DPP 1 Chemical Kinetics Chemistry For YOU Sahendra Kumar

Q 1 . For a reaction, 2A+ B → 3Z, If the rate of consumption of A is 2 × 10 ̶ 4 mol dm ̶ 3 s ̶ 1 the

rate of formation of Z(in old m ̶ 3 s ̶ 1) will be: CSIR-NET June 15
4
a)3 × 10 ̶ 4 (b) 2× 10 ̶ 4 (c) × 10 ̶ 4 (d) 4 × 10 ̶ 4
3
Q 2 For the reaction, 2X3 ⇋ 3X2, the rate of formation of X2 is: GATE-2008
1 1 3
a) 3( ̶ d[X3]/dt)(b) ( ̶ d[X3]/dt) (c) ( ̶ d[X3]/dt) (d) ( ̶ d[X3]/dt)
2 3 2
Q 3 10 mole of N2 and 20 mole of H2 are caused to react and after a certain time 5 mole of
ammonia is found the value of extent of reaction for reactant is
a) 5 b) 2.5 c)-5 d) -2.5
Q 4 Consider the statements
i)Kinetic study can disprove a mechanism but it can not establish a mechanism with certainty.
ii) Stoichiometric coefficient never be negative entity
iii) Extent of reaction is same for every reactant and product.
The true statement above are a) i,ii b) ii,iii c) i,iii d) i,ii,iii
Q 5 Consider the statement
i)The term molecularity has no meaning in composite mechanism.
ii) Rate of conversion is defined as time derivative of extent of reaction
iii) Elementary reaction is a reaction that occur in single step with no experimentally detectable
reaction intermediate .
a) i,ii b) ii,iii c) i,iii d) i,ii,iii
Q 6 For the reaction 2NO + 2H2 → N2 + 2H2O the rate expression can be written in the
following ways {dN2 /dt}=k1 [NO] [H2] , {dH2O/dt}=k [NO] [H2] ,
- {dNO /dt}=k1’ [NO] [H2] , -{dH2 /dt}=k1” [NO] [H2]
The relationship between k1 , k , k1’ and k1” is IIT Gate 1998
a) k1 = k = k1’ = k1” b) 2k1 = k = k1’ = k1”
c) k1 = k =2 k1’ = k1” d) k1 = k = k1’ = 2k1
Q 7 The combustion of ethane is represented by TIFR 2015
2 C2H6 + 7 O2 → 4 CO2 (g) + 6 H2O (l)
Which of the following is true for the above reaction
a) The rate of consumption of ethane is 7 times faster than the rate of consumption of O2 .
b) Water is formed at the rate equal to two third the rate of formation of CO2
c) Rate of consumption of oxygen equal to rate of formation of water .
d) CO2 is formed twice as fast as ethane is consumed
Q 8 Consider the statements
i)To make rate of reaction intensive we divide rate of conversion by volume.
ii) Reaction rate is defined as change in advancement of reaction with time
iii) order of reaction is determined experimentally.
The correct statements above are a) i,ii b) ii,iii c) i,iii d) i,ii,iii
Q 9 For the reaction of the type X Y The correct rate expression is ([X] 0 and [X] corresponds
to the concentration of X at time t=0 and t=t , respectively) GATE PAPER 2013
a) –{dX/dt}=k1[X]0 –(k1 + k2)[X] b) –{dX/dt}=(k1 + k2)[X]- k2[X]0
c) –{dX/dt}=(k1 + k2)[X]0- k1[X] c) –{dX/dt}=(k1 - k2)[X]- k1[X]0
Q 10 For the reaction 2A+B→C+2D which is first order in A and also first order in B , the rate is
given as GATE PAPER 1997
a) k[A]2[B] b) k[A][B]2 c) k[A]2 d) k[A][B]
Q 11 Consider the statements
i)Rate constant is independent on concentration but dependent on temperature and pressure
ii) The decomposition of acetaldehyde is given by following balanced reaction
CH3CHO (g) → CH4 (g) + CO (g)
The rate of reaction in terms of pressure is (-1/RT){dPCH3CHO/dt}
iii) The rate law concept apply to all reactant regardless the phase of reactant ,products and
surrounding medium.
The correct statements above are a) i,ii b) ii,iii c) i,iii d) i,ii,iii
Q 12 Consider the statements
i)Reaction having order four or more is practically impossible
ii) In place of concentration of reactant and product any physical property such as viscocity ,
surface tension or absorbance may be measured for the determination of rate of the reaction
iii) Rate of reaction , independent of reactant and product species is the time derivative of extent
of reaction divided by volume.
The correct statements above are a) i,ii b) ii,iii c) i,iii d) i,ii,iii
Q 11 Consider the statements
i)Reaction rate will always has a unit of concn time-1 .
ii) order of an elementary reaction is always equal to its molecularity.
iii) differential method is most reliable for investigating a chemical reaction than integration
method if there is no much previous information.
The correct statements above are a) i,ii b) ii,iii c) i,iii d) i,ii,iii
Q 13 For the reaction A 2B and B→C dB/dt is given by CSIR NET 2015
a) k1 [A] – k-1 [B] -2k2[B]
2
b) 2k1 [A] – 2k-1 [B]2 -k2[B]
c) (1/2)k1 [A] –(1/2) k-1 [B]2 -2k2[B] d) 2k1 [A] – 2k-1 [B]1/2 -k2[B]
Q 14 Experimentally determined rate law for the chemical reaction
2NO2F → 2NO2 + F2 , and the rate = k [NO2F] CSIR JUNE 16
The rate determining step consistent with the rate law is
a) 2NO2F → 2NO2 + F2 b) NO2F + F → NO2 + F2
c) NO2F → NO2 + F d) NO2 + F → NO2 F
Q 15 For the reaction H2 + I2 → 2HI the rate of disappearance of I 2 is found to be 10-6 mole per litre per
second . Corresponding rate of appearance of HI is
a) 1 × 10-6 mole /litre-second b) 2 × 10-6 mole /litre-second
c) 1 × 10-5 mole /litre-second d) 2× 10-5 mole /litre-second
16 The rate law of a chemical reaction 2NO + O2 → 2NO2 if the volume of the reaction vessel is reduced
to one fourth of its initial volume the rate of reaction
a) will reduce 64 times b) will grow 64 times
c) will reduce 32 times d) will grow 32 times
Q 17 Consider the statements
i) Method of integration is the method of guess and try , the differential method is called the method of
systemic exploration.
ii) The method of analysis must be much be faster then the rate of reaction
iii) If double lograthims ( log rate vs log concentration) plots are linear than reaction has an order that is
given by slope
The true statement above are a) I,ii b) ii,iii c) I,iii d) I,ii,iii
Q 18 The value of rate constant for the gas phase reaction is 2NO 2 + F2 → 2NO2F is 38 dm3 mole-1 sec-1
The order of the reaction is Gate Exam 2008
a) 0 b) 1 c) 2 d) 3
Q 19 The rate law for the reaction A+B → P is
Rate = {-(dA/dt)}={dP/dt}=k[A]3/2 [B]-1/2 the order of the reaction is
a) 0 b) 1 c) 2 d) 3
Q 20 For a reaction A→B, the rate constant has been experimentally determinate to be 1x10 9 L mol-1 S-1.
The order of reactions IISC 2007
(a) Not defined (b) 1 (c) 2 (d) 0.
Q 21 For a reaction 2A+B→C + D , if rate of consumption of A is 0.1 mole L-1 s-1 the rate of formation of
C (mole L-1 s-1 ) is ………………… IIT JAM 2017