Safety Data Sheet for DODICOR 2725 NF corrosion inhibitor

SAFETY DATA SHEET
according to Regulation (EC) No. 1907/2006
DODICOR 2725 NF Page 1(30)

Substance key: 000000212085 Revision Date: 01.12.2017
Version : 4 - 1 / EU Date of printing : 18.12.2017
SECTION 1: Identification of the substance/mixture and of the company/undertaking
1.1. Product identifier

Trade name
DODICOR 2725 NF
Material number: 109548
Chemical nature: Preparation of an Alkinol containing quaternary Ammonium
compound with nonionic surfactant
1.2. Relevant identified uses of the substance or mixture and uses advised against
Relevant identified uses of the substance or mixture
Industry sector : Fuel industry
Type of use : Acid inhibitor
Corrosion inhibitor
1.3. Details of the supplier of the safety data sheet

Identification of the company
Clariant Produkte (Deutschland) GmbH
65926 Frankfurt am Main
Telephone no. : +49 69 305 18000
Information about the substance/mixture
BU Oil & Mining Services
Product Stewardship
e-mail: SDS.Europe@clariant.com
1.4. Emergency telephone number

00800-5121 5121 (24 h)
SECTION 2: Hazards identification
2.1 Classification of the substance or mixture

Classification (REGULATION (EC) No 1272/2008)
Acute toxicity, Category 4 H332: Harmful if inhaled.
Acute toxicity, Category 4 H312: Harmful in contact with skin.
Skin corrosion, Sub-category 1B H314: Causes severe skin burns and eye damage.
Serious eye damage, Category 1 H318: Causes serious eye damage.
Skin sensitisation, Category 1 H317: May cause an allergic skin reaction.
Specific target organ toxicity - repeated H373: May cause damage to organs through
exposure, Category 2 prolonged or repeated exposure.
Chronic aquatic toxicity, Category 3 H412: Harmful to aquatic life with long lasting
effects.
SAFETY DATA SHEET

2.2 Label elements

Labelling (REGULATION (EC) No 1272/2008)
Hazard pictograms :
Signal word : Danger
Hazard statements : H312 + H332 Harmful in contact with skin or if inhaled.

H314 Causes severe skin burns and eye damage.
H317 May cause an allergic skin reaction.
H373 May cause damage to organs through prolonged or
repeated exposure.
H412 Harmful to aquatic life with long lasting effects.
Precautionary statements :
Prevention:
P260 Do not breathe dust/ fume/ gas/ mist/ vapours/ spray.
P273 Avoid release to the environment.
P280 Wear protective gloves/ protective clothing/ eye
protection/ face protection.
Response:
P303 + P361 + P353 IF ON SKIN (or hair): Take off
immediately all contaminated clothing. Rinse skin with water.
P304 + P340 + P310 IF INHALED: Remove person to fresh
air and keep comfortable for breathing. Immediately call a
POISON CENTER/doctor.
P305 + P351 + P338 + P310 IF IN EYES: Rinse cautiously
with water for several minutes. Remove contact lenses, if
present and easy to do. Continue rinsing. Immediately call a
POISON CENTER/doctor.
Hazardous components which must be listed on the label:

C11-Oxoalcohol, 6-15 EO
Diethylene glycol
Naphthenic acid imidazoline benzylquat
Prop-2-yn-1-ol
2.3 Other hazards
This substance/mixture contains no components considered to be either persistent,
bioaccumulative and toxic (PBT), or very persistent and very bioaccumulative (vPvB) at levels of
0.1% or higher.
No additional hazards are known except those derived from the labelling.
SECTION 3: Composition/information on ingredients
3.2 Mixtures
Hazardous components
Chemical name CAS-No. Classification Concentration
SAFETY DATA SHEET

EC-No. (% w/w)
Index-No.
Registration number
C11-Oxoalcohol, 6-15 EO 127036-24-2 Acute Tox. 4; H302 >= 30 - < 50
Eye Dam. 1; H318
2-Butoxy ethanol 111-76-2 Acute Tox. 4; H302 >= 20 - < 30
203-905-0 Acute Tox. 4; H332
603-014-00-0 Acute Tox. 4; H312
01-2119475108-36 Skin Irrit. 2; H315
01-2119475108-36- Eye Irrit. 2; H319
0000
01-2119475108-36-
0018
01-2119475108-36-
XXXX
Naphthenic acid imidazoline 73049-47-5 Skin Corr. 1B; H314 >= 10 - < 20
benzylquat 277-250-4
Diethylene glycol 111-46-6 Acute Tox. 4; H302 >= 10 - < 20
203-872-2 STOT RE 2; H373
603-140-00-6
01-2119457857-21
01-2119457857-21-
0002
01-2119457857-21-
0021
01-2119457857-21-
0051
01-2119457857-21-
XXXX
Prop-2-yn-1-ol 107-19-7 Flam. Liq. 3; H226 >= 3 - < 5
203-471-2 Acute Tox. 2; H330
603-078-00-X Acute Tox. 3; H301
01-2119489016-35- Acute Tox. 2; H310
0000 Skin Corr. 1B; H314
Eye Dam. 1; H318
STOT RE 2; H373
Aquatic Chronic 2;
H411
N-(2-Ethylhexyl)isononan-1-amide 93820-33-8 Aquatic Acute 1; >= 0,25 - < 1
298-613-3 H400
01-2119984313-35-
0000
For explanation of abbreviations see section 16.
SECTION 4: First aid measures
4.1 Description of first aid measures

General advice : Remove/Take off immediately all contaminated clothing.
In the case of accident or if you feel unwell, seek medical
advice immediately.
If inhaled : If inhaled, remove to fresh air.

SAFETY DATA SHEET

Get medical advice/ attention.
In case of skin contact : In case of contact, immediately flush skin with soap and plenty
of water.
In case of eye contact : In case of contact, immediately flush eyes with plenty of water
for at least 15 minutes.
If swallowed : If swallowed, seek medical advice immediately and show this

container or label.
4.2 Most important symptoms and effects, both acute and delayed
Symptoms : No symptoms known currently.
Risks : No hazards known at this time.
4.3 Indication of any immediate medical attention and special treatment needed
Treatment : Treat symptomatically.
SECTION 5: Firefighting measures
5.1 Extinguishing media

Suitable extinguishing media : Water spray jet
Alcohol-resistant foam
Carbon dioxide (CO2)
Dry powder
5.2 Special hazards arising from the substance or mixture

Specific hazards during : In case of fires, hazardous combustion gases are formed:
firefighting Carbon monoxide (CO)
Nitrogen oxides (NOx)
5.3 Advice for firefighters

Special protective equipment : Self-contained breathing apparatus
for firefighters
SECTION 6: Accidental release measures
6.1 Personal precautions, protective equipment and emergency procedures

Personal precautions : Ensure adequate ventilation.
Wear suitable protective clothing.
Keep away sources of ignition.
6.2 Environmental precautions

Environmental precautions : Do not allow to enter drains or waterways
SAFETY DATA SHEET

6.3 Methods and material for containment and cleaning up

Methods for cleaning up : Take up mechanically. Dilute remainder with water and take
up with absorbent material (eg sawdust, sand, universal
binder)
6.4 Reference to other sections

Information regarding Safe handling, see chapter 7., For personal protection see section 8., For
disposal considerations see section 13.
SECTION 7: Handling and storage
7.1 Precautions for safe handling

Advice on safe handling : Handle and open container with care.
Ensure adequate ventilation.
Advice on protection against : Keep away from sources of ignition - No smoking.

fire and explosion
Hygiene measures : Wash hands before breaks and at the end of workday. Use
protective skin cream before handling the product. Take off
immediately all contaminated clothing and wash it before
reuse.
7.2 Conditions for safe storage, including any incompatibilities

Further information on : Keep container tightly closed.
storage conditions
7.3 Specific end use(s)

Specific use(s) : No further recommendations.
SECTION 8: Exposure controls/personal protection
8.1 Control parameters

Derived No Effect Level (DNEL) according to Regulation (EC) No. 1907/2006:
Substance name End Use Exposure routes Potential health Value
effects
Prop-2-yn-1-ol Workers Dermal Long-term systemic 0,83 mg/kg
CAS-No.: 107-19-7 effects
Remarks: DNEL
Workers Inhalation Long-term systemic 4,7 mg/m3
effects
Remarks: DNEL
Diethylene glycol Workers Dermal Long-term systemic 43 mg/kg
CAS-No.: 111-46-6 effects bw/day
Remarks: DNEL
SAFETY DATA SHEET

Workers Inhalation Long-term local 60 mg/m3

effects
Remarks: DNEL
General Dermal Long-term systemic 21 mg/kg
population effects bw/day
Remarks: DNEL
General Inhalation Long-term local 12 mg/m3
population effects
Remarks: DNEL
Workers Inhalation Long-term systemic 44 mg/m3
effects
Remarks: DNEL
General Inhalation Long-term systemic 12 mg/m3
population effects
Remarks: DNEL
2-Butoxy ethanol Workers Inhalation Long-term systemic 98 mg/m3
CAS-No.: 111-76-2 effects
Remarks: DNEL
Workers Inhalation Acute systemic 1091 mg/m3
effects
Remarks: DNEL
Workers Inhalation Long-term local 246 mg/m3
effects
Remarks: DNEL
Workers Skin contact Long-term systemic 125 mg/kg
effects bw/day
Remarks: DNEL
Workers Skin contact Acute systemic 89 mg/kg
effects bw/day
Remarks: DNEL
General Inhalation Long-term systemic 59 mg/m3
population effects
Remarks: DNEL
General Inhalation Long-term local 147 mg/m3
population effects
Remarks: DNEL
General Skin contact Long-term systemic 75 mg/kg
Remarks: DNEL
General Skin contact Acute systemic 89 mg/kg
Remarks: DNEL
General Ingestion Long-term systemic 6,3 mg/kg
Remarks: DNEL
General Ingestion Acute systemic 26,7 mg/kg
Remarks: DNEL
General Inhalation Acute systemic 426 mg/m3
population effects
Remarks: DNEL
N-(2- Workers Inhalation Long-term systemic 8,8 mg/m3
SAFETY DATA SHEET

Ethylhexyl)isononan- effects
1-amide
CAS-No.: 93820-33-8
Remarks: DNEL
Workers Dermal Long-term systemic 2,5 mg/kg
effects bw/day
Remarks: DNEL
General Inhalation Long-term systemic 3,125 mg/m3
population effects
Remarks: DNEL
General Dermal Long-term systemic 1,79 mg/kg
Remarks: DNEL
General Oral Long-term systemic 1,79 mg/kg
Remarks: DNEL
Predicted No Effect Concentration (PNEC) according to Regulation (EC) No. 1907/2006:
Substance name Environmental Compartment Value
Prop-2-yn-1-ol Fresh water 0,002 mg/l
CAS-No.: 107-19-7
Marine water 0 mg/l
Water (intermittent release) 0,015 mg/l
Sewage treatment plant 10 mg/l
Fresh water sediment 0,006 mg/kg dry
weight (d.w.)
Marine sediment 0,001 mg/kg dry
weight (d.w.)
Soil 0 mg/kg dry
weight (d.w.)
Oral 1,11 mg/kg food
Diethylene glycol Fresh water sediment 20,9 mg/kg dry
CAS-No.: 111-46-6 weight (d.w.)
Soil 1,53 mg/kg dry
weight (d.w.)
Sewage treatment plant 199,5 mg/l
Fresh water 10 mg/l
Marine water 1 mg/l
weight (d.w.)
2-Butoxy ethanol Fresh water 8,8 mg/l
CAS-No.: 111-76-2
salt water 0,88 mg/l
Fresh water sediment 34,6 mg/kg dry
weight (d.w.)
Soil 2,33 mg/kg dry
weight (d.w.)
Water (intermittent release) 9,1 mg/l
weight (d.w.)
Oral 0,02 mg/kg food
SAFETY DATA SHEET

N-(2-Ethylhexyl)isononan-1- Fresh water 0,00157 mg/l

amide
CAS-No.: 93820-33-8
Intermittent use/release 0,00475 mg/l
Marine water 0,000157 mg/l
Sediment 1,25 mg/kg dry
weight (d.w.)
weight (d.w.)
Soil 0,44 mg/kg dry
weight (d.w.)
Secondary Poisoning 33,3 mg/kg food
8.2 Exposure controls
Personal protective equipment
Eye protection : Depending on the risk, wear sufficient eye protection (safety
glasses with side protection or goggles, and if necessary,
face shield.)
Hand protection
Remarks : These types of protective gloves are offered by various
manufacturers. Please note the manufacturers´ detailed
statements, especially about the minimum thickness and the
minimum breakthrough time. Consider also the particular
working conditions under which the gloves are being used.
Break through time : 30 min

Glove thickness : 0,4 mm
Remarks : For short-term exposure (splash protection): Nitrile rubber
gloves.
Break through time : 480 min

Glove thickness : 0,7 mm
Remarks : Long-term exposure Impervious butyl rubber gloves
Skin and body protection : Wear suitable protective clothing.
Respiratory protection : Use respiratory protection in case of insufficient exhaust

ventilation or prolonged exposure
Full mask, filter A
Full mask to standard DIN EN 136
Filter class 2
The use of filter apparatus presupposes that the environment
atmosphere contains at least 17% oxygen by volume, and
does not exceed the maximum gas concentration, usually
0.5% by volume. Relevant guidelines to be considered
include EN 136/141/143/371/372 as well as other national
regulations.
Applicable national Regulations must be observed. Take note
of the limitations regarding wear-time, in conjunction with the
Regulations for the use of Respiratory Protective Equipment.
SAFETY DATA SHEET

Protective measures : Avoid contact with skin and eyes.

Do not inhale vapours
SECTION 9: Physical and chemical properties
9.1 Information on basic physical and chemical properties

Appearance : Liquid
Colour : yellow to brownish
Odour : characteristic
Odour Threshold : not tested.
pH : approx. 4 (20 °C)

Concentration: 10 g/l
pour point : approx. -20 °C

Method: ISO 3016
Initial boiling point : > 100 °C

Method: DIN 51751
Flash point : approx. 92 °C

Method: EN 22719 (closed cup)
Evaporation rate : Not applicable
Burning number : Not applicable
Upper explosion limit / upper : not tested.

flammability limit
Lower explosion limit / Lower : not tested.

flammability limit
Vapour pressure : approx. 1 mbar (20 °C)

Method: calculated
Relative vapour density : Not applicable
Density : approx. 1,01 g/cm3 (20 °C)

Method: DIN EN ISO 15212-1
Bulk density : Not applicable
Solubility(ies)
Water solubility : soluble (20 °C)
Solubility in other solvents : not tested.

Solvent: fat
SAFETY DATA SHEET

Partition coefficient: n- : not determined

octanol/water
Auto-ignition temperature : not tested.
Decomposition temperature : 240 °C

Method: DTA
Viscosity
Viscosity, dynamic : approx. 35 mPa.s (20 °C)
Method: DIN 53015
Viscosity, kinematic : not tested.
Explosive properties : no data available
Oxidizing properties : Not applicable
9.2 Other information

Minimum ignition energy : not tested.
Particle size : Not applicable
Self-ignition : Not applicable
SECTION 10: Stability and reactivity
10.1 Reactivity
See section 10.3. "Possibility of hazardous reactions"
10.2 Chemical stability
Stable under normal conditions.
10.3 Possibility of hazardous reactions
Hazardous reactions : Uncleaned empty vessels may contain product gases which
can form explosive mixtures with air.
10.4 Conditions to avoid

Conditions to avoid : None known.
10.5 Incompatible materials

Materials to avoid : not known
10.6 Hazardous decomposition products

When handled and stored appropriately, no dangerous decomposition products are known
SAFETY DATA SHEET

SECTION 11: Toxicological information
11.1 Information on toxicological effects

Acute toxicity
Product:
Acute oral toxicity : LD50 (Rat): > 2.000 mg/kg
Method: OECD Test Guideline 401
Acute inhalation toxicity : Acute toxicity estimate: 12,64 mg/l

Exposure time: 4 h
Test atmosphere: vapour
Method: Calculation method
Acute dermal toxicity : Acute toxicity estimate: 1.881 mg/kg

Method: Calculation method
Components:
2-Butoxy ethanol:
Acute oral toxicity : LD50 (Rat): 1.746 mg/kg
Acute toxicity estimate: 500 mg/kg

Method: Converted acute toxicity point estimate
Acute dermal toxicity : LD50 (Pig): 6.411 mg/kg
Acute toxicity estimate: 1.100 mg/kg

Method: Converted acute toxicity point estimate
Diethylene glycol:
Acute oral toxicity : LD50 (Rat, male): 19.600 mg/kg
Method: Other
GLP: no
Acute inhalation toxicity : LC50 (Rat): > 4,6 mg/l

Exposure time: 4 h
Method: Other
GLP: no
Assessment: The substance or mixture has no acute
inhalation toxicity
Acute dermal toxicity : LD50 (Rabbit): 13.300 mg/kg

Method: Other
GLP: no
Assessment: The substance or mixture has no acute dermal
toxicity
Prop-2-yn-1-ol:
Acute oral toxicity : LD50 (Rat): 56,4 mg/kg
Method: BASF test
SAFETY DATA SHEET

Acute inhalation toxicity : LC50 (Rat): 2 mg/l

Exposure time: 2 h
GLP: no
Acute dermal toxicity : LD50 (Rabbit): 88 mg/kg
N-(2-Ethylhexyl)isononan-1-amide:
Acute oral toxicity : LD50 (Rat, male and female): > 2.000 mg/kg
GLP: yes
Acute inhalation toxicity : Remarks: This information is not available.
Acute dermal toxicity : Remarks: This information is not available.
Skin corrosion/irritation
Product:
Remarks: no data available
Components:
2-Butoxy ethanol:
Species: Rabbit
Result: irritating
Diethylene glycol:
Species: Rabbit
Exposure time: 23 h
Method: Draize Test
Result: No skin irritation
GLP: no
Prop-2-yn-1-ol:
Species: Rabbit
Method: BASF test
Result: Corrosive
Species: Rabbit
Exposure time: 4 h
Result: No skin irritation
GLP: yes
SAFETY DATA SHEET

Serious eye damage/eye irritation

Product:
Components:
2-Butoxy ethanol:
Species: rabbit eye
Result: irritating
Diethylene glycol:
Species: rabbit eye
Method: Other
Result: non-irritant
GLP: no
Prop-2-yn-1-ol:
Species: rabbit eye
Method: BASF test
Result: Risk of serious damage to eyes.
Species: rabbit eye
Exposure time: 24 h
Result: No eye irritation
GLP: yes
Respiratory or skin sensitisation

Product:
Result: May cause sensitisation by skin contact.
Remarks: The product has not been tested. The information is derived from the properties of the
individual components.
Components:
Diethylene glycol:
Test Type: Guinea pig maximization test
Exposure routes: Skin contact
Species: Guinea pig
Method: Directive 67/548/EEC, Annex V, B.6.
Result: Does not cause skin sensitisation.
GLP: yes
Prop-2-yn-1-ol:
Result: The product causes irritation of eyes, skin and mucous membranes.
SAFETY DATA SHEET

Remarks: Not applicable
Test Type: Guinea pig maximization test
Species: Guinea pig
Result: Does not cause skin sensitisation.
GLP: yes
Germ cell mutagenicity

Product:
Germ cell mutagenicity- : No information available.
Assessment
Components:
Diethylene glycol:
Genotoxicity in vitro : Test Type: Ames test
Test system: Salmonella typhimurium
Concentration: 33 - 5000 µg/plate
Metabolic activation: with and without metabolic activation
Result: negative
GLP: yes
Test Type: Ames test

Test system: Escherichia coli
Concentration: 33 - 5000 µg/plate
Result: negative
GLP: yes
Genotoxicity in vivo : Test Type: Micronucleus test

Species: Mouse (male)
Strain: NMRI
Cell type: Bone marrow
Application Route: Intraperitoneal injection
Exposure time: once
Dose: 500 - 1000 - 2000 mg/kg
Result: negative
GLP: yes
Germ cell mutagenicity- : It is concluded that the product is not mutagenic based on
Assessment evaluation of several mutagenicity tests.
Prop-2-yn-1-ol:
Genotoxicity in vitro : Test Type: In vitro gene mutation study in bacteria
Result: Positive results were obtained in some in vitro tests.
SAFETY DATA SHEET

Test Type: In vitro gene mutation study in mammalian cells

Result: Positive results were obtained in some in vitro tests.
Genotoxicity in vivo : Result: Positive results were obtained in some in vivo tests.
Germ cell mutagenicity- : Mutagen

Assessment
Genotoxicity in vitro : Test Type: Ames test
Test system: Salmonella typhimurium
Concentration: 31,6 - 5000 µg/plate
Result: negative
GLP: yes
Test Type: In vitro gene mutation study in mammalian cells

Test system: mouse lymphoma cells
Concentration: 0,0005 - 10 mM
Result: negative
GLP: yes
Test Type: Micronucleus test

Test system: Chinese hamster lung cells
Concentration: 0,012 - 10 mM
Result: negative
GLP: yes
Germ cell mutagenicity- : In vitro tests did not show mutagenic effects
Assessment
Carcinogenicity
Product:
Carcinogenicity - : No information available.
Assessment
Components:
Diethylene glycol:
Carcinogenicity - : Animal testing did not show any carcinogenic effects.
Assessment
Prop-2-yn-1-ol:
Assessment
SAFETY DATA SHEET

Assessment
Reproductive toxicity
Product:
Reproductive toxicity - : No information available.
Assessment No information available.
Components:
Diethylene glycol:
Effects on fertility : Test Type: Fertility/early embryonic development
Species: Mouse, male and female
Strain: CD1
Application Route: Drinking water
Dose: 612 - 3063 - 6125 mg/kg
General Toxicity - Parent: NOAEL: 3.060 mg/kg body weight
Method: Other
GLP: No information available.
Effects on foetal : Species: Rabbit

development Application Route: oral (gavage)
Dose: 100 - 400 - 1000 mg/kg
General Toxicity Maternal: NOAEL: 1.000 mg/kg body weight
Teratogenicity: NOAEL: 1.000 mg/kg body weight
GLP: yes
Reproductive toxicity - : No reproductive toxicity to be expected.

Assessment No teratogenic effects to be expected.
Prop-2-yn-1-ol:
Effects on fertility : Remarks: Based on available data, the classification criteria
are not met.
Effects on foetal : Remarks: Based on available data, the classification criteria

development are not met.
Reproductive toxicity - : No reproductive toxicity to be expected.

Assessment No teratogenic effects to be expected.
Effects on fertility : Test Type: reproductive and developmental toxicity study
Species: Rat, male and female
Strain: wistar
Application Route: oral (gavage)
Dose: 100 - 300 - 1000 mg/kg
General Toxicity - Parent: NOAEL: >= 300 mg/kg body weight
SAFETY DATA SHEET

General Toxicity F1: NOAEL: >= 300 mg/kg body weight

GLP: yes
Effects on foetal : Remarks: This information is not available.

development
Reproductive toxicity - : Weight of evidence does not support classification for

Assessment reproductive toxicity
No information available.
STOT - single exposure

Product:
Components:
Diethylene glycol:
Assessment: The substance or mixture is not classified as specific target organ toxicant, single
exposure.
Prop-2-yn-1-ol:
exposure.
exposure.
STOT - repeated exposure

Product:
Components:
Diethylene glycol:
Target Organs: Kidney
Assessment: May cause damage to organs through prolonged or repeated exposure.
Prop-2-yn-1-ol:
Target Organs: Liver, Kidney
Assessment: May cause damage to organs through prolonged or repeated exposure.
Assessment: The substance or mixture is not classified as specific target organ toxicant,
repeated exposure.
SAFETY DATA SHEET

Repeated dose toxicity

Product:
Components:
Diethylene glycol:
NOAEL: 936 mg/kg
Application Route: oral (feed)
Exposure time: 4 w
Number of exposures: daily
Dose: 500-2500-10000-40000mg/kg diet
Group: yes
GLP: yes
Species: Dog, male

NOAEL: ca. 2.200 mg/kg
Application Route: Skin contact
Exposure time: 4 w
Dose: 0,5 - 2 - 8 ml/kg
Group: yes
GLP: yes
Remarks: By analogy with a product of similar composition
Application Route: Inhalation

Remarks: The study is not necessary from a scientific perspective.
Prop-2-yn-1-ol:
Target Organs: Liver, Kidney
Assessment: The substance or mixture is classified as specific target organ toxicant, repeated
exposure, category 2.
NOAEL: ca. 1.000 mg/kg
Application Route: oral (gavage)
Exposure time: 28 d
Dose: 100 - 300 - 1000 mg/kg
Group: yes
GLP: yes
Aspiration toxicity
Product:
no data available
SAFETY DATA SHEET

Components:
Diethylene glycol:
No aspiration toxicity classification
Prop-2-yn-1-ol:
Further information
Product:
Remarks: The classification was made by the conventional (calculation) method of the CLP
Regulation (EC) No 1272/2008.
Components:
Prop-2-yn-1-ol:
Remarks: Danger of skin resorption and allergy.
SECTION 12: Ecological information
12.1 Toxicity
Product:
Toxicity to fish : LC50 (Leuciscus idus (Golden orfe)): > 10 - 100 mg/l
Exposure time: 96 h
Toxicity to daphnia and other : Remarks: no data available

aquatic invertebrates
Toxicity to algae : Remarks: no data available
Toxicity to microorganisms :
Components:
2-Butoxy ethanol:
Toxicity to fish : LC50 (Oncorhynchus mykiss (rainbow trout)): 1.474 mg/l
Exposure time: 96 h
Toxicity to daphnia and other : EC50 (Daphnia magna (Water flea)): 1.550 mg/l
aquatic invertebrates Exposure time: 48 h
Test Type: Immobilization
SAFETY DATA SHEET

Toxicity to algae : IC50 (Pseudokirchneriella subcapitata (microalgae)): 911 mg/l

Exposure time: 72 h
Diethylene glycol:
Toxicity to fish : LC50 (Pimephales promelas (fathead minnow)): 75.200 mg/l
Exposure time: 96 h
Test Type: flow-through test
Analytical monitoring: yes
Method: Other
GLP: no
Toxicity to daphnia and other : EC50 (Daphnia magna (Water flea)): > 10.000 mg/l
Test Type: static test
Analytical monitoring: no
Method: DIN 38412 T.11
GLP: no
Remarks: The details of the toxic effect relate to the nominal
concentration.
Toxicity to algae : EC50 (green algae): 9.362 mg/l

Exposure time: 96 h
Method: estimated
GLP: no
concentration.
Toxicity to microorganisms : EC20 (activated sludge, domestic): > 1.995 mg/l

End point: Bacteria toxicity (respiration inhibition)
Exposure time: 0,5 h
Test Type: aquatic
Method: ISO 8192
GLP: no
Toxicity to fish (Chronic : Chronic Toxicity Value: 7.694 mg/l

toxicity) End point: Other
Exposure time: 30 d
Species: Fish
Method: Other
GLP: no
concentration.
Toxicity to daphnia and other : Chronic Toxicity Value: 1.891 mg/l

aquatic invertebrates Exposure time: 16 d
(Chronic toxicity) Species: Daphnia sp. (water flea)
Method: Other
GLP: No information available.
SAFETY DATA SHEET

concentration.
Toxicity to soil dwelling :

organisms Remarks: The study is not necessary from a scientific
perspective.
Plant toxicity : Remarks: The study is not necessary from a scientific

perspective.
Sediment toxicity : Remarks: The study is not necessary from a scientific

perspective.
Toxicity to terrestrial : Remarks: The study is not necessary from a scientific

organisms perspective.
Prop-2-yn-1-ol:
Toxicity to fish : LC50 (Pimephales promelas (fathead minnow)): 1,53 mg/l
Exposure time: 96 h
Test Type: flow-through test
Toxicity to daphnia and other : EC50 (Daphnia magna (Water flea)): 3,36 mg/l
Toxicity to algae : EC50 (Desmodesmus subspicatus (green algae)): > 98,1 mg/l
End point: Growth rate
Exposure time: 72 h
Toxicity to microorganisms : EC20 (activated sludge): ca. 2,5 mg/l

Exposure time: 0,5 h
Test Type: aquatic
concentration.
Toxicity to fish (Chronic : Remarks: not required

toxicity)
Toxicity to daphnia and other : Remarks: not required

aquatic invertebrates
(Chronic toxicity)
Toxicity to soil dwelling : 28 mg/kg

organisms Exposure time: 7 d
Species: other soil dwelling arthropod
Plant toxicity : Remarks: Not applicable
Sediment toxicity : Remarks: Not applicable

SAFETY DATA SHEET

Toxicity to terrestrial : Remarks: Not applicable

organisms
Toxicity to fish : LC50 (Danio rerio (zebra fish)): > 1.000 mg/l
Exposure time: 96 h
GLP: yes
concentration.
Toxicity to daphnia and other : EC50 (Daphnia magna (Water flea)): 0,475 mg/l
GLP: yes
concentration.
Toxicity to algae : EC50 (Desmodesmus subspicatus (green algae)): 0,962 mg/l

End point: Growth rate
Exposure time: 72 h
GLP: yes
EC50 (Desmodesmus subspicatus (green algae)): 0,743 mg/l

End point: Biomass
Exposure time: 72 h
GLP: yes
Toxicity to microorganisms : EC50 (activated sludge of a predominantly domestic sewage):

> 1.000 mg/l
End point: Bacteria toxicity (respiration inhibition)
Exposure time: 3 h
Test Type: aquatic
GLP: yes
concentration.
NOEC : 1000 mg/kg dry weight (d.w.)

Exposure time: 28 d
GLP:
SAFETY DATA SHEET

Toxicity to fish (Chronic : Remarks: not required

toxicity)
Toxicity to daphnia and other : NOEC: 0,028 mg/l

aquatic invertebrates End point: Reproduction rate
(Chronic toxicity) Exposure time: 21 d
Species: Daphnia magna (Water flea)
Test Type: semi-static test
Toxicity to soil dwelling : NOEC: 1000 mg/kg dry weight (d.w.)

organisms 1000 mg/kg dry weight (d.w.)
Exposure time: 96 h
Species: Eisenia fetida (earthworms)
GLP:yes
Plant toxicity : Remarks: Not applicable
Sediment toxicity : NOEC: 1000 mg/kg dry weight (d.w.)

Exposure duration: 96 h
Species: Nematode Caenorhabditis elegans
Method: ISO 10872
GLP: yes
Ecotoxicology Assessment
Acute aquatic toxicity : Very toxic to aquatic life.
Chronic aquatic toxicity : This product has no known ecotoxicological effects.
12.2 Persistence and degradability

Product:
Biodegradability : Biodegradation: > 80 %
Method: OECD Test Guideline 302B
Components:
2-Butoxy ethanol:
Biodegradability : Test Type: aerobic
Inoculum: activated sludge
Result: Readily biodegradable.
Biodegradation: 90,4 %
Exposure time: 28 d
Diethylene glycol:
Inoculum: activated sludge, domestic, non-adapted
Concentration: 44 mg/l
Biodegradation: 70 - 80 %
SAFETY DATA SHEET

Related to: Carbon dioxide (CO2)

Exposure time: 28 d
GLP: no
Test Type: aerobic

Inoculum: activated sludge, domestic
Related to: Dissolved organic carbon (DOC)
Exposure time: 28 d
Method: OECD Test Guideline 301A
GLP: yes
Prop-2-yn-1-ol:
Inoculum: Microbial inoculum
Biodegradation: 95 %
Related to: Biochemical Oxygen Demand (BOD)
Exposure time: 28 d
Method: OECD Test Guideline 301C
Physico-chemical : Remarks: Biodegradable

removability
Stability in water : Remarks: Not applicable
Inoculum: activated sludge
Related to: Carbon dioxide (CO2)
Exposure time: 28 d
GLP: yes
12.3 Bioaccumulative potential

Product:
Bioaccumulation : Remarks: no data available
Components:
Diethylene glycol:
Bioaccumulation : Species: Leuciscus idus (Golden orfe)
Exposure time: 3 d
Concentration: 0,05 mg/l
Bioconcentration factor (BCF): 100
SAFETY DATA SHEET

Method: Other
GLP: no
Prop-2-yn-1-ol:
Bioaccumulation : Remarks: Due to the distribution coefficient n-octanol/water,
accumulation in organisms is not expected.
Bioaccumulation : Bioconcentration factor (BCF): 276,2
Remarks: Due to the distribution coefficient n-octanol/water,
accumulation in organisms is not expected.
Partition coefficient: n- : log Pow: 5,3

octanol/water Method: OECD Test Guideline 117
GLP: yes
12.4 Mobility in soil

Product:
Distribution among : Remarks: no data available
environmental compartments
Components:
Diethylene glycol:
Distribution among : Adsorption/Soil
environmental compartments Medium: water - soil
log Koc: 0
Method: other (calculated)
Prop-2-yn-1-ol:
Distribution among : Remarks: The substance does not evaporate into the
environmental compartments atmosphere from the surface of water.
Not expected to adsorb on soil.
Distribution among : Adsorption/Soil
environmental compartments Medium: water - soil
log Koc: 3,8
12.5 Results of PBT and vPvB assessment

Product:
Assessment : This substance/mixture contains no components considered
to be either persistent, bioaccumulative and toxic (PBT), or
very persistent and very bioaccumulative (vPvB) at levels of
0.1% or higher..
SAFETY DATA SHEET

Components:
Diethylene glycol:
Assessment : This substance is not considered to be persistent,
bioaccumulating and toxic (PBT)..
Prop-2-yn-1-ol:
12.6 Other adverse effects

Product:
Additional ecological : no data available
information
Components:
Diethylene glycol:
Environmental fate and : not available
pathways
Additional ecological : Do not allow to enter ground water, waterways or waste water.
information
Prop-2-yn-1-ol:
Environmental fate and : no data available
pathways
Additional ecological : The product should not be allowed to enter drains, water
information courses or the soil.
Additional ecological : The product should not be allowed to enter drains, water
information courses or the soil.
SECTION 13: Disposal considerations
13.1 Waste treatment methods

Product : In accordance with local authority regulations, take to special
waste incineration plant
Contaminated packaging : Packaging that cannot be cleaned should be disposed of as

product waste
SAFETY DATA SHEET

SECTION 14: Transport information
Section 14.1. to 14.5.
ADR
UN no. UN 3265
Proper shipping name: Corrosive liquid, acidic, organic, n.o.s.
Hazard inducer(s): NAPHTHENIC ACID IMIDAZOLINE BENZYL QUAT
Propargyl Alcohol
Class: 8
Primary risk: 8
Packing group: II
Hazard no. : 80
Remarks Shipment permitted
ADN
UN no. UN 3265
Propargyl Alcohol
Class: 8
Primary risk: 8
Packing group: II
RID
UN no. UN 3265
Propargyl Alcohol
Class: 8
Primary risk: 8
Packing group: II
Hazard no. : 80
IATA
UN no. UN 3265
Propargyl Alcohol
Class: 8
Primary risk: 8
Packing group: II
SAFETY DATA SHEET

IMDG
UN no. UN 3265
Propargyl Alcohol
Class: 8
Primary risk: 8
Packing group: II
EmS : F-A S-B
14.6. Special precautions for user

See sections 6 to 8 of this Safety Data Sheet.
14.7. Transport in bulk according to Annex II of MARPOL73/78 and the IBC Code (International
Bulk Chemicals Code)
No transport as bulk according IBC - Code.
SECTION 15: Regulatory information
15.1 Safety, health and environmental regulations/legislation specific for the substance or
mixture
REACH - Candidate List of Substances of Very High : Not applicable
Concern for Authorisation (Article 59).
Regulation (EC) No 1005/2009 on substances that : Not applicable

deplete the ozone layer
Regulation (EC) No 850/2004 on persistent organic : Not applicable

pollutants
Volatile organic compounds : Directive 2004/42/EC

Volatile organic compounds (VOC) content: 36 %
VOC content > 3%
Directive 1999/13/EC on the limitation of emissions of volatile

organic compounds
Volatile organic compounds (VOC) content: 21 %
VOC content > 3%
Other regulations:
Apart from the data/regulations specified in this chapter, no further information is available
concerning safety, health and environmental protection.
15.2 Chemical safety assessment

No Chemical Safety Assessment (CSA) is yet available for the substance, or for the component
substances, contained in this product.
SAFETY DATA SHEET

SECTION 16: Other information
Full text of H-Statements

H226 : Flammable liquid and vapour.
H301 : Toxic if swallowed.
H302 : Harmful if swallowed.
H310 : Fatal in contact with skin.
H312 : Harmful in contact with skin.
H314 : Causes severe skin burns and eye damage.
H315 : Causes skin irritation.
H318 : Causes serious eye damage.
H319 : Causes serious eye irritation.
H330 : Fatal if inhaled.
H332 : Harmful if inhaled.
H373 : May cause damage to organs through prolonged or repeated
exposure.
H400 : Very toxic to aquatic life.
H411 : Toxic to aquatic life with long lasting effects.
Full text of other abbreviations
Acute Tox. : Acute toxicity
Aquatic Acute : Acute aquatic toxicity
Aquatic Chronic : Chronic aquatic toxicity
Eye Dam. : Serious eye damage
Eye Irrit. : Eye irritation
Flam. Liq. : Flammable liquids
Skin Corr. : Skin corrosion
Skin Irrit. : Skin irritation
STOT RE : Specific target organ toxicity - repeated exposure
ADN - European Agreement concerning the International Carriage of Dangerous Goods by Inland
Waterways; ADR - European Agreement concerning the International Carriage of Dangerous
Goods by Road; AICS - Australian Inventory of Chemical Substances; ASTM - American Society
for the Testing of Materials; bw - Body weight; CLP - Classification Labelling Packaging
Regulation; Regulation (EC) No 1272/2008; CMR - Carcinogen, Mutagen or Reproductive
Toxicant; DIN - Standard of the German Institute for Standardisation; DSL - Domestic Substances
List (Canada); ECHA - European Chemicals Agency; EC-Number - European Community
number; ECx - Concentration associated with x% response; ELx - Loading rate associated with
x% response; EmS - Emergency Schedule; ENCS - Existing and New Chemical Substances
(Japan); ErCx - Concentration associated with x% growth rate response; GHS - Globally
Harmonized System; GLP - Good Laboratory Practice; IARC - International Agency for Research
on Cancer; IATA - International Air Transport Association; IBC - International Code for the
Construction and Equipment of Ships carrying Dangerous Chemicals in Bulk; IC50 - Half maximal
inhibitory concentration; ICAO - International Civil Aviation Organization; IECSC - Inventory of
Existing Chemical Substances in China; IMDG - International Maritime Dangerous Goods; IMO -
International Maritime Organization; ISHL - Industrial Safety and Health Law (Japan); ISO -
International Organisation for Standardization; KECI - Korea Existing Chemicals Inventory; LC50
- Lethal Concentration to 50 % of a test population; LD50 - Lethal Dose to 50% of a test
population (Median Lethal Dose); MARPOL - International Convention for the Prevention of
Pollution from Ships; n.o.s. - Not Otherwise Specified; NO(A)EC - No Observed (Adverse) Effect
Concentration; NO(A)EL - No Observed (Adverse) Effect Level; NOELR - No Observable Effect
Loading Rate; NZIoC - New Zealand Inventory of Chemicals; OECD - Organization for Economic
Co-operation and Development; OPPTS - Office of Chemical Safety and Pollution Prevention;
PBT - Persistent, Bioaccumulative and Toxic substance; PICCS - Philippines Inventory of
SAFETY DATA SHEET

Chemicals and Chemical Substances; (Q)SAR - (Quantitative) Structure Activity Relationship;

REACH - Regulation (EC) No 1907/2006 of the European Parliament and of the Council
concerning the Registration, Evaluation, Authorisation and Restriction of Chemicals; RID -
Regulations concerning the International Carriage of Dangerous Goods by Rail; SADT - Self-
Accelerating Decomposition Temperature; SDS - Safety Data Sheet; TCSI - Taiwan Chemical
Substance Inventory; TRGS - Technical Rule for Hazardous Substances; TSCA - Toxic
Substances Control Act (United States); UN - United Nations; vPvB - Very Persistent and Very
Bioaccumulative
Further information
Other information : Observe national and local legal requirements
Classification of the mixture: Classification procedure:

Acute Tox. 4 H332 Calculation method
Acute Tox. 4 H312 Calculation method
Skin Corr. 1B H314 Calculation method
Eye Dam. 1 H318 Calculation method
Skin Sens. 1 H317 Based on product data or assessment
STOT RE 2 H373 Calculation method
Aquatic Chronic 3 H412 Calculation method
This information corresponds to the present state of our knowledge and is intended as a general
description of our products and their possible applications. Clariant makes no warranties, express
or implied, as to the information's accuracy, adequacy, sufficiency or freedom from defect and
assumes no liability in connection with any use of this information. Any user of this product is
responsible for determining the suitability of Clariant's products for its particular application.
Nothing included in this information waives any of Clariant's General Terms and Conditions of
Sale, which control unless it agrees otherwise in writing. Any existing intellectual/industrial
property rights must be observed. Due to possible changes in our products and applicable
national and international regulations and laws, the status of our products could change. Material
Safety Data Sheets providing safety precautions, that should be observed when handling or
storing Clariant products, are available upon request and are provided in compliance with
applicable law. You should obtain and review the applicable Material Safety Data Sheet
information before handling any of these products. For additional information, please contact
Clariant.
REG_EU / EN

Safety Data Sheet for DODICOR 2725 NF corrosion inhibitor

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Safety Data Sheet for DODICOR 2725 NF corrosion inhibitor

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SAFETY DATA SHEET

according to Regulation (EC) No. 1907/2006

DODICOR 2725 NF Page 1(30)

SECTION 1: Identification of the substance/mixture and of the company/undertaking

1.1. Product identifier

1.3. Details of the supplier of the safety data sheet

1.4. Emergency telephone number

SECTION 2: Hazards identification

2.1 Classification of the substance or mixture

Acute toxicity, Category 4 H312: Harmful in contact with skin.

Serious eye damage, Category 1 H318: Causes serious eye damage.

Skin sensitisation, Category 1 H317: May cause an allergic skin reaction.

DODICOR 2725 NF Page 2(30)

2.2 Label elements

Signal word : Danger

Hazard statements : H312 + H332 Harmful in contact with skin or if inhaled.

Hazardous components which must be listed on the label:

SECTION 3: Composition/information on ingredients

DODICOR 2725 NF Page 3(30)

SECTION 4: First aid measures

4.1 Description of first aid measures

If inhaled : If inhaled, remove to fresh air.

DODICOR 2725 NF Page 4(30)

Get medical advice/ attention.

If swallowed : If swallowed, seek medical advice immediately and show this

Risks : No hazards known at this time.

SECTION 5: Firefighting measures

5.1 Extinguishing media

5.2 Special hazards arising from the substance or mixture

Nitrogen oxides (NOx)

5.3 Advice for firefighters

SECTION 6: Accidental release measures

6.1 Personal precautions, protective equipment and emergency procedures

6.2 Environmental precautions

DODICOR 2725 NF Page 5(30)

6.3 Methods and material for containment and cleaning up

6.4 Reference to other sections

SECTION 7: Handling and storage

7.1 Precautions for safe handling

Advice on protection against : Keep away from sources of ignition - No smoking.

7.2 Conditions for safe storage, including any incompatibilities

7.3 Specific end use(s)

SECTION 8: Exposure controls/personal protection

8.1 Control parameters

DODICOR 2725 NF Page 6(30)

Workers Inhalation Long-term local 60 mg/m3

DODICOR 2725 NF Page 7(30)

DODICOR 2725 NF Page 8(30)

N-(2-Ethylhexyl)isononan-1- Fresh water 0,00157 mg/l

Break through time : 30 min

Break through time : 480 min

Skin and body protection : Wear suitable protective clothing.

Respiratory protection : Use respiratory protection in case of insufficient exhaust

DODICOR 2725 NF Page 9(30)

Protective measures : Avoid contact with skin and eyes.

SECTION 9: Physical and chemical properties

9.1 Information on basic physical and chemical properties

Colour : yellow to brownish

Odour Threshold : not tested.

pH : approx. 4 (20 °C)

pour point : approx. -20 °C

Initial boiling point : > 100 °C

Flash point : approx. 92 °C