M19/4/CHEMI/SPM/ENG/TZ1/XX

Chemistry
Standard level
Paper 1

Wednesday 22 May 2019 (afternoon)

45 minutes

Instructions to candidates
yyDo not open this examination paper until instructed to do so.
yyAnswer all the questions.
yyFor each question, choose the answer you consider to be the best and indicate your choice on
the answer sheet provided.
yyThe periodic table is provided for reference on page 2 of this examination paper.
yyThe maximum mark for this examination paper is [30 marks].

2219 – 6110
11 pages © International Baccalaureate Organization 2019
 The Periodic Table
1 2 3 4 5 6 7 8 9 10 11 12 13 14 15 16 17 18

1 Atomic number
2
1 H He
1.01 4.00
Element
3 4 5 6 7 8 9 10
2 Li Be B C N O F Ne
6.94 9.01 Relative atomic mass 10.81 12.01 14.01 16.00 19.00 20.18

11 12 13 14 15 16 17 18
3 Na Mg Al Si P S Cl Ar
22.99 24.31 26.98 28.09 30.97 32.07 35.45 39.95

19 20 21 22 23 24 25 26 27 28 29 30 31 32 33 34 35 36
4 K Ca Sc Ti V Cr Mn Fe Co Ni Cu Zn Ga Ge As Se Br Kr
39.10 40.08 44.96 47.87 50.94 52.00 54.94 55.85 58.93 58.69 63.55 65.38 69.72 72.63 74.92 78.96 79.90 83.90

37 38 39 40 41 42 43 44 45 46 47 48 49 50 51 52 53 54
–2–

5 Rb Sr Y Zr Nb Mo Tc Ru Rh Pd Ag Cd In Sn Sb Te I Xe
85.47 87.62 88.91 91.22 92.91 95.96 (98) 101.07 102.91 106.42 107.87 112.41 114.82 118.71 121.76 127.60 126.90 131.29

55 56 57 † 72 73 74 75 76 77 78 79 80 81 82 83 84 85 86
6 Cs Ba La Hf Ta W Re Os Ir Pt Au Hg Tl Pb Bi Po At Rn
132.91 137.33 138.91 178.49 180.95 183.84 186.21 190.23 192.22 195.08 196.97 200.59 204.38 207.2 208.98 (209) (210) (222)

87 88 89 ‡ 104 105 106 107 108 109 110 111 112 113 114 115 116 117 118
7 Fr Ra Ac Rf Db Sg Bh Hs Mt Ds Rg Cn Unt Uug Uup Uuh Uus Uuo
(223) (226) (227) (267) (268) (269) (270) (269) (278) (281) (281) (285) (286) (289) (288) (293) (294) (294)

† 58 59 60 61 62 63 64 65 66 67 68 69 70 71
Ce Pr Nd Pm Sm Eu Gd Tb Dy Ho Er Tm Yb Lu
140.12 140.91 144.24 (145) 150.36 151.96 157.25 158.93 162.50 164.93 167.26 168.93 173.05 174.97

‡
90 91 92 93 94 95 96 97 98 99 100 101 102 103
Th Pa U Np Pu Am Cm Bk Cf Es Fm Md No Lr
232.04 231.04 238.03 (237) (244) (243) (247) (247) (251) (252) (257) (258) (259) (262)
M19/4/CHEMI/SPM/ENG/TZ1/XX
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1. Which diagram represents a heterogeneous mixture?

A.

B.

C.

D.

2. What is the sum of the coefficients when the equation is balanced with the smallest whole
numbers?

__BaCl2 (aq) + __Fe2(SO4)3 (aq) → __FeCl3 (aq) + __BaSO4 (s)

A. 4

B. 6

C. 8

D. 9

3. What is the empirical formula of a hydrocarbon with 75 % carbon and 25 % hydrogen by mass?

A. C 3H

B. CH2

C. C 2H 6

D. CH4

Turn over
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4. Which graph would not show a linear relationship for a fixed mass of an ideal gas with all
other variables constant?

A. P against V
1
B. P against
V
C. P against T

D. V against T

5. Bromine consists of two stable isotopes that exist in approximately a 1 : 1 ratio. The relative
atomic mass, Ar, of bromine is 79.90. Which are the stable isotopes of bromine?
79
A. Br and 81Br
80
B. Br and 81Br
78
C. Br and 80Br
79
D. Br and 80Br

6. What is the ground state electron configuration of an atom of chromium, Cr (Z = 24)?

A. [Ar]3d6

B. [Ar]4s23d4

C. [Ar]4s13d5

D. [Ar]4s24p4

7. Which describes an atom of bismuth, Bi (Z = 83)?

Principal energy Number of valence

level number electrons

A. 5 3

B. 5 5

C. 6 5

D. 6 15
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8. What are typical characteristics of metals?

Ionization energy Electron affinity

A. low low

B. high high

C. high low

D. low high

9. What is the order of increasing boiling point?

A. CH3CH2CH2CH3 < CH3CH(OH)CH3 < CH3COCH3 < CH3CO2H

B. CH3CH2CH2CH3 < CH3COCH3 < CH3CH(OH)CH3 < CH3CO2H

C. CH3CO2H < CH3COCH3 < CH3CH(OH)CH3 < CH3CH2CH2CH3

D. CH3CH2CH2CH3 < CH3COCH3 < CH3CO2H < CH3CH(OH)CH3

10. Which species does not have resonance structures?

A. C 6H 6

B. NH4+

C. CO32−

D. O3

11. Which describes an ionic compound?

Electrical
Melting point
conductivity of solid

A. high high

B. high low

C. low high

D. low low

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12. Which combination corresponds to a strong metallic bond?

Charge on the
Radius of ion
metal ion

A. large large

B. large small

C. small small

D. small large

13. When equal masses of X and Y absorb the same amount of energy, their temperatures rise
by 5 C and 10 C respectively. Which is correct?

A. The specific heat capacity of X is twice that of Y.

B. The specific heat capacity of X is half that of Y.

C. The specific heat capacity of X is one fifth that of Y.

D. The specific heat capacity of X is the same as Y.

14. What is the enthalpy change of reaction for the following equation?

C2H4 (g) + H2 (g) → C2H6 (g)

C2H4 (g) + 3O2 (g) → 2CO2 (g) + 2H2O (l) ΔH = x

7
C2H6 (g) + O  (g) → 2CO2 (g) + 3H2O (l) ΔH = y
2 2

1
H2 (g) + O  (g) → H2O (l) ΔH = z
2 2

A. x+y+z

B. −x − y + z

C. x−y−z

D. x−y+z
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15. Which is correct for the reaction?

2Al (s) + 6HCl (aq) → 2AlCl3 (aq) + 3H2 (g) ΔH = −1049 kJ

A. Reactants are less stable than products and the reaction is endothermic.

B. Reactants are more stable than products and the reaction is endothermic.

C. Reactants are more stable than products and the reaction is exothermic.

D. Reactants are less stable than products and the reaction is exothermic.

16. Which properties can be monitored to determine the rate of the reaction?

Fe (s) + CuSO4 (aq) → Cu (s) + FeSO4 (aq)

I. change in volume
II. change in temperature
III. change in colour

A. I and II only

B. I and III only

C. II and III only

D. I, II and III

17. Which will increase the rate of reaction between calcium carbonate and hydrochloric acid?

I. an increase in temperature
II. an increase in concentration of hydrochloric acid
III. an increase in particle size of calcium carbonate

A. I and II only

B. I and III only

C. II and III only

D. I, II and III

Turn over
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18. Kc for 2N2O (g)  2N2 (g) + O2 (g) is 7.3 × 1034.

What is Kc for the following reaction, at the same temperature?

1
N2 (g) + O  (g)  N2O (g)
2 2
A. 7.3 × 1034

1
B.
7.3 × 1034

2
C.
7.3 × 1034

1
D.
2 × 7.3 × 1034

19. Which solution is basic at 25 C?

Kw = 1.0 × 10−14

A. [H+] = 1.0 × 10−3 mol dm−3

B. [OH−] = 1.0 × 10−13 mol dm−3

C. solution of pH = 4.00

D. [H3O+] = 1.0 × 10−13 mol dm−3

20. Which is not a source of oxides of sulfur and nitrogen?

A. burning coal

B. internal combustion engines

C. burning methane

D. volcanic eruptions

21. Where does oxidation occur in a voltaic cell?

A. positive electrode and anode

B. negative electrode and anode

C. positive electrode and cathode

D. negative electrode and cathode

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22. Which is the species oxidized and the oxidizing agent in the reaction?

MnO2 (s) + 4HCl (aq) → MnCl2 (aq) + Cl2 (g) + 2H2O (l)

Species oxidized Oxidizing agent

A. Cl− HCl

B. MnO2 MnO2

C. MnO2 HCl

D. Cl− MnO2

23. Which product will be obtained at the anode (positive electrode) when molten NaCl is electrolysed?

A. Na (l)

B. Cl (g)

C. Cl2 (g)

D. Na (s)

24. Which functional group is surrounded in the molecule?

O
C

A. hydroxyl

B. carboxyl

C. carbonyl

D. ether

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25. What is the IUPAC name of the following molecule?

Br

CH3CHCHCH3

CH2CH3

A. 2-bromo-3-ethylbutane

B. 3-methyl-4-bromopentane

C. 2-ethyl-3-bromobutane

D. 2-bromo-3-methylpentane

26. What is the mechanism of the reaction between alkenes and halogens in the absence of light?

A. radical substitution

B. electrophilic substitution

C. electrophilic addition

D. nucleophilic substitution

27. Which alcohol would produce a carboxylic acid when heated with acidified potassium
dichromate(VI)?

A. propan-2-ol

B. butan-1-ol

C. 2-methylpropan-2-ol

D. pentan-3-ol

28. How should a measurement of 5.00 g from a balance be recorded?

A. 5.00 ± 0.1 g

B. 5.00 ± 0.01 g

C. 5.00 ± 1 g

D. 5.00 ± 0.001 g
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29. The dotted line represents the formation of oxygen, O2 (g), from the uncatalysed complete
decomposition of hydrogen peroxide, H2O2 (aq).

Volume / dm3
B

Time / s

Which curve represents a catalysed reaction under the same conditions?

30. What is the degree of unsaturation (index of hydrogen deficiency) for the molecule?

A. 1

B. 2

C. 4

D. 5