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SAFETY DATA SHEET

Melioderm Brown DR

Section 1. Identification
GHS product identifier : Melioderm Brown DR
Product code : P49818
Product description : Dye preparation
Other means of identification : Not available.
Product type : solid

Relevant identified uses of the substance or mixture and uses advised against

Identified uses
Product for colouring leather.

Supplier's details : PT Stahl Chemicals Indonesia

15139 Kota Tangerang Banten

ID
Telephone:+85262215516457
Telefax:+8662215910755
Email:

Emergency telephone number (with : 00780 3011 0293 / +65 3158 1074 (NCEC)
hours of operation) 24HRS (FOR CHEMICAL EMERGENCIES ONLY)

Section 2. Hazards identification

Classification according to NR 26; ABNT NBR 14725-2

Classification of the substance or : AQUATIC HAZARD (LONG-TERM) - Category 2

mixture

GHS label elements

Hazard pictograms :

Signal word : Not applicable.

Hazard statements : Toxic to aquatic life with long lasting effects.

Precautionary statements

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General : Not applicable.

Prevention : Avoid release to the environment.
Response : Collect spillage.
Storage : Not applicable.
Disposal : Dispose of contents and container in accordance with all local,
regional, national and international regulations.

Other hazards which do not result : Fine dust clouds may form explosive mixtures with air. Handling
in classification and/or processing of this material may generate a dust which can cause
mechanical irritation of the eyes, skin, nose and throat.

Section 3. Composition/information on ingredients

Substance/mixture : Mixture
Product description : Dye preparation
Other means of identification : Not available.

CAS number/other identifiers

Product code : P49818

Ingredient name % CAS number

Ferro Nitrophenol azo-complex, Ammonium Sodium salt of >= 25 - < 50 74204-29-8
Phenylamino Nitrobenzenesulfonate
Benzene, C10-13-alkyl derivs. >= 1 - < 3 67774-74-7
sodium carbonate >= 1 - < 3 497-19-8

There are no additional ingredients present which, within the current knowledge of the supplier and in the
concentrations applicable, are classified as hazardous to health or the environment and hence require reporting
in this section.
Occupational exposure limits, if available, are listed in Section 8.

Section 4. First aid measures

Description of necessary first aid measures

Eye contact : Immediately flush eyes with plenty of water, occasionally lifting the
upper and lower eyelids. Check for and remove any contact lenses.
Continue to rinse for at least 10 minutes. Get medical attention if
irritation occurs.
Inhalation : Remove victim to fresh air and keep at rest in a position comfortable
for breathing. If not breathing, if breathing is irregular or if respiratory
arrest occurs, provide artificial respiration or oxygen by trained
personnel. It may be dangerous to the person providing aid to give
mouth-to-mouth resuscitation. Get medical attention if adverse health
effects persist or are severe. If unconscious, place in recovery position

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and get medical attention immediately. Maintain an open airway.

Loosen tight clothing such as a collar, tie, belt or waistband. In case of
inhalation of decomposition products in a fire, symptoms may be
delayed. The exposed person may need to be kept under medical
surveillance for 48 hours.
Skin contact : Flush contaminated skin with plenty of water. Remove contaminated
clothing and shoes. Get medical attention if symptoms occur. Wash
clothing before reuse. Clean shoes thoroughly before reuse.
Ingestion : Wash out mouth with water. Remove dentures if any. Remove victim
to fresh air and keep at rest in a position comfortable for breathing. If
material has been swallowed and the exposed person is conscious, give
small quantities of water to drink. Stop if the exposed person feels sick
as vomiting may be dangerous. Do not induce vomiting unless directed
to do so by medical personnel. If vomiting occurs, the head should be
kept low so that vomit does not enter the lungs. Get medical attention
if adverse health effects persist or are severe. Never give anything by
mouth to an unconscious person. If unconscious, place in recovery
position and get medical attention immediately. Maintain an open
airway. Loosen tight clothing such as a collar, tie, belt or waistband.

Most important symptoms/effects, acute and delayed

Potential acute health effects

Eye contact : Exposure to airborne concentrations above statutory or recommended

exposure limits may cause irritation of the eyes.
Inhalation : Exposure to airborne concentrations above statutory or recommended
exposure limits may cause irritation of the nose, throat and lungs.
Exposure to decomposition products may cause a health hazard.
Serious effects may be delayed following exposure.
Skin contact : No known significant effects or critical hazards.
Ingestion : No known significant effects or critical hazards.

Over-exposure signs/symptoms

Eye contact : Adverse symptoms may include the following:

irritation
redness
Inhalation : Adverse symptoms may include the following:
respiratory tract irritation
coughing
Skin contact : No specific data.
Ingestion : No specific data.

Indication of immediate medical attention and special treatment needed, if necessary

Notes to physician : In case of inhalation of decomposition products in a fire, symptoms

may be delayed. The exposed person may need to be kept under
medical surveillance for 48 hours.
Specific treatments : No specific treatment.

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Protection of first-aiders
See toxicological information (Section 11)
Section 5. Firefighting measures
Extinguishing media
Suitable extinguishing media
Unsuitable extinguishing media
Specific hazards arising from the
chemical
Hazardous thermal
decomposition products
Special protective actions for fire-
fighters
Special protective equipment for
fire-fighters
Section 6. Accidental release measures
Personal precautions, protective equipment and emergency procedures
For non-emergency personnel
For emergency responders
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: No action shall be taken involving any personal risk or without
suitable training. It may be dangerous to the person providing aid to
give mouth-to-mouth resuscitation.
: Use dry chemical powder.
: Do not use water jet.
: Fine dust clouds may form explosive mixtures with air. This material
is toxic to aquatic life with long lasting effects. Fire water
contaminated with this material must be contained and prevented from
being discharged to any waterway, sewer or drain.
: Decomposition products may include the following materials:
carbon dioxide
carbon monoxide
nitrogen oxides
sulfur oxides
metal oxide/oxides
: Promptly isolate the scene by removing all persons from the vicinity
of the incident if there is a fire. No action shall be taken involving any
personal risk or without suitable training. Move containers from fire
area if this can be done without risk. Use water spray to keep fire-
exposed containers cool.
: Fire-fighters should wear appropriate protective equipment and self-
contained breathing apparatus (SCBA) with a full face-piece operated
in positive pressure mode.
: No action shall be taken involving any personal risk or without
suitable training. Evacuate surrounding areas. Keep unnecessary and
unprotected personnel from entering. Do not touch or walk through
spilled material. Shut off all ignition sources. No flares, smoking or
flames in hazard area. Avoid breathing dust. Provide adequate
ventilation. Wear appropriate respirator when ventilation is
inadequate. Put on appropriate personal protective equipment.
: If specialized clothing is required to deal with the spillage, take note of
any information in Section 8 on suitable and unsuitable materials. See
also the information in "For non-emergency personnel".
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Environmental precautions
: Avoid dispersal of spilled material and runoff and contact with soil,
waterways, drains and sewers. Inform the relevant authorities if the
product has caused environmental pollution (sewers, waterways, soil
or air). Water polluting material. May be harmful to the environment if
released in large quantities. Collect spillage.

Methods and materials for containment and cleaning up

Small spill : Move containers from spill area. Use spark-proof tools and explosion-
proof equipment. Vacuum or sweep up material and place in a
designated, labeled waste container. Dispose of via a licensed waste
disposal contractor.
Large spill : Move containers from spill area. Use spark-proof tools and explosion-
proof equipment. Approach release from upwind. Prevent entry into
sewers, water courses, basements or confined areas. Vacuum or sweep
up material and place in a designated, labeled waste container. Avoid
creating dusty conditions and prevent wind dispersal. Dispose of via a
licensed waste disposal contractor. Note: see Section 1 for emergency
contact information and Section 13 for waste disposal.

Section 7. Handling and storage

Precautions for safe handling

Protective measures : Put on appropriate personal protective equipment (see Section 8). Do
not ingest. Avoid contact with eyes, skin and clothing. Avoid
breathing dust. Avoid release to the environment. Avoid the creation
of dust when handling and avoid all possible sources of ignition (spark
or flame). Prevent dust accumulation. Use only with adequate
ventilation. Wear appropriate respirator when ventilation is
inadequate. Keep in the original container or an approved alternative
made from a compatible material, kept tightly closed when not in use.
Electrical equipment and lighting should be protected to appropriate
standards to prevent dust coming into contact with hot surfaces, sparks
or other ignition sources. Take precautionary measures against
electrostatic discharges. To avoid fire or explosion, dissipate static
electricity during transfer by grounding and bonding containers and
equipment before transferring material. Empty containers retain
product residue and can be hazardous. Do not reuse container.
Advice on general occupational : Eating, drinking and smoking should be prohibited in areas where this
hygiene material is handled, stored and processed. Workers should wash hands
and face before eating, drinking and smoking. Remove contaminated
clothing and protective equipment before entering eating areas. See
also Section 8 for additional information on hygiene measures.

Conditions for safe storage, : Store in accordance with local regulations. Store in a segregated and
including any incompatibilities approved area. Store in original container protected from direct
sunlight in a dry, cool and well-ventilated area, away from
incompatible materials (see Section 10) and food and drink. Eliminate

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all ignition sources. Separate from oxidizing materials. Keep container

tightly closed and sealed until ready for use. Containers that have been
opened must be carefully resealed and kept upright to prevent leakage.
Do not store in unlabeled containers. Use appropriate containment to
avoid environmental contamination.
Keep under shade.

Section 8. Exposure controls/personal protection

Control parameters

Occupational exposure limits (according to national legislation NR 15)

None.

Appropriate engineering controls
Environmental exposure controls
: Use only with adequate ventilation. If user operations generate dust,
fumes, gas, vapor or mist, use process enclosures, local exhaust
ventilation or other engineering controls to keep worker exposure to
airborne contaminants below any recommended or statutory limits.
The engineering controls also need to keep gas, vapor or dust
concentrations below any lower explosive limits. Use explosion-proof
ventilation equipment.
: Emissions from ventilation or work process equipment should be
checked to ensure they comply with the requirements of environmental
protection legislation. In some cases, fume scrubbers, filters or
engineering modifications to the process equipment will be necessary
to reduce emissions to acceptable levels.

Individual protection measures

Hygiene measures : Wash hands, forearms and face thoroughly after handling chemical
products, before eating, smoking and using the lavatory and at the end
of the working period. Appropriate techniques should be used to
remove potentially contaminated clothing. Wash contaminated
clothing before reusing. Ensure that eyewash stations and safety
showers are close to the workstation location.
Eye/face protection : Safety eyewear complying with an approved standard should be used
when a risk assessment indicates this is necessary to avoid exposure to
liquid splashes, mists, gases or dusts. If contact is possible, the
following protection should be worn, unless the assessment indicates a
higher degree of protection: safety glasses with side-shields. If
operating conditions cause high dust concentrations to be produced,
use dust goggles.

Skin protection

Hand protection : Chemical-resistant, impervious gloves complying with an approved

standard should be worn at all times when handling chemical products
if a risk assessment indicates this is necessary. Considering the
parameters specified by the glove manufacturer, check during use that

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the gloves are still retaining their protective properties. It should be

Body protection
Other skin protection
Respiratory protection
noted that the time to breakthrough for any glove material may be
different for different glove manufacturers. In the case of mixtures,
consisting of several substances, the protection time of the gloves
cannot be accurately estimated.
: Personal protective equipment for the body should be selected based
on the task being performed and the risks involved and should be
approved by a specialist before handling this product.
: Appropriate footwear and any additional skin protection measures
should be selected based on the task being performed and the risks
involved and should be approved by a specialist before handling this
product.
: Use a properly fitted, particulate filter respirator complying with an
approved standard if a risk assessment indicates this is necessary.
Respirator selection must be based on known or anticipated exposure
levels, the hazards of the product and the safe working limits of the
selected respirator.

Section 9. Physical and chemical properties

Appearance

Physical state : solid [Powder.]

Color : Dark Brown.

Odor : Faint odor.

Odor threshold : Not available.
pH : 8 - 9 [Conc. (% w/w): 10 g/l ]

Melting point : Not available.

Boiling point : Not available.
Flash point : Not applicable.
Evaporation rate : Not available.
Flammability (solid, gas) : Not available.
Lower and upper explosive : Lower: Not available.
(flammable) limits Upper: Not available.
Vapor pressure : Not available.
Vapor density : Not available.
Relative density : Not available.
Solubility : Soluble in the following materials:
cold water

Partition coefficient: n- : Not available.

octanol/water
Auto-ignition temperature : Not available.
Decomposition temperature : Not available.
Viscosity : Dynamic: Not available.
Kinematic: Not available.

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Section 10. Stability and reactivity

Reactivity : Not considered to be reactive according to our database.

Chemical stability : The product is stable.

Possibility of hazardous reactions : Under normal conditions of storage and use, hazardous reactions will
not occur.

Conditions to avoid : Avoid the creation of dust when handling and avoid all possible
sources of ignition (spark or flame). Take precautionary measures
against electrostatic discharges. To avoid fire or explosion, dissipate
static electricity during transfer by grounding and bonding containers
and equipment before transferring material. Prevent dust
accumulation.

Incompatible materials : Reactive or incompatible with the following materials:

oxidizing materials

Hazardous decomposition products : Under normal conditions of storage and use, hazardous decomposition
products should not be produced.

Section 11. Toxicological information

Information on toxicological effects

Acute toxicity

Product/ingredient name Result Species Dose Exposure

Benzene, C10-13-alkyl derivs.
LD50 Oral Rat 5.000 mg/kg -
sodium carbonate
LD50 Oral Rat 2.800 mg/kg -

Conclusion/Summary : Not available.

Irritation/Corrosion

Product/ingredient name Result Species Score Exposure Observation

sodium carbonate Eyes - Mild Rabbit - 0,008 hrs -
irritant
Eyes - Severe Rabbit - -
irritant

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Eyes - Rabbit - 24 hrs -

Moderate
irritant
Conclusion/Summary
Skin : Not available.
Eyes : Not available.
Respiratory : Not available.

Sensitization

Conclusion/Summary
Skin : Not available.
Respiratory : Not available.

Mutagenicity

Conclusion/Summary : Not available.

Carcinogenicity

Conclusion/Summary : Not available.

Reproductive toxicity

Conclusion/Summary : Not available.

Teratogenicity

Conclusion/Summary : Not available.

Specific target organ toxicity (single exposure)

Not available.

Specific target organ toxicity (repeated exposure)

Not available.

Aspiration hazard

Name Result
Benzene, C10-13-alkyl derivs. ASPIRATION HAZARD - Category 1

Information on likely routes of : Not available.

exposure

Potential acute health effects

Eye contact : Exposure to airborne concentrations above statutory or recommended

exposure limits may cause irritation of the eyes.
Inhalation : Exposure to airborne concentrations above statutory or recommended

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exposure limits may cause irritation of the nose, throat and lungs.
Exposure to decomposition products may cause a health hazard.
Serious effects may be delayed following exposure.
Skin contact : No known significant effects or critical hazards.
Ingestion : No known significant effects or critical hazards.

Symptoms related to the physical, chemical and toxicological characteristics

Eye contact : Adverse symptoms may include the following:

irritation
redness
Inhalation : Adverse symptoms may include the following:
respiratory tract irritation
coughing
Skin contact : No specific data.
Ingestion : No specific data.

Delayed and immediate effects as well as chronic effects from short and long-term exposure

Short term exposure

Potential immediate effects : Not available.

Potential delayed effects : Not available.

Long term exposure

Potential immediate effects : Not available.

Potential delayed effects : Not available.

Potential chronic health effects

Conclusion/Summary : Not available.

General : Repeated or prolonged inhalation of dust may lead to chronic

respiratory irritation.
Carcinogenicity : No known significant effects or critical hazards.
Mutagenicity : No known significant effects or critical hazards.
Teratogenicity : No known significant effects or critical hazards.
Developmental effects : No known significant effects or critical hazards.
Fertility effects : No known significant effects or critical hazards.

Numerical measures of toxicity

Acute toxicity estimates

Route ATE value

Oral 224.972,5 mg/kg

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Section 12. Ecological information

Toxicity

Product/ingredient name Result Species Exposure

sodium carbonate
Acute LC50 300 mg/l Fish - Lepomis 96 h
Fresh water macrochirus
Acute LC50 176 mg/l Crustaceans - Amphipoda 48 h
Fresh water
Acute LC50 265 mg/l Daphnia - Daphnia 48 h
Fresh water magna
Acute EC50 242 mg/l Algae - Navicula 96 h
Fresh water seminulum

Conclusion/Summary : Not available.

Persistence/degradability

Conclusion/Summary : Not available.

Bioaccumulative potential

Product/ingredient name LogPow BCF Potential

Benzene, C10-13-alkyl derivs. 6,4 35,00 low

Mobility in soil

Soil/water partition coefficient : Not available.

(KOC)
Other adverse effects : No known significant effects or critical hazards.No known significant
effects or critical hazards.

Section 13. Disposal considerations

Disposal methods : The generation of waste should be avoided or minimized wherever
possible. Disposal of this product, solutions and any by-products
should at all times comply with the requirements of environmental
protection and waste disposal legislation and any regional local
authority requirements. Dispose of surplus and non-recyclable
products via a licensed waste disposal contractor. Waste should not be
disposed of untreated to the sewer unless fully compliant with the
requirements of all authorities with jurisdiction. Waste packaging
should be recycled. Incineration or landfill should only be considered
when recycling is not feasible. This material and its container must be
disposed of in a safe way. Care should be taken when handling

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emptied containers that have not been cleaned or rinsed out. Empty
containers or liners may retain some product residues. Avoid dispersal
of spilled material and runoff and contact with soil, waterways, drains
and sewers.

Section 14. Transport information

Brazil IMDG IATA

UN number UN3077 UN3077 UN3077

UN proper Environmentally hazardous Environmentally hazardous Environmentally hazardous

shipping name substance, solid, n.o.s. (Ferro substance, solid, n.o.s. (Ferro substance, solid, n.o.s.
Nitrophenol azo-complex, Nitrophenol azo-complex, (Ferro Nitrophenol azo-
Ammonium Sodium salt of Ammonium Sodium salt of complex, Ammonium
Phenylamino Phenylamino Sodium salt of
Nitrobenzenesulfonate) Nitrobenzenesulfonate) Phenylamino
Nitrobenzenesulfonate)
Transport hazard 9 9 9
class(es)

Packing group III III III

Environmental Yes. Yes. Yes.

hazards
Additional Risk number: 90 This product is not regulated as a
information The environmentally hazardous dangerous good when
substance mark is not required transported in sizes of ≤5 L or ≤5
when transported in sizes of ≤5 kg, provided the packagings
L or ≤5 kg. meet the general provisions of
4.1.1.1, 4.1.1.2 and 4.1.1.4 to
4.1.1.8.
Marine pollutant:
Yes.
This product is not regulated as
a dangerous good when
transported in sizes of ≤5 L or
≤5 kg, provided the packagings
meet the general provisions of
5.0.2.4.1, 5.0.2.6.1.1 and
5.0.2.8.

Special precautions for user : Transport within user’s premises: always transport in closed
containers that are upright and secure. Ensure that persons
transporting the product know what to do in the event of an accident
or spillage.

Section 15. Regulatory information

Safety, health and environmental : No known specific national and/or regional regulations applicable to
regulations specific for the product this product (including its ingredients).
National Regulations : Federal Decree nr 2.657, of July 3, 1998.

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Ordinance nr 229, of May 24, 2011 - Amending the Regulatory

Standard nr 26.
Brazilian Standard ABNT - NBR 14725:2014.
One should be pay attention to the possible existence of Local
Regulations.

International regulations

Chemical Weapon Convention List Schedules I, II & III Chemicals

Chemical Weapons Convention List Schedule I Chemicals

None of the components are listed.

Chemical Weapons Convention List Schedule II Chemicals

None of the components are listed.

Chemical Weapons Convention List Schedule III Chemicals

None of the components are listed.

Montreal Protocol (Annexes A, B, C, E)

None of the components are listed.

Stockholm Convention on Persistent Organic Pollutants

Annex A - Elimination - Production

None of the components are listed.

Annex A - Elimination - Use

None of the components are listed.

Annex B - Restriction - Production

None of the components are listed.

Annex B - Restriction - Use

None of the components are listed.

Annex C - Unintentional - Production

None of the components are listed.

Rotterdam Convention on Prior Inform Consent (PIC)

None of the components are listed.

UNECE Aarhus Protocol on POPs and Heavy Metals

Heavy metals - Annex 1

None of the components are listed.

POPs - Annex 1 - Production

None of the components are listed.

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POPs - Annex 1 - Use

None of the components are listed.

POPs - Annex 2
None of the components are listed.

POPs - Annex 3
None of the components are listed.

Section 16. Other information

History

Date of printing : 22.06.2017

Date of issue/Date of revision
Date of previous issue
Version
Key to abbreviations
Procedure used to derive the classification
: 05.12.2017
: 09.11.2017
: 5.3
: ATE = Acute Toxicity Estimate
BCF = Bioconcentration Factor
GHS = Globally Harmonized System of Classification and Labelling of Chemicals
IATA = International Air Transport Association
IBC = Intermediate Bulk Container
IMDG = International Maritime Dangerous Goods
LogPow = logarithm of the octanol/water partition coefficient
MARPOL = International Convention for the Prevention of Pollution From Ships, 1973
as modified by the Protocol of 1978. ("Marpol" = marine pollution)
UN = United Nations

Classification Justification
Aquatic Chronic 2, H411 Calculation method

References : ANTT
IMDG Code
IATA Dangerous Goods Regulations
ECHA
IHS Database
GESTIS
SciFinder

Notice to reader

To the best of our knowledge, the information contained herein is accurate. However, neither the above-
named supplier, nor any of its subsidiaries, assumes any liability whatsoever for the accuracy or
completeness of the information contained herein. Final determination of suitability of any material is the
sole responsibility of the user. All materials may present unknown hazards and should be used with caution.
Although certain hazards are described herein, we cannot guarantee that these are the only hazards that
exist.

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