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Lecture ﴾5﴿
3- Magnetic storage
This method is considered one of the latest technologies used to store the electrical
energy generated by Renewable energy sources.
In this way, electrical energy is converted into magnetic energy by coils made of
superconducting metals with low electrical resistance. In this method, a high
electric current is passed over a coil that converts electrical current into magnetic
energy. The stored magnetic energy is calculated from the following equation:
The inductance of the coil depends on its geometry, and this method is one of the
most efficient ways to store energy. There is no need to convert energy into other
forms such as mechanical energy, and then convert it to electric energy which
increasing the losses.
One of the main disadvantages of this type of battery is the low value of the
energy-to-mass ratio. It makes it not possible to use it to store large amounts of
energy.
Large storage capacity batteries have been achieved and one of these batteries is
Nickel-cadmium battery. There is also another type of battery with a high energy
density, which is the sodium sulfur battery, which operates at a temperature of
250cº this battery is used in electric cars.
Ministry of Higher Education and Scientific وزارة التعليم العالي والبحث العلمي
Research جامعة الكرخ للعلوم
AL-Karkh University of Sciences كليــة علــوم الطاقة والبيئة
College of Energy and Environment Science
Department of Energy science
قسم علوم الطاقة
5- Chemical storage
This method involves converting the excess energy into a chemical fuel that can be
stored easily and quickly. The most important of these methods is the production
of hydrogen gas, which is considered one of the new alternative energy and
receiving wide interest as a future fuel and an alternative to conventional fuels.
Example1
What quantity of heat is required to raise the temperature of 450 grams of water from
15°C to 85°C? The specific heat capacity of water is 4.18 J/g/°C.
Sol/
In this problem, we know the following:
m = 450 g
C = 4.18 J/g/°C
Tinitial = 15°C
Tfinal = 85°C
We wish to determine the value of Q - the quantity of heat. To do so, we would use the
equation Q = m•C•ΔT. The m and the C are known; the ΔT can be determined from
the initial and final temperature.
T = Tfinal - Tinitial = 85°C - 15°C = 70.°C
With three of the four quantities of the relevant equation known, we can substitute and
solve for Q.
Q = m•C•ΔT = (450 g)•(4.18 J/g/°C)•(70.°C)
Q = 131670 J
Q = 1.3x105 J = 130 kJ (rounded to two significant digits)
Example2
A 12.9 gram sample of an unknown metal at 26.5°C is placed in a Styrofoam cup
containing 50.0 grams of water at 88.6°C. The water cools down and the metal warms
up until thermal equilibrium is achieved at 87.1°C. Assuming all the heat lost by the
water is gained by the metal and that the cup is perfectly insulated, determine the
specific heat capacity of the unknown metal. The specific heat capacity of water is 4.18
J/g/°C.
Sol/
the quantity of heat lost by the water (Qwater) equals the quantity of heat gained by the
metal (Qmetal). Since the m, C and ΔT values of the water are known, the Qwater can be
calculated. This Qwater value equals the Qmetal value. Once the Qmetal value is known, it
Ministry of Higher Education and Scientific وزارة التعليم العالي والبحث العلمي
Research جامعة الكرخ للعلوم
AL-Karkh University of Sciences كليــة علــوم الطاقة والبيئة
College of Energy and Environment Science
Department of Energy science
قسم علوم الطاقة
can be used with the m and ΔT value of the metal to calculate the Qmetal. Use of this
strategy leads to the following solution:
Part 1: Determine the Heat Lost by the Water
Given:
m = 50.0 g
C = 4.18 J/g/°C
Tinitial = 88.6°C
Tfinal = 87.1°C
ΔT = -1.5°C (Tfinal - Tinitial)
Solve for Qwater:
Qwater = m•C•ΔT = (50.0 g)•(4.18 J/g/°C)•(-1.5°C)
Qwater = -313.5 J (unrounded)
(The - sign indicates that heat is lost by the water)
Part 2: Determine the value of Cmetal
Given:
Qmetal = 313.5 J (use a + sign since the metal is gaining heat)
m = 12.9 g
Tinitial = 26.5°C
Tfinal = 87.1°C
ΔT = (Tfinal - Tinitial )
Solve for Cmetal:
Rearrange Qmetal = mmetal•Cmetal•ΔTmetal to obtain Cmetal = Qmetal / (mmetal•ΔTmetal)
Cmetal = Qmetal / (mmetal•ΔTmetal) = (313.5 J)/[(12.9 g)•(60.6°C)]
Cmetal = 0.40103 J/g/°C
Cmetal = 0.40 J/g/°C (rounded to two significant digits)
Example3
A man places 48.2 grams of ice in his beverage. What quantity of energy would be
absorbed by the ice (and released by the beverage) during the melting process? The heat
of fusion of water is 333 J/g.
The equation relating the mass (48.2 grams), the heat of fusion (333 J/g), and the
quantity of energy (Q) is Q = m•ΔHfusion. Substitution of known values into the
equation leads to the answer.
Ministry of Higher Education and Scientific وزارة التعليم العالي والبحث العلمي
Research جامعة الكرخ للعلوم
AL-Karkh University of Sciences كليــة علــوم الطاقة والبيئة
College of Energy and Environment Science
Department of Energy science
قسم علوم الطاقة
Example4
A solar power system that uses water as a storage medium, the volume of the
container was 1m3 and the amount of change in temperature 10cº. It has been
suggested to use paraffin wax instead of water as a storage medium. compare
between the volume occupied by paraffin and the volume occupied by water.
Sol/
The amount of heat stored in water is calculated from the following equation: