PT.

ANUGRAH VISI CEMERLANG

MATERIAL SAFETY DATA SHEET

Date November 09, 2021

1. CHEMICAL PRODUCT AND COMPANY IDENTIFICATION

Product Name : ALCOHOL TEHNIK

2. HAZARDS IDENTIFICATION
GHS CLASSIFICATION OF THE SUBSTANCE OR MIXTURE :
Flammable liquids : Category 2
Serious eye damage/eye irritation : Category 2
Toxic to reproduction : Category 2
Specific target organ toxicity (single exposure)
: Category 1 (systemic
toxicity, central
nervous system,
kidney)
Category 3
(respiratory
irritation)
Specific target organ toxicity (repeated exposure)
: Category 2 (blood
vessel, liver,
spleen)

GHS LABEL ELEMENTS :

PICTOGRAMS :

SIGNAL WORD: DANGER

HAZARD STATEMENTS :
Highly flammable liquid and vapor.
Causes serious eye irritation.
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Suspected of damaging fertility or the unborn child.

Causes systemic toxicity and damage to central nervous
system and kidney.
May cause respiratory irritation.
May cause damage to blood vessel, liver, and spleen through
prolonged or repeated exposure.

PRECAUTIONARY STATEMENTS:
Prevention:
Obtain special instructions before use, and DO NOT handle
until all safety precautions have been read and understood.
Keep away from heat/sparks/open flames/hot surfaces. – No
smoking.
Keep container tightly closed and take precautionary
measures against static discharge; ground/bond container
and receiving equipment.
Use explosion-proof electrical/ventilating/lighting
equipment and non-sparking tools.
Use only outdoors or in a well-ventilated area and DO NOT
breathe mist/vapors.
Use personal protective equipment; protective helmet/eye
protection/face protection/respirator/protective
gloves/protective clothing/protective boots as required.
Wash hands, face, and other necessary parts thoroughly,
and gargle after handling.
Avoid release to the environment.

Response:
In case of fire: Use water fog, dry chemical, foam, carbon
dioxide, or dry sand for extinction.
IF INHALED: Remove victim to fresh air and keep at rest
in a position comfortable for breathing. Get medical
advice/attention.
IF ON SKIN: Wash with plenty of soap and water. Get medical
advice/attention if you feel unwell.
IF IN EYES: Rinse cautiously with water for several minutes.
Remove contact lenses, if present and easy to do. Continue
rinsing. If eye irritation persists: Get medical
advice/attention.
IF exposed or concerned, or if you feel unwell: Get medical
advice/attention.

Storage:
Keep container tightly closed. Avoid direct sunlight, open
flame, ignition sources. Store in cool/well ventilated
area. Store locked up.
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Disposal:
Dispose of contents/container in accordance with
local/regional/national/international regulations.
Do not reuse the container for any other purpose. Dispose
of in accordance with applicable laws and regulations.

OTHER HAZARDS WHICH DO NOT RESULT IN CLASSIFICATION :

Not known.

3. COMPOSITION/INFORMATION ON INGREDIENTS
Chemical Name % CAS No.
Alcohol teknic >= 99.9 67-63-0

4. FIRST AID MEASURES

INHALATION :
If you feel unwell, remove to fresh air immediately. Get
medical attention if cough or other symptoms develop.

EYE CONTACT :
Immediately flush eyes with plenty of water for several
minutes and get medical attention.
Part eyelids with fingers to assure complete flushing.
Check for and remove contact lenses if easily possible.

SKIN CONTACT :
Immediately remove contaminated clothing and shoes. Flush
skin with large amounts of water, clean off with soap and
water. Get medical attention if symptoms develop.

INGESTION :
Do NOT induce vomiting. Rinse mouth with water. Never give
anything by mouth to an unconscious person. Keep the
affected person warm and at rest. Get medical attention
immediately.

MOST IMPORTANT SYMPTOMS/EFFECTS, ACUTE AND DELAYED :

Vapor causes irritation to eyes and respiratory tract.
Contact with liquid causes severe irritation to eyes and
mild irritation to skin. High concentration of vapor may
cause narcotic effect. Symptoms including inflammation of
eyes, nose and pharynx mucous membrane, coughing, headache,
dizziness, drowsiness, euphoria, decreased blood pressure,
unconsciousness, respiratory paralysis are observed.
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SPECIAL PROTECTIVE ACTIONS FOR FIRST-AIDERS :

Wear appropriate personal protective equipment such as
respirator, goggles, protective gloves, etc.

NOTE TO PHYSICIAN :
Treat symptomatically.

5. FIRE FIGHTING MEASURES

EXTINGUISHING MEDIA: water fog, alcohol foam, dry chemical,
CO2, dry sand.
Initial fire: dry chemical, CO2, dry
sand.
Large fire: water fog or alcohol foam.
UNSUITABLE EXTINGUISHING MEDIA:
Do not use water jet to fight fire. Water fog may be used
to cool containers.

SPECIAL HAZARDS :
Flammable liquid（Flash point = 11.7 oC). Vapors may cause
flash fire.

FIRE FIGHTING INSTRUCTIONS:

Keep unnecessary and unprotected personnel away. Shut off
supply if possible. Remove containers to safe place if
possible. Keep surrounding areas cool by spraying water.
Fight fire from an upwind position.

FIRE FIGHTING EQUIPMENT:

Respiratory and eye protection required for fire-fighting
personnel. Full protective equipment and self-contained
breathing apparatus (SCBA) should be used for all indoor
fires and any significant outdoor fires.

HAZARDOUS COMBUSTION PRODUCTS:

Carbon oxides.

6. ACCIDENTAL RELEASE MEASURES

PERSONAL PRECAUTIONS, PROTECTIVE EQUIPMENT AND EMERGENCY
PROCEDURES:
Evacuate immediate area. Warn personnel of fire, explosion
and health hazard. Remove all sources of ignition.
Keep unnecessary and unprotected personnel away. Wear
appropriate personal protective equipment as specified in
Section 8. Keep upwind, evacuate downwind.
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ENVIRONMENTAL PRECAUTIONS:
Do not flush into sewer, river or any body of water.

CONTAINMENT/CLEAN-UP METHODS:
Absorb or cover with dry earth, sand or other non-combustible
material and transfer to sealable containers. Large spills:
Dike far ahead of liquid spill for later disposal.
Use non-sparking tools and equipment.
Stop leak if possible without personal risk.
Avoid runoff to sewers or waterways.

7. HANDLING AND STORAGE

HANDLING
Technical Measures:
Use only in well-ventilated area. Keep away from heat,
sparks, and flame. Use explosion-proof electrical
equipment. Take precautions against build-up of
electrostatic charges. This material can form explosive
mixture with air. Beware of vapor leaks.
Avoid contact with eyes, skin, and clothing. Avoid
ingestion and inhalation. Wear appropriate personal
protective equipment. Provide hand and eye wash station
near work area. Wash thoroughly after handling.

Ventilation:
Use only under local exhaust or general ventilation.

Safe Handling Advice:

Do not handle until all safety precautions have been read
and understood. Take precautions against build-up of
electrostatic charges. Prevent leak and spill. Avoid
vapor formation. Do not fall, drop, shock or drag the
container. Avoid contact with eye, skin or clothing. Avoid
inhalation and ingestion. Use only in well-ventilated area
or outdoors.

STORAGE
Storage Conditions:
Protect from direct sunlight. Store in dark, cool, and
well-ventilated area. Keep away from heat, flame, and all
sources of ignition. Ground and bond containers and
equipment to prevent build-up of electrostatic charges.
Keep container tightly closed. Keep away from alkaline
solution, amines, alcohol amines, aldehydes, strong
oxidizers, chlorinated compounds, etc. Store locked up.
Store in a segregated and approved area.
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Packaging Material:
Use UN approved containers or containers approved by local
and national authorities.

8. EXPOSURE CONTROLS / PERSONAL PROTECTION

EXPOSURE LIMITS :
ACGIH-TLV: 200 ppm(TWA), 400 ppm(STEL)
OSHA-PEL : 400 ppm, 980 mg/m3(TWA)

ENGINEERING CONTROLS :
Provide general ventilation. Use closed system or local
exhaust ventilation. Provide safety shower and eye wash
station near work area.

PERSONAL PROTECTIVE EQUIPMENT

Respiratory protection : Chemical cartridge respirator
with organic vapor cartridge.
Hand protection : Protective gloves.
Eye protection : Safety glasses, goggles, face
shield.
Skin and body protection : Safety helmet, protective
clothing, safety boots, apron.

9. PHYSICAL AND CHEMICAL PROPERTIES

PHYSICAL STATE : Liquid.
APPEARANCE : Clear colorless liquid.
ODOR : Alcoholic odor.
ODOR THRESHOLD : 100 ppm
pH : Not available.
BOILING POINT : 83 oC
MELTING POINT : -90 oC
FLASH POINT : 11.7 oC (closed cup)
AUTOIGNITION TEMPERATURE : 456 oC
FLAMMABLE LIMITS : 2 – 12 vol% (in air)
VAPOR PRESSURE : 4.4 kPa (at 20 oC)
VAPOR DENSITY : 2.1 (air = 1)
SPECIFIC GRAVITY : 0.79
SOLUBILITY : Miscible in water.
Log Pow : 0.05
KINEMATIC VISCOSITY : ca. 1.6 mm2/s

10. STABILITY AND REACTIVITY

STABILITY : Stable for normal storage and handling.
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HAZARDOUS REACTIONS : Reacts with alkaline solutions, amines,

alcohol amines, aldehydes, strong
oxidizers, chlorinated compounds.
Attacks aluminum, iron, etc.
CONDITIONS TO AVOID : Heat, sunlight.
MATERIALS TO AVOID : Alkaline solutions, amines, alcohol
amines, aldehydes, strong oxidizers,
chlorinated compounds, etc.
HAZARDOUS DECOMPOSITION PRODUCTS: Carbon oxides.

11. TOXICOLOGICAL INFORMATION

ACUTE TOXICITY:
Oral rat LD50 3437 mg/kg [Not classified]
Skin rabbit LD50 4059 mg/kg [Not classified]
Inhalation(vapor) rat LC50 29512 ppm (4hr)
[Not classified]

SKIN CORROSION/IRRITATION:
Rabbit Not irritating to mild
Human Not irritating. [Not classified]

SERIOUS EYE DAMAGE/EYE IRRITATION:

Rabbit Mild to severe [Category 2]

RESPIRATORY SENSITIZATION: Not available.

SKIN SENSITIZATION: Not available.

GERM CELL MUTAGENICITY:

In vivo
Mouse bone marrow micronucleus test Negative
[Not classified]

CARCINOGENICITY:
Classified in 3 (Unclassifiable as to carcinogenicity in
humans) by IARC and A4 (Not classifiable as a human
carcinogen) by ACGIH.

REPRODUCTIVE TOXICITY:
In the two-generation reproduction study by the drinking
water medication using rats, there was no influence on
fertility and growth of the born pups.
On the other hand, no teratogenicity was observed in rats
in the growth toxicity and the teratogenicity test.
However, reproductive toxicity, such as decline in a
pregnancy rate, an increase in embryo absorption, and an
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increase in fetus death, were observed at the dose in which

a fall of the increasing weight, and toxicity such as an
anesthesia action to parental animals were observed.
[Category 2]

SPECIFIC TARGET ORGAN TOXICITY:

Single Exposure:
Rat: Decrease in activity caused by inhalation exposure.
Human: Stimuli to alimentary canals, decreases of blood
pressure and temperature, etc., central-nerves
condition; and kidney damage have been confirmed through
acute poisoning to humans caused by oral ingestion.
[Category 1](systemic toxicity, central nervous system,
kidney)
[Category 3](respiratory irritation)
Repeated Exposure:
Rat: Effect on blood vessel, liver, and spleen were
observed in inhalation exposure test.
[Category 2](blood vessel, liver, spleen)

ASPIRATION HAZARD:
The death of cardiopulmonary arrest is observed within 24
hours by the intratracheal administration in the rat.
(Kinematic viscosity: ca. 1.6 mm2/s)

See “GHS Classifications of Regulated Chemicals” for further

information.
(http://www.safe.nite.go.jp/english/ghs_index.html)

12. ECOLOGICAL INFORMATION

HAZARDOUS TO THE AQUATIC ENVIRONMENT (ACUTE):
ECOTOXICITY:
Medaka LC50 >100 mg/L/96hr [Not classified]

HAZARDOUS TO THE AQUATIC ENVIRONMENT (CHRONIC):

BIOACCUMULATION POTENTIAL:
Low (Miscible in water) [Not classified]

See “GHS Classifications of Regulated Chemicals” for further

information.
(http://www.safe.nite.go.jp/english/ghs_index.html)

13. DISPOSAL CONSIDERATIONS

WASTE FROM RESIDUES :
Whatever cannot be saved for recovery may be burned in an
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approved incinerator or disposed in approved waste facility.

Ensure compliance with local, state, federal and national
regulations.

CONTAMINATED PACKAGING :
Empty the container completely before disposal.

14. TRANSPORT INFORMATION

UN number : UN1219
Proper shipping name : ISOPROPYL ALCOHOL
UN class : 3
Packing group : II

15. REGULATORY INFORMATION

INVENTORY STATUS
X : All components of this product comply with the inventory
requirements administered by the governing country(s).

United States : TSCA Inventory [X]

European Union : EINECS [X] ELINCS [ ] NLP [ ]
Australia : AICS [X]
Canada : DSL [X] NDSL [ ]
China : IECSC [X]
Japan : ENCS [X]
Korea : KECI [X]
New Zealand : NZIoC [X]
Philippine : PICCS [X]

16. OTHER INFORMATION

References:
･ Handbook of Dangerous Goods (Gunter Hommel, 1991)
･ International Chemical Safety Cards (ICSC, 2007)
･ GHS model MSDS (Japan Advanced Information center of Safety
and Health)

Classification system:
Classification according to JIS Z 7252:2009 Classification
of chemicals based on "Globally Harmonized System of
Classification and Labelling of Chemicals (GHS)"

To the best of our knowledge, the information contained herein

is accurate.
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However, we cannot assume any liability whatsoever for the

accuracy or completeness of the information contained herein.
Final determination of suitability of any material is the sole
responsibility of the user. All materials may present unknown
hazards and should be used with caution. Although certain hazards
are described herein, we cannot guarantee that these are the
only hazards that exist.