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Name+ Solidum, Joseph Cyron E, CHMO2G TOPIC I Problem Set introduction to Electrochemistry Bap et sh ret St Half reachons: Fe + ev Fe’ (reduction) ont* 3 Sn? + 2e7 Cexidahon) Ee ee a Fe E26 pst SS Fe + nt te 4+ rena: 2 Fi oro = 2s + Sp a ro? exuaagmesgens °° DY cee) + Ag Sct + ro) Half reachons: (Orts) > Cr + ae ) | (oxidation) ( Age +o Ag¢s) ) 3 Crectuc ton) CrCs) +3Agt +26 2 oft Ag(s) ipsem reaowegam _Crte) + 3Agh = Crh” + Ag’s) CBE _ Aah RAL rls Dheiven: 0.0380 m cul NOs) Ecey ** Ecey) = E°- a log @ cut +2¢7 > Cols) , B°= 0.337 PDhgy?tlre’*(o.v88em), a MoM) othe Ste | eH 0.77IV Beg = 0-491~ 29552 log (“o> (Sim) EO-7S1V. 0.751 Ceathoot ) wPllg! Agen)” oo 077M) Ken (0: as) M) [ag Cen),] tes Ag t2cNr _o: - 0as|~ £°= -0.31Y ae 99 (© 0798 )g=e2] Canode) Ecell = @ art tor AsPbs) £= -o.wey Leb)? 5 as037].= 4.1 x po = Kep ) ZnY t 267 S ants) 7 at tag? Le"). Cer" ]EY] 0592 ; rT) ry Ecc = 0.763 ~ = |09 (3-2 x10 ‘)F 2 @ cep» | Po°*00- 20) |] ca**(0-05v0m) | Ca Eright: cat ¢ acm F Cdes) Bo = -0.403V ae > ppt tae F Ms) FP = oe xt 2nts) £°=-0.7%3V saayunh = ke 9.0592 . = -0.442 Eright = -0-403 - FF 9h) o _ _ 0-0592 =-0-153 Elefe = ~0-/26- = log ( 5 Feel) = Eright - Eiete = - 0.992 - (0-153) py P| Por, 9t4), £, (o-coron) |] Hey” C2-Lonis?m) | Hy Fright: #g* tack # Hglt) E> + 0.854 Elert : Ph? dae TF Pls) FPF -0. RG . 0542 Fright = +0.854- 222 Jog (Saxe r) tape fae =P J[I Flee = -P-DG- one Jog ( {eons | = 70.26BV Pla celery =_0-777V 79x07 : 279x107. Ecen= Eright- Flett (Sic NTPSE Pe resehey LON va LF zn¢s) ]2n”*(o -leoom) |} Pb™ "(0.0220 m) | Pbés) Ps -0-G on _ Eright ° Eleit = 2ne +49¢ Dt Znls) E°> -0.763 Eve = Eright — Elefe = 70-26 =(-0-76}) = 0. 3FV 0.0592 (S 1200 0.037 - eisv ° “2. (¢ 0220 oo) Eee] Es ) ou SCE || PbI, (#9 0") I (1-00) Pb PoIzcs) te > Pbls) + 28 pb + ze Ph(s) ECO kep of MT, ~ LPI ]=79 xp? 0592. fade =>. ° go’ log Samet) i at [I J=1-20 ze ee ; = —0.366V py (ee Ea] 1 Eppr, =~ 0- Iag- 2 T =0.065A Eright: Zn" tae =F Zncs) EP ~0- 763 GP) Co Ico? (5.40 «18 ’m) |] 263" (2.95 415°) |2n Ele(t: Gort rae F Cots) BOF 29 o- OSI bs (sasx08 Eright = - 0-763 ~—p— = =6-838V Elest> ~ 0077 sit bg C Sonne 343V Ecellz Fright Elest = -0.828 V-(0243v)- 0.005R=-a760v [1] Solve for §R), = 0-995 -0-005R = -0.788 V 0-065 R = - 0-293 Sub back 4 eqn CA] R= 450. Bel) = - 0-838 -(-0.345) - ©. 065-(4.50) F-0 788 Whciven: o.asvq Co 1 Solve for +t. = 08510 A . ; Coulemerty * GQ-It » t= Co tee o Co¢s) (mate) Q=nF Na Law L (8&2 aes (-asnges (108 i mp2] \ mole FO gt Q= B/8-6377295 6 eae QL x ,we have -@ obey t a: weet ont = aip.esrms %* (A

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