Test Topic - Alkyl Halide and Aryl halides Date-25/02/2016

Max. Marks -120 Time- 30 minutes

Instructions- For every correct answers 4 marks will be awarded and for every wrong answer 1 mark will be deducted.
No marks will be awarded or deducted for un-attempted questions.

1. What will be the products when reactants are alcohol & thionyl chloride in the presence of pyridine?
A.RCl+S+HCl B.RCl+SO2+HCl
C.RCl+SO2+H2O D.RCl+S+H2O

2. Which C-X bond has the highest bond energy per mole?
A.C-F B.C-Cl
C.C-Br D.C-I

3. Which alkyl halide has the highest reactivity for a particular alkyl group?
A.R-F B.R-Cl
C.R-Br D.R-I

4. Ethyl chloride with nascent hydrogen produces

A.methane B.ethane
C.propane D.butane

5. Which one is not a nucleophile?

A.C2H5O- B.SCN-
C.NH3 D.H3C+

6. The number of molecules taking part in the rate determining step is called
A.Order of reaction B.Rate of reaction
C.Mole of a reaction D.Extent of a reaction

7. During SN1 mechanism carbon atom changes its state of hybridization as

A.Sp2 to sp2 B.sp2 to sp3
C.sp3 to sp D.sp3 to sp2

8. What will be the order of reaction of a reaction whose rate can be expressed as R = K [A] [B]?
A.Zero B.One
C.Two D.Three

9. Which one among the following is not a good leaving group?

A.HSO4- B.Cl-
C.OH- D.Br-

10. What is the order of kinetics in the SN1 mechanism?

A
Zero B.First
.
C.Second D.Third
11. Which alkyl halide out of the following may follow both SN1 and SN2 mechanism?
A
CH3-X B.(CH3)3 C-CH2 - X
.
C.(CH3)2 CH - X D.(CH3)3 C - X

12. In elimination reactions of alkyl halide which site is more susceptible for the attack of base
 A
α- carbon B.β - carbon
.
C.α - hydrogen D.β - hydrogen

13. When two moles of ethyl chloride react with two moles of sodium in the presence of ether what will be
formed?
A
2 moles of ethane B.1 mole of ethane
.
C.2 moles of butane D.1 mole of butane

14. The ether used in Wurtz synthesis is

A
acidic B.basic
.
C.aqueous D.dry

15. When CO2 is made to react with ethyl magnesium iodide followed by acid hydrolysis the product formed is
A
propane B.propanoic acid
.
C.propanal D.propanol

16. Grignard reagent is reactive due to

A
the presence of halogen atom B.the presence of magnesium atom
.
C.the polarity of C-Mg bond D.all

17. SN2 reaction can be best carried out with

A
primary alkyl halide B.secondary alkyl halide
.
C.tertiary alkyl halide D.all

18. Elimination bimolecular reactions involve

A
first order kinetics B.second order kinetics
.
C.third order kinetics D.zero order kinetics

19. For which mechanisms the first step involved is the same?

A
E1 + E2 B.E2 + SN2
.
C.E1 and SN1 D.SN1 and SN2

20. The rate of E1 reaction depends upon

A
the concentration of substrate B.the concentration of nucleophile
.
the concentration of substrate as well as base the concentration of substrate as well as
C. D.
nucleophile nucleophile
21. Alkyl halides are considered to be very reactive compounds towards nucleophile because
A they have an electrophilic carbon & a good leaving
they have an electrophilic carbon B.
. group
they have an electrophilic carbon & a bad leaving they have a nucleophilic carbon & a good leaving
C. D.
group group

22. Which one of the following species is not an electrophile?

 A
NH3 B.Br+
.
C.H+ D.BF3

23. Which one of the following reactants will be required to form straight chain alcohol by using Grignard
reagent
A
formaldehyde B.ketone
.
C.ethylene epoxide D.both a & c

24. Which one of the following alcohols will be formed when ethyl magnesium bromide reacts with acetone?
A
primary alcohol B.secondary alcohol
.
C.tertiary alcohol D.dihydric alcohol

25. Which one of the following molecules does not form alcohol when reacts with Grignard reagent?
A
formaldehyde B.acetaldehyde
.
C.propanone D.carbondioxide

26. In primary alkyl halides the halogen atom is attached to a carbon which is further attached to how many
carbon atoms
A
two B.three
.
C.one D.four

27. Ethylene epoxide treated with Grignards reagent followed by acid hydrolysis yield
A
primary alcohol B.secondary alcohol
.
C.tertiary alcohol D.dihydric alcohol

28. The best method of preparation of alkyl halides is a reaction of alcohol with

A
Zn / HCI B.SOCl2 / Pyridine
.
C.PCI3 D.PCI5

29. Alkyl halides undergo a type of reaction

A
Nucleophilic substitution B.Nucleophilic addition
.
C.Elimination D.both a & c

30. 50% inversion of configuration of molecules take place in a

A
E1 - reaction B.E2 - reaction
.
C.SN1 - reaction D.SN2 - reaction
The end.