" CHEMISTRY-IA Cie Laws of Chemical Combination 1. Correct statement in the following is/are 1) Chemical equation is balanced according to law of conservation of mass 2) Law of conservation is not applicable for nuclear reactions 3) Law of combining volumes was proposed by Ga 4) All the above Two gaseous samples were analysed. One contained 1.2 g of carbon and 3.2 g of oxygen. The other contained 27.3% carbon and 72.7% oxygen. The experimental data is in accordance with 1) Law of conservation of mass 2) Law of definite proportions 3) Law of reciprocal proportions 4) Law of multiple proportions 3. Percentage of copper and oxygen in samples of CuO obtained by different methods were found to be the same. This proves the law of 1) Constant proportions 2) Reciprocal proportions 3) Multiple proportions 4) Conservation of mass 4. (A): The law of conservation of mass holds g00d for all reactions. Nuclear reactions can not proceed acco- rding to law of conservation of mass. 1) Both A and R are true and R is the correct explanation of A 2) Both A and R are true but R is not the correct explanation of A 3) A is true and R is false 4) Ris true and A is false (B) 5. “The total mass of reactants is always equal to the total mass of products in a chemical reaction.” This statement is known as 6 1) Law of conservation of mass 2) Law of definite proportions 3) Law of equivalent weights 4) Law of combining masses In the reaction Hydrogen, + Oxygen,,, Bi¥es water vapour, the ratio of volumes is 2:1:2 This illustrates the law of 1) conservation of mass 2) combining weights 3) combining volumes 4) all the above Two samples of lead oxide were separately reduced to metallic lead by heating in a current of hydrogen. The weight of lead from one oxide was half the weight of lead obtained from the other oxide. The data illustrates. 1) Law of reciprocal proportions 2) Law of constant proportions 3) Law of multiple proportions 4) Law of equivalent proportions One part of an element A combines with two parts of B (another element). Six parts of element C combine with four parts of element B. If A and C combine together, the ratio of their masses will be governed by: 1) law of definite proportions 2) law of multiple proportions 3) law of reciprocal proportions 4) law of conservation of mass 14 g of element X combine with 16 g of oxygen. On the basis of this information, which of the followings is a correct statement? 1) The element X could have an atomic weight of 7 and its oxide is XO 2) The element X could have an atomic weight of 14 and its oxide formula is X,O 3) The element X could have an atomic weight of 7 and its oxide is X,0 4) The element X could have an atomic weight of 14 and its oxide is XO, 21710. Carbon and oxygen combine to form two oxides, carbon monoxide and carbon dioxide in which the ratio of the weights of carbon and oxygen is respectively 12:16 and 12:32 These figures illustrate the 1) Law of multiple proportions 2) Law of reciprocal proportions 3) Law of conservation of mass 4) Law of constant proportions 11. Two elements X (at.mass 16) and Y (at. mass 14) combine to form compounds A, B and C in which the ratio of weight of Y combines with a fixed mass of X is 1 3: 5 respectively. If 32 parts by mass of X combines with 84 parts by mass of Y in B, then in C, 16 parts by mass of X will combine with 1) 14 parts by mass of Y 2) 42 parts by mass of Y 3) 70 parts by mass of ¥ 4) 84 parts by mass of Y 12. 4.4g of an oxide of nitrogen gives 2.24L of nitrogen and 60g of another oxide of nitrogen gives 22.4L of nitrogen at S.T.P. The data illustrates 1) Law of conservation of mass 2) Law of constant proportions 3) Law of multiple proportions 4) Law of reciprocal proportions Mole concept 13. Correct statement in the following is 1) The molar volume of any gas at STP is 22.71 lit. 2) The volume of 1 mole of water at STP is 22.4 lit 3) The molar voulume of any gas at STP contains 22.4 molecules 4) All of these 14. Correct statement in the following is/are A) Mass of one gram molecule oxygen is32 grams B) Mass of one gram atom oxygen is16 grams C) Mass of one molecule oxygen is 32 amu 16. 17. 18. 19. 20. 21 CHEMISTRYAA | 1D) Mass of one oxygen atom is 16 amu IW”Allareieorree> — 2) A, B and C only 3) Band C only 4) Aand B only What will be the mass of one "°C atom in grams will be 3) 1.9926 x 10° 2) 1.2 x 10% 4) 12 Avogadro number is 1) The number of atoms in one gram-atomic- weight 2) The number of molecules in one gram- molecular weight 3) The number of atoms in 0.012 kg of C-12 A mole is 1) The amount of substance containing the same number of chemical units as the number of atoms in exactly 12g of C!? 2) The amount of substance containing Avogadro number of chemical units 3) The unit for expressing amount of a substance DrAlthesabovs] Number of molecules in one litre of oxygen at STP conditions is 5 » Sax? 32 22. 32 3) 32 x 22.4 = ) x 4) a Which of the following has the least number of atoms? 1) 0.5 g atom of Zn 2) 0.645g of Zn 3) 0.25 mole of Zn Air contains nitrogen and oxygen in the volume ratio of 4:1. The average molecular weight of air is 130 -2))2818 3) 28 ‘The number of gram atoms of sulphur present in 3 mole of hydrogen sulphide is 22 315 4) 1.0 4) 144 DOCTORS SERIES for Sti Chaitanya Jr. AllMS StudentsReuse ee 49, One mole of molecules of dioxygen represents 1) 6.02x10® molecules of oxygen 2) 8 gms of oxygen 3) 16g of O, 4) 11.2L of O, at STP 23. One mole of sodium represents 1) 6.02x10* atoms of sodium — 2) 46 gms of sodium 3) 11g of sodium 4) 34.5g of sodium 24. The charge present on 1 mole electrons is 2) Coulomb 4) 0.1 Faraday 25, The weight of 0.1 mole of Na,CO, is 3) 160x109 C 1) 106 g 2) 106 3)53¢g 4) 6.02 x 10g 26. Avogadro number of helium atoms have a mass of 1) 2g 24g 3) 8g 4) 4x6.02x10%%g 27. The volume of two moles of oxygen at STP is WAL 212 3)40L ea 28. ‘The following property of a gas does not vary with pressure and temperature. 1) density 3) volume 4) vapour density. [The ratio between the number of molecules in equal masses of nitrogen and oxygen is 178 2) 391 48:7 30. The gas which is twice as dense as oxygen under the same conditions is 1) Ozone 2) Sulphur trioxide 4) Carbon dioxide GL | mole of water vapour is condensed to liquid at 25°C, Now this water contains i) 3 moles of atoms ii) 1 mole of hydrogen molecules iii) 10 moles of electrons iv) 16 g of oxygen The correct combination is 1) @ & Gi) 2) (i) & (iti) 3) @) & (iv) -4) All are correct 32. A chemical equation is always balanced with respect which one of the following i) Number of atoms ii) Number of molecules iii) Number of moles iv) Mass 2) Only iii correct 1) Only i is correct 3) Only iv Correct 33. One gram of hydrogen contains 6x10” atoms. 35. Then 4 grams of He contains Iy6x10 atoms) 2) 12x10 atoms 3) 24x10 atoms 4) 1.510% atoms Elements ‘A’ and ‘B’ combine in the ratio of their 1) Atomic weights 2) Molecular weights 3) Equivalent weights 4) Mass numbers M g of a substance when vapourized occupy a volume of 5.6 litre at NTP. The molecular mass of the substance will be: 4) 4M DM 2)2M 3): 3M Equivalent weights 36. 37. 38. 39, 40. Molecular weight of orthophosphoric acid is M. Its equivalent weight is 3M -2)M gM gM ) Iz MG Which of the following acid has the same molecular weight and equivalent weight ? 2)H,PO, 3)H,PO, 4) H,SO, ‘The equivalent mass of CaCO, H100 50 -3)33.3 4) 25 0.5g of a metal on oxidation gave 0.79g of its oxide. The equivalent mass of the metal is 110 214 3)20 4)40 The vapour density of a volatile chloride of a metal is 59.5 and the equivalent mass of the metal is 24, The atomic mass of the element will be 19% 2) 48 3) 24 4) 12 21941 43. 44, 45. 46. 47. 48. Which one of the relationship is wrong? 1) 2 Vapour Density = Mol, Mass 2) At, Mass = Eq. mass x valency 64 3) At. Mass = ‘The following is not a fixed quantity 1) atomic weight of an element 3) molecular weight of a compound 4) formula weight of a substance The equivalent weight of Bayer’s reagent is (alkaline KMnO,) 1) 31.6 QV 52K 3) 794) 158 Molecular weight of KMnO, is "M". In a reaction KMnQ, is reduced to K,MnO,. The equivalent weight of KMnO, is When Ferrous sulphate acts as reductant, its equivalent weight is M M M Des As 1) twice that of its molecular weight 3) one-half of ee molecular weight 4) one-third of its molecular weight 2H,0 > 4e- + O, + 4H*. The equivalent weight of oxygen is 132 -2)16 3B In acidic medium dichromate ion oxidises ferrous ion to ferric ion. If the gram-molecular weight of potassium dichromate is 294 g, its equivalent weight is 1) 2942) 147 ‘The equivalent weight of hypo in the reaction [M = molecular weight] 2Na,$,0, +L, > 2Nal + Na,$,0, is am 44 4) 24.5 ae M ay ) 4 M 22g 49. 50. 51 52. 53. 54, 55. 56. onverted to Cuyl, M M D9 CHEMISTRY-1A ‘The equivalent weight of CuSO, when it is [M=mol.wt] a> 4)2M ‘The sulphate of a divalent element contains 42.2% element. The equivalent mass would be 1) 17.0 2) 35.0 3) 51.0 4) 68.0 The equivalent weight of iodine in the reaction (Mis molecular weight) 2Na,S,0, +1, > 2Nal + Na,S,0, is 1M 4)2M M M az 5 The equivalent weight of glucose in the reaction CH,.0,+ 60, > 6CO, + 6H,0 is (Mis molecular weight) & 48 48 ‘The atomic weight of a metal (M) is 27 and its equivalent weight is 9, the formula of its chloride M M Dy MD willbe 1)MCI_ 2)MCI, 3) M,Cl, <4) MCI) Match the following Medium Equivalent of KMnO, A) Acidic a) 158 B) Neutral b) 79 C) Strongly basic c) 52.6 D) Weakly basic d) 31.6 The correct match is A-d,B-c,C-aD-b 3)A-d,B-b,C-a,D-c 4)A-d,B-c,C-aD-a The equivalent weight of a tetravalent element is 8, the relative vapour density of its oxide is 1) 16: 2 3) 8 3) 64 For the reaction Fe,S, + 50, —> 2FeSO, + SO,, the equivalent weight of Fe,S3is M M M _ DOCTORS SERIES for Sti Chaitanya Jr. AllMS StudentsISTRY-IA In the redox ionic equation 2Mn0, + Br + HO +> 2Mn0,+ BrO, + 20H the equivalent weight of potassium perman: “M’ g mol is gante of molar im M i 4) DS ) Methods of concentration The number of millimoles of H,SO, present in $ litres of 0.2N H,SO, solution is 1) 500 2) 1000 3) 250 405x103 59, The number of Glucose molecules present in 10 ml of decimolar solution is 1) 6.0 x 10° 2) 6.0 x 109 3) 6.0 x 107! 4) 6.0 x 10 60. 0.1 gram mole of urea is dissolved in 100g. of water. The molality of the solution is 2).0.01M 3) 0.01m 4) 1.0M 61. Aqueous NaOH solution is labelled as 10% by weight. Mole fraction of the solute in it is 1) 0.05 3) 0.052 4) 0.52 2. 6 g. of Urea is dissolved in 90g. of water. The mole fraction of solute is DUS 21/50 B)HSH 4) 1/501 63. The density of 3 molal solution of NaOH is 1.110 gm/ml. Molarity of the solution is 1) 197M 3) 3.45 M BR, MF, and calculations 64. Molecules A) Glucos ) 2.45 Empirical formula B) Oxalic aci 2) CH,O C) Inorganic Ben 3) CH D) Oxygenated water 4) CHO, The correct match is ABCD A-B-C D D3 5 24 2ededmtes Sy 3-2 4 a8 23 i 65, A compound contains carbon and hydrogen in the mass ratio 3:1. The formula of the compound is ICH, 2) CH, 4) CoH, 66. The metal which can form an oxide having metal : oxygen atoms ratio 2:3 is 1D Bi 2) Sn 3)Na 4) Ba 67. An organic compound on analysis was found to contain 0.032% of sulphur. The molecular mass of the compound. If its molecule contains two sulphur atoms, i 1) 200 2) 2000 — 3)/20000) 4) 200000 68. The weight percentage of oxygen in NaOH is 4) 20 40 26 3)8 69. The empirical formula of acetic acid is the same as that of 1) Sucrose 3) Oxalic acid 4) Formic acid 70. A compound contains 90% C and 10% H. The empirical formula of the compound is 1) CHiy 2) C\sHyy =>’ CysHyo 71. 0.14 g of an element on combustion gives 0.28 g of its oxide. What is that element ? 1) Nitrogen é Carbon 3) Fluorine 72. 60g of a compound on analysis gave 24g C, 4g H and 32 g O. The empirical formula of the compound is YD GHO, 2) C,H,O, 3) CH,O, 4) CH,O 73. Caffine contains 28.9% by mass of nitrogen If molecular mass of caffine is 194, then the number of N atoms present in one molecule of caffine i; DEN B Wht D3 ye 3)5 46 = 74, Oyo HO Wy, 75 |. The weight percentage of nitrogen in urea (NH,CONKH,), is 1) 384 2466, 3) 59.1 4) 61.3 10g of hydrofluoric acid gas occupies 5.6 litre of volume at STP. If the empirical formula of the gas is HF, then its molecular formula will be (Atomic Mass of F = 19) DHF 2) HF, VRP 4) HF, ame76. 79. 80. Two elements X (At. Mass = 75) and Y (At Mass = 16) combine to giv having 75.8% of X. The formula of the compound is DRY KY and N compound 3) X,Y. ace compound made of C, H tains 20% nitrogen. What will be its molecular ass if it contains only one nitrogen atom in it? DO = =—-2) 1403) 100 4) 65 $.6g of an organic compound on burning with excess of oxygen gave 17.6g of CO, and 7.2g HO. The organic compound is 1) CH, oe. CH,COOH 3) C,H, An organic compound contains C = 40%, H = 13.33% and N = 46.67%. Its emperical formula is 1) C,H,N 2) C,H,N 3)CHJN 4) CHN An organic compound containing ‘C’ and ‘H’ has 92.3% of carbon. What is its empirical formula ? 1) CH, “ayCH 2)CH, 3) CH, Oxidation states 81. 82. 83 84, 85. When zinc is added to CuSO, solution, copper is precipitated, it is so because of 1) Reduction of Zn 3) Hydrolysis of CuSO, 4) Reduction of SO,>- Highest oxidation number that is exhibited by fluorine is )-l D0 3)+1 4)+7 Oxidation state of *S’ in S, molecule is yo 242 3) 4) 46 Oxidation state of Fe in K,[Fe(CN),] 1) +6 2) 44 oe 4) 45 Oxidation number and valency of oxygen in OF, are 1) +12 (2y#22 3) 41,1 4) 42,1 86. 87 88. 89. 90. o1 92. 93. 94. CHEMISTRY-1A _ In which of the following the oxidation state of chlorine is +5 ? 1) HCIO, (BYAGIO, 3) HCIO, 4) HCL All elements commonly exhibit an oxidation state of +l 2-1 Byer 4) +2. Thio sulphate reacts differently with iodine and bromine in the reaction given below 28,07 +, > 8,07 +21" $,02+4Br, +5H,0 — 2SO7 +8Br’ +10H* Which of the following statements justifies the itis behaviour of thisulphate? 2 2) Bromine is weeker oxidant than iodine 3) Thisulphate undergoes oxidation by bromine and reduction by iodine in these reaction 4) Bromine undergoes oxidation and iodine undergoes reduction in these reactions. The largest oxidation number exhibited by an clement depends on outer electronic configu- ration. With which of the following outer electronic configuration the element will exhibit the largest oxidation number ? 1) 3d'4s? 2) 3d?4s* ata 4) 30%! The element that always exhibits a negative oxidation state in its compounds is 1) Nitrogen The minimum oxidation state that nitrogen exhibits is 1) -2 2) Oxygen 4) Chlorine 34 4) -5 In the conversion of K,Cr,O, to K,CrO, the oxidation number of the following changes DK 2) Cr 3)0 4) None Oxidation state of N in NH is 1) +13 2) 43 Ses 4-1 Oxidation number of C in CH,O is 2) 42 1) -2 3)0 44GiEMISTRY-TA qs. Oxidation state of Ni in Ni(CO), is Do a4 38 96, Chlorine is in + 3 oxidation state in HCI 2) HCIO, 3) ICI 4)2 2)R;0 3) PbO, ‘reduction’ involves 4) H,0, 2) loss of electrons the valency of negative part 4) decrease in the valecny of positive part 99. The oxidation number of ‘Mn’ in potassium permanganate is 1) +6 3) 45 4) 48 100. The oxidation number of ‘N’ in NH, is +13 -2)0 Be 41 101.What is the oxidation state of carbon in carbondioxide? +2 GQ 346 4H 102.In the reaction : Pb,O, + 8HC! —> 3PbCI, + Cl, + 4H,O, the oxidation state of lead changes from : 2) 421044 to zero 4) +4 to zero 103.In the conversion of CrO;? > Cr,0}-. the oxidation number of oxygen 1) increases 3) becomes zero 104.(A) : Average oxidation number of chlorine in bleaching powder is rer. CoC Ly (R) : Oxidation number of chlorine is always zero. 1) Both A and R are true and R is the correct, explanation 2) Both A and R are true but R is not the correct explanation of A 3) Ais true but R is false 4) A is false but R is true 2) decreases Oxygen exhibits positive oxidation number 105. Oxidation number of carbon is zero in the compound ao 2) chloroform WAZ 4) carbon tetrachloride 1) methyl chloride 106. LIST - 1 % LIST - 2 on A) +3 state 1) Nitrogen No B) + 1 state 2) Nitrous oxide" ©) 0 stat 3) Nitrate ion NO D) +5 stat 4) Hydroxylaminie” Nady 5) Nitrite ion No The correct match is ABCD ABCD 11432 2) 3.2" 4<3. 3.453 1 45 213 107. If three electrons are lost by Mn’, its final oxidation state would be no 246 3420 444 108. Oxidation number and Covalency of sulphur in S, molecule are respectively 1) 6 and 8 2) 0 and 8 3) 0 and 2 4) 6 and 2 109. The oxidation state of Barium in Ba(H,PO,), is 143 QHD 3H 4 110. The number of electrons involved in the half- reaction Cr,0}- — 2Cr** + 7H,0 + 14H" is 3 26 3)5 4) 10 111.Sum of the oxidation numbers of carbon in acetaldehyde is Q+2 3-4 4d 112.In bleaching powder oxidation states of Cl are I-1, +2 22,41 DAt 4) 2,41 113.Oxidation number of sulphur in oleum (HS,0,) is 3-2 Mayer D+4 114. The compound formed in the brown ring test has the formula [Fe(H,O),NO] $O,. The oxidation state of iron in the compound is Deh 242 3)+3 4) zero 223 242115.In the reaction of chlorine with dry slaked lime, the oxidation number of chlorine changes i) from -1 to +1 ii) from + 1 to -1 iii) from zero to -1 iv) from zero to +1 The correct combination is 1) Only ii and ii are correct 3) Only i and ii are correct 4) Alll are correct 116. When copper is added to a solution of silver nitrate, silver is precipitated. This is due to i) Oxidation of silver ii) Oxidation of copper iii) Oxidation of silver ion iv) Reduction of silver ion The correct combination is 1) ii and iv are correct 2) i and ii are correct 4) All are correct 117. Average oxidation state of sulphur atoms in the thiosulphate ion 15.0 2/440 3)4+35 ana! 118. Oxidation numbers of sodium, mercury in sodium amalgam are ‘1) zero, zero, 3) -2, 42 119.Chlorine is passed into dilute, cold KOH solution. What are the oxidation numbers of chlorine in the products formed? 1-145 2)-1,43 3) 41,47 AEE 120. The oxidation state of sulphur in Na,S,O, is N32 228 BYSM 4) 25 121. The oxidation number of sulphur in $0, is DAD 2) +6 3) 444 45 122. Phosphorous exhibits highest oxidation state in 1) PH, 2) 4+1,-1 4) zero, +1 2) HPO, CHEMISTRY-IA 123. Iron has the lowest oxidation state in 1) FeSO, 2) K,[Fe(CN),] 3) Fe(CO),, 4) FeO 124. The oxidation number of Cr in CrO, is D+ 10- 2)+6 3)+4 4)+5 125.LIST-1 LIST-2 A)NI ) Oxidant B) KM 2) Both oxidant and reductant Cc) Soy Neither oxidant nor reductant 5) Dehydrating agent The correct match ABCD ABCD )4315 222 413 Byamamensy 4) 38 2 1 4 126.In the reaction, I, + 2KCIO,-> 2KIO, + Cl, i) Iodine is oxidised ii) Chlorine is reduced iii) Iodine displaces chlorine iv) KCIO, is decomposed The correct combination is 1) only i and iv are correct 2) only iii and iv are correct 4) all are correct 127. Oxidation number of iron in Na,[Fe(CN),NO] Dae 2) 43 3) 41 40 128. The oxidation number of phosphorus in sodium hypophosphite is 143 242 By 4) -1 129. Which of the following reactions does not involve the change in oxidation state of metal? 1) VO?V,0, 2) Na Nat BY Cro SCO} 4) Zn*-Zn 130. Oxidation state of oxygen in potassium superoxide is @E® »-1 3)-2 40EMISTR' “1,(A) : Oxidation state of carbon in glucose is zero (R) : Oxidation state of an atom in any element is 2er0 1) Both A and R are true and R is the correct explanation 3) Ais true but R is false 4) Ais false but R is true rypes of redox reactions 132. Fluorine does not undergo disproportionation because 1) Fluorine is always exhibit -1 oxidation state 2) Fluorine exhibit only two oxidaion numbers 3) Fluorine exhibit three oxidation numbers 4) None of the above 133.2HgO — 2Hg + O,, in the reactant Hg act as 2) Reducing agent 3) Oxidised 4) None of the above 4.2H,O, > 2H,O + O,. This reaction is an example for 2) Combination 1) Decor sition — 4) Both 1 and 2 35.K+Cl > KCl. This is an example of 1) oxidation 136.(A): F, + NaOH —> NaF + OF, + H,0 is an example of redox reactions with respect (0 fluorine. (R): of -1 in all its compounds 1) Both A and R are true and R is the correct explanation 2) Both A and R are true but R is not the correct explanation of A 3) Ai but R is 2) reduction 4) none of these Fluorine shows universal oxidation state 137. The conve example of on KMnO,~» K,MnO, is an 1) oxidation half reaction 3) oxidation and reduction 4) nither oxidation nor reduction 138. PbS + 4H,0, —» PbSO,+ 4H,O. In this reaction PbS undergoes 3) both 139. MnO, + 4HCI —» MnCl, + Cl, + 2H,O, In the reaction. MnO, acts as 2) reductant 3) both 4) none 140.In the reaction P, + 30H + 3H,O — 3H,PO, + PH, phosphorus is undergoing 1) oxidation 2) reduction Miuligemnamionation 4) hydrolysis 141.Which of the following undergo dispro- portionation during hydrolysis ? 1)N,0, 2) C10, 4) CO, 142. Which of the A and reduction reaction? 1) BaO,+H,SO,— BaSO,+H,0, 2) N,O,+H,0 > 2HNO, 3) AgNO,+KI— Agl+KNO, | 4) SnCl#HgCl, > SnCly+He 143.Which of the following is not a redox reaction? 1) 2BaO + 0, 2BaO, 3) 2KCIO, — 2KCI + 30, 4) SO, + 2H,8 > 2H,0 +38 144,2Cul > Cu + Cul, This reaction is 2) reduction 4) none of these 2) Neutralisation reaction 3) Oxidation reaction 4) Reduction reactionCHEMISTRY-1A 145.In a reaction between zine and iodine, in which zine iodide is formed, what is being oxidised 1) Zine ions 2) lodide ions 4) Iodine 146. Which one of the following reactions does not involve either oxidation or reduction 1) VO} > V,0, 2) Na Na* COS CHOY 4) Zn Zn 147. In the reaction : C,O2- + MnO, + Ht —> Mn + CO, + H,O, the oxidising agent is WMnOg 2)C,0, 3) Mn* 4) Ht 148. The reaction 3CIO™,,, —> ClO¥-g) + 2Clgg is an example of 1) Oxidation reaction 2) Reduction reaction +3) Disproportionation reaction 4) Decomposition reaction 149. The oxidation number of hydrogen in CaH, and NaH are respectively 1-1 and-1 2)+1and+1 3) +1 and-2 4)-2and-1 150.In the reaction : Cl, + H,S — 2HCI + S, the oxidation number of S changes from 1) 0t02 2) 2 to zero DEmzso 4-2-1 151. Which of the following is redox reaction 1) H,SO, with NaOH 2) In atmosphere, O, from O, by lightning 3) Evaporation of H,O aa neaa ese mornin, 152.C + 0,—> CO, This reaction is 2) Decomposition reactions 3) Displacement reactions 4) Disproportionation reactions 153, Which of the following is not chemical combinations 1) C+0,-+C0, 3) 2AL4N, 9 2AIN 2) $+0,-»SO, 154. Which of the following is decomposition reac 2) CH, + 20,-9CO, 3)S$+0,>580, 4) Cl, + 2KBr—2KCl + Br, 2H,0 155. Which of the following is not an example of a decomposition reactions 1) 2HgO > 2Hg +0, 2) 2H,0 + 2H,+ 0, 3) 2KCIO, + 2KCI + 30, 156. Following reaction describes the rusting of iron 4Fe + 30, >4Fe*+60*. Which one of the following statement is incorrect 1) This is an example of a redox reaction 3) , is an oxidising agent 4) Metallic iron is a reducing agent 157. Which one of the following is not prepared from halide by chemical oxidation process “DFP 2Ch 3y)B, 4L 158. The reactions of Br,, Cl, I, ,P, with NaOH involves 1) Decomposition 2) Displacement 159. Which of the following is metal displacement reaction 2) 2Na + 2H,O — 2NaOH +H, 3) Ca + 2H,0 — Ca(OH), + H 4) 2HgO > 2Hg + 0, 3) CombinationPRmeSRN Ree nee ree 160.2n + CuSO, ~ ZnSO, + Cu, Zn can act as 4) Oxidant 1) Oxidising agent 3) Reduced 161. Which of the following is a redox reaction? 1) NaCl+KNO, ~» NaNO,+KCI 2) CaC,0,42HCI~ CaCl, +H,C,0, 3) Mg(OH),+2NH Cl MgCl,+2NH,OH 4) Zn+2AgCN—>2Ag + Zn(CN), 162. Which of the following is not an example of disproportionation reaction? 1) Cl, + 2NaOH ~> NaCl + NaOCI + H,O 2) P,#3NaOH+3H,0 > PH,+3NaH,PO, 3) 2NaOH+2F,, > 2NaF+OF,+H,0 4) 2H,0,-42H,0+0, 163. In the reaction 3Mg + N, > Mg.N, 1) Magnesium is reduced 2) Magnesium is oxidised 3) Nitrogen is oxidized 4) Nitrogen is reductant 64. Which one of the halogen is prepared by only electrolysis method DC, By, 3F, 41 165. Which of the following is a disproportionation reaction 1) 2H,0,> 2H,0 + 0, 2) 2H, > 2H, +0, 3) 2HgO > 2Hg + 0, 4) Mg CO, > MgO + CO, 166. Which of the following is not metal displace- ment 1) Zn + CuSO, > ZnSO, + Cu 2) 2Na + 2H,O —> 2NaOH + H, 3) TiCl, + 2Mg Ti + 2MgCl, 4) 3Fe,O, + 8Al — 4A1,0, + 9Fe 167.1n the reaction 2A/ +N, —>2 AIN, Al is 1) Reduced 3) Oxidising agent 2) Oxidised 4) None of the above 168. When P reacts with caustic soda. The products are PH, and NaH,PO,. This reaction is an example of 1) Oxidation reaction 2) Reduction reaction 3) Oxidation and reduction 4) Neutralization reaction 169. Among the following ion the one that cannot undergo disproportionation CIO” 2)ClO; 3) ClO; 4) CIO, 170.3Cl,+ 6NaOH — SNaCl + NaCIO, + 3H,O, chlorine gets 1) Oxidised 3) Both 1& 2 2) Reduced 4) None of the above 171.Which reactions are useful to prepare hydrogen in the laboratory 1) Decomposition _2) Displacement 3) Combination 4) Disproportionation 172. 1n which of the following reaction there is no change in valency 1) 2H,0, > 2H,0 + 0, 2) CaCO, > Cad + CO, 3) 2H,O — 2H, +0, 4) 2HgO + 2Hg +0, 173.In C + H,O-> CO +H,, H,O acts as 1) Oxidising agent 3) (1) and (2) both 2) Reducing agent 4) None of these 174. The reaction is Decomposition but it’s not redox reaction 1) 2HgO > 2H, +0, 2) 2H,0 > 2H, +0, 3) Mg CO, > MgO + CO, 4) 2 KCIO, + 2KCI +30,CHEMISTRY, 175. Which one of the following generally gets displaced by more electro positive metals in nonmetal displacement reactions DH, YN, )F, 4) Cl, 176. KIO, + SKI + 6HC! —> 31, + 6KCI + 3H,0 Correct statement of this reaction is 1) Vis reduced to 1, 2) 10, is oxidized to 1, 3) 10, is reduced to 1, 4) Oxidation number of I decreases from —1 (in KI) to zero (in 1,) 177. When one mole of ozone completely reacts with SO,, the number of moles of $O, formed is 1 22 3)3 178.In the reaction, 3Br, + 6CO,> + 3H,0 —> SBr + BrO, + 6HCO, 1) Bromine is oxidised and carbonate is reduced 4) zero 2) Bromine is reduced and water is oxidised 3) Bromine is neither reduced nor oxidised 4) Bromine is both reduced and oxidised 179. The oxidation numbers of Mn in MnO, and [Mn(CN),}* are respectively. 1)+7 and +3 2)+6and +3 3)+7 and +2 4)+6and +2 180. In the reaction CO} +14H* +61" > 2Cr* +3H,0+1,. which element is reduced? DH 2Cr 3)0 4yt 181, In which of the following compounds transition metal is in zero oxidation state? 1) [Co(NH,),ICl, 2) [Fe(H,0),NO]SO, 3) Fe(CO), 4) K,[Fe(CN),] 182.Which group in p-block elements show highest positive oxidation state? 1) Group 16 2) Group 17 3) Group 18 4) Group 15 183. C,H, + H, —>C,H, In terms of redox reaction notations A) CH, is reduced 1) Ais true, but B 2) A is false, but B is true 3) Both A and B are true B) H, is oxidisea false 4) Neither A nor B is true 184. 4CIO;,44) -? 3CIO4(aq) + Chagy iS an example of 1) Oxidation reaction 2) Reduction reaction 3) Decomposition reaction 4) Disproportionation reaction Redox titrations 185, Excess of KI reacts with CuSO, solution and then Na,$,O, solution is added to it. Which of the statements is incorrect for this reaction? 1) Na,S,0, is oxidised 2) Cul, is formed 4) Evolved L, is reduced 186. Six grams each of magnesium and oxygen were allowed to react. Assuming that the reaction is complete, the mass of MgO formed in the reaction is, 1) 42 grams 2) 28 grams 3) 21 grams 4) 10 grams 187. Which one of the following is an example for disproportionation reaction ? 1) Znq) + CuSO yy, —5 ZNSO jug) + CU 2) AB ag) + AB) — 2AB ug) 3) Sy + Ong —4 SO, 4) Pug) + 30H, + 3H,0 __, PH) + 3H,POs ag) 188. The strength of an aqueous solution of I, can be determined by titrating the solution with standard solution of 1) Oxalic acid 2) Sodium thiosulphate 3) Sodium hydroxide 4) Mohr’s salt 228 DOCTORS SERIES for Sri Chaitanya Jr. AllMS Students(EMISTRY-IA gin the standardization of Na K.Cr.O, by iodometry, the eq of K,Cr,0, is }) (molecular weight)/2 5,0, using alent weight 2) (molecular weight\/6 4) (molecular weight)/3 4) same as molecular weight |99.qThe role of starch in jodometric titrations is that 1) it acts an oxidant 2) it is reducing agent 3) it acts as indicator 4) it is a medium 101. Number of moles of FeSO,, that can reduce one mole of permanganate in aqueous acid solutions is 2 a4 3)5 47 192. Equivalent weight of As,O , in the following equation As,O, + 21, + 2H,O — As,0,+ 4HT {at.wt. of arsenic = 75] 149.5 2)949 3) 99 Redox reactions and electrode processes 4) 156.6 193. Which of the following statement is correct for a galvanic cell? 1) Reduction occurs at cathode 2) Oxidation occurs at anode 3) Electrons flow from anode to cathode 4) All the statements are correct 194. In a electrochemical cell 1) Potential energy changes into kinetic energy 2) Kinetic energy changes into potential energy 3) Chemical energy changes into electrical energy 4) Electrical energy changes into chemical energy 195. The electrode potential of an electrode is 1) The potential applied to the electrode 2) The ionization potential of the material of the electrode 3) The tendency of the electrode to lose or gain electrons when it is in contact with its ions 4) The potential energy of the electrons in an electrode. 196, Which of the following may not be present in all galvanic cells 2) Cathode 4) Saltbridge 1) Electrolyte 3) Anode 197. Daniel cell is shown as Zn, 1 Zn su 1) Zn, 1 Zn aH Cu, / Cu? ogy 2) Zig) 1 Za gy Cu aay / CU) 3) Cuyy) / Cu * gy M Zn agy J CUys) 7s 2 4) Cu gy / Cty Zn" (aq) / Zt) 198. Which of the following metals will not react with solution of CuSO, ? Fe 2)Zn 3) Mg 4) AB, 199. In the copper zinc cell 1) Reduction occurs at the copper cathode 2) Oxidation occurs at the copper cathode 3) Reduction occurs at the anode 4) Chemical energy is converted to light energy Stoichiometric Calculations 200.The mass of CO, obtained when 2g of pure limestone is calcined? FIC AA 2 1) 44g 2) 0.22g 3) O.88g 4) 8.8g 201. What is the weight of oxygen that is required for the ene combustion of 2.8 kg of crore WAL 4 kg 3)96.0 kg 4) 9.6 ke 1) 28 kg 202.Xg of Ag was dissolved in HNO, and the solution was treated with excess of NaC/ when 2.87g of AgCl was precipitated. The value of X is 1) 108g 2)216g 3)2.70g 4) 162g 203. 1.2g of Mg (At. mass 24) will produce MgO equal to 1) 0.05 gm 2) 2g 3) 40 mg 4) 4g. 204.30 g of marble stone on heating produced 11g of CO,. The percentage of CaCO, in marble is 3) 83.3% 4) 86.6% 1) 75% — 2) 80%206 208 209 212. 213. 205, The weight of oxygen required to completely react with 27g of Al is 1) 8g 2) 16g 4) 24g produced when 3 moles of HCI react with excess of CaCO, is yt BEB 32 4) 2.5 207. The weight of a pure sample of KCIO, to be decomposed in order to get 0.96g of 2) 1.225g 4) None 3) 32g The number of moles of CC 3) 9.90g 6g of Mg reacts with excess of an acid, The amount of hydrogen produced would be ose = 2) Ig 3) 2g 4) 4g The number of moles of Fe,O, formed when 5.6 lit of O, reacts with 5.6g of Fe? 1) 0.125 2) 0.01 3,005 4) 0.10 What volume of H, at NTP is required to convert 2.8g of N, in to NH,? 1) 2240 ml 2) 22400 ml 3) 6.72 lit 4) 224 Jit . The number of grams of NaOH that comple- tely neutralises 9.8g of phosphoric acid is 1) 120 2)24 = 3) 364 The volume of CO, obtained by the complete decomposition of one mole of NaHCO, at STP is 1) 22.41 ‘Dana 3) 448L 4) 448 L Aluminium reacts with hydrogen chloride to produce H, according to the equation 2Al + 6HCI > 2AICI, + 3H, Then 2grams of H, would be produced from 1) 1 mole of Al 2) 2 moles of Al (3) 28 moles of Al) 4) 3/2 moles of Al 214.A peroxidase enzyme contains 2% selenium (Se=80). The minimum molecular weight of the enzyme is 1) 1000 2) 2000 4) 800 215 216 219 220. 221 222. 223. ___ DOCTORS SERIES for Sti Chaitanya Jr. AllMS Students The amount of Mg in gis. to be dissolved in dilute H,SO, to liberate Hy which is jus, sufficient to reduce 160g of ferric oxide is 1) 24 2) 48 372 4) 96 The mass of 80% pure H,SO, required tg completely neutralise 60g of NaOH is 192g 2) 58.8g 3) 73.5g 4) 98g Haemoglobin contains 0.33% iron (Fe=56) The molecular weight of haemoglobin is 68000. The number of iron atoms in one molecule of haemoglobin is 12 2)3 340 The number of moles of KI required to produce 0.4 mole K, Hg I, is 4KI + HgCl, > K,Hgl, + 2KCI D1 2)3 3) 16 4) 167 The number of molecules of CO, liberated by the complete combustion of 0.1 gram atom of graphite in air is 1) 3.01 x 10 45 2) 6.02 x 10° 4) 3.01 x 108 .5g of a sample of magnesium carbonate on treatment with excess of dilute hydrochloric acid gave 1.12 L of CO, at STP. The percentage of magnesium carbonate in the mixture is 42 -2)40 3) 84.4) 80 100 mL of PH, when decomposed produces phosphorus and hydrogen. The change in volume is : 1) 50 mL increase 2) 500 mL decrease 3) 900 mL decrease 4) none of these 8A1430HNO,-> 8 Al(NO,),+3NH,NO,+9H,0 as per thegiven equation the number of moles of the aluminium metal that can be oxidised by one mole of HNO, is 83 2) 830 3) 3/8 Copper metal rects with conctrated HNO, as Cu + 4HNO, -*-5 Cu(NO,), + 2NO, + 2H,0 The number of moles of the HNO, reduced by one mole of the Cu will be D4 2)2 3) 05 4) 30/8 4) 0.25ISTRY-IA Uncertainty in Measurement 374,0,00025 has how many significant figures? ns 23 3-4 42 495. The proper value of significant figures in 38.0 ** 0.0035 + 0.00003 is 2) 38.0035 4) 38.0 1) 38 3) 38.00353 226. The number of significant figures in electronic charge 1.602 x 10°C yI 22 44 227. The correctly reported answer of the addition of 4.523, 2.3 and 6.24 will have significant 3)3 figures 1) Two 2) Three 3) Four 4) Five 228. After rounding 1.235 and 1.225 to three significant figures, we will have their answers respectively as 1) 1.23, 1.22 2) 1.24, 1.123 3) 1.23, 1.23 4) 1.24, 1.22 29. The number of significant figures in mare 1) One 2) Two 3) Three 4) Infinite 230.On dividing 0.25 by 22.1176, the actual answer is 0.011303. The correctly reported answer will be 1) 0.011 3) 0.0113 2) 0.01 4) 0.013 231.8.281 has how many significant figures? 1 22 33 44 232. Which of the following is incorrect about S.1 units ? 1) Density in kgm-3 2) Force in Newtons 3) Pressure in Pascals 4) Amount of the susbtance in mol L"! 233. Planck's constant has the dimensions of 2) Work 3) Angular momentum 4) Torque 1) Force 234. Which of the following units represents the largest amount of energy? 1) Calorie 3) Joule 2) erg 4) Blectron-volt 235. Which of the following statement is correct? 1) There is no difference between precision and accuracy. 2) A good precision always means good accuracy 3) Accuracy means that all measured values of an experiment are close to the actual value. 4) A measurement may have good accuracy but poor precision. 236.The actual product of 4.327 and 2.8 is 12.1156. The correctly reported answer will be 12 2) 124 3) 12.12 4) 12.116 ANSWERS 01)4 02)2 ~-03)1-04) 405) 1 06)3 07)3 ««:08)3_-—«09)3— 10) 1 11)3 12)8-13)114)1—15)1 16)4 17)4 18)2 19)4 202 21)1 -22)1--23)1 24) 1-25) 2 26)2 27)4 += -28)4 29)4 30)3 31)4 32)4 = -33)1-34)3. 35) 4 36)4 37)1 38)2 39)2 40)2 41)4 42)243)244)1 45) 46)3 47/3 48)149)1 50)2 51)2 52)3.53)4 54)1 55) 4 56)4 57)2 58)1 59)1 60)1 61)2 62)3 63)2_-64)2_—«65). 66)1 67)4 += 68)1_-69)2_—-70)3 71)4 72)4 =—-73)2 74275) 3. 76)4 77)1 +=—-78)2-—«79)3 80) 4 81)2 82)283)1-84)3_aa5) 2 86)2 87)3_-88)1_—-89)3_-90)3 91)2 92)4 93)3 94)3 95)496) 4 101)2 106) 4 141)1 116)3 121)2 126) 3 131) 2 136) 4 141)3 146)3 151)4 156) 2 161)4 166) 2 171)2 176)3 181)3 186) 4 191)3 196) 4 201) 4 206) 2 211)4 216) 1 221)1 226) 4 231)4 236) 4 97)2 102) 3 107) 2 112)3 117)4 122)3 127)1 132)2 137)2 142) 4 147) 1 152)1 157)1 162)3 167)2 172)2 177)3 182)3 187)4 192)1 197)2 202) 2 207) 1 212)2 217)3 222)1 227)1 282) 4 98) 1 103) 4 108) 3 113) 4 118) 1 123) 3 128) 3 133) 1 138) 1 143) 2 148) 3 153) 4 158) 4 163) 2 168) 3 173)1 178) 4 183) 3 188) 2 193) 4 198) 4 203) 2 208) 1 213)3 218) 4 223) 2 228) 4 233) 3 99) 2 104)3 109) 2 114)4 119) 4 124) 2 129) 3 134) 4 139) 1 144) 1 149) 1 154)1 159)1 164) 3 169) 4 174)3 179) 1 184) 4 189) 2 194)3 199)1 204) 3 209) 3 214)3 219)3 224) 4 229) 4 234) 1 100) 3 105) 3 110)2 115)2 120) 3 125) 3 130) 1 135) 3 140)3 145) 3 150) 3 155) 4 160) 2 165) 14 170) 3 175)1 180) 2 185) 2 190) 3 195) 3 200) 3 205) 4 210)3 215)3 220)3 225) 4 230) 1 235) 3