10 Electrochemistry Topic1 Electrochemical Cells Objective Questions I (Only 1. Given, Go™ +e”. CoP. one correct option) +181V +167V +e 9 Ce B= + ely Bi + 36° — Bi E°= 4 020 Po* + 26° 5 pp, cet Oxidising power of the species will increase in the order (2019 Main, 12 apni (@) Ce* < Pb cB < Coe (b) Bi < Cet < Pb < Co! (©) Co” < Cet < Bi** < Pot @) Co™ 2. A solution of Ni(NO. electrodes usin Ni will be deposited atthe cathode? (@) 020°) 0.10) 0.15 3. Calculate the standard cell following reaction takes place Fe® (aq) + Ag’ (aq) —> Fe (aq) + Agis) Given that, (@) 0.05 Ev asyyq == V (2019 Main, 8 Ape) (a) x4 2y— (x+y ) x» @ x 4. Given, that B§, 4 = +1.23V;, Foor soy ~ 205 Ee oe ae she The strongest oxidising agent is (@) Au”) 0 (ice (a) be, 5. Consider the following reduction processes: 2 > Zins) B= = 076V + Causy, B= 247 > Mels); E=~ 236 » Nii): =~ 038 De is electrolysed between platinum ig 0.1 Faraday electricity. How many mole of (2019 Main, 9 Apri 1) potential (in V) ofthe cellin which (2019 Main, 8 Apri) The reducing power of the metals increases in the (2015 Maint © Niczn Ma (ag) + 48,01, 7 Ee=15iV ,0% (ag) * 141 (aq) + 66° —2€F*(ag) + THOU), ‘ Eea138V Fe! (ag)+ > Fe** (aq) Ciylg)+ 26° —+ 2Cl (aq) enity the incorrect statement regarding the quantiatve timation of aqueous FetNO, J eee {@)Mn0 can be ‘used in aqueous HCl ()Cr0} can be used in aqueous HCL {e)Ma0, can be asd in aqueous $0, { cA 0F canbe sed in aqueous H2SO. ‘of KNO, is used to make ‘sal-ridge 45, Saturated solution (2001, 1m) because {a velocity of K* is greater than that of NO3 (velocity of NOs is eater than hat of (@ velocities of bath K” and NOS ae early he SNE {(@KNO, is highly soluble in water 46. The as atl atm s bubbled through aS containing 2 Be ay iyi wd AMZ" Hf 25°C Me order of eduction potential is Z>Y >, fheB (0999, 20) {@ Ywill oxidise X and not 2 (©) F wil oxidise Z and not (© Ywill oxidise both Xand Z hs (4) Ywill reduce both X and Z ee wn potential values 0! li The standard redution potential AIMS Te ly, The tations X,Y, Zare 0.52, 3.03800~ | 4 der of reducing power ofthe corresrr jing metal mee fg xryez nen 2 22 72x wax? j 4, The standard redvton potentials (OF half reactions meas an a is 7 REN | penal 21. 2. 23. 24. (a) AgiAgCl(s)iKC! (6) Ptiig(g )HCHsolm)| ABNOs (© PilHy(g CIO | ABSA {) Pe|Hy(g)KCUsol) | ABCKSIAS “The clei charge fr elsrode depotion oF os6 FAS ‘equivalent ofa substance is (1994, 1" (2) one ampere per second {6 96,500 coulomb per second {6 one ampere for one hour {@) charge on one mole of electrons “A solution containing one mote pet Ii ‘AgNO, He (NO; ) and MEINOS ) Pe electrolysed bY twsing inert standard el reas in vous reduction potential ae g/g =-+ 080, He? 2s = +079 ut /Cu =+0.34, Mg?*/Mg =~ 237 with nreaing voltage the sequence of deposition of s7=98 lite of each Cu (NOs a> onthe cathode willbe ‘ases, 190 (a) Ag. He, Cu ME (b) Mg, Co, He, AB (o) Ag, Hg, Cu (4) Cu, Hg, AB. cases, 100 toraday's laws of electrolysis ar elated the {a atomic number ofthe cation {by atomic mmber of the anion (2) Seivatent weight of the electlyte (@) speed of the cation ‘The standard reduction potentials at 298K for ‘the following half eels ere given Zn?" (ag)+ 2° = Znls); B= -0.762V CP*(aq) + 36° — CH(5); Be OaANG 2H (aq)+ 26° = Hye B= 0.0000 Fe?*(ag)+ ==? Fe (aq = 0.710 ‘Which isthe strongest reducing agent? (age, 1m) (a Za(s) (0) Crs) (ile) (Fe (ag)158 Electrochemistry Objective Questions II (One or more than one correct option) ‘25. Ina galvanic cell, the salt-bridge (2014 Ade) (@) does not participate chemically in the cell reaction 4b) stops the diffusion of fons from one electrode to another (6) isncessary forthe occurrence ofthe cll reaction (@) ensures mixing of the two electrolytic soutions For the reduction of NO; jon in an aqueous solution E* is + 0964. Values of E*for some met ions ar give below S(ag)+20—V; E=-L19V Fe"(ag)+3e Fe, E=-008y ‘Au® (0g) + 3° —3 Au; E*=+ 1L40V Hg (ag)+2e sg; E*=+ 086y ‘The pas) of metals that sare oxidised by NO; in aquous solution sar) ‘20a (@) Vand Hg_(b) Hg and Fe (c) Fe and Au (4) Fe and V . Numerical Answer Type Questions 2F. Consider a 70% efficient hydrogen-xygen fel cell working Under standandconitons aI bar an 298K, Isl reactions 1 HxG)+ 30,62) —> 000 The work derived from the cell on the consumption of 10x 107 mole of (gs used to compress 1.00 mole of « ‘monoatomic ideal gas in a thermally insulted contine ‘Whatisthe change inthe temperature (i K) of the ie 8? ‘The standard reduction potentials for the two halls are given below: Ox) + 4H" (ag) + 4° —92H.00, E=123V 2 (ag) + 28” > H44g), Use, F =96800C mol"! =83183 mol" K". 2920 say) Forthe electrochemical el. Ma(s)Mg™ (ag. LD C2 (09,1 ND [Cus The standard emf ofthe els 2.70 V at 30 K. When the concentration of Mg*"is change 10x M, th ell potential anges to 267 Vat 300K. The value of is_ (Ge El 00K" vn Fry ee ee a A(s)|A" (09,2M)|B™*(agIMD) | B(s) The vale of SH forthe cell rection itis of AG® at 30K. the emf the ‘ellis zero, the AS® (in JK" mot) ofthe cell reaction per mole ofB formed at 300 Kis ; (Given: 12) =07. (univers gas constant) = 83) mol! HS and Gar ently, eopy and Gibbs ene. canis sav) respectively.) Passage Based Questions Chemical reactions involve interaction of molecules, A large number of “nce (apoxitely 6023 10") ae present ina fe pa any ceil oop vain with i sonic maces. To handle such lage numbers conenieng tl cnet ast This come ing inven eh alchemy, Hcg clecrsheisy and races. The linger ilsates apical case, involving chemical reaction, ich oui a clear understanding of te concept A40M ago soltion of aCls repr 500 mL of his olan is eectolsed. This ads mig voto of rine gas at ne ofthe elects (stoic mas Na = 2% lg =200,1F = 965000), (2007, 3+ aM tay 30. The total number of moles of chorne gas evolved is (aos O10 20 (30 31. Ifthe cathode is 2 Hy cectode, the maximum weg (in gram) of alga formes fom this solution is (9200 ) (400 (ue 32, The tol charge (caulombs) required for complete clestolysisis (@mns 4080 (©) 96500 (a 193000 Subjective Questions 38, The flowing eecrochemia cl bas been aet-p PuD|Fe” e® (a=) 1Ce" Canty) Efe Fe )<077V and E(Ce, Ce )=161V 1 an ammeter is coneced beeen electrodes, predict the dieton of flow cut inceases decrees with time? the two platinum of Curent, will the 00 20 A. omer iiss 20) was a pana mad pee et Sak wa ped fr 16min Me etc lena hore fhe she tl a ter Sr fea ae Cae ee A cope peg in 35, AcallAg [Ag Co [Co intily conan yy in Ce" os Cae shang i he ct pa thegee 8A stom eh A ar a4, tory gmetad og 80 Hon nant Et of lon cng Sting plang Oo? Desy fiver 105 pgs her 957ee Uaistisro ws! 2 ‘ i their Topic2 Conductivity of Electrolytic Solutions and Measurement and Nernst Equation Objective Questions I (Only one correc option) 1. “Molar conductivity (A..) of aqueous solution of sodium ‘Stearate, which behaves asa strong electrolyte, is recorded at 2 The decreasing order of electrical conductivity of the following aqueous solution is 0.1 M formic acid (4), 0.1 M acetic acid (B), 0.1 M benzoic acid (C), (a) 4>C>B (4>B>c (2019 Main, 12 ape ()C>B>4 (C>4>B 3. Which one of the following graphs between molat conductivity (A, )versus VC is comet? (2019 main, 10 Ap ie a a 4, Consider he statements Sand S_ S, + Conductivity =x increases with concentration of electrolyte. 5, ee Eaiee tien el concentration of electrolyte Tecan opin ange felowing i a (8) §,iscomect and, is wrong (b) Sis wrong and Si comect (6) Both, and S are wrong (@) Both, and S, are coret ‘5. ‘The standard Gibbs energy for the given cell reaction ayy sol 31298 Kis Za) + Cu (ag)—+Zn°*(ag)+ Cals) Fr=2Va1296K (Faraday's constant, F = 96000 C mol”) (2018 Main 9 Apap (2) 364 (0) 192) 384d) 199 8. AS for NaCl, HCI and Nad are 1264, 4259 a 10058 cm? mole spectively. Ifthe conductivity of MHLAis 5x10? Sem”! dere of dissociation of HA (2019 Main, 12 @ O25 Jot the reaction “(aq)+ 2Ag(s) B10 10 cba te Fae recs o 298K, (025) 050 7. Given the equilibrium (©) 075 constant (K Cuts) 2g" (ag) Cu? 303 FF ae 208 F 059) L J a (2019 Main, 11 Jen) (3) 04736 v (©) 008736 me (0) 0.4736 mv @) oosnse 8. Forthe cell, 2n(s) fn 0 ern Gell and their standard electrode penis > SEER a ap Ata tiven below. Au (ai | AB (aa TGR AE" (agyMs) As (aay Te Aus) | Asch | re Fyn” | 140 | op ri WE 076 V, which eathode wit Mn; E°==1.18 eV Divine > Mat) = +1 51eV The E" for 3Mn®* > Mn+ 2Mn™ will be (a) = 2.69 V5 the rea {by ~2.69V5 the rea {e) ~033V; the reaction will ot oeeur {@) ~0.33 V- the reaction will cur 4, The euivatent conductance of NACI st concentration Con Bere cittion are Ac and 2, respectively The come Pip berwenn Ac and 2 is civenias rier jon will not occur jon will occur constant Bis postive) (2014 Main) Merayc., were OT Deere. ATH AEE 15. Resistance of 0.2 M solution of an electrolyte § 50. The Fede conductance ofthe solution of 0.5 M S10 fame teal is 14 Sm-! and resistance of same SAT oft fame electrolyte is 2806. The mola? conduc? of 0 BR dcgcien sare. cntkmen Barty, 5102, 0) 2420 OAM we 16. Thestandard reduction potential data a 95°C is given below: Spe rneya 0.77 Vs Entre: (ele E(u / Cu) =+ 0.34 Vs ECU” /Cuy=+ 0.52 Vi E%(0,(g) +44 + 4e" ) > 2H20)=* 1B vs . | eS bas © BCE cy =-0.74 VE pen=1091V 8 2c) 2 Pog Rk § st Mi on am 2 Se or? Oe OY PAS @ 3 4 rie f Az code Sen bene OS = Golan Se Se P. N+ CH,COOH ‘Conductivity decreases a : and then increases Kl. M+ AgNO, (0.01 M) decreases ines and then does not yi See s change much __ R CH,COOH+ KOH ey and then does not change much, ft Hoe Oe ‘change much and then increases Codes PQ Res pP QR s @> 42ers Qeaed | Oel aa 48. Consider the following cell reaction, : BFe(s)+ Ogle) + 4H (ag) —> 2Fe™ (aq) + 24,00, E =1.61V At [Fe**]=10° M, PO: atm and pH =3, the eell potential at 25°Cis aon @ LTV. @) LTV. © 18TV @ STV 49. AgNO, (aqueous) was added to an aqueous KCI solution radally and the conductivity of the solution was measured ‘The plot of conductance (A) versus the volume of ABNOs MA hee) Tame VWolame Volum Wolume e Q ® ) (b) (Q) oe ©® § OS Se