Material Safety Data Sheets: Dahej Petrochemical Complex Dual Feed Cracker Unit & Associated Units

DAHEJ PETROCHEMICAL COMPLEX
Dual Feed Cracker Unit

& Associated Units
ONGC Petro additions Ltd. EIL
SEZ, Dahej, Gujarat, India JOB NO. 6987
Page: 1 of 429
Material Safety Data Sheets
X 05 21.012013 Var. MSDS added Team SE/LE CM Yun A. Garayhi

(SE)
X 04 13.10.2012 SE data sheets added Team SE CM Yun A. Garayhi
(SE)
X 03 09.05.2012 MSDS for DMDS added R. Mauritz K. Nießer R. Mauritz
X 02 16.11.2011 Pages 170 to 202 added R. Mauritz K. Nießer R. Mauritz
X 01 28.4.2011 R. Mauritz K. Nießer R. Mauritz
Status Issue Date Reason for Issue / Remark Prepared Checked Approved OPaL/EILo
ENGINEERING Linde Proj. No.: 3110 A9NK

DIVISION Linde Project Code : DAHEJ
Samsung Proj. No.: SC 2252

Samsung Job Code : OPaL
Contract No / PO No.: Item No.:

MR/OW/MM/DFC/02/2007 N/A
Contractor Doc. No.: Company Doc. No.:

&AA-00-S-LX 1030 6987-LEPC1-AA-00-SO-LX 1030
Intellectual property rights reserved - refer to protection notice ISO 16016

Dahej Petrochemicals Complex DFCU & AU Page 2of 429
6987-LEPC1-AA-00-SO-LX 1030 Issue: 05
Contents:
Page
Nalco AquaMax EC1405A (Corrosion Inhibitor I and III) 4

Nalco EC1010A (Corrosion Inhibitor II) 18
Nalco EC1005A (Amine (BFW)) 31
Nalco Fortis EC3071A (C4 Polymerisation Inhibitor) 43
Nalco Actrene EC3214A (Polymerisation Inhibitor I) 59
Nalco Actrene EC3269A (Polymerisation Inhibitor II) 74
Nalco Arsenal EC3430A (Polymerisation Inhibitor III) 88
Nalco ELIMIN-OX (Oxygen Scavanger) 98
Nalco AquaMax EC6577A (Emulsion Breaker) 110
Nalco Arsenal EC9055A (Antifoam Inhibitor) 118
Nitrogen 126
KL7741B (C2 Hydrogenation catalyst) 134
KL7752 (C3 Hydrogenation catalyst) 140
KL7763 (PGHU I catalyst) 146
KL8233 (PGHU II catalyst) 152
KL5850 (Inert material for hydrogenation reactors) 159
Siliporite (Molsieve for driers) 165
Ethylene 171
Ethane 174
1-Butene 177
n-Butene 180
Isobutane 183
1,3 Butadiene 186
1,2 Butadiene 189
Hydrogen 192
Methane 195
Propylene 198
Propane 201
Dimethyl Disulphide (DMDS) 204
Methanol 212
NMP 220
Silicone Oil 230
Sodium Nitrite 238

Dahej Petrochemicals Complex DFCU & AU Page 3of 429
6987-LEPC1-AA-00-SO-LX 1030 Issue: 05
TBC 85 wt-% 248

Propadiene 1,2 256
Methyl Acetylene 260
n-Butane 264
Butane (containing >0 0,1% 1,3 butadiene) 268
Isobutene 272
cis-Butene 276
trans-Butene 280
Ethyl acetylene 284
Vinyl acetylene 288
Methyl 3- butene 1 295
Nalco Fortis EC3071B 299
SIYPro E640 312
Preslia 32 325
Coke 332
CBFS 338
ACU Raffinate (Naphtha) 342
Benzene 353
C6 Raffinate 365
Sodium Hydroxide Solution (Caustic) 375
Sulphuric Acid, 98% 383
PSA Adsorbent 391
Pyrolysis Gasoline, Hydrogenated 411
C9+ Oil 416

SAFETY DATA SHEET
PRODUCT
AQUAMAX(TM) EC1405A
EMERGENCY TELEPHONE NUMBER(S)

See section 16, for Emergency Telephone Numbers.
1. IDENTIFICATION OF THE SUBSTANCE/PREPARATION AND OF THE

COMPANY/UNDERTAKING
PRODUCT NAME : AQUAMAX(TM) EC1405A
APPLICATION : CORROSION INHIBITOR
COMPANY IDENTIFICATION : NALCO EUROPE B.V.

Postbus 627
2300 AP Leiden, The Netherlands
EMERGENCY TELEPHONE NUMBER(S) : See section 16, for Emergency Telephone Numbers.
Date issued : 24.04.2009

Version Number : 3.5
COMPANY CONTACT TELEPHONE NUMBERS.

NALCO EUROPE B.V. +31 71 5241 100 NALCO NORGE AS (NO) +47 51 96 36 00
NALCO AB (SE) +46 (0)8-50074000 NALCO POLSKA Sp.z.o.o. (PL) PRZEMYS ŁOWA 55
PL-43-110 TYCHY
TEL:+48 (0)32-3262750
FAX: +48(0)32 329 13 11
e-mail: office@nalco.pl
NALCO ANADOLU KIMYA (TR) +90 216 5743464 NALCO PORTUGUESA LDA. +351 214130996
(P)
NALCO APPLIED SERVICES +31 (0)73 6456980 NTD S.r.l (IT) +39 (0) 313351325
OF EUROPE BV
NALCO BELGIUM N.V./S.A. (B) +32 (0)3-450 69 10 CHEMIA BRUGG AG (CH) +41 (0)56 4606260
NALCO DANMARK A/S +45-48195800 OEKOPHIL AG (CH) +41 (0)41 760 2220
NALCO DEUTSCHLAND GmbH +49 (0)69-79340 WYSS WASSERTECHNIK AG +41 (0)52 235 38 38
(D) (CH)
NALCO ESPAÑOLA S.A. (E) +34 93-4095555 Nalco Company OOO +7 (0)495 980 72 80
NALCO FINLAND OY (FI) +358 (0)9 2517 4700 NALCO ÖSTERREICH + 43(0)1 27026350
Ges.m.b.H. (A)
NALCO FRANCE SAS +33 (0)3 20 11 70 00 First Distributor: Nalco Czechia Stankova 882/2,CZ-149 00 Praha
s.r.o. (CZ) 4,Czech Republic,+420 (0)2 679 123
50
NALCO HELLAS S.A. (GR) +30 210 238 9620 Local Support: Nalco Hungary +36 1 880 5761
Kft. (HU)
NALCO ITALIANA S.R.L.(I) +39 06-54565000 Local Support: Nalco Österreich +385 (0)1 377 95 21
Ges.m.b.H., Representation
Office Predstavnistvo Zagreb
(HR)
NALCO LIMITED +44 (0)1606 74488 Local Support: Nalco Österreich +40 (0) 21 224 17 93
Ges.m.b.H. Representation
Office ROMANIA (RO)
NALCO NETHERLANDS B.V. +31 (0)13-5952200
For Product Safety information please contact Jacqueline Bland, e-mail EUProductSafety@nalco.com
2. HAZARDS IDENTIFICATION
HAZARD CLASSIFICATION :
Our hazard evaluation has identified the following chemical substance(s) as hazardous. Consult Section 15 for the
nature of the hazard(s). This product is classified as dangerous in accordance with the Preparations Directive
1999/45/EC.
NALCO EUROPE B.V. Postbus 627 • 2300 AP Leiden • The Netherlands • +31 71 5241 100
For additional copies of an MSDS visit www.nalco.com and request access
1 / 14
SAFETY DATA SHEET
PRODUCT
AQUAMAX(TM) EC1405A

Harmful by inhalation, in contact with skin and if swallowed. Causes burns. May cause sensitization by skin
contact.
HUMAN HEALTH HAZARDS - ACUTE :
INHALATION :
Irritating, in high concentrations, to the eyes, nose, throat and lungs. Vapors may have a strong offensive odor
which may cause sensory response including headache, nausea and vomiting.
SKIN CONTACT :
May cause severe irritation or tissue damage depending on the length of exposure and the type of first aid
administered. Harmful if absorbed through skin.
EYE CONTACT :
Corrosive. Will cause eye burns and permanent tissue damage.
INGESTION :
Not a likely route of exposure. Corrosive; causes chemical burns to the mouth, throat and stomach.
ENVIRONMENTAL HAZARDS :
Keep out of waterways.
PHYSICAL AND CHEMICAL HAZARDS :

Combustible.
3. COMPOSITION/INFORMATION ON INGREDIENTS
nature of the hazard(s). This product is classified as dangerous in accordance with the Preparations Directive
1999/45/EC.
Hazardous Substance(s) EINECS / CAS NO SYMBOL R-PHRASES / % (w/w)

ELINCS NO NOTAS
Monoethanolamine 205-483-3 141-43-5 C R20/21/22, R34 60 - 100
Methoxypropylamine 226-241-3 5332-73-0 C R10, R22, R35, 1- 5
R43, R52
Methoxypropylamine 226-241-3 5332-73-0 C R10, R22, R35, 5 - 10
R43, R52
Refer to Section 16 for descriptions of relevant risk phrases and Notas.
4. FIRST AID MEASURES
INHALATION :
Remove to fresh air, treat symptomatically. Get medical attention.
SKIN CONTACT :
Immediately flush with plenty of water for at least 15 minutes. For a large splash, flood body under a shower.
Remove contaminated clothing. Wash off affected area immediately with plenty of water. Get immediate medical
attention. Contaminated clothing, shoes, and leather goods must be discarded or cleaned before re-use.
EYE CONTACT :
PROMPT ACTION IS ESSENTIAL IN CASE OF CONTACT. Immediately flush eye with water for at least 15
minutes while holding eyelids open. Get immediate medical attention.
2 / 14
SAFETY DATA SHEET
PRODUCT
AQUAMAX(TM) EC1405A

INGESTION :
DO NOT INDUCE VOMITING. If conscious, washout mouth and give water to drink. Get immediate medical
attention.
NOTE TO PHYSICIAN :
Probable mucosal damage may contraindicate the use of gastric lavage. Based on the individual reactions of the
patient, the physician's judgement should be used to control symptoms and clinical condition.
5. FIRE FIGHTING MEASURES
FLASH POINT : 89 °C PMCC
EXTINGUISHING MEDIA :
Dry powder, Carbon dioxide, Foam, Other extinguishing agent suitable for Class B fires, For large fires, use water
spray or fog, thoroughly drenching the burning material.
Keep containers cool by spraying with water.
FIRE AND EXPLOSION HAZARD :

Combustible Liquid; may form combustible mixtures at or above the flash point. May evolve oxides of carbon
(COx) under fire conditions. May evolve oxides of nitrogen (NOx) under fire conditions. Empty product containers
may contain product residue. Do not pressurize, cut, heat, weld, or expose containers to flame or other sources of
ignition.
SPECIAL PROTECTIVE EQUIPMENT FOR FIRE FIGHTING :

In case of fire, wear a full face positive-pressure self contained breathing apparatus and protective suit.
6. ACCIDENTAL RELEASE MEASURES
PERSONAL PRECAUTIONS :
Restrict access to area as appropriate until clean-up operations are complete. Ensure clean-up is conducted by
trained personnel only. Ventilate spill area if possible. Do not touch spilled material. Stop or reduce any leaks if it
is safe to do so. Remove sources of ignition. Use personal protective equipment recommended in Section 8
(Exposure Controls/Personal Protection). Notify appropriate government, occupational health and safety and
environmental authorities.
METHODS FOR CLEANING UP :

SMALL SPILLS: Soak up spill with absorbent material. Place residues in a suitable, covered, properly labeled
container. Wash affected area. LARGE SPILLS: Contain liquid using absorbent material, by digging trenches or
by diking. Reclaim into recovery or salvage drums or tank truck for proper disposal. Wash site of spillage
thoroughly with water. Contact an approved waste hauler for disposal of contaminated recovered material.
Dispose of material in compliance with regulations indicated in Section 13 (Disposal Considerations).
ENVIRONMENTAL PRECAUTIONS :
Prevent material from entering sewers or waterways.
7. HANDLING AND STORAGE
HANDLING :
Do not get in eyes, on skin, on clothing. Do not take internally. Do not breathe vapors/gases/dust. Use with
adequate ventilation. Avoid generating aerosols and mists. Keep away from acids and oxidizing agents. Do not
3 / 14
SAFETY DATA SHEET
PRODUCT
AQUAMAX(TM) EC1405A

use, store, spill or pour near heat, sparks or open flame. Keep the containers closed when not in use. Have
emergency equipment (for fires, spills, leaks, etc.) readily available.
STORAGE CONDITIONS :
Store the containers tightly closed. Store away from heat and sources of ignition. Use proper grounding
procedures. Store separately from acids. Store separately from oxidizers. Amine and sulphite products should
not be stored within close proximity or resulting vapors may form visible airborne particles.
SUITABLE CONSTRUCTION MATERIAL :

Carbon Steel C1018, Stainless Steel 304, Stainless Steel 316L, EPDM, PTFE, HDPE (high density polyethylene),
Perfluoroelastomer, TFE, FEP (encapsulated)
UNSUITABLE CONSTRUCTION MATERIAL :

Viton, Neoprene, Nitrile, MDPE
SPECIFIC USE(S) :
CORROSION INHIBITOR
For specific dosages and customized applications please contact your representative.
8. EXPOSURE CONTROLS/PERSONAL PROTECTION
OCCUPATIONAL EXPOSURE LIMITS
Exposure guidelines have not been established for this product. Available exposure limits for the substance(s) are
shown below. Exposure guidelines have not been established for this product. Available exposure limits for the
substance(s) are shown below.
Country/Source Substance(s) Category: ppm mg/m3
AIHA/WEEL Methoxypropylamine TWA 5

STEL 15
AUSTRIA Monoethanolamine MAK 1 2.5

MAK STEL 3 7.6
Skin*
MAK 1 2.5
MAK STEL 3 7.6
Skin*
BELGIUM Monoethanolamine TWA 1 2.5

STEL 3 7.6
Skin*
TWA 1 2.5
STEL 3 7.6
Skin*
BULGARIA Monoethanolamine TWA 8

STEL 15
TWA 8
STEL 15
DENMARK Monoethanolamine GV 1 2.5

Skin*
GV 1
Skin*
4 / 14
SAFETY DATA SHEET
PRODUCT
AQUAMAX(TM) EC1405A

GV 1 2.5
Skin*
GV 1
Skin*
FINLAND Monoethanolamine HTP 8H 1 2.5

HTP 15MIN 3 7.6
Skin*
HTP 8H 1 2.5
HTP 15MIN 3 7.6
Skin*
FRANCE Monoethanolamine VME 1 2.5

VLE 3 7.6
Skin*
VME 1 2.5
VLE 3 7.6
Skin*
GERMANY Monoethanolamine AGW 2 5.1

Skin*
AGW 2 5.1
Skin*
IRELAND Monoethanolamine TWA 3 8

STEL 6 15
TWA 3 8
STEL 6 15
ITALY Monoethanolamine TWA 1 2.5

STEL 3 7.6
Skin*
TWA 1 2.5
STEL 3 7.6
Skin*
NETHERLANDS Monoethanolamine TGG 2.5

TGG 15 7.6
Skin*
TGG 2.5
TGG 15 7.6
Skin*
NORWAY Monoethanolamine ADM. NORM 3 8

ADM. NORM 1 2.5
Skin*
ADM. NORM 3 8
ADM. NORM 1 2.5
Skin*
SPAIN Monoethanolamine VLA-ED 1 2.5

VLA-EC 3 7.5
Skin*
VLA-ED 1 2.5
VLA-EC 3 7.5
Skin*
SWEDEN Monoethanolamine NGV 3 8

KTV 6 15
5 / 14
SAFETY DATA SHEET
PRODUCT
AQUAMAX(TM) EC1405A

Skin*
NGV 3 8
KTV 6 15
Skin*
SWITZERLAND Monoethanolamine TWA 2 5

STEL 4 10
TWA 2 5
STEL 4 10
UNITED KINGDOM Monoethanolamine TWA 1 2.5

STEL 3 7.6
Skin*
TWA 1 2.5
STEL 3 7.6
Skin*
POLAND Monoethanolamine MAC-NDS 2.5

MAC-NDSC 7.5
h
MAC-NDS 2.5
MAC-NDSC 7.5
h
HUNGARY Monoethanolamine ÁK 2.5

CK 7.6
Skin*
ÁK 2.5
CK 7.6
Skin*
LATVIA Monoethanolamine TWA 0.5
TWA 0.5
CZECH REPUBLIC Monoethanolamine PEL 2.5

NPK-P 7.5
Skin*
PEL 2.5
NPK-P 7.5
Skin*
CROATIA Monoethanolamine MDK 3 8

KDK 6 15
MDK 3 8
KDK 6 15
ROMANIA Monoethanolamine TWA 1 2.5

STEL 3 7.6
Skin*
TWA 1 2.5
STEL 3 7.6
Skin*
RUSSIAN Monoethanolamine (Vapor and aerosol.) CEIL 0.5

FEDERATION
CEIL 0.5
6 / 14
SAFETY DATA SHEET
PRODUCT
AQUAMAX(TM) EC1405A

SERBIA Monoethanolamine MAC 3 8

Skin*
MAC 3 8
Skin*
SLOVAKIA Monoethanolamine TWA 1 2.5

CEILING 7.6
Skin*
TWA 1 2.5
CEILING 7.6
Skin*
SLOVENIA Monoethanolamine STEL MULT

Skin*
TWA 1 2.5
STEL MULT
Skin*
TWA 1 2.5
* A skin notation refers to the potential significant contribution to overall exposure by the cutaneous route, including mucous membranes and
the eyes.
MONITORING MEASURES :
A small volume of air is drawn through an absorbant or barrier to trap the substance(s) which can then be desorbed
or removed and analyzed as referenced below:
Substance(s) Method Analysis Absorbant
Monoethanolamine US NIOSH: 2007 Gas chromatography Silica gel
Methoxypropylamine No method identified
ENGINEERING MEASURES :
General ventilation is recommended. Use local exhaust ventilation if necessary to control airborne mist and vapor.
PERSONAL PROTECTION
GENERAL ADVICE :
The use and choice of personal protection equipment is related to the hazard of the product, the workplace and the
way the product is handled. In general, we recommend as a minimum precaution that safety glasses with
side-shields and workclothes protecting arms, legs and body be used. In addition any person visiting an area
where this product is handled should at least wear safety glasses with side-shields. The applicable European
standard can be found in EN 166.
RESPIRATORY PROTECTION :
Where concentrations in air may exceed the limits given in this section, the use of a half face filter mask or air
supplied breathing apparatus is recommended. A suitable filter material depends on the amount and type of
chemicals being handled. Consider the use of filter type: A-B-E-K-P The applicable European standard can be
found in EN 140, EN 137, EN 143 and EN 14387. In event of emergency or planned entry into unknown
7 / 14
SAFETY DATA SHEET
PRODUCT
AQUAMAX(TM) EC1405A

concentrations a positive pressure, full-facepiece SCBA should be used. If respiratory protection is required,
institute a complete respiratory protection program including selection, fit testing, training, maintenance and
inspection.
HAND PROTECTION :
When handling this product, the use of chemical gauntlets is recommended. The choice of work glove depends on
work conditions and what chemicals are handled, but we have positive experience under light handling conditions
using gloves made from PVC Gloves should be replaced immediately if signs of degradation are observed.
Breakthrough time not determined as preparation, consult PPE manufacturers. The applicable European standard
can be found in EN 374.
SKIN PROTECTION :
Wear chemical resistant apron, chemical splash goggles, impervious gloves and boots. A full slicker suit is
recommended if gross exposure is possible. When handling this product, the use of a chemical resistant suit and
rubber boots is recommended. The applicable European standard can be found in EN ISO 20345.
EYE PROTECTION :
Wear a face shield with chemical splash goggles. The applicable European standard can be found in EN 166.
HYGIENE RECOMMENDATIONS :
Eye wash station and safety shower are necessary. If clothing is contaminated, remove clothing and thoroughly
wash the affected area. Launder contaminated clothing before reuse.
9. PHYSICAL AND CHEMICAL PROPERTIES
PHYSICAL STATE Liquid
APPEARANCE Clear Light yellow
ODOR Amine

SPECIFIC GRAVITY 1.026 (15 °C)
SOLUBILITY IN WATER Complete
pH () > 12.5
VISCOSITY 8.3 cst (40 °C) ASTM D-445
POUR POINT ASTM D-97 -24 °C
VAPOR PRESSURE 1 kPa (25 °C) ASTM D6378
Note: These physical properties are typical values for this product and are subject to change.
10. STABILITY AND REACTIVITY
STABILITY :
Stable under normal conditions.
HAZARDOUS POLYMERIZATION :
Hazardous polymerization will not occur.
CONDITIONS TO AVOID :
Heat and sources of ignition including static discharges.
8 / 14
SAFETY DATA SHEET
PRODUCT
AQUAMAX(TM) EC1405A

MATERIALS TO AVOID :
Contact with strong acids (e.g. sulfuric, phosphoric, nitric, hydrochloric, chromic, sulfonic) may generate heat,
splattering or boiling and toxic vapors., Contact with strong oxidizers (e.g. chlorine, peroxides, chromates, nitric
acid, perchlorate, concentrated oxygen, permanganate) may generate heat, fires, explosions and/or toxic vapors.,
Avoid contact with SO2 or acidic bisulfite products, which may react to form visible airborne amine salt particles.,
Certain amines in contact with nitrous acid, organic or inorganic nitrites or atmospheres with high nitrous oxide
concentrations may produce N-nitrosamines, many of which are cancer-causing agents to laboratory animals.
HAZARDOUS DECOMPOSITION PRODUCTS :

Under fire conditions: Oxides of carbon, Oxides of nitrogen
11. TOXICOLOGICAL INFORMATION
No toxicity studies have been conducted on this product.
SENSITIZATION :
This product is not expected to be a sensitizer.
CARCINOGENICITY :
None of the substances in this product are listed as carcinogens by the International Agency for Research on
Cancer (IARC), the National Toxicology Program (NTP) or the American Conference of Governmental Industrial
Hygienists (ACGIH).
For additional information on the hazard of the preparation, please consult section 2 and 12.
12. ECOLOGICAL INFORMATION
ECOTOXICOLOGICAL EFFECTS :
MOBILITY :
The environmental fate was estimated using a level III fugacity model embedded in the EPI (estimation program
interface) Suite TM, provided by the US EPA. The model assumes a steady state condition between the total input
and output. The level III model does not require equilibrium between the defined media. The information provided
is intended to give the user a general estimate of the environmental fate of this product under the defined
conditions of the models.
If released into the environment this material is expected to distribute to the air, water and soil/sediment in the
approximate respective percentages;
Air Water Soil/Sediment

<5% 30 - 50% 50 - 70%
The portion in water is expected to be soluble or dispersible.
PERSISTENCY AND DEGRADATION :
The organic portion of this preparation is expected to be readily biodegradable.
BIOACCUMULATION POTENTIAL
This preparation or material is not expected to bioaccumulate.
9 / 14
SAFETY DATA SHEET
PRODUCT
AQUAMAX(TM) EC1405A

13. DISPOSAL CONSIDERATIONS
If this preparation becomes a waste, the final user must define and assign the appropriate European Waste
Catalogue code. Use only authorized contractors. Ensure compliance with EC, national and local regulations.
Dispose of wastes in an approved incinerator or waste treatment/disposal site, in accordance with all applicable
regulations. Do not dispose of wastes in local sewer or with normal garbage. This product is ashless and can be
burned directly in appropriate equipment. Any chemical waste is a potential environmental pollutant and is NOT
suitable for disposal via ground, municipal sewers, drains, natural streams or rivers.
Empty drums should be taken for recycling, recovery, or disposal through a suitably qualified or licensed
contractor.
EUROPE WASTE CODE :

16 03 05*- OFF SPECIFICATION BATCHES AND UNUSED PRODUCTS - Organic wastes containing dangerous
substances. If this product is used in any further processes, the final user must redefine and assign the most
appropriate European Waste Catalogue Code.
14. TRANSPORT INFORMATION
The information in this section is for reference only and should not take the place of a shipping paper (bill of lading)
specific to an order. Please note that the proper Shipping Name / Hazard Class may vary by packaging,
properties, and mode of transportation. Typical Proper Shipping Names for this product are as follows.
LAND TRANSPORT
Proper Shipping Name : AMINES, LIQUID, CORROSIVE, N.O.S.
Technical Name(s) : Monoethanolamine
UN/ID No : UN 2735
Hazard Class - Primary : 8
Packing Group : II
ADR/RID H.I.n. : 80
CLASSIFICATION CODE : C7
AIR TRANSPORT (ICAO/IATA)

Technical Name(s) : Methoxypropylamine
UN/ID No : UN 2735
Packing Group : II
IATA Cargo Packing Instructions : 812
IATA Cargo Aircraft Limit : 30 L (Max net quantity per package)
IATA Passenger Packing Instructions : Y808 / 808
IATA Passenger Aircraft Limit : 0.5 L / 1 L
MARINE TRANSPORT (IMDG/IMO)

Technical Name(s) : Methoxypropylamine
UN/ID No : UN 2735
Packing Group : II
OTHER APPLICABLE INFORMATION

CEFIC TREMCARD REFERENCE : 80GC7-II+III
10 / 14
SAFETY DATA SHEET
PRODUCT
AQUAMAX(TM) EC1405A

EMERGENCY ACTION CODE : 2X
15. REGULATORY INFORMATION
CLASSIFICATION AND LABELLING :
GOVERNING DIRECTIVE(S): Dangerous Substances Directive 67/548/EEC and Dangerous Preparations

Directive 1999/45/EC.
HAZARD SYMBOLS
CORROSIVE
Contains:..Methoxypropylamine Monoethanolamine
RISK PHRASES
R20/21/22 - Harmful by inhalation, in contact with skin and if swallowed.
R34 - Causes burns.
R43 - May cause sensitization by skin contact.
SAFETY PHRASES
S24/25 - Avoid contact with skin and eyes.
S26 - In case of contact with eyes, rinse immediately with plenty of water and seek medical advice.
S36/37/39 - Wear suitable protective clothing, gloves and eye/face protection.
S45 - In case of accident or if you feel unwell, seek medical advice immediately (show the label where possible).
NATIONAL REGULATIONS FRANCE

Table of occupational diseases, Article L461-4. Social Security Code- Decree 11/2/2003: Relevant, see table(s):
49, 49 bis
Classified Industrial Sites (ICPE): Relevant. Headings: 1432C
NATIONAL REGULATIONS GERMANY

WGK 1 (Annex 4)
NATIONAL REGULATIONS NORWAY
NATIONAL REGULATIONS RUSSIAN FEDERATION

The law of Russian Federation "About the sanitary-epidemiological safety of the population", 30 March 1999 N
52-FZ.
The law of Russian Federation "About the safety of the dangerous industrial objects", 21 July 1997 No. 116-FZ.
The law of Russian Federation "About protection of the rights of the consumers", 07 February 1992 N 2300-1.
11 / 14
SAFETY DATA SHEET
PRODUCT
AQUAMAX(TM) EC1405A

The law of Russian Federation "Basics of the legislation of Russian Federation about occupational safety", 6
August 1993 N 5600-1.
The law of Russian Federation "About the industrial regulation", 27 December 2002 N 184-FZ.
GOST 30333-2007: Chemical production safety passport. General requirements.
GOST 19433-88: Dangerous goods. Classification and marking.
GOST 12.1.007-76 (Occupational safety standards system. Noxious substances. Classification and general safety
requirements).
PRODUCT REGISTRATION NUMBER

France 81241
Norway 092225
INTERNATIONAL CHEMICAL CONTROL LAWS

EUROPE
The substances in this preparation have been reviewed for compliance with the EINECS or ELINCS inventories.
Safety Data Sheet according to Regulation (EC) No 1907/2006.
Nalco is committed to and fully supports the Registration, Evaluation, Authorization and restriction of CHemicals
(REACH) regulation. It is our intention to pre-register all chemical substances that we manufacture or import into
European Union and to work with our suppliers to ensure a smooth transition to this new regulatory environment.
Should you require any further information on Nalco's REACH programme please contact us at reach@nalco.com
or visit our website.
UNITED STATES :
The substances in this preparation are included on or exempted from the TSCA 8(b) Inventory (40 CFR 710)
CANADA :
The substance(s) in this preparation are included in or exempted from the Domestic Substance List (DSL).
JAPAN
All substances in this product comply with the Law Regulating the Manufacture and Importation Of Chemical
Substances and are listed on the Existing and New Chemical Substances list (ENCS).
16. OTHER INFORMATION
LIST OF RELEVANT R-PHRASES AND NOTAS IN SECTION 3

R10 - Flammable.
R34 - Causes burns.
R35 - Causes severe burns.
R52 - Harmful to aquatic organisms.
- REVISED INFORMATION: section(s):
- 2, 3, 15, 16
-4
12 / 14
SAFETY DATA SHEET
PRODUCT
AQUAMAX(TM) EC1405A

-6
-7
- 11
This product material safety data sheet provides health and safety information. The product is to be used in
applications consistent with our product literature. Individuals handling this product should be informed of the
recommended safety precautions and should have access to this information. For any other uses, exposures
should be evaluated so that appropriate handling practices and training programs can be established to insure
safe workplace operations. Please consult your local sales representative for any further information.
Trans-European +32-(0)3-575-5555
Belgium / Luxembourg +32-(0)3-575-0330
Bulgaria +32-(0)3-575-5555
Croatia +385 (0)91-1-25-75-23
Czech Republic +420-602-669421
Denmark +47-22-33-69-99
Finland +358-(0)9-471 977
France / French Switzerland +33-(0)6-11-07-32-81
Germany / Austria / German Switzerland +49-(0)6232-130128
Hungary +36-30-9-506-447
Italy / Italian Switzerland +39-333-210-7947
Latvia +32-(0)3-575-5555
The Netherlands +32-(0)3-575-0330
Norway +47-22-33-69-99
Poland +48-(0)601-66-2626 (SGS) / +48 (0) 14 637 40 81 (SPOT)
Portugal +351-91-911-1399
Romania +40-744 -34-14-53
Russia / Belarus +7-812-449-0474
Saudi Arabia +966-(3)847-1515
Serbia +32-(0)3-575-5555
Slovak Republic +421-(0)905-585-938
Slovenia +386-41-634-916
Spain +34-977-551577
Sweden +47-22-33-69-99
UAE +44-(0)7071-223-738
UK and Republic of Ireland +44-(0)7071-223-738
Nalfleet International +32-(0)3-575-5555
POISON CONTROL CENTER TELEPHONE NUMBERS
Belgium +32-70-245245
Czech Republic +420 224 91 92 93
Hungary +36-80-201-199 ETTSZ, 1096 Budapest, Nagyvárad tér 2
France +33-(0)145-42-59-59 ORFILA
Slovak Republic +421 (0)2 5477 4166
Prepared By : SHE Department

13 / 14
SAFETY DATA SHEET
PRODUCT
AQUAMAX(TM) EC1405A

Numbers quoted in the MSDS are given in the format: 1,000,000 = 1 million and 1,000 = 1 thousand. 0.1 = 1 tenth
and 0.001 = 1 thousandth
14 / 14
SAFETY DATA SHEET
PRODUCT
NALCO® EC1010A

(800) 424-9300 (24 Hours) CHEMTREC
1. CHEMICAL PRODUCT AND COMPANY IDENTIFICATION
PRODUCT NAME : NALCO® EC1010A
APPLICATION : CORROSION INHIBITOR
COMPANY IDENTIFICATION : Nalco Company

1601 W. Diehl Road
Naperville, Illinois
60563-1198
EMERGENCY TELEPHONE NUMBER(S) : (800) 424-9300 (24 Hours) CHEMTREC
NFPA 704M/HMIS RATING

HEALTH : 2 / 2* FLAMMABILITY : 2/2 INSTABILITY : 0/0 OTHER :
0 = Insignificant 1 = Slight 2 = Moderate 3 = High 4 = Extreme * = Chronic Health Hazard
nature of the hazard(s).
Hazardous Substance(s) CAS NO % (w/w)

Heavy Aromatic Naphtha 64742-94-5 30.0 - 60.0
Naphthalene 91-20-3 1.0 - 5.0
1,2,4-Trimethylbenzene 95-63-6 1.0 - 5.0
Ethylbenzene 100-41-4 0.1 - 1.0
**EMERGENCY OVERVIEW**
WARNING
Combustible. Irritating to eyes and skin. Vapours may cause drowsiness and dizziness. This product contains
naphthalene. The International Agency for Research on Cancer (IARC) has evaluated naphthalene and determined it
to be possibly carcinogenic to humans (Group 2B, based on sufficient evidence in experimental animals and
inadequate evidence in humans). This product contains ethylbenzene. The International Agency for Research on
Cancer (IARC) has evaluated ethylbenzene and determined it to be possibly carcinogenic to humans (Group 2B,
based on sufficient evidence in experimental animals and inadequate evidence in humans).
Keep away from heat. Keep away from sources of ignition - No smoking. Keep container tightly closed. Do not get in
eyes, on skin, on clothing. Do not take internally. Use with adequate ventilation. Avoid breathing vapor. In case of
contact with eyes, rinse immediately with plenty of water and seek medical advice. After contact with skin, wash
immediately with plenty of water. Use a mild soap if available.
Wear suitable protective clothing and gloves. Wear chemical splash goggles.
Combustible Liquid; may form combustible mixtures at or above the flash point. Empty product containers may
contain product residue. Do not pressurize, cut, heat, weld, or expose containers to flame or other sources of ignition.
May evolve oxides of carbon (COx) under fire conditions. May evolve oxides of nitrogen (NOx) under fire conditions.
Nalco Company 1601 W. Diehl Road • Naperville, Illinois 60563-1198 • (630)305-1000

1 / 13
SAFETY DATA SHEET
PRODUCT
NALCO® EC1010A

(800) 424-9300 (24 Hours) CHEMTREC
PRIMARY ROUTES OF EXPOSURE :

Eye, Skin, Inhalation
EYE CONTACT :
Can cause moderate to severe irritation.
SKIN CONTACT :
Can cause moderate irritation.
INGESTION :
Not a likely route of exposure. May cause nausea and vomiting. Can cause chemical pneumonia if aspirated into
lungs following ingestion. Can cause central nervous system depression.
INHALATION :
Repeated or prolonged exposure may irritate the respiratory tract. Product mist or vapors may cause headache,
nausea, vomiting, drowsiness, stupor or unconsciousness. Can cause central nervous system depression.
AGGRAVATION OF EXISTING CONDITIONS :

Skin contact may aggravate an existing dermatitis condition.
HUMAN HEALTH HAZARDS - CHRONIC :

This product contains naphthalene. The International Agency for Research on Cancer (IARC) has evaluated
naphthalene and determined it to be possibly carcinogenic to humans (Group 2B, based on sufficient evidence in
experimental animals and inadequate evidence in humans). This product contains ethylbenzene. The International
Agency for Research on Cancer (IARC) has evaluated ethylbenzene and determined it to be possibly carcinogenic to
humans (Group 2B, based on sufficient evidence in experimental animals and inadequate evidence in humans).
EYE CONTACT :
Immediately flush eye with water for at least 15 minutes while holding eyelids open. Get medical attention.
SKIN CONTACT :
Immediately flush with plenty of water for at least 15 minutes. Use a mild soap if available. If symptoms develop, seek
medical advice.
INGESTION :
Do not induce vomiting: contains petroleum distillates and/or aromatic solvents. If conscious, washout mouth and give
water to drink. Get medical attention.
INHALATION :
Remove to fresh air, treat symptomatically. If symptoms develop, seek medical advice.
NOTE TO PHYSICIAN :
Based on the individual reactions of the patient, the physician's judgement should be used to control symptoms and
clinical condition.

2 / 13
SAFETY DATA SHEET
PRODUCT
NALCO® EC1010A

(800) 424-9300 (24 Hours) CHEMTREC
FLASH POINT : 116 °F / 47 °C ( PMCC )
Foam, Carbon dioxide, Dry powder, Other extinguishing agent suitable for Class B fires, For large fires, use water
Water mist may be used to cool closed containers.
UNSUITABLE EXTINGUISHING MEDIA :

Do not use water unless flooding amounts are available.

Combustible Liquid; may form combustible mixtures at or above the flash point. Empty product containers may contain
product residue. Do not pressurize, cut, heat, weld, or expose containers to flame or other sources of ignition. May
evolve oxides of carbon (COx) under fire conditions. May evolve oxides of nitrogen (NOx) under fire conditions.

Restrict access to area as appropriate until clean-up operations are complete. Use personal protective equipment
recommended in Section 8 (Exposure Controls/Personal Protection). Stop or reduce any leaks if it is safe to do so.
Keep people away from and upwind of spill/leak. Ventilate spill area if possible. Remove sources of ignition. Ensure
clean-up is conducted by trained personnel only. Do not touch spilled material. Have emergency equipment (for fires,
spills, leaks, etc.) readily available. Notify appropriate government, occupational health and safety and environmental
authorities.

container. Wash affected area. LARGE SPILLS: Contain liquid using absorbent material, by digging trenches or by
diking. Reclaim into recovery or salvage drums or tank truck for proper disposal. Clean contaminated surfaces with
water or aqueous cleaning agents. Contact an approved waste hauler for disposal of contaminated recovered
material. Dispose of material in compliance with regulations indicated in Section 13 (Disposal Considerations).
Toxic to aquatic organisms, may cause long-term adverse effects in the aquatic environment., Prevent material from
entering sewers or waterways., If drains, streams, soil or sewers become contaminated, notify local authority.
HANDLING :
Do not get in eyes, on skin, on clothing. Do not take internally. Use with adequate ventilation. Do not breathe
vapors/gases/dust. Keep the containers closed when not in use. Keep away from acids and oxidizing agents. Do not
use, store, spill or pour near heat, sparks or open flame.

3 / 13
SAFETY DATA SHEET
PRODUCT
NALCO® EC1010A

(800) 424-9300 (24 Hours) CHEMTREC
Store in suitable labeled containers. Store the containers tightly closed. Store away from heat and sources of ignition.
Have appropriate fire extinguishers available in and near the storage area. Connections must be grounded to avoid
electrical charges. Store separately from oxidizers.

Stainless Steel 304, Stainless Steel 316L, Aluminum, Hastelloy C-276, HDPE (high density polyethylene), Nylon,
PVC, Plexiglass, Teflon, Kalrez

Brass, Copper, Mild steel, Natural rubber, Buna-N, Polyethylene, Polypropylene, EPDM, Ethylene propylene,
Neoprene, Polyurethane, Viton, Alfax, Hypalon
OCCUPATIONAL EXPOSURE LIMITS :

shown below.
Substance(s) Category: ppm mg/m3 Non-Standard

Unit
Oil Mist (Mist) ACGIH/TWA 5
ACGIH/STEL 10
Naphthalene ACGIH/TWA 10
ACGIH/STEL 15
ACGIH/Skin*
OSHA Z1/PEL 10 50
1,2,4-Trimethylbenzene ACGIH/TWA 25
Ethylbenzene ACGIH/TWA 100

ACGIH/STEL 125
OSHA Z1/PEL 100 435
Heavy Aromatic Naphtha Manufacturer's 100

Recommendation/TWA
* Can be absorbed through the skin.
The use of local exhaust ventilation is recommended to control emissions near the source. Laboratory samples should
be handled in a fumehood. Provide mechanical ventilation of confined spaces.
Where concentrations in air may exceed the limits given in this section or when significant mists, vapors or aerosols
are generated, an approved air purifying respirator equipped with suitable filter cartridges is recommended. Consult
the respirator / cartridge manufacturer data to verify the suitability of specific devices. In event of emergency or
planned entry into unknown concentrations a positive pressure, full-facepiece SCBA should be used. If respiratory
protection is required, institute a complete respiratory protection program including selection, fit testing, training,
maintenance and inspection.

4 / 13
SAFETY DATA SHEET
PRODUCT
NALCO® EC1010A

(800) 424-9300 (24 Hours) CHEMTREC
HAND PROTECTION :
When handling this product, the use of chemical gloves is recommended. The choice of work glove depends on work
conditions and what chemicals are handled. Please contact the PPE manufacturer for advice on what type of glove
material may be suitable. Gloves should be replaced immediately if signs of degradation are observed.
SKIN PROTECTION :
Wear standard protective clothing.
EYE PROTECTION :
Wear chemical splash goggles.
Use good work and personal hygiene practices to avoid exposure. Keep an eye wash fountain available. Keep a
safety shower available. If clothing is contaminated, remove clothing and thoroughly wash the affected area. Launder
contaminated clothing before reuse. Always wash thoroughly after handling chemicals. When handling this product
never eat, drink or smoke.
HUMAN EXPOSURE CHARACTERIZATION :

Based on our recommended product application and personal protective equipment, the potential human exposure is:
Low
APPEARANCE Dark Amber
ODOR Hydrocarbon
SPECIFIC GRAVITY 0.93 @ 60 °F / 16 °C

DENSITY 7.7 lb/gal
SOLUBILITY IN WATER Insoluble
VISCOSITY 10 cst @ 100 °F / 38 °C
POUR POINT -32 °F / -36 °C
BOILING POINT 295 °F / 146 °C
VAPOR PRESSURE < 5.2 mm Hg @ 100 °F / 37.8 °C
EVAPORATION RATE 0.6
STABILITY :

5 / 13
SAFETY DATA SHEET
PRODUCT
NALCO® EC1010A

(800) 424-9300 (24 Hours) CHEMTREC
Contact with strong oxidizers (e.g. chlorine, peroxides, chromates, nitric acid, perchlorate, concentrated oxygen,
permanganate) may generate heat, fires, explosions and/or toxic vapors.

SENSITIZATION :
CARCINOGENICITY :
This product contains ethylbenzene. The International Agency for Research on Cancer (IARC) has evaluated
ethylbenzene and determined it to be possibly carcinogenic to humans (Group 2B, based on sufficient evidence in
experimental animals and inadequate evidence in humans). This product contains naphthalene. The International
Agency for Research on Cancer (IARC) has evaluated naphthalene and determined it to be possibly carcinogenic to
humans (Group 2B, based on sufficient evidence in experimental animals and inadequate evidence in humans).
HUMAN HAZARD CHARACTERIZATION :

Based on our hazard characterization, the potential human hazard is: High
The following results are for the product.
ACUTE FISH RESULTS :

Species Exposure LC50 Test Descriptor
Fathead Minnow 96 hrs 39.8 mg/l Product
ACUTE INVERTEBRATE RESULTS :

Species Exposure LC50 EC50 Test Descriptor
Ceriodaphnia dubia 48 hrs 22.9 mg/l Product
MOBILITY :
interface) Suite TM, provided by the US EPA. The model assumes a steady state condition between the total input and
output. The level III model does not require equilibrium between the defined media. The information provided is
intended to give the user a general estimate of the environmental fate of this product under the defined conditions of
the models.

6 / 13
SAFETY DATA SHEET
PRODUCT
NALCO® EC1010A

(800) 424-9300 (24 Hours) CHEMTREC

<5% 10 - 30% 70 - 90%
The portion in water is expected to float on the surface.
ENVIRONMENTAL HAZARD AND EXPOSURE CHARACTERIZATION

Based on our hazard characterization, the potential environmental hazard is: Moderate
Based on our recommended product application and the product's characteristics, the potential environmental
exposure is: Low
If released into the environment, see CERCLA/SUPERFUND in Section 15.
If this product becomes a waste, it could meet the criteria of a hazardous waste as defined by the Resource
Conservation and Recovery Act (RCRA) 40 CFR 261. Before disposal, it should be determined if the waste meets the
criteria of a hazardous waste.
Hazardous Waste: D001, D018
Hazardous wastes must be transported by a licensed hazardous waste transporter and disposed of or treated in a
properly licensed hazardous waste treatment, storage, disposal or recycling facility. Consult local, state, and federal
regulations for specific requirements.
specific to an order. Please note that the proper Shipping Name / Hazard Class may vary by packaging, properties,
and mode of transportation. Typical Proper Shipping Names for this product are as follows.
The presence of an RQ component (Reportable Quantity for U.S. EPA and DOT) in this product causes it to be
regulated with an additional description of RQ for road, or as a class 9 for road and air, ONLY when the net weight in
the package exceeds the calculated RQ for the product.
LAND TRANSPORT :
Proper Shipping Name : FLAMMABLE LIQUID, N.O.S.

Technical Name(s) : 1,2,4-TRIMETHYLBENZENE, HEAVY AROMATIC
NAPHTHA
UN/ID No : UN 1993
Packing Group : III
Flash Point : 47 °C / 116 °F

7 / 13
SAFETY DATA SHEET
PRODUCT
NALCO® EC1010A

(800) 424-9300 (24 Hours) CHEMTREC
DOT Reportable Quantity (per package) : 2,460 lbs

DOT RQ Component : NAPHTHALENES
AIR TRANSPORT (ICAO/IATA) :

NAPHTHA
UN/ID No : UN 1993
Packing Group : III
IATA Cargo Aircraft Limit : 220 (Max net quantity per package)
MARINE TRANSPORT (IMDG/IMO) :

NAPHTHA
UN/ID No : UN 1993
Packing Group : III
*Marine Pollutant : HEAVY AROMATIC NAPHTHA
*Note: This product is regulated as a Marine Pollutant when shipped by Rail, Highway, or Air in bulk quantities (greater
than 119 gallons) and when shipped by water in all quantities.
This section contains additional information that may have relevance to regulatory compliance. The information in this
section is for reference only. It is not exhaustive, and should not be relied upon to take the place of an individualized
compliance or hazard assessment. Nalco accepts no liability for the use of this information.
NATIONAL REGULATIONS, USA :
OSHA HAZARD COMMUNICATION RULE, 29 CFR 1910.1200 :

Based on our hazard evaluation, the following substance(s) in this product is/are hazardous and the reason(s) is/are
shown below.
Heavy Aromatic Naphtha : Combustible., Irritant

Naphthalene : Skin irritant, Combustible., Cancer suspect agent (refer to Section 3)
1,2,4-Trimethylbenzene : Irritant, Combustible.
Ethylbenzene : Flammable, Irritant, Cancer suspect agent (refer to Section 3)
CERCLA/SUPERFUND, 40 CFR 302 :

This product contains the following Reportable Quantity (RQ) Substance. Also listed is the RQ for the product. If a
reportable quantity of product is released, it requires notification to the NATIONAL RESPONSE CENTER,
WASHINGTON, D.C. (1-800-424-8802).

8 / 13
SAFETY DATA SHEET
PRODUCT
NALCO® EC1010A

(800) 424-9300 (24 Hours) CHEMTREC
RQ Substance RQ
Naphthalene 2,460 lbs
SARA/SUPERFUND AMENDMENTS AND REAUTHORIZATION ACT OF 1986 (TITLE III) - SECTIONS 302, 311,
312, AND 313 :
SECTION 302 - EXTREMELY HAZARDOUS SUBSTANCES (40 CFR 355) :

This product does not contain substances listed in Appendix A and B as an Extremely Hazardous Substance.
SECTIONS 311 AND 312 - MATERIAL SAFETY DATA SHEET REQUIREMENTS (40 CFR 370) :
Our hazard evaluation has found this product to be hazardous. The product should be reported under the following
indicated EPA hazard categories:
X Immediate (Acute) Health Hazard

X Delayed (Chronic) Health Hazard
X Fire Hazard
- Sudden Release of Pressure Hazard
- Reactive Hazard
Under SARA 311 and 312, the EPA has established threshold quantities for the reporting of hazardous chemicals.
The current thresholds are: 500 pounds or the threshold planning quantity (TPQ), whichever is lower, for extremely
hazardous substances and 10,000 pounds for all other hazardous chemicals.
SECTION 313 - LIST OF TOXIC CHEMICALS (40 CFR 372) :

This product contains the following substance(s), (with CAS # and % range) which appear(s) on the List of Toxic
Chemicals
Hazardous Substance(s) CAS NO % (w/w)

Naphthalene 91-20-3 1.0 - 5.0
Ethylbenzene 100-41-4 0.1 - 1.0
1,2,4-Trimethylbenzene 95-63-6 1.0 - 5.0
TOXIC SUBSTANCES CONTROL ACT (TSCA) :

This product has been certified as KOSHER/PAREVE for year-round use INCLUDING THE PASSOVER SEASON by
the CHICAGO RABBINICAL COUNCIL.
FEDERAL WATER POLLUTION CONTROL ACT, CLEAN WATER ACT, 40 CFR 401.15 / formerly Sec. 307, 40 CFR
116.4 / formerly Sec. 311 :
This product contains the following substances listed in the regulation. Additional components may be unintentionally
present at trace levels.
Substance(s) Citations
• Naphthalene Sec. 307, Sec. 311
• Ethylbenzene
• Benzene
• Toluene

9 / 13
SAFETY DATA SHEET
PRODUCT
NALCO® EC1010A

(800) 424-9300 (24 Hours) CHEMTREC
• Xylene Sec. 307
CLEAN AIR ACT, Sec. 112 (Hazardous Air Pollutants, as amended by 40 CFR 63), Sec. 602 (40 CFR 82, Class I and
II Ozone Depleting Substances) :
Substance(s) Citations
• Ethylbenzene Sec. 112
• Benzene
• Toluene
• Xylene
• Cumene
• Naphthalene
CALIFORNIA PROPOSITION 65 :
This product contains the following substances which require warning under California Proposition 65. Additional
components may be unintentionally present at trace levels.
Substance(s) Concentration EFFECTS

• Naphthalene <5% Causes Cancer
• Ethylbenzene <1%
• Benzene < .001 % Causes Cancer, Causes Birth Defects, Causes

Reproductive Harm
• Toluene < .001 % Causes Birth Defects, Causes Reproductive
Harm
MICHIGAN CRITICAL MATERIALS :

Naphthalene
Ethylbenzene
STATE RIGHT TO KNOW LAWS :

The following substances are disclosed for compliance with State Right to Know Laws:
Naphthalene 91-20-3
1,2,4-Trimethylbenzene 95-63-6
Ethylbenzene 100-41-4
Heavy Aromatic Naphtha 64742-94-5
Fatty acid-amine condensate Proprietary
Substituted fatty acid ester Proprietary

10 / 13
SAFETY DATA SHEET
PRODUCT
NALCO® EC1010A

(800) 424-9300 (24 Hours) CHEMTREC
INTERNATIONAL CHEMICAL CONTROL LAWS :
CANADIAN ENVIRONMENTAL PROTECTION ACT (CEPA) :

AUSTRALIA
All substances in this product comply with the National Industrial Chemicals Notification & Assessment Scheme
(NICNAS).
CHINA
This product contains substance(s) which are not in compliance with the Provisions on the Environmental
Administration of New Chemical Substances and may require additional review.
EUROPE
JAPAN
KOREA
All substances in this product comply with the Toxic Chemical Control Law (TCCL) and are listed on the Existing
Chemicals List (ECL)
NEW ZEALAND
All substances in this product comply with the Hazardous Substances and New Organisms (HSNO) Act 1996,and are
listed on or are exempt from the New Zealand Inventory of Chemicals.
PHILIPPINES
This product contains substance(s) which are not in compliance with the Republic Act 6969 (RA 6969) and may require
additional review.

F103976
Due to our commitment to Product Stewardship, we have evaluated the human and environmental hazards and
exposures of this product. Based on our recommended use of this product, we have characterized the product's
general risk. This information should provide assistance for your own risk management practices. We have evaluated
our product's risk as follows:
* The human risk is: Low
* The environmental risk is: Low

11 / 13
SAFETY DATA SHEET
PRODUCT
NALCO® EC1010A

(800) 424-9300 (24 Hours) CHEMTREC
Any use inconsistent with our recommendations may affect the risk characterization. Our sales representative will
assist you to determine if your product application is consistent with our recommendations. Together we can
implement an appropriate risk management process.
recommended safety precautions and should have access to this information. For any other uses, exposures should
be evaluated so that appropriate handling practices and training programs can be established to insure safe workplace
operations. Please consult your local sales representative for any further information.
REFERENCES
Threshold Limit Values for Chemical Substances and Physical Agents and Biological Exposure Indices, American
Conference of Governmental Industrial Hygienists, OH., (Ariel Insight™ CD-ROM Version), Ariel Research Corp.,
Bethesda, MD.
Hazardous Substances Data Bank, National Library of Medicine, Bethesda, Maryland (TOMES CPS™ CD-ROM
Version), Micromedex, Inc., Englewood, CO.
IARC Monographs on the Evaluation of the Carcinogenic Risk of Chemicals to Man, Geneva: World Health
Organization, International Agency for Research on Cancer.
Integrated Risk Information System, U.S. Environmental Protection Agency, Washington, D.C. (TOMES CPS™
CD-ROM Version),
Micromedex, Inc., Englewood, CO.
Annual Report on Carcinogens, National Toxicology Program, U.S. Department of Health and Human Services, Public
Health Service.
Title 29 Code of Federal Regulations, Part 1910, Subpart Z, Toxic and Hazardous Substances, Occupational Safety
and Health Administration (OSHA), (Ariel Insight™ CD-ROM Version), Ariel Research Corp., Bethesda, MD.
Registry of Toxic Effects of Chemical Substances, National Institute for Occupational Safety and Health, Cincinnati,
OH,
(TOMES CPS™ CD-ROM Version), Micromedex, Inc., Englewood, CO.
Ariel Insight™ (An integrated guide to industrial chemicals covered under major regulatory and advisory programs),
North American Module, Western European Module, Chemical Inventories Module and the Generics Module (Ariel
Insight™ CD-ROM Version), Ariel Research Corp., Bethesda, MD.
The Teratogen Information System, University of Washington, Seattle, WA (TOMES CPS™ CD-ROM Version),
Micromedex, Inc., Englewood, CO.
Prepared By : Product Safety Department

Date issued : 03/05/2010

12 / 13
SAFETY DATA SHEET
PRODUCT
NALCO® EC1010A

(800) 424-9300 (24 Hours) CHEMTREC

13 / 13
MATERIAL SAFETY DATA SHEET
PRODUCT
NALCO® EC1005A

PRODUCT NAME : NALCO® EC1005A
APPLICATION : NEUTRALIZING AMINE

Postbus 627

NALCO AB (SE) +46 (0)8-50074000 NALCO POLSKA Sp.z.o.o. (PL) +48 (0)32-3262750
NALCO ANADOLU KIMYA (TR) +90 216 5743464 NALCO PORTUGUESA LDA. (P) +351 214130996
NALCO APPLIED SERVICES OF +31 (0)73 6456980 NTD S.r.l (IT) +39 (0) 313351325
EUROPE BV
NALCO DEUTSCHLAND GmbH (D) +49 (0)69-79340 WYSS WASSERTECHNIK AG (CH) +41 (0)52 235 38 38
NALCO ESPAÑOLA S.A. (E) +34 93-4095555 ZAO Nalco (RU) +7 (0)495 980 72 80
NALCO FINLAND OY (FI) +358 (0)9 2517 4700 NALCO ÖSTERREICH Ges.m.b.H. + 43(0)1 27026350
(A)
NALCO FRANCE SAS +33 (0)3 20 11 70 00 First Distributor: Nalco Czechia s.r.o. Stankova 882/2,CZ-149 00
(CZ) Praha 4,Czech Republic,+420
(0)2 679 123 50
NALCO HELLAS S.A. (GR) +30 210 238 9620 Local Support: Nalco Hungary Kft. +36 (0)1 471 91 81
(HU)
Ges.m.b.H., Representation Office
Predstavnistvo Zagreb (HR)
Ges.m.b.H. Representation Office
ROMANIA (RO)
This product is classified as dangerous in accordance with the Preparations Directive 1999/45/EC.
Harmful by inhalation, in contact with skin and if swallowed. Causes burns. May cause sensitization by skin
contact.
INHALATION :
Corrosive to respiratory system. Harmful by inhalation.
1 / 12
PRODUCT
NALCO® EC1005A

SKIN CONTACT :
Causes skin burns. May cause sensitization by skin contact. Harmful in contact with skin.
EYE CONTACT :
Corrosive. Will cause eye burns and permanent tissue damage.
INGESTION :
Not a likely route of exposure. Corrosive; causes chemical burns to the mouth, throat and stomach. May cause
nausea and vomiting. Can cause central nervous system depression. Harmful if swallowed.

ELINCS NO NOTAS
Methoxypropylamine 226-241-3 5332-73-0 C R10, R22, R35, 5 - 10
R43, R52
INHALATION :
SKIN CONTACT :
Get immediate medical attention. Immediately flush with plenty of water for at least 15 minutes. For a large
splash, flood body under a shower. Remove contaminated clothing. Wash off affected area immediately with
plenty of water. Contaminated leather articles such as shoes or belts must be discarded.
EYE CONTACT :
PROMPT ACTION IS ESSENTIAL IN CASE OF CONTACT. Get immediate medical attention. Immediately
flush eye with water for at least 15 minutes while holding eyelids open.
INGESTION :
Get immediate medical attention. DO NOT INDUCE VOMITING. If conscious, washout mouth and give water to
drink.
NOTE TO PHYSICIAN :
Probable mucosal damage may contraindicate the use of gastric lavage. Based on the individual reactions of
the patient, the physician's judgement should be used to control symptoms and clinical condition.
FLASH POINT : > 94 °C PMCC
This product would not be expected to burn unless all the water is boiled away. The remaining organics may be
ignitable. Use extinguishing media appropriate for surrounding fire. Keep containers cool by spraying with
water.
2 / 12
PRODUCT
NALCO® EC1005A


May evolve oxides of carbon (COx) under fire conditions. May evolve oxides of nitrogen (NOx) under fire
conditions. Low Fire Hazard; liquids may burn upon heating to temperatures at or above the flash point.

Restrict access to area as appropriate until clean-up operations are complete. Use personal protective
equipment recommended in Section 8 (Exposure Controls/Personal Protection). Stop or reduce any leaks if it is
safe to do so. Ventilate spill area if possible. Ensure clean-up is conducted by trained personnel only. Do not
touch spilled material. Have emergency equipment (for fires, spills, leaks, etc.) readily available. Notify
appropriate government, occupational health and safety and environmental authorities.

container. Wash affected area. LARGE SPILLS: Contain liquid using absorbent material, by digging trenches
or by diking. Reclaim into recovery or salvage drums or tank truck for proper disposal. Clean contaminated
surfaces with water or aqueous cleaning agents. Contact an approved waste hauler for disposal of
contaminated recovered material. Dispose of material in compliance with regulations indicated in Section 13
(Disposal Considerations).
HANDLING :
vapors/gases/dust. Keep the containers closed when not in use. Have emergency equipment (for fires, spills,
leaks, etc.) readily available. Ensure all containers are labeled. Discard contaminated shoes, belts and other
articles made of leather.
Store in suitable labeled containers. Store the containers tightly closed. Store separately from oxidizers.

PVC, Stainless Steel 316L, Hastelloy C-276, Plexiglass, Kalrez, EPDM, PTFE, Teflon, HDPE (high density
polyethylene), Ethylene propylene, Mild steel, Polypropylene, Polyethylene, Carbon Steel C1018, Stainless Steel
304

Copper, Aluminum, Alfax, Brass, Nylon, Buna-N, Natural rubber, Polyurethane, Hypalon, Viton, Neoprene
SPECIFIC USE(S) :
NEUTRALIZING AMINE
3 / 12
PRODUCT
NALCO® EC1005A

Exposure guidelines have not been established for this product. Available exposure limits for the substance(s)
are shown below.

__
AIHA/WEEL Methoxypropylamine TWA 5
STEL 15
AUSTRIA Monoethanolamine MAK 1 2.5

MAK STEL 4 10
Skin*
BELGIUM Monoethanolamine TWA 3 7.6

STEL 6 15
DENMARK Monoethanolamine GV 1 2.5

Skin*
GV 1
Skin*
FINLAND Monoethanolamine HTP 8H 1 2.5

HTP 15MIN 3 7.6
Skin*
FRANCE Monoethanolamine VME 3 8
GERMANY Monoethanolamine MAK 2 5.1

Skin*
IRELAND Monoethanolamine TWA 3 8

STEL 6 15
ITALY Monoethanolamine TWA 3

STEL 6
NETHERLANDS Monoethanolamine MAC 1 2.5

MAC-TGG 3 7.6
15
Skin*
NORWAY Monoethanolamine ADM. NORM 3 8
SPAIN Monoethanolamine VLA-ED 3 7.5

VLA-EC 6 15
Skin*
SWEDEN Monoethanolamine NGV 3 8

KTV 6 15
Skin*
SWITZERLAND Monoethanolamine TWA 2 5

STEL 4 10
UNITED KINGDOM Monoethanolamine TWA 3 7.6

STEL 6 15
POLAND Monoethanolamine MAC-NDS 3

MAC- 10
NDSCh
CZECH REPUBLIC Monoethanolamine PEL 5
4 / 12
PRODUCT
NALCO® EC1005A

NPK-P 10
CROATIA Monoethanolamine MDK 3 8

KDK 6 15
ROMANIA Monoethanolamine TWA 2

STEL 5
SLOVENIA Monoethanolamine TWA 2 5.1

Skin*
the eyes.
A small volume of air is drawn through an absorbant or barrier to trap the substance(s) which can then be
desorbed or removed and analyzed as referenced below:
Methoxypropylamine No method identified
The use of local exhaust ventilation is recommended to control emissions near the source. Laboratory samples
should be handled in a fumehood. Provide mechanical ventilation of confined spaces.
PERSONAL PROTECTION
GENERAL ADVICE :
The use and choice of personal protection equipment is related to the hazard of the product, the workplace and
the way the product is handled. In general, we recommend as a minimum precaution that safety glasses with
inspection.
HAND PROTECTION :
When handling this product, the use of chemical gauntlets is recommended. The choice of work glove depends
on work conditions and what chemicals are handled, but we have positive experience under light handling
conditions using gloves made from PVC Gloves should be replaced immediately if signs of degradation are
observed. Breakthrough time not determined as preparation, consult PPE manufacturers. The applicable
European standard can be found in EN 374.
SKIN PROTECTION :
When handling this product, the use of a chemical resistant suit and rubber boots is recommended. The
applicable European standard can be found in EN 14605 and EN ISO 20345.
5 / 12
PRODUCT
NALCO® EC1005A

EYE PROTECTION :
Wear a face shield with chemical splash goggles. The applicable European standard can be found in EN 166.
Use good work and personal hygiene practices to avoid exposure. Keep an eye wash fountain available. Keep
a safety shower available. If clothing is contaminated, remove clothing and thoroughly wash the affected area.
Launder contaminated clothing before reuse. Always wash thoroughly after handling chemicals. When handling
this product never eat, drink or smoke.
APPEARANCE Clear Light yellow
ODOR Amine
FLASH POINT : > 94 °C PMCC

SPECIFIC GRAVITY 1.0 - 1.04 (16 °C)
pH (100 %) > 11.0
VISCOSITY 42 SUS (38 °C)
MELTING POINT ASTM D-97 -34.3 °C
POUR POINT < -34 °C
BOILING POINT > 93 °C
STABILITY :
None known
Contact with strong acids (e.g. sulfuric, phosphoric, nitric, hydrochloric, chromic, sulfonic) may generate heat,
splattering or boiling and toxic vapors., Contact with strong oxidizers (e.g. chlorine, peroxides, chromates, nitric
acid, perchlorate, concentrated oxygen, permanganate) may generate heat, fires, explosions and/or toxic
vapors., Avoid contact with SO2 or acidic bisulfite products, which may react to form visible airborne amine salt
particles., Certain amines in contact with nitrous acid, organic or inorganic nitrites or atmospheres with high
nitrous oxide concentrations may produce N-nitrosamines, many of which are cancer-causing agents to
laboratory animals.

6 / 12
PRODUCT
NALCO® EC1005A

ACUTE ORAL TOXICITY :

Species LD50 Test Descriptor
Rat 2,500 mg/kg Product
PRIMARY SKIN IRRITATION : Causes burns.
SENSITIZATION :
May cause sensitization by skin contact.
CARCINOGENICITY :
Hygienists (ACGIH).
MUTAGENICITY :
A bacterial mutagenicity (Ames) bioassay was negative for methoxypropylamine.

Species Exposure LC50 NOEC Method Test Descriptor
Fathead Minnow 96 hrs 1,046 mg/l Product

Species Exposure LC50 EC50 Method Test Descriptor
Ceriodaphnia 48 hrs 141 mg/l Product
dubia
MOBILITY :
interface) Suite TM , provided by the US EPA. The model assumes a steady state condition between the total
input and output. The level III model does not require equilibrium between the defined media. The information
provided is intended to give the user a general estimate of the environmental fate of this product under the
defined conditions of the models. If released into the environment this material is expected to distribute to the air,
water and soil/sediment in the approximate respective percentages;

<5% 30 - 50% 50 - 70%
7 / 12
PRODUCT
NALCO® EC1005A

contractor.
EUROPE WASTE CODE :

16 03 05*- OFF SPECIFICATION BATCHES AND UNUSED PRODUCTS - Organic wastes containing
dangerous substances. If this product is used in any further processes, the final user must redefine and assign
the most appropriate European Waste Catalogue Code.
NATIONAL REGULATIONS AUSTRIA :

Waste Code :55352
NATIONAL REGULATIONS FRANCE :

Waste Code :Relevant.
The information in this section is for reference only and should not take the place of a shipping paper (bill of
lading) specific to an order. Please note that the proper Shipping Name / Hazard Class may vary by packaging,
LAND TRANSPORT
Technical Name(s) : Monoethanolamine, Methoxypropylamine
UN/ID No : UN 2735
Packing Group : II
ADR/RID H.I.n. : 80

UN/ID No : UN 2735
8 / 12
PRODUCT
NALCO® EC1005A

Packing Group : II
IATA Passenger Aircraft Limit : 0.5 L / 1 L

UN/ID No : UN 2735
Packing Group : II

EMERGENCY ACTION CODE : 2X

HAZARD SYMBOLS
CORROSIVE
Contains:..Monoethanolamine Methoxypropylamine
RISK PHRASES
R34 - Causes burns.
SAFETY PHRASES
S23 - Do not breathe vapor.
S45 - In case of accident or if you feel unwell, seek medical advice immediately (show the label where possible).
NATIONAL REGULATIONS DENMARK

MAL CODE No No
FIRE CLASS Non-regulated. Non-regulated.
ORGANIC SOLVENTS/VOCS No No
9 / 12
PRODUCT
NALCO® EC1005A

SUSPECT CARCINOGENS No No

Table of occupational diseases, Article L461-4. Social Security Code- Decree 11/2/2003: Relevant, see
table(s): 49, 49 bis
Special medical supervision - Decree of 11 July 1977: Relevant.
Work Restrictions:
Fair labor standards act, Article R234-9 and 10 (women): Not-applicable.
Fair labor standards act, Article R234-16, 20 and 21 (young workers): Relevant.
Fair labor standards act, Decree of the 8/10/90 (temporary work and contract last given): Not-applicable.
Classified Industrial Sites (ICPE): Not-applicable. Water Discharge: Relevant.

WGK 1 (Annex 4)
NATIONAL REGULATIONS HOLLAND

ABM RESULT
ABM RESULT Substance(s) % (w/w)
9B

Denmark 1650831
Denmark 1650831
Norway 085004

EUROPE
Should you require any further information on Nalco's REACH programme please contact us at
reach@nalco.com or visit our website.
UNITED STATES
CANADA :
JAPAN
Substances and are listed on the Ministry of International Trade & industry List (MITI).
10 / 12
PRODUCT
NALCO® EC1005A


R10 - Flammable.
R34 - Causes burns.
R35 - Causes severe burns.
R36/37/38 - Irritating to eyes, respiratory system and skin.
R52 - Harmful to aquatic organisms.
- 2, 3, 15, 16
-4
-7
- 11
Denmark +47-22-33-69-99
Finland +358-(0)9-4711
Hungary +36-30-9-506-447
Norway +47-22-33-69-99
Poland +48-(0)601-66-2626
Portugal +351-91-911-1399
Saudi Arabia +966-(3)847-1515
Spain +34-977-551577
Sweden +47-22-33-69-99
UAE +44-(0)7071-223-738
Belgium +32-70-245245
France +33-(0)145-42-59-59 ORFILA
11 / 12
PRODUCT
NALCO® EC1005A


Numbers quoted in the MSDS are given in the format: 1,000,000 = 1 million and 1,000 = 1 thousand. 0.1 = 1
tenth and 0.001 = 1 thousandth
12 / 12
SAFETY DATA SHEET
PRODUCT
FORTIS® EC3071A


COMPANY/UNDERTAKING
PRODUCT NAME : FORTIS® EC3071A
APPLICATION : PROCESS ANTIFOULANT

Postbus 627


NALCO AB (SE) +46 (0)8-50074000 NALCO POLSKA Sp.z.o.o. (PL) PRZEMYSLOWA 55
PL-43-110 TYCHY
TEL:+48 (0)32-3262750
FAX: +48(0)32 329 13 11
(P)
OF EUROPE BV
(D) (CH)
Ges.m.b.H. (A)
50
Kft. (HU)
(HR)
Office ROMANIA (RO)
Flammable. Harmful by inhalation and in contact with skin. Irritating to eyes and skin. Harmful to aquatic
organisms, may cause long-term adverse effects in the aquatic environment.
1 / 16
SAFETY DATA SHEET
PRODUCT
FORTIS® EC3071A

INHALATION :
Repeated or prolonged exposure may irritate the respiratory tract.
SKIN CONTACT :
Can cause moderate irritation. Harmful if absorbed through skin.
EYE CONTACT :
Can cause mild irritation.
INGESTION :
Not a likely route of exposure. There may be irritation to the gastro-intestinal tract. May cause nausea and
vomiting. Can cause chemical pneumonia if aspirated into lungs following ingestion. Can cause central nervous
system depression.

experimental animals and inadequate evidence in humans).
Keep out of waterways. This product may pose a risk to the aquatic ecosystem if released.

Flammable.

ELINCS NO NOTAS
Xylene 215-535-7 1330-20-7 Xn R10, R20/21, 30 - 60
R38 Nota C
Substituted phenol Proprietary Proprietary Xi R36, R52/53 10 - 30
Isobutanol 201-148-0 78-83-1 Xi R10, R37/38, 1- 5
R41, R67
Ethylbenzene 202-849-4 100-41-4 F, Xn R11, R20 10 - 30
INHALATION :
SKIN CONTACT :
Immediately wash with plenty of soap and water. If symptoms develop, seek medical advice.
EYE CONTACT :
Get medical attention. Immediately flush eye with water for at least 15 minutes while holding eyelids open.
2 / 16
SAFETY DATA SHEET
PRODUCT
FORTIS® EC3071A

INGESTION :
Get medical attention. Do not induce vomiting: contains petroleum distillates and/or aromatic solvents. If
conscious, washout mouth and give water to drink.
NOTE TO PHYSICIAN :
Based on the individual reactions of the patient, the physician's judgement should be used to control symptoms
and clinical condition.


Flammable Liquid; may release vapors that form flammable mixtures at or above the flash point. Vapors can travel
to a source of ignition and flash back. Empty product containers may contain product residue. Do not pressurize,
cut, heat, weld, or expose containers to flame or other sources of ignition. May evolve oxides of carbon (COx)
under fire conditions.

Ventilate spill area if possible. Remove sources of ignition. Ensure clean-up is conducted by trained personnel
only. Do not touch spilled material. Have emergency equipment (for fires, spills, leaks, etc.) readily available.
Notify appropriate government, occupational health and safety and environmental authorities.

by diking. Reclaim into recovery or salvage drums or tank truck for proper disposal. Clean contaminated surfaces
with water or aqueous cleaning agents. Contact an approved waste hauler for disposal of contaminated recovered
Prevent material from entering sewers or waterways. This product may pose a risk to the aquatic ecosystem if
released.
3 / 16
SAFETY DATA SHEET
PRODUCT
FORTIS® EC3071A

HANDLING :
leaks, etc.) readily available. Ensure all containers are labeled. Do not use, store, spill or pour near heat, sparks or
open flame.
Store in suitable labeled containers. Store the containers tightly closed. Store away from heat and sources of
ignition. Have appropriate fire extinguishers available in and near the storage area. Connections must be
grounded to avoid electrical charges. Store separately from oxidizers.

Viton, Carbon Steel C1018, Stainless Steel 304, Stainless Steel 316L, MDPE (medium density polyethylene),
Perfluoroelastomer, PTFE, FEP (encapsulated), Surface-modified HDPE (high density polyethylene)

Neoprene, Nitrile, EPDM, TFE, HDPE (high density polyethylene)
SPECIFIC USE(S) :
PROCESS ANTIFOULANT
shown below.
AUSTRIA Xylene MAK 50 221
MAK STEL 100 442
Skin*
2,6-Di-tert-Butyl-4-Methylphenol MAK 10
Isobutanol MAK 50 150

MAK STEL 200 600
Ethylbenzene MAK 100 440

MAK CEIL 200 880
Skin*
BELGIUM Xylene TWA 50 221

STEL 100 442
Skin*
2,6-Di-tert-Butyl-4-Methylphenol TWA 10
Isobutanol TWA 50 154
Ethylbenzene TWA 100 442

STEL 125 551
Skin*
4 / 16
SAFETY DATA SHEET
PRODUCT
FORTIS® EC3071A

BULGARIA Xylene TWA 221

STEL 442
Skin*
STEL 50
Ethylbenzene TWA 435

STEL 545
Skin*
DENMARK Xylene GV 25 109

Skin*
GV 25
Skin*
2,6-Di-tert-Butyl-4-Methylphenol GV 10
Isobutanol LOFT 50 150

Skin*
LOFT 50
Skin*
Ethylbenzene GV 50 217
GV 50
FINLAND Xylene HTP 8H 50 220

HTP 15MIN 100 440
Skin*
2,6-Di-tert-Butyl-4-Methylphenol HTP 8H 10
HTP 15MIN 20
Isobutanol HTP 8H 50 150

HTP 15MIN 75 230
Skin*
Ethylbenzene HTP 8H 50 220

HTP 15MIN 200 880
Skin*
FRANCE Xylene Skin*

VME 50 221
VLE 100 442
2,6-Di-tert-Butyl-4-Methylphenol VME 10
Isobutanol VME 50 150
Ethylbenzene Skin*
VME 20 88.4
VLE 100 442
GERMANY Xylene AGW 100 440

Skin*
2,6-Di-tert-Butyl-4-Methylphenol (Inhalable fraction.) MAK 20
Isobutanol AGW 100 310
Ethylbenzene AGW 100 440

Skin*
IRELAND Xylene TWA 50 221

STEL 100 442
Skin*
5 / 16
SAFETY DATA SHEET
PRODUCT
FORTIS® EC3071A


STEL 75 225

STEL 125 545
Skin*
ITALY Xylene TWA 50 221

STEL 100 442
Skin*
2,6-Di-tert-Butyl-4-Methylphenol (Inhalable fraction and vapor.) TWA 2
Isobutanol TWA 50

STEL 200 884
Skin*
NETHERLANDS Xylene TGG 210

TGG 15 442
Skin*
Ethylbenzene TGG 215

Skin*
TGG 15 430
NORWAY Xylene ADM. NORM 25 108

Skin*
Isobutanol CEIL 25 75
Skin*
Ethylbenzene ADM. NORM 5 20

Skin*
SPAIN Xylene VLA-ED 50 221

VLA-EC 100 442
Skin*
Isobutanol VLA-ED 50 154
Ethylbenzene VLA-ED 100 441

VLA-EC 200 884
Skin*
SWEDEN Xylene NGV 50 200

KTV 100 450
Skin*
Isobutanol NGV 50 150

KTV 75 250
Skin*
Ethylbenzene NGV 50 200

KTV 100 450
SWITZERLAND Xylene TWA 100 435

STEL 200 870
Skin*
2,6-Di-tert-Butyl-4-Methylphenol (Inhalable dust) TWA 10

STEL 50 150
6 / 16
SAFETY DATA SHEET
PRODUCT
FORTIS® EC3071A


STEL 100 435
Skin*
UNITED KINGDOM Xylene TWA 50 220

STEL 100 441
Skin*

STEL 75 231

STEL 125 552
Skin*
POLAND Xylene MAC-NDS 100
Isobutanol MAC-NDS 100

MAC-NDSC 200
h
Ethylbenzene MAC-NDS 100

MAC-NDSC 350
h
HUNGARY Xylene ÁK 221

CK 442
Skin*
Ethylbenzene ÁK 442
CK 884
Skin*
LATVIA Xylene TWA 50 221

STEL 100 442
Skin*
Isobutanol TWA 10

STEL 200 884
Skin*
CZECH REPUBLIC Xylene PEL 200

NPK-P 400
Skin*
Isobutanol PEL 300

NPK-P 600
Skin*
Ethylbenzene PEL 200

NPK-P 500
Skin*
CROATIA Xylene MDK 100 440

KDK 150 655
2,6-Di-tert-Butyl-4-Methylphenol MDK 10
Isobutanol MDK 100 300
Ethylbenzene MDK 100 440

Skin*
7 / 16
SAFETY DATA SHEET
PRODUCT
FORTIS® EC3071A

ROMANIA Xylene TWA 50 221

STEL 100 442
Skin*

STEL 66 200

STEL 200 884
Skin*
RUSSIAN Xylene (Vapour.) TWA 50

FEDERATION
CEIL 150
Isobutanol (Vapour.) CEIL 10
Ethylbenzene (Vapour.) TWA 50

CEIL 150
SERBIA Xylene MAC 100 435

Skin*
2,6-Di-tert-Butyl-4-Methylphenol MAC 10
Isobutanol MAC 50 150
Ethylbenzene MAC 100 435
SLOVAKIA Xylene TWA 50 221

CEILING 442
Skin*

CEILING 884
Skin*
SLOVENIA Xylene TWA 50 221

STEL MULT
Skin*
2,6-Di-tert-Butyl-4-Methylphenol (Inhalable fraction.) TWA 10

STEL MULT

STEL MULT
Skin*
the eyes.
Xylene US NIOSH: 1501 Gas chromatography Charcoal
8 / 16
SAFETY DATA SHEET
PRODUCT
FORTIS® EC3071A

2,6-Di-tert-Butyl-4-Methylphenol No method identified
Isobutanol US NIOSH: 1401 Gas chromatography Charcoal
Ethylbenzene US NIOSH: 1501 Gas chromatography Charcoal
BIOLOGICAL EXPOSURE INDICES :

Ethylbenzene
A biological index of exposure to ethyl benzene (CAS 100-41-4) is the detection of ethyl benzene in the blood post
shift (Germany, 1mg/l). Another biological index is the detection of mandelic acid in the urine post shift (USA,
1.5g/g creatinine; Findland, 5.2mmol/l; Germany 800mg/g creatinine) and the detection of phenylglyoxylic acid in
urine post shift (Germany, 800mg/g creatinine).
General ventilation is recommended. The use of local exhaust ventilation is recommended to control emissions
near the source. Laboratory samples should be handled in a fumehood. Provide mechanical ventilation of
confined spaces.
PERSONAL PROTECTION
GENERAL ADVICE :
chemicals being handled. Consider the use of filter type: A-P The applicable European standard can be found in
EN 140, EN 137, EN 143 and EN 14387. In event of emergency or planned entry into unknown concentrations a
positive pressure, full-facepiece SCBA should be used. If respiratory protection is required, institute a complete
respiratory protection program including selection, fit testing, training, maintenance and inspection.
HAND PROTECTION :
SKIN PROTECTION :
When handling this product, the use of overalls, a chemical resistant apron and rubber boots is recommended.
The applicable European standard can be found in EN ISO 20345.
9 / 16
SAFETY DATA SHEET
PRODUCT
FORTIS® EC3071A

EYE PROTECTION :
When handling this product, the use of splash chemical goggles is recommended. The applicable European
safety shower available. If clothing is contaminated, remove clothing and thoroughly wash the affected area.
ENVIRONMENTAL EXPOSURE CONTROL PRECAUTIONS :

Consider the provision of containment around storage vessels.
APPEARANCE Clear Yellow
ODOR Aromatic

SPECIFIC GRAVITY 0.89 (15.6 °C)
VISCOSITY Calculated 1 cst (38 °C)
VISCOSITY Calculated 0.75 cst (66 °C)
INITIAL BOILING POINT 135.9 °C
VAPOR PRESSURE 1.86 kPa (37.8 °C)
STABILITY :
permanganate) may generate heat, fires, explosions and/or toxic vapors., Contact with strong alkalies (e.g.
ammonia and its solutions, carbonates, sodium hydroxide (caustic), potassium hydroxide, calcium hydroxide
(lime), cyanide, sulfide, hypochlorites, chlorites) may generate heat, splattering or boiling and toxic vapors.

Under fire conditions: Oxides of carbon
10 / 16
SAFETY DATA SHEET
PRODUCT
FORTIS® EC3071A

SENSITIZATION :
CARCINOGENICITY :
MOBILITY :

5 - 10% 30 - 50% 50 - 70%
The organic portion of this preparation is expected to be inherently biodegradable.
Component substances have a potential to bioaccumulate.
11 / 16
SAFETY DATA SHEET
PRODUCT
FORTIS® EC3071A

contractor.
EUROPE WASTE CODE :


Waste Code :55327

NATIONAL REGULATIONS POLAND :

Waste Code: Regulations of 27 September 2001, Waste catalogue, J. of Laws No. 112, item 1206
Do not dispose into a local sewage system or with normal household waste. Do not dispose into municipal drains,
sewers, soil, natural streams or rivers.The waste product should be disposed of at an authorised incineration plant
or a waste treatment/disposal plant in line with the existing regulations (Act of 27 April 2001 on Waste,
consolidated text annexed to the J. of Laws No. 39, item 251 of 2007). The product incineration produces ash. The
product may be incinerated directly using suitable equipment.
Reclamation, recycling and disposal of packaging waste should comply with the existing regulations (Act of 11 May
2001 on Packaging and Packaging Waste, J. of Laws No. 63, item 638, as amended).
Use the services of appropriately authorised businesses.
Decree about waste of 27.04.2001 (DZ.U nr.62 item 628 with later changes Dz U 2003,nr 7 item 78.
LAND TRANSPORT
Technical Name(s) : Xylene, Ethylbenzene
UN/ID No : UN 1993
Packing Group : III
ADR/RID H.I.n. : 30
CLASSIFICATION CODE : F1

UN/ID No : UN 1993
Packing Group : III
IATA Passenger Aircraft Limit : 10 L / 60 L
12 / 16
SAFETY DATA SHEET
PRODUCT
FORTIS® EC3071A


UN/ID No : UN 1993
Packing Group : III
*Marine Pollutant : Substituted phenol

CEFIC TREMCARD REFERENCE : 30GF1-III
EMERGENCY ACTION CODE : 3[Y]

HAZARD SYMBOLS
HARMFUL
Contains:..Xylene
RISK PHRASES
R10 - Flammable.
R20/21 - Harmful by inhalation and in contact with skin.
R36/38 - Irritating to eyes and skin.
R52/53 - Harmful to aquatic organisms, may cause long-term adverse effects in the aquatic environment.
SAFETY PHRASES
S36/37 - Wear suitable protective clothing and gloves.
S57 - Use appropriate containment to avoid environmental contamination.
NATIONAL REGULATIONS AUSTRIA

Danger classification according to VbF: A II

4 Bis, 84
13 / 16
SAFETY DATA SHEET
PRODUCT
FORTIS® EC3071A

Dangerous or Poisonous Substances and Preparations: Relevant.

Work Restrictions:
Classified Industrial Sites (ICPE): Relevant. Headings: 1433, 1434, 1432B
Water Discharge: Relevant.

WGK 2 (Annex 4)
NATIONAL REGULATIONS POLAND

Act of 11 January 2001 on Chemical Substances and Preparations (J. of Laws No. 11, item 84, J. of Laws No. 100,
item 1085, J. of Laws No. 123, item 1350 and J. of Laws No. 125, item 1367 and of 2002 J. of Laws No. 135, item
1145 and No. 142, item 1187; of 2003 J. of Laws No. 189, item 1852; of 2004 J. of Laws No. 96, item 959 and J. of
Laws No. 121, item 1263; of 2005 J. of Laws No. 179, item 1485; of 2006 J. of Laws No. 171, item 1225)
Regulation of the Minister of Health of 28 September 2005 on the List of Hazardous Substances with Classification
and Labelling (J. of Laws, No. 201, item 1674)
Regulation (EC) No. 1907/2006 of the European Parliament and of the Council of 18 December 2006 concerning
the Registration, Evaluation, Authorisation and Restriction of Chemicals (REACH), establishing a European
Chemicals Agency, amending Directive 1999/45/EC and repealing Council Regulation (EEC) No. 793/93 and
Commission Regulation (EC) No 1488/94 as well as Council Directive 76/769/EEC and Commission Directives
91/155/EEC, 93/67/EEC, 93/105/EC and 2000/21/EC (Corrigendum, OJ L 136 of 29.5.2007)
Decree of Health Ministry of 13.11.2007 about MSDS (Dz.U nr.215 item 1588).
Regulation of the Minister of Health of 2 September 2003 on Criteria and Methods for Classification of Chemical
Substances and Preparations (J. of Laws No. 171, item 1666; of 2004 J. of Laws No. 243, item 2440; of 2007 J. of
Laws No. 174, item 1222)
Regulation of the Minister of Health of 2 September 2003 on Package Labelling of Hazardous Substances and
Hazardous Preparations (J. of Laws No. 173, item 1679; of 2004 J. of Laws No. 260, item 2595)
Regulation of the Minister of Labour and Social Policy of 29 November 2002 on Workplace Concentration and
Exposure Limits Applicable to Health Hazards (J. of Laws No. 217, item. 1833; of 2005 J. of Laws No. 212, item
1769; of 2007 J. of Laws No. 161, item 1142)
Regulation of the Minister Health of 20 April 2005 on Tests and Measurements of Workplace Health Hazards (J. of
Laws No. 73, item. 645)
Regulation of the Minister of Economy of 21 December 2005 on Fundamental Requirements for Personal
Protection Equipment (J. of Laws No. 259, item 2173)
Regulation of the Minister of Labour and Social Policy of 26 September 1997 on General Health and Safety
Provisions (consolidated text of 2003 J. of Laws No. 169, item 1650; of 2007 J. of Laws No. 49, item 330)
Regulation of the Minister of Health of 30 December 2004 on Health and Safety Related to Exposure to Chemical
Factors at Workplace (J. of Laws No. 11, item 86 of 2005)
Goverment Statement of 23.03.2007 concerning the changes in attachment A and B to European agremment
regarding international transport the dangerous products (ADR ) issue in Geneva of 30.09.1957 ( Dz. U nr.99
item.667).
Decree of Industry Ministry of 21.02.2005 change the decree of production, using and turnover of dangerous
products and substance contents the dangerous substance (DZ.U nr.39,poz.372 from 2005 with later changes).
14 / 16
SAFETY DATA SHEET
PRODUCT
FORTIS® EC3071A

EUROPE
UNITED STATES :
CANADA :
The substances in this preparation are listed on the Domestic Substances List (DSL), are exempt, or have been
reported in accordance with the New Substances Notification Regulations.
JAPAN

R10 - Flammable.
R11 - Highly flammable.
R20 - Harmful by inhalation.
R36 - Irritating to eyes.
R37/38 - Irritating to respiratory system and skin.
R38 - Irritating to skin.
R41 - Risk of serious damage to eyes.
R67 - Vapours may cause drowsiness and dizziness.
-7
15 / 16
SAFETY DATA SHEET
PRODUCT
FORTIS® EC3071A

Bulgaria +32-(0)3-575-5555
Croatia +385 (0)91-1-25-75-23
Denmark +47-22-33-69-99
Finland +358-(0)9-471 977
Hungary +36-30-9-506-447
Latvia +32-(0)3-575-5555
Norway +47-22-33-69-99
Poland +48-(0)601-66-2626 (SGS) / +48 (0) 14 637 40 81 (SPOT)
Portugal +351-91-911-1399
Romania +40-744 -34-14-53
Saudi Arabia +966-(3)847-1515
Serbia +32-(0)3-575-5555
Slovenia +386-41-634-916
Spain +34-977-551577
Sweden +47-22-33-69-99
UAE +44-(0)7071-223-738
Belgium +32-70-245245
France +33-(0)145-42-59-59 ORFILA

16 / 16
SAFETY DATA SHEET
PRODUCT
ACTRENE® EC3214A


COMPANY/UNDERTAKING
PRODUCT NAME : ACTRENE® EC3214A

Postbus 627


PL-43-110 TYCHY
TEL:+48 (0)32-3262750
FAX: +48(0)32 329 13 11
(P)
OF EUROPE BV
(D) (CH)
Ges.m.b.H. (A)
50
Kft. (HU)
(HR)
Office ROMANIA (RO)
1 / 15
SAFETY DATA SHEET
PRODUCT
ACTRENE® EC3214A

Flammable. Harmful by inhalation. Limited evidence of a carcinogenic effect. Toxic to aquatic organisms, may
cause long-term adverse effects in the aquatic environment. Harmful: may cause lung damage if swallowed.
Repeated exposure may cause skin dryness or cracking. Vapours may cause drowsiness and dizziness.
INHALATION :
Harmful if inhaled. Product mist or vapors may cause headache, nausea, vomiting, drowsiness, stupor or
unconsciousness.
SKIN CONTACT :
Frequent or prolonged contact with product may defat and dry the skin, leading to discomfort and dermatitis.
EYE CONTACT :
May cause irritation with prolonged contact.
INGESTION :

Harmful to aquatic organisms. Keep out of waterways.

Flammable.

ELINCS NO NOTAS
Heavy Aromatic Naphtha 265-198-5 64742-94-5 Xn, N R51/53, R65, 60 - 100
R66, R67
Aliphatic alcohol Proprietary Proprietary Xn R10, R20 10 - 30
Naphthalene 202-049-5 91-20-3 Xn, N R22, R40, 5 - 10
R50/53
Substituted alkylamine Proprietary Proprietary Xn, Xi R20/21/22, 1- 5
R36/38
1,2,4-Trimethylbenzene 202-436-9 95-63-6 Xn, N R10, R20, 1- 5
R36/37/38,
R51/53
Alkyl-N-heterocycle Proprietary Proprietary Xn R22, R52/53 1- 5
Isoamyl Alcohol 204-633-5 123-51-3 Xn R10, R20 Nota C 1- 5
C12-C14 Tert-Alkyl Primary Amine 273-279-1 68955-53-3 T, C, N R22, R23/24, <1
R34, R43,
R48/23, R50
2 / 15
SAFETY DATA SHEET
PRODUCT
ACTRENE® EC3214A

INHALATION :
SKIN CONTACT :
EYE CONTACT :
INGESTION :
NOTE TO PHYSICIAN :


contain product residue. Do not pressurize, cut, heat, weld, or expose containers to flame or other sources of
ignition. May evolve oxides of carbon (COx) under fire conditions. May evolve oxides of nitrogen (NOx) under fire
conditions.


3 / 15
SAFETY DATA SHEET
PRODUCT
ACTRENE® EC3214A

Harmful to aquatic organisms. Prevent material from entering sewers or waterways.
HANDLING :
leaks, etc.) readily available. Ensure all containers are labeled. Do not use, store, spill or pour near heat, sparks or
open flame.

Viton, Carbon Steel C1018, Stainless Steel 304, Stainless Steel 316L, PTFE

HDPE (high density polyethylene), Neoprene, MDPE (medium density polyethylene), Nitrile, EPDM, TFE
SPECIFIC USE(S) :
PROCESS ANTIFOULANT
shown below.
Manufacturer's Heavy Aromatic Naphtha TWA 100

Recommendation
AUSTRIA Naphthalene MAK 10 50

Skin*
Isoamyl Alcohol MAK 100 360

MAK STEL 200 720
Trimethylbenzene MAK 20 100

MAK STEL 30 150
BELGIUM Naphthalene TWA 10 53

STEL 15 80
Skin*
Isoamyl Alcohol TWA 100 366
4 / 15
SAFETY DATA SHEET
PRODUCT
ACTRENE® EC3214A

STEL 125 459
Trimethylbenzene TWA 20 100
BULGARIA Naphthalene TWA 50

STEL 75
Isoamyl Alcohol TWA 360

STEL 450
DENMARK Naphthalene GV 10 50
Isoamyl Alcohol GV 100 360

GV 100
Trimethylbenzene GV 25 120
GV 25
FINLAND Naphthalene HTP 8H 1 5

HTP 15MIN 2 10
Isoamyl Alcohol HTP 8H 100 370

HTP 15MIN 150 550
Trimethylbenzene HTP 8H 20 100
FRANCE Naphthalene VME 10 50
Isoamyl Alcohol VME 100 360
GERMANY Naphthalene Skin*
Isoamyl Alcohol MAK 20 73

PEAK CAT
IRELAND Naphthalene TWA 10 50

STEL 15 75

STEL 125 450

Skin*
ITALY Naphthalene TWA 10 50

STEL 125
Trimethylbenzene TWA 25
NETHERLANDS Naphthalene TGG 50

TGG 15 80
NORWAY Naphthalene ADM. NORM 10 50
Isoamyl Alcohol ADM. NORM 50 180
Trimethylbenzene ADM. NORM 20 100
SPAIN Naphthalene VLA-ED 10 53

VLA-EC 15 80
Skin*
Isoamyl Alcohol VLA-ED 100 366
5 / 15
SAFETY DATA SHEET
PRODUCT
ACTRENE® EC3214A

VLA-EC 125 458
SWEDEN Naphthalene NGV 10 50

KTV 15 80
Trimethylbenzene NGV 25 120

KTV 35 170
SWITZERLAND Naphthalene TWA 10 50

Skin*

STEL 200 720

STEL 40 200
UNITED KINGDOM Isoamyl Alcohol TWA 100 366

STEL 125 458
POLAND Naphthalene MAC-NDS 20

MAC-NDSC 50
h
Isoamyl Alcohol MAC-NDS 200

MAC-NDSC 400
h
Trimethylbenzene MAC-NDS 100

MAC-NDSC 170
h
HUNGARY Naphthalene ÁK 50
Skin*
Isoamyl Alcohol ÁK 360

CK 1,440
LATVIA Naphthalene TWA 10 50
CZECH REPUBLIC Naphthalene PEL 50

NPK-P 100
Isoamyl Alcohol PEL 300

NPK-P 600
Skin*
Heavy Aromatic Naphtha PEL 200

NPK-P 1,000
CROATIA Naphthalene MDK 10 50

KDK 15 75
Isoamyl Alcohol MDK 100 360

KDK 125 450
Trimethylbenzene MDK 25 125
ROMANIA Naphthalene TWA 9.5 50

STEL 200
6 / 15
SAFETY DATA SHEET
PRODUCT
ACTRENE® EC3214A

RUSSIAN Naphthalene (Vapour.) CEIL 20

FEDERATION
Isoamyl Alcohol (Vapour.) CEIL 5
SERBIA Naphthalene MAC 10 50
Isoamyl Alcohol MAC 100 360
Trimethylbenzene MAC 25 125
SLOVAKIA Naphthalene TWA 10 50

Skin*
SLOVENIA Naphthalene TWA 10 50

STEL MULT
the eyes.
Naphthalene US NIOSH: 1501 Gas chromatography Charcoal
Isoamyl Alcohol US NIOSH: 1402 Gas chromatography Charcoal
Heavy Aromatic Naphtha US NIOSH: 1550 Gas chromatography Charcoal

Heavy Aromatic Naphtha
A biological index of exposure to aromatic petroleum solvent, xylene based, is the detection of total xylene in the
blood post shift (Germany, 1.5 mg/l), or the detection of methylhippuric acid in the urine post shift (USA, 1.5g/g
creatinine; Germany, 2g/l).
General ventilation is recommended.
PERSONAL PROTECTION
GENERAL ADVICE :
7 / 15
SAFETY DATA SHEET
PRODUCT
ACTRENE® EC3214A

HAND PROTECTION :
SKIN PROTECTION :
EYE PROTECTION :

APPEARANCE Clear Red Orange
ODOR Aromatic

MELTING POINT -30 °C
STABILITY :
8 / 15
SAFETY DATA SHEET
PRODUCT
ACTRENE® EC3214A


SENSITIZATION :
The following substance present at very low concentrations, may precipitate an allergic reaction in sensitive
individuals: C12-C14 Tert-Alkyl Primary Amine
CARCINOGENICITY :
The following values are estimated based on known component toxicity.

Fish 96 hrs 8.8 mg/l Product (estimated)

Crustacean 48 hrs 9.9 mg/l Product (estimated)
MOBILITY :
9 / 15
SAFETY DATA SHEET
PRODUCT
ACTRENE® EC3214A


10 - 30% 50 - 70% 10 - 30%
burned directly in appropriate equipment. This product is NOT suitable for disposal by either landfill or via
municipal sewers, drains, natural streams or rivers.
contractor.
EUROPE WASTE CODE :

NATIONAL REGULATIONS CZECH REPUBLIC

Valid and applicable waste legislation in the Czech Republic: Waste Act (No. 185/2001 Coll.), Packaging Act (No.
477/2001 Coll.) and the Decree of the Ministry of the Environment on the Catalogue of Wastes (No. 381/2001
Coll.), as amended

10 / 15
SAFETY DATA SHEET
PRODUCT
ACTRENE® EC3214A

LAND TRANSPORT
Technical Name(s) : 1,2,4-Trimethylbenzene, Aliphatic alcohol
UN/ID No : UN 1993
Packing Group : III
ADR/RID H.I.n. : 30

UN/ID No : UN 1993
Packing Group : III

UN/ID No : UN 1993
Packing Group : III


HAZARD SYMBOLS
11 / 15
SAFETY DATA SHEET
PRODUCT
ACTRENE® EC3214A

HARMFUL DANGEROUS FOR THE

ENVIRONMENT
Contains:..Heavy Aromatic Naphtha Naphthalene
RISK PHRASES
R10 - Flammable.
R40 - Limited evidence of a carcinogenic effect.
R51/53 - Toxic to aquatic organisms, may cause long-term adverse effects in the aquatic environment.
R65 - Harmful: may cause lung damage if swallowed.
R66 - Repeated exposure may cause skin dryness or cracking.
The following substance present at very low concentrations, may precipitate an allergic reaction in sensitive
individuals: C12-C14 Tert-Alkyl Primary Amine
SAFETY PHRASES
S37/39 - Wear suitable gloves and eye/face protection.
S62 - If swallowed, do not induce vomiting: seek medical advice immediately and show this container or label.

This preparation is classified as per Act on Chemical Substances and Chemical Preparations (No. 356/2003 Coll.)
This Safety Data Sheet is drawn up as per Act No. 356/2003 Coll. and Decree 231/2004 Coll. on detailed
particulars of safety data sheet
Occupational exposure limits for the Czech Republic in section 8 are given as per Government's Regulation No.
178/2001 Coll. laying down conditions of health protection of employees at work

4 Bis, 15, 15 Bis, 15 Ter, 4
Classified Industrial Sites (ICPE): Relevant. Headings: 1430, 1433, 1173, 1432B

WGK 2 (Annex 4)
NATIONAL REGULATIONS NORWAY

12 / 15
SAFETY DATA SHEET
PRODUCT
ACTRENE® EC3214A

item.667).

52-FZ.
August 1993 N 5600-1.
requirements).

Norway 090802

EUROPE
13 / 15
SAFETY DATA SHEET
PRODUCT
ACTRENE® EC3214A

UNITED STATES :
CANADA :
This product contains substance(s) which are not listed on the Domestic Substances List (DSL) or the
Non-Domestic Substances List (NDSL).
JAPAN

R10 - Flammable.
R22 - Harmful if swallowed.
R23/24 - Toxic by inhalation and in contact with skin.
R34 - Causes burns.
R48/23 - Toxic: danger of serious damage to health by prolonged exposure through inhalation.
R50 - Very toxic to aquatic organisms.
R50/53 - Very toxic to aquatic organisms, may cause long-term adverse effects in the aquatic environment.
- 2, 3, 15, 16
14 / 15
SAFETY DATA SHEET
PRODUCT
ACTRENE® EC3214A

Bulgaria +32-(0)3-575-5555
Croatia +385 (0)91-1-25-75-23
Denmark +47-22-33-69-99
Finland +358-(0)9-471 977
Hungary +36-30-9-506-447
Latvia +32-(0)3-575-5555
Norway +47-22-33-69-99
Poland +48-(0)601-66-2626 (SGS) / +48 (0) 14 637 40 81 (SPOT)
Portugal +351-91-911-1399
Romania +40-744 -34-14-53
Saudi Arabia +966-(3)847-1515
Serbia +32-(0)3-575-5555
Slovenia +386-41-634-916
Spain +34-977-551577
Sweden +47-22-33-69-99
UAE +44-(0)7071-223-738
Belgium +32-70-245245
France +33-(0)145-42-59-59 ORFILA

15 / 15
SAFETY DATA SHEET
PRODUCT
ACTRENE® EC3269A


COMPANY/UNDERTAKING
PRODUCT NAME : ACTRENE® EC3269A
APPLICATION : ANTIFOULANT

Postbus 627


PL-43-110 TYCHY
TEL:+48 (0)32-3262750
FAX: +48(0)32 329 13 11
(P)
OF EUROPE BV
(D) (CH)
Ges.m.b.H. (A)
50
Kft. (HU)
(HR)
Office ROMANIA (RO)
1 / 14
SAFETY DATA SHEET
PRODUCT
ACTRENE® EC3269A

Flammable. Harmful by inhalation. Irritating to eyes, respiratory system and skin. Limited evidence of a
carcinogenic effect. May cause sensitization by skin contact. Toxic to aquatic organisms, may cause long-term
adverse effects in the aquatic environment. Harmful: may cause lung damage if swallowed.
INHALATION :
Repeated or prolonged exposure may irritate the respiratory tract. Inhalation of product mist or vapors may cause
respiratory allergy.
SKIN CONTACT :
Can cause moderate irritation. Repeated or prolonged contact may cause skin sensitization.
EYE CONTACT :
Can cause severe irritation.
INGESTION :

Keep out of waterways.

Flammable.

ELINCS NO NOTAS
Heavy Aromatic Naphtha 265-198-5 64742-94-5 Xn, N R51/53, R65, 60 - 100
R66, R67
Naphthalene 202-049-5 91-20-3 Xn, N R22, R40, 5 - 10
R50/53
N,N'-Di-Sec-Butyl-1,4-Phenylenediamin 202-992-2 101-96-2 T, C, N R22, R23, R34, 1- 5
e R43, R50/53
1,2,4-Trimethylbenzene 202-436-9 95-63-6 Xn, N R10, R20, 1- 5
R36/37/38,
R51/53
Substituted phenol Proprietary Proprietary Xi, N R36/37/38, 1- 5
R51/53
Substituted phenol Proprietary Proprietary Xi, N R36/37/38, 0.1 - 1
R50/53
Substituted phenol Proprietary Proprietary Xi, N R36/37/38, 1- 5
R50/53
Substituted alkylamine Proprietary Proprietary F-, Xn, Xi R10, R20/21, 10 - 30
R36/37/38
2 / 14
SAFETY DATA SHEET
PRODUCT
ACTRENE® EC3269A

INHALATION :
SKIN CONTACT :
Immediately wash with plenty of soap and water. Get medical attention.
EYE CONTACT :
Immediately flush eye with water for at least 15 minutes while holding eyelids open. Get medical attention.
INGESTION :
Do not induce vomiting: contains petroleum distillates and/or aromatic solvents. If conscious, washout mouth and
give water to drink. Get medical attention.
NOTE TO PHYSICIAN :
FLASH POINT : 53.9 °C
Alcohol foam, Carbon dioxide, Foam, Dry powder, Other extinguishing agent suitable for Class B fires, For large
fires, use water spray or fog, thoroughly drenching the burning material.


contain product residue. Do not pressurize, cut, heat, weld, or expose containers to flame or other sources of
ignition. May evolve oxides of carbon (COx) under fire conditions. May evolve oxides of nitrogen (NOx) under fire
conditions.


3 / 14
SAFETY DATA SHEET
PRODUCT
ACTRENE® EC3269A

Prevent material from entering sewers or waterways. Spilled product may pose a risk to the aquatic ecosystem if
released. If drains, streams, soil or sewers become contaminated, notify local authority.
HANDLING :
Use with adequate ventilation. Keep the containers closed when not in use. Do not use in locations where vapor
is likely to travel to welding flames or arcs or to other hot surfaces. Vapors are much heavier than air, this can result
in uneven distribution. Do not take internally. Do not breathe vapors/gases/dust. Do not get in eyes, on skin, on
clothing. Have emergency equipment (for fires, spills, leaks, etc.) readily available.
Store in suitable labeled containers. Store away from heat and sources of ignition. Store separately from
oxidizers. Store the containers tightly closed. Use proper grounding procedures. Have appropriate fire
extinguishers available in and near the storage area.

Teflon, PTFE, FEP (encapsulated), Aluminum, Mild steel, Carbon Steel C1018, Stainless Steel 304, Stainless
Steel 316L, Hastelloy C-276, Kalrez, Perfluoroelastomer, Compatibility with Plastic Materials can vary; we
therefore recommend that compatibility is tested prior to use., Surface-modified HDPE (high density polyethylene)

Copper, Viton, Neoprene, Ethylene propylene, Polypropylene, Polyethylene, MDPE (medium density
polyethylene), Nitrile, Plexiglass, EPDM, TFE, Brass, Alfax, Nylon, PVC, Buna-N, HDPE (high density
polyethylene), Natural rubber, Polyurethane, Hypalon, Compatibility with Plastic Materials can vary; we therefore
recommend that compatibility is tested prior to use.
SPECIFIC USE(S) :
ANTIFOULANT
shown below.
Manufacturer's Heavy Aromatic Naphtha TWA 100

Recommendation
AUSTRIA Naphthalene MAK 10 50

Skin*

MAK STEL 30 150
4 / 14
SAFETY DATA SHEET
PRODUCT
ACTRENE® EC3269A

BELGIUM Naphthalene TWA 10 53

STEL 15 80
Skin*
BULGARIA Naphthalene TWA 50

STEL 75
DENMARK Naphthalene GV 10 50
Trimethylbenzene GV 25 120
GV 25
FINLAND Naphthalene HTP 8H 1 5

HTP 15MIN 2 10
Trimethylbenzene HTP 8H 20 100
FRANCE Naphthalene VME 10 50
GERMANY Naphthalene Skin*
IRELAND Naphthalene TWA 10 50

STEL 15 75

Skin*
ITALY Naphthalene TWA 10 50
Trimethylbenzene TWA 25
NETHERLANDS Naphthalene TGG 50

TGG 15 80
NORWAY Naphthalene ADM. NORM 10 50
Trimethylbenzene ADM. NORM 20 100
SPAIN Naphthalene VLA-ED 10 53

VLA-EC 15 80
Skin*
SWEDEN Naphthalene NGV 10 50

KTV 15 80
Trimethylbenzene NGV 25 120

KTV 35 170
SWITZERLAND Naphthalene TWA 10 50

Skin*

STEL 40 200
UNITED KINGDOM Trimethylbenzene TWA 25 125
POLAND Naphthalene MAC-NDS 20

MAC-NDSC 50
h
Trimethylbenzene MAC-NDS 100

MAC-NDSC 170
h
5 / 14
SAFETY DATA SHEET
PRODUCT
ACTRENE® EC3269A

HUNGARY Naphthalene ÁK 50
Skin*
LATVIA Naphthalene TWA 10 50
CZECH REPUBLIC Naphthalene PEL 50

NPK-P 100
Heavy Aromatic Naphtha PEL 200

NPK-P 1,000
CROATIA Naphthalene MDK 10 50

KDK 15 75
Trimethylbenzene MDK 25 125
ROMANIA Naphthalene TWA 9.5 50
RUSSIAN Naphthalene (Vapour.) CEIL 20

FEDERATION
SERBIA Naphthalene MAC 10 50
Trimethylbenzene MAC 25 125
SLOVAKIA Naphthalene TWA 10 50

Skin*
SLOVENIA Naphthalene TWA 10 50
the eyes.
Naphthalene US NIOSH: 1501 Gas chromatography Charcoal
Heavy Aromatic Naphtha US NIOSH: 1550 Gas chromatography Charcoal

Heavy Aromatic Naphtha
A biological index of exposure to aromatic petroleum solvent, xylene based, is the detection of total xylene in the
blood post shift (Germany, 1.5 mg/l), or the detection of methylhippuric acid in the urine post shift (USA, 1.5g/g
creatinine; Germany, 2g/l).
Use general ventilation with local exhaust ventilation.
PERSONAL PROTECTION
GENERAL ADVICE :
6 / 14
SAFETY DATA SHEET
PRODUCT
ACTRENE® EC3269A

inspection.
HAND PROTECTION :
SKIN PROTECTION :
When handling this product, the use of a chemical resistant suit and rubber boots is recommended. The applicable
European standard can be found in EN ISO 20345.
EYE PROTECTION :
Keep an eye wash fountain available. Keep a safety shower available. If clothing is contaminated, remove
clothing and thoroughly wash the affected area. Launder contaminated clothing before reuse.

APPEARANCE Red
ODOR Hydrocarbon
FLASH POINT : 53.9 °C

SPECIFIC GRAVITY 0.89 - 0.9 (15.6 °C) ASTM D-1298
MELTING POINT ASTM D-97 -40 °C
7 / 14
SAFETY DATA SHEET
PRODUCT
ACTRENE® EC3269A

STABILITY :
permanganate) may generate heat, fires, explosions and/or toxic vapors., Strong acids, Certain amines in contact
with nitrous acid, organic or inorganic nitrites or atmospheres with high nitrous oxide concentrations may produce
N-nitrosamines, many of which are cancer-causing agents to laboratory animals.

SENSITIZATION :
Repeated or prolonged contact may cause skin sensitization.
CARCINOGENICITY :
MOBILITY :

10 - 30% 30 - 50% 10 - 30%
8 / 14
SAFETY DATA SHEET
PRODUCT
ACTRENE® EC3269A

contractor.
EUROPE WASTE CODE :


Coll.), as amended


9 / 14
SAFETY DATA SHEET
PRODUCT
ACTRENE® EC3269A

LAND TRANSPORT
Technical Name(s) : Substituted alkylamine, 1,2,4-Trimethylbenzene
UN/ID No : UN 1993
Packing Group : III
ADR/RID H.I.n. : 30

UN/ID No : UN 1993
Packing Group : III

UN/ID No : UN 1993
Packing Group : III
*Marine Pollutant :


HAZARD SYMBOLS
10 / 14
SAFETY DATA SHEET
PRODUCT
ACTRENE® EC3269A


ENVIRONMENT
Contains:..Heavy Aromatic Naphtha Naphthalene N,N'-Di-Sec-Butyl-1,4-Phenylenediamine
RISK PHRASES
R10 - Flammable.
SAFETY PHRASES
S28 - After contact with skin, wash immediately with plenty of water.
S37 - Wear suitable gloves.
S62 - If swallowed, do not induce vomiting: seek medical advice immediately and show this container or label.

This Safety Data Sheet is drawn up as per Act No. 356/2003 Coll. and Decree 231/2004 Coll. on detailed
particulars of safety data sheet

4 Bis, 84, 15, 15 Bis, 15 Ter
Classified Industrial Sites (ICPE): Relevant. Headings: 1173, 1430, 1433, 1432B

WGK 3 (Annex 4)
11 / 14
SAFETY DATA SHEET
PRODUCT
ACTRENE® EC3269A

NATIONAL REGULATIONS ITALY

RISK CODE Contains a group III aromatic amine. Handle in a restricted area. (Reference Ministry of Health
circular 46 of 12th June 1979)

item.667).

52-FZ.
August 1993 N 5600-1.
requirements).
12 / 14
SAFETY DATA SHEET
PRODUCT
ACTRENE® EC3269A


EUROPE
UNITED STATES :
CANADA :
The substances in this preparation are listed on the Domestic Substances List (DSL), are exempt, or have been
reported in accordance with the New Substances Notification Regulations.
JAPAN

R10 - Flammable.
R23 - Toxic by inhalation.
R34 - Causes burns.
R50/53 - Very toxic to aquatic organisms, may cause long-term adverse effects in the aquatic environment.
-2
- 15
- 16
13 / 14
SAFETY DATA SHEET
PRODUCT
ACTRENE® EC3269A

Bulgaria +32-(0)3-575-5555
Croatia +385 (0)91-1-25-75-23
Denmark +47-22-33-69-99
Finland +358-(0)9-471 977
Hungary +36-30-9-506-447
Latvia +32-(0)3-575-5555
Norway +47-22-33-69-99
Poland +48-(0)601-66-2626 (SGS) / +48 (0) 14 637 40 81 (SPOT)
Portugal +351-91-911-1399
Romania +40-744 -34-14-53
Saudi Arabia +966-(3)847-1515
Serbia +32-(0)3-575-5555
Slovenia +386-41-634-916
Spain +34-977-551577
Sweden +47-22-33-69-99
UAE +44-(0)7071-223-738
Belgium +32-70-245245
France +33-(0)145-42-59-59 ORFILA

14 / 14
SAFETY DATA SHEET
PRODUCT
ARSENAL® EC3430A

IDENTIFICATION OF THE SUBSTANCE/PREPARATION AND OF THE

1.
COMPANY/UNDERTAKING
PRODUCT NAME : ARSENAL® EC3430A

Postbus 627


NALCO AB (SE) +46 (0)31-21 88 00 Nalco Mobotec Polska Sp. z o.o. PRZEMYS ŁOWA 55
PL-43-110 TYCHY
TEL:+48 (0)32-3262750
FAX: +48(0)32 329 13 11
OF EUROPE BV
NALCO BELGIUM N.V./S.A. (B) +32 (0)3-450 69 10 Nalco Switzerland AG (CH) +41 (0)52 235 38 38
NALCO DANMARK A/S +45-48195800 Nalco Company OOO +7 (0)495 980 72 80
NALCO DEUTSCHLAND GmbH +49 (0)69-79340 NALCO ÖSTERREICH + 43(0)1 27026350
(D) Ges.m.b.H. (A)
NALCO ESPAÑOLA S.A. (E) +34 93-4095555 First Distributor: Nalco Czechia Stankova 882/2,CZ-149 00 Praha
s.r.o. (CZ) 4,Czech Republic,+420 (0)2 679
123 50
NALCO FINLAND OY (FI) +358 (0)9 2517 4700 Local Support: Nalco Hungary Kft. +36 1 880 5761
(HU)
NALCO FRANCE SAS +33 (0)3 20 11 70 00 Local Support: Nalco Österreich +385 (0)1 377 95 21
NALCO HELLAS S.A. (GR) +30 210 238 9620 Local Support: Nalco Österreich +40 (0) 21 224 17 93
ROMANIA (RO)
NALCO ITALIANA S.R.L.(I) +39 06-54565000 NALCO LIMITED +44 (0)1606 74488
Harmful if swallowed. Irritating to eyes and skin. May cause sensitization by skin contact. Harmful: danger of
serious damage to health by prolonged exposure if swallowed. Limited evidence of a carcinogenic effect. Very
toxic to aquatic organisms.
INHALATION :
NALCO EUROPE B.V. Postbus 627 • 2300 AP Leiden • The Netherlands • 0031 71 5241100
1 / 10
SAFETY DATA SHEET
PRODUCT
ARSENAL® EC3430A

Elevated temperatures or mechanical action may form vapors, mists or fumes which may be irritating to the eyes,
nose, throat and lungs.
SKIN CONTACT :
Can cause moderate irritation. Prolonged or frequently repeated skin contact may cause allergic reactions in some
individuals.
EYE CONTACT :
Irritating, and may injure eye tissue if not removed promptly.
INGESTION :
There may be irritation to the gastro-intestinal tract. Harmful if swallowed.

Limited evidence of carcinogenicity for Bis-(hydroxylammonium)-sulfate has been found based on a study
demonstrating increased incidence of tumor, red blood cell toxicity and methemoglobemia at high concentrations
via the oral route of exposure in Wistar rats. Relevance to humans has not been established

ELINCS NO NOTAS
Hydroxylamine Sulfate 233-118-8 10039-54-0 Xn, N R22, R36/38, 10 - 30
R43, R48/22,
R50
INHALATION :
SKIN CONTACT :
Get immediate medical attention. Remove contaminated clothing. Wash off affected area immediately with plenty
of water. For a large splash, flood body under a shower. Contaminated leather articles such as shoes or belts
must be discarded.
EYE CONTACT :
Get immediate medical attention. Immediately flush eye with water for at least 15 minutes while holding eyelids
open.
INGESTION :
Seek medical advice immediately, showing the label and/or SDS. Do not induce vomiting without medical advice.
If conscious, washout mouth and give water to drink.
NOTE TO PHYSICIAN :
2 / 10
SAFETY DATA SHEET
PRODUCT
ARSENAL® EC3430A

FLASH POINT : Not applicable
ignitable. Use extinguishing media appropriate for surrounding fire.

May evolve oxides of nitrogen (NOx) and sulfur (SOx) under fire conditions. Hydroxylammonium sulfate
decomposes exothermically above 180 C with a violent gas evolution.

Ventilate spill area if possible. Ensure clean-up is conducted by trained personnel only. Do not touch spilled
material. Have emergency equipment (for fires, spills, leaks, etc.) readily available. Notify appropriate
government, occupational health and safety and environmental authorities.

Prevent material from entering sewers or waterways. Spilled product may pose a risk to the aquatic ecosystem if
released. If drains, streams, soil or sewers become contaminated, notify local authority.
HANDLING :
leaks, etc.) readily available. Ensure all containers are labeled.
ignition. Store separately from oxidizers. Store separately from acids. Store separately from bases.

Compatibility with Plastic Materials can vary; we therefore recommend that compatibility is tested prior to use.

Iron, Copper, Zinc, Nitrile
3 / 10
SAFETY DATA SHEET
PRODUCT
ARSENAL® EC3430A

This product does not contain any substance that has an established exposure limit.
PERSONAL PROTECTION
GENERAL ADVICE :
inspection.
HAND PROTECTION :
using gloves made from PVC . Gloves should be replaced immediately if signs of degradation are observed.
SKIN PROTECTION :
When handling this product, the use of a chemical resistant suit and rubber boots is recommended. The applicable
European standard can be found in EN ISO 20345.
EYE PROTECTION :

4 / 10
SAFETY DATA SHEET
PRODUCT
ARSENAL® EC3430A

APPEARANCE Clear Colorless
ODOR No data available.

pH (100.0 %) 1.2
STABILITY :
Avoid extremes of temperature. Heat and sources of ignition
Avoid temperatures greater than 176 °F
permanganate) may generate heat, fires, explosions and/or toxic vapors., Acids, Bases, Copper, Iron, Nitrites

Under fire conditions: Oxides of carbon, Oxides of nitrogen, Oxides of sulfur, Hydroxylammonium sulfate
decomposes exothermically above 180 C with a violent gas evolution.

Species: Rat
LD50: 642 mg/kg
Test Descriptor: Product
ACUTE DERMAL TOXICITY :

Species: Rabbit
LD50: 1,500 - 2,000 mg/kg
5 / 10
SAFETY DATA SHEET
PRODUCT
ARSENAL® EC3430A

SENSITIZATION :
Repeated or prolonged contact may cause skin sensitization.
CARCINOGENICITY :
Limited evidence of carcinogenicity for Bis-(hydroxylammonium)-sulfate has been found based on a study
demonstrating increased incidence of tumor, red blood cell toxicity and methemoglobemia at high concentrations
via the oral route of exposure in Wistar rats. Relevance to humans has not been established

Fathead Minnow 96 hrs 7.5 mg/l Product
contractor.
EUROPE WASTE CODE :

16 03 03* - OFF SPECIFICATION BATCHES AND UNUSED PRODUCTS - Inorganic wastes containing
dangerous substances. If this product is used in any further processes, the final user must redefine and assign the
most appropriate European Waste Catalogue Code.

Coll.), as amended
6 / 10
SAFETY DATA SHEET
PRODUCT
ARSENAL® EC3430A

LAND TRANSPORT
Proper Shipping Name : CORROSIVE LIQUID, ACIDIC, INORGANIC, N.O.S.
Technical Name(s) : Hydroxylamine sulfate
UN/ID No : UN 3264
Packing Group : III
ADR/RID H.I.n. : 80

UN/ID No : UN 3264
Packing Group : III
IATA Passenger Aircraft Limit : 1L/5L

UN/ID No : UN 3264
Packing Group : III


HAZARD SYMBOLS
7 / 10
SAFETY DATA SHEET
PRODUCT
ARSENAL® EC3430A

ENVIRONMENT
Contains:..Hydroxylamine Sulfate
RISK PHRASES
R48/22 - Harmful: danger of serious damage to health by prolonged exposure if swallowed.
SAFETY PHRASES
S46 - If swallowed, seek medical advice immediately and show this container or label.

This Safety Data Sheet is drawn up as per Act No. 356/2003 Coll. and per Act 371/2008 Coll.

WGK 3 (Annex 4)

EUROPE
UNITED STATES :
JAPAN
8 / 10
SAFETY DATA SHEET
PRODUCT
ARSENAL® EC3430A


R48/22 - Harmful: danger of serious damage to health by prolonged exposure if swallowed.
-2
-4
-5
-7
Bulgaria +32-(0)3-575-5555
Croatia +385 (0)91-1-25-75-23
Denmark +47-22-33-69-99
Finland +358-(0)9-471 977
Hungary +36-30-9-506-447
Latvia +32-(0)3-575-5555
Norway +47-22-33-69-99
Poland +48-(0)601-66-2626 (SGS) / +48 (0) 14 637 40 81 (SPOT)
Portugal +351-91-911-1399
Romania +40-744 -34-14-53
Saudi Arabia +966-(3)847-1515
Serbia +32-(0)3-575-5555
Slovenia +386-41-634-916
Spain +34-977-551577
Sweden +47-22-33-69-99
UAE +44-(0)7071-223-738
9 / 10
SAFETY DATA SHEET
PRODUCT
ARSENAL® EC3430A

Belgium +32-70-245245
France +33-(0)145-42-59-59 ORFILA

10 / 10
SAFETY DATA SHEET
PRODUCT
NALCO ELIMIN-OX®


1.
COMPANY/UNDERTAKING
PRODUCT NAME : NALCO ELIMIN-OX®
APPLICATION : OXYGEN SCAVENGER

Postbus 627


PL-43-110 TYCHY
TEL:+48 (0)32-3262750
FAX: +48(0)32 329 13 11
OF EUROPE BV
(D) Ges.m.b.H. (A)
123 50
(HU)
ROMANIA (RO)
INHALATION :
1 / 12
SAFETY DATA SHEET
PRODUCT
NALCO ELIMIN-OX®

May cause irritation of mucous membranes.
SKIN CONTACT :
May cause irritation with prolonged contact. May cause sensitization by skin contact.
EYE CONTACT :
INGESTION :
There may be irritation to the gastro-intestinal tract with nausea and vomiting.

No adverse effects expected other than those mentioned above.

ELINCS NO NOTAS
Carbohydrazide 207-837-2 497-18-7 Xn R22, R38, R43 5 - 10
INHALATION :
SKIN CONTACT :
Immediately flush with plenty of water for at least 15 minutes. If symptoms develop, seek medical advice.
EYE CONTACT :
Immediately flush eye with water for at least 15 minutes while holding eyelids open. If symptoms develop, seek
medical advice.
INGESTION :
Do not induce vomiting without medical advice. If conscious, washout mouth and give water to drink. Get medical
attention.
NOTE TO PHYSICIAN :
2 / 12
SAFETY DATA SHEET
PRODUCT
NALCO ELIMIN-OX®

conditions.

Restrict access to area as appropriate until clean-up operations are complete. Stop or reduce any leaks if it is safe
to do so. Do not touch spilled material. Ventilate spill area if possible. Use personal protective equipment
recommended in Section 8 (Exposure Controls/Personal Protection). Ensure clean-up is conducted by trained
personnel only. Have emergency equipment (for fires, spills, leaks, etc.) readily available. Notify appropriate
government, occupational health and safety and environmental authorities.

by diking. Reclaim into recovery or salvage drums or tank truck for proper disposal. Contact an approved waste
hauler for disposal of contaminated recovered material. Dispose of material in compliance with regulations
indicated in Section 13 (Disposal Considerations).
Do not contaminate surface water.
HANDLING :
Do not get in eyes, on skin, on clothing. Do not take internally. Use with adequate ventilation. Ensure all
containers are labeled. Keep the containers closed when not in use. Do not breathe vapors/gases/dust. Have
emergency equipment (for fires, spills, leaks, etc.) readily available.
Store the containers tightly closed. Store in suitable labeled containers. Keep at temperatures above 4 °C

Brass, Carbon Steel C1018, EPDM, FEP (encapsulated), HDPE (high density polyethylene), Hastelloy C-276,
Kalrez, MDPE, Nitrile, PVC, Polyurethane, Polypropylene, Polyethylene, Plexiglass, Perfluoroelastomer, PTFE,
Stainless Steel 304, Stainless Steel 316L, Teflon, TFE, Viton

Aluminum, Alfax, Buna-N, Ethylene propylene, Hypalon, Mild steel, Natural rubber, Neoprene
SPECIFIC USE(S) :
OXYGEN SCAVENGER
3 / 12
SAFETY DATA SHEET
PRODUCT
NALCO ELIMIN-OX®

PERSONAL PROTECTION
GENERAL ADVICE :
If significant mists, vapors or aerosols are generated an approved respirator is recommended. A suitable filter
material depends on the amount and type of chemicals being handled. The applicable European standard can be
found in EN 140, EN 137, EN 143 and EN 14387. Consider the use of filter type: A-P In event of emergency or
planned entry into unknown concentrations a positive pressure, full-facepiece SCBA should be used. If respiratory
protection is required, institute a complete respiratory protection program including selection, fit testing, training,
maintenance and inspection.
HAND PROTECTION :
using gloves made from PVC Nitrile Viton Gloves should be replaced immediately if signs of degradation are
SKIN PROTECTION :
Wear standard protective clothing. Wear a complete suit protecting against chemicals. (if skin contact is likely)
The applicable European standard can be found in EN 14605 and EN ISO 20345.
EYE PROTECTION :
Wear chemical splash goggles. The applicable European standard can be found in EN 166.
APPEARANCE Colorless
ODOR None

4 / 12
SAFETY DATA SHEET
PRODUCT
NALCO ELIMIN-OX®


pH (1 %) 6.7 ASTM E-70
VISCOSITY 3.0 cps (15.6 °C)
FREEZING POINT -2 °C
STABILITY :
Stable if kept under conditions specified in Section 7, HANDLING AND STORAGE.
At temperatures below 4 °C (40 °F), this product loses its stability and forms precipitates. Once formed, the
precipitate cannot be resolubilized and loss of product activity will occur.
permanganate) may generate heat, fires, explosions and/or toxic vapors., Contact with strong acids (e.g. sulfuric,
phosphoric, nitric, hydrochloric, chromic, sulfonic) may generate heat, splattering or boiling and toxic vapors.,
Nitrites


Species: Rat
LD50: > 5,000 mg/kg
ACUTE DERMAL TOXICITY :

Species: Rabbit
LD50: > 2,000 mg/kg
PRIMARY SKIN IRRITATION :

Species: Rabbit
Draize Score: 0.2 /8.0
PRIMARY EYE IRRITATION :

Species: Rabbit
Draize Score: 0.3 /110.0
5 / 12
SAFETY DATA SHEET
PRODUCT
NALCO ELIMIN-OX®

SENSITIZATION :
CARCINOGENICITY :
Hygienists (ACGIH).
MUTAGENICITY :
Negative in the Ames Test. Negative in the Ames Test.

Rainbow Trout 96 hrs 360 mg/l Product
Bluegill Sunfish 96 hrs 190 mg/l Product
Fathead Minnow 96 hrs 400 mg/l 100 mg/l Product
Scophthalmus 96 hrs 156 mg/l OSPAR 1995 Product
maximus

Acartia tonsa 48 hrs 70 mg/l ISO Product
TC147SC5WG2
Corophium 240 hrs > 10,000 mg/l Product
volutator
AQUATIC PLANT RESULTS :

Species Exposure EC50/LC50 Method Test Descriptor
Marine Algae 72 hrs 45 mg/l ISO 10253 Product
(Skeletonema (EC50)
costatum)
MOBILITY :
6 / 12
SAFETY DATA SHEET
PRODUCT
NALCO ELIMIN-OX®


<5% 30 - 50% 50 - 70%
The portion in water is expected to be soluble or dispersible.
This product is suitable for disposal in an approved landfill or by controlled incineration. This product is ashless
and can be burned directly in appropriate equipment. Any chemical waste is a potential environmental pollutant
and is NOT suitable for disposal via ground, municipal sewers, drains, natural streams or rivers.
contractor.
EUROPE WASTE CODE :

16 03 03* - OFF SPECIFICATION BATCHES AND UNUSED PRODUCTS - Inorganic wastes containing
dangerous substances. If this product is used in any further processes, the final user must redefine and assign the

Waste Code :55352

Coll.), as amended

7 / 12
SAFETY DATA SHEET
PRODUCT
NALCO ELIMIN-OX®

LAND TRANSPORT
Proper Shipping Name : PRODUCT IS NOT REGULATED DURING
TRANSPORTATION

TRANSPORTATION

TRANSPORTATION

HAZARD SYMBOLS
IRRITANT
Contains:..Carbohydrazide
RISK PHRASES
SAFETY PHRASES

8 / 12
SAFETY DATA SHEET
PRODUCT
NALCO ELIMIN-OX®


WGK 1 (Annex 4)
NATIONAL REGULATIONS HOLLAND

ABM RESULT
ABM RESULT Substance(s) % (w/w)
11 B
NATIONAL REGULATIONS HUNGARY

Relevant and applicable Hungarian legislation on protection of human health and the environment:
Decree 44/2000. (XII.27.) EüM (Minister of Health Affairs) and its amendments: Decree 33/2004. (IV.26.) ESzCsM
(Minister of Health, Social and Family Affairs) and Decree 26/2007. (VI.7.) EüM (1907/2006/EK - REACH) on
detailed rules of certain procedures and activities related to dangerous substances and preparations.
Joint Ministerial Decree: 25/2000. (IX.30.) EüM-ESzCsM on chemical safety at work.

item.667).
9 / 12
SAFETY DATA SHEET
PRODUCT
NALCO ELIMIN-OX®


52-FZ.
August 1993 N 5600-1.
requirements).

Denmark 1787926
Norway 091440

EUROPE
UNITED STATES :
CANADA :
JAPAN

10 / 12
SAFETY DATA SHEET
PRODUCT
NALCO ELIMIN-OX®


-7
- 10
Bulgaria +32-(0)3-575-5555
Croatia +385 (0)91-1-25-75-23
Denmark +47-22-33-69-99
Finland +358-(0)9-471 977
Hungary +36-30-9-506-447
Latvia +32-(0)3-575-5555
Norway +47-22-33-69-99
Poland +48-(0)601-66-2626 (SGS) / +48 (0) 14 637 40 81 (SPOT)
Portugal +351-91-911-1399
Romania +40-744 -34-14-53
Saudi Arabia +966-(3)847-1515
Serbia +32-(0)3-575-5555
Slovenia +386-41-634-916
Spain +34-977-551577
Sweden +47-22-33-69-99
UAE +44-(0)7071-223-738
Belgium +32-70-245245
France +33-(0)145-42-59-59 ORFILA

11 / 12
SAFETY DATA SHEET
PRODUCT
NALCO ELIMIN-OX®

12 / 12
SAFETY DATA SHEET
PRODUCT
AQUAMAX(TM) EC6577A


COMPANY/UNDERTAKING
PRODUCT NAME : AQUAMAX(TM) EC6577A
APPLICATION : EMULSION BREAKING CHEMICAL

Postbus 627


NALCO AB (SE) +46 (0)31-21 88 00 NALCO POLSKA Sp.z.o.o. (PL) PRZEMYS ŁOWA 55
PL-43-110 TYCHY
TEL:+48 (0)32-3262750
FAX: +48(0)32 329 13 11
(P)
OF EUROPE BV
(D) (CH)
Ges.m.b.H. (A)
50
Kft. (HU)
(HR)
Office ROMANIA (RO)
This product is not classified as dangerous in accordance with Directives 67/548/EEC or 1999/45/EC.
1/8
SAFETY DATA SHEET
PRODUCT
AQUAMAX(TM) EC6577A

INHALATION :
SKIN CONTACT :
EYE CONTACT :
INGESTION :
There may be irritation to the gastro-intestinal tract.

ELINCS NO NOTAS
Modified polyethyleneimine Polymer Polymer R52/53 5 - < 25
INHALATION :
SKIN CONTACT :
Get immediate medical attention. Remove contaminated clothing. Wash off affected area immediately with plenty
of water. For a large splash, flood body under a shower.
EYE CONTACT :
Get immediate medical attention. Immediately flush eye with water for at least 15 minutes while holding eyelids
open.
INGESTION :
Seek medical advice immediately, showing the label and/or SDS. Do not induce vomiting without medical advice.
If conscious, washout mouth and give water to drink.
NOTE TO PHYSICIAN :
2/8
SAFETY DATA SHEET
PRODUCT
AQUAMAX(TM) EC6577A


conditions.

Ensure adequate ventilation. Do not touch spilled material. Ensure clean-up is conducted by trained personnel
only. Have emergency equipment (for fires, spills, leaks, etc.) readily available. Notify appropriate government,
occupational health and safety and environmental authorities.

Do not contaminate surface water.
HANDLING :
Prevent contact with skin, eyes and clothing. Use with adequate ventilation. Do not breathe vapors/gases/dust.
Keep the containers closed when not in use. Have emergency equipment (for fires, spills, leaks, etc.) readily
available. Ensure all containers are labeled.
Store in suitable labeled containers. Store the containers tightly closed.

Compatibility with Plastic Materials can vary; we therefore recommend that compatibility is tested prior to use.
SPECIFIC USE(S) :
EMULSION BREAKING CHEMICAL
Use general ventilation with local exhaust ventilation.
3/8
SAFETY DATA SHEET
PRODUCT
AQUAMAX(TM) EC6577A

PERSONAL PROTECTION
GENERAL ADVICE :
chemicals being handled. Consider the use of filter type: P The applicable European standard can be found in EN
140, EN 137, EN 143 and EN 14387. In event of emergency or planned entry into unknown concentrations a
HAND PROTECTION :
When handling this product, the use of chemical gloves is recommended. The choice of work glove depends on
Breakthrough time not determined as preparation, consult PPE manufacturers.
SKIN PROTECTION :
The applicable European standard can be found in EN ISO 20345.
EYE PROTECTION :
When handling this product, the use of safety glasses with side shields is recommended. The applicable European
Use good work and personal hygiene practices to avoid exposure. Consider the provision in the work area of a
safety shower and eyewash. Always wash thoroughly after handling chemicals. When handling this product never
eat, drink or smoke.
APPEARANCE Light yellow
ODOR Amine

pH (100.0 %) 10.0
VISCOSITY 14.5 cps (40 °C)
VAPOR PRESSURE 7.33 kPa
4/8
SAFETY DATA SHEET
PRODUCT
AQUAMAX(TM) EC6577A

STABILITY :
Avoid extremes of temperature.
Bases, Acids, Oxidizing agents, Reducing agents

contractor.
EUROPE WASTE CODE :

16 03 04 - OFF SPECIFICATION BATCHES AND UNUSED PRODUCTS - Inorganic wastes other than those
mentioned in 16 03 03. If this product is used in any further processes, the final user must redefine and assign the
5/8
SAFETY DATA SHEET
PRODUCT
AQUAMAX(TM) EC6577A

LAND TRANSPORT
TRANSPORTATION

TRANSPORTATION

TRANSPORTATION
This preparation is not regulated, however, we recommend the following safety precautions:
SAFETY PHRASES

EUROPE
UNITED STATES :
6/8
SAFETY DATA SHEET
PRODUCT
AQUAMAX(TM) EC6577A

JAPAN
This product contains substance(s) which are not in compliance with the Law Regulating the Manufacture and
Importation Of Chemical Substances and are not listed on the Existing and New Chemical Substances list (ENCS).
Bulgaria +32-(0)3-575-5555
Croatia +385 (0)91-1-25-75-23
Denmark +47-22-33-69-99
Finland +358-(0)9-471 977
Hungary +36-30-9-506-447
Latvia +32-(0)3-575-5555
Norway +47-22-33-69-99
Poland +48-(0)601-66-2626 (SGS) / +48 (0) 14 637 40 81 (SPOT)
Portugal +351-91-911-1399
Romania +40-744 -34-14-53
Saudi Arabia +966-(3)847-1515
Serbia +32-(0)3-575-5555
Slovenia +386-41-634-916
Spain +34-977-551577
Sweden +47-22-33-69-99
UAE +44-(0)7071-223-738
Belgium +32-70-245245
France +33-(0)145-42-59-59 ORFILA
7/8
SAFETY DATA SHEET
PRODUCT
AQUAMAX(TM) EC6577A


8/8
SAFETY DATA SHEET
PRODUCT
Arsenal® EC9055A


1.
COMPANY/UNDERTAKING
PRODUCT NAME : Arsenal® EC9055A
APPLICATION : ANTIFOAM

Postbus 627


PL-43-110 TYCHY
TEL:+48 (0)32-3262750
FAX: +48(0)32 329 13 11
OF EUROPE BV
(D) Ges.m.b.H. (A)
123 50
(HU)
ROMANIA (RO)
INHALATION :
1/8
SAFETY DATA SHEET
PRODUCT
Arsenal® EC9055A

Elevated temperatures or mechanical action may form vapors, mists or fumes which may be irritating to the eyes,
nose, throat and lungs.
SKIN CONTACT :
EYE CONTACT :
INGESTION :
May cause nausea and vomiting. Can cause central nervous system depression.
INHALATION :
SKIN CONTACT :
EYE CONTACT :
INGESTION :
Get medical attention. Do not induce vomiting without medical advice. If conscious, washout mouth and give
water to drink.
NOTE TO PHYSICIAN :
FLASH POINT : 120 °C
Foam, Carbon dioxide, Dry powder, For large fires, use water spray or fog, thoroughly drenching the burning
material.


May evolve oxides of carbon (COx) under fire conditions.

2/8
SAFETY DATA SHEET
PRODUCT
Arsenal® EC9055A

Ensure adequate ventilation. Do not touch spilled material. Ensure clean-up is conducted by trained personnel
only. Have emergency equipment (for fires, spills, leaks, etc.) readily available. Notify appropriate government,
occupational health and safety and environmental authorities.

HANDLING :
leaks, etc.) readily available. Ensure all containers are labeled.
Store in suitable labeled containers. Store the containers tightly closed. Store separately from oxidizers.

Carbon Steel C1018, Stainless Steel 304, Stainless Steel 316L, MDPE, HDPE (high density polyethylene), TFE,
Perfluoroelastomer, Nitrile, Neoprene, Viton, EPDM, PTFE, FEP (encapsulated)
SPECIFIC USE(S) :
ANTIFOAM
PERSONAL PROTECTION
GENERAL ADVICE :
3/8
SAFETY DATA SHEET
PRODUCT
Arsenal® EC9055A

HAND PROTECTION :
SKIN PROTECTION :
The applicable European standard can be found in EN 14605 and EN ISO 20345.
EYE PROTECTION :
Wear safety glasses with side-shields. The applicable European standard can be found in EN 166.
Use good work and personal hygiene practices to avoid exposure. Consider the provision in the work area of a
safety shower and eyewash. Always wash thoroughly after handling chemicals. When handling this product never
eat, drink or smoke.

APPEARANCE Hazy
ODOR Somewhat sweet
FLASH POINT : 120 °C

VISCOSITY 171 cst (40 °C) ASTM D-445
POUR POINT -17 °C
FREEZING POINT -34 °C
4/8
SAFETY DATA SHEET
PRODUCT
Arsenal® EC9055A

STABILITY :

contractor.
EUROPE WASTE CODE :

16 03 06 - OFF SPECIFICATION BATCHES AND UNUSED PRODUCTS - Organic wastes other than those
mentioned in 16 03 05. If this product is used in any further processes, the final user must redefine and assign the

Waste Code :55373
5/8
SAFETY DATA SHEET
PRODUCT
Arsenal® EC9055A

Coll.), as amended

LAND TRANSPORT
TRANSPORTATION

TRANSPORTATION

TRANSPORTATION
This preparation is not regulated, however, we recommend the following safety precautions:
SAFETY PHRASES


Table of occupational diseases, Article L461-4. Social Security Code- Decree 11/2/2003: Not-applicable.
Dangerous or Poisonous Substances and Preparations: Not-applicable.
Work Restrictions:
6/8
SAFETY DATA SHEET
PRODUCT
Arsenal® EC9055A

Classified Industrial Sites (ICPE): Not-applicable. Water Discharge: Relevant.

WGK 2 (Annex 4)
NATIONAL REGULATIONS, USA

FOOD AND DRUG ADMINISTRATION (FDA) Federal Food, Drug and Cosmetic Act :
When use situations necessitate compliance with FDA regulations, this product is acceptable under : 21 CFR
175.105 Adhesives 21 CFR 175.105 Adhesives

EUROPE
The substance(s) in this preparation are included in or exempted from the EINECS or ELINCS inventories
UNITED STATES :
CANADA :
JAPAN

-2
-5
-6
-8
- 11
- 12
7/8
SAFETY DATA SHEET
PRODUCT
Arsenal® EC9055A

Bulgaria +32-(0)3-575-5555
Croatia +385 (0)91-1-25-75-23
Denmark +47-22-33-69-99
Finland +358-(0)9-471 977
Hungary +36-30-9-506-447
Latvia +32-(0)3-575-5555
Norway +47-22-33-69-99
Poland +48-(0)601-66-2626 (SGS) / +48 (0) 14 637 40 81 (SPOT)
Portugal +351-91-911-1399
Romania +40-744 -34-14-53
Saudi Arabia +966-(3)847-1515
Serbia +32-(0)3-575-5555
Slovenia +386-41-634-916
Spain +34-977-551577
Sweden +47-22-33-69-99
UAE +44-(0)7071-223-738
Belgium +32-70-245245
France +33-(0)145-42-59-59 ORFILA

8/8
Revision Date 31-Aug-2010, Issuing Date 05-Mar-2010, Page 1 / 8
_____________________________________________________________________
NITROGEN, GAS
Material Safety Data Sheet
_____________________________________________________________________
1. PRODUCT AND COMPANY IDENTIFICATION
Product Name NITROGEN, GAS
Product Code(s) G-7, 1018
UN-No UN1066
Recommended Use Compressed gas.
Synonyms LASER Nitrogen; LASER Nitrogen Ultra; Nitrogen, compressed
Supplier Address* Linde Gas North America LLC - Linde Merchant Production Inc. - Linde LLC
575 Mountain Ave.
Murray Hill, NJ 07974
Phone: 908-464-8100
www.lindeus.com
Linde Gas Puerto Rico, Inc.

Las Palmas Village
Road No. 869, Street No. 7
Catano, Puerto Rico 00962
Phone: 787-641-7445
www.pr.lindegas.com
Linde Canada Limited

5860 Chedworth Way
Mississauga, Ontario L5R 0A2
Phone: 905-501-1700
www.lindecanada.com
* May include subsidiaries or affiliate companies/divisions.
For additional product information contact your local customer service.
Chemical Emergency Phone Chemtrec: 1-800-424-9300 for US/ 703-527-3887 outside US

Number
WARNING!
Emergency Overview
Simple asphyxiant
Contents under pressure
Keep at temperatures below 52°C / 125°F
Appearance Colorless Physical State Compressed gas. Odor Odorless
OSHA Regulatory Status This material is considered hazardous by the OSHA Hazard Communication Standard (29 CFR
1910.1200).
Potential Health Effects

NITROGEN, GAS, Material Safety Data Sheet , Revision Date 31-Aug-2010, Page 2 / 8
___________________________________________________________________
Principle Routes of Exposure Inhalation.
Acute Toxicity
Inhalation Simple asphyxiant. May cause suffocation by displacing the oxygen in the air. Exposure to oxygen-
deficient atmosphere (<19.5%) may cause dizziness, drowsiness, nausea, vomiting, excess salivation,
diminished mental alertness, loss of consciousness and death. Exposure to atmospheres containing 8-
10% or less oxygen will bring about unconsciousness without warning and so quickly that the
individuals cannot help or protect themselves. Lack of sufficient oxygen may cause serious injury or
death.
Eyes This product is a gas at room temperature. Contact with liquid may cause frostbite.
Skin This product is a gas at room temperature. Contact with liquid may cause frostbite.
Skin Absorption Hazard No known hazard in contact with skin.
Ingestion Not an expected route of exposure.
Chronic Effects None known.
Aggravated Medical None known.

Conditions
Environmental Hazard See Section 12 for additional Ecological Information.
Chemical Name CAS-No Volume % Chemical Formula

Nitrogen 7727-37-9 >99 N2
Eye Contact None required for gas. If frostbite is suspected, flush eyes with cool water for 15 minutes and obtain
immediate medical attention.
Skin Contact None required for gas. For dermal contact or suspected frostbite, remove contaminated clothing and
flush affected areas with lukewarm water. DO NOT USE HOT WATER. A physican should see the patient
promptly if contact with the product has resulted in blistering of the dermal surface or in deep tissue
freezing.
Inhalation PROMPT MEDICAL ATTENTION IS MANDATORY IN ALL CASES OF INHALATION OVEREXPOSURE. RESCUE
PERSONNEL SHOULD BE EQUIPPED WITH SELF-CONTAINED BREATHING APPARATUS. Conscious inhalation
victims should be assisted to an uncontaminated area and inhale fresh air. If breathing is difficult,
administer oxygen. Unconscious persons should be moved to an uncontaminated area and, as
necessary, given artificial resuscitation and supplemental oxygen. Treatment should be symptomatic
and supportive.
Ingestion None under normal use. Get medical attention if symptoms occur.
Notes to Physician Treat symptomatically.

___________________________________________________________________
5. FIRE-FIGHTING MEASURES
Flammable Properties Not flammable.
Suitable Extinguishing Media Use extinguishing measures that are appropriate to local circumstances and the surrounding
environment.
Explosion Data
Sensitivity to Mechanical Impact None
Sensitivity to Static Discharge None
Specific Hazards Arising from the Cylinders may rupture under extreme heat. Continue to cool fire exposed cylinders until flames are
Chemical extinguished. Damaged cylinders should be handled only by specialists.
Protective Equipment and As in any fire, wear self-contained breathing apparatus pressure-demand, MSHA/NIOSH (approved or
Precautions for Firefighters equivalent) and full protective gear.
Personal Precautions Ensure adequate ventilation. Evacuate personnel to safe areas. Use personal protective equipment.
Monitor oxygen level.
Environmental Precautions Prevent spreading of vapors through sewers, ventilation systems and confined areas.
Methods for Containment Stop the flow of gas or remove cylinder to outdoor location if this can be done without risk. If leak is in
container or container valve, contact the appropriate emergency telephone number in Section 1 or call
your closest Linde location.
Methods for Cleaning Up Return cylinder to Linde or an authorized distributor.
Handling Use only in ventilated areas. Never attempt to lift a cylinder by its valve protection cap. Protect
cylinders from physical damage; do not drag, roll, slide or drop. When moving cylinders, even for short
distance, use a cart designed to transport cylinders. Use equipment rated for cylinder pressure. Use
backflow preventive device in piping. Never insert an object (e.g. wrench, screwdriver, pry bar,etc.)
into valve cap openings. Doing so may damage valve, causing leak to occur.
Use an adjustable strap wrench to remove over-tight or rusted caps. Close valve after each use and
when empty. If user experiences any difficulty operating cylinder valve discontinue use and contact
supplier.
Never put cylinders into trunks of cars or unventilated areas of passenger vehicles. Never attempt to
refill a compressed gas cylinder without the owner's written consent. Never strike an arc on a
compressed gas cylinder or make a cylinder a part of an electrical circuit.
For additional recommendations consult Compressed Gas Association's (CGA) Safety Bulletin SB-2,
Oxygen-Deficient Atmospheres.
For additional handling recommendations, consult Compressed Gas Association's pamphlets P-1, G-
10.1, P-8.1, P-8.2, P-9, P-16, P-18, and Safety Bulletin SB-2.
___________________________________________________________________
Storage Protect from physical damage. Cylinders should be stored upright with valve protection cap in place
and firmly secured to prevent falling. Store in cool, dry, well-ventilated area of non-combustible
construction away from heavily trafficked areas and emergency exits. Keep at temperatures below
52°C / 125°F. Full and empty cylinders should be segregrated. Use a "first in-first out" inventory
system to prevent full cylinders from being stored for excessive periods of time. Always store and
handle compressed gas cylinders in accordance with Compressed Gas Association, pamphlet CGA-P1,
Safe Handling of Compressed Gases in Containers.
8. EXPOSURE CONTROLS / PERSONAL PROTECTION
Exposure Guidelines This product does not contain any hazardous materials with occupational exposure limits established
by the region specific regulatory bodies.
Engineering Measures Showers. Eyewash stations. Ventilation systems. Local exhaust ventilation to prevent accumulation of
high concentrations and maintain air-oxygen levels at or above 19.5%.
Ventilation Ensure adequate ventilation, especially in confined areas.
Personal Protective Equipment
Eye/Face Protection If splashes are likely to occur, wear: Goggles. Face-shield.
Skin and Body Protection Wear cold insulating gloves when handling liquid. Work gloves and safety shoes are recommended
when handling cylinders.
Respiratory Protection
General Use No special protective equipment required.
Emergency Use Use positive pressure airline respirator with escape cylinder or self contained breathing apparatus for
oxygen-deficient atmospheres (<19.5%).
Hygiene Measures Wear suitable gloves and eye/face protection.
Appearance Colorless. Odor Odorless.

Odor Threshold No information available. Physical State Compressed gas
Flash Point No information available. Autoignition Temperature No information available.
Decomposition Temperature No information available. Boiling Point/Range -195.8°C / -320.4°F
Freezing Point -209.9°C / -345.9°F Molecular Weight 28.01
Water Solubility Very slight Evaporation Rate No information available
Vapor Pressure No data available. Vapor Density 0.97 (air = 1)
Gas Density 0.072 lb/ft³ (1.153 kg/m³) (@ VOC Content (%) Not applicable.
21.1°C)
Specific Vol. @ 21.1°C & 1 atm 13.8 ft³/lb (0.867 m³/kg) Critical Pressure 492.9 psia (3399 kPa abs)
Flammability Limits in Air
Upper Not applicable
Lower Not applicable
___________________________________________________________________
Stability Stable.
Incompatible Products None known.
Conditions to Avoid None known.
Hazardous Decomposition None known.

Products
Hazardous Polymerization Hazardous polymerization does not occur.
Acute Toxicity
LD50 Oral: No information available.
LD50 Dermal: No information available.
LC50 Inhalation: No information available.
Inhalation Product is a simple asphyxiant.
Repeated Dose Toxicity No information available.
Chronic Toxicity
Chronic Toxicity None known.
Carcinogenicity Contains no ingredient listed as a carcinogen.
Irritation No information available.
Sensitization No information available.
Reproductive Toxicity No information available.
Developmental Toxicity Oxygen deficiency during pregnancy has produced developmental abnormalities in humans and
experimental animals.
Synergistic Materials None known.
Target Organ Effects None known.
Ecotoxicity
The environmental impact of this product has not been fully investigated.
Ozone depletion potential; ODP; (R-11 = 1): Does not contain ozone depleting chemical (40 CFR Part 82).
___________________________________________________________________
Waste Disposal Methods Do not attempt to dispose of residual waste or unused quantities. Return in the shipping container
PROPERLY LABELED WITH ANY VALVE OUTLET PLUGS OR CAPS SECURED AND VALVE PROTECTION CAP IN
PLACE to Linde for proper disposal.
DOT
Proper Shipping Name Nitrogen, compressed

Hazard Class 2.2
Subsidiary Class None
UN-No UN1066
Description UN1066,Nitrogen, compressed,2.2
Emergency Response Guide Number 121
TDG

Hazard Class 2.2
UN-No UN1066
Description UN1066,NITROGEN, COMPRESSED,2.2
MEX

Hazard Class 2.2
UN-No UN1066
Description UN1066, Nitrogen, compressed,2.2
IATA
UN-No UN1066
Hazard Class 2.2
ERG Code 2L
Description UN1066,Nitrogen, compressed,2.2
Maximum Quantity for Passenger 75 kg
Maximum Quantity for Cargo Only 150 kg
Limited Quantity No information available.
IMDG/IMO

Hazard Class 2.2
UN-No UN1066
EmS No. F-C, S-V
ADR

Hazard Class 2.2
UN-No UN1066
Classification Code 1A
___________________________________________________________________
International Inventories
TSCA Complies
DSL Complies
EINECS/ELINCS Complies
Legend
TSCA - United States Toxic Substances Control Act Section 8(b) Inventory
DSL/NDSL - Canadian Domestic Substances List/Non-Domestic Substances List
EINECS/ELINCS - European Inventory of Existing Commercial Chemical Substances/EU List of Notified Chemical Substances
U.S. Federal Regulations
SARA 313
Section 313 of Title III of the Superfund Amendments and Reauthorization Act of 1986 (SARA). This product does not contain any chemicals
which are subject to the reporting requirements of the Act and Title 40 of the Code of Federal Regulations, Part 372.
SARA 311/312 Hazard Categories
Acute Health Hazard No

Chronic Health Hazard No
Fire Hazard No
Sudden Release of Pressure Hazard Yes
Reactive Hazard No
Clean Water Act
This product does not contain any substances regulated as pollutants pursuant to the Clean Water Act (40 CFR 122.21 and 40 CFR 122.42).
Risk and Process Safety Management Programs

This material, as supplied, does not contain any regulated substances with specified thresholds under 40 CFR Part 68.
This product does not contain any substances regulated as Highly Hazardous Chemicals pursuant to the 29 CFR Part 1910.110.
Clean Air Act, Section 112 Hazardous Air Pollutants (HAPs) (see 40 CFR 61)
This product does not contain any substances regulated as hazardous air pollutants (HAPS) under Section 112 of the Clean Air Act
Amendments of 1990.
CERCLA/SARA
This material, as supplied, does not contain any substances regulated as hazardous substances under the Comprehensive Environmental
Response Compensation and Liability Act (CERCLA) (40 CFR 302) or the Superfund Amendments and Reauthorization Act (SARA) (40 CFR
355). There may be specific reporting requirements at the local, regional, or state level pertaining to releases of this material.
U.S. State Regulations
California Proposition 65
This product does not contain any Proposition 65 chemicals.
U.S. State Right-to-Know Regulations

___________________________________________________________________
Chemical Name Massachusetts New Jersey Pennsylvania Illinois Rhode Island

Nitrogen X X X - X
International Regulations
Canada
This product has been classified in accordance with the hazard criteria of the Controlled Products Regulations (CPR) and the MSDS
contains all the information required by the CPR.
WHMIS Hazard Class

A Compressed gases
Prepared By Product Stewardship

23 British American Blvd.
Latham, NY 12110
1-800-572-6501
Issuing Date 05-Mar-2010
Revision Date 31-Aug-2010
Revision Number 1
Revision Note (M)SDS sections updated. 1.
NFPA Health Hazard 0 Flammability 0 Stability 0 Physical and Chemical

Hazards Simple asphyxiant
HMIS Health Hazard 0 Flammability 0 Physical Hazard 3 Personal Protection -
Note: Ratings were assigned in accordance with Compressed Gas Association (CGA) guidelines as published in CGA Pamphlet P-19-2009,
CGA Recommended Hazard Ratings for Compressed Gases, 3rd Edition.
General Disclaimer
For terms and conditions, including limitation of liability, please refer to the purchase agreement in effect between Linde LLC, Linde Merchant
Production, Inc. or Linde Gas North America LLC (or any of their affiliates and subsidiaries) and the purchaser.
DISCLAIMER OF EXPRESSED AND IMPLIED WARRANTIES

Although reasonable care has been taken in the preparation of this document, we extend no warranties and make no representations as to the accuracy
or completeness of the information contained herein, and assume no responsibility regarding the suitability of this information for the user's intended
purposes or for the consequences of its use. Each individual should make a determination as to the suitability of the information for their particular
purpose(s).
End of Safety Data Sheet

Safety Data Sheet (SDS)
SDS Number: 23005-01 06/02/2006
EMERGENCY ASSISTANCE CHEMTREC (International): +1-703-527-3887 (Call Collect)
1. IDENTIFICATION OF THE SUBSTANCE / PREPARATION AND COMPANY

Product name : KL7741B
COMMON NAME: Metal Oxide
PRODUCT USE: Catalyst.
SUPPLIER: KataLeuna GmbH Catalysts
Gebäude 8322, Am Haupttor
D-06237 Leuna, Germany
+49 3461 43 4384
+49 3461 43 3607 (FAX)
Preparation Description:
Palladium oxide(s) on a carrier of alumina.
Compliance Statement
Not classified as dangerous under EC criteria.
Hazard Classification:
Human health hazards: Not expected to give rise to an acute hazard under normal conditions of use.
Safety hazards: No specific hazards.
Environmental precautions: No specific hazards.

Eye:
Flush eye with water.
Page 1 of 6
KL7741B SDS Number: 23005
Skin Contact:
Wash skin with water and, if available, soap.
Inhalation:
Move to fresh air.
Ingestion:
In case of accident or if you feel unwell, seek medical advice immediately (show the label where possible).

Extinguishing Media:
Material will not burn; use an extinguishing medium appropriate for the surrounding fire.

Personal Precautions:
Avoid raising a dust cloud. Do not breathe dust. Avoid contact with skin and eyes. Wear suitable protective
clothing and gloves.
Spill Management:
Shovel up and place in a labeled, sealable container for subsequent safe disposal. Flush contaminated area
with plenty of water.
Environmental Compliance:
Refer to latest state or local regulations to determine if there are disposal or reporting requirements.

Handling Recommendations:
Avoid contact with skin and eyes.
Avoid raising a dust cloud.
Do not breathe dust.
Do not eat, smoke or drink in areas where catalyst is present.
Use only in well ventilated areas. Use local exhaust extraction.
Take precautionary measures against static discharge.
Earth all equipment.
Storage:
Keep container tightly closed and dry.
Reseal plastic liner.
Storage class: 13

Engineering Controls:
Page 2 of 6
Hygiene measures:
Do not breathe dust. Avoid contact with skin and eyes. Wash hands thoroughly after handling.
Respiratory protection:
If risk of inhalation of dust wear general purpose dust respirator (disposable) NPF 7-10. In a confined space
self-contained breathing apparatus may be required.
Eye protection:
Dust-tight monogoggles
Hand protection:
PVC, neoprene, or nitrile rubber gloves
Body Protection:
Disposable one-piece coated overall with attached hood, safety boots - chemical resistant without lace holes
Chemical Name Authority Limits Special Notations
Aluminum oxide EH40 TWA 10 mg/m³ total dust

Aluminum oxide EH40 TWA 4 mg/m³ respirable dust
Physical & Chemical Properties Characteristics

Appearance and Odour: Off-White To Gray Extrudates, Odourless
Solubility in water: <1%
Bulk density (for solids): 800-900 kg/m³
10. STABILITY/REACTIVITY
Stability:
Stable. Hygroscopic.
Materials to avoid:
Strong acids, strong bases, strong oxidizing agents.
Page 3 of 6

This material is composed of metals and or naturally occurring minerals whose toxicity is relatively well known. The
toxicity of this material is expected to be low and primarily associated with mild or mechanical irritation from dusts
which may be generated during transportation or handling.

Ecotoxicological data have not been determined specifically for this material. The information given below
is based on a knowledge of the components and the ecotoxicology of similar products.
ENVIRONMENTAL IMPACT
Toxicity:
Not expected to be toxic.
Persistence & Bioaccumulation:

Not inherently biodegradable.
Sewage treatment:
Not toxic at the limit of water solubility.

Product disposal:
Recover or recycle, if possible. Otherwise: Send to an approved contractor for regeneration or metal
recovery or dispose with a licensed disposal contractor.
Waste disposal:
If product is unused, see above. If used, evaluate the toxicity and physical properties of the material you
have generated and dispose of the material in accordance with local, state and federal regulations.
Container disposal:
Empty containers may contain residues. Ensure container is properly cleaned. Do not cut, puncture, torch or
weld on or near the emptied container. Send drum to a drum recoverer or metal reclaimer. Remove all
packaging for recovery or waste disposal. DO NOT USE CONTAINER FOR OTHER PURPOSES.
Regulatory Information - Product

Authority
2001/118/EC: Commission Decision of 16 January 2001 amending Decision 2000/532/EC as regards the list
of wastes
Description
06 03 wastes from MFSU of salts and their solutions and metallic oxides
06 03 16 metallic oxides other than those mentioned in 06 03 15
Page 4 of 6
Regulatory Information - Used Material

Authority
of wastes
Description
16 08 spent catalysts
16 08 01 spent catalysts containing gold, silver, rhenium, rhodium, palladium, iridium or platinum
(except 16 08 07)
16 08 07 spent catalysts contaminated with dangerous substances
Other Information
If spent-unregenerated catalyst becomes a waste material, conduct proper testing to determine if it has either
a characteristic or listed waste. Comply with all federal, state and local laws regulating the handling and
disposal of wastes.

Transport Statement:
Not dangerous for conveyance under UN, IMO, ADR/RID and IATA/ICAO codes.
National Inventories
National Authority Country Status
EINECS/ELINCS EC All components listed.
TSCA USA All components listed.
MITI Japan All components listed.
DSL/NDSL Canada All components listed.
TCCL Korea All components listed.
AICS Australia All components listed.
PICCS Philippines All components listed.
IECS China All components listed.
European Community
Classification Not classified as dangerous under EC criteria.
Safety Phrases S22: Do not breathe dust.

S24/25: Avoid contact with skin and eyes.
Page 5 of 6
SDS Prepared By: CRI/Criterion, Inc.

16825 Northchase Drive, Suite #1110
Houston, TX 77060 (USA)
+1 281-874-2600 (USA CST)
Uses and restrictions:

Use as a raw material/intermediate for catalyst manufacture, as a catalyst for refinery processing or for
petrochemicals manufacture.
SDS distribution:
The information in this document should be made available to all who may handle the product.
Other information:
The content and format of this safety data sheet is in accordance with Commission Directive 2001/58/EC.
Ammendment Notation:
Amendments from the previous version of the MSDS are indicated by two vertical bars in the left margin and
the section is highlighted.
Disclaimer:
This information is based on our current knowledge and is intended to describe the product for the purposes
of health, safety and environmental requirements only. It should not, therefore, be construed as guaranteeing
any specific property of the product.
Date of issue:
07.11.2005
United Kingdom - (British English
Page 6 of 6
SDS Number: 23017-01 04/07/2009

Product name : KL7752
+49 3461 43 4384
+49 3461 43 3607 (FAX)
Human health hazards:

Not expected to give rise to an acute hazard under normal conditions of use.
Environmental precautions:
No specific hazards.
Palladium on a carrier of alumina.

Eye:
Page 1 of 6
KL7752 SDS Number: 23017
Skin Contact:
Inhalation:
Move to fresh air.
Ingestion:
Eye:
Flush eye with water. Get medical attention immediately.
Skin Contact:
Inhalation:
Move to fresh air.
Ingestion:


Spill Management:

Storage:
Page 2 of 6

Storage class: 13

Hygiene measures:
Eye protection:
Hand protection:
Body Protection:

Product
Appearance and Odour: Gray Extrudates, Odourless
Bulk density (for solids): 900 - 1100 kg/m³
Stability:
Materials to avoid:
Page 3 of 6

This material is composed of metals and or naturally occurring minerals whose toxicity is relatively well
known. The toxicity of this material is expected to be low and primarily associated with mild or mechanical
irritation from dusts which may be generated during transportation or handling.

Toxicity:


Product disposal:
Waste disposal:
Container disposal:

Authority
of wastes
Description
Page 4 of 6

Authority
of wastes
Description
16 08 01 spent catalysts containing gold, silver, rhenium, rhodium, palladium, iridium or platinum
(except 16 08 07)
16 08 07 spent catalysts contaminated with dangerous substances
Other Information
disposal of wastes.

Not dangerous for conveyance under UN, USA DOT, Canadian TDG, IMO, ADR/RID and IATA/ICAO
codes.
European Community
Label Name Not classified as dangerous under EC criteria.

Page 5 of 6

+1 281-874-2600 (USA CST)
Product.Steward@CRI-Criterion.com

SDS distribution:
Other information:
Disclaimer:
Date of issue:
07.04.2009
Page 6 of 6
SDS Number: 23006-01 07/29/2004

+49 3461 43 4384
+49 3461 43 3607 (FAX)
Palladium oxide(s) on a carrier of alumina.
Human health hazards: Not expected to give rise to an acute hazard under normal conditions of use.

Eye:
Page 1 of 6
Skin Contact:
Inhalation:
Move to fresh air.
Ingestion:


Spill Management:

Storage:
Storage class: 13

Page 2 of 6
Hygiene measures:
Eye protection:
Hand protection:
Body Protection:
disposable one-piece coated overall with attached hood, safety boots - chemical resistant without lace holes


Appearance and Odour: Brown Extrudates or Spheres. Odorless
Bulk density (for solids): 550-600 kg/m³
Stability:
Materials to avoid:
Page 3 of 6


Toxicity:

Sewage treatment:

Product disposal:
Waste disposal:
Container disposal:

Authority
of wastes
Description
Page 4 of 6

Authority
of wastes
Description
16 08 01 spent catalysts containing gold, silver, rhenium, rhodium, palladium, iridium or platinum (except
16 08 07)
16 08 07* spent catalysts contaminated with dangerous substances
Other Information
disposal of wastes.
European Community

Page 5 of 6
SDS Prepared By: CRI International, Inc.

+1 281-874-2600 (USA CST)

SDS distribution:
Other information:
Disclaimer:
Date of issue:
29.07.2004
United Kingdom - (British English)
Page 6 of 6
SDS Number: 23,226-01 01/14/2006

PRODUCT USE: Arsenic/sulphur removal for FCC feeds
+49 3461 43 4384
+49 3461 43 3607 (FAX)
Nickel, molybdenum and phosphorous oxides on an alumina carrier.
DANGEROUS COMPONENTS/CONSTITUENTS
Component Chemical EC No. CAS Symbol EC R Phrases %w
Formula
Molybdenum MoO3 2152047 1313-27-5 Xn R48/20/22 12 - 19 %
oxide R36/37
Nickel oxide NiO 2152157 1313-99-1 T R49 R43 R53 10 - 14 %
Notes: The phosphorous contained in this product, reported as P2O5, is chemically bound and will not be
released as highly reactive phosphorous pentoxide.
Carcinogen Category 1
Human health hazards: May cause cancer by inhalation. May cause sensitization by skin contact. Harmful:
danger of serious damage to health by prolonged exposure through inhalation and if swallowed.
Page 1 of 7
KL8233 SDS Number: 23,226
Other Dangers: Contains a substance classified as a Category 1 carcinogen.

Eye:
Flush eye with water. If persistent irritation occurs, get medical attention.
Skin Contact:
Wash skin with water and, if available, soap. If persistent irritation occurs, get medical attention.
Inhalation:
Move to fresh air. If rapid recovery does not occur, obtain medical attention.
Ingestion:
Do not induce vomiting. Give nothing by mouth. Get medical attention immediately.
Advice to physicians:
Treat symptomatically. If skin sensitisation has developed and a causal relationship has been confirmed,
further exposure should not be allowed.

Fire Hazards:
Will not burn or support combustion.

clothing and gloves. Wear high efficiency dust respirator NPF 1000. In a confined space, wear compressed
air line apparatus, full face constant flow type NPF 2000 self-breathing apparatus open circuit type NPF
2000.
Spill Management:
Prevent contamination of soil and water. Do not wash spills into sewers or other public water systems.
Prevent further leakage or spillage and prevent from entering drains.
Spill Disposal:
Shovel up and place in a labeled, sealable container for subsequent safe disposal.
Page 2 of 7

Storage:

Hygiene measures:
Eye protection:
Hand protection:
Body Protection:

Molybdenum oxide EH40 TWA 10 mg/m³ as Mo
Molybdenum oxide EH40 STEL 20 mg/m³ as Mo
Nickel oxide EH40 TWA 0.5 mg/m³ as Ni; total dust; Carcinogen
Nickel carbonyl EH40 STEL 0.24 mg/m³ as Ni; formed from reaction
with CO under certain
conditions
Nickel oxide: Category 1 carcinogen to which the special provisions for carcinogens in the COSHH
Regulations apply.(EH40)
Page 3 of 7

Appearance and Odour: Yellowish-Green Extrudates, Odourless
Solubility in water: < 5%
Bulk density (for solids): 0.74 g/cc
Stability:
Materials to avoid:
Strong acids, strong bases, strong oxidizing agents. May form nickel carbonyl, a very toxic and potentially
lethal gas, on contact with carbon monoxide.
Hazardous decomposition products:

In use the catalyst is reduced and sulfided. The reduced form, especially when warm, reacts with oxygen on
contact with air. Enough heat can be produced to burn coke or residual organic material left on the catalyst,
and could ignite flammable mixtures that it may contact. To protect against this possibility, spent catalyst
should be oxidized and cooled before removing it from the reactor. Other measures, such as cooling and
blanketing with nitrogen or water wetting the catalyst may also be used to retard oxidation.

Acute Lethality
Route Material Tested LD/LC50 Species
Oral Molybdenum oxide 3260 mg/kg Rat
Dermal Molybdenum oxide >2000 mg/kg Rabbit
Inhalation Molybdenum oxide >5.84 mg/l(4 hrs) Rat
Sensitization
Route Material Tested Description Species
Dermal Nickel compounds Sensitiser
Other Health Effects:

Nickel and nickel compounds as dust may cause effects on the respiratory tract, lymph nodes, blood, eyes
and cardiovascular system. Nickel is a sensitiser. Nickel and nickel compounds bind to DNA and have been
shown to cause genotoxicity.
Carcinogenicity:
Nickel oxide is classified by:
IARC: Group 1, Carcinogenic to Humans.
EC as a Category 1 carcinogen (91/632/EEC)
ACGIH as a confirmed human carcinogen (A1)
Page 4 of 7

Toxicity:
Expected to be slightly toxic. May cause long-term adverse effects in the aquatic environment.

Mobility:
Sinks in water. If product enters soil, one or more constituents will be mobile and may contaminate
groundwater.
Sewage treatment:
Other information:
Comply with Council Directives 76/464/EEC and 80/68/EEC with respect to the potential leaching of Nickel
compounds and molybdenum cCompounds into the aquatic environment and into groundwater.

Product disposal:
Waste disposal:
Container disposal:
Empty containers may contain residues. Ensure container is properly cleaned. Send drum to a drum
recoverer or metal reclaimer.
Regulatory Controls:
Comply with all federal, state and local laws regulating the handling and disposal of wastes.

Authority
of wastes
Description
06 03 15* metallic oxides containing heavy metals
Page 5 of 7

Authority
of wastes
Description
16 08 02* spent catalysts containing dangerous transition metals or dangerous transition metal compounds

European Community
Label Name CONTAINS NICKEL COMPOUNDS / MOLYBDENUM OXIDE
Hazard Symbols T: Toxic
Classification Carcinogen Category 1
Risk Phrases R49: May cause cancer by inhalation.

R43: May cause sensitization by skin contact.
R48/20/22: Harmful: danger of serious damage to health by prolonged
exposure through inhalation and if swallowed.
S53: Avoid exposure - obtain special instructions before use.
S45: In case of accident or if you feel unwell, seek medical advice
immediately (show the label where possible).
ENVIRONMENTAL CLASSIFICATIONS
UK. RELEASES TO WATER: Nickel oxide The annual reporting level threshold is 20 kilograms.
Page 6 of 7

+1 281-874-2600 (USA CST)

SDS distribution:
Other information:
Full text of the risk phrases of the components:

R36/37:
Irritating to eyes and respiratory system.
R43:
R48/20/22:
Harmful: danger of serious damage to health by prolonged exposure through inhalation and if swallowed.
R49:
May cause cancer by inhalation.
R53:
May cause long-term adverse effects in the aquatic environment.
Disclaimer:
Date of issue:
14.01.2006
Page 7 of 7
SDS Number: 23116-01 07/29/2004

PRODUCT USE: Inert support for catalyst manufacture.
+49 3461 43 4384
+49 3461 43 3607 (FAX)
Amorphous silica/alumina carrier.
Notes: On the basis of available information, the components of this preparation are not expected to impart
hazardous properties to this product.
Human health hazards: No specific hazards.
Page 1 of 6

Eye:
Skin Contact:
Inhalation:
Move to fresh air.
Ingestion:


Spill Management:

Wash hands thoroughly after handling.
Storage:

Page 2 of 6
Hygiene measures:
Eye protection:
Hand protection:
Body Protection:
standard issue work clothes, safety shoes or boots

Silica, amorphous (non- EH40 TWA 6 mg/m³ total dust
crystalline)
Silica, amorphous (non- EH40 TWA 2.4 mg/m³ respirable dust
crystalline)

Appearance and Odour: White to Off-White, Odourless
Bulk density (for solids): ~1300 kg/m³
Stability:
Materials to avoid:
Page 3 of 6


Toxicity:

Sewage treatment:

Product disposal:
Waste disposal:
Container disposal:

Authority
of wastes
Description
Page 4 of 6
European Community

SDS Prepared By: CRI International, Inc.

+1 281-874-2600 (USA CST)

SDS distribution:
Other information:
Page 5 of 6
Disclaimer:
Date of issue:
27.07.2004
United Kingdom - (British English)
Page 6 of 6
A
SAFETY DATA SHEET

according to Regulation (EC) No. 1907/2006
Product: SILIPORITE Page: 1 / 6
SDS No.: 971219-001 (Version 1.9 ) Date 18.12.2010 (Cancel and replace : 11.05.2010)
1. IDENTIFICATION OF THE SUBSTANCE/MIXTURE AND OF THE COMPANY/UNDERTAKING
Generic Safety Data Sheet
Identification of the mixture: SILIPORITE

Grades SILIPORITE : NK 10, NK 10 CL, NK 10 DC, NK 10 PH, NK 10 R, NK 10 RB, NK 10 RL, NK 20,
NK 20 C, NK 30, NK 30 COS, NK 30 SRC, G5, G5 COS, G5 DC, G5 CO2M, G5 CO2MLZ, G5
L86, G 586, G5 SIL, 82, H3RI, SRA, SA 4, EPX, EHP, OPX K, OPX R, OPX T, 3 HS, RA, NPG
50, PHYG 1, PHYG 3, G5 O2, NITROXY 5, NPL 50, LSX, OPTISIEVE 3, OPTISIEVE 4,
OPTISIEVE 5, OPTISIEVE 10, OPX M, AIRSIEV Ox8, AIRSIEV P140, AIRSIEV P180, CECA
GLAS, AIRSIEV P 220
Use of the Substance/Mixture : Manufacture of double glazing., Purifier for liquids and gases in many industries : printing,
water treatment..., Desiccant
Company/Undertaking Identification:
Supplier CECA
Tamis Moléculaires
Adresse postale : 89 Boulevard National
92250 LA GARENNE-COLOMBES
FRANCE
Téléphone: 01 49 00 38 00
Télécopie: 01 49 00 38 01
http://www.cecachemicals.com
Email address : ceca.fds@ceca.fr
Emergency telephone number +33 1 49 00 77 77
Classification (Regulation (EC) No 1272/2008):

see chapter: 16
Classification according to EU Directives 1999/45/EC :
This mixture is not classified as dangerous according to Directive 1999/45/EC.
Label elements (D. 1999/45/EC amended by D. 2006/8/CE):
Further information The product does not need to be labelled in accordance with EC directives or respective national laws.
Other hazards:
Potential health effects:
Dehydrating/desiccant effect.
Environmental Effects:
In its normal state, this product does not present any specific risk for the environment.
1
Chemical nature of the mixture :
Preparation containing zeolites
CECA SA 89 Boulevard National - 92250 LA GARENNE-COLOMBES - FRANCE

Quick-FDS [15696-24067-26652-010755] - 2010-12-21 - 06:41:07
Hazardous components (according to Regulation (EC) No. 1907/2006) :

Classification
1 2 Classification
Chemical Name & REACH Registration Number EC-No. CAS-No. Concentration Directive
Regulation (EC) No 1272/2008
67/548/EEC
Zeolites 215-283-8 1318-02-1 > 80 % WEL substance
Mineral binder > 15 % WEL substance
Quartz (SiO2) 238-878-4 14808-60- <3% WEL substance

7
Tridymite 239-487-1 15468-32- <1% WEL substance

3
Cristobalite 238-455-4 14464-46- <1% WEL substance
1
Cristalline silica, respirable fraction < 10µm – < 0.1 % Xn; R48/20 STOT RE 1 (Inhalation); H372
1
: See chapter 14 for Proper Shipping Name
2
:See the text of the regulation for applicable exceptions or provisions : The transition time according to REACH Regulation, Article 23, is still
not expired.
For the full text of the R, H, EUH-phrases mentioned in this Section, see Section 16.
Description of necessary first-aid measures, Most important symptoms/effects, acute and delayed:
General advice:
Remove soiled/dirty clothing, brush well and wash carefully.
Inhalation:
Move patient from contaminated area to fresh air. Blow nose. In case of persistent problems : Consult a physician. If dust inhalation is severe
: move operator to fresh air, wash mouth and throat with plenty of water.
Skin contact:
Wash immediately, abundantly and thoroughly with soap and water.
Eye contact:
Wash immediately, abundantly and thoroughly with water. If irritation persists, consult an ophthalmologist. Do not scrub the eyes.
Ingestion:
Immediately give large quantities of water to drink. In case of problems : Consult a doctor.
Extinguishing media:
Suitable extinguishing media: Incombustible product., Use suitable means to extinguish neighbouring fires.
Specific hazards: No data available.
Advice for firefighters:
Specific methods:
Non combustible product that reacts violently with water, foam and olefins or other adsorbable substances.
Special protective actions for fire-fighters:

In the event of fire, wear self-contained breathing apparatus.
Personal precautions, protective equipment and emergency procedures:

Avoid breathing dust. Do not crush, avoid the formation and spread of dust in the air.
Quick-FDS [15696-24067-26652-010755] - 2010-12-21 - 06:41:07

Prevent product from entering drains.
Methods and materials for containment and cleaning up:
Methods for cleaning up:

Pick up and arrange disposal without creating dust. Sweep up and shovel. Keep in suitable, closed containers for disposal.
Elimination: See chapter 13
Precautions for safe handling:
Technical measures/Precautions:
Provide water supplies and ocular fountains near the point of use. Protect from moisture/humidity.
Safe handling advice:

Smoking, eating and drinking should be prohibited in the application area. Avoid contact with water, olefins and other adsorbable compounds.
Hygiene measures:
Remove immediately soaked or soiled clothing. Wash separately. Wash immediately any affected parts of the body. See heading 4.
Wash hands after handling. Remove contaminated clothing and protective equipment before entering eating areas.
Conditions for safe storage, including any incompatibilities:

Keep container tightly closed in a dry and well-ventilated place.
Packaging material:
Recommended: Watertight drums with polyethyleneliner., Cardboard containers, Big bags., Large flexible bulk containers.
Specific use(s) (End Use): None.
CONTROL PARAMETERS:
Exposure Limit Values (dust)
Source Date Value type Value Value Remarks

(ppm) (mg/m3)
EH40 WEL 2007 TWA – 4 Respirable dust.
EH40 WEL 2007 TWA – 10 Inhalable dust.
ACGIH (US) 2008 TWA – 10 Inhalable particles.
ACGIH (US) 2008 TWA – 3 Respirable particles.
Exposure Limit Values
Aluminium oxide
(ppm) (mg/m3)
EH40 WEL 2007 TWA – 10 Inhalable dust.
EH40 WEL 2007 TWA – 4 Respirable dust.
ACGIH (US) 2009 TWA – 1 Respirable fraction.
Quartz (SiO2)
(ppm) (mg/m3)
EH40 WEL 2007 TWA – 0.1 Respirable.
ACGIH (US) 2007 TWA – 0.025 Respirable fraction.
Derived No Effect Level (DNEL): No data available.
Predicted No Effect Concentration: No data available.
EXPOSURE CONTROLS:
General protective measures: Respect of exposure limit values relating to respirable fractions of cristalline silica can
preventsilicosis and consequent cancer of the lungs.
Personal protective equipment:
Quick-FDS [15696-24067-26652-010755] - 2010-12-21 - 06:41:07

Respiratory protection: Appropriate normalized breathing apparatus is recommended.

Hand protection: Impervious gloves
Eye/face protection: Safety glasses, Eye wash bottle with pure water
Skin and body protection: Protective suit
Environmental exposure controls: See chapter 6

Appearance:
Physical state (20°C): solid
Form: Beads or extrudates of different sizes., powder
Colour: Brown., white
Odour: None.
Olfactory threshold: Not relevant
pH: pH 8 - 11, aqueous sludge
Melting point/range : > 1,600 °C
Boiling point/boiling range: No data available.
Flash point: not applicable
Evaporation rate: No data available.
Flammability (solid, gas): No data available.
Vapour pressure: No data available.
Vapour density: No data available.
Relative density: No data available.
Bulk density: 600 - 900 kg/m3 depending on grade
Water solubility: insoluble
Partition coefficient: n-octanol/water: No data available.
Autoignition temperature: No data available.
Decomposition temperature: No data available.
Viscosity: No data available.
Explosive properties: No data available.
Oxidizing properties: No data available.
Reactivity & Chemical stability: No data available.
Possibility of hazardous reactions:

Further information: Stable under recommended storage conditions.
Conditions to avoid:
Store protected from moisture (to maintain the technical properties of the product)
Hazardous decomposition products: No data available.
To our knowledge, no harmful effects for man under normal conditions of use.
Toxicological information:
Acute toxicity:
Local effects ( Corrosion / Irritation / Serious eye damage ):
Skin contact:
Exothermic reaction with adsorbable bodies (water), risk of superficial burns.
Eye contact:
Exothermic reaction with adsorbable bodies (water), risk of superficial burns., Possible temporary
irritation due to dust.
Quick-FDS [15696-24067-26652-010755] - 2010-12-21 - 06:41:07

Respiratory or skin sensitization:
Inhalation: No data available.
Skin contact: No data available.
CMR effects :
Mutagenicity: No data available.
Carcinogenicity:
Respect of exposure limit IARC : group 1 - Carcinogenic to man., MAK value (Germany) : Category I
values relating to respirable
fractions of cristalline silica can
preventsilicosis and
consequent cancer of the
lungs. Respirable fractions of
cristalline silica :
Reproductive toxicity: No data available.
Specific target organ toxicity :
Single exposure : No data available.
Repeated exposure: No data available.
Aspiration hazard: No data available.
Ecotoxicology Assessment: No known harmful effect on the aquatic environment. Product must not be released into the
environment if dangerous substances are adsorbed onto the product. Insoluble in aqueous solution,
the product can be separated by filtration or sedimentation.
Acute toxicity
Microorganisms: No data available.
Persistence and degradability: No data available.
Bioaccumulative potential : No data available.
Mobility in soil - Distribution among environmental compartments:

Absorption / desorption: Water: insoluble
Results of PBT and vPvB No data available.

assessment:
Waste treatment:
Disposal of product: In accordance with local and national regulations. If product has been used (contains adsorbed
substances) : dispose of at an approved waste disposal site only. If product not used (in original state)
: dispose of in accordance with local regulations.
Not classified as dangerous in the meaning of transport regulations.
Quick-FDS [15696-24067-26652-010755] - 2010-12-21 - 06:41:07

Safety data sheets: according to Regulation (EC) No. 1907/2006

UK REGULATION Chip3: Chemical (Hazard Information and Packaging for Supply) Regulations 2002
INVENTORIES:
EINECS: Conforms to
TSCA: Conforms to
AICS: Conforms to
DSL: All components of this product are on the Canadian DSL list.
ENCS (JP): Does not conform
KECI (KR): Does not conform
PICCS (PH): Conforms to
IECSC (CN): Conforms to
NZIOC: Does not conform
Classification (Regulation (EC) No 1272/2008):

Not a hazardous substance or mixture according to Globally Harmonized System.
Not a hazardous substance or mixture according to Globally Harmonized System.
Full text of R, H, EUH-phrases referred to under sections 2 and 3
R48/20 Harmful: danger of serious damage to health by prolonged exposure through inhalation.
H372 Causes damage to organs through prolonged or repeated exposure if inhaled.
Thesaurus:
NOAEL : No Observed Adverse Effect Level (NOAEL)
LOAEL : Lowest Observed Adverse Effect Level (LOAEL)
bw : Body weight
food : oral feed
dw : Dry weight
This safety data sheet complies with international standard ISO 11014-1. In case of formulations or mixtures, it is necessary to ascertain that a
new danger will not appear. The information contained is based on our knowledge of the product, at the date of publishing and it is given quite
sincerely. Users are advised of possible additional hazards when the product is used in applications for which it was not intended. This sheet
shall only be used and reproduced for prevention and security purposes. The references to legislative, regulatory and codes of practice
documents cannot be considered as exhaustive. It is the responsibility of the person receiving the product to refer to the totality of the official
documents concerning the use, the possession and the handling of the product. It is also the responsibility of the handlers of the product to pass
on to any subsequent persons who will come into contact with the product (usage, storage, cleaning of containers, other processes) the totality
of the information contained within this safety data sheet and necessary for safety at work, the protection of health and the protection of
environment.
NB: In this document the numerical separator of the thousand is the "." (point), the decimal separator is "," (comma).
Quick-FDS [15696-24067-26652-010755] - 2010-12-21 - 06:41:07

Safety data sheet
Ethylene
Creation date : 28.01.2005 Version : 6.0 DE / E SDS No. : 055a
Revision date : 04.01.2011 page 1 / 3
1 IDENTIFICATION OF THE SUBSTANCE/PREPARATION AND P377 Leaking gas fire: Do not extinguish,
OF THE COMPANY unless leakcan be stopped safely.
Product name P381 Eliminate all ignition sources if safe to do
Ethylene so.
EC No (from EINECS): 200-815-3
CAS No: 74-85-1 Precautionary Statement Storage
Index-Nr. 601-010-00-3 P403 Store in a well-ventilated place.
Chemical formula C2H4
REACH Registration number: Precautionary Statement Disposal
Not available. None.
Known uses
Not known. 3 COMPOSITION/INFORMATION ON INGREDIENTS
Company identification Substance/Preparation: Substance.
Linde AG, Linde Gas Division, Seitnerstraße 70, D-82049 Pullach Components/Impurities
E-Mail Address Info@de.linde-gas.com Ethylene
Emergency phone numbers (24h): 089-7446-0 CAS No: 74-85-1
Index-Nr.: 601-010-00-3
2 HAZARDS IDENTIFICATION EC No (from EINECS): 200-815-3
Classification of the substance or mixture REACH Registration number:
Not available.
Classification acc. to Regulation (EC) No 1272/2008/EC Contains no other components or impurities which will influence the
(CLP/GHS) classification of the product.
Press. Gas (Liquefied gas) - Contains gas under pressure; may
explode if heated. 4 FIRST AID MEASURES
Flam. Gas 1 - Extremely flammable gas. Inhalation
STOT SE 3 - May cause drowsiness or dizziness. In high concentrations may cause asphyxiation. Symptoms may
include loss of mobility/consciousness. Victim may not be aware of
Classification acc. to Directive 67/548/EEC & 1999/45/EC asphyxiation. In low concentrations may cause narcotic effects.
F+; R12 | R67 Symptoms may include dizziness, headache, nausea and loss of co-
Extremely flammable. ordination. Remove victim to uncontaminated area wearing self
Vapours may cause drowsiness and dizziness. contained breathing apparatus. Keep victim warm and rested. Call a
Risk advice to man and the environment doctor. Apply artificial respiration if breathing stopped.
Compressed gas. Ingestion
Label Elements Ingestion is not considered a potential route of exposure.
- Labelling Pictograms 5 FIRE FIGHTING MEASURES

Specific hazards
Exposure to fire may cause containers to rupture/explode.
Hazardous combustion products
Incomplete combustion may form carbon monoxide.
Suitable extinguishing media
All known extinguishants can be used.
- Signal word Specific methods
Danger If possible, stop flow of product. Move container away or cool with
water from a protected position. Do not extinguish a leaking gas
- Hazard Statements flame unless absolutely necessary. Spontaneous/explosive re-
H280 Contains gas under pressure; may ignition may occur. Extinguish any other fire.
explode if heated. Special protective equipment for fire fighters
H220 Extremely flammable gas. In confined space use self-contained breathing apparatus.
H336 May cause drowsiness or dizziness.
6 ACCIDENTAL RELEASE MEASURES
- Precautionary Statements Personal precautions
Wear self-contained breathing apparatus when entering area unless
Precautionary Statement Prevention atmosphere is proved to be safe. Evacuate area. Ensure adequate
P210 Keep away from heat/sparks/open air ventilation. Eliminate ignition sources.
flames/hot surfaces. - No smoking. Environmental precautions
P260 Do not breathe gas, vapours. Try to stop release. Prevent from entering sewers, basements and
workpits, or any place where its accumulation can be dangerous.
Precautionary Statement Reaction Clean up methods
P304+P340+P315 IF INHALED: Remove victim to fresh air Ventilate area.
and keep at rest in a position
comfortable for breathing. Get
immediate medical advise/attention.
055a / EDV / 29.12.2010

Safety data sheet
Ethylene
7 HANDLING AND STORAGE place where its accumulation could be dangerous. Contact supplier
Handling if guidance is required.
Ensure equipment is adequately earthed. Suck back of water into EWC Nr. 16 05 04*
the container must be prevented. Purge air from system before
introducing gas. Do not allow backfeed into the container. Use only 14 TRANSPORT INFORMATION
properly specified equipment which is suitable for this product, its ADR/RID
supply pressure and temperature. Contact your gas supplier if in Class 2 Classification Code 2F
doubt. Keep away from ignition sources (including static UN number and proper shipping name
discharges). Refer to supplier's handling instructions. UN 1962 Ethylene
Storage UN 1962 Ethylene
Secure cylinders to prevent them falling. Segregate from oxidant Labels 2.1 Hazard number 23
gases and other oxidants in store. Keep container below 50°C in a
well ventilated place. Observe "Technische Regeln Druckgase IMDG
(TRG) 280 Ziffer 5" Class 2.1
UN number and proper shipping name
8 EXPOSURE CONTROLS/PERSONAL PROTECTION UN 1962 Ethylene
Labels 2.1
Personal protection Packing Instruction P200
Ensure adequate ventilation. Do not smoke while handling product. EmS FD,SU
Carry working gloves and protection shoes while handling gas
cylinders. IATA
Class 2.1
9 PHYSICAL AND CHEMICAL PROPERTIES UN number and proper shipping name
UN 1962 Ethylene
General information Labels 2.1
Appearance/Colour: Colourless gas. Packing Instruction P200
Odour: Poor warning properties at low concentrations. Sweetish. Other transport information
Important information on environment, health and safety Avoid transport on vehicles where the load space is not separated
Molecular weight: 28 g/mol from the driver's compartment. Ensure vehicle driver is aware of the
Melting point: -169 °C potential hazards of the load and knows what to do in the event of
Boiling point: -103 °C an accident or an emergency. Before transporting product
Critical temperature: 9,5 °C containers ensure that they are firmly secured. Ensure that the
Autoignition temperature: 425 °C cylinder valve is closed and not leaking. Ensure that the valve outlet
Flammability range: 2,3 %(V) - 34 %(V) cap nut or plug (where provided) is correctly fitted. Ensure that the
Relative density, gas: 1 valve protection device (where provided) is correctly fitted. Ensure
Relative density, liquid: 0,57 adequate ventilation. Ensure compliance with applicable regulations.
Vapour Pressure 20 °C: Not applicable.
Solubility mg/l water: No reliable data available. 15 REGULATORY INFORMATION
Other data
Gas/vapour heavier than air. May accumulate in confined spaces, Further national regulations
particularly at or below ground level. Pressure Vessel Regulation
Gefahrstoffverordnung (GefStoffV)
10 STABILITY AND REACTIVITY Technische Regeln für Gefahrstoffe (TRGS)
Stability and reactivity Regulations for the prevention of industrial accidents
May decompose violently at high temperature and/or pressure or in Water pollution class
the presence of a catalyst Can form explosive mixture with air. May Not polluting to waters according to VwVwS from 17.05.99.
react violently with oxidants. TA-Luft
Not classified according to TA-Luft.
11 TOXICOLOGICAL INFORMATION
Acute toxicity 16 OTHER INFORMATION
No known toxicological effects from this product. Ensure all national/local regulations are observed. Ensure operators
understand the flammability hazard. The hazard of asphyxiation is
often overlooked and must be stressed during operator training.
12 ECOLOGICAL INFORMATION Before using this product in any new process or experiment, a
thorough material compatibility and safety study should be carried
General out.
No known ecological damage caused by this product. Advice
Whilst proper care has been taken in the preparation of this
13 DISPOSAL CONSIDERATIONS document, no liability for injury or damage resulting from its use can
General be accepted. Details given in this document are believed to be
Do not discharge into areas where there is a risk of forming an correct at the time of going to press.
explosive mixture with air. Waste gas should be flared through a Further information
suitable burner with flash back arrestor. Do not discharge into any Hommel: Handbook of dangerous goods
055a / EDV / 29.12.2010

Safety data sheet
Ethylene
Kühn-Birett: Merkblätter gefährliche Arbeitsstoffe

Linde safety advice
End of document
055a / EDV / 29.12.2010

Safety data sheet
Ethane
1 IDENTIFICATION OF THE SUBSTANCE/PREPARATION AND

OF THE COMPANY Precautionary Statement Disposal
Product name None.
Ethane
EC No (from EINECS): 200-814-8 3 COMPOSITION/INFORMATION ON INGREDIENTS
CAS No: 74-84-0 Substance/Preparation: Substance.
Index-Nr. 601-002-00-X Components/Impurities
Chemical formula C2H6 Ethane
REACH Registration number: CAS No: 74-84-0
Not available. Index-Nr.: 601-002-00-X
Known uses EC No (from EINECS): 200-814-8
Not known. REACH Registration number:
Company identification Not available.
Linde AG, Linde Gas Division, Seitnerstraße 70, D-82049 Pullach Contains no other components or impurities which will influence the
E-Mail Address Info@de.linde-gas.com classification of the product.
Emergency phone numbers (24h): 089-7446-0
4 FIRST AID MEASURES
2 HAZARDS IDENTIFICATION Inhalation
Classification of the substance or mixture In high concentrations may cause asphyxiation. Symptoms may
Classification acc. to Regulation (EC) No 1272/2008/EC asphyxiation. In low concentrations may cause narcotic effects.
(CLP/GHS) Symptoms may include dizziness, headache, nausea and loss of co-
Press. Gas (Liquefied gas) - Contains gas under pressure; may ordination. Remove victim to uncontaminated area wearing self
explode if heated. contained breathing apparatus. Keep victim warm and rested. Call a
Flam. Gas 1 - Extremely flammable gas. doctor. Apply artificial respiration if breathing stopped.
Skin/eye contact
Classification acc. to Directive 67/548/EEC & 1999/45/EC For liquid spillage - flush with water for at least 15 minutes Obtain
F+; R12 medical assistance.
Extremely flammable. Ingestion
Risk advice to man and the environment Ingestion is not considered a potential route of exposure.
Liquefied gas.
Contact with liquid may cause cold burns/frost bite. 5 FIRE FIGHTING MEASURES
Label Elements Specific hazards
- Labelling Pictograms Hazardous combustion products
Specific methods
If possible, stop flow of product. Move container away or cool with
- Signal word flame unless absolutely necessary. Spontaneous/explosive re-
Danger ignition may occur. Extinguish any other fire.
Special protective equipment for fire fighters
- Hazard Statements In confined space use self-contained breathing apparatus.
H280 Contains gas under pressure; may
explode if heated. 6 ACCIDENTAL RELEASE MEASURES
H220 Extremely flammable gas. Personal precautions
- Precautionary Statements atmosphere is proved to be safe. Evacuate area. Ensure adequate
air ventilation. Eliminate ignition sources.
Precautionary Statement Prevention Environmental precautions
P210 Keep away from heat/sparks/open Try to stop release. Prevent from entering sewers, basements and
flames/hot surfaces. - No smoking. workpits, or any place where its accumulation can be dangerous.
Clean up methods
Precautionary Statement Reaction Ventilate area. Keep area evacuated and free from ignition sources
P377 Leaking gas fire: Do not extinguish, until any spilled liquid has evaporated. (Ground free from frost).
unless leakcan be stopped safely.
P381 Eliminate all ignition sources if safe to do 7 HANDLING AND STORAGE
so.
Handling
Ensure equipment is adequately earthed. Suck back of water into
Precautionary Statement Storage
P403 Store in a well-ventilated place.
051a / EDV / 19.11.2010

Safety data sheet
Ethane
discharges). Refer to supplier's handling instructions. UN 1035 Ethane
Storage UN 1035 Ethane
gases and other oxidants in store. Keep container below 50°C in a Packing Instruction P200
well ventilated place. Observe "Technische Regeln Druckgase
(TRG) 280 Ziffer 5" IMDG
Class 2.1
8 EXPOSURE CONTROLS/PERSONAL PROTECTION UN number and proper shipping name
UN 1035 Ethane
Personal protection Labels 2.1
Ensure adequate ventilation. Do not smoke while handling product. Packing Instruction P200
Carry working gloves and protection shoes while handling gas EmS FD,SU
cylinders.
IATA
9 PHYSICAL AND CHEMICAL PROPERTIES Class 2.1
General information UN number and proper shipping name
Appearance/Colour: Colourless gas. UN 1035 Ethane
Odour: None. Stenchant often added Labels 2.1
Packing Instruction P200
Important information on environment, health and safety Other transport information
Molecular weight: 30 g/mol Avoid transport on vehicles where the load space is not separated
Melting point: -183 °C from the driver's compartment. Ensure vehicle driver is aware of the
Boiling point: -88,6 °C potential hazards of the load and knows what to do in the event of
Critical temperature: 32 °C an accident or an emergency. Before transporting product
Autoignition temperature: 515 °C containers ensure that they are firmly secured. Ensure that the
Flammability range: 2,7 %(V) - 16 %(V) cylinder valve is closed and not leaking. Ensure that the valve outlet
Relative density, gas: 1 cap nut or plug (where provided) is correctly fitted. Ensure that the
Relative density, liquid: 0,54 valve protection device (where provided) is correctly fitted. Ensure
Vapour Pressure 20 °C: 37,8 bar adequate ventilation. Ensure compliance with applicable regulations.
Solubility mg/l water: 61 mg/l
Other data 15 REGULATORY INFORMATION
Gas/vapour heavier than air. May accumulate in confined spaces,
particularly at or below ground level.
Further national regulations
10 STABILITY AND REACTIVITY Pressure Vessel Regulation
Stability and reactivity Technische Regeln für Gefahrstoffe (TRGS)
Can form explosive mixture with air. May react violently with Regulations for the prevention of industrial accidents
oxidants. Water pollution class
Not polluting to waters according to VwVwS from 17.05.99.
General thorough material compatibility and safety study should be carried
No known ecological damage caused by this product. out.
Advice
13 DISPOSAL CONSIDERATIONS Whilst proper care has been taken in the preparation of this
document, no liability for injury or damage resulting from its use can
place where its accumulation could be dangerous. Contact supplier Kühn-Birett: Merkblätter gefährliche Arbeitsstoffe
if guidance is required. Linde safety advice
EWC Nr. 16 05 04*
051a / EDV / 19.11.2010

Safety data sheet
Ethane
End of document
051a / EDV / 19.11.2010

Safety data sheet
Butene 1-
Creation date : 28.01.2005 Version : 2.0 DE / E SDS No. : 017

Product name None.
Butene 1-
Index-Nr. 601-012-00-4 Components/Impurities
Chemical formula C4H8 Butene 1-
Not available. Index-Nr.: 601-012-00-4
Skin/eye contact
Liquefied gas.
Specific methods
Evacuate area. Wear self-contained breathing apparatus when
- Precautionary Statements entering area unless atmosphere is proved to be safe. Ensure
adequate air ventilation. Eliminate ignition sources.
Clean up methods
so.
Handling
017 / EDV / 19.11.2010

Safety data sheet
Butene 1-
discharges). Refer to supplier's handling instructions. UN 1012 1-Butylene
Storage UN 1012 1-Butylene
8 EXPOSURE CONTROLS/PERSONAL PROTECTION UN 1012 1-Butylene
Labels 2.1
Ensure adequate ventilation. Do not smoke while handling product. EmS FD, SU
cylinders. IATA
Class 2.1
General information UN 1012 1-Butylene
Appearance/Colour: Colourless gas. Labels 2.1
Odour: Sweetish. Poor warning properties at low concentrations. Packing Instruction P200
Other transport information
Boiling point: -6,2 °C an accident or an emergency. Before transporting product
Critical temperature: 146 °C containers ensure that they are firmly secured. Ensure that the
Flammability range: 1,6 %(V) - 10 %(V) cap nut or plug (where provided) is correctly fitted. Ensure that the
Relative density, gas: 2 valve protection device (where provided) is correctly fitted. Ensure
Relative density, liquid: 0,63 adequate ventilation. Ensure compliance with applicable regulations.
Vapour Pressure 20 °C: 2,6 bar
Solubility mg/l water: No reliable data available. 15 REGULATORY INFORMATION
Other data
particularly at or below ground level. Further national regulations
Pressure Vessel Regulation
10 STABILITY AND REACTIVITY Gefahrstoffverordnung (GefStoffV)
Technische Regeln für Gefahrstoffe (TRGS)
Can form explosive mixture with air. May react violently with Water pollution class
oxidants. Not polluting to waters according to VwVwS from 17.05.99.
11 TOXICOLOGICAL INFORMATION 16 OTHER INFORMATION
Acute toxicity Ensure operators understand the flammability hazard. The hazard of
No known toxicological effects from this product. asphyxiation is often overlooked and must be stressed during
operator training. Before using this product in any new process or
experiment, a thorough material compatibility and safety study
12 ECOLOGICAL INFORMATION should be carried out.
General Advice
No known ecological damage caused by this product. Whilst proper care has been taken in the preparation of this
13 DISPOSAL CONSIDERATIONS be accepted. Details given in this document are believed to be
correct at the time of going to press.
General Further information
Do not discharge into areas where there is a risk of forming an Hommel: Handbook of dangerous goods
explosive mixture with air. Waste gas should be flared through a Kühn-Birett: Merkblätter gefährliche Arbeitsstoffe
suitable burner with flash back arrestor. Do not discharge into any Linde safety advice
place where its accumulation could be dangerous. Contact supplier
if guidance is required.
EWC Nr. 16 05 04*
End of document
017 / EDV / 19.11.2010

Safety data sheet
Butene 1-
017 / EDV / 19.11.2010

Safety data sheet
Butane n-, liquified under pressure

Product name None.
Chemical formula C4H10 Butane n-, liquified under pressure
Skin/eye contact
Liquefied gas.
Specific methods
Clean up methods
so.
Handling
014 / EDV / 19.11.2010

Safety data sheet
discharges). Refer to supplier's handling instructions. UN 1011 Butane
Storage UN 1011 Butane
well ventilated place. IMDG
Class 2.1
8 EXPOSURE CONTROLS/PERSONAL PROTECTION UN number and proper shipping name
Exposure limit value UN 1011 Butane
Value type value Note Labels 2.1
TLV (ACGIH) 800 ppm ACGIH 1995 - 1996 Packing Instruction P200
Germany - AGW 1.000 ppm TRGS 900 EmS FD,SU
Personal protection IATA

Protect eyes, face and skin from liquid splashes. Class 2.1
9 PHYSICAL AND CHEMICAL PROPERTIES UN 1011 Butane
Odour: Sweetish. Poor warning properties at low concentrations. Other transport information
Stenchant often added Avoid transport on vehicles where the load space is not separated
from the driver's compartment. Ensure vehicle driver is aware of the
Important information on environment, health and safety potential hazards of the load and knows what to do in the event of
Molecular weight: 58 g/mol an accident or an emergency. Before transporting product
Melting point: -138 °C containers ensure that they are firmly secured. Ensure that the
Boiling point: -0,5 °C cylinder valve is closed and not leaking. Ensure that the valve outlet
Critical temperature: 152 °C cap nut or plug (where provided) is correctly fitted. Ensure that the
Autoignition temperature: 365 °C valve protection device (where provided) is correctly fitted. Ensure
Flammability range: 1,5 %(V) - 8,5 %(V) adequate ventilation. Ensure compliance with applicable regulations.
Relative density, gas: 2,1
Relative density, liquid: 0,6 15 REGULATORY INFORMATION
Vapour Pressure 20 °C: 2 bar
Other data Further national regulations
Gas/vapour heavier than air. May accumulate in confined spaces, Regulations for the prevention of industrial accidents
Water pollution class
Stability and reactivity Not polluting to waters according to VwVwS from 17.05.99.
Can form explosive mixture with air. May react violently with
oxidants. 16 OTHER INFORMATION
Ensure all national/local regulations are observed. Ensure operators
11 TOXICOLOGICAL INFORMATION understand the flammability hazard. The hazard of asphyxiation is
Acute toxicity often overlooked and must be stressed during operator training.
No known toxicological effects from this product. Before using this product in any new process or experiment, a
thorough material compatibility and safety study should be carried
out.
12 ECOLOGICAL INFORMATION Advice
General Whilst proper care has been taken in the preparation of this
No known ecological damage caused by this product. document, no liability for injury or damage resulting from its use can
be accepted. Details given in this document are believed to be
13 DISPOSAL CONSIDERATIONS correct at the time of going to press.
Further information
General Kühn-Birett: Merkblätter gefährliche Arbeitsstoffe
explosive mixture with air. Waste gas should be flared through a Linde safety advice
suitable burner with flash back arrestor. Do not discharge into any No. 14 Handling liquefied petroleum gas
EWC Nr. 16 05 05
014 / EDV / 19.11.2010

Safety data sheet
End of document
014 / EDV / 19.11.2010

Safety data sheet
Isobutane

Product name None.
Isobutane
Chemical formula C4H10 Isobutane
Skin/eye contact
Liquefied gas.
Specific methods
Clean up methods
so.
Handling
075 / EDV / 19.11.2010

Safety data sheet
Isobutane
introducing gas. Do not allow backfeed into the container. Use only EWC Nr. 16 05 04*
properly specified equipment which is suitable for this product, its
supply pressure and temperature. Contact your gas supplier if in 14 TRANSPORT INFORMATION
doubt. Keep away from ignition sources (including static ADR/RID
discharges). Refer to supplier's handling instructions. Class 2 Classification Code 2F
Storage UN number and proper shipping name
Secure cylinders to prevent them falling. Segregate from oxidant UN 1969 Isobutane
gases and other oxidants in store. Keep container below 50°C in a UN 1969 Isobutane
well ventilated place. Observe "Technische Regeln Druckgase Labels 2.1 Hazard number 23
(TRG) 280 Ziffer 5"
IMDG
8 EXPOSURE CONTROLS/PERSONAL PROTECTION Class 2.1
Exposure limit value UN number and proper shipping name
Value type value Note UN 1969 Isobutane
Germany - AGW 1.000 ppm TRGS 900 Labels 2.1
Packing Instruction P200
Personal protection EmS FD,SU
Ensure adequate ventilation. Do not smoke while handling product.
Carry working gloves and protection shoes while handling gas IATA
cylinders. Class 2.1
9 PHYSICAL AND CHEMICAL PROPERTIES UN 1969 Isobutane
Odour: Sweetish. Poor warning properties at low concentrations. Other transport information
Stenchant often added Avoid transport on vehicles where the load space is not separated
from the driver's compartment. Ensure vehicle driver is aware of the
Important information on environment, health and safety potential hazards of the load and knows what to do in the event of
Molecular weight: 58 g/mol an accident or an emergency. Before transporting product
Melting point: -159 °C containers ensure that they are firmly secured. Ensure that the
Boiling point: -12 °C cylinder valve is closed and not leaking. Ensure that the valve outlet
Critical temperature: 135 °C cap nut or plug (where provided) is correctly fitted. Ensure that the
Autoignition temperature: 460 °C valve protection device (where provided) is correctly fitted. Ensure
Flammability range: 1,3 %(V) - 8,5 %(V) adequate ventilation. Ensure compliance with applicable regulations.
Relative density, gas: 2
Relative density, liquid: 0,59 15 REGULATORY INFORMATION
Vapour Pressure 20 °C: 3 bar
Other data Further national regulations
Gas/vapour heavier than air. May accumulate in confined spaces, Regulations for the prevention of industrial accidents
Water pollution class
Stability and reactivity Not polluting to waters according to VwVwS from 17.05.99.
oxidants. 16 OTHER INFORMATION
11 TOXICOLOGICAL INFORMATION understand the flammability hazard. Contact with liquid may cause
Acute toxicity cold burns/frost bite. The hazard of asphyxiation is often overlooked
No known toxicological effects from this product. and must be stressed during operator training. Before using this
product in any new process or experiment, a thorough material
compatibility and safety study should be carried out.
12 ECOLOGICAL INFORMATION Advice
General Whilst proper care has been taken in the preparation of this
No known ecological damage caused by this product. document, no liability for injury or damage resulting from its use can
13 DISPOSAL CONSIDERATIONS correct at the time of going to press.
Further information
General Kühn-Birett: Merkblätter gefährliche Arbeitsstoffe
explosive mixture with air. Waste gas should be flared through a Linde safety advice
suitable burner with flash back arrestor. Do not discharge into any
075 / EDV / 19.11.2010

Safety data sheet
Isobutane
End of document
075 / EDV / 19.11.2010

Safety data sheet
1,3-Butadiene, stabilized
1 IDENTIFICATION OF THE SUBSTANCE/PREPARATION AND Precautionary Statement Reaction

OF THE COMPANY P377 Leaking gas fire: Do not extinguish,
Product name unless leakcan be stopped safely.
1,3-Butadiene, stabilized P308 + P313 IF exposed or concerned: Get medical
EC No (from EINECS): 203-450-8 advice/attention.
CAS No: 106-99-0 P381 Eliminate all ignition sources if safe to do
Index-Nr. 601-013-00-X so.
Chemical formula C4H6
REACH Registration number: Precautionary Statement Storage
Not available. P403 Store in a well-ventilated place.
Known uses
Not known. Precautionary Statement Disposal
Company identification None.
Linde AG, Linde Gas Division, Seitnerstraße 70, D-82049 Pullach
E-Mail Address Info@de.linde-gas.com 3 COMPOSITION/INFORMATION ON INGREDIENTS
Emergency phone numbers (24h): 089-7446-0 Substance/Preparation: Substance.
Components/Impurities
2 HAZARDS IDENTIFICATION 1,3-Butadiene, stabilized
Classification of the substance or mixture CAS No: 106-99-0
Index-Nr.: 601-013-00-X
Classification acc. to Regulation (EC) No 1272/2008/EC EC No (from EINECS): 203-450-8
(CLP/GHS) REACH Registration number:
Press. Gas (Liquefied gas) - Contains gas under pressure; may Not available.
explode if heated. Contains no other components or impurities which will influence the
Flam. Gas 1 - Extremely flammable gas. classification of the product.
Carc. 1A - May cause cancer.
Muta. 1B - May cause genetic defects. 4 FIRST AID MEASURES
Inhalation
Classification acc. to Directive 67/548/EEC & 1999/45/EC May have carcinogenic effect. May cause heritable genetic damage
F+; R12, R45, R46 | Carc. Cat.1; R45 | Mut. Cat.2; R46 In low concentrations may cause narcotic effects. Symptoms may
Extremely flammable. include dizziness, headache, nausea and loss of co-ordination. In
May cause cancer. high concentrations may cause asphyxiation. Symptoms may
May cause heritable genetic damage include loss of mobility/consciousness. Victim may not be aware of
Risk advice to man and the environment asphyxiation. Remove victim to uncontaminated area wearing self
Liquefied gas. contained breathing apparatus. Keep victim warm and rested. Call a
Contact with liquid may cause cold burns/frost bite. doctor. Apply artificial respiration if breathing stopped.
Label Elements Skin/eye contact
For liquid spillage - flush with water for at least 15 minutes Obtain
- Labelling Pictograms medical assistance.
Ingestion
Ingestion is not considered a potential route of exposure.
5 FIRE FIGHTING MEASURES

Specific hazards
- Signal word Hazardous combustion products
Danger Incomplete combustion may form carbon monoxide.
- Hazard Statements All known extinguishants can be used.
H280 Contains gas under pressure; may Specific methods
explode if heated. If possible, stop flow of product. Move container away or cool with
H220 Extremely flammable gas. water from a protected position. Do not extinguish a leaking gas
H350 May cause cancer. flame unless absolutely necessary. Spontaneous/explosive re-
H340 May cause genetic defects. ignition may occur. Extinguish any other fire.
- Precautionary Statements Use self-contained breathing apparatus and chemically protective
clothing.
Precautionary Statement Prevention
P210 Keep away from heat/sparks/open 6 ACCIDENTAL RELEASE MEASURES
flames/hot surfaces. - No smoking. Personal precautions
P202 Do not handle until all safety precautions Evacuate area. Eliminate ignition sources. Ensure adequate air
have been read and understood. ventilation. Wear self-contained breathing apparatus when entering
area unless atmosphere is proved to be safe.
013 / EDV / 25.08.2009

Safety data sheet
Environmental precautions May cause cancer.

Try to stop release. Prevent from entering sewers, basements and May cause heritable genetic damage
workpits, or any place where its accumulation can be dangerous.
Clean up methods
Ventilate area. Keep area evacuated and free from ignition sources 12 ECOLOGICAL INFORMATION
until any spilled liquid has evaporated. (Ground free from frost). General
No known ecological damage caused by this product.
7 HANDLING AND STORAGE
Handling 13 DISPOSAL CONSIDERATIONS
Ensure equipment is adequately earthed. Suck back of water into General
the container must be prevented. Purge air from system before Avoid discharge to atmosphere. Do not discharge into any place
introducing gas. Do not allow backfeed into the container. Use only where its accumulation could be dangerous. Toxic and corrosive
properly specified equipment which is suitable for this product, its gases formed during combustion should be scrubbed before
supply pressure and temperature. Contact your gas supplier if in discharge to atmosphere. Do not discharge into areas where there
doubt. Keep away from ignition sources (including static is a risk of forming an explosive mixture with air. Waste gas should
discharges). Refer to supplier's handling instructions. be flared through a suitable burner with flash back arrestor. Contact
Storage supplier if guidance is required.
Secure cylinders to prevent them falling. Segregate from oxidant EWC Nr. 16 05 04*
well ventilated place. Observe "Technische Regeln Druckgase 14 TRANSPORT INFORMATION
(TRG) 280 Ziffer 5"
ADR/RID
8 EXPOSURE CONTROLS/PERSONAL PROTECTION Class 2 Classification Code 2F
Exposure limit value UN 1010 Butadiene, stabilized
Value type value Note UN 1010 Butadiene, stabilized
TLV (ACGIH) 10 ppm ACGIH 1995 - 1996 Labels 2.1 Hazard number 239
Germany - TRK 5 ppm TRGS 900
IMDG
Personal protection Class 2.1
Ensure adequate ventilation. Do not smoke while handling product. UN number and proper shipping name
Keep self contained breathing apparatus readily available for UN 1010 Butadiene, stabilized
emergency use. Carry working gloves and protection shoes while Labels 2.1
handling gas cylinders. Packing Instruction P200
EmS FD,SU
9 PHYSICAL AND CHEMICAL PROPERTIES
General information IATA
Appearance/Colour: Colourless gas. Class 2.1
Odour: Poor warning properties at low concentrations. UN number and proper shipping name
Important information on environment, health and safety UN 1010 Butadiene, stabilized
Molecular weight: 54 g/mol
Melting point: -109 °C Packing Instruction P200
Boiling point: -4,5 °C Other transport information
Critical temperature: 152 °C Avoid transport on vehicles where the load space is not separated
Autoignition temperature: 415 °C from the driver's compartment. Ensure vehicle driver is aware of the
Flammability range: 1,4 %(V) - 16,3 %(V) potential hazards of the load and knows what to do in the event of
Relative density, gas: 1,9 an accident or an emergency. Before transporting product
Relative density, liquid: 0,65 containers ensure that they are firmly secured. Ensure that the
Vapour Pressure 20 °C: 2,4 bar cylinder valve is closed and not leaking. Ensure that the valve outlet
Solubility mg/l water: 1025 mg/l cap nut or plug (where provided) is correctly fitted. Ensure that the
Other data valve protection device (where provided) is correctly fitted. Ensure
Gas/vapour heavier than air. May accumulate in confined spaces, adequate ventilation. Ensure compliance with applicable regulations.
15 REGULATORY INFORMATION
10 STABILITY AND REACTIVITY Water pollution class
Stability and reactivity according to §19 WGH Annex 1 : WGK 2 (water endangering)
oxidants. May polymerise. Inhibitor usually added. 16 OTHER INFORMATION
11 TOXICOLOGICAL INFORMATION understand the toxicity hazard. Ensure operators understand the
flammability hazard. Users of breathing apparatus must be trained.
Acute toxicity Before using this product in any new process or experiment, a
Anaesthetizing. thorough material compatibility and safety study should be carried
Carcinogenic, mutagenic and teratogenic effects out.
013 / EDV / 25.08.2009

Safety data sheet
Advice
Further information
Hommel: Handbook of dangerous goods
Linde safety advice
End of document
013 / EDV / 25.08.2009

Safety data sheet
Butadiene 1,2-
1 IDENTIFICATION OF THE SUBSTANCE/PREPARATION AND P403 Store in a well-ventilated place.

OF THE COMPANY
Product name Precautionary Statement Disposal
Butadiene 1,2- None.
EC No (from EINECS): 209-674-2
CAS No: 590-19-2 3 COMPOSITION/INFORMATION ON INGREDIENTS
Index-Nr. Substance/Preparation: Substance.
Chemical formula C4H6 Components/Impurities
REACH Registration number: Butadiene 1,2-
Not available. CAS No: 590-19-2
Known uses Index-Nr.:
Industrial application. EC No (from EINECS): 209-674-2
Company identification REACH Registration number:
Linde AG, Linde Gas Division, Seitnerstraße 70, D-82049 Pullach Not available.
E-Mail Address Info@de.linde-gas.com Contains no other components or impurities which will influence the
Emergency phone numbers (24h): 089-7446-0 classification of the product.
2 HAZARDS IDENTIFICATION 4 FIRST AID MEASURES

Classification of the substance or mixture Inhalation
Symptoms may include dizziness, headache, nausea and loss of co-
Classification acc. to Regulation (EC) No 1272/2008/EC ordination. In high concentrations may cause asphyxiation.
(CLP/GHS) Symptoms may include loss of mobility/consciousness. Victim may
Press. Gas (Liquefied gas) - Contains gas under pressure; may not be aware of asphyxiation. Remove victim to uncontaminated
explode if heated. area wearing self contained breathing apparatus. Keep victim warm
Flam. Gas 1 - Extremely flammable gas. and rested. Call a doctor. Apply artificial respiration if breathing
stopped. In low concentrations may cause narcotic effects.
Classification acc. to Directive 67/548/EEC & 1999/45/EC: Symptoms may include dizziness, headache, nausea and loss of co-
Proposed by the industry ordination.
F+; R12 Skin/eye contact
Extremely flammable. For liquid spillage - flush with water for at least 15 minutes Obtain
Risk advice to man and the environment medical assistance.
Liquefied gas. Ingestion
Contact with liquid may cause cold burns/frost bite. Ingestion is not considered a potential route of exposure.
Label Elements
5 FIRE FIGHTING MEASURES
- Labelling Pictograms Specific hazards
Hazardous combustion products
Specific methods
- Signal word If possible, stop flow of product. Move container away or cool with
Danger water from a protected position. Do not extinguish a leaking gas
flame unless absolutely necessary. Spontaneous/explosive re-
- Hazard Statements ignition may occur. Extinguish any other fire.
H280 Contains gas under pressure; may Special protective equipment for fire fighters
explode if heated. In confined space use self-contained breathing apparatus.
H220 Extremely flammable gas.
- Precautionary Statements Personal precautions
Evacuate area. Eliminate ignition sources. Ensure adequate air
Precautionary Statement Prevention ventilation. Wear self-contained breathing apparatus when entering
P210 Keep away from heat/sparks/open area unless atmosphere is proved to be safe.
flames/hot surfaces. - No smoking. Environmental precautions
Try to stop release. Prevent from entering sewers, basements and
Precautionary Statement Response workpits, or any place where its accumulation can be dangerous.
P377 Leaking gas fire: Do not extinguish, Clean up methods
unless leak can be stopped safely. Ventilate area. Keep area evacuated and free from ignition sources
P381 Eliminate all ignition sources if safe to do until any spilled liquid has evaporated. (Ground free from frost).
so.
012 / EDV / 31.01.2011

Safety data sheet
Butadiene 1,2-
7 HANDLING AND STORAGE Avoid discharge to atmosphere. Do not discharge into any place
Handling where its accumulation could be dangerous. Do not discharge into
Ensure equipment is adequately earthed. Suck back of water into areas where there is a risk of forming an explosive mixture with air.
the container must be prevented. Purge air from system before Waste gas should be flared through a suitable burner with flash
introducing gas. Do not allow backfeed into the container. Use only back arrestor. Contact supplier if guidance is required.
properly specified equipment which is suitable for this product, its EWC Nr. 16 05 04*
supply pressure and temperature. Contact your gas supplier if in
doubt. Keep away from ignition sources (including static 14 TRANSPORT INFORMATION
discharges). Refer to supplier's handling instructions. ADR/RID
Storage Class 2 Classification Code 2F
Secure cylinders to prevent them falling. Segregate from oxidant UN number and proper shipping name
gases and other oxidants in store. Keep container below 50°C in a UN 1010 Butadiene, stabilized
well ventilated place. Observe "Technische Regeln Druckgase UN 1010 Butadiene, stabilized
(TRG) 280 Ziffer 5" Labels 2.1 Hazard number 239
8 EXPOSURE CONTROLS/PERSONAL PROTECTION IMDG

Class 2.1
Personal protection UN number and proper shipping name
Protect eyes, face and skin from liquid splashes. Ensure adequate UN 1010 Butadiene, stabilized
ventilation. Do not smoke while handling product. Keep self Labels 2.1
contained breathing apparatus readily available for emergency use. Packing Instruction P200
Wear working gloves and protection shoes while handling gas EmS FD,SU
cylinders.
IATA
9 PHYSICAL AND CHEMICAL PROPERTIES Class 2.1
General information UN 1010 Butadiene, stabilized
Appearance/Colour: Colourless gas.
Odour: Poor warning properties at low concentrations. Packing Instruction P200
Important information on environment, health and safety Other transport information
Molecular weight: 54 g/mol Ensure vehicle driver is aware of the potential hazards of the load
Boiling point: 18,50 °C and knows what to do in the event of an accident or an emergency.
Critical temperature: 176 °C Before transporting product containers ensure that they are firmly
Autoignition temperature: 340 °C secured. Ensure that the cylinder valve is closed and not leaking.
Flammability range: 1,6 %(V) - 18,3 %(V) Ensure that the valve outlet cap nut or plug (where provided) is
Relative density, gas: 1,9 correctly fitted. Ensure that the valve protection device (where
Relative density, liquid: 0,65 provided) is correctly fitted. Ensure adequate ventilation. Ensure
Vapour Pressure 20 °C: 1,4 bar compliance with applicable regulations. Avoid transport on vehicles
Other data where the load space is not separated from the driver's
Gas/vapour heavier than air. May accumulate in confined spaces, compartment.
10 STABILITY AND REACTIVITY
Stability and reactivity Further national regulations
Can form explosive mixture with air. May react violently with Regulations for the prevention of industrial accidents
oxidants. May decompose violently at high temperature and/or Pressure Vessel Regulation
pressure or in the presence of a catalyst May react with bases, Gefahrstoffverordnung (GefStoffV)
copper, silver, mercury, magnesium, zinc and their alloys. Inhibitor Technische Regeln für Gefahrstoffe (TRGS)
usually added. Water pollution class
according to §19 WGH Annex 1 : WGK 1 (slightly water
11 TOXICOLOGICAL INFORMATION endangering)
Acute toxicity
Anaesthetizing. 16 OTHER INFORMATION
understand the toxicity hazard. Ensure operators understand the
12 ECOLOGICAL INFORMATION flammability hazard. Users of breathing apparatus must be trained.
Before using this product in any new process or experiment, a
Advice
General document, no liability for injury or damage resulting from its use can
012 / EDV / 31.01.2011

Safety data sheet
Butadiene 1,2-

Further information
Linde safety advice
End of document
012 / EDV / 31.01.2011

Safety data sheet
Hydrogen compressed
Creation date : 28.01.2005 Version : 2.0 DE / E SDS No. : 8360/7

OF THE COMPANY Precautionary Statement Reaction
Product name P377 Leaking gas fire: Do not extinguish,
Hydrogen compressed unless leakcan be stopped safely.
Trade name P381 Eliminate all ignition sources if safe to do
Gasart 318 Wasserstoff 3.0 so.
Gasart 319 Wasserstoff 3.8
Gasart 320 Wasserstoff 5.0 Precautionary Statement Storage
Gasart 321 Wasserstoff 5.3/ECD P403 Store in a well-ventilated place.
Gasart 322 Wasserstoff 5.6
Gasart 322 Wasserstoff 6.0 Precautionary Statement Disposal
EC No (from EINECS): 215-605-7 None.
CAS No: 1333-74-0
Index-Nr. 3 COMPOSITION/INFORMATION ON INGREDIENTS
Chemical formula H2 Substance/Preparation: Substance.
REACH Registration number: Components/Impurities
Listed in Annex IV/V of Regulation (EC) No 1907/2006 (REACH), Hydrogen compressed
exempted from registration. CAS No: 1333-74-0
Known uses Index-Nr.:
Not known. EC No (from EINECS): 215-605-7
Company identification REACH Registration number:
Linde AG, Linde Gas Division, Seitnerstraße 70, D-82049 Pullach Listed in Annex IV/V of Regulation (EC) No 1907/2006 (REACH),
E-Mail Address Info@de.linde-gas.com exempted from registration.
Emergency phone numbers (24h): 089-7446-0 Contains no other components or impurities which will influence the
classification of the product.
2 HAZARDS IDENTIFICATION
Classification of the substance or mixture 4 FIRST AID MEASURES
Inhalation
Classification acc. to Regulation (EC) No 1272/2008/EC In high concentrations may cause asphyxiation. Symptoms may
(CLP/GHS) include loss of mobility/consciousness. Victim may not be aware of
Press. Gas (Compressed gas) - Contains gas under pressure; may asphyxiation. Remove victim to uncontaminated area wearing self
Classification acc. to Directive 67/548/EEC & 1999/45/EC 5 FIRE FIGHTING MEASURES

F+; R12 Specific hazards
Extremely flammable. Exposure to fire may cause containers to rupture/explode.
Risk advice to man and the environment Hazardous combustion products
This gas is not intended for filling ballons for play and advertising None.
purposes because of the danger of explosion. Suitable extinguishing media
Compressed gas. All known extinguishants can be used.
Label Elements Specific methods
- Labelling Pictograms water from a protected position. Do not extinguish a leaking gas
ignition may occur. Extinguish any other fire.
In confined space use self-contained breathing apparatus.

- Signal word Personal precautions
Danger Wear self-contained breathing apparatus when entering area unless
atmosphere is proved to be safe. Evacuate area. Ensure adequate
- Hazard Statements air ventilation. Eliminate ignition sources.
H280 Contains gas under pressure; may Environmental precautions
explode if heated. Try to stop release.
H220 Extremely flammable gas. Clean up methods
Ventilate area.
- Precautionary Statements
Precautionary Statement Prevention
Handling
P210 Keep away from heat/sparks/open
flames/hot surfaces. - No smoking.
8360/7 / EDV / 19.11.2010

Safety data sheet
Hydrogen compressed

the container must be prevented. Purge air from system before 14 TRANSPORT INFORMATION
introducing gas. Do not allow backfeed into the container. Use only ADR/RID
properly specified equipment which is suitable for this product, its Class 2 Classification Code 1F
supply pressure and temperature. Contact your gas supplier if in UN number and proper shipping name
doubt. Keep away from ignition sources (including static UN 1049 Hydrogen, compressed
discharges). Refer to supplier's handling instructions. UN 1049 Hydrogen, compressed
Storage Labels 2.1 Hazard number 23
Secure cylinders to prevent them falling. Segregate from oxidant Packing Instruction P200
8 EXPOSURE CONTROLS/PERSONAL PROTECTION UN 1049 Hydrogen, compressed
Labels 2.1
Ensure adequate ventilation. Do not smoke while handling product. EmS FD, SU
cylinders. IATA
Class 2.1
General information UN 1049 Hydrogen, compressed
Odour: None. Packing Instruction P200
Other transport information
Boiling point: -253 °C an accident or an emergency. Before transporting product
Critical temperature: -240 °C containers ensure that they are firmly secured. Ensure that the
Flammability range: 4 %(V) - 75 %(V) cap nut or plug (where provided) is correctly fitted. Ensure that the
Relative density, gas: 0,07 valve protection device (where provided) is correctly fitted. Ensure
Relative density, liquid: Not applicable. adequate ventilation. Ensure compliance with applicable regulations.
Vapour Pressure 20 °C: Not applicable.
Solubility mg/l water: 1,6 mg/l 15 REGULATORY INFORMATION
Maximum filling pressure (bar): 200 bar
Other data
Burns with a colourless invisible flame. Further national regulations
Regulations for the prevention of industrial accidents
10 STABILITY AND REACTIVITY Pressure Vessel Regulation
Stability and reactivity Technische Regeln für Gefahrstoffe (TRGS)
Acute toxicity Ensure all national/local regulations are observed. Ensure operators
No known toxicological effects from this product. understand the flammability hazard. The hazard of asphyxiation is
12 ECOLOGICAL INFORMATION thorough material compatibility and safety study should be carried
General out.
General correct at the time of going to press.
Do not discharge into areas where there is a risk of forming an Further information
suitable burner with flash back arrestor. Waste gas should be flared Hommel: Handbook of dangerous goods
through a suitable burner with flash back arrestor. Do not discharge Linde safety advice
into any place where its accumulation could be dangerous. Contact No. 3 Oxygen deficiency
supplier if guidance is required. No. 7 Safe handling of gas cylinders and cylinder bundles
EWC Nr. 16 05 04*
8360/7 / EDV / 19.11.2010

Safety data sheet
Hydrogen compressed
No. 11 Transport of gas receptacles in vehicles

No. 13 Handling of hydrogen
End of document
8360/7 / EDV / 19.11.2010

Safety data sheet
methane

Product name None.
methane
Chemical formula CH4 methane
Press. Gas (Compressed gas) - Contains gas under pressure; may ordination. Remove victim to uncontaminated area wearing self
Classification acc. to Directive 67/548/EEC & 1999/45/EC 5 FIRE FIGHTING MEASURES

F+; R12 Specific hazards
Extremely flammable. Exposure to fire may cause containers to rupture/explode.
Risk advice to man and the environment Hazardous combustion products
Compressed gas. Incomplete combustion may form carbon monoxide.
Label Elements All known extinguishants can be used.
Specific methods
- Labelling Pictograms If possible, stop flow of product. Move container away or cool with
ignition may occur. Extinguish any other fire.
In confined space use self-contained breathing apparatus.
- Signal word 6 ACCIDENTAL RELEASE MEASURES

Danger Personal precautions
- Hazard Statements atmosphere is proved to be safe. Evacuate area. Ensure adequate
H280 Contains gas under pressure; may air ventilation. Eliminate ignition sources.
explode if heated. Environmental precautions
H220 Extremely flammable gas. Try to stop release.
Clean up methods
- Precautionary Statements Ventilate area.
Precautionary Statement Prevention 7 HANDLING AND STORAGE

P210 Keep away from heat/sparks/open
Handling
flames/hot surfaces. - No smoking.
Precautionary Statement Reaction
introducing gas. Do not allow backfeed into the container. Use only
P377 Leaking gas fire: Do not extinguish,
properly specified equipment which is suitable for this product, its
supply pressure and temperature. Contact your gas supplier if in
P381 Eliminate all ignition sources if safe to do
doubt. Keep away from ignition sources (including static
so.
discharges). Refer to supplier's handling instructions.
Storage
8321 / EDV / 19.11.2010

Safety data sheet
methane
Secure cylinders to prevent them falling. Segregate from oxidant 14 TRANSPORT INFORMATION
gases and other oxidants in store. Keep container below 50°C in a ADR/RID
well ventilated place. Observe "Technische Regeln Druckgase Class 2 Classification Code 1F
(TRG) 280 Ziffer 5" UN number and proper shipping name
UN 1971 Methane, compressed
8 EXPOSURE CONTROLS/PERSONAL PROTECTION UN 1971 Methane, compressed
Labels 2.1 Hazard number 23
Ensure adequate ventilation. Do not smoke while handling product.
Carry working gloves and protection shoes while handling gas IMDG
cylinders. Class 2.1
9 PHYSICAL AND CHEMICAL PROPERTIES UN 1971 Methane, compressed
Odour: None. EmS FD, SU
Important information on environment, health and safety IATA
Molecular weight: 16 g/mol Class 2.1
Melting point: -182 °C UN number and proper shipping name
Boiling point: -161 °C UN 1971 Methane, compressed
Critical temperature: -82 °C Labels 2.1
Autoignition temperature: 595 °C Packing Instruction P200
Flammability range: 4,4 %(V) - 15 %(V) Other transport information
Relative density, gas: 0,6 Avoid transport on vehicles where the load space is not separated
Relative density, liquid: Not applicable. from the driver's compartment. Ensure vehicle driver is aware of the
Vapour Pressure 20 °C: Not applicable. potential hazards of the load and knows what to do in the event of
Solubility mg/l water: 26 mg/l an accident or an emergency. Before transporting product
Maximum filling pressure (bar): 200 bar containers ensure that they are firmly secured. Ensure that the
cylinder valve is closed and not leaking. Ensure that the valve outlet
10 STABILITY AND REACTIVITY cap nut or plug (where provided) is correctly fitted. Ensure that the
Stability and reactivity valve protection device (where provided) is correctly fitted. Ensure
Can form explosive mixture with air. May react violently with adequate ventilation. Ensure compliance with applicable regulations.
oxidants.
Acute toxicity Further national regulations
No known toxicological effects from this product. Pressure Vessel Regulation
12 ECOLOGICAL INFORMATION Regulations for the prevention of industrial accidents
General Water pollution class
No known ecological damage caused by this product. Not polluting to waters according to VwVwS from 17.05.99.
13 DISPOSAL CONSIDERATIONS 16 OTHER INFORMATION

General understand the flammability hazard. The hazard of asphyxiation is
Do not discharge into areas where there is a risk of forming an often overlooked and must be stressed during operator training.
explosive mixture with air. Waste gas should be flared through a Before using this product in any new process or experiment, a
suitable burner with flash back arrestor. Waste gas should be flared thorough material compatibility and safety study should be carried
through a suitable burner with flash back arrestor. Do not discharge out.
into any place where its accumulation could be dangerous. Contact Advice
supplier if guidance is required. Whilst proper care has been taken in the preparation of this
EWC Nr. 16 05 04* document, no liability for injury or damage resulting from its use can
Further information
Linde safety advice
No. 3 Oxygen deficiency
No. 7 Safe handling of gas cylinders and cylinder bundles
No. 11 Transport of gas receptacles in vehicles
8321 / EDV / 19.11.2010

Safety data sheet
methane
End of document
8321 / EDV / 19.11.2010

Safety data sheet
Propylene

Product name None.
Propylene
Chemical formula C3H6 Propylene
Skin/eye contact
Liquefied gas.
Specific methods
- Precautionary Statements atmosphere is proved to be safe. Ensure adequate air ventilation.
Evacuate area. Eliminate ignition sources.
Clean up methods
so.
Handling
105 / EDV / 19.11.2010

Safety data sheet
Propylene
discharges). Refer to supplier's handling instructions. UN 1077 Propylene
Storage UN 1077 Propylene
8 EXPOSURE CONTROLS/PERSONAL PROTECTION UN 1077 Propylene
Labels 2.1
cylinders. IATA
Class 2.1
General information UN 1077 Propylene
Stenchant often added Other transport information
Avoid transport on vehicles where the load space is not separated
Important information on environment, health and safety from the driver's compartment. Ensure vehicle driver is aware of the
Molecular weight: 42 g/mol potential hazards of the load and knows what to do in the event of
Melting point: -185 °C an accident or an emergency. Before transporting product
Boiling point: -47,7 °C containers ensure that they are firmly secured. Ensure that the
Critical temperature: 92,4 °C cylinder valve is closed and not leaking. Ensure that the valve outlet
Autoignition temperature: 455 °C cap nut or plug (where provided) is correctly fitted. Ensure that the
Flammability range: 2 %(V) - 11 %(V) valve protection device (where provided) is correctly fitted. Ensure
Relative density, gas: 1,5 adequate ventilation. Ensure compliance with applicable regulations.
Relative density, liquid: 0,6
Solubility mg/l water: 384 mg/l 15 REGULATORY INFORMATION
Other data
particularly at or below ground level. Further national regulations
Pressure Vessel Regulation
10 STABILITY AND REACTIVITY Gefahrstoffverordnung (GefStoffV)
Acute toxicity Ensure all national/local regulations are observed. Ensure operators
No known toxicological effects from this product. understand the flammability hazard. The hazard of asphyxiation is
12 ECOLOGICAL INFORMATION thorough material compatibility and safety study should be carried
General out.
General correct at the time of going to press.
Do not discharge into areas where there is a risk of forming an Further information
place where its accumulation could be dangerous. Contact supplier Linde safety advice
EWC Nr. 16 05 04*
105 / EDV / 19.11.2010

Safety data sheet
Propylene
End of document
105 / EDV / 19.11.2010

Safety data sheet
Propane

Product name None.
Propane
Chemical formula C3H8 Propane
Skin/eye contact
Liquefied gas.
Specific methods
- Precautionary Statements atmosphere is proved to be safe. Ensure adequate air ventilation.
Evacuate area. Eliminate ignition sources.
Clean up methods
so.
Handling
104 / EDV / 19.11.2010

Safety data sheet
Propane
introducing gas. Do not allow backfeed into the container. Use only place where its accumulation could be dangerous. Contact supplier
properly specified equipment which is suitable for this product, its if guidance is required.
supply pressure and temperature. Contact your gas supplier if in EWC Nr. 16 05 04*
doubt. Keep away from ignition sources (including static
discharges). Refer to supplier's handling instructions. 14 TRANSPORT INFORMATION
Storage ADR/RID
Secure cylinders to prevent them falling. Segregate from oxidant Class 2 Classification Code 2F
gases and other oxidants in store. Keep container below 50°C in a UN number and proper shipping name
well ventilated place. Observe "Technische Regeln Druckgase UN 1978 Propane
(TRG) 280 Ziffer 5" UN 1978 Propane
Labels 2.1 Hazard number 23
8 EXPOSURE CONTROLS/PERSONAL PROTECTION
Exposure limit value IMDG
Value type value Note Class 2.1
TLV (ACGIH) 2.500 ppm ACGIH 1995 - 1996 UN number and proper shipping name
Germany - AGW 1.000 ppm TRGS 900 UN 1978 Propane
Labels 2.1
cylinders. IATA
Class 2.1
General information UN 1978 Propane
Stenchant often added Other transport information
Avoid transport on vehicles where the load space is not separated
Important information on environment, health and safety from the driver's compartment. Ensure vehicle driver is aware of the
Molecular weight: 44 g/mol potential hazards of the load and knows what to do in the event of
Melting point: -188 °C an accident or an emergency. Before transporting product
Boiling point: -42,1 °C containers ensure that they are firmly secured. Ensure that the
Critical temperature: 97 °C cylinder valve is closed and not leaking. Ensure that the valve outlet
Autoignition temperature: 470 °C cap nut or plug (where provided) is correctly fitted. Ensure that the
Flammability range: 2,2 %(V) - 9,5 %(V) valve protection device (where provided) is correctly fitted. Ensure
Relative density, gas: 1,5 adequate ventilation. Ensure compliance with applicable regulations.
Relative density, liquid: 0,58
Vapour Pressure 20 °C: 8,3 bar 15 REGULATORY INFORMATION
Other data
Gas/vapour heavier than air. May accumulate in confined spaces, Further national regulations
Regulations for the prevention of industrial accidents
Stability and reactivity Water pollution class
Can form explosive mixture with air. May react violently with Not polluting to waters according to VwVwS from 17.05.99.
oxidants. TA-Luft
Not classified according to TA-Luft.
Advice
suitable burner with flash back arrestor. Do not discharge into any Kühn-Birett: Merkblätter gefährliche Arbeitsstoffe
104 / EDV / 19.11.2010

Safety data sheet
Propane

Linde safety advice
End of document
104 / EDV / 19.11.2010

I
I=?.*&. .
.-.
=a
.
(NONG K0MG)TOPSHIP CHEMICALS TRADING CO., LTD

Add.: UNIT 618419. BE., ADVANCED TECHNOLOGY CENTRE, 2 CHOl FAR RD.,
SHNNG SHUI, N.T. HK
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Dimethyl disulphide, 99.5%
I
MS& Nsme: Dimethyl disulphide, 99.5%
Catalog Numbers: AC165590000, AC165590010, ACl65592500
Synonyms: Methyl drsolfide; DlmethyldisuIfi&; Disulflde, dimethyl
For infometion in Nmrth Amerly call: 8OU-ACROS-01
Far emeraencies in the US, cafl CHEMTREC: 800-424-9390:
EMERGENCY OVERVIEW
Appeamnce:dear,wl~~Iess Ijquid. Flash Point: 15 deg C.
Dangorl Highly toxic. May be fatal if inhaled. Fiammabla liquid and vapor.
Q u s s resptmtory traa irritetlon. Oauseseyeand skin irritation. Stench. May cause
digestive Crsa irritation. &@ration hazard if swallowed. Can enter fungsand muse
damage. May be harmful if swallowed. May muse blood abnormalities. May cause
centra! nervous system effects.
Target Orgem: blood, heart, spleen, lungs, lymph nodes.
Potenttal Health Effects

Eyer Causes eye irrltatii.
Skb: askl3 i M W . HBY -We dW-5.
In@estbnrMay cause gastrointestinal irritationwith nausea, vomiting and diarrhea.
May cause liver damage. May be hatmfut if swalfowed.
%halathan: May be btal ff inhaled. Vapors may cause dizziness or suffocation.
(HONG K0NG)TOPSHIP CHEMICALS TRADlNG CO., LTD
Add.: UNIT 618-619. W.. ADVANCED TECHNOLOCjY CENTRE. 2 CHOl FAR RD..
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Causes upper respiratory tract irritation. Exposure may cause Mood abnwmalitigs.
Causes imitation of the m u m u membrane.
Chronic: Effects may be delayed. Exposure t o hlgh concentrations may cause
tearing, cyanosis (bluish discoloration of skin due to deficient oxygenation of the
blood), centml nervous system depression or hemorrhage in the lung. Prolonged or
r e a t e d exDosure may cause hemolvti anemia which can lead to renal failurn.
Eyes: Imrned~atelyflush eyes with plenty of water for at least 15 mlnutes,

ocmsionally llftlng the upper and lower eyeiids. Get medical aid.
Skin: Get medical aid. lmmedrately flush skin with plenty of water for at l?.ast 15
minutes whlle removing contaminated ctothlng and shoes. Wash clothing before
reuse.
Inpestion: Do not induce vomiting. If vlmm is consciousand akrt, gjve 2-4 cupluls
of mllk or water. Never give anything by mouth to an unconscious person. Get
medical aid immediately.
Inhalation: Get medical aid immediately. Remove from exposure and move t o
hedl air immediatety. Ifbreathing is difftcwlt, give oxygen. DO NOT use
mouth-to-mwth resuscitation. If breathing has ceased apply artificial respiration
using oxygen and a suitable mechanical device such as a bag and a mask.
General Imfonnation: As in any fire, wear a self-contained breathing apparatus in

pressure-demand, MSHWIOSH (approved or equivalenl), and full protective gear.
Water runoff can cause environmental damage, Dike and collect water used to fight
fire. Vapors may form an explosive mixture with arr. Vapors can travel to a source of
ignition and flash back. t a n bum In a fire, releasing bxlc vapors. Will bum if
involved in a fire. Use water spray to keep fire-exposed containers cool. Containers
may explode in the heat of a fire. Flammable liquid and vapor. Mpors may be
heavier than air. They can spread along the ground and collect in low or confined
areas. May be ignited by heat, sparks, and flame. Conrainerr may explode when
heated.
Extinguishing Media: Water may be ineffective. Use agent most appropriate to
(HONG K0NG)TOPSHIP CHEMICALS TRADING CO., LTD
Add.. UNrr 6i8-619, W.,
AWANCED TECHNOLOGY CENTRE, 2 CHOI FAR RD.,
SHEUNG SHUI. N T. HK
TEL.:+852-2723-9220. FAX: +852-2721-3906
extinguish fire. Do NOT use straight streams of water. For large fires, use water
spray, fag or regular foam. For small fires, use dry chemical, carbon dioxide, water
spray or regular foam. Cool containers with flooding quantitles of water until well
after fire is out. For large fires flood fire wlth water from a d~stance.
Plash ptnt: 15 deg c(59.00 deg F)
Autoignition Temprrature: Not applicable
Otpiosion Limits, Lower:l.lO ~01%
Upper: 16.08vll YO
NPPA Rating:(astlrnated) Heatth:3;flarnmability:4; Instabi1ity:O
General Infinnatlonr Use proper personal protective equipment as lndlcated in

Section 8.
Spills/Leaks: Absorb spItl with inert matenal (e.g. vermiculite, sand or earth),
then place in suitable container. Use water spray to dilute spifi t o a non-flammable
mixture. Avoid runoff into storm sewers and ditches whkh lead to waterways. Clean
up sp~ilsimmediatdy, observing precautions in the Protective Equipment section.
Remove all sources of ignitton. Absorb spill using an akorbent, non-cumbustible
material such as earth, sand,or v&miculite. Do not use combustible materials such
as sawdust. Use a spark-proof tool. Provide ventilatlon. A vapor suppressing foam
may be used to reduce vapors. Water spray may reduce vapor but may not prevent
Handtlng: Wash thoroughly aRer hanoling. Ground and bond containers when
transferring material. Use spark-proof toots and explosion proof equipment. AvoM
contact with eyes, Skin, and clothing. Empty containers rebin product residue,
(tiquid and/or vapor), and can be dangerous, Keep container tightly cloyed, Keep
away from heat, s p a b and flame. Do mt Ingest or inhale. Use only in a ehemieal
fume hood. Do not pressurirr, at, weld, braze, solder, drill, grlnd, or expose empty
contalnem to heat, sparks or open flames.
Storage: Keep away from heat, sparks, and flame. Keep away from sources of
ignition. Store in a tightly closed container. Store i n a cool, dry, welluentilated area
(HONG K0NG)TOPSHP CHEMICALS TRADING CO., LTD
Add.: UNIT 618619, 6/F, ADVANCED TECHNOLOGY CENTRE. 2 CHOl FAR RD.,
SHRlNG SHUI, N.T. HK
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away from incompatible substances. Flammables-area. Keep containers tightly

closed.
Engineering Controls: Use explosion-pmof ventilation equipment. Fadiities

storing or utilizing this material should be equipped wlth an eyewash facility and a
safety shower. Use only under a chemical fume h a d .
Exmosure Limits
Dimethyl
- diilphtde Inone listed m e listed none iisted i
OSHA Vacated PELS: Dimethyl disulphlde: No OSHA Vacated PELS are listed for
this chemical.
Personal Pmtecthre Equipment
ma: Wear appropriate protective eyeglasses or chemical safety goggles as
described by OSHA's eye and face protection regulations in 29 CFR 1910.133 or
European Standard EN166.
Clothing: Wear appropriate protective clothing to prevent skin exposure.
Rewlrators: A respimtaty protection program that meets OSHA's 29 CFR
1910.134 and ANSI 288.2 requirements or European Standard EN 149 must be
followed whenever ~0rkUlBceconditions warrant a resuitator's use.
PhVritaI Statc: Uquid

-
Apwrence: clear yellow clear, colorless
Odor: stench
pH: Not available.
Evafroratbn Rate:Not available.
Wscooity: 0.620 cP 20 deg C
Boiling Point: 109 deg C @ 760.00mm Hg
Decomposition Tempetaturo:Not available.
bolubiiity: insoluble
Swcifk Oravity/DenslZy?1.0625g/m3
Mdecular Fonnula:clzHIS2
Molecular Waigkt:94.19
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Chemical Stability: Stable under normal temperatures and pressures. Reacts

vigorously with oxldlzing apents. Photochemically oxidized by ozone.
Conditions t o A v d d Incompatible materials, ignition sources, excess heat, strong
oxidants.
kncompatibllities wlth Other Materiak Oxidizing agents, may react with copper,
rubber, and plastic.
Hazardous Decomposition PMdrrcts Carbon monoxide, oxides of sulfur,
initsting and toxic fumes and gases, carbon dioxide, hydrogen wlflde.
Ha?ardous Polymerization: Has not been reported.
RT.-
CAS# 624-92-0: 301927500
lDso/rcso:
CASO 624-92-0:
Dmize test, tabbit, eye: 100 uU24H:
Inhalation, mouse: LC50 = 12300 ug/m3/2H;
Inhalation, rat: LC50 = 15850 ug/m3/2H;<BR.
OPat mk U350 = 535
Cardnagenkity:
CASI 624-92-0: Not Bsted by ACGIH. IARC, NTP, or CA Prop 65.
Epldemlology: No information found.
TeiatogenkZ ~ ~ ~ a t i U n ~ l a b t P . -----
Reproducthre Eff- No information available.

Mutppenldty: No inforrnatEon availabb
Neurataxjcjty: No information avaitable.
tattoxizity: No data available. Estimated Koc varues of36-218suggest moderate

to hlgh soil mobllity of solution-phase Dimethyl disulphide. VolatllizaLton and
(HONG K0NG)TOPSHSP CHEMICALS TRADING CO., LTD
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- -- --4-
photodegradation are expected to be major fate processes for Dimethyl disulphide

In water. Aquatic hydrolysis, b m c e n t r a t i o n and adsorption to sediment are not
expected to be important fate precesses because of the lack d hydmytab~egroup
and high water solub~lity.Based upon a vapor pressure of 28.7 mm Hg at 25 deg C
D~methyld~sulphideis expected to exist prlmary In the vapor phase in the ambient
atmosphere.
Environmental: No inforrnation available.
Physkai: No information avadable.
Other: Plo information available.
Chemical waste generators must determine whether a discarded c h m i

classified as a hazardous waste. US EPA guidelines for the classification
determ~nationare listed in 40 CFR Pam 361.3. Additlonally, waste generamrs must
consult state and local hamrdous waste regulations to ensure complete and
accurate classification.
RCRA P-rfes: None listed.
RCRA U-Series: None listed.
Shlooino name I~irnethvldisulDhlde 199.5 I D~methyld ~ w l W d e

Hazard Class 3 3
YN Number UN2381 2Gl
Packlng Gmup fI I1
Additional Info 1
US FEDERAL
TSCA
CAS# 624-92-0 is listed on the TSCA inventory.
HeaM & Safety Repwthg Upt
None of the chemicals are on the health 5 Safety Reporting Lfst.
(HONGKONG)TOPSHIP CHEMICALS TRADING CO., LTB
Add. UNIT 618-619, 6 / F , ADVANCED TECHNOLOGY CENTRE, 2 CHOl FAR RD
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None of the chem~calsm this product are under a Chemical Test Rule.
W f o n 12b
Mone of the chem~catsare listed under TSCA Section 12b.
TSCA Significant Hew U Y Rulc
None of the chern~calsin this materlal have a SNUR under TSCA.
CERCLA Hazardnus Substances and corresponding RQs
None of the chemicals in this material have an RQ.
SARA Section 302 Extremely Harardws Substances
None of the chemicals in this product have a TPQ.
SARA Codes
CAS # 624-92-0: awte, flammable.
Section 313 No chemicals are reportable under Section 313.
Clean Air Act:
This material does not contain any hazardous air pollutants.
m i s material does not contain any Class 1 Ozone depleton.
This material does not contain any Class 2 Ozone cfepletors.
Clean Wstar Act:
None of the chemicals in thlr; produd are listed as Hazardous Substances under
the CWA.
None of the chemicals in this product are listed as Priority Pollutants under the
MA-
None of the chemicals in this product are listed as Toxic Pollutants under the
WA.
MATE
CWS# 624-92-0 can be found on the following state right to know lists: New
Jersey, Pennsylvania, Wassachusectr
Calrfomia No Significant Risk Level: None of the chemicals in this product are ilsted-
EuropeanfXnternatbnal Regulations
European Labaling in &€Ordance with EC: DireCthis
Hazard Symbols:
T+ F
Risk Phrases:
R llHighly flammable
R 26 Very torlc by inhalation
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SHEUNG SHUI, N.T. HK
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Safety Phrases:
-
S 16 Keep away from sources of ignition No smoking.
S 26 In case of Contad with eyes, rinse immediately with plenty of
water and seek medical adv~cx.
5 33 Take precautionary measures agalnst statrc dfschargas.
S 45 In case of accident or if you feel unwell, seek medical advice
immediately (show the label where possible).
WGK [Water DanSar/Wtectinn)
CAS# 624-92-0: 2
-
Canada DSL/NDSL
CAS# 624-92-0 is listed on Canada's DSL List.
-
Canada WHMIS
This product has a WHMIS dasiflcation of 82, D23.
Canadlan Insredlent Disclosure Llst
MSDS creation ~ a b e : 3 / 0 4 / 1 9 ~
Revision #2 Date 3/U1/2%03
METHANOL
1. Product Identification
Synonyms: Methyl alcohol, carbinol

CAS No.: 67-56-1
Molecular Weight: 32.04
Chemical Formula: CH3OH
Company Identification: ONGIC KOREA (++82 2 581 9637)
2. Composition/Information on Ingredients
Ingredient CAS No Percent Hazardous

------------------------------ ------------ ------------ ---------
Methyl Alcohol 67-56-1 100% Yes
3. Hazards Identification
Emergency Overview
--------------------------
POISON! DANGER! VAPOR HARMFUL. MAY BE FATAL OR CAUSE BLINDNESS IF SWALLOWED.
HARMFUL IF INHALED OR ABSORBED THROUGH SKIN. CANNOT BE MADE NONPOISONOUS.
FLAMMABLE LIQUID AND VAPOR. CAUSES IRRITATION TO SKIN, EYES AND RESPIRATORY TRACT.
AFFECTS CENTRAL NERVOUS SYSTEM AND LIVER.
(tm)
SAF-T-DATA Ratings (Provided here for your convenience)
---------------------------------------------------------------------------------
--------------------------
Health Rating: 3 - Severe (Poison)
Flammability Rating: 3 - Severe (Flammable)
Reactivity Rating: 1 - Slight
Contact Rating: 3 - Severe (Life)
Lab Protective Equip: GOGGLES & SHIELD; LAB COAT & APRON; VENT HOOD; PROPER GLOVES;
CLASS B EXTINGUISHER
Storage Color Code: Red (Flammable)
---------------------------------------------------------------------------------
--------------------------

----------------------------------
Inhalation:
A slight irritant to the mucous membranes. Toxic effects exerted upon nervous system, particularly the
optic nerve. Once absorbed into the body, it is very slowly eliminated. Symptoms of overexposure may
include headache, drowsiness, nausea, vomiting, blurred vision, blindness, coma, and death. A person may
get better but then worse again up to 30 hours later.
Ingestion:
Toxic. Symptoms parallel inhalation. Can intoxicate and cause blindness. Usual fatal dose: 100-125
milliliters.
Skin Contact:
Methyl alcohol is a defatting agent and may cause skin to become dry and cracked. Skin absorption can
occur; symptoms may parallel inhalation exposure.
Eye Contact:
Irritant. Continued exposure may cause eye lesions.
Chronic Exposure:
Marked impairment of vision has been reported. Repeated or prolonged exposure may cause skin
irritation.
Aggravation of Pre-existing Conditions:
Persons with pre-existing skin disorders or eye problems or impaired liver or kidney function may be
more susceptible to the effects of the substance.
4. First Aid Measures
Inhalation:
Remove to fresh air. If not breathing, give artificial respiration. If breathing is difficult, give oxygen. Get
medical attention immediately.
Ingestion:
Induce vomiting immediately as directed by medical personnel. Never give anything by mouth to an
unconscious person. Get medical attention immediately.
Skin Contact:
Immediately flush skin with plenty of water for at least 15 minutes while removing contaminated clothing
and shoes. Get medical attention. Wash clothing before reuse. Thoroughly clean shoes before reuse.
Eye Contact:
Immediately flush eyes with plenty of water for at least 15 minutes, lifting lower and upper eyelids
occasionally. Get medical attention immediately.
5. Fire Fighting Measures
Fire:
Flash point: 12C (54F) CC
Autoignition temperature: 464C (867F)
Flammable limits in air % by volume:
lel: 6.0; uel: 36
Flammable Liquid and Vapor!
Explosion:
Above flash point, vapor-air mixtures are explosive within flammable limits noted above. Moderate
explosion hazard and dangerous fire hazard when exposed to heat, sparks or flames. Sensitive to static
discharge.
Fire Extinguishing Media:
Use alcohol foam, dry chemical or carbon dioxide. (Water may be ineffective.)
Special Information:
In the event of a fire, wear full protective clothing and NIOSH-approved self-contained breathing
apparatus with full facepiece operated in the pressure demand or other positive pressure mode. Use
water spray to blanket fire, cool fire exposed containers, and to flush non-ignited spills or vapors away
from fire. Vapors can flow along surfaces to distant ignition source and flash back.
6. Accidental Release Measures
Ventilate area of leak or spill. Remove all sources of ignition. Wear appropriate personal protective
equipment as specified in Section 8. Isolate hazard area. Keep unnecessary and unprotected personnel
from entering. Contain and recover liquid when possible. Use non-sparking tools and equipment. Collect
liquid in an appropriate container or absorb with an inert material (e. g., vermiculite, dry sand, earth), and
place in a chemical waste container. Do not use combustible materials, such as saw dust. Do not flush to
sewer! If a leak or spill has not ignited, use water spray to disperse the vapors, to protect personnel
attempting to stop leak, and to flush spills away from exposures. US Regulations (CERCLA) require
reporting spills and releases to soil, water and air in excess of reportable quantities. The toll free number
for the US Coast Guard National Response Center is (800) 424-8802.
7. Handling and Storage
Protect against physical damage. Store in a cool, dry well-ventilated location, away from any area where
the fire hazard may be acute. Outside or detached storage is preferred. Separate from incompatibles.
Containers should be bonded and grounded for transfers to avoid static sparks. Storage and use areas
should be No Smoking areas. Use non-sparking type tools and equipment, including explosion proof
ventilation. Containers of this material may be hazardous when empty since they retain product residues
(vapors, liquid); observe all warnings and precautions listed for the product. Do Not attempt to clean
empty containers since residue is difficult to remove. Do not pressurize, cut, weld, braze, solder, drill,
grind or expose such containers to heat, sparks, flame, static electricity or other sources of ignition: they
may explode and cause injury or death.
8. Exposure Controls/Personal Protection
Airborne Exposure Limits:

For Methyl Alcohol:
- OSHA Permissible Exposure Limit (PEL):
200 ppm (TWA)
- ACGIH Threshold Limit Value (TLV):
200 ppm (TWA), 250 ppm (STEL) skin
Ventilation System:
A system of local and/or general exhaust is recommended to keep employee exposures below the
Airborne Exposure Limits. Local exhaust ventilation is generally preferred because it can control the
emissions of the contaminant at its source, preventing dispersion of it into the general work area. Please
refer to the ACGIH document, Industrial Ventilation, A Manual of Recommended Practices, most recent
edition, for details. Use explosion-proof equipment.
Personal Respirators (NIOSH Approved):
If the exposure limit is exceeded and engineering controls are not feasible, wear a supplied air, full-
facepiece respirator, airlined hood, or full-facepiece self-contained breathing apparatus. Breathing air
quality must meet the requirements of the OSHA respiratory protection standard (29CFR1910.134). This
substance has poor warning properties.
Skin Protection:
Rubber or neoprene gloves and additional protection including impervious boots, apron, or coveralls, as
needed in areas of unusual exposure.
Eye Protection:
Use chemical safety goggles. Maintain eye wash fountain and quick-drench facilities in work area.
9. Physical and Chemical Properties
Appearance:
Clear, colorless liquid.
Odor:
Characteristic odor.
Solubility:
Miscible in water.
Specific Gravity:
0.8
pH:
No information found.
% Volatiles by volume @ 21C (70F):
100
Boiling Point:
64.5C (147F)
Melting Point:
-98C (-144F)
Vapor Density (Air=1):
1.1
Vapor Pressure (mm Hg):
97 @ 20C (68F)
Evaporation Rate (BuAc=1):
5.9
10. Stability and Reactivity
Stability: Stable under ordinary conditions of use and storage.

Hazardous Decomposition Products: May form carbon dioxide, carbon monoxide, and formaldehyde when
heated to decomposition.
Hazardous Polymerization: Will not occur.
Incompatibilities: Strong oxidizing agents such as nitrates, perchlorates or sulfuric acid. Will attack some
forms of plastics, rubber, and coatings. May react with metallic aluminum and generate hydrogen gas.
Conditions to Avoid:
Heat, flames, ignition sources and incompatibles.
11. Toxicological Information
Methyl Alcohol (Methanol) Oral rat LD50: 5628 mg/kg; inhalation rat LC50: 64000 ppm/4H; skin rabbit
LD50: 15800 mg/kg; Irritation data-standard Draize test: skin, rabbit: 20mg/24 hr. Moderate; eye, rabbit:
100 mg/24 hr. Moderate. Investigated as a mutagen, reproductive effector.
--------\Cancer Lists\------------------------------------------------------
---NTP Carcinogen---
Ingredient Known Anticipated IARC Category
------------------------------ ----- ----------- -------------
Methyl Alcohol (67-56-1) No No None
12. Ecological Information
Environmental Fate:
When released into the soil, this material is expected to readily biodegrade. When released into the soil,
this material is expected to leach into groundwater. When released into the soil, this material is expected
to quickly evaporate. When released into the water, this material is expected to have a half-life between
1 and 10 days. When released into water, this material is expected to readily biodegrade. When released
into the air, this material is expected to exist in the aerosol phase with a short half-life. When released
into the air, this material is expected to be readily degraded by reaction with photochemically produced
hydroxyl radicals. When released into air, this material is expected to have a half-life between 10 and 30
days. When released into the air, this material is expected to be readily removed from the atmosphere by
wet deposition.
Environmental Toxicity:
This material is expected to be slightly toxic to aquatic life.
13. Disposal Considerations
Whatever cannot be saved for recovery or recycling should be handled as hazardous waste and sent to a
RCRA approved incinerator or disposed in a RCRA approved waste facility. Processing, use or
contamination of this product may change the waste management options. State and local disposal
regulations may differ from federal disposal regulations. Dispose of container and unused contents in
accordance with federal, state and local requirements.
14. Transport Information
Domestic (Land, D.O.T.)

-----------------------
Proper Shipping Name: METHANOL
Hazard Class: 3
UN/NA: UN1230
Packing Group: II
Information reported for product/size: 358LB
International (Water, I.M.O.)

-----------------------------
Proper Shipping Name: METHANOL
Hazard Class: 3, 6.1
UN/NA: UN1230
Packing Group: II
15. Regulatory Information
--------\Chemical Inventory Status - Part 1\---------------------------------

Ingredient TSCA EC Japan Australia
----------------------------------------------- ---- --- ----- ---------
Methyl Alcohol (67-56-1) Yes Yes Yes Yes

--Canada--
Ingredient Korea DSL NDSL Phil.
----------------------------------------------- ----- --- ---- -----
Methyl Alcohol (67-56-1) Yes Yes No Yes
--------\Federal, State & International Regulations - Part 1\----------------

-SARA 302- ------SARA 313------
Ingredient RQ TPQ List Chemical Catg.
----------------------------------------- --- ----- ---- --------------
Methyl Alcohol (67-56-1) No No Yes No

-RCRA- -TSCA-
Ingredient CERCLA 261.33 8(d)
----------------------------------------- ------ ------ ------
Methyl Alcohol (67-56-1) 5000 U154 No
Chemical Weapons Convention: No TSCA 12(b): No CDTA: No

SARA 311/312: Acute: Yes Chronic: Yes Fire: Yes Pressure: No
Reactivity: No (Pure / Liquid)
Australian Hazchem Code: 2PE

Poison Schedule: S6
WHMIS:
This MSDS has been prepared according to the hazard criteria of the Controlled Products Regulations
(CPR) and the MSDS contains all of the information required by the CPR.
16. Other Information
NFPA Ratings: Health: 1 Flammability: 3 Reactivity: 0

Label Hazard Warning:
POISON! DANGER! VAPOR HARMFUL. MAY BE FATAL OR CAUSE BLINDNESS IF SWALLOWED.
HARMFUL IF INHALED OR ABSORBED THROUGH SKIN. CANNOT BE MADE NONPOISONOUS.
FLAMMABLE LIQUID AND VAPOR. CAUSES IRRITATION TO SKIN, EYES AND RESPIRATORY TRACT.
AFFECTS CENTRAL NERVOUS SYSTEM AND LIVER.
Label Precautions:
Avoid breathing vapor.
Avoid contact with eyes, skin and clothing.
Wash thoroughly after handling.
Keep container closed.
Use only with adequate ventilation.
Keep away from heat, sparks and flame.
Label First Aid:
If inhaled, remove to fresh air. If not breathing, give artificial respiration. If breathing is difficult, give
oxygen. If swallowed, induce vomiting immediately as directed by medical personnel. Never give anything
by mouth to an unconscious person. In case of contact, immediately flush eyes or skin with plenty of
water for at least 15 minutes while removing contaminated clothing and shoes. Wash clothing before
reuse. In all cases get medical attention immediately.
Product Use: Laboratory Reagent.
Revision Information: No Changes.
Safety data sheet
Page: 1/10
BASF Safety data sheet according to Regulation (EC) No. 1907/2006
Date / Revised: 08.01.2010 Version: 5.0
Product: N-Methylpyrrolidone dist.
(30036605/SDS_GEN_EU/EN)
Date of print 08.03.2010
1. Identification of the substance/mixture and of the company/undertaking
N-Methylpyrrolidone dist.
Chemical name: N-Methylpyrrolidone
Use: Intermediate, Must not be used in cosmetic products.
Company:
BASF SE
67056 Ludwigshafen
GERMANY
Operating Division Intermediates
Telephone: +49 621 60-42259
Telefax number: +49 621 60-49134
E-mail address: product-safety.intermediates@basf.com
Emergency information:
International emergency number:
Telephone: +49 180 2273-112
According to REGULATION (EC) No 1272/2008 on classification, labelling and packaging of

substances and mixtures
Label elements and precautionary statement:
Pictogram:
Signal Word:
Danger
Page: 2/10
Hazard Statement:
Causes serious eye irritation. Causes skin irritation. May cause respiratory irritation. May damage the
unborn child.
Precautionary Statements (Prevention):

Wear protective gloves/clothing and eye/face protection. Use only outdoors or in a well-ventilated
area. Use personal protective equipment as required. Avoid breathing
dust/fume/gas/mist/vapours/spray. Obtain special instructions before use. Do not handle until all
safety precautions have been read and understood. Wash with plenty of water and soap thoroughly
after handling.
Precautionary Statements (Response):

Call a POISON CENTER or doctor/physician if you feel unwell. IF IN EYES: Rinse cautiously with
water for several minuts. Remove contact lenses, if present and easy to do. Continue rinsing. IF
INHALED: Remove to fresh air and keep at rest in a position comfortable for breathing. IF ON SKIN (on
hair): Wash with plenty of soap and water. IF exposed or concerned: Get medical advice/attention. If
skin irritation occurs: Get medical advice/attention. If eye irritation persists: Get medical
advice/attention. Take off contaminated clothing and wash before reuse. Specific treatment (see on
this label).
Precautionary Statements (Storage):

Store in a well-ventilated place. Keep container tightly closed. Store locked up.
Precautionary Statements (Disposal):

Dispose of contents/container to hazardous or special waste collection point.
Classification of the substance and mixture:

Skin corrosion/irritation: Cat. 2
Serious eye damage/eye irritation: Cat. 2
Toxic to reproduction: Cat. 1B (unborn child)
Specific target organ toxicity following single exposure: Cat. 3 (irritating to respiratory system)
Possible Hazards (according to Directive 67/548/EWG or 1999/45/EC)
Irritating to eyes, respiratory system and skin.

May cause harm to the unborn child.
Category 2: Substances which should be regarded as if they cause developmental toxicity to humans
or substances which should be regarded as if they impair fertility in humans
Chemical nature
N-Methylpyrrolidone
CAS Number: 872-50-4
EC-Number: 212-828-1
INDEX-Number: 606-021-00-7
Hazardous ingredients (GHS)

according to Regulation (EC) No. 1272/2008
Page: 3/10
N-Methylpyrrolidone
Content (W/W): >= 75 % - <= 100 Skin corr./irr.: Cat. 2
% Eye dam./irr.: Cat. 2
CAS Number: 872-50-4 Repro.: Cat. 1B (unborn child)
EC-Number: 212-828-1 STOT single: Cat. 3 (irr. to respiratory syst.)
Hazardous ingredients
according to Directive 1999/45/EC
N-Methylpyrrolidone
Content (W/W): >= 75 % - <= 100 %
Hazard symbol(s): T
R-phrase(s): 61, 36/37/38
The wording of the hazard symbols and R-phrases is specified in chapter 16 if dangerous ingredients
are mentioned.
4. First-Aid Measures
General advice:
Remove contaminated clothing.
If inhaled:
Keep patient calm, remove to fresh air. If breathing difficulties develop, aid in breathing and seek
On skin contact:
Wash thoroughly with soap and water.
On contact with eyes:

Immediately wash affected eyes for at least 15 minutes under running water with eyelids held open,
consult an eye specialist.
On ingestion:
Rinse mouth and then drink plenty of water.
5. Fire-Fighting Measures
Suitable extinguishing media:
water spray, dry extinguishing media, foam, carbon dioxide
Specific hazards:
nitrous gases
Page: 4/10
Special protective equipment:

Wear a self-contained breathing apparatus.
Further information:
Collect contaminated extinguishing water separately, do not allow to reach sewage or effluent
systems.

Personal precautions:
Handle in accordance with good industrial hygiene and safety practice.
Do not empty into drains.
Methods for cleaning up or taking up:

For large amounts: Pump off product.
For residues: Pick up with suitable absorbent material (e.g. sand, sawdust, general-purpose binder,
kieselguhr). Dispose of absorbed material in accordance with regulations.
Handling
Ensure thorough ventilation of stores and work areas.
Protection against fire and explosion:

Prevent electrostatic charge - sources of ignition should be kept well clear - fire extinguishers should
be kept handy.
Storage
Further information on storage conditions: Containers should be stored tightly sealed in a dry place.
Storage stability:
Storage duration: 24 Months
Components with workplace control parameters
872-50-4: N-Methylpyrrolidone
Page: 5/10
Personal protective equipment

Hand protection:
Chemical resistant protective gloves (EN 374)
Suitable materials also with prolonged, direct contact (Recommended: Protective index 6,
corresponding > 480 minutes of permeation time according to EN 374):
butyl rubber (butyl) - 0.7 mm coating thickness
Suitable materials short-term contact and/or splashes (recommended: At least protective index 2,
corresponding > 30 minutes of permeation time according to EN 374)
nitrile rubber (NBR) - 0.4 mm coating thickness
chloroprene rubber (CR) - 0.5 mm coating thickness
Supplementary note: The specifications are based on tests, literature data and information of glove
manufacturers or are derived from similar substances by analogy. Due to many conditions (e.g.
temperature) it must be considered, that the practical usage of a chemical-protective glove in practice
may be much shorter than the permeation time determined through testing.
Manufacturer's directions for use should be observed because of great diversity of types.
Eye protection:
Safety glasses with side-shields (frame goggles) (e.g. EN 166)
General safety and hygiene measures:

Handle in accordance with good industrial hygiene and safety practice. Wearing of closed work
clothing is required additionally to the stated personal protection equipment. Females of childbearing
age should not come into contact with the product.

Form: liquid
Colour: colourless, clear
Odour: faint specific odour
pH value: 8.5 - 10
(100 g/l, 20 °C)
Melting point: -23.6 °C

Boiling point: 204.3 °C
Flash point: 91 °C (DIN 51758)

Lower explosion limit: 1.3 %(V)
(83.5 °C, 13.5 hPa)
Upper explosion limit: 9.5 %(V)
Ignition temperature: 245 °C (DIN 51794)
Self ignition: not self-igniting
Vapour pressure: 0.32 mbar

(20 °C)
Density: 1.028 g/cm3 (DIN 51757)

(25 °C)
Page: 6/10
Solubility in water: miscible

Solubility (qualitative) solvent(s): organic solvents
miscible
Partitioning coefficient n-octanol/water (log Pow): -0.46 (OECD Guideline 107)
(25 °C)
Surface tension: 0.41 mN/m
Viscosity, dynamic: 1.796 mPa.s

(20 °C)
Grain size distribution: Test substance The substance / product is marketed or

used in a non solid or granular form.
Molar mass: 99.00 g/mol

Thermal decomposition: approx. > 300 °C
Substances to avoid:
bases, acids
Hazardous reactions:
Exothermic reaction.
Acute toxicity
Assessment of acute toxicity:

Virtually nontoxic by inhalation. Of low toxicity after short-term skin contact. Of low toxicity after single
ingestion.
Experimental/calculated data:
LD50 rat (oral): 3,605 mg/kg
LC50 rat (by inhalation): > 5.1 mg/l 4 h
LD50 rat (dermal): 5,000 mg/kg
Irritation
Assessment of irritating effects:

Eye contact causes irritation. Skin contact causes irritation.
Skin corrosion/irritation rabbit: Irritant. (Draize test)
Serious eyes damages/irritation rabbit: Irritant. (Draize test)

Page: 7/10
Germ cell mutagenicity
Assessment of mutagenicity:
The substance was not mutagenic in bacteria. The substance was not mutagenic in mammalian cell
culture. The substance was not mutagenic in a test with mammals.
Carcinogenicity
Assessment of carcinogenicity:
Results from a number of long-term carcinogenity studies and short-term tests are available. Taking
into account all of the information, there is no indication that the substance itself is carcinogenic.
Reproductive toxicity
Assessment of reproduction toxicity:

As shown in animal studies, the product may cause damage to the testes after repeated high
exposures that cause other toxic effects.
Developmental toxicity
Assessment of teratogenicity:
The substance caused malformations/developmental toxicity in laboratory animals.
Ecotoxicity
Assessment of aquatic toxicity:

There is a high probability that the product is not acutely harmful to aquatic organisms. The inhibition of
the degradation activity of activated sludge is not anticipated when introduced to biological treatment
plants in appropriate low concentrations.
Toxicity to fish:
LC50 (96 h) > 500 mg/l, Salmo gairdneri, syn. O. mykiss (static)
The details of the toxic effect relate to the nominal concentration.
Aquatic invertebrates:
EC50 (24 h) > 1,000 mg/l, Daphnia magna (DIN 38412 Part 11, static)
Aquatic plants:
EC50 (72 h) > 500 mg/l, Scenedesmus subspicatus (DIN 38412 Part 9)
Microorganisms/Effect on activated sludge:

EC50 (0.5 h) > 600 mg/l, activated sludge, industrial (DIN EN ISO 8192, aquatic)
Persistence and degradability
Assessment biodegradation and elimination (H2O):

Page: 8/10
Readily biodegradable (according to OECD criteria). Easily eliminated from water.
Elimination information:
73 % BOD of the ThOD (28 d) (OECD 301C; ISO 9408; 92/69/EEC, C.4-F) (aerobic, Inoculum
conforming to MITI requirements (OECD 301C)) Readily biodegradable (according to OECD criteria).
sum parameter
Chemical oxygen demand (COD): (DIN 38409 Part 41) approx. 1,600 mg/g
Biochemical oxygen demand (BOD) Incubation period 5 d: < 2 mg/g
Theoretical Oxygen Demand (ThOD): 1,939 mg/g
Bioaccumulation potential
Bioaccumulation potential:
Because of the n-octanol/water distribution coefficient (log Pow) accumulation in organisms is not to
be expected.
Other adverse effects
Adsorbable organically-bound halogen (AOX):

This product contains no organically-bound halogen.

Incinerate in suitable incineration plant, observing local authority regulations.
Contaminated packaging:
Contaminated packaging should be emptied as far as possible; then it can be passed on for recycling
after being thoroughly cleaned.
Land transport
ADR
Not classified as a dangerous good under transport regulations
RID
Inland waterway transport

ADNR
Hazardous good only when carried in inland waterway tanker
Page: 9/10
(ADNR)
Sea transport
IMDG
Air transport
IATA/ICAO
Regulations of the European union (Labelling) / National legislation/Regulations
as in Annex I of Directive 67/548/EEC:
Hazard symbol(s)
T Toxic.
R-phrase(s)
R61 May cause harm to the unborn child.
R36/37/38 Irritating to eyes, respiratory system and skin.
S-phrase(s)
S53 Avoid exposure - obtain special instructions before use.
S45 In case of accident or if you feel unwell, seek medical advice immediately
(show the label where possible).
Hazard determining component(s) for labelling: N-METHYL-2-PYRROLIDONE
Other regulations
as in Annex I of Directive 67/548/EEC

Repr. Cat. 2 - Category 2: Substances which should be regarded as if they cause developmental
toxicity to humans or substances which should be regarded as if they impair fertility in humans
Full text of hazard symbols and R-phrases if mentioned as hazardous components in chapter 3:
T Toxic.
61 May cause harm to the unborn child.
Page: 10/10
36/37/38 Irritating to eyes, respiratory system and skin.
Vertical lines in the left hand margin indicate an amendment from the previous version.
The data contained in this safety data sheet are based on our current knowledge and experience and
describe the product only with regard to safety requirements. The data do not describe the product's
properties (product specification). Neither should any agreed property nor the suitability of the product for
any specific purpose be deduced from the data contained in the safety data sheet. It is the responsibility of
the recipient of the product to ensure any proprietary rights and existing laws and legislation are observed.
Material: 60002712 WACKER® AK 350
SILICONE FLUID
Version: 1.0 (US) Date of print: 06/04/2010 Date of last alteration: 06/27/2008
1 Product and company identification

1.1 Identification of the substance or preparation:
Commercial product name: WACKER® AK 350
SILICONE FLUID
Use of substance / preparation: Industrial.
Intermediate chemical
1.2 Company/undertaking identification:
Manufacturer/distributor: Wacker Chemie AG
Hanns-Seidel-Platz 4
81737 München
Germany
Customer information: Wacker Chemical Corporation

3301 Sutton Road
Adrian, Michigan 49221-9397
USA
InfoLine:
Tel (517) 264-8240, Fax (517) 264-8740
Hours of operation:
Monday - Friday, 8 am to 5 pm (eastern standard time)
Corporate website: www.wacker.com
Emergency telephone no. (24h): (517) 264-8500

Transportation emergency: (800) 424-9300 (CHEMTREC, USA)
(703) 527-3887 (CHEMTREC, international)
This MSDS was prepared by the Regulatory Affairs and Product Safety Department (RAPS) of Wacker
Chemical Corporation.
2 Composition/information on ingredients
2.1 Chemical characterization (substance):
Chemical characteristics
Polydimethylsiloxane
2.2 Information on ingredients:

Type CAS No. Substance Content [wt. %] Note
Lower Upper
INHA 63148-62-9 Polydimethyl siloxane 100.0 100.0 NH
Type: HYD - by-product upon hydrolysis, INHA - ingredient, NEBE - by-product, MONO - residual
monomer, VERU - impurity, VUL - by-product upon vulcanization. *** Note: C1 - IARC carcinogen,
C2 - NTP carcinogen, C3 - OSHA carcinogen, NH - non-hazardous, R - reproductive toxin.
This material does not contain any OSHA or WHMIS reportable hazardous ingredients.
Substances listed in the Subsections "HAPS" and "California Proposition 65 Carcinogens /
Reproductive Toxins" that are not listed in Section 2 are only present at quantities below 0.1%
for California Proposition 65 listed toxins or below 1% for non-carcinogenic HAPS or they are
inextricably bound in the product.
3 Hazards identification
3.1 Hazards classifications
HMIS® rating (product as packaged):
Health: 1 Fire: 1 Reactivity: 0 PPE: B
Page: 1/8
SILICONE FLUID
(HMIS codes are based on contact with the product as packaged and any hydrolysis by-products,
if present.) Hazardous Materials Identification System and HMIS are registered trademarks of
the National Paint and Coatings Association.
Canadian WHMIS Classification: None.
3.2 Emergency overview and potential hazards
This material is not hazardous under OSHA criteria. This material is not hazardous under WHMIS
criteria. Liquid silicone based materials have lubricating properties that can substantially
reduce or eliminate traction and may pose a slip hazard. Please use warning labels on consumer
products where traction is essential for safety.
Physical Hazards:
No known physical hazards.
Acute health effects
Route of entry or possible contact:
eyes , skin , ingestion
Eye contact:
May cause slight eye irritation.
Skin contact:
No acute toxic effects are expected.
Inhalation:
Inhalation is not expected due to low vapor pressure.
Ingestion:
Not expected in industrial use.
Additional information on acute health effects:
The toxicological evaluation is based on test results with a similar product.
3.3 Further information:
Chronic health effects:
none known
Medical conditions which may be aggravated by exposure:
none known
Carcinogens/Reproductive toxins:
There are no carcinogenic ingredients present at or over 0.1% in this material. This material
does not contain any reproductive toxins at or above OSHA or WHMIS reportable levels.
See Section 11 for Toxicological Information, if any.
4 First-aid measures
4.1 General information:
Get medical attention if irritation or other symptoms occur. Before seeking medical attention
remove contaminated clothing and shoes. Take a copy of the Safety Data Sheet when going for
medical treatment.
4.2 After inhalation:
Material cannot be inhaled under normal conditions. No special measures required.
4.3 After contact with the skin:
For skin contact: Wipe off excess material with cloth or paper. Use a waterless hand cleaner to
remove as much of the remaining material as possible. Wash with soap and water.
4.4 After contact with the eyes:
If contact with eyes, immediately hold eyelids apart and flush with plenty of water for at
least 15 min.
4.5 After swallowing:
After swallowing: No special treatment is required.
Page: 2/8
SILICONE FLUID
5 Fire-fighting measures
5.1 Flammable properties: Method
Flash point..........................: > 300 °C (> 572 °F) (ISO 2592)
Boiling point / boiling range........: not determined
Lower explosion limit (LEL)..........: not applicable
Upper explosion limit (UEL)..........: not applicable
Ignition temperature ................: approx. 450 °C (842 °F) (DIN 51794)
NFPA Hazard Class (comb./flam.liquid): IIIB
5.2 Fire and explosion hazards:
This material does not present any unusual fire or explosion hazards.
5.3 Recommended extinguishing media:
water-mist , carbon dioxide , sand , dry chemical or alcohol-resistant foam .
5.4 Unsuitable extinguishing media:
water-spray , sharp water jet .
5.5 Special exposure hazards arising from the substance or preparation itself, combustion products,
resulting gases:
Hazardous decomposition products: carbon dioxide , carbon monoxide , formaldehyde , silicon
dioxide and incompletely burnt hydrocarbons .
5.6 Fire fighting procedures:
Fire fighters should wear full protective clothing including a self-contained breathing
apparatus. Cool endangered containers with water.
6 Accidental release measures

6.1 Precautions:
If material is released indicate risk of slipping. Do not walk through spilled material.
HAZWOPER PPE Level: D
6.2 Containment:
Prevent material from entering surface waters, drains or sewers and soil. Contain any fluid
that runs out using suitable material (e.g. earth). Close leak if possible without risk.
Spills of material which could reach surface waters must be reported to the United States Coast
Guard National Response Center's toll free phone number (800) 424-8802.
6.3 Methods for cleaning up:
Take up mechanically and dispose of according to local/state/federal regulations. For small
amounts: Absorb with a liquid binding material such as diatomaceous earth and dispose of
according to local/state/federal regulations. Contain larger amounts and pump up into suitable
containers. Clean any slippery coating that remains using a detergent / soap solution or
another biodegradable cleaner. Apply sand or other inert granular material to improve traction.
7 Handling and storage

No special protective measures required.
7.1 Handling
Precautions for safe handling:
Spilled substance increases risk of slipping.
Precautions against fire and explosion:
Observe the general rules for fire prevention.
7.2 Storage
Conditions for storage rooms and vessels:
none known
Advice for storage of incompatible materials:
not applicable
Further information for storage:
Keep container tightly closed. Store in a dry and cool place.
Maximum temperature allowed during storage and transportation: 50 °C (122 °F)
Page: 3/8
SILICONE FLUID
8 Exposure controls and personal protection

8.1 Engineering controls
Ventilation:
Use with adequate ventilation.
Local exhaust:
not necessary
8.2 Associate substances with specific control parameters such as limit values
none known .
8.3 Personal protection equipment (PPE)
Respiratory protection is not normally required.
Hand protection:
Recommendation: Any liquid-tight rubber or vinyl gloves.
Eye protection:
Recommendation: Safety glasses with side shields.
Other protective clothing or equipment:
Additional protective clothing or equipment is not normally required. Provide eye bath and
safety shower.
8.4 General hygiene and protection measures:
When handling do not eat, drink, smoke or apply cosmetics. Wash thoroughly after handling.
9 Physical and chemical properties

9.1 Appearance
Physical state / form................: liquid
Colour...............................: colourless
Odour................................: odourless
9.2 Safety parameters Method
Melting point / melting range........: -50 - -35 °C (-58 - -31 °F)
Boiling point / boiling range........: not determined
Flash point..........................: > 300 °C (> 572 °F) (ISO 2592)
Ignition temperature ................: approx. 450 °C (842 °F) (DIN 51794)
Lower explosion limit (LEL)..........: not applicable
Upper explosion limit (UEL)..........: not applicable
Vapour pressure......................: not applicable
Density..............................: approx. 0.97 g/cm³ at 25 °C (77 °F) (DIN 51757)
Water solubility / miscibility.......: virtually insoluble at 20 °C (68 °F)
pH-Value.............................: approx. 7
Viscosity (dynamic)..................: 324 - 356 mPa.s at 25 °C (77 °F) (DIN 53018)
Viscosity (kinematic)................: approx. 350 mm²/s at 25 °C (77 °F) (DIN 53018)
9.3 Further information
Thermal decomposition................: Decomposition begins at > 250 °C (> 482
°F)
Page: 4/8
SILICONE FLUID
10 Stability and reactivity

If stored and handled in accordance with standard industrial practices no hazardous reactions
are known.
10.1 Conditions to avoid:
none known
10.2 Materials to avoid:
none known
10.3 Hazardous decomposition products:
If stored and handled in accordance with standard industrial practices and local regulations
where applicable: none known . Measurements have shown the formation of small amounts of
formaldehyde at temperatures above about 150 °C (302 °F) through oxidation.
10.4 Further information:
Hazardous polymerization cannot occur.
11 Toxicological information
Toxicological testing has been conducted with this material.
11.2 Toxicological data:
Acute toxicity (LD50/LC50-values relevant to classification):
Exposition Value/value range Species Source
oral > 5000 mg/kg rat literature
dermal > 2008 mg/kg rat (Limit Test) test report
Primary irritation:
Exposition Effect Species/Testsystem Source
to skin not irritating rabbit test report
to eyes mildly irritating rabbit test report
Sensitization:
Exposition Effect Test method Species Source
to skin not sensitizing Magnusson- guinea-pig test report
Kligmann
Reference points for mutagenic potential:
Test system Effect Source
Bacterial Reverse Mutation Test not mutagenic test report
Experience with man:
Human patch test: Product displays good compatibility with the skin.
12 Ecological information
12.1 Information on elimination (persistence and degradability)
Biodegradation / further information:
Biologically not degradable. Polydimethylsiloxanes are degradable to a certain extent in
abiotic processes.
Insoluble in water.
12.2 Behaviour in environmental compartments
Mobility
Forms thin oil film on surface of water. Absorbed by floating particles. Separation by
sedimentation.
Bioaccumulation is not expected to occur.
Page: 5/8
SILICONE FLUID
12.3 Ecotoxicological effects:

According to past experience toxicity to fish is improbable.
Effects in sewage treatment plants (bacteria toxicity: respiration-/reproduction inhibition):
According to current knowledge adverse effects on water purification plants are not expected.
12.4 Additional information
Other harmful effects
-
General information:
No environmental problems expected if handled and treated in accordance with standard
industrial practices and local regulations where applicable.
13 Disposal considerations
13.1 Product disposal
Recommendation:
Material that cannot be used or chemically reprocessed should be disposed of at an approved
facility in accordance with any applicable governmental regulations.
13.2 Packaging diposal
Recommendation:
Completely discharge containers (no tear drops, no powder rest, scraped carefully). Containers
may be recycled or re-used. Observe local/state/federal regulations.
14 Transport information
14.1 US DOT & CANADA TDG SURFACE
Valuation....................: Not regulated for transport
14.2 Transport by sea IMDG-Code
14.3 Air transport ICAO-TI/IATA-DGR
15 Regulatory information
15.1 U.S. Federal regulations
TSCA inventory status and TSCA information:
This material or its components are listed on or are in compliance with the requirements of the
TSCA Chemical Substance Inventory.
TSCA 12(b) Export Notification:
This material does not contain any TSCA 12(b) regulated chemicals.
CERCLA Regulated Chemicals:
This material does not contain any CERCLA regulated chemicals.
SARA 302 EHS Chemicals:
This material does not contain any SARA extremely hazardous substances.
SARA 311/312 Hazard Class:
This product does not present any SARA 311/312 hazards.
SARA 313 Chemicals:
This material does not contain any SARA 313 chemicals above de minimus levels.
HAPS (Hazardous Air Pollutants):
This material does not contain any hazardous air pollutants.
15.2 U.S. State regulations
Page: 6/8
SILICONE FLUID
California Proposition 65 Carcinogens:

This material does not contain any chemicals known to the state of California to cause cancer.
California Proposition 65 Reproductive Toxins:
This material does not contain any chemicals known to the state of California to cause
reproductive effects.
Massachusetts Substance List:
This material contains no listed components.
New Jersey Right-to-Know Hazardous Substance List:
Pennsylvania Right-to-Know Hazardous Substance List:
15.3 Canadian regulations

This product has been classified in accordance with the Hazard criteria of the CPR and the MSDS
contains all the information required by the CPR.
WHMIS Hazard Classes:
None.
DSL Status:
This material or its components are listed on the Canadian Domestic Substances List.
Canadian Ingredient Disclosure List:
15.4 Other international regulations

EU Risk Phrases:
R-Phrase Description
R- -
EU Safety Phrases:
S-Phrase Description
S- -
Details of international registration status
Listed on or in accordance with the following inventories:
AICS - Australia
TSCA - USA
DSL - Canada
ECL - Korea
PICCS - Philippines
ENCS - Japan
EINECS - Europe
IECSC - China
16 Other information
16.1 Additional information:
This Material Safety Data Sheet (MSDS) meets the requirements of the Federal OSHA Hazard
Communication Standard (29 CFR 1910.1200). This product has been classified according to the
hazard criteria of the Controlled Products Regulations (CPR) and the MSDS contains all of the
information required by the CPR. This information relates to the specific material designated
and may not be valid for such material used in combination with any other materials or in any
process. Such information is to the best of our knowledge and belief accurate and reliable as
of the date compiled. However, no representation, warranty or guarantee expressed or implied,
is made as to its accuracy, reliability or completeness. It is the user's responsibility to
satisfy himself as to the suitability and completeness of such information for his own
particular use. We do not accept liability for any loss or damage that may occur from the use
Page: 7/8
SILICONE FLUID
of this information. Nothing herein shall be construed as a recommendation for uses which
infringe valid patents or as extending a license under valid patents. This MSDS provides
selected regulatory information on this product, including its components. This is not intended
to include all regulations. It is the responsibility of the user to know and comply with all
applicable rules, regulations and laws relating to the product being used.
Vertical lines in the left-hand margin indicate changes compared with the previous version.
16.2 Glossary of Terms:
ACGIH - American Conference of Governmental ppm - Parts per Million
Industrial Hygienists SARA - Superfund Amendments and Reauthorization Act
DOT - Department of Transportation STEL - Short Term Exposure Limit
hPa - Hectopascals TSCA - Toxic Substances Control Act
mPa*s - Milli Pascal-Seconds TWA - Time Weighted Average
OSHA - Occupational Safety and Health Administration WHMIS - Canadian Workplace Hazardous Materials
PEL - Permissible Exposure Limit Identification System
Flash point determination methods Common name
ASTM D56 Tagliabue (Tag) closed cup
ASTM D92, DIN 51376, ISO 2592 Cleveland open cup
ASTM D93, DIN 51758, ISO 2719 Pensky-Martens closed cup
ASTM D3278, DIN 55680, ISO 3679 Setaflash or Rapid closed cup
DIN 51755 Abel-Pensky closed cup
16.3 Conversion table:
Pressure: 1 hPa * 0.75 = 1 mm Hg = 1 Torr; 1 bar = 1000 hPa
Viscosity: 1 mPa*s = 1 Centipoise (Cp)
Page: 8/8
Safety data sheet
Page: 1/10
Product: Sodium Nitrite HQ free flowing (non-food grade)
1. Identification of the substance/mixture and of the company/undertaking
Sodium Nitrite HQ free flowing (non-food grade)

Use: Chemical
Company:
BASF SE
67056 Ludwigshafen
GERMANY
Operating Division Inorganics E-CAA
Telephone: +49 621 60-40055
Telefax number: +49 621 60-6640055
E-mail address: reinhard-ulrich.roth@basf.com
Emergency information:
International emergency number:
Telephone: +49 180 2273-112
According to REGULATION (EC) No 1272/2008 on classification, labelling and packaging of

substances and mixtures
Label elements and precautionary statement:
Pictogram:
Signal Word:
Danger
Hazard Statement:
Toxic if swallowed. Very toxic to aquatic life. May intensify fire; oxidizer.
Page: 2/10
Precautionary Statements (Prevention):

Avoid release to the environment. Keep away from heat/sparks/open flames/hot surfaces. – No
smoking. Wear protective gloves and eye/face protection. Do no eat, drink or smoke when using this
product. Take any precaution to avoid mixing with combustibles ... Wash with plenty of water and soap
thoroughly after handling. Keep/Store away from clothing/combustible materials.
Precautionary Statements (Response):

Immediately call a POISON CENTER or doctor/physician. IF SWALLOWED: rinse mouth. Collect
spillage. In case of fire: Use water for extinction.
Precautionary Statements (Storage):

Store locked up. Store aways from other materials.
Precautionary Statements (Disposal):

Dispose of contents/container to hazardous or special waste collection point.
Classification of the substance and mixture:

Oxidizing solids: Cat. 2
Acute toxicity: Cat. 3 (oral)
Acute hazards to the aquatic environment: Cat. 1
Other hazards which do not result in classification:

No data available.
Possible Hazards (according to Directive 67/548/EWG or 1999/45/EC)
Toxic if swallowed.
Contact with combustible material may cause fire.
Very toxic to aquatic organisms.
Chemical nature
sodium nitrite
NaNO2
Contains: anticaking agent
Hazardous ingredients
according to Directive 1999/45/EC
sodium nitrite
Content (W/W): >= 99 %
Hazard symbol(s): O, T, N
R-phrase(s): 8, 25, 50
Page: 3/10
The wording of the hazard symbols and R-phrases is specified in chapter 16 if dangerous ingredients
are mentioned.
4. First-Aid Measures
General advice:
If danger of loss of consciousness, place patient in recovery position and transport accordingly. Apply
artificial respiration if necessary.
If inhaled:
After inhalation of decomposition products, remove the affected person to a source of fresh air and
keep calm. Provide medical aid. Immediately inhale corticosteroid dose aerosol.
On skin contact:
Wash thoroughly with soap and water.
On contact with eyes:

Immediately wash affected eyes for at least 15 minutes under running water with eyelids held open,
consult an eye specialist.
On ingestion:
Rinse mouth immediately and then drink plenty of water, induce vomiting, seek medical attention.
Note to physician:
Hazards: Risk of pulmonary edema. Symptoms can appear later. Danger of methaemoglobin
formation after ingestion.
Treatment: Treat according to symptoms (decontamination, vital functions), treat with toluonium
chloride to reverse methaemoglobinanaemia.
5. Fire-Fighting Measures
water
Unsuitable extinguishing media for safety reasons:

ABC powder, carbon dioxide
Specific hazards:
nitrogen oxides
The substances/groups of substances mentioned can be released in case of fire. Has a fire-promoting
effect due to release of oxygen.

Wear a self-contained breathing apparatus.
Page: 4/10

Personal precautions:
Use breathing apparatus if exposed to vapours/dust/aerosol. Avoid contact with eyes.
Do not discharge into the subsoil/soil. Do not discharge into waterways or sewer systems without
proper authorization.
Methods for cleaning up or taking up:

For residues: Pick up with suitable appliance and dispose of.
Handling
Keep container tightly sealed. Breathing must be protected when large quantities are decanted without
local exhaust ventilation. Processing machines must be fitted with local exhaust ventilation. Protect
against moisture. Protect against heat. Do not mix with combustible substances. Handle in accordance
with good industrial hygiene and safety practice.
Protection against fire and explosion:

The substance/product is non-combustible. Has a fire-promoting effect due to release of oxygen.
Where required Prevent electrostatic charge - sources of ignition should be kept well clear - fire
extinguishers should be kept handy.
Storage
Segregate from oxidizable substances. Segregate from acids. Segregate from ammonium salts.
Further information on storage conditions: Keep container tightly closed and in a well-ventilated place.
This product is classified as a dangerous substance for storage. The authority permits and storage
regulations must be observed. Keep away from food, drink and animal feeding stuffs.
7632-00-0: sodium nitrite
7631-99-4: sodium nitrate

Breathing protection if dusts are formed. Particle filter with high efficiency for solid and liquid particles
(e.g. EN 143 or 149, Type P3 or FFPE).
Page: 5/10
Hand protection:
Chemical resistant protective gloves (EN 374)
Suitable materials also with prolonged, direct contact (Recommended: Protective index 6,
corresponding > 480 minutes of permeation time according to EN 374):
polyvinylchloride (PVC) - 0.7 mm coating thickness
nitrile rubber (NBR) - 0.4 mm coating thickness
chloroprene rubber (CR) - 0.5 mm coating thickness
Supplementary note: The specifications are based on tests, literature data and information of glove
manufacturers or are derived from similar substances by analogy. Due to many conditions (e.g.
temperature) it must be considered, that the practical usage of a chemical-protective glove in practice
may be much shorter than the permeation time determined through testing.
Manufacturer's directions for use should be observed because of great diversity of types.
Eye protection:
Safety glasses with side-shields (frame goggles) (e.g. EN 166)
General safety and hygiene measures:

Handle in accordance with good industrial hygiene and safety practice. Do not breathe dust. Keep
away from food, drink and animal feeding stuffs. No eating, drinking, smoking or tobacco use at the
place of work. Take off immediately all contaminated clothing. Hands and/or face should be washed
before breaks and at the end of the shift.

Form: crystalline
Colour: white to slightly yellow
Odour: faint odour
pH value: 8-9
(100 g/l, 20 °C)
Melting point: 280 °C

Boiling point:
The substance / product decomposes
therefore not determined.
Flammability: does not ignite

Fire promoting properties: Oxidizing.
Radioactivity:
not radioactive for transport
purposes (activity < 70 kBq/kg)
Density: 2.17 g/cm3 (ISO 2811-3)

(20 °C)
Bulk density: 1,100 - 1,300 kg/m3
Solubility in water: readily soluble

Hygroscopy: hygroscopic
Partitioning coefficient n-octanol/water (log Pow): -3.7
(25 °C)
Page: 6/10
Surface tension: (other)

Based on chemical structure, surface
activity is not to be expected.
Viscosity, dynamic:
not applicable

Thermal decomposition: > 320 °C
nitrogen monoxide, nitrogen dioxide, disodium oxide
Substances to avoid:
reducing agents, oxidizable substances, ammonium salts, amines, amine compounds, acids
Hazardous reactions:
Hazardous reactions in presence of mentioned substances to avoid.

disodium oxide
nitrogen oxides
Acute toxicity
Assessment of acute toxicity:

Of high toxicity after single ingestion. There is a risk of damage to the blood (methemoglobinemia)
after a single uptake.
LD50 rat (oral): 180 mg/kg
Irritation
Assessment of irritating effects:

Not irritating to the skin. Eye contact causes irritation.
Skin corrosion/irritation rabbit: non-irritant (OECD Guideline 404)
Serious eyes damages/irritation rabbit: Irritant. (OECD Guideline 405)
Respiratory/Skin sensitization
Assessment of sensitization:
There is no evidence of a skin-sensitizing potential.
Carcinogenicity
Page: 7/10
Assessment of carcinogenicity:
In long-term studies in rats and mice in which the substance was given by drinking-water, a
carcinogenic effect was not observed. Under certain conditions nitrites can enhance the formation of
nitrosamines in vivo. Nitrosamines are carcinogenic in animal studies.
Reproductive toxicity
Assessment of reproduction toxicity:

The results of animal studies gave no indication of a fertility impairing effect.
Developmental toxicity
Assessment of teratogenicity:
In animal studies the substance did not cause malformations.
Repeated dose toxicity and Specific target organ toxicity (repeated exposure)
Assessment of repeated dose toxicity:

After repeated administration the prominent effect is damage of the blood (methemoglobin formation).
Aspiration hazard
Toxic if swallowed.
Ecotoxicity
Assessment of aquatic toxicity:

Very toxic (acute effect) to aquatic organisms. The inhibition of the degradation activity of activated
sludge is not anticipated when introduced to biological treatment plants in appropriate low
concentrations.
Toxicity to fish:
LC50 (96 h) 0.54 - 26.3 mg/l, Salmo gairdneri, syn. O. mykiss (other, Flow through.)
LC50 (96 h) 118.3 - 150.7 mg/l, other (other, semistatic)
Aquatic invertebrates:
LC50 (96 h) 4.93 mg/l, aquatic crustacea (other, static)
Literature data.
LC50 (120 h) 34.8 mg/l, other (other, semistatic)
Aquatic plants:
Toxic limit concentration (192 h) 1,230 mg/l (growth rate), Scenedesmus quadricauda (other, static)
Microorganisms/Effect on activated sludge:

EC20 (0.5 h) > 1,800 mg/l, (DIN EN ISO 8192, aquatic)
Page: 8/10
EC50 (48 h) 421 mg/l, protozoa (other, static)
Chronic toxicity to fish:

No observed effect concentration (31 d) 6.16 mg/l, Ictalurus punctatus, syn: I. robustus (other, Flow
through.)
Chronic toxicity to aquatic invertebrates:

No observed effect concentration (80 d), aquatic crustacea (other, static)
Persistence and degradability
Assessment biodegradation and elimination (H2O):

Inorganic product which cannot be eliminated from water by biological purification processes. Can be
oxidized to nitrate, or be reduced to nitrogen, by microorganisms.
Bioaccumulation potential
Bioaccumulation potential:
Accumulation in organisms is not to be expected. The product has not been tested. The statement has
been derived from the structure of the product.
Additional information
Other ecotoxicological advice:

Do not allow to enter soil, waterways or waste water channels. Do not release untreated into natural
waters. Inhibition of degradation activity in activated sludge is not to be anticipated during correct
introduction of low concentrations.

Contact manufacturer regarding recycling.
Check for possible recycling.
Contact waste centre regarding recycling.
Contaminated packaging:
Contaminated packaging should be emptied as far as possible and disposed of in accordance with
official regulations after being thoroughly cleaned.
Land transport
ADR
Hazard class: 5.1
Packing group: III
ID number: UN 1500
Hazard label: 5.1, 6.1, EHSM
Proper shipping name: SODIUM NITRITE
Page: 9/10
RID
Hazard class: 5.1
Packing group: III
ID number: UN 1500
Inland waterway transport

ADNR
Hazard class: 5.1
Packing group: III
ID number: UN 1500
Sea transport
IMDG
Hazard class: 5.1
Packing group: III
ID number: UN 1500
Marine pollutant: YES
Air transport
IATA/ICAO
Hazard class: 5.1
Packing group: III
ID number: UN 1500
Hazard label: 5.1, 6.1
Regulations of the European union (Labelling) / National legislation/Regulations
Directive 1999/45/EC ('Preparation Directive'):
Hazard symbol(s)
O Oxidizing.
T Toxic.
N Dangerous for the environment.
R-phrase(s)
Page: 10/10
R8 Contact with combustible material may cause fire.

R25 Toxic if swallowed.
R50 Very toxic to aquatic organisms.
S-phrase(s)
S45 In case of accident or if you feel unwell, seek medical advice immediately
(show the label where possible).
S61 Avoid release to the environment. Refer to special instructions/safety
data sheets.
Hazard determining component(s) for labelling: SODIUM NITRITE
Other regulations
as in Annex I of Directive 67/548/EEC

Recommended use: for industrial use only
This product is of industrial quality and unless otherwise specified or agreed intended exclusively for
industrial use. Any other intended applications should be discussed with the manufacturer.
Full text of hazard symbols and R-phrases if mentioned as hazardous components in chapter 3:
O Oxidizing.
T Toxic.
8 Contact with combustible material may cause fire.
25 Toxic if swallowed.
50 Very toxic to aquatic organisms.
Vertical lines in the left hand margin indicate an amendment from the previous version.
The data contained in this safety data sheet are based on our current knowledge and experience and
describe the product only with regard to safety requirements. The data do not describe the product's
properties (product specification). Neither should any agreed property nor the suitability of the product for
any specific purpose be deduced from the data contained in the safety data sheet. It is the responsibility of
the recipient of the product to ensure any proprietary rights and existing laws and legislation are observed.
SAFETY DATA SHEET
TBC 85% WATER Page: 1 / 8
Date: 19/08/2004 Version: 5.03 UK Cancels and replaces version: 4.00 UK
1 Product and company identification.

PRODUCT NAME : TBC 85% WATER
Use : Polymerisation inhibitor for monomers.
(For further information, refer to the product technical data sheet).
SUPPLIER : Manufacturer :
Name : Rhodia Organique.
Address : 190 avenue Thiers - 69457 LYON Cedex 06
Telephone number : 33 4 37 24 88 88
Telefax number : 33 4 37 24 88 89.
EMERGENCY TELEPHONE : 00 44 1865 407 333 (UK : 01865 407 333)
NUMBER
2 Composition / information on ingredients

>> SUBSTANCE
Common chemical name : 4-TERT-BUTYLPYROCATECHOL >= 98 %
Further data : Approx. 85 % aqueous solution.
CAS number : 98-29-3
Hazardous impurities : CATECHOL (CAS: 120-80-9) : < 1 % - EC Classification : Xn -
R 21/22, 36/38
3 Hazards identification
MOST IMPORTANT HAZARDS
Adverse human health effects
: Harmful on contact with skin and if swallowed.
Corrosive. Causes burns.
Environmental effects : Toxic to aquatic organisms.
May cause long-term adverse effects to the aquatic environment.
Physical and chemical hazards
- Fire or explosion
: Does NOT present any particular fire hazard.
Specific hazards : According to EC criteria, this product is classified as :
- CORROSIVE.- HARMFUL.- DANGEROUS FOR THE
ENVIRONMENT.
SAFETY DATA SHEET
TBC 85% WATER Page: 2/8
4 First-aid measures
Inhalation : Not specifically applicable.
Skin contact : Remove all contaminated clothing and footwear. Wash
immediately and thoroughly for a prolonged period (at least 15
minutes)
In case of inflammation (redness, irritation, ...) obtain medical
attention. [*]
Eye contact : Immediately rinse with plenty of running water for a prolonged
period, (at least 15 minutes) whilst keeping the eyes wide open If
irritation persists, consult a doctor. [*]
Ingestion : NEVER attempt to induce vomiting. Do not give anything to drink.
Always obtain medical attention. Show this sheet to the doctor.
[*]
Further information : Place contaminated clothing in a sealed bag for disposal. Use
appropriate protective equipment when treating a contaminated
person. [*]
5 Fire - fighting measures

Extinguishing media
- Suitable : Water spray.Foam.Powders.Carbon dioxide (CO2).
- Not suitable : None. If there is a fire close by, use suitable extinguishing
agents.
Specific hazards : Pungent irritating fumes are released.
Specific fire fighting methods : Cool down the containers/equipment exposed to heat with a
water spray.
Protection of fire-fighters : Self-contained breathing apparatus.
6 Accidental release measures

Personal precautions : Avoid contact with skin and eyes.
For further information refer to section 8
"Exposure-controls/personal protection".
Mark out the contaminated area with signs and prevent access to
unauthorized personnel.Stop the leak.
Environmental precautions : Contain the spilled material by bunding (product is hazardous for
the environment).
Methods for cleaning up
SAFETY DATA SHEET
- Recovery : Pump up the product into a spare container: - suitably labelled.

- with a closing device.
- corrosion-resistant.
Keep the recovered product for subsequent disposal.
- Neutralization : Absorb residues with:
- inert absorbent material.
- Cleaning/Decontamination : Wash with caustic soda solution (2-5 % NaOH).Then wash with
plenty of water.Recover the cleaning water for subsequent
disposal.
- Disposal : For disposal of contaminated materials refer to section 13:
"Disposal considerations".
7 Handling and storage

HANDLING
Technical measures : Ventilation.
Measures : Avoid any direct contact with the product.Do NOT handle without
gloves.
Safe handling advice : Carefully comply with the instructions for use.
STORAGE
Technical measures : The floor of the depot should be impermeable.
Storage conditions
- Recommended : Store:
- protected from air.
- protected from light.
- the container tightly closed.
- in a temperate area.
Incompatible products : Products reacting with water.
Packaging : Packaging with a closing device.
- General purpose stainless steel tankers.
- Steel drum varnished with an epoxyphenolic resin.
Packaging materials
- Recommended : Stainless steel.Coated steels.Plastic materials (polyethylene).
- Not suitable : Iron.
8 Exposure controls / personal protection

Engineering measures : Extraction to remove vapours at their source.Ensure good
ventilation of the work station.
Control parameters
Occupational exposure limits
- Limits (France) : Catechol VME: 20 mg/m3 (5 ppm). [*]
SAFETY DATA SHEET
- Limits (U.S.A./A.C.G.I.H.) : Catechol TLV ( TWA ) : 20 mg/m3 (5 ppm). [*]

- Limits (UK) : Pyrocatechol:
OES: 5 ppm (23 mg/m3). (Long term exposure limit - 8h TWA
reference period).
- Hand protection : Protective gloves made of PVC.
- Eye protection : Long face shield.
- Skin and body protection : Protective clothing.PVC apron covering the tops of the
boots.Boots made of PVC.
Collective emergency : Safety shower.Eye fountain.
equipment
Hygiene measures : Always wash your hands after handling the product.
Do NOT eat, drink or smoke during use.
Separate normal clothes from work-clothes.
9 Physical and chemical properties

APPEARANCE
- Physical state : Liquid.
- Form : clear.
- Colour : amber-yellow.
Odour : phenol.
pH : Approx. 4 (Product as is).
Specific temperatures
- Crystallisation : 12 - 15°C.
Flammability characteristics
- Flash point : Not applicable.
Oxidizing properties : Non oxidizing material according to EC criteria.
Relative density (water = 1) : 1.06 at 25°C.
Solubility
- in water : Not applicable: separates into 2 phases.
- in organic solvents : Not applicable: separates into 2 phases.
Octanol/water partition coefficient : 2.83 (log POW). [*]
(evaluation by structure-activity relationship)
Dynamic viscosity : 87 mPa.s at 25 °C.
SAFETY DATA SHEET
10 Stability and reactivity.

Stability : Stable at room temperature.
Hazardous reactions
- Conditions to avoid : No dangerous reactions known under normal conditions of use.
- Materials to avoid : - strong bases.
- strong oxidizing agents.
- Hazardous decomposition products : On combustion or on thermal decomposition (pyrolysis) releases:
irritating fumes.(Carbon oxides (CO + CO2)).(Phenol).
11 Toxicological information
Acute toxicity : LD50 skin: 1331 mg/kg (Rat) (undiluted product)
Harmful In contact with skin.
LD 50 oral: 815 mg/kg (Rat) (undiluted product)
Harmful if swallowed.
(Unpublished internal reports)
Local effects : Causes burns./on contact with skin (Rabbit) (Unpublished
internal reports)
Sensitisation : (LLNA) (Mouse) (Unpublished internal reports)
NOT considered to be : skin sensitiser [*]
Repeated dose toxicity
: Repeated dose toxicity (3 month(s)) (Rat) on ingestion
Specific effects No observed adverse effect level (NOAEL) : 70 mg/kg/day
(undiluted product) [*]
(Published data).
- Mutagenicity : Ames test.(with or without metabolic activation). Negative.

Chromosomal aberrations :(CHO)(with or without metabolic
activation).Negative.
(Unpublished internal reports)
12 Ecological information
MOBILITY
Expected behaviour of the product : Ultimate destination of the product : WATER.
BIODEGRADABILITY
- Ultimate aerobic biodegradability : Not readily biodegradable. (Unpublished internal reports)
BIOACCUMULATION
SAFETY DATA SHEET
Octanol/water partition coefficient : Not potentially bioaccumulable.

Refer to § 9 for actual figures.
ECOTOXICITY
Effects on the aquatic environment : EC 50 (Daphnia: Daphnia magna)/48 h: 1-10 mg/l. (Dry
product).(Unpublished internal reports)
Toxic to aquatic organisms tested.
13 Disposal considerations
RESIDUES FROM
PRODUCT
Prohibition : Discharging waste into rivers and drains is forbidden.
Destruction/Disposal : Incinerate at a licensed installation.
CONTAMINATED PACKAGING
Decontamination/cleaning : Allow it to drain thoroughly.
Destruction/Disposal : Incinerate at a licensed installation.
NOTE : The user's attention is drawn to the possible existence of local
regulations regarding disposal.
14 Transport information
INTERNATIONAL REGULATIONS
Land
- Rail/road (RID/ADR) : Class:8.
Packing group: III.
Hazard identification number: 80.
UN number: 3265.
Labelling: 8.
Sea (IMO/IMDG) : Class: 8.
UN Number: 3265.
Labelling: 8 CORROSIVE.
Packing group: III.
Marine pollutant: NO.
Emergency schedule (EmS): F-A, S-B.
Air (ICAO-IATA) : Class: 8.
UN number: 3265.
Labelling: 8 CORROSIVE.
Packing group: III.
Cargo aircraft : Packing instruction: 820 Quantity : 60 L.
Passenger aircraft: Packing instruction: 818 Quantity : 5 L.
OTHER REGULATIONS
SAFETY DATA SHEET
- United Kingdom: Rail/road : Substance identification number: 3265.

Classification for conveyance: 8.
Packing group: III.
Emergency action code: 2X.
NOTE : The above regulatory prescriptions are those valid on the date of
publication of this sheet.
Given the possible evolution of transport regulations for
hazardous materials, it would be advisable to check their validity
with your sales office.
15 Regulatory information
LABELLING
EC regulations : Mandatory labelling (self-classification) of hazardous substances:
APPLICABLE
- Identification of the hazardous : Chemical name of the substance :
product 4-TERT-BUTYLPYROCATECHOL
EC No. : 202-653-9.
- Classifications/Symbols : - CORROSIVE ( C )
- DANGEROUS FOR THE ENVIRONMENT ( N ).
- R phrases : R 34: Causes burns.
R 21/22: Harmful in contact with skin and if swallowed.
R 51/53: Toxic to aquatic organisms, may cause long-term
adverse effects in the aquatic environment.
- S phrases : S 26: In case of contact with eyes, rinse immediately with plenty
of water and seek medical advice.
S 36/37/39: Wear suitable protective clothing, gloves and
eye/face protection.
S 45: In case of accident or if you feel unwell, seek medical
advice immediately (show the label where possible).
S 61: Avoid release to the environment. Refer to special
instructions/safety data sheet.
>>Further regulations
United Kingdom : Handle in accordance with relevant British legislation:
Chemical Hazard Information and Packaging for Supply
Regulations
Control of Substances Hazardous to Health Regulations
Environmental Hygiene Guidance: EH/40 Occupational
Exposure Limits (revised annually).
Environmental Protection Act
Collection and Disposal of Waste Regulations
Carriage of Dangerous Goods by Road Regulations
Carriage of Dangerous Goods by Rail Regulations
Carriage of Dangerous Goods by Road and Rail (Classification,
Packaging and Labelling) and use of Transport Pressure
Receptacles Regulations
SAFETY DATA SHEET
NOTE : The regulatory information given above only indicates the

principal regulations specifically applicable to the product
described in the Safety Data Sheet. The user's attention is
drawn to the possible existence of additional provisions which
complete these regulations. Refer to all applicable national,
international and local regulations or provisions.
16 Other information
Uses
- Prohibited uses : This product is only intended for industrial use.
Chemical formula : C10 H14 O2
Molecular mass : 166.2
Registration numbers : Registered in the EINECS inventory. Registered in the TSCA
inventory. Registered in the Canadian inventory (CEPA DSL).
Registered in the Chinese inventory Registered in the Korean
inventory. Registered in the Philippine inventory (PICCS)
Registered on the MITI list.
R Phrases of § 2 & 3 : R 21/22: Harmful in contact with skin and if swallowed.
R 34: Causes burns.
R 51/53: Toxic to aquatic organisms, may cause long-term
* Update : This sheet was updated (refer to the date at the top of this page).
Subheadings and text which have been modified since the
previous version are indicated with an asterisk (*).
This safety data sheet should be used in conjunction with technical sheets. It does not replace them. The information
given is based on our knowledge of this product, at the time of publication. It is given in good faith. The attention of
the user is drawn to the possible risks incurred by using the product for any other purpose other than that for which it
was intended. This does not in any way excuse the user from knowing and applying all the regulations governing his
activity. It is the sole responsibility of the user to take all precautions required in handling the product. The aim of
the mandatory regulations mentioned is to help the user to fulfil his obligations regarding the use of hazardous
products. This information is not exhaustive. This does not exonerate the user from ensuring that legal obligations,
other than those mentioned, relating to the use and storage of the product, do not exist.This is solely his
responsibility.
B
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Page : 1 / 4
SAFETY DATA SHEET Revised edition no : 1
Date : 15/7/2005
Supersedes : 0/0/0
Propadiene 1,2 AL103
m
ó
Label 2.1 : flammable
gas.
ê
FF+ : Extremely
flammable
1 IDENTIFICATION OF THE SUBSTANCE / PREPARATION AND OF THE COMPANY / UNDERTAKING
Trade name : Propadiene 1,2

MSDS No : AL103
Chemical formula : C3H4
Company identification : AIR LIQUIDE SA
France
See paragraph 16 "OTHER INFORMATION"
Emergency phone nr : See paragraph 16 "OTHER INFORMATION"
2 COMPOSITION / INFORMATION ON INGREDIENTS
Substance / Preparation : Substance.

Substance name Contents CAS No EC No Index No Classification
Propadiene 1,2 : 100 % 463-49-0 207-335-3 ----- F+; R12
Contains no other components or impurities which will influence the classification of the product.
Hazards identification : Liquefied gas.

Extremely flammable.
First aid measures

- Inhalation : In high concentrations may cause asphyxiation. Symptoms may include loss of
mobility/consciousness. Victim may not be aware of asphyxiation.
In low concentrations may cause narcotic effects. Symptoms may include
dizziness, headache, nausea and loss of co-ordination.
Remove victim to uncontaminated area wearing self contained breathing
apparatus. Keep victim warm and rested. Call a doctor. Apply artificial respiration if
breathing stopped.
- Skin/eye contact : For liquid spillage - flush with water for at least 15 minutes.
- Ingestion : Ingestion is not considered a potential route of exposure.
5 FIRE-FIGHTING MEASURES
Flammable class : Extremely flammable.

Specific hazards : Exposure to fire may cause containers to rupture/explode.
Hazardous combustion products : Incomplete combustion may form carbon monoxide.
Extinguishing media
- Suitable extinguishing media : All known extinguishants can be used.
Specific methods : If possible, stop flow of product.
Move away from the container and cool with water from a protected position.
Do not extinguish a leaking gas flame unless absolutely necessary. Spontaneous/
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5 FIRE-FIGHTING MEASURES (continued)
explosive re-ignition may occur. Extinguish any other fire.

Special protective equipment for fire : In confined space use self-contained breathing apparatus.
fighters
Personal precautions : Evacuate area.

Wear self-contained breathing apparatus when entering area unless atmosphere is
proved to be safe.
Ensure adequate air ventilation.
Eliminate ignition sources.
Environmental precautions : Try to stop release.
Prevent from entering sewers, basements and workpits, or any place where its
accumulation can be dangerous.
Clean up methods : Ventilate area.
Storage : Segregate from oxidant gases and other oxidants in store.

Keep container below 50°C in a well ventilated place.
Handling : Ensure equipment is adequately earthed.
Avoid contact with pure copper, mercury, silver and brass with greater than 70%
copper.
Suck back of water into the container must be prevented.
Purge air from system before introducing gas.
Do not allow backfeed into the container.
Use only properly specified equipment which is suitable for this product, its supply
pressure and temperature. Contact your gas supplier if in doubt.
Keep away from ignition sources (including static discharges).
Refer to supplier's container handling instructions.
8 EXPOSURE CONTROLS / PERSONAL PROTECTION
Personal protection : Ensure adequate ventilation.

Do not smoke while handling product.
Physical state at 20 °C : Liquefied gas.

Colour : Colourless gas.
Odo(u)r : Sweetish. Poor warning properties at low concentrations.
Molecular weight : 40
Melting point [°C] : -136
Boiling point [°C] : -34.4
Critical temperature [°C] : 121
Vapour pressure, 20°C : 7 bar
Relative density, gas (air=1) : 1.4
Relative density, liquid (water=1) : 0.65
Solubility in water [mg/l] : No reliable data available.
Flammability range [vol% in air] : 2.5 to 17
Auto-ignition temperature [°C] : Not known.
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9 PHYSICAL AND CHEMICAL PROPERTIES (continued)
Other data : Gas/vapour heavier than air. May accumulate in confined spaces, particularly at or
below ground level.
Stability and reactivity : Can form explosive mixture with air.

May decompose violently at high temperature and/or pressure or in the presence of
a catalyst.
May react with bases, copper, silver, mercury, magnesium, zinc and their alloys.
Do not use alloys containing more than 70% copper.
Inhibitor usually added.
May react violently with oxidants.
Toxicity information : No known toxicological effects from this product.
12 ECOLOGICAL INFORMATION
Ecological effects information : No known ecological damage caused by this product.
13 DISPOSAL CONSIDERATIONS
General : Do not discharge into areas where there is a risk of forming an explosive mixture
with air. Waste gas should be flared through a suitable burner with flash back
arrestor.
Do not discharge into any place where its accumulation could be dangerous.
Contact supplier if guidance is required.
14 TRANSPORT INFORMATION
UN No. : 2200
H.I. nr : 239
ADR/RID
- Proper shipping name : PROPADIENE, STABILIZED
- ADR Class : 2
- ADR/RID Classification code : 2F
- Labelling ADR : Label 2.1 : flammable gas.
Other transport information : Avoid transport on vehicles where the load space is not separated from the driver's
compartment.
Ensure vehicle driver is aware of the potential hazards of the load and knows what
to do in the event of an accident or an emergency.
Before transporting product containers :
- Ensure that containers are firmly secured.
- Ensure cylinder valve is closed and not leaking.
- Ensure valve outlet cap nut or plug (where provided) is correctly fitted.
- Ensure valve protection device (where provided) is correctly fitted.
- Ensure there is adequate ventilation.
- Compliance with applicable regulations.
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EC Classification : Not included in Annex I.

Proposed by the industry.
F+; R12
EC Labelling
- Symbol(s) : F+ : Extremely flammable
- R Phrase(s) : R12 : Extremely flammable.
- S Phrase(s) : S9 : Keep container in a well-ventilated place.
S16 : Keep away from sources of ignition - No smoking.
S33 : Take precautionary measures against static discharges.
16 OTHER INFORMATION
Ensure all national/local regulations are observed.
Ensure operators understand the flammability hazard.
Contact with liquid may cause cold burns/frostbite.
The hazard of asphyxiation is often overlooked and must be stressed during operator training.
This Safety Data Sheet has been established in accordance with the applicable European Directives and applies to all
countries that have translated the Directives in their national laws.
Before using this product in any new process or experiment, a thorough material compatibility and safety study should be
carried out.
Details given in this document are believed to be correct at the time of going to press. Whilst proper care has been taken in
the preparation of this document, no liability for injury or damage resulting from its use can be accepted.
Recommended uses and restrictions : This SDS is for information purposes only and is subject to change without notice. [
Prior to purchase of products, please contact your local AIR LIQUIDE office for a
complete SDS (with Manufacturer's name and emergency phone number).]
End of document
AIR LIQUIDE SA
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Methyl acetylene AL081
m
ó
gas.
ê
FF+ : Extremely
flammable
Trade name : Methyl acetylene

MSDS No : AL081
Chemical formula : C3H4 / CH3-C=CH
France

Methyl acetylene : 100 % 74-99-7 200-828-4 ----- F+; R12

First aid measures

breathing stopped.
Remove contaminated clothing.
Obtain medical assistance.
Immediately flush eyes thoroughly with water for at least 15 minutes.

Extinguishing media
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Continue water spray from protected position until container stays cool.
Special protective equipment for fire : Use self-contained breathing apparatus and chemically protective clothing.
fighters In confined space use self-contained breathing apparatus.
Personal precautions : Wear self-contained breathing apparatus when entering area unless atmosphere is
proved to be safe.
Evacuate area.
Use self-contained breathing apparatus and chemically protective clothing.
Reduce vapour with fog or fine water spray.
Hose down area with water.
Wash contaminated equipment or sites of leaks with copious quantities of water.
Storage : Keep container below 50°C in a well ventilated place.

Segregate from oxidant gases and other oxidants in store.
copper.

Keep self contained breathing apparatus readily available for emergency use.
Keep suitable chemically resistant protective clothing readily available for
emergency use.
Occupational Exposure Limits : Methyl acetylene : TLV© -TWA [ppm] : 1000
Methyl acetylene : MAK - Germany [ppm] : 1000
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Odo(u)r : Garlic like. Poor warning properties at low concentrations.
Vapour pressure, 20°C : 5.1 bar
Solubility in water [mg/l] : 3070
Flammability range [vol% in air] : 2.3 to 16.8
below ground level.
Stability and reactivity : May react violently with oxidants.

Forms explosive acetylides with copper, silver and mercury.
Can form explosive mixture with air.
a catalyst.
May polymerise.
General : Avoid discharge to atmosphere.

Do not discharge into areas where there is a risk of forming an explosive mixture
arrestor.
UN No. : 1060
H.I. nr : 239
ADR/RID
- Proper shipping name : METHYLACETYLENE AND PROPADIENE MIXTURE, STABILIZED
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14 TRANSPORT INFORMATION (continued)
- ADR Class : 2
compartment.

F+; R12
EC Labelling
Contact with liquid may cause cold burns/frostbite.
Users of breathing apparatus must be trained.
carried out.
End of document
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Butane n- AL014
m
ó
gas.
ê
FF+ : Extremely
flammable
Trade name : Butane n-

MSDS No : AL014
France

Butane n- : 100 % 106-97-8 203-448-7 601-004-00-0 F+; R12

First aid measures

breathing stopped.

Extinguishing media
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Butane n- AL014

fighters
proved to be safe.
Evacuate area.


Occupational Exposure Limits : Butane n- : TLV© -TWA [ppm] : 800
Butane n- : OEL (UK)-LTEL [ppm] : 600
Butane n- : OEL (UK)-STEL [ppm] : 750
Butane n- : VME - France [ppm] : 800
Butane n- : MAK - Germany [ppm] : 1000

Odo(u)r : Sweetish. Poor warning properties at low concentrations. Stenchant often added.
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Butane n- AL014

Auto-ignition temperature [°C] : 365
below ground level.

Acute toxicity : No known toxicological effects from this product.
arrestor.
UN No. : 1011
H.I. nr : 23
ADR/RID
- Proper shipping name : BUTANE
- ADR Class : 2
compartment.
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Butane n- AL014
EC Classification : Index No : 601-004-00-0

F+; R12
EC Labelling
carried out.
End of document
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Butane (containing >= 0,1 % 1,3-butadiene) AL128
m
óLabel 2.1 : flammable
gas.
Tê
ê FT : Toxic F+ : Extremely
flammable
Trade name : Butane (containing >= 0,1 % 1,3-butadiene)

MSDS No : AL128
Chemical formula : nC4H10 (1,3 C4H6)
France

Butane (containing >= 0,1 % 1,3- : 100 % 106-97-8 203-448-7 601-004-01-8 F+; R12
butadiene) Carc. Cat. 1; R45
Muta. Cat. 2; R46

May cause cancer.
May cause heritable genetic damage.
First aid measures

breathing stopped.
- Skin/eye contact : Obtain medical assistance.
Immediately flush eyes thoroughly with water for at least 15 minutes.

Extinguishing media
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Special protective equipment for fire : Use self-contained breathing apparatus and chemically protective clothing.
fighters In confined space use self-contained breathing apparatus.

proved to be safe.
Keep area evacuated and free from ignition sources until any spilled liquid has
evaporated. (Ground free from frost).


Keep self contained breathing apparatus readily available for emergency use.
Occupational Exposure Limits : Butane (containing >= 0,1 % 1,3-butadiene) : TLV© -TWA [ppm] : 800
Butane (containing >= 0,1 % 1,3-butadiene) : OEL (UK)-LTEL [ppm] : 600
Butane (containing >= 0,1 % 1,3-butadiene) : OEL (UK)-STEL [ppm] : 750
Butane (containing >= 0,1 % 1,3-butadiene) : VME - France [ppm] : 800
Butane (containing >= 0,1 % 1,3-butadiene) : MAK - Germany [ppm] : 1000

Odo(u)r : Poor warning properties at low concentrations.
Relative density, gas (air=1) : Heavier than air.
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below ground level.

May polymerise.
Acute toxicity : May have carcinogenic effect.

Possible risks of irreversible effects.
General : Avoid discharge to atmosphere.

Do not discharge into areas where there is a risk of forming an explosive mixture
arrestor.
UN No. : 1011
H.I. nr : 23
ADR/RID
- Proper shipping name : BUTANE
- ADR Class : 2
compartment.
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F+; R12
Carc. Cat. 1; R45
Muta. Cat. 2; R46
EC Labelling
T : Toxic
R45 : May cause cancer.
R46 : May cause heritable genetic damage.
- S Phrase(s) : S45 : In case of accident or if you feel unwell, seek medical advice immediately (
show the label when possible).
S53 : Avoid exposure - obtain special instructions before use.
Ensure operators understand the toxicity hazard.
Users of breathing apparatus must be trained.
carried out.
End of document
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Isobutene AL076
m
ó
gas.
ê
FF+ : Extremely
flammable
Trade name : Isobutene

MSDS No : AL076
Chemical formula : C4H8 / CH2=C(CH3)2
France

Isobutene : 100 % 115-11-7 204-066-3 601-012-00-4 F+; R12

First aid measures

breathing stopped.

Extinguishing media
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Isobutene AL076

fighters
proved to be safe.
Evacuate area.



Melting point [°C] : 140.3
Relative density, gas (air=1) : 2
Flammability range [vol% in air] : 1.6 to 10
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Isobutene AL076
below ground level.

arrestor.
UN No. : 1055
H.I. nr : 23
ADR/RID
- Proper shipping name : ISOBUTYLENE
- ADR Class : 2
compartment.

F+; R12
EC Labelling
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Isobutene AL076
15 REGULATORY INFORMATION (continued)

carried out.
End of document
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Butene cis AL015
m
ó
gas.
ê
FF+ : Extremely
flammable
Trade name : Butene cis

MSDS No : AL015
France

Butene cis : 100 % 590-18-1 209-673-7 601-012-00-4 F+; R12

First aid measures

breathing stopped.

Extinguishing media
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Butene cis AL015

fighters

proved to be safe.



Boiling point [°C] : 3.7
Solubility in water [vol/vol] : No reliable data available.
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Butene cis AL015
below ground level.

arrestor.
UN No. : 1012
H.I. nr : 23
ADR/RID
- Proper shipping name : BUTYLENE
- ADR Class : 2
compartment.

F+; R12
EC Labelling
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Butene cis AL015

carried out.
End of document
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Butene trans- AL016
m
ó
gas.
ê
FF+ : Extremely
flammable
Trade name : Butene trans-

MSDS No : AL016
France

Butene trans- : 100 % 624-64-6 210-855-3 601-012-00-4 F+; R12

First aid measures

breathing stopped.

Extinguishing media
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Butene trans- AL016

fighters

proved to be safe.



Solubility in water [vol/vol] : No reliable data available.
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Butene trans- AL016
below ground level.

arrestor.
UN No. : 1012
H.I. nr : 23
ADR/RID
- Proper shipping name : BUTYLENE
- ADR Class : 2
compartment.

F+; R12
EC Labelling
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Butene trans- AL016

carried out.
End of document
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Ethyl acetylene AL052
m
ó
gas.
ê
FF+ : Extremely
flammable
Trade name : Ethyl acetylene

MSDS No : AL052
France

Ethyl acetylene : 100 % 107-00-6 203-451-3 ----- F+; R12

First aid measures

breathing stopped.

Extinguishing media
Continue water spray from protected position until container stays cool.
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fighters
proved to be safe.
Evacuate area.

copper.


Odo(u)r : Garlic like. Poor warning properties at low concentrations.
Boiling point [°C] : 8
Flammability range [vol% in air] : Not known.
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below ground level.

a catalyst.
Forms explosive acetylides with copper, silver and mercury.
May polymerise.
arrestor.
UN No. : 2452
H.I. nr : 239
ADR/RID
- Proper shipping name : ETHYLACETYLENE, STABILIZED
- ADR Class : 2
compartment.
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EC Classification : Not included in Annex I. Proposed by the industry.

F+; R12
EC Labelling
carried out.
End of document
AIR LIQUIDE SA
France
Page 1 of 7
MATHESON TRI-GAS, INC. Emergency Contact:

150 Allen Road Suite 302 CHEMTREC 1-800-424-9300
Basking Ridge, New Jersey 07920 Calls Originating Outside the US:
Information: 1-800-416-2505 703-527-3887 (Collect Calls Accepted)
SUBSTANCE: VINYL ACETYLENE
TRADE NAMES/SYNONYMS:
BUTENYNE; 1-BUTEN-3-YNE; 1-BUTENYNE; MONOVINYLACETYLENE; VINYLACETYLENE; 3-
BUTEN-1-YNE; 00231821; RTECS EN0950000
CHEMICAL FAMILY: hydrocarbons, aliphatic
CREATION DATE: Apr 21 2006

REVISION DATE: Sep 13 2007
2. COMPOSITION, INFORMATION ON INGREDIENTS
COMPONENT: VINYL ACETYLENE

CAS NUMBER: 689-97-4
PERCENTAGE: 100
NFPA RATINGS (SCALE 0-4): HEALTH=2 FIRE=4 REACTIVITY=3
EMERGENCY OVERVIEW:
COLOR: colorless
PHYSICAL FORM: liquid, gas
ODOR: distinct odor
MAJOR HEALTH HAZARDS: respiratory tract irritation, skin irritation, eye irritation, central nervous
system depression, difficulty breathing
PHYSICAL HAZARDS: May explode when heated. Flammable gas. May cause flash fire. Flash back
hazard. May polymerize. Containers may rupture or explode. May form peroxides during prolonged storage.
POTENTIAL HEALTH EFFECTS:

INHALATION:
Page 2 of 7
SHORT TERM EXPOSURE: irritation, nausea, vomiting, irregular heartbeat, headache, drowsiness,
fatigue, dizziness, tingling sensation, loss of coordination, suffocation, convulsions, unconsciousness, coma
LONG TERM EXPOSURE: no information is available
SKIN CONTACT:
SHORT TERM EXPOSURE: irritation
LONG TERM EXPOSURE: irritation
EYE CONTACT:
SHORT TERM EXPOSURE: irritation
LONG TERM EXPOSURE: irritation
INGESTION:
SHORT TERM EXPOSURE: ingestion of a gas is unlikely
LONG TERM EXPOSURE: ingestion of a gas is unlikely
INHALATION: If adverse effects occur, remove to uncontaminated area. Give artificial respiration if not
breathing. If breathing is difficult, oxygen should be administered by qualified personnel. Get immediate
medical attention.
SKIN CONTACT: Wash skin with soap and water for at least 15 minutes while removing contaminated
clothing and shoes. Get medical attention, if needed. Thoroughly clean and dry contaminated clothing and
shoes before reuse.
EYE CONTACT: Flush eyes with plenty of water for at least 15 minutes. Then get immediate medical
attention.
INGESTION: If a large amount is swallowed, get medical attention.
NOTE TO PHYSICIAN: For inhalation, consider oxygen.
FIRE AND EXPLOSION HAZARDS: Flammable. The gas is heavier than air. Vapors or gases may ignite
at distant ignition sources and flash back. Vapor/air mixtures are explosive above flash point. Gas/air
mixtures are explosive. Containers may rupture or explode if exposed to heat.
EXTINGUISHING MEDIA: carbon dioxide, regular dry chemical
Large fires: Flood with fine water spray.
FIRE FIGHTING: Move container from fire area if it can be done without risk. Cool containers with water
spray until well after the fire is out. Stay away from the ends of tanks. For fires in cargo or storage area: Cool
containers with water from unmanned hose holder or monitor nozzles until well after fire is out. If this is
impossible then take the following precautions: Keep unnecessary people away, isolate hazard area and deny
Page 3 of 7
entry. Let the fire burn. Withdraw immediately in case of rising sound from venting safety device or any
discoloration of tanks due to fire. For tank, rail car or tank truck: Stop leak if possible without personal risk.
Let burn unless leak can be stopped immediately. For smaller tanks or cylinders, extinguish and isolate from
other flammables. Evacuation radius: 800 meters (1/2 mile). Do not attempt to extinguish fire unless flow of
material can be stopped first. Flood with fine water spray. Cool containers with water spray until well after
the fire is out. Apply water from a protected location or from a safe distance. Avoid inhalation of material or
combustion by-products. Stay upwind and keep out of low areas. Evacuate if fire gets out of control or
containers are directly exposed to fire. Evacuation radius: 500 meters (1/3 mile). Consider downwind
evacuation if material is leaking.
FLASH POINT: <23 F (<-5 C)

LOWER FLAMMABLE LIMIT: 2%
UPPER FLAMMABLE LIMIT: 100% (decomposes)
HAZARDOUS COMBUSTION PRODUCTS:

Thermal decomposition or combustion products: oxides of carbon
OCCUPATIONAL RELEASE:
Avoid heat, flames, sparks and other sources of ignition. Do not touch spilled material. Stop leak if possible
without personal risk. Reduce vapors with water spray. Keep unnecessary people away, isolate hazard area
and deny entry. Remove sources of ignition. Ventilate closed spaces before entering.
STORAGE: Store and handle in accordance with all current regulations and standards. Store in a well-
ventilated area. Keep away from heat, sparks and flame. Protect from physical damage. Protect from sunlight.
Subject to storage regulations: U.S. OSHA 29 CFR 1910.101. Keep separated from incompatible substances.
8. EXPOSURE CONTROLS, PERSONAL PROTECTION
EXPOSURE LIMITS:
VINYL ACETYLENE:
No occupational exposure limits established.
VENTILATION: Ventilation equipment should be explosion-resistant if explosive concentrations of

material are present. Provide local exhaust ventilation system. Ensure compliance with applicable exposure
limits.
EYE PROTECTION: Wear splash resistant safety goggles with a faceshield. Provide an emergency eye
wash fountain and quick drench shower in the immediate work area.
Page 4 of 7
CLOTHING: Wear appropriate chemical resistant clothing.
GLOVES: Wear appropriate chemical resistant gloves.
RESPIRATOR: Under conditions of frequent use or heavy exposure, respiratory protection may be needed.
Respiratory protection is ranked in order from minimum to maximum. Consider warning properties before
use.
Any supplied-air respirator with a full facepiece that is operated in a pressure-demand or other positive-
pressure mode.
Any self-contained breathing apparatus that has a full facepiece and is operated in a pressure-demand or
other positive-pressure mode.
For Unknown Concentrations or Immediately Dangerous to Life or Health -
Any supplied-air respirator with a full facepiece that is operated in a pressure-demand or other positive-
pressure mode in combination with an auxiliary self-contained breathing apparatus operated in pressure-
demand or other positive-pressure mode.
Any self-contained breathing apparatus that has a full facepiece and is operated in a pressure-demand or
other positive-pressure mode.
PHYSICAL STATE: gas

COLOR: colorless
PHYSICAL FORM: liquid, gas
ODOR: distinct odor
MOLECULAR WEIGHT: 52.05
MOLECULAR FORMULA: C4-H4
BOILING POINT: 41 F (5 C) @ 757 mmHg
FREEZING POINT: Not available
VAPOR PRESSURE: 1350 mmHg @ 25 C
VAPOR DENSITY (air=1): 1.8
SPECIFIC GRAVITY (water=1): 0.7905 @ 0 C
WATER SOLUBILITY: 1.79 g/L @ 30 C
PH: Not applicable
VOLATILITY: Not applicable
ODOR THRESHOLD: 60 mg/m3
EVAPORATION RATE: Not applicable
COEFFICIENT OF WATER/OIL DISTRIBUTION: Not applicable
SOLVENT SOLUBILITY:
Soluble: benzene
REACTIVITY: May explode when heated. May decompose explosively when heated. May polymerize
violently or explosively. Avoid contact with heat, light, sunlight, oxygen, air, peroxides, high temperatures
Page 5 of 7
and oxidizers. May form explosive peroxides.
CONDITIONS TO AVOID: Avoid heat, flames, sparks and other sources of ignition. Minimize contact
with material. Containers may rupture or explode if exposed to heat.
INCOMPATIBILITIES: combustible materials, oxidizing materials, peroxides, 1,3-butadiene
HAZARDOUS DECOMPOSITION:
Thermal decomposition or combustion products: oxides of carbon
POLYMERIZATION: May polymerize violently or explosively. Avoid contact with heat, light, sunlight,
oxygen, air, peroxides, high temperatures and oxidizers.
VINYL ACETYLENE:
TOXICITY DATA: 97200 mg/m3 inhalation-mouse LC50
LOCAL EFFECTS:
Irritant: inhalation, skin, eye
ACUTE TOXICITY LEVEL:
Moderately Toxic: inhalation
TARGET ORGANS: central nervous system
FATE AND TRANSPORT:

KOW: 1.4 (log = 0.148) estimated
KOC: 70 (log = 1.85) estimated
HENRY'S LAW CONSTANT: 2.9 E -2
BIOCONCENTRATION: 0.76 (estimated from KOW)
ENVIRONMENTAL SUMMARY: Leaches through the soil or the sediment at a rapid rate. Accumulates
very little in the bodies of living organisms. Highly volatile from water.
Dispose in accordance with all applicable regulations. Subject to disposal regulations: U.S. EPA 40 CFR 262.
Hazardous Waste Number(s): D001. D003.
Page 6 of 7
U.S. DOT 49 CFR 172.101:

PROPER SHIPPING NAME: Compressed gas, flammable, n.o.s. (VINYL ACETYLENE)
ID NUMBER: UN1954
HAZARD CLASS OR DIVISION: 2.1
LABELING REQUIREMENTS: 2.1
QUANTITY LIMITATIONS:
PASSENGER AIRCRAFT OR RAILCAR: Forbidden
CARGO AIRCRAFT ONLY: 150 kg
CANADIAN TRANSPORTATION OF DANGEROUS GOODS:

SHIPPING NAME: Compressed gas, flammable, n.o.s. (VINYL ACETYLENE)
UN NUMBER: UN1954
CLASS: 2.1
U.S. REGULATIONS:
CERCLA SECTIONS 102a/103 HAZARDOUS SUBSTANCES (40 CFR 302.4): Not regulated.
SARA TITLE III SECTION 302 EXTREMELY HAZARDOUS SUBSTANCES (40 CFR 355.30): Not
regulated.
SARA TITLE III SECTION 304 EXTREMELY HAZARDOUS SUBSTANCES (40 CFR 355.40): Not
regulated.
SARA TITLE III SARA SECTIONS 311/312 HAZARDOUS CATEGORIES (40 CFR 370.21):
ACUTE: Yes
CHRONIC: No
FIRE: Yes
REACTIVE: Yes
SUDDEN RELEASE: Yes
SARA TITLE III SECTION 313 (40 CFR 372.65): Not regulated.
OSHA PROCESS SAFETY (29CFR1910.119): Not regulated.
STATE REGULATIONS:
California Proposition 65: Not regulated.
CANADIAN REGULATIONS:
WHMIS CLASSIFICATION: Not determined.
Page 7 of 7
NATIONAL INVENTORY STATUS:
U.S. INVENTORY (TSCA): Listed on inventory.
TSCA 12(b) EXPORT NOTIFICATION: Not listed.
CANADA INVENTORY (DSL/NDSL): Not determined.
“RTECS®” is a United States trademark owned and licensed under authority of the U.S. Government, by
and through Symyx Software, Inc. Portions ©Copyright 2001, U.S. Government. All rights reserved.
©Copyright 1984-2008 ChemADVISOR, Inc. All rights reserved.
MATHESON TRI-GAS, INC. MAKES NO EXPRESS OR IMPLIED WARRANTIES,

GUARANTEES OR REPRESENTATIONS REGARDING THE PRODUCT OR THE
INFORMATION HEREIN, INCLUDING BUT NOT LIMITED TO ANY IMPLIED WARRANTY
OF MERCHANTABILITY OR FITNESS FOR USE. MATHESON TRI-GAS, INC. SHALL NOT BE
LIABLE FOR ANY PERSONAL INJURY, PROPERTY OR OTHER DAMAGES OF ANY NATURE,
WHETHER COMPENSATORY, CONSEQUENTIAL, EXEMPLARY, OR OTHERWISE,
RESULTING FROM ANY PUBLICATION, USE OR RELIANCE UPON THE INFORMATION
HEREIN.
B
C
Page : 1 / 4
Date : 15/7/2005
Supersedes : 0/0/0
Methyl 3- butene 1 AL079
p
ó
Label 3 : Flammable
liquid.
ê
FF+ : Extremely
flammable
Trade name : Methyl 3- butene 1

MSDS No : AL079
France

Methyl 3- butene 1 : 100 % 563-45-1 209-249-1 ----- F+; R12

First aid measures

breathing stopped.

Extinguishing media
AIR LIQUIDE SA
France
B
C
Page : 2 / 4
Date : 15/7/2005
Supersedes : 0/0/0

fighters
proved to be safe.
Evacuate area.


Physical state at 20 °C : Liquid.

Colour : Colourless.
Odo(u)r : Mildly aromatic.
Poor warning properties at low concentrations.
AIR LIQUIDE SA
France
B
C
Page : 3 / 4
Date : 15/7/2005
Supersedes : 0/0/0
below ground level.

Ecological effects information : No ecological damage caused by this product.
arrestor.
UN No. : 2561
H.I. nr : 33
ADR/RID
- Proper shipping name : 3-METHYL-1-BUTENE
- ADR Class : 3
- ADR Packing group : I
- Labelling ADR : Label 3 : Flammable liquid.
compartment.

F+; R12
EC Labelling
AIR LIQUIDE SA
France
B
C
Page : 4 / 4
Date : 15/7/2005
Supersedes : 0/0/0

carried out.
End of document
AIR LIQUIDE SA
France
PRODUCT
FORTIS EC3071B

PRODUCT NAME : FORTIS EC3071B

Postbus 627

NALCO EUROPE B.V. +31 71 5241 100

NALCO AB (SE) +46 (0)8-50074000 NALCO ITALIANA S.R.L.(I) +39 06-542971
NALCO ANADOLU KIMYA (TR) +90 216 5743464 NALCO Kft. (HU) +36 (0)1 471 91 81
NALCO APPLIED SERVICES OF +31 (0)73 6456980 NALCO LIMITED +44 (0)1606 74488
EUROPE BV
NALCO BELGIUM N.V./S.A. (B) +32 (0)3-450 69 10 NALCO NETHERLANDS B.V. +31 (0)13-5952200
NALCO DANMARK A/S +45-48195800 NALCO NORGE AS (NO) +47 51 96 36 00
NALCO DEUTSCHLAND GmbH (D) +49 (0)69-79340 NALCO ÖSTERREICH Ges.m.b.H. + 43(0)1 27026350
(A)
NALCO ESPAÑOLA S.A. (E) +34 93-4095555 NALCO POLSKA Sp.z.o.o. (PL) +48 (0)32-3262750
NALCO FINLAND OY (FI) +358 (0)9 2517 4700 NALCO PORTUGUESA LDA. (P) +351 214130996
NALCO FRANCE SAS +33 (0)3 20 11 70 00 WYSS WASSERTECHNIK AG (CH) +41 (0)52 235 38 38
Hazardous Substance(s) EINECS / SYMBOL R-PHRASES / % (w/w)

ELINCS NO NOTAS
Xylene 215-535-7 Xn R10, R20/21, 30 - 60
R38 Nota C
Substituted phenol Proprietary Xi R36, R52/53 10 - 30
Isobutanol 201-148-0 Xi R10, R37/38, 1- 5
R41, R67
Ethylbenzene 202-849-4 F, Xn R11, R20 10 - 30
Flammable. Harmful by inhalation and in contact with skin. Irritating to eyes and skin. Harmful to aquatic
organisms, may cause long-term adverse effects in the aquatic environment.
NALCO EUROPE B.V. Postbus 627 • 2300 AP Leiden, , , The Netherlands • 0031 71 5241100
1 / 13
PRODUCT
FORTIS EC3071B

INHALATION :
SKIN CONTACT :
Can cause moderate irritation. Harmful if absorbed through skin.
EYE CONTACT :
INGESTION :
Not a likely route of exposure. There may be irritation to the gastro-intestinal tract. May cause nausea and
vomiting. Can cause chemical pneumonia if aspirated into lungs following ingestion. Can cause central nervous
system depression.

ethylbenzene and determined it to be possibly carcinogenic to humans (Group 2B, based on sufficient evidence
in experimental animals and inadequate evidence in humans).

Flammable.
INHALATION :
SKIN CONTACT :
EYE CONTACT :
INGESTION :
NOTE TO PHYSICIAN :
Foam, Carbon dioxide, Dry powder, Other extinguishing agent suitable for Class B fires, For large fires, use
water spray or fog, thoroughly drenching the burning material.
2 / 13
PRODUCT
FORTIS EC3071B



Flammable Liquid; may release vapors that form flammable mixtures at or above the flash point. Vapors can
travel to a source of ignition and flash back. Empty product containers may contain product residue. Do not
pressurize, cut, heat, weld, or expose containers to flame or other sources of ignition. May evolve oxides of
carbon (COx) under fire conditions.

Restrict access to area as appropriate until clean-up operations are complete. Use personal protective
equipment recommended in Section 8 (Exposure Controls/Personal Protection). Stop or reduce any leaks if it is
safe to do so. Ventilate spill area if possible. Remove sources of ignition. Ensure clean-up is conducted by
trained personnel only. Do not touch spilled material. Have emergency equipment (for fires, spills, leaks, etc.)
readily available. Notify appropriate government, occupational health and safety and environmental authorities.

container. Wash affected area. LARGE SPILLS: Contain liquid using absorbent material, by digging trenches
or by diking. Reclaim into recovery or salvage drums or tank truck for proper disposal. Clean contaminated
surfaces with water or aqueous cleaning agents. Contact an approved waste hauler for disposal of
contaminated recovered material. Dispose of material in compliance with regulations indicated in Section 13
(Disposal Considerations).
Prevent material from entering sewers or waterways. This product may pose a risk to the aquatic ecosystem if
released.
HANDLING :
leaks, etc.) readily available. Ensure all containers are labelled. Do not use, store, spill or pour near heat,
sparks or open flame.
Store in suitable labelled containers. Store the containers tightly closed. Store away from heat and sources of

HDPE (high density polyethylene), Viton, Carbon Steel C1018, Stainless Steel 304, Stainless Steel 316L, MDPE
(medium density polyethylene), Perfluoroelastomer, PTFE, FEP (encapsulated)

Neoprene, Nitrile, EPDM, TFE
3 / 13
PRODUCT
FORTIS EC3071B

SPECIFIC USE(S) :
PROCESS ANTIFOULANT
For specific dosages and customized applications please contact your Nalco representative.
Exposure guidelines have not been established for this product. Available exposure limits for the substance(s)
are shown below.

________BELGIU Xylene TWA 100 440
M
STEL 150 660
Di-tert-Butyl-Methylphenol TWA 10

STEL 125 551
DENMARK Xylene GV 25 109

Skin*
Di-tert-Butyl-Methylphenol GV 10
Isobutanol LOFT 50 150

Skin*
LOFT 50
Skin*
Ethylbenzene GV 50 217
FINLAND Xylene HTP 8H 50 220

HTP 15MIN 100 440
Skin*
Di-tert-Butyl-Methylphenol HTP 8H 10
HTP 15MIN 20
Isobutanol HTP 8H 50 150

HTP 15MIN 75 230
Skin*
Ethylbenzene HTP 8H 50 220

HTP 15MIN 200 880
Skin*
FRANCE Di-tert-Butyl-Methylphenol VME 10
Isobutanol VME 50 150
Ethylbenzene VLE 200 884
GERMANY Xylene MAK 100 440

Skin*
Di-tert-Butyl-Methylphenol (Inhalable fraction.) MAK 10

Di-tert-Butyl-Methylphenol Ex_Limit
4 / 13
PRODUCT
FORTIS EC3071B

Isobutanol MAK 100 310
Ethylbenzene MAK 100 440

Skin*
IRELAND Xylene TWA 50 221

STEL 100 442
Skin*

STEL 75 225

STEL 125 545
Skin*
ITALY Xylene TWA 50 221

STEL 100 442
Skin*
Di-tert-Butyl-Methylphenol (Vapor and aerosol, inhalable fraction) TWA 2
Isobutanol TWA 50

STEL 200 884
Skin*
NETHERLANDS Xylene MAC TGG 50 210

Skin*
Di-tert-Butyl-Methylphenol MAC TGG 10
Isobutanol MAC TGG 50 150
Ethylbenzene MAC TGG 50 215

Skin*
NORWAY Xylene ADM. NORM 25 108

Skin*
Ethylbenzene ADM. NORM 5 20

Skin*
SPAIN Xylene VLA-EC 100 442

Skin*
VLA-ED 50 221
Di-tert-Butyl-Methylphenol (Respirable fraction.) VLA-ED 3

Di-tert-Butyl-Methylphenol (Inhalable fraction.) VLA-ED 10
Isobutanol VLA-ED 50 154
Ethylbenzene VLA-ED 100 441

VLA-EC 125 551
Skin*
SWEDEN Xylene NGV 50 200

KTV 100 450
Skin*
Di-tert-Butyl-Methylphenol (Respirable dust) NGV 5

Di-tert-Butyl-Methylphenol (Total dust.) NGV 10
Ethylbenzene NGV 50 200
5 / 13
PRODUCT
FORTIS EC3071B

KTV 100 450
SWITZERLAND Xylene TWA 100 435

STEL 200 870
Skin*
Di-tert-Butyl-Methylphenol (Inhalable dust) TWA 10

STEL 50 150

STEL 100 435
Skin*
UNITED KINGDOM Xylene TWA 50 220

STEL 100 441
Skin*

STEL 75 231

STEL 125 552
Skin*
the eyes.
A small volume of air is drawn through an absorbant or barrier to trap the substance(s) which can then be
desorbed or removed and analyzed as referenced below:
Xylene US NIOSH: 1501 Gas chromatography Charcoal
Di-tert-Butyl-Methylphenol No method identified
Isobutanol US NIOSH: 1401 Gas chromatography Charcoal
Ethylbenzene US NIOSH: 1501 Gas chromatography Charcoal

Ethylbenzene
A biological index of exposure to ethyl benzene (CAS 100-41-4) is the detection of ethyl benzene in the blood
post shift (Germany, 1mg/l). Another biological index is the detection of mandelic acid in the urine post shift
(USA, 1.5g/g creatinine; Findland, 5.2mmol/l; Germany 800mg/g creatinine) and the detection of phenylglyoxylic
acid in urine post shift (Germany, 800mg/g creatinine).
General ventilation is recommended. The use of local exhaust ventilation is recommended to control emissions
near the source. Laboratory samples should be handled in a fumehood. Provide mechanical ventilation of
confined spaces.
6 / 13
PRODUCT
FORTIS EC3071B

PERSONAL PROTECTION
GENERAL ADVICE :
The use and choice of personal protection equipment is related to the hazard of the product, the workplace and
the way the product is handled. In general, we recommend as a minimum precaution that safety glasses with
chemicals being handled. Consider the use of filter type: A-P The applicable European standard can be found
in EN 141, EN 143 and EN 371. In event of emergency or planned entry into unknown concentrations a positive
pressure, full-facepiece SCBA should be used. If respiratory protection is required, institute a complete
HAND PROTECTION :
When handling this product, the use of chemical gauntlets is recommended. The choice of work glove depends
on work conditions and what chemicals are handled, but we have positive experience under light handling
conditions using gloves made from PVC Gloves should be replaced immediately if signs of degradation are
SKIN PROTECTION :
The applicable European standard can be found in EN 345.
EYE PROTECTION :
Use good work and personal hygiene practices to avoid exposure. Keep an eye wash fountain available. Keep
a safety shower available. If clothing is contaminated, remove clothing and thoroughly wash the affected area.

APPEARANCE Clear Yellow
ODOR Aromatic
7 / 13
PRODUCT
FORTIS EC3071B


VISCOSITY Calculated 1 cst (38 °C)
VISCOSITY Calculated 0.75 cst (66 °C)
INITIAL BOILING POINT 135.9 °C
VAPOR PRESSURE 1.86 kPa (37.8 °C)
STABILITY :
permanganate) may generate heat, fires, explosions and/or toxic vapors., Contact with strong alkalies (e.g.
ammonia and its solutions, carbonates, sodium hydroxide (caustic), potassium hydroxide, calcium hydroxide
(lime), cyanide, sulfide, hypochlorites, chlorites) may generate heat, splattering or boiling and toxic vapors.

SENSITIZATION :
CARCINOGENICITY :
ethylbenzene and determined it to be possibly carcinogenic to humans (Group 2B, based on sufficient evidence
in experimental animals and inadequate evidence in humans).
8 / 13
PRODUCT
FORTIS EC3071B

MOBILITY :
interface) Suite TM , provided by the US EPA. The model assumes a steady state condition between the total
input and output. The level III model does not require equilibrium between the defined media. The information
provided is intended to give the user a general estimate of the environmental fate of this product under the
defined conditions of the models. If released into the environment this material is expected to distribute to the air,
water and soil/sediment in the approximate respective percentages;

5 - 10% 30 - 50% 50 - 70%
Component substances have a potential to bioconcentrate.
burned directly in appropriate equipment. This product is NOT suitable for disposal via municipal sewers, drains,
natural streams or rivers.
contractor.
EUROPE WASTE CODE :

16 03 05*- OFF SPECIFICATION BATCHES AND UNUSED PRODUCTS - Organic wastes containing
dangerous substances. If this product is used in any further processes, the final user must redefine and assign
the most appropriate European Waste Catalogue Code.

Relevant.
NATIONAL REGULATIONS GERMANY :

70104
The information in this section is for reference only and should not take the place of a shipping paper (bill of
lading) specific to an order. Please note that the proper Shipping Name / Hazard Class may vary by packaging,
LAND TRANSPORT
9 / 13
PRODUCT
FORTIS EC3071B

UN/ID No : UN 1993
Packing Group : III
ADR/RID H.I.n. : 30

UN/ID No : UN 1993
Packing Group : III

UN/ID No : UN 1993
Packing Group : III
*Marine Pollutant : Substituted phenol


HAZARD SYMBOLS
HARMFUL
Contains:..Xylene
RISK PHRASES
R10 - Flammable.
10 / 13
PRODUCT
FORTIS EC3071B

SAFETY PHRASES
S23C - Do not breathe vapor.
S36/37 - Wear suitable protective clothing and gloves.
NATIONAL REGULATIONS AUSTRIA

DVBFCLASS4 A II

Table: 4 Bis
Dangerous or Poisonous Substances and Preparations: Relevant.
Work Restrictions:
Classified Industrial Sites (ICPE): Relevant. Headings: 1430, 1433, 1434

VbF A II
TA Luft 3.1.7 II
WGK 2 (Annex 4)
StörfallVO (Seveso Directive) Not Regulated
UNITED STATES
CANADA :
This product contains substance(s) which are found on the Non-Domestic Substances List (NDSL), or are not in
compliance with the Canadian Environmental Protection Act (CEPA) and may require additional review.
EUROPE
JAPAN
11 / 13
PRODUCT
FORTIS EC3071B

RELEVANT RISK PHRASES AND NOTAS

R10 - Flammable.
R11 - Highly flammable.
R36 - Irritating to eyes.
R37/38 - Irritating to respiratory system and skin.
R41 - Risk of serious damage to eyes.
Denmark +47-22-33-69-99
Finland +358-(0)9-4711
Hungary +36-30-9-506-447
Norway +47-22-33-69-99
Poland +48-(0)601-66-2626
Portugal +351-91-911-1399
Spain +34-977-551577
Sweden +47-22-33-69-99
UAE +44-(0)7071-223-738
Belgium +32-70-245245
France +33-(0)145-42-59-59 ORFILA
12 / 13
PRODUCT
FORTIS EC3071B


REVISED INFORMATION: Signficant changes to regulatory or health information for this revision is indicated by
a bar in the left-hand margin of the MSDS.
Numbers quoted in the MSDS are given in the format: 1,000,000 = 1 million and 1,000 = 1 thousand
13 / 13
SAFETY DATA SHEET (EC 1907/2006)
SiYPro E640
Material no. Version
Revision date
Specification
Print Date
VA-Nr Page 1 / 13
1. IDENTIFICATION OF THE SUBSTANCE/PREPARATION AND OF THE COMPANY/UNDERTAKING
Product information
Trade name : SiYPro E640
Company : Evonik Degussa GmbH

Industrial Chemicals
Paul Baumann Str. 1
D-45772 Marl, Germany
Telephone :
Telefax :
Email address : SiYPro@evonik.com
Emergency telephone number : +49 (0)2365 49-2232
Emergency telephone : +49 (0)2365 49-4423
number(Telefax)
Plant fire brigade, Infracor GmbH
Use of the Substance / : Process additive for the petrochemical industry
Preparation
Function : Polymerization inhibitor for monomers.
Classification
R10: Flammable.
Xn, Harmful
R20: Harmful by inhalation.
R65: Harmful: may cause lung damage if swallowed.
Xi, Irritant
R37/38: Irritating to respiratory system and skin.
R41: Risk of serious damage to eyes.
R43: May cause sensitization by skin contact.
N, Dangerous for the environment

R51/53: Toxic to aquatic organisms, may cause long-term adverse effects in the aquatic environment.
Additional safety information for humans and the environment

Risk advice to man and the environment
Do not breathe vapour.
In use, may form flammable/explosive vapour-air mixture.
After contact with skin, wash immediately with plenty of soap.
Do not allow material to contaminate ground water system.
Chemical nature
Preparation on the base:
Information on ingredients / Hazardous components
SDB(P27/001) / 31.07.2009 14:37

SiYPro E640
Revision date
Specification
Print Date
VA-Nr Page 2 / 13
substituted alkylamine > 1% - < 20%
Xn; R22
Xi; R41
Diethylene glycol monobutyl ether > 1% - < 20%
CAS-No. 112-34-5 EC-No. 203-961-6
Xi; R36
Solvent naphtha (petroleum), heavy arom.; Kerosine - unspecified (< 0.1% Benzene) > 50%
- < 100%
CAS-No. 64742-95-6 EC-No. 265-199-0
Xn; R65
xylene, mixture of isomers > 0% - < 10%
CAS-No. 1330-20-7 EC-No. 215-535-7
R10
Xn; R20/21
Xi; R38
cumene > 0% - < 10%
CAS-No. 98-82-8 EC-No. 202-704-5
R10
Xn; R65
Xi; R37
N; R51, R53
mesitylene > 1% - < 10%
CAS-No. 108-67-8 EC-No. 203-604-4
R10
Xi; R37
N; R51, R53
1,2,4-trimethylbenzene > 10% - < 50%
CAS-No. 95-63-6 EC-No. 202-436-9
R10
Xn; R20
Xi; R36/37/38
N; R51, R53
phosphoric acid ester > 1% - < 20%
Xi; R38, R43

N; R50/53
propylbenzene > 1% - < 10%
CAS-No. 103-65-1 EC-No. 203-132-9
R10
Xn; R65
Xi; R37
N; R51, R53
2-propyltoluene > 1% - < 10%
CAS-No. 1074-17-5 EC-No. 214-037-7
N; R51/53
3-Propyltoluene > 1% - < 10%
CAS-No. 1074-43-7 EC-No. 214-040-3
N; R51/53
4-propyltoluene > 1% - < 10%
CAS-No. 1074-55-1 EC-No. 214-044-5
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N; R51/53
m-diethylbenzene > 1% - < 10%
CAS-No. 141-93-5 EC-No. 205-511-4
R10
Xi; R36/37/38
indan > 1% - < 10%
CAS-No. 496-11-7 EC-No. 207-814-7
R10
Xn; R65
1,2,3-trimethylbenzene >= 1% - < 10%
CAS-No. 526-73-8 EC-No. 208-394-8
R10
Xn; R20
Xi; R36/37/38
N; R51/53
2-ethyltoluene > 1% - < 10%
CAS-No. 611-14-3 EC-No. 210-255-1
R10
Xn; R65
4-ethyltoluene > 1% - < 10%
CAS-No. 622-96-8 EC-No. 210-761-2
R10
Xn; R65
See chapter 16 for text of risk phrases
General advice
Pay attention to self-protection.
Remove victims from hazardous area. Immediately remove soiled or soaked clothing and remove it to a
safe distance. Keep victim warm, in a stabilized position and covered.
Do not leave victims unattended.
If the casualty is unconscious: Place the victim in the recovery position.
Inhalation
Inhalation is possible if aerosols, mists, dusts, or smoke form.
Move victims into fresh air.
With labored breathing: Provide with oxygen. Consult a doctor.
If the casualty is not breathing: Perform mouth-to-mouth resuscitation, notify emergency physician
immediately.
Skin contact
Wash off affected area immediately with plenty of water for at least 15 minutes.
With liposoluble substances, products, or preparations, continue decontamination with polyethylene
glycol 400 after initial rinsing with water and then wash with water and soap.
If symptoms persist, consult a physician for treatment.
Eye contact
With eye held open, thoroughly rinse immediately with plenty of water for at least 10 minutes.
Consult an ophthalmologist immediately if the symptoms persist.
When dealing with caustic substances, notify emergency physician immediately (key words: burns in
eye).
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Ingestion
Rinse out mouth.
Immediately give large quantities of water to drink.
Consult a physician immediately.
When dealing with caustic substances, notify emergency physician immediately.
Notes to physician
In case of substances with high water solubility, inhalation of vapors, aerosols, mists, and smoke from
caustic substances, products, and preparations, as well as caustic gases, results in irritations up to
formation of necrosis in the upper respiratory tract.
The initial focus is on the local action: signs of irritation of the respiratory tract such as coughing,
burning behind the sternum, tears, burning in the eyes or nose.
There is a fundamental risk of acute toxic pulmonary edema!
In case of substances with low water solubility, only slight local irritations may appear at first, but after
several hours of latency without symptoms, may develop into increasingly labored breathing and
cyanosis as a result of a delayed pulmonary edema.
There is a danger of underestimating the severity of the intoxication!

water, mist, water spray, foam, carbon dioxide (CO2), dry powder
Extinguishing media which must not be used for safety reasons
high volume water jet
Specific hazards during fire fighting
In case of fire cool endangered containers with water.
In the case of fire, the following hazardous smoke fumes may be produced:
Carbon oxides
Special protective equipment for fire-fighters
Wear suitable protective clothing.
wear a self contained respiratory apparatus
Further information
Water used to extinguish fire should not enter drainage systems, soil, or stretches of water Ensure there
are sufficient retaining facilities for water used to extinguish fire. Contaminated fire-extinguishing water
must be disposed of in accordance with the regulations issued by the appropriate local authorities.
Fire residues should be disposed of in accordance with the regulations.
Personal precautions
Wear personal protective equipment; see section 8.
Avoid contact with the skin and the eyes.
Do not inhale vapours / aerosols.
Take precautionary measures against static discharges.
Keep away from heat and sources of ignition.
Do not smoke.
Refer to protective measures listed in sections 7 and 8.
Environmental precautions
Prevent product from entering drains.
Do not allow entrance in sewage water, soil or stretches of water.
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Methods for cleaning up

Use a liquid-binding material to take up small amounts
Fill into marked, sealable containers.
Suitable binder: universal absorbent, diatomaceous earth, oil absorbent, sand (for damming
up)
Additional advice
Avoid penetration into drainage system or in rooms situated at a lower level because of danger of
explosion.

Handling
Safe handling advice

Observe the rules usually applicable when handling chemicals.
Wear personal protective equipment; see section 8.
Advice on protection against fire and explosion
Take precautionary measures against static charges, keep away from sources of ignition.
Explosion protection equipment required.
Storage
Requirements for storage areas and containers

Keep container tightly closed.
Keep in a well-ventilated place.
Keep in a cool place.
Advice on common storage
Keep separate from foodstuffs, luxury foods, feedstuffs.
8. EXPOSURE CONTROLS / PERSONAL PROTECTION
Diethylene glycol monobutyl ether

CAS-No. 112-34-5 EC-No. 203-961-6
Control parameters 10 ppm Time W eighted Average (TWA):(EU ELV)
67.5 mg/m3
Control parameters 15 ppm Short Term Exposure Limit (STEL):(EU
101.2 mg/m3 ELV)
xylene, mixture of isomers
CAS-No. 1330-20-7 EC-No. 215-535-7
221 mg/m3
442 mg/m3 ELV)
Control parameters Skin designation:(EU ELV)
Can be absorbed through the skin.
cumene
CAS-No. 98-82-8 EC-No. 202-704-5
100 mg/m3
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250 mg/m3 ELV)

Control parameters Skin designation:(EU ELV)
Can be absorbed through the skin.
mesitylene
CAS-No. 108-67-8 EC-No. 203-604-4
100 mg/m3
1,2,4-trimethylbenzene
CAS-No. 95-63-6 EC-No. 202-436-9
100 mg/m3
CAS-No. 526-73-8 EC-No. 208-394-8
100 mg/m3
Engineering measures
Provide appropriate exhaust ventilation at machinery.
Vapours may form explosive mixture with air.
Keep away from sources of ignition - No smoking.
see also section 7.
Respiratory protection
Use suitable respiratory protection where aerosols/vapours are generated.
If workplace exposure limit is exeeded apply respirator with ABEK-P3 combination filter.
Note time limit for wearing respiratory protective equipment.
Hand protection
Recommendation:
suitable protective gloves
Glove material nitrile rubber, butyl-rubber, Fluorinated rubber (Viton), Remember that the
useful time per day of a chemical protection glove may be much shorter
than the permeation time determined according to EN 374 due to the
many different influential factors involved (e.g. temperature)., The rupture
time and material thickness data are guideline values! Exact rupture time
/ material thickness data can be obtained from the protective glove
manufacturer.
Material thickness 0.5 - 0.85 mm
Method DIN EN 374
Eye protection
close-fitting protective goggles (e.g. closed goggles)
Skin and body protection
suitable protective clothing - Use disposable clothing if appropriate.
Hygiene measures
Wash off immediately in the event of contact with the skin (rinsing agent: glycol polyethylene 400), rinse
off afterwards with copious amounts of water.
No eating, drinking, smoking, or snuffing tobacco at work. Wash face and/or hands before break and
end of work.
Take off clothing and shoes contaminated with product. Clean before reuse.
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Protective measures
The personal protective equipment used must meet the requirements of directive 89/686/EEC and
amendments (CE certification).
Appearance
Form clear solution
Colour orange
Safety data
Melting point/range -62.2 °C
Method: ASTM D 97-66
Boiling point/range 155 °C
Flash point 53 °C
Method: ISO 2719
Ignition temperature 425 °C

Method: DIN 51 794
Density 0.888 g/cm3 (15.6 °C)
Water solubility insoluble
Partition coefficient (n-octanol/water) log Pow: 0.55

Method: (calculated)
related to substance: substituted alkylamine
Viscosity, kinematic 1.04 mm2/s (38 °C)
0.79 mm2/s (66 °C)
Conditions to avoid Keep away from heat and sources of ignition.
Acute oral toxicity LD50 rat: 1053 mg/kg

Method: OECD Test Guideline 401
(literature value)
LD50 rat: 5660 mg/kg

(literature value)
related to substance: diethylene-glycol-monobutyl-ether-; butyldigol
LD50 : > 3000 mg/kg

(literature value)
related to substance: Solvent naphtha (petroleum), heavy aromatic
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LD50 Rat: > 2000 mg/kg

(literature value)
related to substance: phosphoric acid ester
Acute inhalation toxicity LC50 Rat: > 5.5 mg/l / 4 h

related to substance: aliphatic hydrocarbons
LC50 Rat: 28 mg/l / 4 h

Method: literature
related to substance: xylene, mixture of isomers
Acute dermal toxicity LD50 Rabbit: > 3500 mg/kg

related to substance: aliphatic hydrocarbons
LD50 Rabbit: 4000 mg/kg

(literature value)
related to substance: diethylene-glycol-monobutyl-ether-; butyldigol
LD50 : > 3160 mg/kg

(literature value)
LD50 Rabbit: > 2000 mg/kg

(literature value)
Skin irritation Rabbit / 4 h

slightly irritating
slightly irritating
(literature value)
Rabbit
irritating
(literature value)
Eye irritation Rabbit / 24 h

Risk of serious damage to eyes.
slight irritation
(literature value)
Rabbit
not irritating
(literature value)
Sensitization Buehler Test guinea pig: not sensitizing

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Maximisation Test guinea pig: sensitizing

(literature)
Repeated dose toxicity inhalative Rat
Number of exposures: 5 days/weeks, 6 hours/day
Testing period: 28 d
NOAEL: 0.024 mg/l
Method: literature
Gentoxicity in vitro Ames test Salmonella typhimurium

negative
Method: US-EPA-method
(literature value)
Gentoxicity in vivo Cytogenetic test Rat intraperitoneal (i.p.)

negative
Method: literature
Elimination information (persistence and degradability)

Biodegradability aerobic
inoculum: Activated sludge
Concentration: 15.42 mg/l
Exposure time: 28 d
Result: 9 % Not readily biodegradable.
Method: (DOC; Die Away test / 92/69/EEC part C.4-A)
Result: Readily biodegradable.

Behaviour in environmental compartments
Ecotoxicity effects
Toxicity to fish LC50 Oncorhynchus mykiss: 9.22 mg/l
Method: literature
LC50 Brachydanio rerio (zebra fish): 7.1 mg/l / 96 h

(literature value)
Toxicity to daphnia EC50 Daphnia magna: 6.1 mg/l / 48 h

Method: literature
EC50 Daphnia magna (Water flea): 0.42 mg/l / 48 h

(literature value)
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Toxicity to algae EC50 scenedesmus subspicatus: ca. 272 mg/l / 72 h

End point: growth rate
Analytical monitoring: yes
Method: OECD TG 201
NOEC scenedesmus subspicatus: 22 mg/l / 72 h

End point: growth rate
Method: OECD TG 201
IC50 : > 100 mg/l

(literature value)
Toxicity to bacteria EC 10 Pseudomonas putida: 428 mg/l / 16 h

Analytical monitoring: no
Method: DIN 38412 part 8
EC50 : > 100 mg/l

(literature value)
chronic toxicity in daphnia NOEC Daphnia magna: 1.5 mg/l / 21 d

Test substance: substituted alkylamine
Method: OECD 202 part 2
Further information on ecology

Further Information Toxic to aquatic organisms.
May cause long-term adverse effects in the environment.
Product
With respect to local regulations, e.g. dispose of to suitable waste incineration plant.
No waste key number as per the European W aste Types List can be assigned to this product, since
such classification is based on the (as yet undetermined) use to which the product is put by the
consumer.
The waste key number must be determined as per the European W aste Types List (decision on EU
Waste Types List 2000/532/EC) in cooperation with the disposal firm / producing firm / official authority.

Land transport ADR/RID/GGVSE (Germany)
Class 3
ADR/RID-Labels 3
UN-No 1223
Packaging group III
orange warning plate 30 / 1223
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Description of the goods (Technical name)

KEROSENE (mixture)
Sea transport IMDG-Code/GGVSee
Class 3
UN-No 1223
Packaging group III
EmS F-E, S-E
Proper technical name (Proper shipping name)
KEROSENE (mixture)
Air transport ICAO-TI/IATA-DGR
Class 3
UN-No 1223
Packaging group III
Proper technical name (Proper shipping name)
Kerosene (mixture)
Inland waterway transport ADN/ADNR/GGVBinSch (Germany)

Class 3
ADR/RID-Labels 3
UN-No / Substance number 1223
Packaging group III
Description of the goods (Technical name)
KEROSENE (mixture)
Loading instructions/Remarks
IATA_C ERG-Code 3L
IATA_P ERG-Code 3L
Labelling according to EC Directives

Statutory basis/list According to the Dangerous Preparations Directive (1999/45/EG):
hazard-defining component(s)
substituted alkylamine
Solvent naphtha (petroleum), heavy arom.; Kerosine - unspecified (< 0.1% Benzene)
cumene
mesitylene
phosphoric acid ester
Symbol(s) Xn Harmful
N Dangerous for the environment
R-phrase(s) R10 Flammable.

R20 Harmful by inhalation.
R37/38 Irritating to respiratory system and skin.
R41 Risk of serious damage to eyes.
R43 May cause sensitization by skin contact.
R65 Harmful: may cause lung damage if swallowed.
R51/53 Toxic to aquatic organisms, may cause long-term
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S-phrase(s) S23 Do not breathe vapour.

S24/25 Avoid contact with skin and eyes.
S36/37/39 Wear suitable protective clothing, gloves and eye/face
protection.
S61 Avoid release to the environment. Refer to special
instructions/safety data sheets.
S62 If swallowed, do not induce vomiting: seek medical
advice immediately and show this container or label.
National legislation
Major Accident Hazard The product is subject to the EC directive 82/501/EEC and amendments
Legislation (see regulations concerning malfunctions).
employment restriction Please note Directive 92/85/EEC (Pregnant Workers Directive) and
amendments.
Please note Directive 94/33/EC (Protection of Young Workers at the
Workplace Directive) and amendments.
Other regulations Please note Directive 76/769/EEC (Marketing and use restrictions
Directive) and amendments.
Risk phrase (R phrase) texts

substituted alkylamine
R22 Harmful if swallowed.
R41 Risk of serious damage to eyes.
Diethylene glycol monobutyl ether
R36 Irritating to eyes.
Solvent naphtha (petroleum), heavy arom.; Kerosine - unspecified (< 0.1% Benzene)
R10 Flammable.
R20/21 Harmful by inhalation and in contact with skin.
R38 Irritating to skin.
cumene
R10 Flammable.
R37 Irritating to respiratory system.
R51 Toxic to aquatic organisms.
R53 May cause long-term adverse effects in the aquatic environment.
mesitylene
R10 Flammable.
R10 Flammable.
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phosphoric acid ester
R43 May cause sensitization by skin contact.
R50/53 Very toxic to aquatic organisms, may cause long-term adverse effects
in the aquatic environment.
propylbenzene
R10 Flammable.
2-propyltoluene
R51/53 Toxic to aquatic organisms, may cause long-term adverse effects in the
aquatic environment.
3-Propyltoluene
4-propyltoluene
m-diethylbenzene
R10 Flammable.
indan
R10 Flammable.
R10 Flammable.
2-ethyltoluene
R10 Flammable.
4-ethyltoluene
R10 Flammable.
Further information
Changes since the last version are highlighted in the margin. This version replaces all previous
versions.
The information provided in this Safety Data Sheet is correct to the best of our knowledge, information
and belief at the date of its publication. The information given is designed only as a guidance for safe
handling, use, processing, storage, transportation, disposal and release and is not to be considered a
warranty or quality specification. The information relates only to the specific material designated and
may not be valid for such material used in combination with any other materials or in any process,
unless specified in the text.
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Petroleum Coke MSDS No. 4027
EMERGENCY OVERVIEW
CAUTION
Excessive exposure to dust may cause eye, mouth, nose, and/or throat
irritation. Excessive skin contact may cause irritation.
NFPA 704 (Section 16)
1. CHEMICAL PRODUCT and COMPANY INFORMATION
HOVENSA L.L.C.
1 Estate Hope
Christiansted, VI 00820-5652
EMERGENCY TELEPHONE NUMBER (24 hrs): CHEMTREC (800) 424-9300

COMPANY CONTACT (business hours): Safety Department (340) 692-3000
SYNONYMS: Coke
SEE SECTION 16 FOR ABBREVIATIONS AND ACRONYMS.
2. COMPOSITION AND INFORMATION ON INGREDIENTS
INGREDIENT NAME (CAS No.) CONCENTRATION PERCENT BY WEIGHT

Petroleum Coke:(64741-79-3) 100
A solid, carbonaceous material resulting from the thermal decomposition of petroleum residue; remaining
hydrocarbons have a very high carbon to hydrogen ratio.
EYES
Contact may cause slight to moderate irritation.
SKIN
May cause slight to moderate irritation with prolonged or repeated contact.
INGESTION
Low order of oral toxicity. Not an expected route of exposure under most conditions. However, good
personal hygiene should be practiced to minimize ingestion (such as from hands).
INHALATION
Inhalation of excessive dust concentrations may be irritating to the nose, mouth, throat, and lungs.
CHRONIC and CARCINOGENICITY
Repeated chronic inhalation exposure may cause impaired lung function. There is no evidence that such
exposures cause pneumoconiosis, carcinogenicity, or other chronic health effects.
Revision Date: 06/06/2006 Page 1 of 6

MEDICAL CONDITIONS AGGRAVATED BY EXPOSURE

Persons with preexisting respiratory disease, such as asthma, may have symptoms aggravated by dust
exposure.
EYES
In case of contact with eyes, immediately flush with clean, low-pressure water for at least 15 min. Hold
eyelids open to ensure adequate flushing. Seek medical attention.
SKIN
Remove contaminated clothing. Wash contaminated areas thoroughly with soap and water or waterless
hand cleanser. Obtain medical attention if irritation or redness develops.
INGESTION
Obtain medical attention if large amounts are ingested.
INHALATION
Remove person to fresh air. If person is not breathing provide artificial respiration. If necessary, provide
additional oxygen once breathing is restored if trained to do so. Seek medical attention immediately.
FLAMMABLE PROPERTIES:
FLASH POINT: N/A
AUTOIGNITION TEMPERATURE: N/D
LOWER EXPLOSIVE LIMIT (%): N/D
UPPER EXPLOSIVE LIMIT (%): N/D
FIRE AND EXPLOSION HAZARDS
Product will burn. In very large quantities, spontaneous heating and combustion (smoldering) may occur.
EXTINGUISHING MEDIA
Water, foam, carbon dioxide, or dry chemical.
FIRE FIGHTING INSTRUCTIONS
Small fires in the incipient (beginning) stage may typically be extinguished using handheld portable fire
extinguishers and other fire fighting equipment.
Large fires are best extinguished with water. Surfactant (foam or soap) in water may be effective in
reaching deep, smoldering fires (such as in coke pile).
Firefighting activities that may result in potential exposure to high heat, smoke or toxic by-products of
combustion should require NIOSH/MSHA- approved pressure-demand self-contained breathing
apparatus with full facepiece and full protective clothing.
See Section 16 for the NFPA 704 Hazard Rating.
ACTIVATE FACILITY'S SPILL CONTINGENCY OR EMERGENCY RESPONSE PLAN if applicable.
Carefully shovel, scoop or sweep up into a waste container for reclamation or disposal. Avoid creating
dusty conditions; water fog may be necessary to minimize dust generation. Respiratory protection
(Section 8) is recommended if a visible dust is generated.

7. HANDLING and STORAGE
HANDLING and STORAGE PRECAUTIONS

No special storage requirements are necessary. Avoid creating dusty conditions. Minimize physical
contact with the product.
8. EXPOSURE CONTROLS and PERSONAL PROTECTION
EXPOSURE LIMITS
Component (CAS No.)
Source TWA Note
(ppm)
Petroleum Coke (64741-79-3) OSHA 15 mg/m3 (total dust);
5 mg/m3 (respirable dust)
ACGIH 10 mg/m3 (total dust);

3 mg/m3 (respirable dust)
ENGINEERING CONTROLS
Use adequate ventilation to keep dust concentrations of this product below occupational exposure limits.
EYE/FACE PROTECTION
Chemical splash or dust goggles are recommended where dust may be generated.
SKIN PROTECTION
Avoid repeated or prolonged skin contact. Gloves and skin protection are recommended for
repeated/prolonged contact. Disposable clothing such as Tyvek® (DuPont) may be warranted to
minimize skin and clothing contamination, depending on the work to be performed.
RESPIRATORY PROTECTION
A NIOSH/ MSHA-approved air-purifying respirator with particulate classification N-95 or greater filter
cartridges or canister may be permissible under certain circumstances where airborne concentrations are
or may be expected to exceed exposure limits or for odor or irritation. Protection provided by air-purifying
respirators is limited. Refer to OSHA 29 CFR 1910.134, ANSI Z88.2-1992, NIOSH Respirator Decision
Logic, and the manufacturer for additional guidance on respiratory protection selection.
Use a positive pressure, air-supplied respirator if there is a potential for uncontrolled release, exposure
levels are not known, in oxygen-deficient atmospheres, or any other circumstance where an air-purifying
respirator may not provide adequate protection.
WORK/HYGIENIC PRACTICES
Use good personal hygiene practices. Avoid repeated and/or prolonged skin exposure. Wash hands
with soap and water before eating, drinking, smoking, or using toilet facilities. Do not allow eating,
drinking, or smoking in the work area. As with any dust, remove contaminated clothing and launder
before reuse.
9. PHYSICAL and CHEMICAL PROPERTIES
APPEARANCE
Black solid
ODOR
Practically odorless
BASIC PHYSICAL PROPERTIES

BOILING POINT: N/A

VAPOR PRESSURE: N/A (essentially non-volatile)
SPECIFIC GRAVITY (H2O = 1): > 1.0
PERCENT VOLATILES: Negligible
SOLUBILITY (in H2O) Negligible
10. STABILITY and REACTIVITY
STABILITY: Stable. Hazardous polymerization will not occur.
CONDITIONS TO AVOID and INCOMPATIBLE MATERIALS
Ignition sources; open flame. Avoid strong oxidizing materials.
HAZARDOUS DECOMPOSITION PRODUCTS:
Smoke, carbon monoxide, and/or oxides of sulfur when burned
11. TOXICOLOGICAL PROPERTIES
ACUTE TOXICITY:
Acute Dermal (rabbits) LD50: > 2 g/kg
Acute Oral (rats) LD50: > 2 g/kg
Primary Dermal Irritation: slightly irritating (rabbits)
Draize Eye Irritation: practically non-irritating (rabbits)
CHRONIC EFFECTS AND CARCINOGENICITY
Carcinogenicity: OSHA: NO IARC: NO NTP: NO ACGIH: NO
Repeated inhalation of the petroleum coke dust (10.2 and 30.7 mg/m3) over a two-year period resulted in
lung damage typical of high dust exposure including inflammation and scarring in rats. Similar exposures
in monkeys did not produce similar lung effects. There was no observation of a carcinogenic effect at any
dose following a lifetime exposure. There is no evidence of pneumoconiosis or carcinogenicity in human
health studies.
Keep out of sewers, drainage and waterways. Report spills and releases, as applicable, under Federal
and State regulations.
Consult federal, state and local waste regulations to determine appropriate disposal options.
14. TRANSPORTATION INFORMATION
PROPER SHIPPING NAME: NONE
HAZARD CLASS and PACKING GROUP: N/A
DOT IDENTIFICATION NUMBER: N/A
DOT SHIPPING LABEL: N/A
U.S. FEDERAL, STATE and LOCAL REGULATORY INFORMATION
Any spill or uncontrolled release of this product, including any substantial threat of release, may be
subject to federal, state and/or local reporting requirements. This product and/or its constituents may
also be subject to other regulations at the state and/or local level. Consult those regulations applicable to
your facility/operation.
CERCLA SECTION 103 and SARA SECTION 304 (RELEASE TO THE ENVIRONMENT)

The CERCLA definition of hazardous substances contains a “petroleum exclusion” clause which exempts
crude oil, refined, and unrefined petroleum products and any indigenous components of such. However,
other federal reporting requirements (e.g., SARA Section 304 as well as the Clean Water Act if the spill
occurs on navigable waters) may still apply.
SARA SECTION 311/312 - HAZARD CLASSES
ACUTE HEALTH CHRONIC HEALTH FIRE SUDDEN RELEASE OF PRESSURE REACTIVE
-- -- -- -- --
SARA SECTION 313 - SUPPLIER NOTIFICATION
This product does not contain toxic chemicals subject to the reporting requirements of Section 313 of the
Emergency Planning and Community Right-To-Know Act (EPCRA) of 1986 and of 40 CFR 372.
CALIFORNIA PROPOSITON 65 LIST OF CHEMICALS

This product does not contain any chemicals that are included on the Proposition 65 “List of Chemicals”
required by the California Safe Drinking Water and Toxic Enforcement Act of 1986.
NFPA® HAZARD RATING HEALTH: 0 Negligible

FIRE: 1 Slight
REACTIVITY: 0 Negligible
HMIS® HAZARD RATING HEALTH: 0 Negligible

FIRE: 1 Slight
PHYSICAL: 0 Negligible
SUPERSEDES MSDS DATED: 03/22/99
ABBREVIATIONS:
AP = Approximately < = Less than > = Greater than
N/A = Not Applicable N/D = Not Determined ppm = parts per million
ACRONYMS:
ACGIH American Conference of Governmental NFPA National Fire Protection Association (617)
Industrial Hygienists 770-3000
AIHA American Industrial Hygiene Association NIOSH National Institute of Occupational Safety
ANSI American National Standards Institute and Health
(212) 642-4900 NOIC Notice of Intended Change (proposed
API American Petroleum Institute change to ACGIH TLV)
(202) 682-8000 NTP National Toxicology Program
CERCLA Comprehensive Emergency Response, OPA Oil Pollution Act of 1990
Compensation, and Liability Act OSHA U.S. Occupational Safety & Health
DOT U.S. Department of Transportation Administration
[General info: (800) 467-4922] PEL Permissible Exposure Limit (OSHA)
EPA U.S. Environmental Protection Agency RCRA Resource Conservation and Recovery Act
HMIS Hazardous Materials Information System REL Recommended Exposure Limit (NIOSH)
IARC International Agency for Research on SARA Superfund Amendments and
Cancer Reauthorization Act of 1986 Title III
MSHA Mine Safety and Health Administration SCBA Self-Contained Breathing Apparatus

SPCC Spill Prevention, Control, and TWA Time Weighted Average (8 hr.)
Countermeasures WEEL Workplace Environmental Exposure Level
STEL Short-Term Exposure Limit (generally 15 (AIHA)
minutes) WHMIS Canadian Workplace Hazardous
TLV Threshold Limit Value (ACGIH) Materials Information System
TSCA Toxic Substances Control Act
DISCLAIMER OF EXPRESSED AND IMPLIED WARRANTIES

Information presented herein has been compiled from sources considered to be dependable, and is accurate and reliable to the best
of our knowledge and belief, but is not guaranteed to be so. Since conditions of use are beyond our control, we make no warranties,
expressed or implied, except those that may be contained in our written contract of sale or acknowledgment.
Vendor assumes no responsibility for injury to vendee or third persons proximately caused by the material if reasonable safety
procedures are not adhered to as stipulated in the data sheet. Additionally, vendor assumes no responsibility for injury to vendee or
third persons proximately caused by abnormal use of the material, even if reasonable safety procedures are followed. Furthermore,
vendee assumes the risk in their use of the material.

SCHEDULE - 5
(See Rule 68-J, 2(2) & 2(3))
SAFETY DATA SHEET

1. CHEMICAL IDENTITY
Chemical Name : Carbon Black Feed Stock Chemical Classification : Data not available
Synonyms : CBFS Trade Name : CBFS
Formula : Heavy & Light Fuel Oils C.A.S. No.: U.N. No. :
Shipping Name 1 Hazchem No. :

Codes/Label
Regulated Identification Data not available Data not available
Hazardous Waste Data not available
I.D. No. :
Hazardous Ingredients: C.A.S. No. Hazardous C.A.S. No.
Ingredients
Mixture of Asphaltenes, 1. Data N.A. 3. Data N.A.
Naphthalenes,Aromatics etc 2. 4.
2. PHYSICAL AND CHEMICAL DATA
BOILING Range/Point ºC Physical State Appearance
ºC Liquid Dark Black liquid
Melting/Freezing Point ºC Vapour Pressure Odour :
ºC - Variable at 35ºC : Data not available. Data not available.
Vapour Density Solubility in Water Others : --
Data not available at 30ºC : Forms Emulsion.
(Air = 1)
Specific Gravity pH : Data Not Available.
(Water=1) = 1.007(min.) at 15ºC
3. FIRE AND EXPLOSION HAZARD DATA
Flammability YES/NO LEL : Flash Autoignition C
YES Data not available. Point 70 ºC min.: Temperature :
Data not available.

TDG Flammability : UEL : % Flash Point ºC : : Data Not available
Data not available Data not available
Explosion Sensitivity to Impact Explosion sensitivity Hazardous
to Static Electricity : Combustion products:
Toxic Gases & Vapor,
Data Not Available Data not available. CO etc.
Hazardous Polymerisation-Yes Explosive Corrosive
Combustible Liquid YES Material Material
YES Data not available Yes
Flammable Material : Oxidiser : Others :
YES Data Not Available Data not available
Pyrophoric Material : Organic : Peroxide :
YES Data Not Available Data Not Available
4. REACTIVITY DATA
Chemical Stability : Stable.
Incompatibility with other Material : Data not available.
Reactivity Data not available.
Hazardous Reaction Products Data not available.
5. HEALTH HAZARDS DATA
Route of Entry : Inhalation : Vapours of CBFS can be inhaled especially
when it is hot.
Skin Contact : Causes irritation and skin burning and

redness.
Skin Absorption :
Eye Contact : Causes irritation and acute allergic

inflammation of the eyes, sclera and the cornea.
Effects of Exposure/Symptoms Acute Exposure : When hot, it may cause burns and release
toxic gasses. Vapours cause irritation to the eyes, nose and
throat. Avoid contact with skin and eyes when it is hot.
Chronic Exposure : May cause chronic Bronchitis on

chronic inhalation.
Emergency Treatment : Eyes : causes irritation to eyes. Wash with water and
apply anti-allergic drops. If irritation persists seek medical
attention
Skin : Causes skin irritation. Wash with copious

amounts of fluids and administer anti-inflmmatory , anti-
allergic drugs. For severe burns, seek medical attention.
Inhalation : Remove the patient to fresh air. Adninster

Oxygen through mask. If choking persistes nebulize steroids
and asthalin.
Ingestion : If ingested induce vomiting. Administer

universal antidote and antacids. Clinically watch for
deterioation and development of signs. Treat accordingly.
TLV (ACGIH) : Data not available STEL : Data N.A. ppm : Data not available
Permissible Odour Threshold
Exposure Limit LD- : Data not available
LD- mg./kg. Data Not available
NFPA Hazard Health : Data n.a.
Signal Flammability : Stability : SPECIAL :
Data not available Data not available Data not available
6. PREVENTIVE MEASURES
Ventilation :
Eye & Face :
Hand & Arms ;
Other Clothing & Equipment :
Handling and Storage
Precautions
7. EMERGENCY AND FIRST AID MEASURE
FIRE FIRE EXTINGUISHING MEDIA :
Extinguish with Dry Chemical Powder, Foam or Carbon Diaoxide

Cool exposed container with water.
FIRE Special Procedures :
Flammable. Keep away from spark, flame & heat.

Hot CBFS may cause burn. Use protective clothing. Use dry sand for spilled
liquid.
Unusual Hazards :
Data not available.
EXPOSURE First Aid Measures :
Antidotes/Dosages :
SPILLS Steps to be taken :
Contain covering with sand. Eliminate sparks, flames and all source of
ignition.
Waste Disposal Method :
8. ADDITIONAL INFORMATION/REFERENCES
9. MANUFACTURE/SUPPLIERS DATA
Contact Person in
Name of Firm Emergency
Mailing Address
Telephone/Telex Nos. Local Bodies
Telephonic Address Involved
Standard
Packing
Tremcard
Detail/Ref.
Others
10. DISCLAIMER
Information contained in this material data sheet is believed to be reliable but no representation,
guarantee or warranties of any kind are made as to its accuracy, suitability for a particular application or
results to be obtained from them. It is upto the manufacture/seller to ensure that the information
contained in the material safety data sheet is relevant to the product manufactured/handled or sold by him
as the case may be. The Government makes no warranties, expressed or im plied, in respect of the
adequacy of this document for any particular purpose.
ACU Raffinate
MSDS# 830495
Version 7.
Material Safety Data Sheet Effective Date 02/07/2009
According to OSHA Hazard Communication Standard, 29 CFR
1910.1200
1. MATERIAL AND COMPANY IDENTIFICATION
Material Name : ACU Raffinate

Uses : Raw material for use in the chemical industry.
Product Code : Q9146
Company : Shell Chemical LP
PO Box 2463
HOUSTON TX 77252-2463
USA
MSDS Request : 1-800-240-6737
Customer Service : 1-866-897-4355
Emergency Telephone Number

Chemtrec Domestic : 1-800-424-9300
(24 hr)
Chemtrec : 1-703-527-3887
International (24 hr)
Chemical Name CAS No. Concentration

Hydrocarbons, C5 and Higher, 68476-50-6 100.00 %
C5-6-Rich
Contains n-Hexane, CAS # 110-54-3.

Contains Benzene, CAS # 71-43-2.
Contains Toluene, CAS # 108-88-3.
Contains n-Heptane, CAS # 142-82-5
Emergency Overview
Appearance and Odour : Light coloured. Liquid. Aromatic hydrocarbon..
Health Hazards : Vapours may cause drowsiness and dizziness. Irritating to

skin. Irritating to eyes. Harmful: may cause lung damage if
swallowed. May cause cancer. May cause leukaemia (AML -
acute myelogenous leukaemia).
Safety Hazards : Extremely flammable. Vapours are heavier than air. Vapours
may travel across the ground and reach remote ignition
sources causing a flashback fire danger. Electrostatic charges
may be generated during pumping. Electrostatic discharge may
cause fire.
Health Hazards
Inhalation : Slightly irritating to respiratory system. Vapours may cause
drowsiness and dizziness.
Skin Contact : Irritating to skin.
Eye Contact : Irritating to eyes.
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Ingestion : Harmful: may cause lung damage if swallowed.

Other Information : Possibility of organ or organ system damage from prolonged
exposure; see Chapter 11 for details. Target organ(s):
Cardiovascular system.
Blood.
Central nervous system (CNS).
Auditory system.
Blood-forming organs.
Kidney.
Liver.
Peripheral nervous system.
Immune system.
Respiratory system.
Possible risk of impaired fertility. Possible risk of irreversible
(genetic) effects. May cause cancer. May cause leukaemia
(AML - acute myelogenous leukaemia).
Signs and Symptoms : Eye irritation signs and symptoms may include a burning
sensation, redness, swelling, and/or blurred vision. Skin
irritation signs and symptoms may include a burning sensation,
redness, swelling, and/or blisters. If material enters lungs, signs
and symptoms may include coughing, choking, wheezing,
difficulty in breathing, chest congestion, shortness of breath,
and/or fever. The onset of respiratory symptoms may be
delayed for several hours after exposure. Breathing of high
vapour concentrations may cause central nervous system
(CNS) depression resulting in dizziness, light-headedness,
headache, nausea and loss of coordination. Continued
inhalation may result in unconsciousness and death. Damage
to blood-forming organs may be evidenced by: a) fatigue and
anaemia (RBC), b) decreased resistance to infection, and/or
excessive bruising and bleeding (platelet effect).
Environmental Hazards : Toxic to aquatic organisms, may cause long-term adverse
effects in the aquatic environment.
General Information : Keep victim calm. Obtain medical treatment immediately.

Inhalation : DO NOT DELAY. Remove to fresh air. If rapid recovery does
not occur, transport to nearest medical facility for additional
treatment.
Skin Contact : Remove contaminated clothing. Immediately flush skin with
large amounts of water for at least 15 minutes, and follow by
washing with soap and water if available. If redness, swelling,
pain and/or blisters occur, transport to the nearest medical
facility for additional treatment.
Eye Contact : Immediately flush eyes with large amounts of water for at least
15 minutes while holding eyelids open. Transport to the
nearest medical facility for additional treatment.
Ingestion : If swallowed, do not induce vomiting: transport to nearest
medical facility for additional treatment. If vomiting occurs
spontaneously, keep head below hips to prevent aspiration.
Advice to Physician : Potential for chemical pneumonitis. Consider: gastric lavage
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with protected airway, administration of activated charcoal.

Potential for cardiac sensitisation, particularly in abuse
situations. Hypoxia or negative inotropes may enhance these
effects. Consider: oxygen therapy. Call a doctor or poison
control center for guidance.
Clear fire area of all non-emergency personnel.
Flash point : -12 °C / 10 °F

Explosion / Flammability : 1.2 - 6.7 %(V)
limits in air
Specific Hazards : The vapour is heavier than air, spreads along the ground and
distant ignition is possible. Will float and can be reignited on
surface water. Carbon monoxide may be evolved if incomplete
combustion occurs.
Extinguishing Media : Foam, water spray or fog. Dry chemical powder, carbon
dioxide, sand or earth may be used for small fires only.
Unsuitable Extinguishing : Do not use water in a jet.
Media
Protective Equipment for : Wear full protective clothing and self-contained breathing
Firefighters apparatus.
Additional Advice : Keep adjacent containers cool by spraying with water.
Observe all relevant local and international regulations. Avoid contact with spilled or released
material. For guidance on selection of personal protective equipment see Chapter 8 of this
Material Safety Data Sheet. See Chapter 13 for information on disposal.
Protective measures : Isolate hazard area and deny entry to unnecessary or

unprotected personnel. Stay upwind and keep out of low areas.
Shut off leaks, if possible without personal risks. Remove all
possible sources of ignition in the surrounding area. Use
appropriate containment (of product and fire fighting water) to
avoid environmental contamination. Prevent from spreading or
entering drains, ditches or rivers by using sand, earth, or other
appropriate barriers. Attempt to disperse the vapour or to direct
its flow to a safe location for example by using fog sprays.
Take precautionary measures against static discharge. Ensure
electrical continuity by bonding and grounding (earthing) all
equipment. Ventilate contaminated area thoroughly.
Clean Up Methods : For large liquid spills (> 1 drum), transfer by mechanical means
such as vacuum truck to a salvage tank for recovery or safe
disposal. Do not flush away residues with water. Retain as
contaminated waste. Allow residues to evaporate or soak up
with an appropriate absorbent material and dispose of safely.
Remove contaminated soil and dispose of safely.
For small liquid spills (< 1 drum), transfer by mechanical means
to a labelled, sealable container for product recovery or safe
disposal. Allow residues to evaporate or soak up with an
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appropriate absorbent material and dispose of safely. Remove

contaminated soil and dispose of safely.
Additional Advice : Notify authorities if any exposure to the general public or the
environment occurs or is likely to occur. Local authorities
should be advised if significant spillages cannot be contained.
The vapour is heavier than air, spreads along the ground and
distant ignition is possible. Vapour may form an explosive
mixture with air. See Chapter 13 for information on disposal.
U.S. regulations may require reporting releases of this material
to the environment which exceed the reportable quantity (refer
to Chapter 15) to the National Response Centre at (800) 424-
8802. Notify authorities if any exposure to the general public or
the environment occurs or is likely to occur. Under Section 311
of the Clean Water Act (CWA) this material is considered an
oil. As such, spills into surface waters must be reported to the
National Response Centre at (800) 424-8802. This material is
covered by EPA's Comprehensive Environmental Response,
Compensation and Liability Act (CERCLA) Petroleum
Exclusion. Therefore, releases to the environment may not be
reportable under CERCLA.
General Precautions : Avoid breathing vapours or contact with material. Only use in
well ventilated areas. Wash thoroughly after handling. For
guidance on selection of personal protective equipment see
Chapter 8 of this Material Safety Data Sheet. Use the
information in this data sheet as input to a risk assessment of
local circumstances to help determine appropriate controls for
safe handling, storage and disposal of this material.
Handling : Avoid inhaling vapour and/or mists. Avoid contact with skin,
eyes, and clothing. Avoid exposure. Obtain special instructions
before use. Extinguish any naked flames. Do not smoke.
Remove ignition sources. Avoid sparks. Electrostatic charges
may be generated during pumping. Electrostatic discharge may
cause fire. Ensure electrical continuity by bonding and
grounding (earthing) all equipment. Restrict line velocity during
pumping in order to avoid generation of electrostatic discharge
(<= 1 m/sec until fill pipe submerged to twice its diameter, then
<= 7 m/sec). Avoid splash filling. Do NOT use compressed air
for filling, discharging, or handling operations. Handling
Temperature: Ambient.
Storage : Vapours from tanks should not be released to atmosphere.
Breathing losses during storage should be controlled by a
suitable vapour treatment system. Bulk storage tanks should
be diked (bunded). The vapour is heavier than air. Beware of
accumulation in pits and confined spaces. Storage
Temperature: Ambient.
Product Transfer : Electrostatic charges may be generated during pumping.
Electrostatic discharge may cause fire. Ensure electrical
continuity by bonding and grounding (earthing) all equipment.
Restrict line velocity during pumping in order to avoid
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generation of electrostatic discharge (<= 1 m/sec until fill pipe

submerged to twice its diameter, then <= 7 m/sec). Avoid
splash filling. Do NOT use compressed air for filling,
discharging, or handling operations. Keep containers closed
when not in use. Do not use compressed air for filling,
discharging or handling.
Recommended Materials : For containers, or container linings use mild steel, stainless
steel.
Unsuitable Materials : Natural, butyl, neoprene or nitrile rubbers.
Additional Information : Ensure that all local regulations regarding handling and storage
facilities are followed.
Occupational Exposure Limits
Material Source Type ppm mg/m3 Notation

Benzene ACGIH TWA 0.5 ppm
ACGIH STEL 2.5 ppm
ACGIH SKIN_DES Can be absorbed through
the skin.
OSHA TWA 1 ppm
OSHA STEL 5 ppm
OSHA ACTION 0.5 ppm
OSHA Z1A TWA 1 ppm
OSHA Z1A STEL 5 ppm
OSHA REF
Toluene ACGIH TWA 20 ppm
OSHA Z1A TWA 100 ppm 375 mg/m3
OSHA Z1A STEL 150 ppm 560 mg/m3
SHELL IS TWA 50 ppm
OSHA Z2 TWA 200 ppm
OSHA Z2 Ceiling 300 ppm
OSHA Z2 MAX. 500 ppm
CONC
n-Hexane ACGIH TWA 50 ppm
ACGIH SKIN_DES Can be absorbed through
the skin.
OSHA Z1 PEL 500 ppm 1,800 mg/m3
OSHA Z1A TWA 50 ppm 180 mg/m3
n-Heptane OSHA Z1 PEL 500 ppm 2,000 mg/m3
OSHA Z1A TWA 400 ppm 1,600 mg/m3
OSHA Z1A STEL 500 ppm 2,000 mg/m3
ACGIH TWA 400 ppm
ACGIH STEL 500 ppm
Additional Information : Skin notation means that significant exposure can also occur
by absorption of liquid through the skin and of vapour through
the eyes or mucous membranes. Shell has adopted as Interim
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Standards the OSHA Z1A values that were established in 1989

and later rescinded. SHELL IS is the Shell Internal Standard.
Exposure Controls : The level of protection and types of controls necessary will vary
depending upon potential exposure conditions. Select controls
based on a risk assessment of local circumstances.
Appropriate measures include: Use sealed systems as far as
possible. Adequate explosion-proof ventilation to control
airborne concentrations below the exposure guidelines/limits.
Local exhaust ventilation is recommended. Firewater monitors
and deluge systems are recommended. Eye washes and
showers for emergency use.
Personal Protective : Personal protective equipment (PPE) should meet
Equipment recommended national standards. Check with PPE suppliers.
Respiratory Protection : If engineering controls do not maintain airborne concentrations
to a level which is adequate to protect worker health, select
respiratory protection equipment suitable for the specific
conditions of use and meeting relevant legislation. Check with
respiratory protective equipment suppliers. Where air-filtering
respirators are unsuitable (e.g., airborne concentrations are
high, risk of oxygen deficiency, confined space) use
appropriate positive pressure breathing apparatus. Where air-
filtering respirators are suitable, select an appropriate
combination of mask and filter. Select a filter suitable for
organic gases and vapours [boiling point >65 °C (149 °F)].
Where respiratory protective equipment is required, use a full-
face mask. Respirator selection, use and maintenance should
be in accordance with the requirements of the OSHA
Respiratory Protection Standard, 29 CFR 1920.134.
Hand Protection : Where hand contact with the product may occur the use of
gloves approved to relevant standards (e.g. Europe: EN374,
US: F739, AS/NZS:2161) made from the following materials
may provide suitable chemical protection: Longer term
protection: Viton. Incidental contact/Splash protection: Nitrile
rubber. Suitability and durability of a glove is dependent on
usage, e.g. frequency and duration of contact, chemical
resistance of glove material, glove thickness, dexterity. Always
seek advice from glove suppliers. Contaminated gloves should
be replaced.
Personal hygiene is a key element of effective hand care.
Gloves must only be worn on clean hands. After using gloves,
hands should be washed and dried thoroughly. Application of a
non-perfumed moisturizer is recommended.
Eye Protection : Chemical splash goggles (chemical monogoggles).
Protective Clothing : Chemical resistant gloves/gauntlets, boots, and apron. Where
risk of splashing or in spillage clean up, use chemical resistant
one-piece overall with integral hood.
Appearance : Light coloured. Liquid.

Odour : Aromatic hydrocarbon..
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Boiling point : 35.0 °C / 95.0 °F

Flash point : -12 °C / 10 °F
Explosion / Flammability : 1.2 - 6.7 %(V)
limits in air
Vapour pressure : 3.04 psi (Reid vapour pressure)
Specific gravity : 0.66
Water solubility : 1.0 g/l Slight
Stability : Stable.
Stability : Stable under normal conditions of use. Reacts violently with

strong oxidising agents.
Conditions to Avoid : Avoid heat, sparks, open flames and other ignition sources.
Prevent vapour accumulation.
Materials to Avoid : Strong oxidising agents.
Hazardous Decomposition : Thermal decomposition is highly dependent on conditions. A
Products complex mixture of airborne solids, liquids and gases, including
carbon monoxide, carbon dioxide and other organic compounds
will be evolved when this material undergoes combustion or
thermal or oxidative degradation.
Basis for Assessment : Information given is based on data from components.

Acute Oral Toxicity : Low toxicity: LD50 >2000 mg/kg , Rat (n-Hexane)
Aspiration into the lungs when swallowed or vomited may
cause chemical pneumonitis which can be fatal.
Acute Dermal Toxicity : Low toxicity: LD50 >2000 mg/kg , Rabbit (Benzene)
Acute Inhalation Toxicity : Low toxicity: LC50>5000 ppm / 1 hours, Rat (n-Hexane)
High concentrations may cause central nervous system
depression resulting in headaches, dizziness and nausea;
continued inhalation may result in unconsciousness and/or
death.
Skin Irritation : Irritating to skin. (n-Hexane, Benzene)
Eye Irritation : Irritating to eyes.(Benzene, Toluene)
Respiratory Irritation : Inhalation of vapours or mists may cause irritation to the
respiratory system.
Repeated Dose Toxicity : Blood: may cause haemolysis of red blood cells and/or
anaemia. (Benzene)
Blood-forming organs: repeated exposure affects the bone
marrow. (Benzene)
Nervous system: repeated exposure affects the nervous
system. Effects were seen at high doses only. (Toluene, n-
Hexane)
Peripheral nervous system: repeated exposure causes
peripheral neuropathy in animals. (n-Hexane)
Immune System: animal studies on this material or its
components have demonstrated immunotoxicity. (Benzene)
Respiratory system: repeated exposure affects the respiratory
system. Effects were seen at high doses only. (Toluene)
Kidney: can cause kidney damage. (Toluene)
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Liver: can cause liver damage. (Toluene)

Auditory system: prolonged and repeated exposures to high
concentrations have resulted in hearing loss in rats. Solvent
abuse and noise interaction in the work environment may
cause hearing loss. (Toluene)
Cardiovascular system: chronic abuse of similar materials has
been associated with irregular heart rhythms and cardiac
arrest. (n-Hexane, Benzene, Toluene)
Repeated inhalation exposure of toluene to animals caused
histological changes in the brain, degeneration of the heart
tissue, and possible immune suppression.
Intentional abuse of toluene vapours has been linked to
damage of brain, liver, kidney and to death.
Carcinogenicity : Known human carcinogen. (Benzene)
May cause leukaemia (AML - acute myelogenous leukaemia).
(Benzene)
Material : Carcinogenicity Classification

Toluene : ACGIH Group A4: Not classifiable as a human carcinogen.
Toluene : IARC 3: Classification not possible from current data.
Benzene : ACGIH Group A1: Confirmed human carcinogen.
Benzene : NTP: Known carcinogen.
Benzene : IARC 1: Human carcinogen.
Benzene : OSHASP: Cancer hazard.
Reproductive and : Causes foetotoxicity in animals at doses which are maternally

Developmental Toxicity toxic. (n-Hexane, Benzene, Toluene)
There are occupational studies which report an association
between inhalation exposure to toluene and adverse effects on
reproduction (including spontaneous abortions and birth
defects). The methodology of these studies and the reliability
of their results have been questioned. In a study in rats,
inhalation of toluene did not have adverse effects on
reproduction. (Toluene)
Many case studies involving abuse during pregnancy indicate
that toluene can cause birth defects, growth retardation and
learning difficulties. (Toluene)
Affects reproductive system in animals at doses which produce
other toxic effects. (n-Hexane)
Acute Toxicity
Fish : Expected to be toxic: 1 < LC/EC/IC50 <= 10 mg/l
Aquatic Invertebrates : Expected to be toxic: 1 < LC/EC/IC50 <= 10 mg/l
Algae : Expected to be toxic: 1 < LC/EC/IC50 <= 10 mg/l
Microorganisms : Expected to be toxic: 1 < LC/EC/IC50 <= 10 mg/l
Mobility : If product enters soil, it will be highly mobile and may

contaminate groundwater. Floats on water.
Persistence/degradability : Expected to be readily biodegradable. Oxidises rapidly by
photo-chemical reactions in air.
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Bioaccumulation : Contains components with the potential to bioaccumulate.

Other Adverse Effects : In view of the high rate of loss from solution, the product is
unlikely to pose a significant hazard to aquatic life.
Material Disposal : Recover or recycle if possible. It is the responsibility of the

waste generator to determine the toxicity and physical
properties of the material generated to determine the proper
waste classification and disposal methods in compliance with
applicable regulations.
Do not dispose into the environment, in drains or in water
courses. Waste product should not be allowed to contaminate
soil or water.
Local Legislation : Disposal should be in accordance with applicable regional,
national, and local laws and regulations.
US Department of Transportation Classification (49CFR)

Identification number UN 1993
Proper shipping name Flammable liquids, n.o.s.
Technical name (Hexane, HEPTANE)
Class / Division 3
Packing group II
Contains OIL
Emergency Response Guide 128
No .
Additional Information This material is an 'OIL' under 49 CFR Part 130 when
transported in a container of 3500 gallon capacity or greater.
IMDG
Proper shipping name FLAMMABLE LIQUID, N.O.S.
Class / Division 3
Packing group II
Marine pollutant: No
IATA (Country variations may apply)

Proper shipping name Flammable liquid, n.o.s.
Class / Division 3
Packing group II
The regulatory information is not intended to be comprehensive. Other regulations may apply to this
material.
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Federal Regulatory Status
Notification Status
AICS Listed.
NDSL Listed.
TSCA Listed.
EINECS Listed. 270-690-8
KECI (KR) Listed. KE-20088
PICCS (PH) Listed.
Comprehensive Environmental Release, Compensation & Liability Act (CERCLA)
ACU Raffinate (68476-50-6) Reportable quantity: 200 lbs
n-Hexane (110-54-3) Reportable quantity: 5,000 lbs

Toluene (108-88-3) Reportable quantity: 1,000 lbs
Benzene (71-43-2) Reportable quantity: 10 lbs
Shell classifies this material as an "oil" under the CERCLA Petroleum Exclusion, therefore
releases to the environment are not reportable under CERCLA. The components with RQs are
given for information.
Clean Water Act (CWA) Section 311
Toluene (108-88-3) Reportable quantity: 1,000 lbs

Benzene (71-43-2) Reportable quantity: 10 lbs
Under Section 311 of the Clean Water Act (CWA) this material is considered an oil. As such,
spills into surface waters must be reported to the National Response Centre at (800) 424-8802.
The components with RQs are given for information.
SARA Hazard Categories (311/312)
Immediate (Acute) Health Hazard. Delayed (Chronic) Health Hazard. Fire Hazard.
SARA Toxic Release Inventory (TRI) (313)
n-Hexane (110-54-3) 60.00%

Toluene (108-88-3) 5.00%
Benzene (71-43-2) 5.00%
State Regulatory Status
California Safe Drinking Water and Toxic Enforcement Act (Proposition 65)
Known to the State of California to cause birth defects or other reproductive harm.
Known to the state of California to cause cancer.
Toluene (108-88-3) 5.00% Developmental toxin.

Benzene (71-43-2) 5.00% Carcinogenic.
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Developmental toxin.
Male reproductive toxin.
New Jersey Right-To-Know Chemical List
n-Heptane (142-82-5) 60.00% Listed.

n-Hexane (110-54-3) 60.00%
Listed.
Toluene (108-88-3) 5.00%
Listed.
Benzene (71-43-2) 5.00%
Listed.
Pennsylvania Right-To-Know Chemical List
n-Heptane (142-82-5) 60.00% Listed.

n-Hexane (110-54-3) 60.00% Listed.
Toluene (108-88-3) 5.00% Environmental hazard.
Listed.
Benzene (71-43-2) 5.00% Special hazard.
Environmental hazard.
Listed.
MSDS Version Number : 7.
MSDS Effective Date : 02/07/2009
MSDS Revisions : A vertical bar (|) in the left margin indicates an amendment
from the previous version.
MSDS Regulation : The content and format of this MSDS is in accordance with the
OSHA Hazard Communication Standard, 29 CFR 1910.1200.
Uses and Restrictions : Raw material for use in the chemical industry.
Restricted to professional users.
MSDS Distribution : The information in this document should be made available to

all who may handle the product
Disclaimer : The information contained herein is based on our current

knowledge of the underlying data and is intended to describe
the product for the purpose of health, safety and environmental
requirements only. No warranty or guarantee is expressed or
implied regarding the accuracy of these data or the results to
be obtained from the use of the product.
11/11
MATERIAL SAFETY
DATA SHEET
Prepared to U.S. OSHA, CMA, ANSI and Canadian WHMIS Standards
1. PRODUCT AND COMPANY INFORMATION
CHEMICAL NAME; CLASS: BENZENE

Packaged in Cylinders Pressurized with Nitrogen or Helium
SYNONYMS: Benzol: Benzole; Benzolene: Carbon Oil; Coal Naphtha; Cyclohexatriene; Phene;
Mineral Naphtha; Motor Benzol; Nitration Benzene; Phenyl Hydride; Pyrobenzoyl;
Pyrobenzole; NCI-C55276
CHEMICAL FAMILY NAME: Aromatic Hydrocarbon/Benzene
FORMULA: C6H6
Document Number: 20008

PRODUCT USE: Manufacture of chemicals; minor component
of gasoline; solvent and reactant in
laboratories
MANUFACTURED/SUPPLIED FOR:
ADDRESS: 2700 Post Oak Drive
Houston, TX 77056-8229
EMERGENCY PHONE: CHEMTREC: 1-800-424-9300
BUSINESS PHONE:
General MSDS Information 1-713/896-2896
Fax on Demand: 1-800/231-1366
BENZENE - C6H6- MSDS EFFECTIVE DATE: AUGUST 31, 2005

PAGE 1 OF 12
2. HAZARD IDENTIFICATION
EMERGENCY OVERVIEW: Benzene is a colorless, flammable, toxic liquid, with a characteristic aromatic odor.
Benzene is a known human carcinogen and a possible human mutagen. Inhalation of vapors of Benzene can
cause serious, permanent damage to the blood system. Skin and eye contact can be irritating. This liquid is very
flammable; vapors are heavier than air and may travel long distances to source of ignition and flashback. If
involved in a fire Benzene will decompose to produce toxic gases (i.e. carbon monoxide, carbon dioxide, irritating
aldehydes and ketones). Persons responding to fires or emergencies involving Benzene must have adequate fire
protection and wear personal protective equipment to protect against the significant health hazards posed by
Benzene.
SYMPTOMS OF OVER-EXPOSURE BY ROUTE OF EXPOSURE: Benzene is a serious poison by all routes of

exposure. The symptoms of each route of exposure are described below.
INHALATION: The immediate symptoms of inhalation of vapors of Benzene are due to the initial excitation, followed
by depression of the central nervous system. Central nervous system symptoms include drowsiness, headache,
nausea, incoordination and unconsciousness, that can lead to death in severe cases. Other symptoms of acute
over-exposure to vapors of Benzene can include transient euphoria, ataxia (incoordination of voluntary muscular
movements), vertigo, tinnitus, substernal pain, cough, hoarseness and general irritation of the nose, throat and
respiratory tract, confusion, stupefaction and coma. In cases of severe over-exposure (as may occur in a confined
space, or other poorly ventilated areas, or if large volumes are used or released), tremors, convulsions and death,
due to respiratory paralysis or circulatory collapse can occur within minutes to several hours following exposure.
Reversible liver and kidney effects have been reported after exposure to Benzene. The effects associated with
various levels of Benzene vapors are as follows:
CONCENTRATION SYMPTOM OF EXPOSURE
Brief (10 minute) up to 25 ppm: No symptoms.
50-150 ppm: Exhilaration, headache, tiredness, nose and throat irritation.
20,000 (for 5-10 min): Collapse and death
One of the most significant health effects associated with Benzene is the potential for blood system disorders which
develop after long-term exposures to relatively low vapor concentrations. There are reports that exposure to low
levels (10 ppm) over an extended time period (24 weeks) of Benzene vapors can damage the bone marrow and
blood systems. This damage can result in the development of serious health disorders (including anemia and
leukemia). Adverse effects on the immune system have also been reported. Refer to “Other Health Effects” in this
section for further information.
CONTACT WITH SKIN or EYES: Contact with the skin can cause irritation and redness. Repeated or prolonged
contact can also cause dermatitis, resulting in dry, itchy, cracked skin as Benzene is a defatting agent, removing oils
from the skin. Contact with the vapors of Benzene and the eyes will be irritating. Direct contact of the liquid with the
eyes can cause irritation, pain; prolonged contact may result in tissue damage.
SKIN ABSORPTION: Benzene poisoning through skin contact has been reported, although skin absorption is not
considered as significant a route of exposure as via inhalation or ingestion. Symptoms of absorption may be similar
as those described in “Ingestion”.
INGESTION: Ingestion of Benzene will cause a burning sensation in the mouth and stomach, nausea, vomiting,
excess salivation and vomiting of blood. Benzene is readily absorbed into the body following ingestion exposures,
producing symptoms of central nervous system depression and other symptoms similar to those described in
“Inhalation”. If ingested, Benzene presents a potential aspiration hazard. Aspiration of even small amounts of
Benzene into the lungs can result in immediate pulmonary edema (a potentially fatal accumulation of fluid in the
lungs), chemical pneumonitis and hemorrhage of pulmonary tissue.

PAGE 2 OF 12
2. HAZARD IDENTIFICATION (Continued)
INJECTION: Injection is not anticipated to be a significant route of over-exposure for this product. If Benzene is
“injected” (as may occur through punctures by contaminated, sharp objects), symptoms described in “Inhalation” can
occur.
OTHER HEALTH EFFECTS: The chief target organ affected by serious Benzene exposure is the blood and bone
marrow system. Chronic Benzene exposure eventually leads to pancytopenia (abnormal decrease of all three
formed elements of the blood; hemoglobin, disease-fighting leukocytes and blood-clotting thrombocytes), followed by
thrombocytopenia (problems with the blood-clotting properties of the blood) and anemia. These syndromes can lead
to sudden, overwhelming infections. After exposure to Benzene, bleeding from the nose, gums, or mucous
membranes and development of small bruises can occur. Benzene is a known human carcinogen and can produce
forms of leukemia. Direct contact with the liquid with mucous membranes will result in the development of
hemorrhagic lesions.
HEALTH EFFECTS OR RISKS FROM EXPOSURE: An Explanation in Lay Terms. Over-exposure to may cause
the health effects described on the following page.
ACUTE: Acute inhalation over-exposure to Benzene will initially act as a narcotic, possibly leading to coma in
extreme cases. Following exposure to high concentrations, victims may be unconscious, and if exposure continues,
death can follow from respiratory failure and circulatory collapse. Contact with the skin can cause irritation and
dermatitis. Contact with the eyes is irritating, causing burning and watering of the eyes. Ingestion of Benzene will
cause gastric distress, hemorrhage and possible severe depression of the central nervous system. Aspiration of
Benzene into the lungs, following ingestion, can result in severe damage to the lungs; death may result.
CHRONIC: Chronic exposure to Benzene causes serious damage to the health by all routes of exposure. Chronic
oral and inhalation exposure causes severe effects on the blood system, including damage to the bone marrow,
leading to a decrease in production or changes to the cells of hemoglobin, hematocrit, red and white blood cells.
Effects can occur with an exposure level as low as 10 ppm for 24 weeks. Benzene also causes harmful changes to
the immune system, decreasing the production of mature B- and T- white blood cells. Benzene is a confirmed human
carcinogen, which can produce Hodgkin’s Disease, leukemia and lymphomas by inhalation. Human mutation data
are reported for Benzene. See Section 11 (Toxicological Information) for further information. Symptoms of chronic
exposure by most routes can be delayed for months to years after exposure has ceased.
TARGET ORGANS: Respiratory system, central nervous system, blood and immune systems, bone marrow, heart,
liver, kidneys, skin, eyes and reproductive system.
3. COMPOSITION and INFORMATION ON INGREDIENTS

CHEMICAL NAME CAS # mole % EXPOSURE LIMITS IN AIR
ACGIH OSHA
TLV STEL PEL STEL IDLH OTHER
ppm ppm ppm ppm ppm
Benzene 71-43-2 100% 10, NE 1 5 500 NIOSH REL: 0.1 ppm TWA; 1
ppm STEL
A2
OSHA Action Level: 0.5 ppm

EPA-A; IARC-1; MAK-A1;
NIOSH-X; NTP-1; OSHA-X;
This material is classified as hazardous under OSHA regulations in the United States and the WHMIS in
Canada.
NE = Not Established C = Ceiling Limit A2 = Suspected Human Carcinogen. See Section 16 for Definitions of Terms Used.
NOTE: All WHMIS required information is included. It is located in appropriate sections based on the ANSI Z400.1-2004 format.

PAGE 3 OF 12
4 FIRST-AID MEASURES
RESCUERS SHOULD NOT ATTEMPT TO RETRIEVE VICTIMS OF EXPOSURE TO BENZENE
WITHOUT ADEQUATE PERSONAL PROTECTIVE EQUIPMENT. If necessary, a Self-Contained
Breathing Apparatus should be worn.
INHALATION: If vapors, mists, or sprays of Benzene are inhaled, remove victim to fresh air. Remove victim(s) to
fresh air as quickly as possible. Only trained personnel should administer supplemental oxygen and/or cardio-
pulmonary resuscitation if necessary. Remove or cover gross contamination to avoid exposure to rescuers.
SKIN EXPOSURE: If Benzene contaminates the skin, immediately begin decontamination with running water.
Minimum flushing is for 15 minutes. Remove exposed or contaminated clothing, taking care not to contaminate
eyes. Victim must seek medical attention if any adverse reaction occurs.
EYE EXPOSURE: If Benzene or its vapors enter the eyes, open victim's eyes while under gentle running water. Use
sufficient force to open eyelids. Have victim "roll" eyes. Minimum flushing is for 15 minutes. Victim must seek
INGESTION: If Benzene is swallowed, CALL PHYSICIAN OR POISON CONTROL CENTER FOR MOST
CURRENT INFORMATION. If professional advice is not available, do not induce vomiting. Victim should drink milk,
egg whites, or large quantities of water. If vomiting occurs naturally, have victim lean forward to reduce risk of
aspiration. Never induce vomiting or give diluents (milk or water) to someone who is unconscious, having
convulsions, or who cannot swallow.
Victims of chemical exposure must be taken for medical attention. Rescuers should be taken for medical attention, if
necessary. Physicians should refer to “Recommendations to Physicians” in Section 11 (Toxicological Information).
Take copy of label and MSDS to health professional with victim.
FLASH POINT, (Closed Cup): -11°C (12°F)
AUTOIGNITION TEMPERATURE: 498°C (928°F)
FLAMMABLE LIMITS (in air by volume, %):
Lower (LEL): 1.3%
Upper (UEL): 7.1%
FIRE EXTINGUISHING MATERIALS:
Water Spray: YES (for cooling only) Carbon Dioxide: YES
Foam: YES Dry Chemical: YES
Halon: YES Other: Any "B" Class.
UNUSUAL FIRE AND EXPLOSION HAZARDS: Benzene is a Class IB flammable liquid and presents a serious fire
hazard to firefighters. Due to the low flash point, vapors can form explosive mixtures with air, at room temperature.
When involved in a fire, this material may decompose and produce toxic gases (i.e., carbon monoxide, carbon
dioxide, irritating aldehydes and ketones). The vapors of Benzene are heavier than air and may spread long
distances; distant ignition and flash-back are possible. Benzene can float on water; therefore, water contaminated
with this product can spread the flammable liquid and can spread fire. Containers of Benzene, when involved in fire,
may rupture or burst in the heat of the fire.
Explosion Sensitivity to Mechanical Impact: Not sensitive.
Explosion Sensitivity to Static Discharge: Benzene can accumulate static charge by flow or agitation; vapors can be
ignited by static discharge.
SPECIAL FIRE-FIGHTING PROCEDURES: In the event of fire, cool containers of this product with water to prevent
failure. Use a water spray or fog to reduce or direct vapors. Water may not be effective in actually extinguishing a
fire involving Benzene, due to its low flash point. Stop the leak or discharge, if possible. For small releases, if it is
not possible to stop the leak, and it does not endanger personnel, let the fire burn itself out. Incipient fire responders
should wear eye protection. Structural fire fighters must wear Self-Contained Breathing Apparatus and full protective
equipment, including chemically resistant clothing. Large fires should be fought from a distance with an unmanned
hose holder or monitor nozzles. If this product is involved in a fire, fire run-off water should be contained to prevent
possible environmental damage. If necessary, decontaminate fire-response equipment with soap and water
solution.

PAGE 4 OF 12
LEAK RESPONSE: Evacuate immediate area. Uncontrolled releases should be responded to by trained personnel
using pre-planned procedures. Proper protective equipment should be used. In case of a leak, clear the affected
area, protect people, and respond with trained personnel.
Minimum Personal Protective Equipment should be Level B: triple-gloves (rubber gloves and nitrile gloves, over
latex gloves), chemically resistant suit and boots, hard-hat, and Self-Contained Breathing Apparatus.
Monitor the surrounding area for combustible vapor levels. Combustible vapor levels must be below 10% of the LEL
for Benzene (LEL = 1.3%) before personnel are permitted to enter the area. If necessary, ventilate area.
Monitoring should be done for the levels of Benzene and oxygen. Colorimetric tubes are available to detect the
presence of Benzene. Levels of Benzene should be below levels listed in Section 2 (Composition and Information
on Ingredients) and the atmosphere must have at least 19.5 percent oxygen before personnel can be allowed in the
area without Self-Contained Breathing Apparatus.
Eliminate all sources of ignition before clean-up operations begin. Use non-sparking tools. Absorb spilled liquid with
activated carbon, polypads or other suitable absorbent materials. Prevent material from entering sewer or confined
spaces. Decontaminate the area thoroughly. Place all spill residue in an appropriate container and seal. If
necessary, decontaminate spill-response equipment with soap and water solution. Dispose of in accordance with
Federal, State, and local hazardous waste disposal regulations (see Section 13, Disposal Considerations).
THIS IS AN EXTREMELY FLAMMABLE, TOXIC LIQUID: Protection of all personnel and the area must be
maintained. All responders must be adequately protected from exposure.

WORK PRACTICES AND HYGIENE PRACTICES: Avoid all contact with this material. All employees who handle
this material should be trained to handle it safely. Avoid breathing the sprays or mists generated by Benzene.
Wash hands after handling chemicals. Do not eat or drink while handling chemicals. All work practices should
minimize the release of Benzene. Eyewash stations and safety showers should be in areas of use of Benzene.
Note: Refer to the OSHA Benzene Standard (29 CFR 1910.1028) for specific requirements associated with the use
of this product. The Action Level for Benzene is 0.5 ppm as an 8-hour, time-weighted average. In workplaces where
employees are exposed above the Action Level, the OSHA requirements for monitoring, establishment of regulated
areas, methods of compliance, respiratory protection, emergency response protocol, medical surveillance, training
and record keeping must be followed.
STORAGE AND HANDLING PRACTICES: Entrances to regulated areas (as defined by the OSHA Benzene
Standard) must be posted with signs which reads as follows:
DANGER
BENZENE
CANCER HAZARD
FLAMMABLE- NO SMOKING
AUTHORIZED PERSONNEL ONLY
Cylinders should be stored upright and be firmly secured to prevent falling or being knocked-over. Cylinders can be
stored in the open, but in such cases, should be protected against extremes of weather and from the dampness of
the ground to prevent rusting. Cylinders of this product must be properly labeled. When handling the liquid, care
must be taken to avoid splashing during dispensing from the container. Never transfer liquids by pressurizing the
original container with air or gas. Do not dispense in storage area unless the dispensing area is segregated by fire-
resistant construction. Never return contaminated Benzene to original container.
Cylinders should be stored in dry, well-ventilated areas away from sources of heat, ignition and direct sunlight. Keep
storage area clear of materials which can burn. Do not allow area where cylinders are stored to exceed 52°C
(125°F). Store containers away from heavily trafficked areas and emergency exits. Store away from process and
production areas, away from elevators, building and room exits or main aisles leading to exits. Protect cylinders
against physical damage. Consideration should be taken to install leak detection and alarm equipment for storage
areas.
Cylinders should be separated from oxygen cylinders, or other oxidizers, by a minimum distance of 20 ft., or by a
barrier of non-combustible material at least 5 ft. high, having a fire-resistance rating of at least 0.5 hours. Isolate
from other incompatible chemicals, such as strong oxidizers, metals, and metal oxides (refer to Section 10, Stability
and Reactivity, for more information).

PAGE 5 OF 12
7. HANDLING AND STORAGE (Continued)
Storage areas must meet national electrical codes for Class 1 Hazardous Areas. Post “No Smoking or Open
Flames” signs in storage or use areas. Consider installation of leak detection and alarm for storage and use areas.
Have appropriate extinguishing equipment in the storage area (i.e. sprinkler system, portable fire extinguishers).
Use only compatible materials for cylinders, process lines, and other Benzene-handling equipment. Lines should be
purged with dry nitrogen both before and after maintenance activity. Use a check valve or other protective device in
the discharge line to prevent hazardous backflow.
Never tamper with pressure relief valves and cylinders. Use non-sparking ventilation systems, approved explosion-
proof equipment, and appropriate electrical systems. Electrical equipment used in gas-handling operations, or
located in storage areas, should be non-sparking or explosion proof.
Use a check valve in the discharge line to prevent hazardous backflow. Never tamper with pressure relief devices in
valves and cylinders.
Periodic inspections of process equipment by knowledgeable persons should be made to ensure that the equipment
is used appropriately and the system is kept in suitable operating condition.
Keep the smallest amount necessary on-site at any one time. Full and empty cylinders should be segregated. Use
a first-in, first-out inventory systems to prevent full containers from being stored for long periods of time.
SPECIAL PRECAUTIONS FOR HANDLING CYLINDERS: Cylinders of Benzene can present significant safety
hazards. The following rules are applicable to work situations in which cylinders are being used.
Before Use: Move cylinders with a suitable hand-truck. Do not drag, slide or roll cylinders. Do not drop cylinders or
permit them to strike each other. Secure cylinders firmly. Leave the valve protection cap (where provided) in-place
until cylinder is ready for use.
During Use: Use designated CGA fittings and other support equipment. Do not use adapters. Do not heat cylinder
by any means to increase the discharge rate of the product from the cylinder. Do not use oils or grease on cylinder-
handling fittings or equipment. Immediately contact the supplier if there are any difficulties associated with operating
cylinder valve. Never insert an object (e.g wrench, screwdriver, pry bar, etc.) into valve cap openings. Doing so may
damage valve, causing a leak to occur. Use an adjustable strap wrench to remove over-tight or rusted caps. Never
strike an arc, on a compressed gas cylinder or make a cylinder part of and electric circuit.
After Use: Close main cylinder valve. Valves should be closed tightly. Replace valve protection cap. Mark empty
cylinders “EMPTY”.
NOTE: Use only DOT or ASME code containers designed for flammable storage. Close valve after each use and
when empty.
STANDARD VALVE CONNECTIONS FOR U.S. AND CANADA: Use the proper CGA connections, DO NOT
USE ADAPTERS:
THREADED: CGA - 510
PIN-INDEXED YOKE: Not applicable.
ULTRA HIGH INTEGRITY: Not applicable.
PROTECTIVE PRACTICES DURING MAINTENANCE OF CONTAMINATED EQUIPMENT: Follow practices
indicated in Section 6 (Accidental Release Measures). Make certain application equipment is locked and tagged-out
safely. Purge gas handling equipment with inert gas (i.e. nitrogen) before attempting repairs. Always use product in
areas where adequate ventilation is provided.
8. EXPOSURE CONTROLS - PERSONAL PROTECTION

VENTILATION AND ENGINEERING CONTROLS: Use with adequate ventilation. Use a mechanical fan or vent
area to outside. Where appropriate, use a non-sparking, grounded ventilation system separate from other exhaust
ventilation systems. Ensure eyewash/safety shower stations are available near areas where this product is used.
RESPIRATORY PROTECTION: Maintain exposure levels of Benzene below the levels listed in Section 2
(Composition and Information on Ingredients) and oxygen levels above 19.5% in the workplace. Use supplied air
respiratory protection if Benzene levels exceed exposure limits and if oxygen level is below 19.5% or during
emergency response to a release of this product. If respiratory protection is required, follow the requirements of the
Federal OSHA Respiratory Protection Standard (29 CFR 1910.134), or equivalent State standards. The following
NIOSH respiratory protection recommendations are for Benzene.

PAGE 6 OF 12
8. EXPOSURE CONTROLS - PERSONAL PROTECTION (Continued)
CONCENTRATION RESPIRATORY EQUIPMENT
At Concentrations Above the NIOSH REL, or Where there is no REL, at any Detectable Concentration: Positive-
pressure, full facepiece SCBA or positive pressure, full-facepiece Supplied Air Respirator
(SAR) with an auxiliary positive pressure SCBA.
Escape Gas mask with organic vapor cartridge or escape-type SCBA should be used.
The IDLH concentration for Benzene is 500 ppm. The carcinogenic effects of Benzene were not considered by
NIOSH in determination of the IDLH.
NOTE: In areas which exceed the OSHA Action Level of Benzene, the respirator selection guidelines in the
Benzene Standard [29 CFR 1910.1028 (g)] apply.
EYE PROTECTION: Splash goggles or safety glasses. Face-shields should be worn if contact with the liquid is
anticipated.
HAND PROTECTION: Wear leather gloves for handling of cylinders of this product. Wear chemically impervious
gloves appropriate for Benzene for industrial use. Gloves should have a resistance to breakthrough greater than 8
hours, such as polyvinyl alcohol, Barricade™ or Responder™. Butyl rubber, natural rubber, neoprene, nitrile
rubber, or polyethylene, polyvinyl chloride, Saranex™, Chemrel™ are not recommended. Use triple gloves for
spill response (see Section 6, Accidental Release Measures).
BODY PROTECTION: Use body protection appropriate for task. An impervious, full-body, encapsulating suit may
be necessary for some operations involving Benzene. Safety shoes are recommended when handling cylinders.
9. PHYSICAL and CHEMICAL PROPERTIES

VAPOR DENSITY (air = 1) = 2.7
BOILING POINT: 80°C (76°F)
FREEZING/MELTING POINT: 5.5°C (42°F)
SPECIFIC GRAVITY @ 20°C (68°F) (water = 1): 0.877 pH: Not applicable.
SOLUBILITY IN WATER @ 25°C (77°F): 180 mg/mL MOLECULAR WEIGHT: 78.11
EVAPORATION RATE (diethyl ether = 1): 2.8 EXPANSION RATIO: Not applicable.
ODOR THRESHOLD: 97 ppm(detection); 97 ppm (recognition) SPECIFIC VOLUME (ft3/lb): 5.5
VAPOR PRESSURE @ 20°C (68°F) 75 mm Hg: 10 kPa
COEFFICIENT WATER/OIL DISTRIBUTION: Log P (oct) = 1.18-1.9; 2.13; 2.15
APPEARANCE AND COLOR: Colorless, flammable liquid, with a characteristic aromatic hydrocarbon odor.
HOW TO DETECT THIS SUBSTANCE (warning properties): The odor of Benzene is not a good warning property
as a the odor threshold is above the TLV.
10. STABILITY and REACTIVITY

STABILITY: Normally stable.
DECOMPOSITION PRODUCTS: If Benzene is involved in a fire, it may ignite to yield toxic fumes of carbon
monoxide, carbon dioxide, irritating aldehydes and ketones.
MATERIALS WITH WHICH SUBSTANCE IS INCOMPATIBLE: Benzene becomes spontaneously flammable in the
presence of sodium peroxide and potassium peroxide. Benzene can explode on contact with chromic anhydride,
permanganic acid and chlorine. Benzene can react vigorously with oxidizing materials. Benzene may react
violently or explosively with risk of fire with nitric acid, ozone, diborane, interhalogens (i.e., bromine trifluoride,
bromine pentafluoride, chloride trifluoride, iodine pentafluoride, iodine heptafluoride), dioxygen difluoride, dioxygenyl
tetrafluoroborate, permanganic acid, peroxodifsulfuric acid, peroxomonosulfuric acid. Benzene will react with nitryl
perchlorate, causing a slight explosion and flash. Benzene will react vigorously with uranium hexafluoride. Benzene
will attack rubber and plastics.
HAZARDOUS POLYMERIZATION: Will not occur.
CONDITIONS TO AVOID: Avoid contact with incompatible materials, sparks, flame static discharge and other
sources of ignition. Avoid exposing cylinders to extremely high temperatures, which could cause the cylinders to
rupture or burst.

PAGE 7 OF 12
TOXICITY DATA: The following information is available for Benzene.
Skin-Rabbit, adult 15 mg/24 hours open Mild irritation effects Inhalation-Human TC: 10 mg/m 3/11 years- intermittent:
Skin-Rabbit, adult 20 mg/24 hours Moderate irritation effects Carcinogenic effects, Blood effects
Eye effects-Rabbit, adult 88 mg Moderate irritation effects Inhalation-Mouse TCLo: 300 ppm/6 hours/16 weeks-intermittent:
Eye effects-Rabbit, adult 2 mg/24H Severe irritation effects Equivocal tumorigenic agent
oms-Human: lymphocyte 5 μmol/L Skin-Mouse TDLo: 1200 g/kg/49 weeks - intermittent: Neoplastic
Microsomal Mutageniticity Assay-Mouse: embryo 2500 mg/L effects
Oral-Mouse TDLo: 6500 mg/kg (female 8-12 days post): Intraperitoneal-Mouse TDLo: 1200 mg/kg/8 weeks - intermittent:
Reproductive effects Teratogenesis, Carcinogenesis, and Neoplastic effects
Mutagenesis Subcutaneous-Mouse TDLo 600 mg/kg/17 weeks - intermittent:
Inhalation-Mouse TCLo: 5 ppm (female 6-15 days post): Teratogenic Equivocal tumorigenic agent
effects Parenteral-Mouse TDLo: 670 mg/kg/19 weeks - intermittent:
3
Inhalation-Man TCLo: 200 mg/m /78 weeks -intermittent: Equivocal tumorigenic agent
Carcinogenic effects, Blood effects Inhalation-Human TC: 150 ppm/15 minutes /8 years - intermittent:
Inhalation-Human TCLo: 10 ppm/8 hours /10 years-intermittent: Carcinogenic effects, Blood effects
Carcinogenic effects, Blood effects Oral-Rat TD: 52 g/kg/1 years - intermittent: Carcinogenic effects
Oral-Rat TDLo: 52 g/kg/52 weeks - intermittent: Carcinogenic effects Oral-Rat TD: 10 g/kg/52 weeks - intermittent: Carcinogenic effects
3
Inhalation-Rat TCLo: 1200 ppm/6 hours/10 weeks - intermittent: Inhalation-Man TC :600 mg/m /4 years - intermittent: Carcinogenic
Equivocal tumorigenic agent effects, Blood effects
Oral-Mouse TDLo :18,250 mg/kg/2 years - continuos: Carcinogenic Inhalation-Man TC: 150 ppm/11 years - intermittent: Carcinogenic
effects effects, Blood effects
Inhalation-Human TC :8 ppb/4 weeks- intermittent: Carcinogenic Inhalation-Mouse TC :1200 ppm/6 hours/10 weeks - intermittent:
effects, Blood effects Equivocal tumorigenic agent
Inhalation-Dog, adult LCLo: 146,000 mg/ Oral-Mouse TD: 2400 mg/kg/8 weeks - intermittent: Neoplastic
3
Inhalation-Cat, adult LCLo: 170,000 mg/m effects
3
Inhalation-Mouse TC: 300 ppm/6 hours/16 weeks intermittent: Inhalation-Human LCLo: 65 mg/m /5 years: Blood effects
Carcinogenic effects Oral-Rat LD50: 3306 mg/kg
Inhalation-Human LCLo :2 pph/5 minutes Inhalation-Rat LC50: 10,000 ppm/7 hours
Oral-Man LDLo: 50 mg/kg Intraperitoneal-Rat LD50 :2890 μg/kg
Inhalation-Human LCLo: 20,000 ppm/5 Oral-Mouse LD50: 4700 mg/kg
Inhalation-Man TCLo: 150 ppm/1 year - intermittent: Blood effects Inhalation-Mouse LC50: 9980 ppm
Inhalation-Human TCLo: 100 ppm Intraperitoneal-Mouse LD50: 340 mg/kg
Intravenous-Rabbit, adult LDLo :88 mg/kg Oral-Dog, adult LDLo: 2000 mg/kg
Additional Information on Benzene: Because of the chronic toxicity effects associated with Benzene, a component of this product, additional
information is provided, as follows:
EFFECTS ON THE BLOOD AND BLOOD-FORMING ORGANS: Extensive studies have conclusively proven that oral and inhalation exposure to
benzene causes severe effects on the blood system, including damaging the bone marrow where new blood cells are formed. Most studies
report a decrease in hemoglobin, hematocrit, red and white blood cells, platelets and/or changes in the cells. Effects of varying severity have
been demonstrated with both intermittent and continuous exposures to concentrations as low as 10 ppm for 24 weeks.
EFFECTS ON THE IMMUNE SYSTEM: Studies have also conclusively shown that benzene causes harmful changes to the immune system which
protects the body from disease. Benzene has decreased the number of mature B- and T-lymphocytes (white blood cells which produce
disease-fighting antibodies). Exposure of mice to 300 ppm for 6 to 23 weeks resulted in a decrease in the number of mature B- and T-
lymphocytes. Rats and mice exposed orally to 25 to 200 mg/kg/day for 2 years had significantly reduced white blood cells and lymphocytes.
SUSPECTED CANCER AGENT: Benzene is listed as follows:
BENZENE: ACGIH-A2 (Suspected Human Carcinogen); EPA-A (Human Carcinogen); IARC-1 (Carcinogenic to Humans); MAK-A1 (Capable of
Inducing Malignant Tumors/Experience with Humans); NIOSH-X (Carcinogen); NTP-1 (Known to be a Carcinogen); OSHA-X (Carcinogen);
Cal-OSHA (Carcinogen).
IRRITANCY OF PRODUCT: Benzene is irritating to the skin, eyes, and other contaminated tissue.
SENSITIZATION OF PRODUCT: Benzene is not known to cause respiratory system or skin sensitization in
humans. Cardiac sensitization to stimulants (i.e. epinephrine, ephedrine) is a possible result of severe or chronic
over-exposure.
REPRODUCTIVE TOXICITY INFORMATION: Listed below is information concerning the effects of Benzene on the
human reproductive system.
Mutagenicity: Human mutation data are available for Benzene. These data were obtained from individuals who were
exposed at levels which produced changes in the blood system.
Embryotoxicity: Benzene is not reported to cause embryotoxic effects in humans.
Teratogenicity: Benzene is not reported to cause embryotoxic effects in humans. Teratogenic data are available
from clinical studies involving test animals exposed to relatively high doses of Benzene. Fetotoxic effects (i.e.,
reduced birth weight and/or minor skeletal variations) were observed at exposures above 50 ppm.
Reproductive Toxicity: Data on reproductive effects on ovaries and testes are available from clinical studies
involving test animals exposed to relatively high doses of Benzene. These data were obtained at doses which
caused toxic effects on other organs.

PAGE 8 OF 12
11. TOXICOLOGICAL INFORMATION (Continued)
A mutagen is a chemical which causes permanent changes to genetic material (DNA) such that the changes will propagate
through generation lines. An embryotoxin is a chemical which causes damage to a developing embryo (i.e. within the first eight
weeks of pregnancy in humans), but the damage does not propagate across generational lines. A teratogen is a chemical which
causes damage to a developing fetus, but the damage does not propagate across generational lines. A reproductive toxin is any
substance which interferes in any way with the reproductive process.
MEDICAL CONDITIONS AGGRAVATED BY EXPOSURE: Pre-existing blood system disorders, respiratory
conditions, central nervous, liver, kidney, and cardio-vascular conditions may be aggravated by severe or chronic
over-exposure to this product. Skin disorders may also be aggravated by exposures to Benzene.
RECOMMENDATIONS TO PHYSICIANS: The following guidelines are derived from “Clinical Toxicology of
Commercial Chemical Products” (5th edition, 1984)
• Check for signs of impending pulmonary edema.
• Because of the aspiration hazard, avoid emetic drugs, whenever practical.
• For over-exposures in which emesis is advisable: If the patient is not drowsy, comatose, or in respiratory
difficulty, induce vomiting. If necessary, as an alternative treatment, remove Benzene from the stomach via
gastric lavage. One or two ounces of mineral oil may be instilled and left in the stomach at the completion of
lavage.
• Avoid epinephrine because of its possible adverse effect on the sensitized myocardium. Avoid all digestible fats,
oils and alcohol,, which may promote the absorption of Benzene in the intestinal system.
• If eyes or skin are affected, wash thoroughly and apply a bland analgetic ointment.
• Because of the possibility of ventricular fibrillation, monitor the EKG continuously and be prepared to administer
external cardiac massage.
RECOMMENDATIONS TO PHYSICIANS (Continued): Refer to the OSHA Benzene Standard [29 CFR 1910.1028;
paragraph(i) and Appendix C] for specific information on Medical Surveillance requirements (i.e. for the general
physical exam, medical history, specific tests, and re-examination protocol).
BIOLOGICAL EXPOSURE INDICES (BEIs): The following Biological Exposure Indices (BEIs) are currently
applicable for Benzene.
BIOLOGICAL EXPOSURE INDICES (BEIs) for Benzene are as follows:
CHEMICAL DETERMINANT SAMPLING TIME BEI
BENZENE
• Total phenol in urine • End of shift • 50 mg/g creatinine
• Benzene in exhaled air: • Prior to next shift
mixed-exhaled • 0.08 ppm
end-exhaled • 0.12 ppm

ENVIRONMENTAL STABILITY: Benzene will be degraded over time into other organic compounds. The following
environmental data are available for Benzene.
Benzene: KOW = 2.13. Water Solubility = 1791 mg/L. BCF (Anguilla japonica, eels) = 3.5. BCF (Clupea harengus Pallasi, pacific herring) = 4.4.
BCF (goldfish) = 4.3. BCF, benzene = 24 (estimated). If benzene is released into the soil, it will be volatilized near the surface or it will leach
to the groundwater. No degradation of benzene (BOD) was reported in coarse-filtered Lake Superior harbor water incubated at 21°C for 12
days. In the marine eco-system, biodegradation occurs from 2 days to 2 weeks in the summer and spring, respectively. The half-life of
14
Benzene in estuarine water was 6 days, as measured by CO2 produced. Biodegradation half-lives of 28 and 16 days were reported in die-
away tests for degradation of up to 3.2 UL/L benzene using groundwater and Lester River water, respectively, under aerobic conditions. In a
base-rich para-brownish soil, 20 ppm benzene was 24% degraded in one week, 44% in 5 weeks and 47% in 10 weeks. It is not expected to
adsorb to sediment nor bioconcentrate in aquatic organisms.
EFFECT OF MATERIAL ON PLANTS or ANIMALS: Benzene may be harmful or fatal to contaminated plant and
animal-life (especially if large quantities of this product are released). Refer to Section 11 (Toxicology Information).

PAGE 9 OF 12
12. ECOLOGICAL INFORMATION (Continued)
EFFECT OF CHEMICAL ON AQUATIC LIFE: Benzene can be harmful or fatal to contaminated aquatic plant and
animal life. Benzene floats on water, and can potentially form slicks which are capable of creating oxygen-deprived
waterways which can contaminate coastal and shore life. The following aquatic toxicity data are available for
Benzene.
LC100 (Tetrahymena pyriformis, ciliate) = 12.8 mmol/L/24 hours TLm (Artemia salina, brine shrimp) = 66-21 mg/L/24 hours
LC50 (Palaemonetes pugio, grass shrimp) = 27 ppm/96 hours TLm (Pimephales promelas, fathead minnow) = 35.5 to 33.5
LC50 (Cancer magister, crab larvae, stage 1) = 108 ppm/96 hours mg/L/24 hours, 96 hours (soft water)
LC50 (Crangon franciscorum, shrimp) = 20 ppm/96 hours TLm (Pimephales promelas, fathead minnow) = 24.4 to 32 mg/L/24
LC50 (Poecilia reticulata, guppy) = 63 ppm/14 days hours, 96 hours (hard water TLm (bluegill) = 22.5 mg/L/24 hours
LC50 (Morone saxatilis, bass) = 5.8 to 10.9 ppm/96 hours (soft water)
LC50 (Salmo trutta, brown trout yearling) = 12 mg/L/1-hour TLm (Carassium auratus, goldfish) = 34.4 mg/L/24 hours, 96 hours
LC50 (Ambystoma mexicana, mexican axototl salamander, 3-4 (soft water)
weeks after hatching) = 370 mg/L/48 hours TLm (Lebistes reticulata, guppy) = 36.6 mg/L/24 hours, 96 hours
LC50 (clawed toad, 3-4 weeks after hatching) = 190 mg/L/48 hours (soft water)
LD50 (Carassium auratus, goldfish) = 46 mg/L/24-hours TLm (Gambusia affinis, mosquito fish) = 395 mg/L/24 hours
LD50 (Lepomis macrochirus, bluegill sunfish) = 60 mg/L/2-hours

PREPARING WASTES FOR DISPOSAL: Waste disposal must be in accordance with appropriate Federal, State,
and local regulations. Return cylinders with any residual product to Air Liquide. Do not dispose of locally.
14. TRANSPORTATION INFORMATION

THIS MATERIAL IS HAZARDOUS AS DEFINED BY 49 CFR 172.101 BY THE U.S. DEPARTMENT OF
TRANSPORTATION.
PROPER SHIPPING NAME: Benzene
HAZARD CLASS NUMBER and DESCRIPTION: 3 (Flammable Liquid)
UN IDENTIFICATION NUMBER: UN 1114
PACKING GROUP: PG II
DOT LABEL(S) REQUIRED: Flammable Liquid
NORTH AMERICAN EMERGENCY RESPONSE GUIDEBOOK NUMBER (1996): 130
MARINE POLLUTANT: Benzene is not classified by the DOT as a Marine Pollutant (as defined by 49 CFR
172.101, Appendix B).
SPECIAL SHIPPING INFORMATION: Cylinders should be transported in a secure position, in a well-ventilated
vehicle. The transportation of compressed gas cylinders in automobiles or in closed-body vehicles present serious
safety hazards and should be discouraged.
NOTE: Shipment of compressed gas cylinders which have not been filled with the owners consent is a violation of
Federal law (49 CFR, Part 173.301 (b).
TRANSPORT CANADA TRANSPORTATION OF DANGEROUS GOODS REGULATIONS: THIS MATERIAL IS
CONSIDERED AS DANGEROUS GOODS. Use the following information for the preparation of Canadian
Shipments.
PROPER SHIPPING NAME: Benzene
HAZARD CLASS NUMBER and DESCRIPTION: 3 (Flammable Liquid),
9.2 (Substance Hazardous to the Environment)
UN IDENTIFICATION NUMBER: UN 1114
PACKING GROUP: PG II
SPECIAL PROVISION: (109)
REGULATED LIMIT: 50 kg

SARA REPORTING REQUIREMENTS: Benzene is subject to the reporting requirements of Sections 302, 304 and
313 of Title III of the Superfund Amendments and Reauthorization Act, as follows:
CHEMICAL SARA 302 SARA 304 SARA 313
Benzene NO YES YES
This product is subject to the reporting requirements of Sections 311 and 312 of Title III of the Superfund
Amendments and Reauthorization Act (40 CFR 370.21).
SARA THRESHOLD PLANNING QUANTITY: Not applicable.
TSCA INVENTORY STATUS: Benzene is listed on the TSCA Inventory.

PAGE 10 OF 12
CERCLA REPORTABLE QUANTITIES (RQ): 10 lbs.
15. REGULATORY INFORMATION (Continued)

CALIFORNIA PROPOSITION 65: Benzene is listed on the California Proposition 65 Lists. WARNING: Benzene is
known to the State of California to cause cancer.
STATE REGULATORY INFORMATION: Benzene is covered under the following specific State regulations:
Alaska - Designated Toxic and Hazardous Minnesota - List of Hazardous Substances: Pennsylvania - Hazardous Substance List:
Substances: Benzene. Benzene. Benzene.
California - Permissible Exposure Limits for Missouri - Employer Information/Toxic Rhode Island - Hazardous Substance List:
Chemical Contaminants: Benzene Substance List: Benzene Benzene
Florida - Substance List: Benzene New Jersey - Right to Know Hazardous Texas - Hazardous Substance List: Benzene
Illinois - Toxic Substance List: Benzene. Substance List: Benzene West Virginia - Hazardous Substance List:
Kansas - Section 302/313 List: Benzene North Dakota - List of Hazardous Chemicals, Benzene
Massachusetts - Substance List: Benzene. Reportable Quantities: Benzene. Wisconsin - Toxic and Hazardous: Benzene
OTHER U.S. FEDERAL REGULATIONS:

• Benzene is subject to the requirements of CFR 29 1910.1000. Benzene is listed on Table Z.2.
• Benzene is subject to the requirements of CFR 29 1910.1028, the OSHA Benzene Standard. The Action Level
for Benzene is 0.5 ppm as an 8-hour, time-weighted average under this regulation.
• The EPA is promulgating water regulations for certain volatile synthetic organic chemicals. Specifically, this
notice promulgates a maximum contaminant level for Benzene at 0.005 mg/L.
• Benzene is not subject to the reporting requirements of Section 112(r) of the Clean Air Act.
• Benzene is not listed in Appendix A as a highly hazardous chemical, per 29 CFR 1910.119: Process Safety
Management of Highly Hazardous Chemicals. Under this regulation, however, any process that involves a
flammable liquid on-site, in one location, in quantities of 10,000 lbs (4,553 kg) or greater is covered under this
regulation unless it is used as a fuel.
• Benzene does not contain any Class I or Class II ozone depleting chemicals (40 CFR part 82).
• Benzene is not listed a Regulated Substance, per 40 CFR, Part 68, of the Risk Management for Chemical
Releases.
OTHER CANADIAN REGULATIONS: Benzene is categorized as a Controlled Product, Hazard Classes B2, D2A
and D2B, as per the Controlled Product Regulations.

NFPA RATING HAZARDOUS MATERIAL INFORMATION
FLAMMABILITY SYSTEM
3 HEALTH (BLUE) 2
HEALTH 2 0 REACTIVITY
OTHER
FLAMMABILITY (RED) 3
REACTIVITY (YELLOW) 0
PROTECTIVE EQUIPMENT X
EYES RESPIRATORY HANDS BODY
See Section 8
For routine industrial applications

PAGE 11 OF 12
16. OTHER INFORMATION (Continued)
MIXTURES: When two or more gases or liquefied gases are mixed, their hazardous properties may combine to
create additional, unexpected hazards. Obtain and evaluate the safety information for each component before
you produce the mixture. Consult an Industrial Hygienist or other trained person when you make your safety
evaluation of the end product. Remember, gases and liquids have properties which can cause serious injury or
death.
Further information can be found in the following pamphlets published by: Compressed Gas Association Inc.
(CGA), 4221 Walney Road 5th floor, Chantilly, VA 20151-2923. Telephone: (703) 788-2700.
P-1 “Safe Handling of Compressed Gases in Containers”
AV-1 "Safe Handling and Storage of Compressed Gases"
PREPARED BY: CHEMICAL SAFETY ASSOCIATES, Inc.
9163 Chesapeake Drive, San Diego, CA 92123-1002
619/565-0302
Fax on Demand: 1-800/231-1366
This Material Safety Data Sheet is offered pursuant to OSHA’s Hazard Communication Standard, 29 CFR, 1910.1200. Other government
regulations must be reviewed for applicability to this product. To the best of Air Liquide’s knowledge, the information contained herein is
reliable and accurate as of this date; however, accuracy, suitability or completeness are not guaranteed and no warranties of any type, either
express or implied, are provided. The information contained herein relates only to this specific product. If this product is combined with other
materials, all component properties must be considered. Data may be changed from time to time. Be sure to consult the latest edition.

PAGE 12 OF 12
C6 Raffinate
Version 5.4
Effective Date 07.08.2008
Material Safety Data Sheet Regulation 1907/2006/EC
1. IDENTIFICATION OF THE SUBSTANCE/PREPARATION AND COMPANY/UNDERTAKING
Material Name : C6 Raffinate

Uses : Chemical feedstock and component of motor gasoline. For use
only in industrial processes.
Product Code : Q9110, Q9140
Manufacturer/Supplier : Shell Chemicals Europe B.V.

PO Box 8610
3009 AP Rotterdam
Netherlands
Local Contact : Shell Chemicals UK

Telephone : +31 (0)10231 7425
Fax : +31 (0)10231 7115
Email contact for : sccmsds@shell.com
MSDS
Emergency Telephone : +44 (0)208 7628322

Number
Health Hazards : Slightly irritating to respiratory system. Vapours may cause

drowsiness and dizziness. Irritating to eyes and skin. Harmful:
may cause lung damage if swallowed. Possibility of organ or
organ system damage from prolonged exposure; see Chapter
11 for details. Target organ(s): Blood. Blood-forming organs.
Immune system. Peripheral nervous system. May cause
cancer. May cause leukaemia (AML - acute myelogenous
leukaemia). May cause heritable genetic damage. Toxic:
danger of serious damage to health by prolonged exposure
through inhalation, in contact with skin and if swallowed.
Possible risk of impaired fertility.
Signs and Symptoms : Eye irritation signs and symptoms may include a burning
sensation, redness, swelling, and/or blurred vision. Skin
irritation signs and symptoms may include a burning sensation,
redness, swelling, and/or blisters. If material enters lungs,
signs and symptoms may include coughing, choking,
wheezing, difficulty in breathing, chest congestion, shortness of
breath, and/or fever. The onset of respiratory symptoms may
be delayed for several hours after exposure. Breathing of high
vapour concentrations may cause central nervous system
(CNS) depression resulting in dizziness, light-headedness,
headache, nausea and loss of coordination. Continued
inhalation may result in unconsciousness and death. Damage
to blood-forming organs may be evidenced by: a) fatigue and
anaemia (RBC), b) decreased resistance to infection, and/or
excessive bruising and bleeding (platelet effect).
Immunotoxicity may be evidenced by decreased resistance to
infection. Peripheral nerve damage may be evidenced by
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C6 Raffinate
Version 5.4
impairment of motor function (incoordination, unsteady walk, or

muscle weakness in the extremities, and/or loss of sensation in
the arms and legs).
Aggravated Medical : Pre-existing medical conditions of the following organ(s) or
Condition organ system(s) may be aggravated by exposure to this
material: Blood. Blood-forming organs. Cardiovascular system.
Eyes. Immune system. Peripheral nervous system. Skin.
Safety Hazards : Highly flammable. In use, may form flammable/explosive
vapour-air mixture. Electrostatic charges may be generated
during pumping. Electrostatic discharge may cause fire.
Environmental Hazards : Expected to be toxic to aquatic organisms. May cause long-
term adverse effects in the aquatic environment.
Synonyms : Naphtha, petroleum, solvent-refined light

Solvent refined light naphtha heartcut (petroleum)
Raffinate
CAS No. : 64741-84-0
INDEX No. : 649-278-00-0
EINECS No. : 265-086-6
Hazardous Components
Chemical Name CAS EINECS Symbol(s) R-phrase(s) Conc.

Naphtha 64741-84-0 265-086-6 100.00 %
(petroleum),
solvent-refined
light
CONTAINS: %
Benzene 71-43-2 200-753-7 F, T R45; R46; < 5.00 %W
R11;
R36/38;
R48/23/24/2
5; R65
n-Hexane 110-54-3 203-777-6 F, Xn, N R11; R38; 15.00 - 30.00
R48/20; %W
R62; R65;
R67; R51/53
Cyclohexane 110-82-7 203-806-2 F, Xn, N R11; R38; >= 5.00 - <= 10.00
R65; R67; %
R50/53
General Information : Keep victim calm. Obtain medical treatment immediately.

Inhalation : DO NOT DELAY. Remove to fresh air. If rapid recovery does
not occur, transport to nearest medical facility for additional
treatment.
Skin Contact : Remove contaminated clothing. Immediately flush skin with
large amounts of water for at least 15 minutes, and follow by
washing with soap and water if available. If redness, swelling,
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pain and/or blisters occur, transport to the nearest medical

facility for additional treatment.
Eye Contact : Immediately flush eyes with large amounts of water for at least
15 minutes while holding eyelids open. Transport to the
nearest medical facility for additional treatment.
Ingestion : If swallowed, do not induce vomiting: transport to nearest
medical facility for additional treatment. If vomiting occurs
spontaneously, keep head below hips to prevent aspiration.
Advice to Physician : Potential for chemical pneumonitis. Consider: gastric lavage
with protected airway, administration of activated charcoal.
Potential for cardiac sensitisation, particularly in abuse
situations. Hypoxia or negative inotropes may enhance these
effects. Consider: oxygen therapy. Call a doctor or poison
control center for guidance.
Clear fire area of all non-emergency personnel.
Specific Hazards : The vapour is heavier than air, spreads along the ground and
distant ignition is possible. Will float and can be reignited on
surface water. Carbon monoxide may be evolved if incomplete
combustion occurs.
Extinguishing Media : Foam, water spray or fog. Dry chemical powder, carbon
dioxide, sand or earth may be used for small fires only.
Unsuitable Extinguishing : Do not use water in a jet.
Media
Protective Equipment for : Wear full protective clothing and self-contained breathing
Firefighters apparatus.
Additional Advice : Keep adjacent containers cool by spraying with water.
Avoid contact with spilled or released material. Immediately remove all contaminated clothing.
For guidance on selection of personal protective equipment see Chapter 8 of this Material Safety
Data Sheet. For guidance on disposal of spilled material see Chapter 13 of this Material Safety
Data Sheet. Observe all relevant local and international regulations.
Protective measures : Isolate hazard area and deny entry to unnecessary or

unprotected personnel. Stay upwind and keep out of low areas.
Remove all possible sources of ignition in the surrounding
area. Use appropriate containment to avoid environmental
contamination. Prevent from spreading or entering drains,
ditches or rivers by using sand, earth, or other appropriate
barriers. Attempt to disperse the vapour or to direct its flow to a
safe location, for example by using fog sprays. Ventilate
contaminated area thoroughly. Shut off leaks, if possible
without personal risks. Remove all possible sources of ignition
in the surrounding area. Use appropriate containment (of
product and fire fighting water) to avoid environmental
contamination. Prevent from spreading or entering drains,
ditches or rivers by using sand, earth, or other appropriate
barriers. Attempt to disperse the vapour or to direct its flow to a
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C6 Raffinate
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safe location for example by using fog sprays. Take

precautionary measures against static discharge. Ensure
electrical continuity by bonding and grounding (earthing) all
equipment. Ventilate contaminated area thoroughly.
Clean Up Methods : For large liquid spills (> 1 drum), transfer by mechanical means
such as vacuum truck to a salvage tank for recovery or safe
disposal. Do not flush away residues with water. Retain as
contaminated waste. Allow residues to evaporate or soak up
with an appropriate absorbent material and dispose of safely.
Remove contaminated soil and dispose of safely.
For small liquid spills (< 1 drum), transfer by mechanical means
to a labelled, sealable container for product recovery or safe
disposal. Allow residues to evaporate or soak up with an
appropriate absorbent material and dispose of safely. Remove
contaminated soil and dispose of safely.
Additional Advice : Notify authorities if any exposure to the general public or the
environment occurs or is likely to occur. Local authorities
should be advised if significant spillages cannot be contained.
The vapour is heavier than air, spreads along the ground and
distant ignition is possible. Vapour may form an explosive
mixture with air. See Chapter 13 for information on disposal.
General Precautions : Avoid breathing vapours or contact with material. Only use in
well ventilated areas. Wash thoroughly after handling. For
guidance on selection of personal protective equipment see
Chapter 8 of this Material Safety Data Sheet. For
comprehensive advice on handling, product transfer, storage
and tank cleaning refer to the product supplier. Use the
information in this data sheet as input to a risk assessment of
local circumstances to help determine appropriate controls for
safe handling, storage and disposal of this material. Extinguish
any naked flames. Do not smoke. Remove ignition sources.
Avoid sparks. Avoid contact with skin, eyes, and clothing.
Storage : Vapours from tanks should not be released to atmosphere.
Breathing losses during storage should be controlled by a
suitable vapour treatment system. Bulk storage tanks should
be diked (bunded). The vapour is heavier than air. Beware of
accumulation in pits and confined spaces.
Product Transfer : Electrostatic charges may be generated during pumping.
Electrostatic discharge may cause fire. Ensure electrical
continuity by bonding and grounding (earthing) all equipment.
Restrict line velocity during pumping in order to avoid
generation of electrostatic discharge (<= 1 m/sec until fill pipe
submerged to twice its diameter, then <= 7 m/sec). Avoid
splash filling. Do NOT use compressed air for filling,
discharging, or handling operations.
Recommended Materials : For containers, or container linings use mild steel, stainless
steel.
Unsuitable Materials : Natural, butyl, neoprene or nitrile rubbers.
Additional Information : Ensure that all local regulations regarding handling and storage
facilities are followed.
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Occupational Exposure Limits
UK Workplace Exposure Limits
Material Source Type ppm mg/m3 Notation

Benzene EH40 MEL TWA 1 ppm
EH40 WEL TWA 1 ppm
EH40 WEL SKIN_DES Can be absorbed through
the skin.
EU OELIII TWA 1 ppm 3.25 mg/m3
EU OELIII SKIN_DES Can be absorbed through
the skin.
n-Hexane EH40 WEL TWA 20 ppm 72 mg/m3
Additional Information : Skin notation means that significant exposure can also occur
by absorption of liquid through the skin and of vapour through
the eyes or mucous membranes.
Material Source Hazard Designation

Benzene EU CARC. Carcinogen/Mutagen
Exposure Controls : The level of protection and types of controls necessary will vary
depending upon potential exposure conditions. Select controls
based on a risk assessment of local circumstances.
Appropriate measures include: Use sealed systems as far as
possible. Adequate ventilation to control airborne
concentrations below the exposure guidelines/limits. Adequate
explosion-proof ventilation to control airborne concentrations.
Firewater monitors and deluge systems are recommended.
Eye washes and showers for emergency use.
Personal Protective : Personal protective equipment (PPE) should meet
Equipment recommended national standards. Check with PPE suppliers.
Respiratory Protection : If engineering controls do not maintain airborne concentrations
to a level which is adequate to protect worker health, select
respiratory protection equipment suitable for the specific
conditions of use and meeting relevant legislation. Check with
respiratory protective equipment suppliers. Where air-filtering
respirators are suitable, select an appropriate combination of
mask and filter. Select a filter suitable for combined
particulate/organic gases and vapours [boiling point <65 °C
(149 °F)] meeting EN371. Where respiratory protective
equipment is required, use a full-face mask. Where air-filtering
respirators are unsuitable (e.g., airborne concentrations are
high, risk of oxygen deficiency, confined space) use
appropriate positive pressure breathing apparatus.
Hand Protection : Where hand contact with the product may occur the use of
gloves approved to relevant standards (e.g. Europe: EN374,
US: F739, AS/NZS:2161) made from the following materials
may provide suitable chemical protection: Longer term
protection: Viton. Incidental contact/Splash protection: Nitrile
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rubber. Suitability and durability of a glove is dependent on

usage, e.g. frequency and duration of contact, chemical
resistance of glove material, glove thickness, dexterity. Always
seek advice from glove suppliers. Contaminated gloves should
be replaced.
Personal hygiene is a key element of effective hand care.
Gloves must only be worn on clean hands. After using gloves,
hands should be washed and dried thoroughly. Application of a
non-perfumed moisturizer is recommended.
Eye Protection : Chemical splash goggles (chemical monogoggles). Approved
to EU Standard EN166, AS/NZS:1337.
Protective Clothing : Chemical resistant gloves/gauntlets, boots, and apron. Where
risk of splashing or in spillage clean up, use chemical resistant
one-piece overall with integral hood.
Monitoring Methods : Monitoring of the concentration of substances in the breathing
zone of workers or in the general workplace may be required to
confirm compliance with an OEL and adequacy of exposure
controls. For some substances biological monitoring may also
be appropriate. Examples of sources of recommended air
monitoring methods are given below or contact supplier.
Further national methods may be available. National Institute of
Occupational Safety and Health (NIOSH), USA: Manual of
Analytical Methods,
http://www.cdc.gov/niosh/nmam/nmammenu.html.
Occupational Safety and Health Administration (OSHA), USA:
Sampling and Analytical Methods, http://www.osha-
slc.gov/dts/sltc/methods/toc.html. Health and Safety Executive
(HSE), UK: Methods for the Determination of Hazardous
Substances, http://www.hsl.gov.uk/search.htm.
Berufsgenossenschaftliches Institut für Arbeitssicherheit (BIA),
Germany http://www.hvbg.de/d/bia/index.html. L'Institut
National de Recherche et de Securité, (INRS), France
http://www.inrs.fr/securite/hygiene_securite_travail.html.
Environmental Exposure : Local guidelines on emission limits for volatile substances must
Controls be observed for the discharge of exhaust air containing vapour.
Appearance : Colourless. Liquid.

Odour : Aromatic.
Boiling point : ca. 60 - 105 °C / 140 - 221 °F
Flash point : < 0 °C / 32 °F
Explosion / Flammability : 1 - 7.5 %(V)
limits in air
Auto-ignition temperature : ca. 200 °C / 392 °F
Vapour pressure : <= 500 mbar at 38 °C / 100 °F
Density : Typical 700 kg/m3 at 20 °C / 68 °F
Water solubility : 1.8 g/l
Dynamic viscosity : ca. 0.5 mPa.s at 20 °C / 68 °F
Vapour density (air=1) : 3.3
Electrical conductivity : < 50 pS/m
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Stability : Stable under normal conditions of use. Reacts violently with

strong oxidising agents.
Conditions to Avoid : Avoid heat, sparks, open flames and other ignition sources.
Prevent vapour accumulation.
Materials to Avoid : Strong oxidising agents.
Hazardous : Thermal decomposition is highly dependent on conditions. A
Decomposition Products complex mixture of airborne solids, liquids and gases, including
carbon monoxide, carbon dioxide and other organic compounds
will be evolved when this material undergoes combustion or
thermal or oxidative degradation.
Basis for Assessment : Information given is based on data from components.

Acute Oral Toxicity : Expected to be of low toxicity: LD50 >2000 mg/kg , Rat
Aspiration into the lungs when swallowed or vomited may
cause chemical pneumonitis which can be fatal.
Acute Dermal Toxicity : Low toxicity: LD50 >2000 mg/kg , Rabbit
Acute Inhalation Toxicity : Expected to be of low toxicity: LC50 >20 mg/l / 4 hours, Rat
Skin Irritation : Irritating to skin.
Eye Irritation : Irritating to eyes.
Respiratory Irritation : Inhalation of vapours or mists may cause irritation to the
respiratory system.
Sensitisation : Not expected to be a skin sensitiser.
Repeated Dose Toxicity : Blood: may cause haemolysis of red blood cells and/or
anaemia. (Benzene)
Blood-forming organs: repeated exposure affects the bone
marrow. (Benzene)
Peripheral nervous system: repeated exposure causes
peripheral neuropathy in animals. (n-Hexane)
Immune System: animal studies on this material or its
components have demonstrated immunotoxicity. (Benzene)
Mutagenicity : May cause heritable genetic damage. (Benzene)
Carcinogenicity : Known human carcinogen. (Benzene)
May cause leukaemia (AML - acute myelogenous leukaemia).
(Benzene)
Reproductive and : Affects reproductive system in animals at doses which produce
Developmental Toxicity other toxic effects. (n-Hexane)
Causes foetotoxicity at doses which are maternally toxic.
(Benzene, n-Hexane)
Additional Information : Exposure to very high concentrations of similar materials has
been associated with irregular heart rhythms and cardiac
arrest.
Myelodysplastic syndrome (MDS) was observed in individuals
exposed to very high levels (50 ppm to 300 ppm range) of
benzene over a long period of time in the workplace. The
relevance of these results to lower levels of exposure is not
known.
7/10
C6 Raffinate
Version 5.4
Acute Toxicity
Fish : Expected to be toxic: 1 < LC/EC/IC50 <= 10 mg/l
Aquatic Invertebrates : Expected to be toxic: 1 < LC/EC/IC50 <= 10 mg/l
Algae : Expected to be toxic: 1 < LC/EC/IC50 <= 10 mg/l
Microorganisms : Expected to be harmful: 10 < LC/EC/IC50 <= 100 mg/l
Mobility : If product enters soil, one or more constituents will be highly
mobile and may contaminate groundwater.
Floats on water.
Persistence/degradability : Expected to be inherently biodegradable. Oxidises rapidly by
photo-chemical reactions in air.
Bioaccumulation : Contains components with the potential to bioaccumulate.
Material Disposal : Recover or recycle if possible. It is the responsibility of the

waste generator to determine the toxicity and physical
properties of the material generated to determine the proper
waste classification and disposal methods in compliance with
applicable regulations.
Do not dispose into the environment, in drains or in water
courses. Waste product should not be allowed to contaminate
soil or water.
Local Legislation : Disposal should be in accordance with applicable regional,
national, and local laws and regulations.
ADR
Class : 3
Packing group : II
Classification code : F1
Hazard indentification no. : 33
UN No. : 1268
Danger label (primary risk) : 3
Proper shipping name : PETROLEUM PRODUCTS, N.O.S.
RID
Class : 3
Packing group : II
Classification code : F1
Hazard indentification no. : 33
UN No. : 1268
Danger label (primary risk) : 3
Proper shipping name : PETROLEUM PRODUCTS, N.O.S. ()
IMDG
Proper shipping name PETROLEUM DISTILLATES, N.O.S.
Class / Division 3
Packing group II
Marine pollutant: No
8/10
C6 Raffinate
Version 5.4
IATA (Country variations may apply)

UN No. : 1268
Proper shipping name : Petroleum distillates, n.o.s.
Class / Division : 3
Packing group : II
The regulatory information is not intended to be comprehensive. Other regulations may apply to this
material.
EC Label Name : Naphtha (petroleum), solvent-refined light; Low boiling point

modified naphtha
EC label/EC Number : 265-086-6
EC Classification : Highly flammable. Toxic.
EC Annex I Number : 649-278-00-0
EC Symbols : F Highly flammable.
T Toxic.
EC Risk Phrases : R45 May cause cancer.
R46 May cause heritable genetic damage.
R11 Highly flammable.
R36/38 Irritating to eyes and skin.
R48/23/24/25 Toxic: danger of serious damage to health by
prolonged exposure through inhalation, in contact with skin and
if swallowed.
R62 Possible risk of impaired fertility.
R67 Vapours may cause drowsiness and dizziness.
R51/53 Toxic to aquatic organisms, may cause long-term
EC Safety Phrases : S53 Avoid exposure. Obtain special instructions before use.
S16 Keep away from sources of ignition - No smoking.
S29 Do not empty into drains.
S45 In case of accident or if you feel unwell, seek medical
advice immediately (show the label where possible).
S61 Avoid release to the environment. Refer to special
instructions/Safety data sheets.
EINECS : Listed. 295-436-3
KECI (KR) : Listed. KE-20067
TSCA : Listed.
AICS : Listed.
DSL : Listed.
CHINA : Listed.
PICCS (PH) :
National Legislation
OE_HPV : Listed.
Other Information : Restricted to professional users.
9/10
C6 Raffinate
Version 5.4
R-phrase(s)
R11 Highly flammable.

R36/38 Irritating to eyes and skin.
R45 May cause cancer.
R46 May cause heritable genetic damage.
R48/20 Harmful: danger of serious damage to health by prolonged exposure through
inhalation.
R48/23/24/25 Toxic: danger of serious damage to health by prolonged exposure through
inhalation, in contact with skin and if swallowed.
R50/53 Very toxic to aquatic organisms, may cause long-term adverse effects in the
R51/53 Toxic to aquatic organisms, may cause long-term adverse effects in the aquatic
environment.
R62 Possible risk of impaired fertility.
R65 Harmful: May cause lung damage if swallowed.
R67 Vapours may cause drowsiness and dizziness.
MSDS Version Number : 5.4
MSDS Effective Date : 07.08.2008
MSDS Revisions : A vertical bar (|) in the left margin indicates an amendment
from the previous version.
MSDS Regulation : The content and format of this safety data sheet is in
accordance with Regulation 1907/2006/EC.
Uses and Restrictions : Chemical feedstock and component of motor gasoline. For use
only in industrial processes.
Restricted to professional users.
MSDS Distribution : The information in this document should be made available to

all who may handle the product
Disclaimer : This information is based on our current knowledge and is
intended to describe the product for the purposes of health,
safety and environmental requirements only. It should not
therefore be construed as guaranteeing any specific property
of the product.
10/10
SODIUM HYDROXIDE SOLUTION (50 wt% NaOH)
Synonyms: Caustic soda solution, sodium hydroxide liquid, sodium hydrate solution
CAS No.: 1310-73-2
Chemical Formula: NaOH in water
Company Identification: ONGIC (+82 2 581 9637)
Emergency call: + 82 2 581 9637

------------------------------------- ------------ --------- ---------
Sodium Hydroxide 1310-73-2 48-50% Yes
Water 7732-18-5 50-52% No
Emergency Overview
--------------------------
POISON! DANGER! CORROSIVE. MAY BE FATAL IF SWALLOWED. HARMFUL IF INHALED. CAUSES
BURNS TO ANY AREA OF CONTACT. REACTS WITH WATER, ACIDS AND OTHER MATERIALS.
(tm)
-----------------------------------------------------------------------------
Health Rating: 3 - Severe (Poison)
Flammability Rating: 0 - None
Reactivity Rating: 2 - Moderate
Contact Rating: 4 - Extreme (Corrosive)
Lab Protective Equip: GOGGLES & SHIELD; LAB COAT & APRON; VENT HOOD; PROPER GLOVES
Storage Color Code: White Stripe (Store Separately)
-----------------------------------------------------------------------------
----------------------------------
Inhalation:
Severe irritant. Effects from inhalation of mist vary from mild irritation to serious damage of the
upper respiratory tract, depending on severity of exposure. Symptoms may include sneezing, sore
throat or runny nose. Severe pneumonitis may occur.
Ingestion:
Corrosive! Swallowing may cause severe burns of mouth, throat, and stomach. Severe scarring of
tissue and death may result. Symptoms may include bleeding, vomiting, diarrhea, fall in blood
pressure. Damage may appear days after exposure.
Skin Contact:
Corrosive! Contact with skin can cause irritation or severe burns and scarring with greater
exposures.
Eye Contact:
Corrosive! Causes irritation of eyes, and with greater exposures it can cause burns that may result
in permanent impairment of vision, even blindness.
Chronic Exposure:
Prolonged contact with dilute solutions or dust has a destructive effect upon tissue.
Persons with pre-existing skin disorders or eye problems or impaired respiratory function may be
more susceptible to the effects of the substance.
Inhalation:
Remove to fresh air. If not breathing, give artificial respiration. If breathing is difficult, give oxygen.
Call a physician.
Ingestion:
DO NOT INDUCE VOMITING! Give large quantities of water or milk if available. Never give
anything by mouth to an unconscious person. Get medical attention immediately.
Skin Contact:
Immediately flush skin with plenty of water for at least 15 minutes while removing contaminated
clothing and shoes. Call a physician, immediately. Wash clothing before reuse.
Eye Contact:
Immediately flush eyes with plenty of water for at least 15 minutes, lifting lower and upper eyelids
occasionally. Get medical attention immediately.
Note to Physician:
Perform endoscopy in all cases of suspected sodium hydroxide ingestion. In cases of severe
esophageal corrosion, the use of therapeutic doses of steroids should be considered. General
supportive measures with continual monitoring of gas exchange, acid-base balance, electrolytes,
and fluid intake are also required.
Fire:
Not considered to be a fire hazard. Hot or molten material can react violently with water.
Can react with certain metals, such as aluminum, to generate flammable hydrogen gas.
Explosion:
May cause fire and explosions when in contact with incompatible materials.
Use any means suitable for extinguishing surrounding fire. Adding water to caustic solution
generates large amounts of heat.
apparatus with full facepiece operated in the pressure demand or other positive pressure mode.
Ventilate area of leak or spill. Keep unnecessary and unprotected people away from area of spill.
Wear appropriate personal protective equipment as specified in Section 8. Contain and recover
liquid when possible. Do not flush caustic residues to the sewer. Residues from spills can be diluted
with water, neutralized with dilute acid such as acetic, hydrochloric or sulfuric. Absorb neutralized
caustic residue on clay, vermiculite or other inert substance and package in a suitable container for
disposal.
US Regulations (CERCLA) require reporting spills and releases to soil, water and air in excess of
reportable quantities. The toll free number for the US Coast Guard National Response Center is
(800) 424-8802.
Keep in a tightly closed container. Protect from physical damage. Store in a cool, dry, ventilated
area away from sources of heat, moisture and incompatibilities. Store above 16C (60F) to prevent
freezing. Always add the caustic to water while stirring; never the reverse. Containers of this
material may be hazardous when empty since they retain product residues (vapors, liquid); observe
all warnings and precautions listed for the product. Do not store with aluminum or magnesium. Do
not mix with acids or organic materials.

- OSHA Permissible Exposure Limit (PEL):
2 mg/m3 Ceiling
- ACGIH Threshold Limit Value (TLV):
2 mg/m3 Ceiling
Ventilation System:
Airborne Exposure Limits. Local exhaust ventilation is generally preferred because it can control
the emissions of the contaminant at its source, preventing dispersion of it into the general work
area. Please refer to the ACGIH document, Industrial Ventilation, A Manual of Recommended
Practices, most recent edition, for details.
If the exposure limit is exceeded and engineering controls are not feasible, a half facepiece
particulate respirator (NIOSH type N95 or better filters) may be worn for up to ten times the
exposure limit or the maximum use concentration specified by the appropriate regulatory agency or
respirator supplier, whichever is lowest.. A full-face piece particulate respirator (NIOSH type N100
filters) may be worn up to 50 times the exposure limit, or the maximum use concentration specified
by the appropriate regulatory agency, or respirator supplier, whichever is lowest. If oil particles
(e.g. lubricants, cutting fluids, glycerine, etc.) are present, use a NIOSH type R or P filter. For
emergencies or instances where the exposure levels are not known, use a full-facepiece positive-
pressure, air-supplied respirator. WARNING: Air-purifying respirators do not protect workers in
oxygen-deficient atmospheres.
Skin Protection:
Wear impervious protective clothing, including boots, gloves, lab coat, apron or coveralls, as
appropriate, to prevent skin contact.
Eye Protection:
Use chemical safety goggles and/or a full face shield where splashing is possible. Maintain eye
wash fountain and quick-drench facilities in work area.
Physical data is displayed for 10%, 30% and 50% aqueous sodium hydroxide solutions. (Merck
Index).
Appearance: Clear, colorless solution.
Odor: Odorless.
Solubility: Completely miscible with water.
Density: 1.53 g/cm3
pH: 14.0
% Volatiles by volume @ 21C (70F): No information found.
Boiling Point: 140C (284F).
Melting Point: 12C (53.6F).
Vapor Density (Air=1): No information found.
Vapor Pressure (mm Hg): 13 @ 60C (140F)
Evaporation Rate (BuAc=1): No information found.
Stability:
Stable under ordinary conditions of use and storage.
Hazardous Decomposition Products:

Sodium oxide. Decomposition by reaction with certain metals releases flammable and explosive
hydrogen gas.
Hazardous Polymerization:
Will not occur.
Incompatibilities:
Sodium hydroxide in contact with acids and organic halogen compounds, especially
trichloroethylene, may causes violent reactions. Contact with nitromethane and other similar nitro
compounds causes formation of shock-sensitive salts. Contact with metals such as aluminum,
magnesium, tin, and zinc cause formation of flammable hydrogen gas. Sodium hydroxide, even in
fairly dilute solution, reacts readily with various sugars to produce carbon monoxide. Precautions
should be taken including monitoring the tank atmosphere for carbon monoxide to ensure safety of
personnel before vessel entry.
Heat, moisture, incompatibles.
Sodium hydroxide: irritation data: skin, rabbit: 500 mg/24H severe; eye rabbit: 50 ug/24H severe.
Investigated as a mutagen.
--------\Cancer Lists\------------------------------------------------------
------------------------------------ ----- ----------- -------------
Sodium Hydroxide (1310-73-2) No No None
Water (7732-18-5) No No None
Environmental Fate: No information found.

Environmental Toxicity: No information found.
Whatever cannot be saved for recovery or recycling should be managed in an appropriate and
approved waste facility. Although not a listed RCRA hazardous waste, this material may exhibit one
or more characteristics of a hazardous waste and require appropriate analysis to determine specific
disposal requirements. Processing, use or contamination of this product may change the waste
management options. State and local disposal regulations may differ from federal disposal
regulations. Dispose of container and unused contents in accordance with federal, state and local
requirements.

-----------------------
Proper Shipping Name: SODIUM HYDROXIDE SOLUTION
Hazard Class: 8
UN/NA: UN1824
Packing Group: II

-----------------------------
Proper Shipping Name: SODIUM HYDROXIDE, SOLUTION
Hazard Class: 8
UN/NA: UN1824
Packing Group: II

----------------------------------------------- ---- --- ----- ---------
Sodium Hydroxide (1310-73-2) Yes Yes Yes Yes
Water (7732-18-5) Yes Yes Yes Yes

--Canada--
----------------------------------------------- ----- --- ---- -----
Sodium Hydroxide (1310-73-2) Yes Yes No Yes
Water (7732-18-5) Yes Yes No Yes

-SARA 302- ------SARA 313------
----------------------------------------- --- ----- ---- --------------
Sodium Hydroxide (1310-73-2) No No No No
Water (7732-18-5) No No No No

-RCRA- -TSCA-
----------------------------------------- ------ ------ ------
Sodium Hydroxide (1310-73-2) 1000 No No
Water (7732-18-5) No No No
Chemical Weapons Convention: No TSCA 12(b): No CDTA: No

SARA 311/312: Acute: Yes Chronic: Yes Fire: No Pressure: No
Reactivity: Yes (Mixture / Liquid)
Australian Hazchem Code: 2R

Poison Schedule: S6
WHMIS:
This MSDS has been prepared according to the hazard criteria of the Controlled Products
Regulations (CPR) and the MSDS contains all of the information required by the CPR.
NFPA Ratings: Health: 3 Flammability: 0 Reactivity: 1

POISON! DANGER! CORROSIVE. MAY BE FATAL IF SWALLOWED. HARMFUL IF INHALED.
CAUSES BURNS TO ANY AREA OF CONTACT. REACTS WITH WATER, ACIDS AND OTHER
MATERIALS.
Label Precautions:
Do not get in eyes, on skin, or on clothing.
Do not breathe mist.
Label First Aid:
If swallowed, DO NOT INDUCE VOMITING. Give large quantities of water. Never give anything by
mouth to an unconscious person. In case of contact, immediately flush eyes or skin with plenty of
water for at least 15 minutes while removing contaminated clothing and shoes. Wash clothing
before reuse. If inhaled, remove to fresh air. If not breathing give artificial respiration. If breathing
is difficult, give oxygen. In all cases get medical attention immediately.
SULFURIC ACID, 98 %
Synonyms: Oil of vitriol; Babcock acid; sulphuric acid

CAS No.: 7664-93-9
Chemical Formula: H2SO4 in H2O
Company Identification: ONGIC (+82 2 581 9637)
Emergency call: + 82 2 581 9637

--------------------------------- ------------ ------------ ---------
Sulfuric Acid 7664-93-9 98 -100% Yes
Water 7732-18-5 0 - 2% No
Emergency Overview
--------------------------
POISON! DANGER! CORROSIVE. LIQUID AND MIST CAUSE SEVERE BURNS TO ALL BODY TISSUE. MAY
BE FATAL IF SWALLOWED OR CONTACTED WITH SKIN. HARMFUL IF INHALED. AFFECTS TEETH.
WATER REACTIVE. CANCER HAZARD. STRONG INORGANIC ACID MISTS CONTAINING SULFURIC ACID
CAN CAUSE CANCER. Risk of cancer depends on duration and level of exposure.
(tm)
---------------------------------------------------------------------------------
Health Rating: 4 - Extreme (Poison)
Flammability Rating: 0 - None
Reactivity Rating: 2 - Moderate
Contact Rating: 4 - Extreme (Corrosive)
Lab Protective Equip: GOGGLES & SHIELD; LAB COAT & APRON; VENT HOOD; PROPER GLOVES
Storage Color Code: White (Corrosive)
---------------------------------------------------------------------------------
----------------------------------
Inhalation: Inhalation produces damaging effects on the mucous membranes and upper respiratory tract.
Symptoms may include irritation of the nose and throat, and labored breathing. May cause lung edema, a
medical emergency.
Ingestion: Corrosive. Swallowing can cause severe burns of the mouth, throat, and stomach, leading to
death. Can cause sore throat, vomiting, diarrhea. Circulatory collapse with clammy skin, weak and rapid
pulse, shallow respirations, and scanty urine may follow ingestion or skin contact. Circulatory shock is
often the immediate cause of death.
Skin Contact: Corrosive. Symptoms of redness, pain, and severe burn can occur. Circulatory collapse with
clammy skin, weak and rapid pulse, shallow respirations, and scanty urine may follow skin contact or
ingestion. Circulatory shock is often the immediate cause of death.
Eye Contact:
Corrosive. Contact can cause blurred vision, redness, pain and severe tissue burns. Can cause blindness.
Chronic Exposure:
Long-term exposure to mist or vapors may cause damage to teeth. Chronic exposure to mists containing
sulfuric acid is a cancer hazard.
Persons with pre-existing skin disorders or eye problems or impaired respiratory function may be more
susceptible to the effects of the substance.
Inhalation:
Remove to fresh air. If not breathing, give artificial respiration. If breathing is difficult, give oxygen. Call
a physician immediately.
Ingestion:
DO NOT INDUCE VOMITING. Give large quantities of water. Never give anything by mouth to an
unconscious person. Call a physician immediately.
Skin Contact:
In case of contact, immediately flush skin with plenty of water for at least 15 minutes while removing
contaminated clothing and shoes. Wash clothing before reuse. Excess acid on skin can be neutralized with
a 2% solution of bicarbonate of soda. Call a physician immediately.
Eye Contact:
Immediately flush eyes with gentle but large stream of water for at least 15 minutes, lifting lower and
upper eyelids occasionally. Call a physician immediately.
Fire:
Concentrated material is a strong dehydrating agent. Reacts with organic materials and may cause
ignition of finely divided materials on contact.
Explosion:
Contact with most metals causes formation of flammable and explosive hydrogen gas.
Dry chemical, foam or carbon dioxide. Do not use water on material. However, water spray may be used
to keep fire exposed containers cool.
apparatus with full facepiece operated in the pressure demand or other positive pressure mode.
Structural firefighter's protective clothing is ineffective for fires involving this material. Stay away from
sealed containers.
Ventilate area of leak or spill. Wear appropriate personal protective equipment as specified in Section 8.
Isolate hazard area. Keep unnecessary and unprotected personnel from entering. Contain and recover
liquid when possible. Neutralize with alkaline material (soda ash, lime), then absorb with an inert material
(e. g., vermiculite, dry sand, earth), and place in a chemical waste container. Do not use combustible
materials, such as saw dust. Do not flush to sewer! US Regulations (CERCLA) require reporting spills and
releases to soil, water and air in excess of reportable quantities. The toll free number for the US Coast
Guard National Response Center is (800) 424-8802.
Store in a cool, dry, ventilated storage area with acid resistant floors and good drainage. Protect from
physical damage. Keep out of direct sunlight and away from heat, water, and incompatible materials. Do
not wash out container and use it for other purposes. When diluting, always add the acid to water; never
add water to the acid. When opening metal containers, use non-sparking tools because of the possibility
of hydrogen gas being present. Containers of this material may be hazardous when empty since they
retain product residues (vapors, liquid); observe all warnings and precautions listed for the product.

For Sulfuric Acid:
- OSHA Permissible Exposure Limit (PEL) -
1 mg/m3 (TWA)
- ACGIH Threshold Limit Value (TLV) -
0.2 mg/m3(T) (TWA) for sulfuric acid - A2 Suspected Human Carcinogen for sulfuric acid contained in
strong inorganic mists.
Ventilation System:
Airborne Exposure Limits. Local exhaust ventilation is generally preferred because it can control the
emissions of the contaminant at its source, preventing dispersion of it into the general work area. Please
refer to the ACGIH document, Industrial Ventilation, A Manual of Recommended Practices, most recent
edition, for details.
If the exposure limit is exceeded and engineering controls are not feasible, a full facepiece respirator
with an acid gas cartridge and particulate filter (NIOSH type N100 filter) may be worn up to 50 times the
exposure limit, or the maximum use concentration specified by the appropriate regulatory agency or
respirator supplier, whichever is lowest. If oil particles (e.g. lubricants, cutting fluids, glycerine, etc.) are
present, use a NIOSH type R or P particulate filter. For emergencies or instances where the exposure
levels are not known, use a full-facepiece positive-pressure, air-supplied respirator. WARNING: Air
purifying respirators do not protect workers in oxygen-deficient atmospheres. Where respirators are
required, you must have a written program covering the basic requirements in the OSHA respirator
standard. These include training, fit testing, medical approval, cleaning, maintenance, cartridge change
schedules, etc. See 29CFR1910.134 for details.
Skin Protection:
Wear impervious protective clothing, including boots, gloves, lab coat, apron or coveralls, as appropriate,
to prevent skin contact.
Eye Protection:
Use chemical safety goggles and/or a full face shield where splashing is possible. Maintain eye wash
fountain and quick-drench facilities in work area.
Appearance: Clear oily liquid.

Odor: Odorless.
Solubility: Miscible with water, liberates much heat.
Specific Gravity: 1.84
pH: 0.3
% Volatiles by volume @ 21C (70F): No information found.
Boiling Point: 290 C (ca. 554F)
Melting Point: 10.5 C
Vapor Density (Air=1): 3.4
Vapor Pressure (mm Hg): 1 @ 145.8 C (295F)
Evaporation Rate (BuAc=1): No information found.
Stability:
Stable under ordinary conditions of use and storage. Concentrated solutions react violently with water,
spattering and liberating heat.
Hazardous Decomposition Products:

Toxic fumes of oxides of sulfur when heated to decomposition. Will react with water or steam to produce
toxic and corrosive fumes. Reacts with carbonates to generate carbon dioxide gas, and with cyanides and
sulfides to form poisonous hydrogen cyanide and hydrogen sulfide respectively.
Hazardous Polymerization:
Will not occur.
Incompatibilities:
Water, potassium chlorate, potassium perchlorate, potassium permanganate, sodium, lithium, bases,
organic material, halogens, metal acetylides, oxides and hydrides, metals (yields hydrogen gas), strong
oxidizing and reducing agents and many other reactive substances.
Heat, moisture, incompatibles.
Toxicological Data:
Oral rat LD50: 2140 mg/kg; inhalation rat LC50: 510 mg/m3/2H; standard Draize, eye rabbit, 250 ug
(severe); investigated as a tumorigen, mutagen, reproductive effector.
Carcinogenicity:
Cancer Status: The International Agency for Research on Cancer (IARC) has classified "strong inorganic
acid mists containing sulfuric acid" as a known human carcinogen, (IARC category 1). This classification
applies only to mists containing sulfuric acid and not to sulfuric acid or sulfuric acid solutions.
--------\Cancer Lists\------------------------------------------------------
------------------------------------ ----- ----------- -------------
Sulfuric Acid (7664-93-9) No No None
Water (7732-18-5) No No None
Environmental Fate:
When released into the soil, this material may leach into groundwater. When released into the air, this
material may be removed from the atmosphere to a moderate extent by wet deposition. When released
into the air, this material may be removed from the atmosphere to a moderate extent by dry deposition.
Environmental Toxicity:
LC50 Flounder 100 to 330 mg/l/48 hr aerated water/Conditions of bioassay not specified; LC50 Shrimp
80 to 90 mg/l/48 hr aerated water /Conditions of bioassay not specified; LC50 Prawn 42.5 ppm/48 hr salt
water /Conditions of bioassay not specified.
This material may be toxic to aquatic life.
Whatever cannot be saved for recovery or recycling should be handled as hazardous waste and sent to a
RCRA approved incinerator or disposed in a RCRA approved waste facility. Processing, use or
contamination of this product may change the waste management options. State and local disposal
regulations may differ from federal disposal regulations. Dispose of container and unused contents in
accordance with federal, state and local requirements.

-----------------------
Proper Shipping Name: SULFURIC ACID (WITH MORE THAN 51% ACID)
Hazard Class: 8
UN/NA: UN1830
Packing Group: II

-----------------------------
Proper Shipping Name: SULFURIC ACID (WITH MORE THAN 51% ACID)
Hazard Class: 8
UN/NA: UN1830
Packing Group: II

----------------------------------------------- ---- --- ----- ---------
Sulfuric Acid (7664-93-9) Yes Yes Yes Yes
Water (7732-18-5) Yes Yes Yes Yes

--Canada--
----------------------------------------------- ----- --- ---- -----
Sulfuric Acid (7664-93-9) Yes Yes No Yes
Water (7732-18-5) Yes Yes No Yes

-SARA 302- ------SARA 313------
----------------------------------------- --- ----- ---- --------------
Sulfuric Acid (7664-93-9) 1000 1000 Yes No
Water (7732-18-5) No No No No

-RCRA- -TSCA-
----------------------------------------- ------ ------ ------
Sulfuric Acid (7664-93-9) 1000 No No
Water (7732-18-5) No No No
Chemical Weapons Convention: No TSCA 12(b): No CDTA: Yes

SARA 311/312: Acute: Yes Chronic: Yes Fire: No Pressure: No
Reactivity: Yes (Pure / Liquid)
Australian Hazchem Code: 2P

Poison Schedule: None allocated.
WHMIS:
This MSDS has been prepared according to the hazard criteria of the Controlled Products Regulations
(CPR) and the MSDS contains all of the information required by the CPR.
NFPA Ratings: Health: 3 Flammability: 0 Reactivity: 2 Other: Water reactive

POISON! DANGER! CORROSIVE. LIQUID AND MIST CAUSE SEVERE BURNS TO ALL BODY TISSUE.
MAY BE FATAL IF SWALLOWED OR CONTACTED WITH SKIN. HARMFUL IF INHALED. AFFECTS
TEETH. WATER REACTIVE. CANCER HAZARD. STRONG INORGANIC ACID MISTS CONTAINING
SULFURIC ACID CAN CAUSE CANCER. Risk of cancer depends on duration and level of exposure.
Label Precautions:
Do not get in eyes, on skin, or on clothing.
Do not breathe mist.
Do not contact with water.
Label First Aid:
In all cases call a physician immediately. In case of contact, immediately flush eyes or skin with plenty of
water for at least 15 minutes while removing contaminated clothing and shoes. Wash clothing before re-
use. Excess acid on skin can be neutralized with a 2% bicarbonate of soda solution. If swallowed, DO
NOT INDUCE VOMITING. Give large quantities of water. Never give anything by mouth to an
unconscious person. If inhaled, remove to fresh air. If not breathing, give artificial respiration. If
breathing is difficult, give oxygen.
DAHEJ PETROCHEMICAL
COMPLEX
ONGC Petro additions Ltd.

Dual Feed Cracker Unit EIL
SEZ, Dahej, Gujarat, India & Associated Units JOB NO. 6987
Page: 1 of 20
MATERIAL SAFETY DATA SHEETS ADSORBENT
PSA Unit 11-LZ-402
X 01 28.10.2009 FIRST ISSUE FU HO CA
Status Issue Date Reason for Issue / Remark Prepared Checked Approved OPaL/EIL
ENGINEERING Linde Proj. No.: 3110 A9NK

DIVISION Linde Project Code : DAHEJ
Samsung Proj. No.: SC 2252

Samsung Job Code : OPaL
Linde PSA Proj. No.:

ENGINEERING 2211 A9NK
Linde PSA Project
DIVISION DAHEJ-P
Code :
Contract No / PO No.: Item No.:
001 2UA1290 11-LZ-402
Contractor Doc. No.: Company Doc. No.:
&AK-11-S-DE 7121 6987-LEPC1-AK-11-PS-DE-7121
SAFETY DATA SHEET
(according to Directive 91/155/EEC as amended)
Product Name: Linde Adsorbent LA

Product Use: Adsorbent
Supplier:
Linde AG, Linde Engineering Division
Dr.-Carl-von-Linde-Str. 6-14
82049 Pullach
GERMANY
Tel: +49-89-7445-0
Fax: +49-89-7445-4908
Emergency Assistance - 24 hour Emergency Telephone Number: +49-89-7445-0
Synonyms: Activated alumina, Aluminium oxide, Alumina desiccant,

Adsorbent alumina
Appearance and Odour: Granules; odourless
Uses: Adsorbent, desiccant, catalyst support,
Classification/Overview:
Classified as hazardous according to Directive 1999/45/EC as amended.
When first wetted, the product can heat up.
Repeated or prolonged exposure may irritate eyes, skin and respiratory system.
Potential Health Effects:
• Eye Contact:
Dust and/or product may cause eye discomfort and/or irritation seen as tearing and reddening.
• Skin Contact:
Repeated or prolonged exposure may cause skin irritation.
• Inhalation:
Exposure to dust particles generated from this material may cause irritation of the respiratory tract.
• Ingestion:
Burns to moist body tissues can result if contact is prolonged.
____________________________________________________________________________________
Linde Adsorbent LA Issue 2
Page 1 of 7 EA080131
Potential Environmental Effects:
If used as directed, no hazardous effects to the environment are to be expected.
3. COMPOSITION / INFORMATION ON INGREDIENTS
Name CAS No. EINECS No. LD50 LC50 Conc.
Aluminium oxide 1344-28-1 215-691-60 unknown unknown < 97 %

Aluminium silicate 14504-95-1 238-509-7 unknown unknown < 0.2 %
Moisture (Loss of ignition) 7732-18-5 none none 3–5%

Eye contact:
Flush immediately with plenty of water for at least 15 minutes. If eye irritation persists, consult a physician.
Skin contact:
Wash off with soap and plenty of water. If skin irritation persists, call a physician.
After inhalation:
Remove the victim into fresh air. If symptoms persist, call a physician.
After ingestion:
Drink at least 2 glasses of water. Obtain medical attention. Never give anything by mouth to an unconscious
person.
Additional information:
This product is a desiccant and generates heat as it adsorbs water. Symptomatic treatment is advised. The
used product can contain material of a hazardous nature. Identify that material and treat symptomatically.

Non-combustible. Use extinguishing media for surrounding fire.
Unsuitable extinguishing media:

N.A.
Special exposure hazards:

The product itself does not burn. The used product can retain material of a hazardous nature. Identify that
material and inform the fire fighters.

In the case of respirable dust and/or fumes, use self-contained breathing apparatus and dust impervious
protective suit.
____________________________________________________________________________________
Personal protection:
See Section 8.
No special environmental precautions required.
Clean-up:
Sweep, shovel or vacuum spilled product into appropriate containers (do not use a vacuum if material has
contacted a hydrocarbon material). Pick-up and arrange disposal without creating dust. Never use spilled
product.
Spilled product should be disposed in accordance with all applicable government regulations.

Handling:
Handle and open container with care. Avoid formation of dust particles. Avoid contact with skin and eyes.
Provide an electrical ground connection during loading and transfer operations to avoid static discharge in an
explosive atmosphere and to prevent persons handling the product from receiving static shocks.
Storage:
Store in original container. Keep in a dry place.
8. EXPOSURE CONTROLS AND PERSONAL PROTECTION

Occupational exposure controls:
Ensure adequate ventilation, especially in confined areas.
Personal protection equipment:

• Eye protection: Safety glasses or goggles.
• Hand protection: Protective gloves.

Type of material: Dustproof (Vinyl-PE-PVC-Nitril-Latex)
Protection Category: Category 1 (EN420)
Breakthrough time: N.A.
• Skin and body protection: Lightweight protective clothing.
• Respiratory protection: In case of insufficient ventilation wear suitable respiratory equipment:

Disposable filtering half mask Class FFP3 (EN149).
Half mask with a particle filter P3 (EN143).
Environmental exposure controls:

Handle in accordance with local environmental regulations and good industrial practices.
____________________________________________________________________________________
Exposure limits:
ACGIH (TLV) OSHA (PEL)

TWA STEL TWA CEILING
Aluminium oxide (total dust) 10 mg/m³ None 15 mg/m³ None

Respirable dust None None 5 mg/m³ None
(ACGIH = American Conference of Governmental Industrial Hygienists; TLV = Threshold Limit Value; OSHA = Occupational
Safety and Health Administration [USA]; PEL = Permissible Exposure Limit; TWA = Time-Weighted Average; STEL = Short
Term Exposure Limit; Ceiling = Ceiling Value)
Colour: White Odour Threshold: Not applicable

Form: Beads Flashpoint: Not applicable
pH at 20°C: 9.4 – 10.1 10% in water Autoignition Temperature: Not applicable
Boiling Point: Not applicable Lower Flammable Limit: Not applicable
Melting Point: 2050°C Higher Flammable Limit: Not applicable
Vapour Pressure: Not applicable Explosive Properties: Not applicable
Vapour Density: Not applicable NFPA Fire Code: Not applicable
Evaporation Rate: Not applicable Oxidizing Properties: Not applicable
3
Bulk Density at 20°C 0.6 – 0.8 g/cm Partition Coefficient Not applicable
Water Solubility: Insoluble (N-Octanol/Water):

Stability:
Stable at normal conditions.

No decomposition if used as directed. Hydrocarbons and other materials that contact the product during
normal use can be retained on the product. It is reasonable to expect that decomposition products will come
from these retained materials of use.
Conditions/Materials to avoid:
Sudden contact with high concentrations of chemicals having high heats of adsorption such as olefins, HCl,
etc. When first wetted, the product can heat up to the boiling point of water. Flood with water to cool material.

PRODUCT TOXICITY
Acute toxicity: non toxic
LOCAL EFFECTS
- Eye contact: Possible temporary irritation due to dust.
Dehydrating/desiccating effect.
____________________________________________________________________________________
Exothermic reaction with adsorbable products
(water, olefins, …), risk of superficial burns.
- Mucous membrane contact: Possible temporary irritation due to dust.
Carcinogenicity / None of the ingredients present at concentrations equal to or greater

Mutagenicity / Reproductive than 0.1 % are listed as a carcinogen or potential carcinogen by IARC,
Toxicity: NPT or OSHA.
[IARC = International Agency for Research on Cancer; NPT = National Toxicology
Program (USA); OSHA = Occupational Safety and Health Administration (USA)]
Supplementary Information:
Activated alumina may adsorb certain gases and liquids. While alumina itself is principally inert, it may exhibit
properties of the adsorbed material.

Ecotoxicity: This product is not hazardous to the environment.
Product must not be released into the environment if
dangerous substances are adsorbed onto the product.
Other information: Insoluble in aqueous solution, the product can be separated
by filtration or sedimentation.

Provisions relating to waste:
EC Directives 75/442/EEC; 91/689/EEC as amended.
EC Regulation No. 259/93 as amended.
Disposal information:
Can be landfilled after chemical and physical treatment, when in compliance with the local regulations. Store
containers and offer for recycling of material according to the local regulations. Contact waste disposal
services. Materials of a hazardous nature that contact the product during normal use may be retained on this
product. The user of the product must identify the hazards associated with the retained material in order to
assess the waste disposal options.
Uncontaminated product: dispose of at an approved waste disposal site.

Product is not subjected to international RID-ADR, IMO-IMDG and OACI-IATA regulations.
____________________________________________________________________________________
WHMIS Classification (Canada): Not controlled
European Union Classification: Not classified
Warning Symbol: None
Warning Word: None
Risk Phrases: None
Safety Phrases: None
USA Regulations:
Section 313 Supplier Notification
This product does not contain any chemicals in concentrations subject to the reporting requirements of
section 313 of the Emergency Planning and Community-Right-To-Know Act of 1986 (Title III of SARA) and of
40 CFR 372.
TSCA – DSL [USA - Canada]

This substance or all the ingredients of this product are on the Domestic Substances List (DSL – Canadian
Environmental Protection Act [Canada] as well as on the Chemical Substances Inventory of the Toxic
Substances Control Act (TSCA Inventory [USA]). The presence on these lists does not require any legal
reporting.

Recommended uses: Petroleum industry
Gas purification & separation
Liquid purification & separation
National Fire Protection Agency (NFPA) codes – (Health, flammability, reactivity): 0, 0, 0
Hazardous Material Information System (HMIS) – (Health, flammability, reactivity): 0, 0, 0
Abbreviations:
N.A. Not applicable
EC European Community
WHMIS = Working hazardous material information system
CAS number = Chemical Abstracts Service Registry Number
LD50 = Lethal dose 50 %
LC50 = Lethal concentration 50 %
EU = European Union.
____________________________________________________________________________________
The data and recommendations presented in this data sheet concerning the use of our product and the materials contained therein are
believed to be accurate and are based on information which is considered reliable as of the date hereof. However, the customer should
determine the suitability of such materials for his purpose before adopting them on a commercial scale. Since the use of our products by
others is beyond our control, no guarantee, express or implied, is made and no responsibility assumed for the use of this material or the
results to be obtained therefrom. Information on this form is furnished for the purpose of compliance with Government Health and Safety
Regulations and shall not be used for any other purposes.
Moreover, the recommendations contained in this data sheet are not to be construed as a license to operate under, or a
recommendation to infringe, any existing patents, nor should they be confused with state, municipal or insurance requirements, or with
national safety codes.
Date of the Previous Revisions: February 10, 2005
Reason for Revision: REACH
EC Safety Data Sheet

according to 2001/58/EC and 91/155/EEC
Date of issue: January 31, 2008
____________________________________________________________________________________
SAFETY DATA SHEET
Product Name: Linde Adsorbent LAC

Supplier:
82049 Pullach
GERMANY
Tel: +49-89-7445-0
Fax: +49-89-7445-4908
Synonyms: Activated Carbon
Appearance and Odour: Extrudates, granules; odourless.
Uses: Adsorbent.
Reaction with strong oxidizing agents causes exothermic reaction and the product can heat up. Repeated or
prolonged exposure may irritate eyes, skin and respiratory system.
• Eye Contact:
• Skin Contact:
• Inhalation:
Exposure to dust particles generated from this material may cause irritation of the respiratory tract.
• Ingestion:

____________________________________________________________________________________
Linde Adsorbent LAC Issue 2
Name CAS–No. EINECS-No. Conc.
Activated Carbon 7440-44-0 231-153-3 < 97 %

Moisture (Loss of ignition) 7732-18-5 3–7%

Eye contact:
Skin contact:
After inhalation:
After ingestion:
person.
The used product can contain material of a hazardous nature. Identify that material and treat
symptomatically.

Prevention:
Keep away from sources of heat or naked flames

Water, carbon dioxide. Use extinguishing media for surrounding fire.

The product itself does burn. The used product can retain material of a hazardous nature. Identify that

protective suit.

See Section 8.
The used product, however, can contain material of a hazardous nature.
____________________________________________________________________________________
Clean-up:
product.
Spilled product should be disposed of in accordance with all applicable government regulations.
Instructions for removal:

See Section 13, Disposal considerations

Handling:
Activated carbon depletes oxygen from air and, therefore, dangerously low levels of oxygen may be
encountered. Whenever workers enter a vessel containing activated carbon, the vessel's oxygen content
should be determined and work procedures for potentially low oxygen areas be followed. Appropriate
protective equipment should be worn.
Storage:
Keep separated from oxidizing substances, unsaturated oils, metal salts, sources of direct heat or naked
flames



Protection Category: Category 1 (EN 420)

Disposable filtering half mask Class FFP3 (EN 149).
Half mask with a particle filter P3 (EN 143).
____________________________________________________________________________________
Colour: black Odour Threshold: not applicable

Form: granules or extrudates Flashpoint: not applicable
pH at 20°C: 9 – 11 (suspension) Autoignition Temperature: 300-375°C
Boiling Point: not applicable Lower Flammable Limit: not applicable
Melting Point: not applicable Higher Flammable Limit: not applicable
Vapour Pressure: not applicable Explosive Properties: not applicable
Vapour Density: not applicable NFPA Fire Code: not applicable
Evaporation Rate: not applicable Oxidizing Properties: not applicable
3
Bulk Density at 20°C 0.3 – 0.7 g/cm Partition Coefficient not applicable
Water Solubility: insoluble (N-Octanol/Water):

Stability:

etc.
Reaction with strong oxidizing agents causes exothermic reaction.

PRODUCT TOXICITY
LOCAL EFFECTS
Exothermic reaction with adsorbable products (hydrocarbons,
carbon dioxide, …), risk of superficial burns.
(hydrocarbons, carbon dioxide, , …) risk of superficial burns.
____________________________________________________________________________________
Carcinogenicity / None of the ingredients present at concentrations equal to or greater
Mutagenicity / Reproductive than 0.1 % are listed as a carcinogen or potential carcinogen by IARC,
Toxicity: NPT or OSHA.
[IARC = International Agency for Research on Cancer; NPT = National Toxicology
Program (USA); OSHA = Occupational Safety and Health Administration (USA)]
Supplementary Information:
Activated carbon may adsorb certain gases and liquids. While activated carbon itself is principally inert, it may
exhibit properties of the adsorbed material.

BOD 1 to 2 mg O2 / gram carbon
COD 2000 mg O2 / gram carbon

Removal of product:
Vacuumup spilled product and flush remaining product with plenty of water (additional personal protection
articles: see section 8)

____________________________________________________________________________________
WHMIS Classification (Canada): Not controlled
European Union Classification: Not classified
Warning Symbol: None
Warning Word: None
Risk Phrases: None
Safety Phrases: None
USA Regulations:
Section 313 Supplier Notification
This product does not contain any chemicals in concentrations subject to the reporting requirements of
section 313 of the Emergency Planning and Community-Right-To-Know Act of 1986 (Title III of SARA) and of
40 CFR 372.
TSCA – DSL [USA - Canada]

This substance or all the ingredients of this product are on the Domestic Substances List (DSL – Canadian
Environmental Protection Act [Canada] as well as on the Chemical Substances Inventory of the Toxic
Substances Control Act (TSCA Inventory [USA]). The presence on these lists does not require any legal
reporting.

National Fire Protection Agency (NFPA) codes – (Health, flammability, reactivity): 0, 0, 0
Hazardous Material Information System (HMIS) – (Health, flammability, reactivity): 0, 0, 0
Abbreviations:
N.A. Not applicable
WHMIS = Working hazardous material information system
CAS number = Chemical Abstracts Service Registry Number
EU = European Union.
Date of the Previous Revisions: February 10, 2005
Reason for Revision: REACH

Date of issue: January 31, 2008
____________________________________________________________________________________
SAFETY DATA SHEET
Product Name: Linde Adsorbent LMS

Supplier:
82049 Pullach
GERMANY
Tel: +49-89-7445-0
Fax: +49-89-7445-4908
Synonyms: Molecular Sieves, Zeolite,
Appearance and Odour: Extrudates, granules; odourless.
Uses: Adsorbent
When first wetted, the product can heat up to the boiling point of water. Flood with water to cool material.
Repeated or prolonged exposure may irritate eyes, skin and respiratory system.
• Eye Contact:
• Skin Contact:
• Inhalation:
• Exposure to dust particles generated from this material may cause irritation of the respiratory tract.
Ingestion:

____________________________________________________________________________________
Linde Adsorbent LMS Issue 3
PREPARATION
Chemical nature: Zeolites
CAS No: 1318-02-1 EINECS No: 215-283-8
Mineral binder
CAS No: 999999-99-4 EINECS No: 310-127-6
Quartz
CAS No: 14808-60-7 EINECS No: 238-878-4
Aluminosilicate
CAS No: 142844-00-6 R-phrases: 38
Components:
Clay: 1332-58-7 alumina: 1344-28-1
Amorphous silica: 7631-86-9 sodium oxide: 1313-59-3
Potassium oxide: 12136-45-7 calcium oxide: 1305-78-8
Silver oxide: 1301-96-8 rare earth oxides: 68188-83-0
Barium oxide: 1304-28-5 strontium oxide: 1314-11-0
Lithium oxide: 12057-24-8
Note:
- Full text of R-phrases is given in Section 16.

Eye contact:
Skin contact:
After inhalation:
After ingestion:
person.
This product is a desiccant and generates heat as it adsorbs water. Symptomatic treatment is advised. The
used product can contain material of a hazardous nature. Identify that material and treat symptomatically.

Non-combustible. Use extinguishing media for surrounding fire.
Unsuitable extinguishing media: N.A.

____________________________________________________________________________________
The product itself does not burn. The used product can retain material of a hazardous nature. Identify that

protective suit.

See Section 8.
Clean-up:
product.
Spilled product should be disposed of in accordance with all applicable government regulations.

Handling:
Zeolite depletes oxygen from air and, therefore, dangerously low levels of oxygen may be encountered.
Whenever workers enter a vessel containing zeolite, the vessel's oxygen content should be determined and
work procedures for potentially low oxygen areas be followed. Appropriate protective equipment should be
worn.
Storage:



Protection Category: Category 1 (EN420)
____________________________________________________________________________________
Disposable filtering half mask Class FFP3 (EN149).
Half mask with a particle filter P3 (EN143).
Environmental exposure controls:

Handle in accordance with local environmental regulations and good industrial practices.

These data do not represent technical or sales specifications.
Color: slight brown or white pH: 8 - 11 (AS)
Form: beads or pellets Viscosity: N.A.
Boiling point/range: N.A. Relative density/Specific Gravity: N.A.
Melting point/range: > 1600°C Vapor pressure: N.A.
Water solubility: insoluble Odor: None
Solubility: N.A. Flash point: N.A.
Bulk density: 600-800 kg/m3 Vapor density: N.A.

Stability:

etc. When first wetted, the product can heat up to the boiling point of water. Flood with water to cool material.

PRODUCT TOXICITY
LOCAL EFFECTS
____________________________________________________________________________________
(water, olefins, …) risk of superficial burns.




The product is classified and labelled in accordance with the EC Directives 67/548/EEC and
1999/45/EC, as amended.
Symbol(s): none
Contains: Aluminosilicate

R-phrases in section 2
R38 Irritating to skin
____________________________________________________________________________________
Abbreviations:
N.A. Not applicable
AS Aqueous slurry
Date of the Previous Revisions: 25.10.2004, 31.01.2008
Reason for Revision: REACH, sections 2, 3,15

Date of issue: June 27, 2008
____________________________________________________________________________________
Gasoline, pyrolysis, hydrogenated; Low boiling point naphtha unspecified Seite 1 von 5
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"Trusted sites".
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IDENTIFICATION
CHARACTERISATION
PHYSICAL AND CHEMICAL PROPERTIES
REGULATIONS
REFERENCES
GESTIS Substance Database
Gasoline, pyrolysis, hydrogenated; Low boiling

point naphtha unspecified
IDENTIFICATION
Gasoline, pyrolysis, hydrogenated;

Low boiling point naphtha unspecified
ZVG number: 184405

CAS number: 94114-03-1
INDEX number: 649-389-00-4
EC number: 302-639-3
The substance is listed due to applicable laws. Therefore just the general information of those is
considered.
CHARACTERISATION
SUBSTANCE GROUP CODE
140000 Hydrocarbons
CHEMICAL CHARACTERISATION
The distillation fraction form the hydrogenation of pyrolysis gasoline.
http://gestis-en.itrust.de/nxt/gateway.dll/gestis_en%2F184405.xml?f=templates&fn=prin... 14.12.12
PHYSICAL AND CHEMICAL PROPERTIES

BOILING POINT
Boiling Point: 20 ... 200 °C
REGULATIONS
GHS-CLASSIFICATION ACCORDING TO REGULATION (EC) 1272/2008
Classification:
Carcinogenicity, Category 1B; H350
Germ cell mutagenicity, Category 1B; H340
Aspiration hazard, Category 1; H304
Signal Word: "Danger"
Hazard Statement - H-phrases:

H350: May cause cancer (state route of exposure if it is conclusively proven that no other routes of
exposure cause the hazard).
H340: May cause genetic defects (state route of exposure if is conclusively proven that no other
routes of exposure cause the hazard).
H304: May be fatal if swallowed and enters airways.
Note P
The classification as a carcinogen or mutagen need not apply if it can be shown that the substance
contains less than 0,1 % w/w benzene (EINECS No 200-753-7). When the substance is not
classified as a carcinogen at least the precautionary statements (P102)-P260-P262-P301 + P310-
P331 (Table 3.1) or the S-phrases (2)-23-24-62 (Table 3.2) shall apply. This note applies only to
certain complex oil-derived substances in Part 3 of this Directive.
Source: 07501
GHS-CLASSIFICATION OF MIXTURES
The classification of mixtures containing this substance results from Annex 1 of Regulation (EC)
1272/2008.
Source: 07501
EUROPEAN CLASSIFICATION
Carc.Cat.2; R45
Muta.Cat.2; R46
Xn; R65
Risk phrases (R-phrases):

R 45 May cause cancer
R 46 May cause heritable genetic damage
R 65 Harmful: may cause lung damage if swallowed
Note P
The classification as a carcinogen or mutagen need not apply if it can be shown that the substance
contains less than 0,1 % w/w benzene (EINECS No 200-753-7). When the substance is not
classified as a carcinogen at least the precautionary statements (P102)-P260-P262-P301+P310-P331
(Table 3.1) or the S-phrases (2)-23-24-62 (Table 3.2) shall apply. This note applies only to certain
complex oil-derived substances in Part 3 of this Directive.
EU classification according to GHS regulation, appendix VI, table 3.2
Source: 07501
CLASSIFICATION OF MIXTURES
The classification of preparations/mixtures containing this substance results from the directive on
dangerous preparations (1999/45/EC).
Note 4
Preparations containing these substances have to be classified as harmful according to R65 if they
meet the criteria in section 3.2.3 in Annex VI.
Source: 07501
TECHNICAL INSTRUCTIONS ON AIR QUALITY CONTROL (TA LUFT)
Chapter 5.2.7.1.1 Carcinogenic Substances

The substance must be assigned to the class (I, II or III) whose substances have the nearest potency.
We can not accomplish this evaluation due to insufficiency of data.
TRGS 900 - GERMAN OCCUPATIONAL EXPOSURE LIMIT VALUES
Scope:
mixtures of hydrocarbons, used as solvent (solvent- hydrocarbons), free from additives
Source: 05350
1500 mg/m³
Scope:
fractions (RCP-group): C5-C8 aliphates
Source: 05350
600 mg/m³
Scope:
fractions (RCP-group): C9-C15 aliphates
Source: 05350
200 mg/m³
Scope:
fractions (RCP-group): C7-C8 aromatic hydrocarbons
Source: 05350
100 mg/m³
Scope:
fractions (RCP-group): C9-C15 aromatic hydrocarbons
Source: 05350
Peak limitation: Excursion factor 2

Duration 15 min, mean; 4 times per shift; interval 1 hour
Category II - Substances with systemic effects
Source: AGS
The calculation of the threshold limit value for hydrocarbons mixtures follows the RCP-Method
(RCP – reciprocal calculation procedure).
Source: 05350
FURTHER REGULATIONS
TRGS 200
Einstufung und Kennzeichnung von Stoffen, Zubereitungen und Erzeugnissen; Ausgabe Oktober
2011
TRGS 201
Einstufung und Kennzeichnung bei Tätigkeiten mit Gefahrstoffen; Ausgabe Oktober 2011
TRGS 400
Gefährdungsbeurteilung für Tätigkeiten mit Gefahrstoffen; Ausgabe Dezember 2010; geändert und
ergänzt September 2012
TRGS 555
Betriebsanweisung und Information der Beschäftigten; Ausgabe Februar 2008; geändert und
ergänzt Juli 2009
TRGS 600
Substitution; Ausgabe August 2008
TRGS 500
Schutzmaßnahmen; Ausgabe Januar 2008, ergänzt Mai 2008
TRGS 510
Lagerung von Gefahrstoffen in ortsbeweglichen Behältern; Ausgabe Oktober 2010
REFERENCES
Quelle: 05350
TRGS 900 "Arbeitsplatzgrenzwerte" Ausgabe Januar 2006, zuletzt geändert und ergänzt : GMBl
2012 (Nr. 40)
Quelle: 07500
Verordnung (EG) Nr. 1272/2008 des Europäischen Parlaments und des Rates vom 16. Dezember
2008 über die Einstufung, Kennzeichnung und Verpackung von Stoffen und Gemischen, zur
Änderung und Aufhebung der Richtlinien 67/548/EWG und 1999/45/EG und zur Änderung der
Verordnung (EG) Nr.1907/2006 (EG-GHS-Verordnung)
Quelle: 07501
Verordnung (EG) Nr. 790/2009 der Kommission vom 10. August 2009 zur Änderung der
Verordnung (EG) Nr. 1272/2008 des Europäischen Parlaments und des Rates über die Einstufung,
Kennzeichnung und Verpackung von Stoffen und Gemischen zwecks Anpassung an den
technischen und wissenschaftlichen Fortschritt (EG-GHS-Verordnung, 1. Änderung)
Quelle: 07504
Erste Allgemeine Verwaltungsvorschrift zum Bundesimmissionsschutzgesetz (Technische
Anleitung zur Reinhaltung der Luft - TA Luft) vom 24.07.2002, GMBl. 2002, Heft 25 - 29, S. 511 -
605.
Quelle: 99999
Angabe des Bearbeiters
This substance datasheet was created with greatest care. Nevertheless no liability irrespective of
legal basis can be accepted.

Material Safety Data Sheets: Dahej Petrochemical Complex Dual Feed Cracker Unit & Associated Units

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Material Safety Data Sheets: Dahej Petrochemical Complex Dual Feed Cracker Unit & Associated Units

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DAHEJ PETROCHEMICAL COMPLEX

Dual Feed Cracker Unit

Material Safety Data Sheets

X 05 21.012013 Var. MSDS added Team SE/LE CM Yun A. Garayhi

ENGINEERING Linde Proj. No.: 3110 A9NK

Samsung Proj. No.: SC 2252

Contract No / PO No.: Item No.:

Contractor Doc. No.: Company Doc. No.:

Intellectual property rights reserved - refer to protection notice ISO 16016

Nalco AquaMax EC1405A (Corrosion Inhibitor I and III) 4

Intellectual property rights reserved - refer to protection notice ISO 16016

TBC 85 wt-% 248

Intellectual property rights reserved - refer to protection notice ISO 16016

EMERGENCY TELEPHONE NUMBER(S)

1. IDENTIFICATION OF THE SUBSTANCE/PREPARATION AND OF THE

APPLICATION : CORROSION INHIBITOR

COMPANY IDENTIFICATION : NALCO EUROPE B.V.

Date issued : 24.04.2009

COMPANY CONTACT TELEPHONE NUMBERS.

EMERGENCY TELEPHONE NUMBER(S)

HUMAN HEALTH HAZARDS - ACUTE :

PHYSICAL AND CHEMICAL HAZARDS :

Hazardous Substance(s) EINECS / CAS NO SYMBOL R-PHRASES / % (w/w)

Refer to Section 16 for descriptions of relevant risk phrases and Notas.

4. FIRST AID MEASURES

EMERGENCY TELEPHONE NUMBER(S)

5. FIRE FIGHTING MEASURES

FLASH POINT : 89 °C PMCC

FIRE AND EXPLOSION HAZARD :

SPECIAL PROTECTIVE EQUIPMENT FOR FIRE FIGHTING :

6. ACCIDENTAL RELEASE MEASURES

METHODS FOR CLEANING UP :

7. HANDLING AND STORAGE

EMERGENCY TELEPHONE NUMBER(S)

SUITABLE CONSTRUCTION MATERIAL :

UNSUITABLE CONSTRUCTION MATERIAL :

8. EXPOSURE CONTROLS/PERSONAL PROTECTION

OCCUPATIONAL EXPOSURE LIMITS

AIHA/WEEL Methoxypropylamine TWA 5

AUSTRIA Monoethanolamine MAK 1 2.5

BELGIUM Monoethanolamine TWA 1 2.5

BULGARIA Monoethanolamine TWA 8

DENMARK Monoethanolamine GV 1 2.5

EMERGENCY TELEPHONE NUMBER(S)

FINLAND Monoethanolamine HTP 8H 1 2.5

FRANCE Monoethanolamine VME 1 2.5

GERMANY Monoethanolamine AGW 2 5.1

IRELAND Monoethanolamine TWA 3 8

ITALY Monoethanolamine TWA 1 2.5

NETHERLANDS Monoethanolamine TGG 2.5

NORWAY Monoethanolamine ADM. NORM 3 8

SPAIN Monoethanolamine VLA-ED 1 2.5

SWEDEN Monoethanolamine NGV 3 8

EMERGENCY TELEPHONE NUMBER(S)

SWITZERLAND Monoethanolamine TWA 2 5

UNITED KINGDOM Monoethanolamine TWA 1 2.5

POLAND Monoethanolamine MAC-NDS 2.5

HUNGARY Monoethanolamine ÁK 2.5

LATVIA Monoethanolamine TWA 0.5

CZECH REPUBLIC Monoethanolamine PEL 2.5

CROATIA Monoethanolamine MDK 3 8

ROMANIA Monoethanolamine TWA 1 2.5

RUSSIAN Monoethanolamine (Vapor and aerosol.) CEIL 0.5