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Volume 4
Worksheet 1
What is Oxidation and Reduction?
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1. What are the two processes that occur during a redox reaction?
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5. Identify the oxidation number of the elements in the following compounds.
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7. In the following reaction, identify which chemical in the reactants is oxidized and which is
reduced.
Si (s) + 2 F2 (g) à SiF4 (s)
8. In the following reaction, identify which chemical in the reactants is oxidized and which is
reduced.
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10. Identify the oxidizing and reducing agents in the following reaction.
4 Fe (s) + 3 O2 (g) à 2 Fe2O3 (s)
11. Challenge: Identify the oxidizing and reducing agents in the following reaction.
12. Which substance is reduced, and which is oxidized in the following reaction?
Cu (s) + 2 Ag+ (aq) à Cu2+ (s) + 2 Ag (s)
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Answer Key
1. What are the two processes that occur during a redox reaction?
The name “redox” gains its name from the two processes that occur: reduction and
oxidation. Reduction occurs when an atom gains electrons, and oxidation is when an
atom loses electrons.
Correct answer: Reduction and oxidation.
Redox processes involve the transfer of electrons from one atom to another.
During reduction, an atom gains an electron. The electron is obtained from the atom
that has been oxidized.
The charge on any metal in its natural state as a solid is always 0, so the charge
on Al in the reactants is 0, written as Al0. Oxygen is in a similar situation. Since it
is bonded to itself, it has a charge of 0, written as O0.
In the products, break apart Al2O3 into its two ions to determine their oxidation
numbers.
Al goes from a neutral state (Al0) to a positive state (Al3+), and it has lost three
electrons to do this.
Continuing from the explanation in part a, oxygen has gone from a neutral state
(O0) to a negative state (O2-), which means that it has gained two electrons.
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7. In the following reaction, identify which atom in the reactants is oxidized and which is
reduced.
Si (s) + 2 F2 (g) à SiF4 (s)
Since Si is in its elemental form (a solid), it is neutral (has no charge), so it can be written
as Si0.
Similarly, F2 is in its elemental form (a diatomic molecule) and also has no charge (F0).
Break apart SiF4 to determine the charges on each of the elements. We know that F
always has a 1- charge, so it can be written as F-. There are four F, so that means it
contributes a total of 4- to the SiF4.
To form a neutral molecule, that means the Si needs to have a 4+ charge to balance the
4 negative charges of the F-.
Si went from: Si0 to Si4+. Since it became more positive, it lost electrons, meaning it was
oxidized.
F went from F0 to F-, meaning it gained electrons to become more negative. When an
atom gains electrons, the process is called reduction.
Correct answer: Oxidized: Si0 to Si4+
Reduced: F0 to F1-
8. In the following reaction, identify which chemical in the reactants is oxidized and which is
reduced.
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9. Identify the oxidizing and reducing agents in the following reaction.
Mg (s) + 2 HCl (g) à MgCl2 (s) + H2 (g)
Mg goes from a neutral state (Mg0) to a more positive state (Mg2+), so it has lost two
electrons and been oxidized. This means it is the reducing agent.
H has gone from H+ to H0, which means it has gained an electron (going from positive to
neutral requires one electron). This means it has been reduced and is the oxidizing
agent.
10. Identify the oxidizing and reducing agents in the following reaction.
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11. Challenge: Identify the oxidizing and reducing agents in the following reaction.
So, we need to determine which atoms changed their oxidation states in the reaction.
Na went from Na0 to Na+, H went from H+ to H0, and O stayed O2- the whole reaction.
H has gone from H+ to H0 (in H2), which means it has gained an electron and been
reduced.
Correct answer: Oxidizing agent: H1+ was reduced to H0 (in H2)
Reducing agent: Na0 was oxidized to Na1+
12. Which substance is reduced, and which is oxidized in the following reaction?
Cu (s) + 2 Ag+ (aq) à Cu2+ (s) + 2 Ag (s)
Ag+ has been transformed into Ag0. By going from a positive to a neutral state, it has
gained an electron and been reduced.
Cu0 has been transformed into Cu2+. Since it has gone from a neutral state to a positive
state, it has lost two electrons and been oxidized.
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