) CH 2  CH  CH 2  COOH (P) 4
|
CH
||
CH 2

CH 3  CH 2
|
(B) CH 3  CH  CH 2  C  CH 2 (Q) 5
|
CH 2
|
CH 3
CHO
|
(C) CH 3  CH 2  CH  CH 2  CH 2  CH 2  COOH (R) 6
(D) CH 3  CH 2  CH 2  CH  COOH (S) 7
|
CH 2
|
COOH

F
Q.2 Statement-1 : O Cl correct IUPAC name of this compound is
1-chloro-6-flouro-3,4-epoxyhexane
Statement-2 : Cl and F both are groups without suffix, Cl comes before F in alphabetical
order so numbering is done from this end.
(A) Statement-1 is true, statement-2 is true and statement-2 is correct explanation for statement-1.
(B) Statement-1 is true, statement-2 is true and statement-2 is NOT the correct explanation for statement-1.
(C) Statement-1 is true, statement-2 is false.
(D) Statement-1 is false, statement-2 is true.

Q.3 The IUPAC name of the crotonaldehyde is :

(A) 2-Propenal (B) Propenal
(C) 2-Butenal (D) Butenal
Q.4 IUPAC name of the following molecule is
CH2OH

COOH
(A) 4-hydroxy methyl 1-carboxy cyclohex-3-ene
(B) 4-hydroxy methyl cyclo hex-3-ene carboxylic acid
(C) 1-hydroxy methyl cyclo hexene-4-carboxylic acid
(D) 4-(hydroxy methyl cyclohex-3-enyl)methanoic acid

Q.5 The IUPAC name of

CH3 – C = C — CH – CH 2 – C  CH
| | | is
Cl CH3 C 2H5
(A) 2-Chloro-4-ethyl-3-methyl-6-heptyn-2 ene
(B) 2-Chloro-4-ethyl-3-methyl-2-hepten-6-yne
(C) 6-Chloro-4-ethyl-5-methyl-1-heptyn-5-ene
(D) 6-Chloro-4-ethyl-5-methyl-5-hepten-1-yne

Q.6 The IUPAC name of

is

(A) 2-Chlorocarbonylethylbenzoate (B) 2-Carboxyethylbenzoylchloride

(C) Ethyl-2-(chlorocarbonyl)benzoate (D) Ethyl-1-(chlorocarbonyl) benzoate

Q.7 IUPAC name of given organic compound :

(CH3)2C(CH2CH3)CH2CH(Cl)CH3 is :
(A) 5-Chloro-3, 3-dimethylhexane (B) 5-Chloro-2-ethyl-2-methylpentane
(C) 2-Chloro-4-ethyl-4-methylpentane (D) 2-Chloro-4, 4-dimethylhexane

COOH

Q.8 IUPAC name of is

(A) Bicyclo-[3,2,1]-octan-2-oic acid (B) Bicyclo-[3,2,1]-octane-1-carboxylic acid

(C) Bicyclo-[3,2,1]-octan-8-oic acid (D) None of these

H C4H9
| |
Q.9 IUPAC name of CH3 – CH2 – C –– C –– CH3 – CH3 is : [3]
| |
CH3 CH3
(A) 3,4,4-Trimethylheptane (B) 4-ethyl-3,4-dimethyl octane
(C) 2-Butyl-2-methyl-3-ethylbutane (D) None of these
Q.10 The incorrect IUPAC name is :
CH3
CH3 – C – CH CH 3 – CH – CH – CH 3
|| CH3 | |
(A) O (B) CH 3 CH 2 – CH3
2-Methyl-3-butanone 2,3-Dimethylpentane

CH3 CH3 – CH – CH – CH3

CH3 – C  C – CH | |
(C) CH3 (D) Cl Br
4-Methyl-2-pentyne 3-Chloro-2-bromobutane

Q.11 Which of the following compound has wrong IUPAC name ?

(A) CH3 – CH2 – CH2 – COOCH2CH3 (B) CH3 – CH – CH2 – CHO
|
CH3
Ethyl butanoate 3-Methylbutanol

(C) CH3 – CH – CH2 – CH3 (D) CH3 – CH – C – CH2 – CH3

| | | ||
OH CH3 CH3 O
2-Methyl-3-butanol 2-Methyl-3-pentanone

Q.12 Write IUPAC names of following compounds

(i) (ii)

(iii) (iv)

(v)
Q.13 Write IUPAC name of following compounds :

(a) will be:

(b)

Q.14 Write IUPAC names of following compounds

(i) (ii)

(iii) (iv)

Q.15 Write IUPAC names of following compounds

O
||
(i) HOOC – N = CH – COOH (ii) Cl  C  Cl (iii) (iv)

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