Typewriter: HoSyPhue.66.37 THCS Nguyén Tai Lu ~ TP Cao Lanh ~ Bang Thap Mobile Zato: 0792.31,08.07 SG GIAO DUC VA DAO TAO. KY TH] HOC SINH GIOI CAP TINH LGOP 9 NGHE AN | NAM HOC 2020 ~ 2021 DE CHINH THUC Mon thi: Héa hoc — Bang A (Dé thi gdm cé 02 trang, gdm 6 cau) Thoi gian lem bai: 150 phit Nga thi: 19/3/2021 ‘Cfu 1: (2,0 diém) Viét phuong trinh phan tng minh hoa cho cdc tring hop sau: 1. Axit phan img tao ra axit 2. Mudi phan tmg tao ra mudi 3. Oxit bazo phan itng tao ra oxit bazo 4, Oxit axit phin img tgo ra oxit bazo 5. Oxit phan img véi axit tao ra hai mudi 6. Oxit axit phan img tao ra oxit axit 7. Mudi phan img véi kim logi tao ra hai, mudi 8, Mudi phan img v6i mudi tgo ra kim logi mae tinh pan a_i hoa: Dé theo hibw kidm tra trinhé, gidng “Ai Ta wigu pha” 1, HeSO4 + NaCl > NaHSO + HCI 2. Nhiéu pit, vi du pir 1 6 trén 3. Fe203 + 2Al > AlzOs + 2Fe hode FeO +02 Fe:0s hoje Fe:O3 + Hz FesO.+ HzO + Mg > MgO + CO — khong ding COs dé dap dim chay kim loai. 5, FeyOy+ 8HCI > 2FeCls + FeCl: + 4H20 hofie 2CaO + 3HsPO, > Ca(H2PO,): + CaHPO, + 2H 6. SO2 + O2 > SOs hode SO + NalICOs -» NaHISOs + COz 7. 2FeCls + Cu > CuCl + 2FeChs hotie | NaxCOs + HCI > NaCl + NaHCOs hotie 2NaHCOs + Ba(OH)2 > NaxCO3 + BaCO3 + 2H20 8, Fe(NOs)2 + AgNOs > Fe(NOs)s + Ag ‘Cfiu 2: (4,0 diém) 1. Cho FeO; vio dung dich H280y long, dur thu dirge dung dich A. Cho timg chat sau vao dung dich A: Fe (du), khi Cla, khi 28, khi SO2, dung dich KMnOy, dung dich HI. Viét ede phurong trinh phan img xay ra. 2. Trong céng nghiép, ngudi ta diéu ché CuSO, bing cach ngm Cu trong dung dich H2SOx loaing c6 théi khi O- lién tuc. Tai sao ngudi ta khong ding eich cho Cu vao dung dich CuSOx dic, nong. Giai thich va viet phurong trinh phan ing, 3. Hay néu cach logi bo tap chat va viét ph/trinh phan img (néu 06) trong cdc trrong hop sau a) SOz cé lan trong CO: b) Fe c6 lan trong Cu ¢) HCI 66 lan trong Cle d) CO2 ¢@ lan trong CO Huing din gidi: 1. Phuong trinh phan img: ~ Hoa tan FesOy vao dung dich H2SO,: FesO4 + 4H2SO, > FeSO, + Fe2($Q,)3 + 4H:0 (2.1) Dung dich A gdm FeSQy, Fex(SOx)1 va HoSOs dir - Cho Fe du vao dung dich A: Fe + H2SO4— FeSO, + Hot (2.2) - Cho khi Ch: vao dung dich A: 6FeSO, + 3Clz > 2FexSO,)3 + 2FeCls, (2.3)Typewriter: HoSyPhue.66.37 THCS Nguyén Tai Lu ~ TP Cao Lanh ~ Bang Thap Mobile Zato: 0792,31,08.07 = Cho khi HS vao dung dich A. Fex(SO,)s + H2S > 2FeSO, + HeSO, +S (24) - Cho khi SOz vao dung dich A: SO + Fex(SO,)\/FeSOy/H2SO. > Khong phan Ong - Cho dung dich KMnOy vio dung dich A: 2KMnOj"!0FeSOs'H2$01>5Fex(SO})sK2SOsMnSOrH20 (2.5) - Cho dung dich HI vao dung dich A: 2HI + Fea(SOu)s > 2FeSOu + le + H2SOx (2.6) 2. Phuong trinh phan img: - Trong cong nghiép: 2Cu + Oz + 2HzS04 > 2CuSO, + 2H2O (27) - Néu ding axit dic néng: Cu + 212804 a ‘Tir phwong trinh phan img ta thay + Tit kigm H28Ox + Khéng gay 6 nhiém mai trréng, do phan (mg (2.7) khéng tao khi SO> 3. a) Loai bo SO2 khoi CO> bing cach suc vao dung dich KMnOx: 02 + 2KMnO4 + 2H,0 > 2H2SO4 + K2SO4 + 2Mn$O4 b) Logi bé Fe khdi Cu bing dung dich CuSO, Fe + CuSOs > FeSOx + Cu ©) Loai bé HCI khéi Cla bing nude edt > Hoa tan HCI, 6 Clo tan kém trong dung dich HCL 4) Loai bo CO: khoi CO bing cdich sue vao nude voi trong du: CO + Ca(OH), > CaCO + 120 — CuSO1 +02 +2120 (2.8) cach diing axit loang Igi hon vi: wu 3: (3,0 diém) 1. Cho so dé phanimg: = A—® »>B—2 5x9 >y_ 5p A c6 thé la chat nao trong s6 edie chat CaC2, AlyCs, CaCO3. C3He? Viet cae phuong trinh phan ting hoan thanh so dé trén, Biét X, Y 1a cl 6 diéu kign thudng 2. Cho cic hidrocacbon mach h6 e6 cong thére phan tir 1 CsHe, CsHi2; Cally. Viét phuong trinh phan tg dudi dang céng thire edu tao thu gon khi cho: - CsHe phan tng lin lrgt véi dung dich Br, HBr - CsHiz phan tg véi Clo (anh sang, ti 1¢ mol 1:1) thu duge sin phdm khi gdm HCI va 1 chat hitu co duy nhat ma phan tir chi chira 1 nguyén ti clo. = C4Hy phan tng voi AgsO (hoe AgNOs) trong NH3 Me di 1. Dé thay Y 1a CoHs — X phai la CaH2 — B la CHy. Vay A la ALiCs ALC, 2242. cH, 2" .0,H, i! 0, Maer 4 pE 2. Phuong trinh phan img: ~ CsHe phan ing lan lot véi dung dich Bro, HBr CH - CH = CH: + Bn > CHs~ CHBr~ CH:Br CHy— CH = CHp + HBr > CHs~ CHBr ~ CH (san pham chinh) CH3~ CH = CH2 + HBr > CH3~ CH ~ CHeBr (san phdm phy) - CsEha phan ting véi Clz: Do chi tao thanh I sin phim — CTCT eta CsEh2 1a (CHs)sC (CHs)C + Cl > (CHs)2C - CH2CI + HCI - Calls phan tng voi AgsO + CTCT e6 lign két HC=C-R > CTCT HC=t 2CH = CH C=CH + AgsO ~ 2CH2 = CH C=CAg + 120 Cfu 4: (5,0 diém) 1. Cho m gam hén hgp X gom NaCl va FeCl ti 1é mol 1:1. Chia X thanh 2 phan bang nhau: ~ CH= CHaTypewriter: HoSyPhue.66.37 THCS Nguyén Tai Lu ~ TP Cao Lanh ~ Bang Thap Mobile Zato: 0792,31,08.07 - Phan 1: Hoa tan hoan toan vao nude thu dge dung dich Y. Cho dung dich AgNOs dir vao Y thu durge 53,85 gam két tha ~ Phin 2: Cho vio dung dich H2S04 die, néng dur thu dirge V lit khi (dkte). Tinh m, V 2. Dt chay hoain toin mudi sunfua cia kim logi M c6 céng thite MaSn (M cé héa tri khéng déi) trong oxi dur thu durge 27 gam chat rin va 2,8 lit khi $O2 (dkte). Tim kim loai M 3. Tién hinh hai thi nghiém sau: nghiém 1: Cho x gam Fe vio dung dich chira a mol HCI. Sau khi phan img két thite, c6 thu durge 31 gam chat rin khan hi nghiém 2: Cho x gam Fe viy gam Zn vao dung dich chira a mol HCI. Sau khi phan img t thie, ¢6 can thu durge 37,5 gam chat ran khan va 4,48 litkhi (dktc). Tinh x, y 1. Goi 2a 1a s6 mol cia NaCl, FeCl trong X ~ Phan 1: Tac dung véi AgNOs du: NaCl + AgNO: > AgCl + NaNOs aD FeCh + 2AgNO3 — 2AgCl + Fe(NOs)2 (42) Fe(NOs)2 + AgNOs — Fe(NOs)3+ Ag. 43) Theo (4.1), (4.2), (4.3) ta 66: maga ~3a; nag = a Khéi luong két tiia thu durgc: 143,5,3a + 108a = 53.85 > a= 0,1 mol 2a + 117.2a= 35,1 gam - Phin 2: Tac dung véi dung dich H2SO, dic, nong 6FeCl+ 6H2SQ4-+ 4FeCh+ Fex(SOx)s+ 3802+ 620 4.4) Dyecy Theo (4.4) tacd: Myo, = =0,05mol — V = 1,12 lit, 2 2. Phuong trinh phan (mg: 2M28qn + 3nO2 —> 2M;O0y + 2nSO> (45) 27 2,8 i eee ae Theo (4.5) ta ¢6: MSs = 0 Melon 2 - 24 _,v1=100n doaiy nt Vay sin phdim dét chay sunfiua tao ra kim loai, inns phuong trinh phan tng: MoS, +nO2—> 2M + n$O: (46) 27 ny M Theo (4.6) ta c6: fue so. 6, M. Lap bang ta thy n= 1; M = 108 (Ag) tha man. Vay M 1a bge. 3.-TN: Fe +2HCI— FeCh: + H: 7) Xt phan tig (4.7): Néu Fe phan tng hét -> chat ran thu duge la FeCls > thy, a =0,244mol > Vi > 4.48 lit 6 TNe (v6 ly) Vay Fe du 6 phan tng (4.7) > HCI hét. Xét thi nghiém 2: Zn +2HCI > ZnCl + Hz 48) Fe + 2HCI—> FeCl + He 9) Dé thay HCI phan tmg hét theo (4.8), (4.9) > nuci= 2 <> a= 0,4 mol Theo (4.7) ta c6 khéi long chat rin la: 127.0,2 + 56 (x—0,2)=31 > x=0,3 mol > mre = 0,3.56 = 16,8 gam Gia str Zn dur theo (4.8) > HCI hét > myn, = 0.2.136 = 27.2 gam Khi d6 khéi rong chat rn khan = 16,8 + 27,2 = 44 gam > 37,5 (v6 ly) Vay Zn hét > Goi sé mol Fe phan itng la t (t 136y +71 = 20,7 ay Giai hé 4.1), 4.1) tacé: y= t= 0.1 mol 2nCO? + 2(n + 1) F2O 6.) 2Cm Haz + (Bn — 1)O2—> 2mCO2 + 2m — 1H (5.2) Theo (5.1), (3.2) taco noo, = 0,1n +0,1m = 0,5 mol > n+ m= 5. Vi m > 2 nén ta e6 3 tnrong hop - Néu m=2—>n =3 > Hon hop T gém CoH: va CsHs - Néu m = 3 n= 2 Hén hop T gdm C3Hiy va CH -Néu m= 4 n= 1-> Hon hop T gdm CsHo va CHs ‘Tue vigt CTCT 2. a) Phuong trinh phan (mg: AliC3 + 12H0 > 3CHi* + 4AIOH)s 63) CaC2 + 2H:0 > C2Hat + Ca(OH) 64) Ca + 2120 > Hat + Ca(OH) (3) Phuong trinh phan img khi mung X véi Ni: Ho > CoH 6.6) 2H2 > CoH (67) Phan ing khi cho ¥ qua dung dich brom du: CoH, + Br > CHiBr2 (8) CoH: + 2Br > CoH2Bry 69) b) Goi 3a, 3a, da Lin hot la s6 mol AliCs, CaC2 va Ca. Ta c6: 144.3a + 64.3a + 40.4a= 78.4 > a=0,1 mol Hén hop X gdm: 0,9 mol CHa 0,3 mol C2H2 ‘Téng sé mol cia X = 1,6 mol 0.4 mol H2 ‘Theo dinh luat bao toan khéi hromg ta c6: mx ~ my ~ moan Bee + mz > mz =mx—5,4= (0.9.16 + 03.26 + 04.2)— 5,4 Theo (5,6), (5.7) ta thy Y gm 5 chit: CH, Hp, C: $6 mol hdn hop Y = 29,12/22.4 = 1,3 mol — S6 mol Hp phan ing =nx—ny= 1,6 ~ 1,3 =0,3 mol + ny, av = 0.1 mol Goi x, y lan luot la s6 mol otia CoH, 17,6 gam CoHs, CoH.Typowriter: HoSyPhnc. 66.37 THCS Nguyéie TH{ Lyu~ TP Co Link Ding Tha Mobile Zale: 0792.21.08. Theo 6.6), G.7)tacd: x +2y=0,3 mol GD 8émd CiHp dy=03-x-y>0 Khéi luong binh brom tang chinh 1a khéi hrong C22, Catia bi hap thy. Ta 6: 28x +26.0,3-x—-y)=5,4 61) Gidi h8 OD, GID ta 06: x=y=0,1 mol (thda man) Vay hon hop Z gém: 0,9 mol CH4; 0,1 mol Hz, 0,1 mol C2Hs — mz = 17,6g (OK) Cau 6: (3,0 diém) 1. Cé 20 mL dung dich H28O« 98% (4 = 1,83 g/mL). Ngudi ta mudn pha loang thé tich axit rén thinh dung dich axit 207% a) Tinh thé tich nude can ding dé pha loing b) C4ch pha tién hanh nhw thé nao? 2. Hinh vé dudi day mé ta thi nghiém didn ché khi X. Chon 4 c&p chat A, B dé diéu ché 4 chat kkhi kchic nhau phi hop v6i hinh vé, Viét phuong trinh phan tng, R }— Dung dich B A =) r Bing ) | Aran, Huong din gidi; > aniston an pnét a da (8-20) 1a) G6.ahi8 Wh, don gitn nh ding OTDC mg N66 142s gam Goi x (mL) 1a thé tich mrde ofn ding > khéi long nude =x gam ~ Khéi long Ha8 04 = 98% .20 1,83 = 35,868 gam - Khéi lwong dung dich sau khi pha=20.1,83 +x =x + 36,6 Néng 46 H280q sau khi pha la C%=- 5,868 x+36,6 b)— Cho dung dich H28O4 dae vao 1 céc chu nhié. cé mo - Cho nude vao cdc chin nhiét, can than dung dich H2804 dae vao nude thong qua da thy tinh, Khuiy déu nhe 2. So dd nay ding 8 diéu ché nhiéu chét khac nheu, do cé sir dung béng nén khi X 1A chat gay hai cho nguéi va mi trong. Do binh hwéng lén trén, nén X phai nng hon khong khi ‘Mét sé trong hop nhw sau 100% =20%— x =142,74 mL - A: NaCl B: Hy8O4 dae xX IAHCL - A: NaHSOs/NazS0Os B: E2804 =X la S02 - A: MnO2 B: HCl dae =X la Ch -A Ca B: Ho8Oadac > X 1k S02