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    © All Rights Reserved
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    7 views21 pages

    Chemistry

    Uploaded by

    Mintu Kumar

    Copyright:

    © All Rights Reserved
    Download as PDF or read online from Scribd
    Flag for inappropriate content
    of 21
    chembeal Kinatice 2 gs iA the branch of Chom } ushich dilale sith the stusly | cater of of themicol yeadions , rely mechanisms A fackoss affecting -volt of vere. Rete of veackon t— The change WM Cont. of a veathand o¢ psaduce ty unt th (3 Called srakt of reathion. 2+ can be expressed. “in +e%mée of es ip the ~vote decree | foe eager ny 5S Uy the on 4 tncreaye 1 Cone. of any See of tha, praduds, supose a chemical tye tebe &) 5 gee Rig ee SPS Ce ak 4 inital Conc of vencdard i product © (R, = SEPT, & after tome Hm (4B) cont. yeadauwt & produd are Ce gZ then a Ast By LP (x te) = 400 Ge ele) =< ALI, | ‘05 on Ae} Ral of xn = charge Dee a. vendhaut Vfme taken oR Charge In conc 4 product Time fecken Rote of xn = = UR)o- Ra R), Aba) He oe Meang in crease In Cenc. ass decease “iy cence, @ e Aa eee = Wax fPl) | ate) tae €, AS meand Rabe ef disapheavance of R= a oR pat of affemence of p= + ae “ae 2. AL an ‘ingtaud op Hime SRE SE eee cee eel | ale a ot ee ds ok ame ae Mesage 9 a ate of wen TN Casje2 The change in cent. of aseacank or a praduct Over @s dent ime Interval ty called a On erase -yoty of mM, e4. ao tx R —>.f Roya AUR Ree] a SE Be Ae ee | Lhsontaneous 5 sol. of om eee i ak oa ae) es Se parhculacr instant of time VS Peeled 25 in ajardemcnuy rate of ae ey. d_ xn R p insta — = AT RD + dC) | ca = | Noles : IN meang fowao bub He Befext to small charge . Us vat, TRL ee Cab) a 7 = RAN or Gaal wie in tesms 6} presaoe Cgadeous oor af Ebi PS cae gu time, Ls Sec = tm “ Rate €xpressfon a tt adripal Subpebe a doneval axn is aA+ bb => eG H4dD tats = ee ip 1 AEC). 5145 Ag 24 410 4 Oo aAdt 6 example, a ake 4, uno, +10, [i denn = Ad fhe) _ pi dtvor) db) iS dh eee Net oH 2NH, ~ “ete o| wx = — ee +1 d(H) Q An a exn Nit @H,—> anit , the cele of disapenids. of ede ts Iie mall st. then caleutih -yeds of appearance sl pomm ona. CNH,) . i O8 ee ite) ACN, ) a a a ‘= ae oe. at ae Bx10 melt ct O 4n Fedlewing xn "y QNs ves AN, OS igs cy allt appearances. of NO, is 2x18" amalio ss, Qoterwnine 96 oh dis ahpeccrence of Nidreqen perdaoxidlt Chee | Sol” ie ope eat ce 1 ALN eG ple SENG) ae) a ee +y AE KE a ssh. “ A (no, *) | BA As =) A Soe nee aaa = X3K\T = |.sx 162 matt J &. Fou as YxN RP ths Cont of a faducd, Aol cone of A decgeases prom 0.5 M av O-4-™ Fn 10 win. Colcuatr ho wot 5 TEN Ausing bis wohesval 4 de (er o.es malin’ Ce) 6.S mall vas (ey 01 O05 moi — Cdd Hiecce mal nan’ xe Facone afedting ttn | weadton ® Contentrabien of yeactaute : EGG Glade \e Higher the cones of concorde, higher wil be wale of sen. QD Tomb. 2 gate of wen oc Tomb. a temp: D increased 10°C , a eee | a yeaclion becomes i - ©. } “ 99°C} Q, 2 vatr of ave ad Bok in x mille! then predic ite vate at g2an 9 (aly Be oe (Cc) Sx C40 © Nobuo a} veadaule: 9h seactaut- molecules have weal bends, qRe wale o-m ts generally igh = oO Suttace crea | weacats - eles th. eS ; Wighes Is tho : wfc an iighes io He wale of vt p Adbhent Hohe ovoks fa cceadion W divecty proportional to she poduct ack moves Come) of ~eadunks & etch aised 64 atoiddonatrl 4 maloe Conc. of weachurte . at stetethad R the vost oj aw id _duedtly gecporiond Se tho pedi of cont of the veackauts each sated by same . power, valich mas Ot -msy nat be eq 40 atoichiomettic Coefiderts.” 2effideort GQ. aa qeresal “fina aA + bh-—> poduct eae x CT Le” Qa = CONE” wie rouge a [m= aie ie oa cone Rake Constant ta dafined aa tho sats of chemicel ON cohen molec Come: of each © Beactauk 1s taken anil}. chasers of hate chard oi O S¢ ts amearwe yo | KN. ONenter the Nolan o ee ey la the wen. Da gin hax Lee volt foe a wx ad Constante Jews. 3). Os Vad tee. aaah sith change in temp, () “WA doef dap ond ¢ ubon tnitte) Conc. teactanhs. H (A), (5) Fhe uid a TR Conitar’ dopunds upon the Order DERN). Rate = KCAL { oxdex | Cm = x+6] , Note:— oyvder af 4 tun eae be 9,!,2,3 L trackons) alto, GO Calentete onder ef per fox Peblousi vale Josas 2 re () Rae = k{A}*Cs) : @ esha Klee bro (a) 241 = @) W2+L-@ . note [ate = KA Ce | outer) @ For a yeachion 2a+Q prodssd- ee 5 a Licme | A 2 Bi Ste ag ake usNek sill We a2. veto fen? gol” ade = utajrCe) AS Rabe Me fas) ee) = eed [8] = aK (ATL) Nend Lote of ain becomes § dimes of the old alo e win. @ fos a yeti tro pots = KLAMBY CG) what wilh be walr of ox 7 ee Bod oy ote doubled £ ce. of @ is halved 9 AS (a) halved (doubted CO) “Fat plad (AT Ramaing Bame Hyd & C Rle= K[ar] (2) ad THe ACYL = “‘ayee)*ces YE Exam flo of Rent o{ Wifferord osdev 5 © Zen gedes wxn Be Hite Cy OP), gu Rate = eLHs) dg)” ANH, Ng+t SH Rake = KE Hy)” _ J WO NOs E> ano, © as, estes (85057 ovden= | QU Niiyo, As ny ery Qole = KLNHyNo, | ovday = | ® and dr dex sxng pas @ ano, —> avo + a, oe K (wo, oxduye= 2 en rh + Ls —?_ 24 pie Recke Kluge? ordes= |4| = 2, SA oxdes omg 5 WM ae BO ng a QNO, = ycuaeio-f | Ordes = 2N= 3 a) 2No_ ae eS NOC Os Gt inthe unit of is qaginr th oxder seaden , OK tes Ze10 widen wen C n= 9) = (mate 24 = mati) - @e ‘kK! 408 Ast oder mm CN=1) a3 hs Qa Ul ada ae 7m Cn= 2) = Lmalies @— ' tes 32d oxdos wm (Aas) = mots* ¢ a (ee ie Cin tesm of peers) The numbey of veacdeut melecutes hat collide Bimuttane ously Wn ene elemercay suadion te being a chem called meleculanity of a anen. => The seathionrg ushote molaculerid ad DQ A124 3 core called crumecutay, binelerutay end tesmralocilacs reachong seer : Molecitavitios [,2 & S aye quik. commen > St Cam rat be servo, > The meng hasing highes walecota ities C more than 3) ove yave, becourc, there wit Dans of CIIEN Se of forge number of Xeacdaws Piaihe wonber of veadart meleculs thot — calide Bimattane ously in an etemercterr sroachion to batry a chemo) change > called molecotanity ze 2, = The seatliong ushoce molocolaritied ang $7243 ce called wmdecolay, bimalecutar and tepmaliculas ~eachongs nee peas ee) E = Molecilartties ie 2 3 ape quits commor 7 8+ cam nat be zero, The aang herting highex wmalecolagidtes C move than 3) ote vowed, because, thee vUbtbetias chances of calltsion of fot ge tunbes of reach, ytomplen xeadionn: the eadions which Ocews though a sequel 6] een move stehe axe called comblen wxne Each shebp a a Com plen seadon A an clementan vention . Ie Mechantom fa veackion = the Bequench eens tx atebs vabich aecount dog an overall 8 cacMlon i> called the rec harusn of He xeaction, —> Oitpeserd eae Stebs occeary sth diferent aes . The wate pvedall seaction Ae pende only on the “Bde o] wlaoest step, Rale deterring pep phe wousert stor “of we Corrplex yeudien en usbich bats dhe overatl Seodion diapers 1A calle.) vate ees mMep (| RDS) =. {Ongely ee veadlon also duped Ubon ROS, piles ew a gee, Som N,O- 2NO- SPgne +a; [Rate = = dell Ge =). Mechanixim « Sen she Ss ehiy Cus) SP NG, nd, } Srepai) + nyo HA ano, +0, 288 my Oe Op” Re = k( mor] osdes = | = eee = | @: Disrugucsh, ble Moleculocst a SKM, £ Oxdor a a eS "4 SS Ree Sey, a Y Was Role= KIN, © men.| —2 puthing Valu 4

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