| fet aasdificcdbion. cheisedaoirystoe. negmber of 4 i _1)-Monodentede or unidentote. Igand setae | | | >) tgonds. WAR ab Rokk hese Vacant \ orbitals te receive bale donoted oglectrons _-Foom. the metal.’ : ¥ ER Ho NH Fs —_> | iD Ligands hevivgs mb lene pairs af-ekectrons | buck: shave Te bonding electrons - 4 x ethylene, benzene, qyclopentudeneyl ton. ORSRV. Duaaevea - Aotyuw the li donde a8 | Tre: ligands, which, , hove. only one. donor atom, and henee’ ean. eoordinede. “Jo the: ¢entral + | | "monodentate. Wigands. i rip in@hals* tone ‘of one. site only ‘are: aabled! ia -elst? Ths ligands “ore theea pes? seal sii = | SE bo Teta togeepttive. Sotho = H is also _ possible. sh Neutral monodentate Fonnadentode: Oe te wapats rigend 2 tigeinds Ho (aque) Fy Gluore) No® Chifrog lium) C4(thio canbory!) or (Chiore) “Rint Hy Cammine) BH BOMB) Eh sd neccium) Co (corbongl) © 2o8O (odo) “Se oH, Coo Cocetato) O 265 NO Cnitrosa! pe 3 Ne nsGihionitroggl) “cN Bea) pot al al a benzene) ens (ege ne to) ass ao Nos Cisothioeyancté)? | = i oa” ‘Cniteo)-<| Eoondinods th I ere 4) ete 3s ' iT a -0f* (higdroxo! on leer Ho Chydrido) Op Calaxo} yO" Bupero80), OF (Peroxg Os Hi Cogclopenta deny. I). ebos a orale td dla! “Igand mos ive: yore thon one free ‘electron pairs | and thus may simulteneousl coordingte. with| 40 or move catems: CES ithe ligeend forms tio o bonds with. two metal actoms caps. 4hus acts a bridge | bebugart the metal | ators. Such oe shen ‘eotled beidging gerd. “OH, FO oe 2 REO Ie Hepa | Be 7 $0477 aD) Poly iendate ririiauliictartole i Oui Ine ligands, havin 456° or mone donor fe ‘atoms ‘one voolled, poly dentate Ygands .” TRese ligands may be of the following za ypes- depending orn the’ number of donor - eomsy predentin them. @ Bidendote ligands = _ the ligands having skool donee atoms one. called | bidentote ligands. ES 1G 3k sas AR 4) Asioni=: bidentote ligands: ———> i uo}Doyo? (oxoledo) ei. iii) Najets- 8-0" Glyeineto) [eee E] fac] CO SG a Fig. Dioxalato platinate Gi) ion = < mas Ca), Fig: Bislalaetnarte) copper ct) ; “Let Cutest oo), a ~ ee fee eta igonds; Figt Ferrus orthophenanthroline (i) ion [re*# (Phe mlAnother ‘xen ple. is ethylene» diamine. © Ny (CHL) - NA with two neutral. deners “ k as ~ jor (©)Tridentade ligands : : =e Te he, me ligands having three: donor atoms. ER es “Lh Rs bpethglene ‘cere (enna AnH), ] Cdien) ts Imino - di- eae ['o0e-8 Le -Wit= Sth c0Or | : * capa & a/v terpyridine.- Cterpy) © Tehodentdte _lijands “the. ligands having tote donovi atoms ane ele fotraddyede geet ES “ty > Teiethglen detramine oe FAN - (CH2),- Be (@H2):~ N- Coll NH. (rien) 3 Shi, ca : ts ~ Niteilo deiocetedo | epee tHe an j. enray” | detadtaen tp lesion Rok ioe | Sha a | adestios @. Te oe igand 9: reisnD = ligands having five dgnaws aha EX jada, Ethglene. disring Arlccetlo mi. DigikeriaeF —o¢ji- 2 L3 doa- 2S chad 2 oe- He | Ss On Hexadentote li gence: THe sefinds having six, Bénor | Tadewk. Ext.) Sergio dione: detro.cetato | cEDTA)*~ ss bo Hu 4 4 Tode- eH) | f- Ha Oe atten em Pe Rttonilfrcos, Racer -8 gor) T00c- a hv ead coo” Ls* Chelate : “ese Polydentote, cae int “etouelares Permit the ateahrnsnt oe “their “tus0 or more, , donor ddoms:Cors sites). toy. te scknel mete! ton imu fan eous|y ovdl Produce. one on more. eggs are. called chelates or chelating tapes AR) TORY I “Ghelecion cat = : The, fonmodion Wo sis « thy ia chelates. with ea. metal _ ion, es ‘ealled ahelochion - or chalets < rings. ott A503 4 $ Ex: Ae S@bvalent 6 [ : rongPh ie 5 he vlink eo} stooge oS y be AT G¥) Eo®atss ea : Ga _ Gellert ft Sainwib | , elotes) ' oe Three i coordi nectia iE lin kages / Cri fentote. chelote 5)| Rh Nomencloluoe : af caoedinedion. com pon Ads; Anionic. ecinplexes Name 6 = In naming anionic. eormplacts lj ands One Kine Aiest dnd Ahern the central metol ion. TS nome. the central metal ton the sully eq al ts ottuched 40 dei name.aind in order to indicate. the - onidettiore stbe cof she Rete bre bY Reman numera nite ‘felon ta => Telia iods flyjiens Raion 2 mote (OI) ion tpt? Mess Hi), ted => acces: promis. plod eae (wi lon penta ai jon “Eng? ay Siege (P)ien 45 ahi Hexocyanofe cnode ton 5 (Ferrieganide ion) J . reMem rama Hexegyonaferncte, () ion CFerri qgenide ion) [Ni Con)a™ > Tetracganonicklate (0) Leo” (Co), alee Tetracarbongleobal fede G)icloaluminete (m) ~ufabtla] Esthium fetrahg ele orozincate (41) 1 Ay (Re Cn] Potassium Hexargyanoferrat eH) “tl ks (Fe Gooshel > Pofassium pentasepnna: tra sak oi a fereote CD) | ka (oscten' | pplcaial recor La. obthede (Die, (Noy (znelg| > sodium fotra ch! “ sNncsiinacepoara lien bis ¢hiosulpheto)=-— ai Tl < oe angentate: (D) Te eannes Os Ne leteaas Bota dia amminedi- peroxo —_ "Ta 28% HEALY § f-234 Fea p08 enodioxo ee: = ahromede (IY) : + ped [Fe lo) (on)e TS sodium aie ee ferrate UF) Ma “footen SS Merelery 4ofioth lodianetoes) : oe t i | | !cationic” and neutral complexes s, a a Se => —— weet [er (no4 cay’ Getty pichloroehraaqua chromium (mm) ion : Cag” (Hs) 1* — Diammine - silver (1) ion. [eu (NBS), >t —s Teleaammine coppée(t)-ton [AX™ (OH) (H.0)5 f° Hydroxo pentaaquacaluminitam cn) mn tN Mena] +» pichloro bis (ethglenediamine)- : = nickel CY) ion Posen ye [ea => pexedinminecoballt a) chloride. [eo¢ ao (un Delt aa Pentaamininechlore Shalt (an) i ion [100404 (wa as 7 NO, => eles Tofaommindeul phortoeobalt @) nitrate. [anivee)q Pas Jetrathioegjandte-N- 3 zinc (I) [ed Gena fers tebhathioe, qaneto -s- cadmium (a1) meric. is DATO| Neutral © eo (Nos), (WH 12 dinmine Ripitrecebalt cou) Co CLAN No, (10 LT jamminechlorotyere- E ‘ : se . nitro cobalt ‘ém) Louth (GHW), 1 8 i bianco et reorre: ap) (er (Ce Heda] “23 Bis (ben wpe) ohes| ram (o) Leolen)2 Os] —raiehlorobis| (thane) neo ‘cobalt Ct) [oo CNHs) sen) > jrisdhtogganede, (52 ool triammine cobeslt (at) [wie cont = Tetrascar ora *Keebals ® ire +a + (et eba] S Het. Uy goidines =| bod PA platinum (1) tetra- Y ahleve plactnacte Gi.) [er (ntl ] (coe). > hexaammine chromium CA) hexaggano cobaltate | Fe(CsHs), > Bis (oqclopentadieng!) iron a van Smee ave , (NH3) 5c ear As > tarhgdirexo -bots 2K40= ~ Eeentoramimine chromium cm) } chloride (te aoa! ide ee oni cm) ion. ue atnido su nifro- Le $ Neo He S *-Bekaamm ine dicobalt- ET shina 23eDAon [ L Cotes re Spe a - a". Di-4t-carbong| bis - a NEsH a | Soe i s)]° _Ceorbong! ey clopento- | tonity cboloxoatdantt »eenyh tren) 7 Leos Fe (c0); Fe(co),;] > Tei-tt-canbeng|- bis- I Cricorbony| iron)os Be. = oo So = : Hat so And Hhycrexo= - | [c Bi), re No = Srecuou fea) 3 oetaaquadii Tron | <> Cit) Sefecte \ die Uchysroxo- bis febraaquaivenig) hpiste s ¢ sulle IT Cas Lat NHa iS TE Now re Hie] Ga), —> gress ratdls ie cba ciasaiene | su Mode cahtogreonlggh AL OA) rie caebany\- visGicartoagl Fwon(o)) ait aw . ix Se Nee et 4a ae cobalt Cy BOR oe ac a (e204), TQ ak oer iene |" patasotien) | elt hgdroxo tetrakis cxalocto givotkede an) X-) (0) )sa