Grotanol 3025 ZSDB - P - ALL EN

SAFETY DATA SHEET
according to Regulation (EC) No. 1907/2006
grotanol® 3025 No Change Service!

Version 05.00 Revision Date 28.01.2014 Print Date 15.07.2014
SECTION 1: Identification of the substance/mixture and of the company/undertaking
1.1 Product identifier

Trade name : grotanol® 3025
1.2 Relevant identified uses of the substance or mixture and uses advised against
Use of the Sub- : Cleaning agent
stance/Mixture
1.3 Details of the supplier of the safety data sheet

Producer/Supplier : Schülke & Mayr GmbH
Robert-Koch-Str. 2
22851 Norderstedt
Germany
Telephone: +4940521000
Telefax: +494052100318
mail@schuelke.com
www.schuelke.com
Contact person : SAI/AT +49 40 52100 100 or S&M UK +44 114 254 3500
sai-at@schuelke.com
1.4 Emergency telephone number

Emergency telephone num- : UK Poisons Emergency number: 0870 600 6266
ber
Emergency telephone num- : +49 (0)40 / 52 100 –0
ber
SECTION 2: Hazards identification
2.1 Classification of the substance or mixture

Classification
Acute toxicity , Category 4 H332: Harmful if inhaled.
Skin sensitisation , Category 1 H317: May cause an allergic skin reaction.
Serious eye damage , Category 1 H318: Causes serious eye damage.
Respiratory sensitisation , Category 1 H334: May cause allergy or asthma symptoms or
breathing difficulties if inhaled.
Chronic aquatic toxicity , Category 2 H411: Toxic to aquatic life with long lasting effects.
Classification (67/548/EEC, 1999/45/EC)
Harmful R20: Harmful by inhalation.
Dangerous for the environment R37: Irritating to respiratory system.
R41: Risk of serious damage to eyes.
R42/43: May cause sensitisation by inhalation and
skin contact.
R51/53: Toxic to aquatic organisms, may cause
long-term adverse effects in the aquatic environ-
ment.
2.2 Label elements
Z11486 ZSDB_P_ALL EN Page 1/12

SAFETY DATA SHEET

Labelling
Hazard pictograms :
Signal word : Danger
Hazard statements : H332 Harmful if inhaled.

H317 May cause an allergic skin reaction.
H318 Causes serious eye damage.
H334 May cause allergy or asthma symptoms or
breathing difficulties if inhaled.
H411 Toxic to aquatic life with long lasting effects.
Precautionary statements : P261 Avoid breathing vapours.

P273 Avoid release to the environment.
P280 Wear protective gloves/ eye protection/ face
protection.
P302+P352 IF ON SKIN: Wash with plenty of soap and
water.
P301+P330 IF SWALLOWED: rinse mouth.
P304+P341 IF INHALED: If breathing is difficult, remove
victim to fresh air and keep at rest in a posi-
tion comfortable for breathing.
P305+P351+P338 IF IN EYES: Rinse cautiously with water for
several minutes. Remove contact lenses, if
present and easy to do. Continue rinsing.
P310 Immediately call a POISON CENTER or
doctor/ physician.
Hazardous components which must be listed on the label:

111-30-8 Glutaral
55965-84-9 Mixture of 5-chloro-2-methyl-2H-isothiazol-3-one (CAS 26172-55-4) and
2-methyl-2H-isothiazol-3-one (CAS 2682-20-4)
Special labelling of certain : Labelling according to Regulation (EC) No. 648/2004: (5 -

mixtures 15% non-ionic surfactants,) Methylchloroisothiazolinone
Further information : Use biocides safely. Always read the label and product infor-
mation before use.
2.3 Other hazards

No information available.
: This substance is not considered to be very persistent nor
very bioaccumulating (vPvB).
SECTION 3: Composition/information on ingredients

3.2 Mixtures
Chemical nature : Solution of the following substances with harmless additives.
SAFETY DATA SHEET

Hazardous components
Chemical Name Index-Number Classification Classification Concentration
CAS-No. (67/548/EEC) () [%]
EC-No.
Registration
number
Glutaral 605-022-00-X T; R23/25 Met. Corr. 1; H290 10 %
111-30-8 C; R34 Acute Tox. 3; H301
203-856-5 Xn; R42/43 Acute Tox. 3; H331
01- N; R50 Skin Corr. 1B;
2119455549- H314
26-XXXX Resp. Sens. 1;
H334
Skin Sens. 1; H317
STOT SE 3; H335
Aquatic Acute 1;
H400
Aquatic Chronic 2;
H411
Alkylpolyethoxy- 68603-25-8 Xn; R22 Acute Tox. 4; H302 5 - 15 %

polypropoxyether Polymer Xi; R36 Eye Irrit. 2; H319
Mixture of 5-chloro-2- 613-167-00-5 T; R23/24/25 Acute Tox. 3; H301 0,1 - 0,3 %

methyl-2H-isothiazol-3- 55965-84-9 C; R34 Acute Tox. 3; H311
one (CAS 26172-55-4) Xi; R43 Acute Tox. 3; H331
and 2-methyl-2H- N; R50/53 Skin Corr. 1B;
isothiazol-3-one (CAS H314
2682-20-4) Skin Sens. 1; H317
Aquatic Acute 1;
H400
Aquatic Chronic 1;
H410
M-Factor 10
For the full text of the R-phrases mentioned in this Section, see Section 16.
For the full text of the H-Statements mentioned in this Section, see Section 16.
SECTION 4: First aid measures
4.1 Description of first aid measures

General advice : Take off all contaminated clothing immediately.
If inhaled : Move the victim to fresh air and keep him calm.
No artificial respiration, mouth-to-mouth or mouth to nose. Use
suitable instruments/apparatus.
If unconscious place in recovery position and seek medical
advice.
If symptoms persist, call a physician.
In case of skin contact : Wash off immediately with plenty of water.
In case of eye contact : In the case of contact with eyes, rinse immediately with plenty
of water and seek medical advice.

SAFETY DATA SHEET

If swallowed : Do NOT induce vomiting.

Rinse mouth with water.
Give small amounts of water to drink.
Obtain medical attention.
4.2 Most important symptoms and effects, both acute and delayed
Symptoms : No information available.
Risks : No information available.
4.3 Indication of any immediate medical attention and special treatment needed
Treatment : No information available.
SECTION 5: Firefighting measures
5.1 Extinguishing media

Suitable extinguishing media : Water, Dry powder, Foam, Carbon dioxide (CO2)
Unsuitable extinguishing : No information available.

media
5.2 Special hazards arising from the substance or mixture

Specific hazards during fire- : No information available.
fighting
Specific risk from the sub- : No special risks to be expected.

stance or the product itself,
its combustion products or
evolved gases
5.3 Advice for firefighters

Special protective equipment : No special precautions required.
for firefighters
Further information : Standard procedure for chemical fires.
SECTION 6: Accidental release measures
6.1 Personal precautions, protective equipment and emergency procedures

Personal precautions : Ensure adequate ventilation. Use personal protective equip-
ment.
6.2 Environmental precautions

Environmental precautions : Do not flush into surface water.
6.3 Methods and materials for containment and cleaning up

Methods for cleaning up : Wipe up with absorbent material (e.g. cloth, fleece).
Soak up with inert absorbent material (e.g. sand, silica gel,
SAFETY DATA SHEET

acid binder, universal binder, sawdust).
6.4 Reference to other sections

See chapter 8 + 13
SECTION 7: Handling and storage
7.1 Precautions for safe handling

Advice on safe handling : Avoid exceeding of the given occupational exposure limits
(see section 8).
Wear personal protective equipment.
Avoid formation of aerosol.
Advice on protection against : No special protective measures against fire required.

fire and explosion
Hygiene measures : Keep away from food and drink.
7.2 Conditions for safe storage, including any incompatibilities

Requirements for storage : Store at room temperature in the original container.
areas and containers
Further information on stor- : Keep away from heat.

age conditions Keep away from direct sunlight.
Keep container tightly closed.
Advice on common storage : Keep away from food and drink.
7.3 Specific end use(s)

Specific use(s) : none
SECTION 8: Exposure controls/personal protection
8.1 Control parameters

Value type (Form of Control parame-
Components CAS-No. Basis
exposure) ters
Glutaral 111-30-8 TLV 0,05 ppm ACGIH
Derived No Effect Level (DNEL)

Glutaral : End Use: Workers, Exposure routes: Inhalation, Potential
health effects: Long-term local effects, Value: 0,25 mg/m3
Predicted No Effect Concentration (PNEC)

Glutaral : Fresh water, Value: 0,0025 mg/l
SAFETY DATA SHEET

Marine water, Value: 0,00025 mg/l
Fresh water sediment, Value: 5,27 mg/kg
Marine sediment, Value: 0,527 mg/kg
Soil, Value: 0,03 mg/kg
Effects on waste water treatment plants, Value: 0,8 mg/l
Intermittent use/release, Value: 0,006 mg/l
8.2 Exposure controls

Personal protective equipment
Eye protection : Tightly fitting safety goggles
Hand protection : Splash protection: disposable nitrile rubber gloves e.g.

Dermatril (layer thickness: 0,11 mm) made by KCL or gloves
from other manufacturers offering the same protection. Pro-
longed contact: Nitrile rubber gloves e.g. Camatril (>480 Min.,
layer thickness: 0,40 mm) or butyl rubber gloves e.g. Butoject
(>480 Min., layer thickness: 0,70 mm) made by KCL or gloves
from other manufacturers offering the same protection.
Respiratory protection : If the occupational exposure limits cannot be met, in excep-

tional cases suitable respiratory equipment should be worn
only for a short period of time.
Respiratory protection complying with EN 141.
Recommended Filter type:
A
Protective measures : Avoid contact with skin and eyes.
Environmental exposure controls

General advice : Do not flush into surface water.
SECTION 9: Physical and chemical properties
9.1 Information on basic physical and chemical properties

Appearance : Liquid
Colour : nearly colourless - light yellow
Odour : aldehyde like
Flash point : > 100 °C, ISO 2719
pH : ca. 6 - 8, Concentration: 5,00 g/l, 20 °C, in water
Melting point/freezing point : < -5 °C
Initial boiling point : ca. 100 °C
Vapour pressure : ca. 25 hPa, 20 °C
Density : ca. 1,032 - 1,036 g/ml, 20 °C
Water solubility : completely miscible, 20 °C
Flow time : < 15 s at 20 °C, DIN 53211

SAFETY DATA SHEET

9.2 Other information

Refractive index : 1,362 - 1,367
SECTION 10: Stability and reactivity
10.1 Reactivity
Stable under recommended storage conditions.
10.2 Chemical stability
No decomposition if stored normally.
10.3 Possibility of hazardous reactions
None reasonably foreseeable.
10.4 Conditions to avoid
Protect from frost, heat and sunlight.
10.5 Incompatible materials
Amines
10.6 Hazardous decomposition products
None reasonably foreseeable.
SECTION 11: Toxicological information

11.1 Information on toxicological effects
Acute toxicity
Product
Acute oral toxicity : LD50: 2079 mg/kg, rat, OECD Test Guideline 401
Components:
Glutaral:
Acute inhalation toxicity : LC50: 0,48 mg/l, 4 h, rat, Aerosol , OECD Test Guideline 403
Acute dermal toxicity : LD50: > 2000 mg/kg, rabbit
Alkylpolyethoxy-polypropoxyether:
Acute inhalation toxicity : LC50: > 8 mg/l, 1 h, rat, vapour
Acute dermal toxicity : LD50 Dermal: 5660 mg/kg, rabbit
Mixture of 5-chloro-2-methyl-2H-isothiazol-3-one (CAS 26172-55-4) and 2-methyl-2H-
isothiazol-3-one (CAS 2682-20-4):
Acute inhalation toxicity : LC50: 2,36 mg/l, 4 h, rat, Aerosol
Acute dermal toxicity : LD50: 660 mg/kg, rabbit
Skin corrosion/irritation
Product
No skin irritation, rabbit, OECD Test Guideline 404
Serious eye damage/eye irritation
Product
No eye irritation, rabbit, 4% solution
Respiratory or skin sensitisation
SAFETY DATA SHEET

Components:
Glutaral:
guinea pig May cause sensitisation by inhalation and skin contact.
no data available
Causes sensitisation. guinea pig
Germ cell mutagenicity
Components:
Glutaral:
Genotoxicity in vitro : Conflicting results have been seen in different studies.
Germ cell mutagenicity- As- : Did not show mutagenic effects in animal experiments.
sessment
Germ cell mutagenicity- As- : no data available
sessment
Germ cell mutagenicity- As- : not mutagenic
sessment
Carcinogenicity
Components:
Glutaral:
Carcinogenicity - Assess- : Animal testing did not show any carcinogenic effects.
ment
Carcinogenicity - Assess- : no data available
ment
Carcinogenicity - Assess- : Animal testing did not show any carcinogenic effects.
ment
Reproductive toxicity
Components:
Glutaral:
Reproductive toxicity - As- : Animal testing did not show any effects on fertility.
sessment
Reproductive toxicity - As- : no data available
sessment
Reproductive toxicity - As- : No toxicity to reproduction
sessment
Teratogenicity
Components:
Glutaral:
Teratogenicity - Assessment : Did not show teratogenic effects in animal experiments.
Teratogenicity - Assessment : no data available
SAFETY DATA SHEET


Teratogenicity - Assessment : Did not show teratogenic effects in animal experiments.
STOT - single exposure
no data available
STOT - repeated exposure

no data available
Repeated dose toxicity

Components:
Glutaral:
No adverse effect has been observed in chronic toxicity tests.
Aspiration toxicity
no data available
SECTION 12: Ecological information
12.1 Toxicity
Product
Toxicity to bacteria : EC50: 355 mg/l, OECD 209
12.2 Persistence and degradability
Product
Biodegradability : According to the results of tests of biodegradability this prod-
uct is considered as being readily biodegradable., 63 o/o,
OECD 301D / EEC 84/449 C6
Chemical Oxygen Demand : ca. 4.500 mg/l , 1% solution
(COD)
12.3 Bioaccumulative potential
Components:
Glutaral :
Bioaccumulation : Does not bioaccumulate.
Partition coefficient: n- : log Pow: ca. -0,36 (23 °C), pH: 7, Method: Directive
octanol/water 92/69/EEC, A.8
Alkylpolyethoxy-polypropoxyether :
Bioaccumulation : no data available
isothiazol-3-one (CAS 2682-20-4) :
Partition coefficient: n- : log Pow: -0,486
octanol/water
: log Pow: 0,401
12.4 Mobility in soil
Product
Mobility : no data available
12.5 Results of PBT and vPvB assessment
Product

SAFETY DATA SHEET

No information available.
12.6 Other adverse effects
Product
Additional ecological infor- : The surfactant(s) contained in this mixture complies(comply)
mation with the biodegradability criteria as laid down in Regulation
(EC) No.648/2004 on detergents. Data to support this asser-
tion are held at the disposal of the competent authorities of the
Member States and will be made available to them, at their
direct request or at the request of a detergent manufactur-
er.Avoid subsoil penetration.Do not flush into surface water or
sanitary sewer system.
SECTION 13: Disposal considerations
13.1 Waste treatment methods

Product : Dispose of the product according to the defined EWC (Euro-
pean Waste Code) No.
Contaminated packaging : Take empty packaging to the recycling plant.
Waste key for the unused : European waste catalog (EWC) 070601
product
Waste key for the unused : Waste material of HZVA from fats, lubricants, soaps, deter-
product(Group) gents, disinfectants and personal protection products.
SECTION 14: Transport information
14.1 UN number
ADR : 3082
IMDG : 3082
IATA IATA_C : 3082
14.2 Proper shipping name
ADR : ENVIRONMENTALLY HAZARDOUS SUBSTANCE, LIQUID,
N.O.S.
(5-Chloro-2-methyl-2H-isothiazol-3-one, 2-Methyl-2H-
isothiazol-3-one)
IMDG : ENVIRONMENTALLY HAZARDOUS SUBSTANCE, LIQUID,
N.O.S.
isothiazol-3-one)
IATAIATA_C : ENVIRONMENTALLY HAZARDOUS SUBSTANCE, LIQUID,
N.O.S.
isothiazol-3-one)
14.3 Transport hazard class
ADR : 9
IMDG : 9
IATAIATA_C : 9
14.4 Packing group
SAFETY DATA SHEET

ADR
Packaging group : III
Classification Code : M6
Hazard Identification Number : 90
Labels : 9 (N)
Tunnel restriction code : E
IMDG
Labels : 9 (N)
EmS Number : F-A, S-F
IATAIATA_C
Labels : 9 (N)
14.5 Environmental hazards
ADR
Environmentally hazardous : yes
IMDG
Marine pollutant : yes
IATA
Environmentally hazardous : yes
14.6 Special precautions for user
For personal protection see section 8.
14.7 Transport in bulk according to Annex II of MARPOL 73/78 and the IBC Code
Exempt
SECTION 15: Regulatory information
15.1 Safety, health and environmental regulations/legislation specific for the substance or mix-
ture
Legislation on the control of : The product belongs to at least one of the categories 1
major-accident hazards in- through 11 mentioned in Annex 1 of the Directive 1996/82/EC
volving dangerous substanc- concerning the control of major accident hazards.
es
Volatile organic compounds : none, Directive 1999/13/EC on the limitation of emissions of

volatile organic compounds
15.2 Chemical Safety Assessment

Exempt
SECTION 16: Other information

Full text of R-Phrases
R22 Harmful if swallowed.
R23/24/25 Toxic by inhalation, in contact with skin and if swallowed.
R23/25 Toxic by inhalation and if swallowed.
R34 Causes burns.
R36 Irritating to eyes.
SAFETY DATA SHEET

R42/43 May cause sensitisation by inhalation and skin contact.

R43 May cause sensitisation by skin contact.
R50 Very toxic to aquatic organisms.
R50/53 Very toxic to aquatic organisms, may cause long-term adverse effects in
the aquatic environment.
Full text of H-Statements

H290 May be corrosive to metals.
H301 Toxic if swallowed.
H302 Harmful if swallowed.
H311 Toxic in contact with skin.
H314 Causes severe skin burns and eye damage.
H317 May cause an allergic skin reaction.
H319 Causes serious eye irritation.
H331 Toxic if inhaled.
H334 May cause allergy or asthma symptoms or breathing difficulties if in-
haled.
H335 May cause respiratory irritation.
H400 Very toxic to aquatic life.
H410 Very toxic to aquatic life with long lasting effects.
H411 Toxic to aquatic life with long lasting effects.
Full text of other abbreviations

Acute Tox. Acute toxicity
Aquatic Acute Acute aquatic toxicity
Aquatic Chronic Chronic aquatic toxicity
Eye Irrit. Eye irritation
Met. Corr. Corrosive to metals
Resp. Sens. Respiratory sensitisation
Skin Corr. Skin corrosion
Skin Sens. Skin sensitisation
STOT SE Specific target organ toxicity - single exposure
Changes compared with the previous edition!!!
The information provided in this Safety Data Sheet is correct to the best of our knowledge, in-
formation and belief at the date of its publication. The information given is designed only as a
guidance for safe handling, use, processing, storage, transportation, disposal and release and
is not to be considered a warranty or quality specification. The information relates only to the
specific material designated and may not be valid for such material used in combination with
any other materials or in any process, unless specified in the text.

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SAFETY DATA SHEET

according to Regulation (EC) No. 1907/2006

grotanol® 3025 No Change Service!

SECTION 1: Identification of the substance/mixture and of the company/undertaking

1.1 Product identifier

1.3 Details of the supplier of the safety data sheet

1.4 Emergency telephone number

SECTION 2: Hazards identification

2.1 Classification of the substance or mixture

2.2 Label elements

Z11486 ZSDB_P_ALL EN Page 1/12

grotanol® 3025 No Change Service!

Signal word : Danger

Hazard statements : H332 Harmful if inhaled.

Precautionary statements : P261 Avoid breathing vapours.

Hazardous components which must be listed on the label:

Special labelling of certain : Labelling according to Regulation (EC) No. 648/2004: (5 -

2.3 Other hazards

SECTION 3: Composition/information on ingredients

grotanol® 3025 No Change Service!

Alkylpolyethoxy- 68603-25-8 Xn; R22 Acute Tox. 4; H302 5 - 15 %

Mixture of 5-chloro-2- 613-167-00-5 T; R23/24/25 Acute Tox. 3; H301 0,1 - 0,3 %

SECTION 4: First aid measures

4.1 Description of first aid measures

In case of skin contact : Wash off immediately with plenty of water.

Z11486 ZSDB_P_ALL EN Page 3/12

grotanol® 3025 No Change Service!

If swallowed : Do NOT induce vomiting.

Risks : No information available.

SECTION 5: Firefighting measures

5.1 Extinguishing media

Unsuitable extinguishing : No information available.

5.2 Special hazards arising from the substance or mixture

Specific risk from the sub- : No special risks to be expected.

5.3 Advice for firefighters

Further information : Standard procedure for chemical fires.

SECTION 6: Accidental release measures

6.1 Personal precautions, protective equipment and emergency procedures

6.2 Environmental precautions

6.3 Methods and materials for containment and cleaning up

grotanol® 3025 No Change Service!

acid binder, universal binder, sawdust).

6.4 Reference to other sections

SECTION 7: Handling and storage

7.1 Precautions for safe handling

Advice on protection against : No special protective measures against fire required.

Hygiene measures : Keep away from food and drink.

7.2 Conditions for safe storage, including any incompatibilities

Further information on stor- : Keep away from heat.

Advice on common storage : Keep away from food and drink.

7.3 Specific end use(s)

SECTION 8: Exposure controls/personal protection

8.1 Control parameters

Derived No Effect Level (DNEL)

Predicted No Effect Concentration (PNEC)

grotanol® 3025 No Change Service!

Marine water, Value: 0,00025 mg/l

Fresh water sediment, Value: 5,27 mg/kg

Marine sediment, Value: 0,527 mg/kg

Soil, Value: 0,03 mg/kg

Effects on waste water treatment plants, Value: 0,8 mg/l

Intermittent use/release, Value: 0,006 mg/l

8.2 Exposure controls