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COOLING
2. Thermodynamic Basics
5. Coefficient of Performances.
7. Refrigerants.
8. Electricity-driven systems.
8.1. Stirling engine.
8.2. Thermoelectric cooling.
9. Comparisons.
Solar cooling refers to any cooling system that uses solar power. This can
be done through passive solar, solar thermal energy conversion and photovoltaic
conversion (sun to electricity). The U.S. Energy Independence and Security Act of
2007 created 2008 through 2012 funding for a new solar air conditioning research
and development program, which should develop and demonstrate multiple new
technology innovations and mass production economies of scale. Solar air
conditioning will play an increasing role in zero energy and energy-plus buildings
design.
Solar energy, radiant light and heat from the sun, has been harnessed by
humans since ancient times using a range of ever-evolving technologies. Solar
radiation, along with secondary solar-powered resources such as wind and wave
power, hydroelectricity and biomass, account for most of the available renewable
energy on earth. Only a minuscule fraction of the available solar energy is used.
Underlying Physics
Thermodynamics
1st Law:
The change of internal energy (U) of a system is equal to the heat absorbed
(Q), plus the external work (W) done on the system W, Q related to the changes the
system experiences when going from an initial to a final state.
Thermodynamic Cycle:-
Entropy
∆S = ∆Q / T
Clausius gave the quantity S the name "entropy", from the Greek word,,
"transformation". Since this definition involves only differences in entropy, the
entropy itself is only defined up to an arbitrary additive constant.
The most probable processes that can occur in an isolated system are those
in which entropy increases or remains constant. In other words:
In an isolated system there is a well-defined trend of occurrence of process
and this is determined by the direction in which entropy increases. In other words:
Heat flows naturally from a system of higher temperature to a system of
lower temperature.
Expansion
Evaporation
Thermal solar cooling techniques
Desiccant Cooling
“The cooling capacity is based on the physical properties of the cooling fluid
that will change phases
At different temperatures, depending on its pressure.”
Absorption Cooling
S
col olar
Condenser lec
tor
Generator
Heat
exchanger
Exp valve
Regulating
valve Pump
Evaporator
Absorber
Heat Driven Systems
Absorption Refrigerator-
The absorption refrigerator is a refrigerator that uses a heat source (e.g.,
solar, kerosene-fueled flame) to provide the energy needed to drive the cooling
system. Absorption refrigerators are a popular alternative to regular compressor
refrigerators where electricity is unreliable, costly, or unavailable, where noise
from the compressor is problematic, or where surplus heat is available (e.g., from
turbine exhausts or industrial processes). Absorption refrigerators powered by heat
from the combustion of liquefied petroleum gas are often used for food storage in
recreational vehicles.
NH3 systems
• Improved reliability, at low cost, independent control of the cooling medium
• Improved pump reliability at low cost
• Improved reliability of the fluid level sensors
• Increased performance of the various heat transfer processes in the machine
• Simplified system concepts
Properties of H2O – NH3
LiBr systems
Adsorption is the use of solids for removing substances from gases and
liquids the phenomenon is based on the preferential partitioning of substances
from the gaseous or liquid phase onto the surface of a solid substrate. The process is
reversible
Adsorption Phase 1
Heating and pressurization
The adsorbent temperature increases, which induces a pressure increase,
from the evaporation pressure up to the condensation pressure. This period is
equivalent to the "compression" phase in compression cycles.
Adsorption Phase 2
During this period, the absorber continues receiving heat while being
connected to the condenser, which now superimposes its pressure. The adsorbent
temperature continues increasing, which induces desorption of vapour. This
desorbed vapour is liquefied in the condenser. The condensation heat is released to
the second heat sink at intermediate temperature.
This period is equivalent to the "condensation" in compression cycles.
Phase 2 Phase 3
During this period, the adsorber releases heat while being closed.The
adsorbent temperature decreases, which induces the pressure decrease from the
condensation pressure down to the evaporation pressure.
This period is equivalent to the "expansion" in compression cycles.
Adsorption Phase 4
During this period, the absorber continues releasing heat while being
connected to the evaporator, which now superimposes its pressure. The adsorbent
temperature continues decreasing, which induces adsorption of vapor. This
adsorbed vapour is
Evaporated in the evaporator. The evaporation heat is supplied by the heat
source at low temperature.
This period is equivalent to the "evaporation" in compression cycles.
Adsorption Refrigeration
Sorber
Sorber
Evaporator
Qcs Evaporator
DESICCANT REFRIGERATION
Refrigeration Regeneration
Addresses the issue of thermal comfort by modifying the water vapor content in a space.
Desiccant refrigeration flow-chart
Desiccant system
A desiccant is a hygroscopic substance that induces or sustains a state of
dryness (desiccation) in its local vicinity in a moderately well-sealed container.
Equation:
The equation is:
COP =│∆Q│∕ ∆W
where
COPheating =│∆Qcold│+∆W∕∆W
COPcooling =│∆Qcold│∕∆W
where
• │∆Qcold│is the heat moved from the cold reservoir (to the hot reservoir).
COP of the refrigeration sub-system
Solar cooling path and local conditions
h e a t 3 D e
0 0 ° C s
1 5 0 ° C
S F ol a l t a P r l aT At he i
E T C
C C o o7n 0lc l ° ee C nc t t r oa
- F 1 l 0a 0t °P C l a t e
electricity
E V j ea
Photovoltaics
- E v a c u a t e
- C o n c e n t r
Refrigerants
There are several environmental factors that concern refrigerants, and also
affect the future availability for chiller applications. This is a key consideration in
intermittent applications where a large chiller may last for 25 years or more. Ozone
depletion potential (ODP) and global warming potential (GWP) of the refrigerant
need to be considered. ODP and GWP data for some of the more common vapor-
compression refrigerants:
Refr O G
igerant DP WP
R- 1
0
134a 300
R- 0 7
123 .012 6
R- 0 1
22 .05 700
R40 0 9
1a .027 70
R40 3
0
4a 260
407a 0
???
R40 1
0
7c 525
R40 0 3
8a .016 020
R40 0 1
9a .039 290
R41 1
0
0a 725
R50 0
0 .7 ???
R50 0 5
2 .18 600
Between points 4 and 5, the saturated liquid refrigerant passes through the
expansion valve and undergoes an abrupt decrease of pressure. That process results
in the adiabatic flash evaporation and auto-refrigeration of a portion of the liquid
(typically, less than half of the liquid flashes). The adiabatic flash evaporation
process is isenthalpic (i.e., occurs at constant enthalpy).
Thermoelectric cooling
Thermoelectric cooling uses the Peltier effect to create a heat flux between
the junction of two different types of materials. A Peltier cooler, heater, or
thermoelectric heat pump is a solid-state active heat pump which transfers heat
from one side of the device to the other side against the temperature gradient (from
cold to hot), with consumption of electrical energy. Such an instrument is also
called a Peltier device, Peltier diode, cooling diode, Peltier heat pump, solid state
refrigerator, or thermoelectric cooler (TEC). Because heating can be achieved
more easily and economically by many other methods, Peltier devices are mostly
used for cooling. However, when a single device is to be used for both heating and
cooling, a Peltier device may be desirable. Simply connecting it to a DC voltage
will cause one side to cool, while the other side warms. The effectiveness of the
pump at moving the heat away from the cold side is dependent upon the amount of
current provided and how well the heat can be removed from the hot side.
Performance
Uses
Peltier devices are commonly used in camping and portable coolers and
for cooling electronic components and small instruments. Some electronic
equipment intended for military use in the field is thermoelectrically cooled.
The cooling effect of Peltier heat pumps can also be used to extract water
from the air in dehumidifiers.
Peltier elements are a common component in thermal cyclers, used for the
synthesis of DNA by polymerase chain reaction (PCR)a common molecular
biological technique which requires the rapid heating and cooling of the reaction
mixture for denaturation, primer annealing and enzymatic synthesis cycles.
The effect is used in satellites and spacecraft to counter the effect of direct
sunlight on one side of a craft by dissipating the heat over the cold shaded side,
whereupon the heat is dissipated by thermal radiation into space.
Peltier devices are used in USB drink coolers/chillers, one of the latest
addition to USB gadgets/toys. These devices are powered directly from the USB
port and are said to keep drinks chilled, some even can keep drinks warm. The
effectiveness of these devices, however, is questionable. The available power from
a USB socket is very limited, so cooling or heating will be minimal.
Stirling Engine
Heat
source
Regenerator
Heat
exchanger Heat
Exchanger
Cold Hot
side side
Expansion Compression
space space
Co
mp n
pis ress n sio
ton ion pa on
Ex pist
The engine is like a steam engine in that all of the engine's heat flows in and
out through the engine wall. This is traditionally known as an external combustion
engine in contrast to an internal combustion engine where the heat input is by
combustion of a fuel within the body of the working fluid. Unlike the steam
engine's use of water in both its liquid and gaseous phases as the working fluid, the
Stirling engine encloses a fixed quantity of permanently gaseous fluid such as air
or helium. As in all heat engines, the general cycle consists of compressing cool
gas, heating the gas, expanding the hot gas, and finally cooling the gas before
repeating the cycle.Originally conceived in 1816 as an industrial prime mover to
rival the steam engine, its practical use was largely confined to low-power
domestic applications for over a century.[2] The Stirling engine is noted for its high
efficiency, quiet operation, and the ease with which it can use almost any heat
source. This compatibility with alternative and renewable energy sources has
become increasingly significant as the price of conventional fuels rises, and also in
light of concerns such as peak oil and climate change. This engine is currently
exciting interest as the core component of micro combined heat and power (CHP)
units, in which it is more efficient and safer than a comparable steam engine.
P h o to v o lta ic -d riv e n s y s te m s
Pow er
fo r1 W o f
W o rk in g
S y s te m s r e frig e r a tio n
COP A p p lic a tio n s A d v a n ta g e s D is a d v a n ta g e s
e ffe c t F lu id s
(W )
V a p o r-c o m p re s s io n
C ondenser - H ig h C O P - In s ta lla tio n c o s t is h ig h
C o m p re s s o r - L o n g te rm e x p e rie na cned it re q u ire s b a tte ry
R134a, foiar el n e rg y b a c k u p .
a n d w id e ly c o m m e rc
E xp.
d e v ic e
e le c tric ity
PV
1 2 -5 0 3 -5 R 2 9 0 , R e frig e ra tio n
a v a ila b le
o r e tc .
- A d ju s ta b le fro m a
E v a p o ra to r s m a ll to a la rg e s y s te m
T h e rm o -e le c tric (P e ltie r)
- N o w o rk in g flu id a-n Ld o w C O P
Q1
H o t s id e
n o m o v in g p a rts - D iffic u lt to a c h ie v e a lo w
H e a t re je c tin g s u rfa c e - Q u ie t re frig e ra tio n
t1 - S m a ll s iz e a n d lig htet m p e ra tu re
P N P N P N
t2
A fe w W 0 .5 - w
R e frig e ra tio n e ig h t - L o w re lia b ility e s p e c ia lly
w h e n th e p o w e r s u p p ly
H e a t a b s o rb in g s u r fa c e is c u t.
C o ld s id e
Q2 PV
S tirlin g
H eat
s o u rc e
- H ig h C O P fo r h ig h- H ig h p ro d u c tio n c o s t
te m p e ra tu re d iffe re- nCc oe m p le x ity in d e s ig n
R e g e n e r a to r
Heat
exchanger H eat
E x cha ng er
- C a n b e u s e d fo r
C o ld H ot
c ry o g e n ic a p p lic a tio n s
s id e s id e a n d it is m e c h a n ic a lly
He, m o re s im p le th a n o th e r
E x p a n s io n
space
C o m p re s s io n
space
3 -1 7 3 H2 , R e frig e ra tio an p p lic a tio n fo r lo w
A ir te m p e ra tu re o p e ra tio n .
Co
mp
pis ress ion - E n v iro n m e n ta l frie n d ly
ns
ton ion pa on
Ex pist w o rk in g flu id
- M o b ility a n d lig h t
w e ig h t
A d so rp tion - H igh w e ig h t a n d p o o r th e rm a l
- N o m o v ing p a rt (excep co tn d u ctivity o f th e a d s orb e n t.
C o n de n se r valve ) F o r hig h cap a c ity s yste m , it
C o n d e n seDr es orb ed
va p ou r ca n c a u se lo n g -te rm
- L ow o p era tin g prob lem s.
H2O /Z e o lite , te m p era tu re ca n b e
S o rb e r - Lo w o p era tin g p re ss u re
M e th an o l/ a ch ie v ed .
8 0 -3 0 00 .3 -0 .8 A ctivate d R e frige ra tio n- T h erm a l C O P is qu itere qu ire m e nt m a ke s it d ifficu lt
to a ch ie ve a ir-tigh tne ss.
S o rbe r ca rb o n h ig h co m p are d to o th- er
E va p o ra tor
E vap o ra to r
V e ry s e n sitive to lo w
Qc s
h e at op e rating syste mte. m p e ra tu re e s pe cia lly th e
de cre a s in g tem p e ra ture
R e frig e ra tio n R e g e n e ra tio n
du rin g n ig h ttim e .
- It is an in te rm itte n t sy ste m .
D e s icc a n t
- E n viro n m e ntally - It ca nn o t fu n ctio n pro pe rly
frie nd ly, w a te r is u s edin a h um id a rea .
a s th e w o rkin g flu id . - It is n o t a p pro p ria te fo r a n
H u m id ifie r
- C a n b e in te gra te d w itha re a w he re w a te r is
4 0 -1 0 00 .5 -1 .5 w ater A ir-co n d itio n
a ven tila tio n a nd s ca rcity.
H e ate r
h e ating s yste m . - R e q u ire s m a inten a n ce d u e
H u m id ifie r
to m o vin g p a rt in a ro to r
D e sicca nt W h e e l H e a t E x ch an g e r
W heel
w he e l.
E jec to r
- L ow te m p e ra tu re he-aLt ow C O P
S o la r C o lle ctor W a te r, sou rce ca n be u sed .
bu ta n e ,
G e n e ra to r - L ow o p era tin g a nd
Pum p 8 0 -1 5 00 .3 -0 .8 R 1 4 1 b, A ir-co n d itio n
in stalla tio n cos t.
C o n de n se r
E je cto r
R 2 4 5 fa ,
E xp . o r e tc.
d e vice
E va p ora to r
Consumption, Performances And Costs
Comparative assessment
Investment cost
Performance data