Material Safety Data Sheet: Lemon D Type Fragrance 00004-Fr-001

MATERIAL SAFETY DATA SHEET
In compliance with EU Regulations 1907/2006/CE, 1272/2008/CE, 830/2015/EU
Revision: 2.1 28/03/2022 Print Date: 29/03/2022
1. Identification of the Product and of the Company

1.1 Product identifier: LEMON D TYPE FRAGRANCE 00004-FR-001
1.2 Relevant identified uses of the product and uses advised against
The product is a mixture of perfume ingredients, to be used as a fragrance.
1.3 Details of the supplier of the safety data sheet

Name Mayaqua s.r.l
Address Via Calabria, 15
IT-20054 Segrate (MI) - Italy
Telephone n. (+39) 02 26921512
e-mail address info@mayaqua.it
1.4 Emergency telephone

In case of necessity call (+39) 02 26921512 or contact a poison center.
2. Hazards identification
2.1 Classification of the substance or mixture
The result of the classification of the mixture, according to the criteria of Regulation 1272/2008/UE, is:
H304 Aspiration hazard Cat. 1

H315 Skin irritation Cat. 2
H317 Skin sensitisation Cat. 1
H319 Eye irritation Cat. 2
H411 Hazard to the aquatic environment, chronic Cat. 2
For the full text of the H phrases and the complete labelling of the product, see next Section 2.2.
2.2 Label elements

The label elements for the hazard communication are the following.
Labelling according to Regulation 1272/2008/CE.
Pictogram:
Sgn. word: Danger

H Phrases: H304 May be fatal if swallowed and enters airways.
H315 Causes skin irritation.
H317 May cause an allergic skin reaction.
contd. on next page
Material Safety Data Sheet: LEMON D TYPE FRAGRANCE 00004-FR-001 Pag. 1 of 15

contd. of previous page
H319 Causes serious eye irritation.
H411 Toxic to aquatic life with long lasting effects.
P Phrases: P260X Do not breathe vapours.
P264 Wash hands thoroughly after handling.
P273 Avoid release to the environment.
P280X Wear protective gloves and clothing; protect eye and face.
P301+310 If swallowed: immediately call a poison center or doctor/physician.
P301+330+331 If swallowed: rinse mouth. do not induce vomiting.
P302+352 If on skin: wash with plenty of soap and water.
P305+351+338 If in eyes: rinse cautiously with water for several minutes. remove contact
lenses, if present and easy to do. continue rinsing.
P333+313 If skin irritation or rash occurs: get medical advice/attention.
P337+313 If eye irritation persists: get medical advice/attention.
P391 Collect spillage.
P405 Store locked up.
P501 Dispose of contents/container according to law.
Other info: Contains: Orange Oil Terpenes 100% natural, Limonene, Citronellol, Geraniol, Citral, Nerol,
Beta pinene, alpha-Terpinene, 2,4-dimethyl-3-cyclohexen-1-carboxaldehyde, Gamma-terpinene,
p-Mentha-1,4(8)-diene
For the most important harmful effects, see sections from 9 to 12.
2.3 Other hazards

All known hazards are listed in this document.
3. Composition/information on ingredients
3.1 Substances
Not applicable.
3.2 Mixtures
The substances, contained in the product, which are relevant for their health or environment hazard, or for
which there are Community workplace exposure limits, are:
substance Reach regist. CE nr.; CLP Classif.1 %

CAS nr. w/w.
Orange Oil Terpenes 100% natu- 01-2119493353- 232-433-8 ; Flam. Liq. 3 H226; Asp. 20,01
ral † 35-XXXX 8028-48-6 Tox. 1 H304; Skin Irrit. 2
H315; Skin Sens. 1 H317;
Aquatic Chron 2 H411
Terpineol † 4,06
01-2119553062- 232-268-1 ; Skin Irrit. 2 H315; Eye
49-XXXX 8000-41-7 Irrit. 2 H319
2,6-dimethyloct-7-en-2-ol 01-2119457274- 242-362-4 ; Skin Irrit. 2 H315; Eye 3,10

37-XXXX 18479-58-8 Irrit. 2 H319
contd. on next page

CAS nr. w/w.
Decanal † 2,42
01-2119967771- 203-957-4 ; Eye Irrit. 2 H319; Aquatic
26-XXXX 112-31-2 Chron 3 H412
Citral † 2,00
01-2119462829- 226-394-6 ; Skin Irrit. 2 H315; Skin
23-XXXX 5392-40-5 Sens. 1 H317; Eye Irrit. 2
H319
3a,4,5,6,7,7a-hexahydro-7- - 226-501-6 ; Aquatic Chron 3 H412 1,42

methano-1(3)H-inden-6-yl acet 5413-60-5
Limonene 01-2119529223- 227-813-5 ; Flam. Liq. 3 H226; Asp. 1,15

47-XXXX 5989-27-5 Tox. 1 H304; Skin Irrit. 2
Aquatic Acute 1 H400 (M
= 1); Aquatic Chron 1
H410 (M = 1)
Citronellol † 0,40
01-2119453995- 203-375-0 ; Skin Irrit. 2 H315; Skin
23-XXXX 106-22-9 Sens. 1 H317; Eye Irrit. 2
H319
Geraniol 01-2119552430- 203-377-1 ; Skin Irrit. 2 H315; Skin 0,30

49-XXXX 106-24-1 Sens. 1 H317; Eye Dam. 1
H318
p-Mentha-1,4(8)-diene - 209-578-0 ; Flam. Liq. 3 H226; Asp. 0,25

586-62-9 Tox. 1 H304; Skin Sens. 1B
H317; Aquatic Acute 1
H400 (M = 1); Aquatic
Chron 1 H410 (M = 1)
Nerol 01-2119983244- 203-378-7 ; Skin Irrit. 2 H315; Skin 0,20

33-XXXX 106-25-2 Sens. 1 H317; Eye Dam. 1
H318
Beta pinene - 204-872-5 ; Flam. Liq. 3 H226; Asp. 0,18

127-91-3 Tox. 1 H304; Skin Irrit. 2
Aquatic Acute 1 H400 (M
= 1); Aquatic Chron 1
H410 (M = 1)
alpha-Terpinene - 202-795-1 ; Flam. Liq. 3 H226; Acute 0,17

99-86-5 Tox. 4 H302 (ATE =
500.00); Skin Sens. 1B
H317; Eye Irrit. 2 H319;
Aquatic Chron 2 H411
Gamma-terpinene - 202-794-6 ; Flam. Liq. 3 H226; Asp. 0,16

99-85-4 Tox. 1 H304; Repr. 2 H361
contd. on next page

CAS nr. w/w.
2,4-dimethyl-3-cyclohexen-1- 01-2119982384- 943-728-2 ; Skin Irrit. 2 H315; Skin 0,10

carboxaldehyde 28-XXXX 68039-49-6 Sens. 1B H317; Aquatic
Chron 2 H411
Note 1. See Section 16 for the full text of the phrases.

Note †. Substance with an Exposure Scenario annexed to this MSDS: see Section 16.
Further information on possible components which present an Acute Toxicity classification under Reg. 1272/2008
can be found on Section 11.
Toxicological and Ecological information are available on Sections 11 and 12.
4. First-aid measures
4.1 Description of first aid measures, by routes of exposure
- Ingestion: This product must not be swallowed. In case of accidental ingestion, rinse mouth with
water; do not induce vomiting; immediately seek medical treatment, showing this safety data sheet.
- Eye contact: Irrigate copiously with water for ten minutes at least. Seek medical advice if irritation or
evidence of tissue damage persists.
- Skin contact: Take off contaminated clothes. Wash with large quantities of water and soap. If the irritation
persists or any sign of tissue damage appears, seek medical advice.
- Inhalation: In case of uneasiness/malaise, move the person to fresh air and keep him/her at rest; seek
medical advice.
4.2 Most important symptoms and effects, both acute and delayed
- Ingestion: Likely nusea, vomit, diarrhea.
- Eye contact: Likely irritation.
4.3 Indication of any immediate medical attention and special treatment needed
Not relevant.
5. Fire-fighting Measures
5.1 Extinguishing media
- Suitable extinguishing media: CO2 , foam, powder.
- Information on appropriate extinguishing media: Not relevant.
- Unsuitable extinguishing media: Direct water jet.

5.2 Special hazards arising from the substance/mixture
In case of combustion, the product may produce fumes containing also carbon monoxide.
5.3 Advice for firefighters

Keep containers cool with water spray.
6. Accidental Release Measures

6.1 Personal precautions, protective equipment and emergency procedures
Take away any ignition sources. Wear protective equipment (glasses, gloves, protective clothes). Provide ade-
quate ventilation. Move away all non-equipped personnel.
6.2 Environmental precautions

Contain the spilled material; do not let it flow into the drains. In case of accidental release to drains or sur-
face/ground water, inform competent Authorities.
6.3 Methods and material for containment and cleaning up

Contain the spilled material with an inert, non-combustible absorbent material such as sand, paper, towels,
sawdust, etc. If necessary, cover drains. Dispose of contaminated material according to Section 13.
6.4 Reference to other sections

See Sections 8 and 13.
7. Handling and storage

7.1 Precautions for safe handling
All working processes must be executed in well-ventilated place with forced vapour suction.
Avoid contact with eyes and skin. Do not eat, drink. Smoking must be forbidden in the areas where the product
is handled. Wash hands after use. Remove contaminated clothing before entering eating areas.
7.2 Conditions for safe storage, including any incompatibilities

Store the product in tightly sealed and preferably full containers, in a cool, dry and ventilated location. Protect
from light, heat, flames.
Do not store with foods.
If properly stored, the product life will last approx. 24 months. After this period, the product must be re-
examined to ascertain its usability.
7.3 Specific end uses

None in addition to those already mentioned on Section 1.
8. Exposure controls/personal protection

8.1 Control parameters
The substances which present Community occupational exposure limits, in accordance with Directives 91/322/EEC
and 98/24/EC, implemented by Directives 2000/39/EC, 2006/15/EC, 2009/161/EU, are the following:

substance CAS TWA Lim. (8h)1 STEL Lim.2
Citral 5392-40-5 5 0
Beta pinene 127-91-3 20 0
Note 1. Limit value expressed in ppm (part per million in air, ml/m3 ) measured or calculated, as Time-Weighted Average
(TWA), in relation to a reference period of 8 hours.
Note 2. Short-term exposure limit (STEL) expressed in ppm (part per million in air, ml/m3 ). A limit value above which
exposure should not occurand which is related to a 15-minute period unless otherwise specified.
List of components for which DNEL and PNEC values are available:
Substance: Terpineol
DNEL [consumer - long term exposure - systemic effects - ingestion] : 0.42 mg/kg bw/day
DNEL [consumer - short term exposure - systemic effects - ingestion] : 2.5 mg/kg bw/day
DNEL [worker - long term exposure - systemic effects - skin contact] : 1.17 mg/kg bw/day
DNEL [consumer - short term exposure - systemic effects - skin contact] : 2.5 mg/kg bw/day
DNEL [worker - short term exposure - systemic effects - skin contact] : 5. mg/kg bw/day
DNEL [consumer - long term exposure - systemic effects - inhalation] : 1.25 mg/m3
DNEL [worker - long term exposure - systemic effects - inhalation] : 5.8 mg/m3
DNEL [consumer - short term exposure - systemic effects - inhalation] : 1.25 mg/m3
DNEL [worker - short term exposure - systemic effects - inhalation] : 5.8 mg/m3
PNEC [water, fresh] : 0.062 mg/L
PNEC [water, sea] : 0.0062 mg/L
PNEC [sediment, fresh] : 0.442 mg/Kg
PNEC [sediment, sea] : 0.044 mg/Kg
PNEC [depurator] : 2.57 mg/L
PNEC [soil] : 0.052 mg/Kg
DNEL [consumer - long term exposure - systemic effects - skin contact] : 12.5 mg/kg bw/day
Substance: Decanal
DNEL [worker - long term exposure - systemic effects - skin contact] : 7. mg/kg bw/day
Substance: Citral

DNEL [worker - long term exposure - systemic effects - inhalation] : 9000. mg/m3
DNEL [worker - long term exposure - systemic effects - skin contact] : 1700. mg/kg bw/day
DNEL [worker - long term exposure - local effects - skin contact] : 0.14 mg/cm2
DNEL [consumer - long term exposure - systemic effects - skin contact] : 1000. mg/kg bw/day
DNEL [consumer - long term exposure - local effects - skin contact] : 0.14 mg/cm2
DNEL [consumer - long term exposure - systemic effects - ingestion] : 600. mg/kg bw/day
PNEC [water, intermittent] : 0.0678 mg/L
Substance: Limonene
PNEC [depurator] : 18. mg/L
Substance: Citronellol
DNEL [worker - short term exposure - local effects - inhalation] : 10. mg/m3
DNEL [worker - long term exposure - local effects - inhalation] : 10. mg/m3
DNEL [consumer - long term exposure - local effects - inhalation] : 10. mg/m3
DNEL [consumer - short term exposure - local effects - inhalation] : 10. mg/m3
DNEL [consumer - short term exposure - local effects - skin contact] : 2.95 mg/cm2

PNEC [depurator] : 580. mg/L
Substance: Geraniol
DNEL [consumer - long term exposure - local effects - skin contact] : 11.8 mg/cm2
Substance: Beta pinene
8.2 Exposure controls
- Eye/face protection: Safety glasses with side protection.
- Hand protection: Chemical resistant gloves (EN 374); materials suitable for direct and prolonged contact
(recommendation: protection factor 6, corresponding to > 480 minutes permeation time). Handle the
product wearing gloves.
- Respiratory protection: Work under forced suction of fumes/vapours.
- Others: The instructions and information reported above are based on the data sheets received from our
Suppliers. Pay attention to the fact that many factors, e.g. Temperature, may alter the permeation time
of the protective gloves thus affecting their effective lifetime.

9. Physical and chemical properties
9.1 Information on basic physical and chemical properties
These are the most relevant physical and chemical properties:
property value/description
Physical state Liquid

Colour giallo chiaro
Odour characteristic
Melting point/freezing point not determinable
Boiling point not determinable
Boiling range not determined
Flash point (CC) 73 ◦ C ± 3 ◦C
Explosion limits not determinable
Auto-ignition temperature not determined
Decomposition temperature not applicable
pH not applicable
Kinematic viscosity non determined
Water Solubility no
Solubility in organic solvents yes
log POW not applicable
Vapour pressure not determined
Relative density (20C) 0,974 ± 0,010
Refraction index (20C) 1,466 ± 0,010
Relative vapour density not determinable
Particle characteristics not applicable
Note: Being the product a mixture of substances with different properties, some of the parameters are not determinable.
9.2 Other information

All the relevant physical and chemical properties are listed on point 9.1.
10. Stability and reactivity

10.1 Reactivity:
Under normal conditions of use, the product does not present hazards by its reactivity.
10.2 Chemical stability:

The product is stable under the recommended handling and storage conditions (see Section 7).
10.3 Possibility of hazardous reactions:

The product does not present possibility of hazardous reactions.
10.4 Conditions to avoid:

Avoid temperatures near or above the flash point. Do not heat the containers.

10.5 Incompatible materials:
Strong oxidizers, highly alkaline or acidic materials; iron and iron salts.
10.6 Hazardous decomposition products:

In case of combustion, dangerous products, such as carbon monoxide or dioxide, can be generated. See Section 5.
11. Toxicological information

11.1 Information on toxicological effects
There are no tested data available on the product as such.
The tables below show the information for hazard classes, based on the available data.
Acute toxicity . According to available data, the classification criteria are not met.
Skin corrosion/irritation; serious eye damage/irritation. The product is classified as follows: Causes
skin irritation. Causes serious eye irritation.
Respiratory or skin sensitisation. The product is classified as follows: May cause an allergic skin
reaction.
CMR. According to available data, the classification criteria are not met.
STOT, single or repeated exposure. According to available data, the classification criteria are not met.
Aspiration hazard . The product is classified as follows: May be fatal if swallowed and enters air-
ways.
Below are indicated, if significant, the values of LD50 (mg/Kg body weight) or LC50 (mg/l) calculated
for the mixture.
Route of expos. Categ. LC50/LD50 min. (mixture)
ingestion - not relevant (mixture not classified)
skin contact - not relevant (mixture not classified)
inhalation - not relevant (mixture not classified)
Information on ingredients.
As a complement of the information given on Sections 2-3, the table below lists the ingredients which are
classified in Acute Toxicity class according to Regulation 1272/2008/EC (CLP) and, where available, their
LC50 or LD50 min. values, measured or estimated (see Note):
substance CAS Route of expos. Categ. LD50/LC501 min.
alpha-Terpinene 99-86-5 ingestion 4 500.00 mg/Kg bw
Note 1. When no measured data are available, the reported value is the point estimate related to the category, according to
Reg. 1272/2008, Ann. I, Table 3.1.2.

The following is the list of components that have a classification in classes of Skin corrosion/irritation;
serious eye damage/irritation; Respiratory or skin sensitisation:
substance CAS H phrase
Orange Oil Terpenes 100% natural 8028-48-6 Causes skin irritation.

May cause an allergic skin reaction.
Terpineol 8000-41-7 Causes skin irritation.

Causes serious eye irritation.
2,6-dimethyloct-7-en-2-ol 18479-58-8 Causes skin irritation.

Decanal 112-31-2 Causes serious eye irritation.
Citral 5392-40-5 Causes skin irritation.

Limonene 5989-27-5 Causes skin irritation.

Citronellol 106-22-9 Causes skin irritation.

Geraniol 106-24-1 Causes skin irritation.

Causes serious eye damage.
p-Mentha-1,4(8)-diene 586-62-9 May cause an allergic skin reaction.
Nerol 106-25-2 Causes skin irritation.

Causes serious eye damage.
Beta pinene 127-91-3 Causes skin irritation.

alpha-Terpinene 99-86-5 May cause an allergic skin reaction.

2,4-dimethyl-3-cyclohexen-1-carboxaldehyde 68039-49-6 Causes skin irritation.

The following is the list of components that have a classification in classes of CMR:
substance CAS H phrase
Gamma-terpinene 99-85-4 Suspected of damaging fertility or the unborn child.

The following is the list of components that have a classification in classes of STOT, single or repeated
exposure:
No substance.
12. Ecological information

There are no tested data available on the product as such, for what regards the environmental impact in case
of accidental release.
12.1 Toxicity
As shown on Section 2, according to criteria exposed on Regulation 1272/2008 (CLP), as regards the effects
on environment this product is classified as follows:
Toxic to aquatic life with long lasting effects.
The following is the list of components that have a classification in classes of Environmental hazard :
substance CAS H phrase (M-fact.)
Orange Oil Terpenes 100% natural 8028-48-6 H411
Decanal 112-31-2 H412
3a,4,5,6,7,7a-hexahydro-7-methano-1(3)H-inden-6-yl acet 5413-60-5 H412
Limonene 5989-27-5 H400 (M = 1.00)

H410 (M = 1.00)
p-Mentha-1,4(8)-diene 586-62-9 H400 (M = 1.00)

H410 (M = 1.00)
Beta pinene 127-91-3 H400 (M = 1.00)

H410 (M = 1.00)
alpha-Terpinene 99-86-5 H411
2,4-dimethyl-3-cyclohexen-1-carboxaldehyde 68039-49-6 H411
12.2 Persistence and degradability

No information is available about persistence and degradability of the product as such.
12.3 Bioaccumulative potential

No information is available about bioaccumulative potential of the product as such.
12.4 Mobility in soil

No information is available about mobility in soil. Do not allow the product to enter sewers or waterways.
12.5 Result of PBT and vPvB assessment

No information is available about PBT and vPvB assessment of the product.
12.6 Other adverse effects

No adverse effects on the environment, other than those explained in this document, are known.
13. Disposal considerations

13.1 Waste treatment methods
To dispose of any remnants of the product and the containers, turn to a chemical-waste collection Company.
Waste and empty containers must be handled and eliminated according to current legislation. Avoid release to
the environment. Do not dump into sewers or waterways.
Attenersi alla direttiva 2008/98/EC (e successive modif.) relativa alla gestione dei rifiuti.
14. Transport information

The transport is subject to ADR agreement concerning carriage by road, RID regulation concerning carriage
by rail, ADN agreement for carriage by inland waterways,IMDG code for transport by sea, and ICAO/IATA
instructions for carriage by air.
14.1 UN Number or ID Number: 3082
14.2 UN proper shipping name:

ENVIRONMENTALLY HAZARDOUS SUBSTANCE, LIQUID, N.O.S. (ORANGE OIL TERPENES 100%
NATURAL, D-LIMONENE)
14.3 Transport hazard class: 9
14.4 Packing group: III
14.5 Environmental hazard

As regards the transport, the product is classified as environmentally hazardous.
IMDG - Marine Pollutant: Yes
14.6 Special precautions for users

IMDG - EmS Code (Emergency Schedule): F-A S-F
14.7 Maritime transport in bulk according to IMO instruments

Not applicable.

15. Regulatory information
15.1 Safety, health and environmental regulations/legislation specific for the product
This document has been prepared according to the following Directives and Regulations, and their emendements,
modifications and adaptations: Directive 67/548/EC (Classification, Labelling and Packaging of dangerous sub-
stances)
Directive 91/322/EEC (establishing indicative limit values on the protection of workers against the risks related
to exposure to chemical, physical and biological agents at work.
Directive 98/24/EC (Protection of the health and safety of workers)
Directive 2000/39/EC (implementing Directive 98/24/EC)
Directive 2006/15/EC (implementing Directive 98/24/EC and emending Directives 91/322/EEC and 2000/39/EC).
Directive 2009/161/EU (implementing Directive 98/24/EC and emending Directive 2000/39/EC).
Regulation 1907/2006/EC (REACH)
Regulation 1272/2008/EC (CLP)
Regulation 790/2009/EC (amending Regulation 1272/2008/EC).
Regulation 453/2010/EU (amending Regulation 1907/2006/EC).
Regulation 830/2015/EU (amending Regulations 1907/2006/EC, 1272/2008/EC).
15.2 Chemical safety assessment

A Chemical Safety Assessment has been carried out for the following substances, contained in the product:
Orange Oil Terpenes 100% natural
Terpineol
Decanal
Citral
Citronellol
16. Other information

Full text of the CLP hazard statements on Section 3 of the MSDS
H226 Flammable liquid and vapour.
H302 Harmful if swallowed.
H304 May be fatal if swallowed and enters airways.
H315 Causes skin irritation.
H317 May cause an allergic skin reaction.
H318 Causes serious eye damage.
H319 Causes serious eye irritation.
H361 Suspected of damaging fertility or the unborn child.
H400 Very toxic to aquatic life.
H410 Very toxic to aquatic life with long lasting effects.
H411 Toxic to aquatic life with long lasting effects.
H412 Harmful to aquatic life with long lasting effects.
Note
This document has been prepared in accordance with the Regulation 830/2015/EU, and with the Regulations
cited on Section 15.
Other sources of information were the latest versions of the Code of Practice and Labelling Manual, prepared
by the International Fragrance Association (IFRA) ; moreover, the IFRA Standard for perfumery substances

were taken into account; and the Guidelines, the Information Letters and Communications by IFRA were also
considered. For more information visit IFRA’s website.
The data and information contained in this Safety Data Sheet are based on current knowledge, and on current
EU and national laws; they only state a description of the safety requirements for the product, and must not
be considered as a guarantee of its properties.
The effective working conditions of the users are beyond our knowledge and control; it is the user’s responsability
to take the appropriate measures in order to comply with the requirements established by current legislation.
The product must not be used for purposes other than those specified in this document.
Exposure Scenarioes
In compliance with the prescriptions of Regulation 1907/2006/EC, we make available the Exposure Scenarioes
of the Substances, where present. Substances presenting an Exposure Scenario are marked with the symbol†
on Section 3.
Here are the substances for which an Exposure Scenario is available, and the link for direct download:
Orange Oil Terpenes 100% natural
Terpineol
Decanal
Citral
Citronellol
List of the acronyms

ADN Accord européen relative au transport international des marchandises dangereuses par voies de navigation intérieures
(European Agreement concerning the international carriage of dangerous goods by inland waterway)
ADR Accord européen relative au transport international des marchandises dangereuses par route (European agreement
concerning the international carriage of dangerous goods by road)
LC50 Lethal Concentration 50% (concentration lethal for the 50% of the individuals tested)
LD50 Lethal Dose 50% (lethal dose for the 50% of the individuals tested)
CLP Classification, Labelling, Packaging
CSR Chemical Safety Report
IATA International Air Transport Association
ICAO International Civil Aviation Organization
IMDG International Maritime Dangerous Goods [code]
log POW (Logarithm of the) octanol-water partition coefficient
PBT Persistent, bioaccumulative, toxic
RID Règlement concernent le transport international ferroviaire des marchandises dangereuses (Convention concerning
the international carriage of dangerous goods by rail)
STEL Short term exposure limit
TWA Time weighted average
vPvB Very persistent, very bioaccumulative
Revision Date: 28/03/2022 Print Date: 29/03/2022
This document was generated by an automated system, therefore it is not signed.

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MATERIAL SAFETY DATA SHEET

In compliance with EU Regulations 1907/2006/CE, 1272/2008/CE, 830/2015/EU

Revision: 2.1 28/03/2022 Print Date: 29/03/2022

1. Identiﬁcation of the Product and of the Company

1.3 Details of the supplier of the safety data sheet

1.4 Emergency telephone

H304 Aspiration hazard Cat. 1

2.2 Label elements

Sgn. word: Danger

Material Safety Data Sheet: LEMON D TYPE FRAGRANCE 00004-FR-001 Pag. 1 of 15

2.3 Other hazards

substance Reach regist. CE nr.; CLP Classif.1 %

2,6-dimethyloct-7-en-2-ol 01-2119457274- 242-362-4 ; Skin Irrit. 2 H315; Eye 3,10

contd. on next page

3a,4,5,6,7,7a-hexahydro-7- - 226-501-6 ; Aquatic Chron 3 H412 1,42

Limonene 01-2119529223- 227-813-5 ; Flam. Liq. 3 H226; Asp. 1,15

Geraniol 01-2119552430- 203-377-1 ; Skin Irrit. 2 H315; Skin 0,30

p-Mentha-1,4(8)-diene - 209-578-0 ; Flam. Liq. 3 H226; Asp. 0,25

Nerol 01-2119983244- 203-378-7 ; Skin Irrit. 2 H315; Skin 0,20

Beta pinene - 204-872-5 ; Flam. Liq. 3 H226; Asp. 0,18

alpha-Terpinene - 202-795-1 ; Flam. Liq. 3 H226; Acute 0,17

Gamma-terpinene - 202-794-6 ; Flam. Liq. 3 H226; Asp. 0,16

contd. on next page

Material Safety Data Sheet: LEMON D TYPE FRAGRANCE 00004-FR-001 Pag. 3 of 15

2,4-dimethyl-3-cyclohexen-1- 01-2119982384- 943-728-2 ; Skin Irrit. 2 H315; Skin 0,10

Note 1. See Section 16 for the full text of the phrases.

- Ingestion: Likely nusea, vomit, diarrhea.

- Eye contact: Likely irritation.

- Suitable extinguishing media: CO2 , foam, powder.

- Information on appropriate extinguishing media: Not relevant.

- Unsuitable extinguishing media: Direct water jet.

Material Safety Data Sheet: LEMON D TYPE FRAGRANCE 00004-FR-001 Pag. 4 of 15

5.3 Advice for ﬁreﬁghters

6. Accidental Release Measures

6.2 Environmental precautions

6.3 Methods and material for containment and cleaning up

6.4 Reference to other sections

7. Handling and storage

7.2 Conditions for safe storage, including any incompatibilities

7.3 Speciﬁc end uses

8. Exposure controls/personal protection

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Substance: Beta pinene

- Eye/face protection: Safety glasses with side protection.

- Respiratory protection: Work under forced suction of fumes/vapours.

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Physical state Liquid

9.2 Other information

10. Stability and reactivity

10.2 Chemical stability:

10.3 Possibility of hazardous reactions:

10.4 Conditions to avoid:

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10.6 Hazardous decomposition products:

11. Toxicological information

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substance CAS H phrase

Orange Oil Terpenes 100% natural 8028-48-6 Causes skin irritation.

Terpineol 8000-41-7 Causes skin irritation.

2,6-dimethyloct-7-en-2-ol 18479-58-8 Causes skin irritation.