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Abstract
Metal matrix composites (MMC) are one of the advanced materials widely used for aerospace, automotive, defence and general engineering
applications. MMC can be tailored to have superior properties such as enhanced high temperature performance, high specific strength
and stiffness, increased wear resistance, better thermal and mechanical fatigue and creep resistance than those of unreinforced alloys. To
fabricate such composites with ideal properties, the processing technique has to ensure high volume fraction of reinforcement incorporation,
uniform distribution of the reinforcement and acceptable adhesion between the matrix and the reinforcing phase without unwanted
interfacial reactions which degrades the mechanical properties. A number of processing techniques such as stir casting/vortex method,
powder metallurgy, infiltration, casting etc. have been developed to synthesize MMC employing a variety of alloy and the reinforcement’s
combinations. Among these infiltration process is widely used for making MMC with high volume fraction of reinforcements and offers many
more advantages compared to other conventional manufacturing processes. The present paper describes various infiltration techniques
used for making the Aluminium MMC
However, the depth and speed of the infiltration is influenced by 4.1. Spontaneous / Pressure-less Infiltration
the coefficient of permeability in the preform, which alters with the In spontaneous infiltration, the molten liquid metal invades
volume fraction of reinforcement. Yamanaka et al. [16] concluded into the voids of the porous body without the application of any
that the temperature, wettability and the volume fraction of external forces (Figure 2) [22-27]. This can be accomplished with
reinforcement in the preform regulate the coefficient of permeability the help of controlled temperature and gas atmosphere ensuring
in the system. An increase in the volume fraction of reinforcement good wetting conditions are maintained for self-permeation [28].
reduces the gaps and open porosity in the porous preform, which Numerous studies in pressure-less infiltration have been carried
reduces the ability of the liquid molten metal to get penetrated. out using Al–Si, Al–Zn, Al–Mg alloys into porous SiC preform and
Based on the experimental studies it is found that the permeability however there are some challenges that should be tackled to develop
k of a porous preform is directly proportional to the square of the spontaneous infiltration a very promising and industrially adaptable
mean diameter of the reinforcement [17]. method. Conventional drawback of the infiltration synthesis method
k=aD2 (1) is the poor wettability between the matrix and the reinforcement
resulting from the formation of oxide layer on the melt surface
where a is the constant which depends upon the reinforcement
[29]. Poor wettability negatively influences the infiltration process
morphology. Dobrzanski et al. [18] fabricated Al2O3 based preforms
by slowing down the infiltration process leading to undesirable
using carbon fiber as the pore forming agent and observed the
reactions at the interface resulting in the formation of intermetallics
increase of permeability with an increase in pore former content.
such as Al4C3 and Al3SiC4 in aluminium -SiC based systems [30].
The strength of the porous preform is negatively affected by Many researchers had investigated the effect of activator content
increasing the pore former content because it increases the porosity in pressure less infiltration of metal matrix composites [31]. Dwell
level and by randomness in distribution of pores. In accordance time and activator primarily controls the rate of infiltration. More the
with the above factor, non uniform distribution of pores in the activation more will be the infiltration depth. The amount of porous
preform will create difference in the collateral wall thickness and areas and residual porosity also govern the infiltration quality
cause inability to withstand localized stress concentration resulting but this can be reduced by increasing the activator content [32].
in deformation [19]. The grain size of the particles has great impact The wettability of preform by liquid molten metal is an essential
on the porosity hike and strength of the preform. Increase in the parameter for processing composites by pressure-less infiltration
grain size is inversely proportional to the mechanical strength of technique. Wittig et al. suggests that the addition of titanium in
the preform owing to low diffusion on grain boundaries [20]. The the steel matrix composites reinforced with ZrO2 particles helps in
morphology of the pores in the preform depends upon the kind and improving the wetting behaviour of liquid metal to ceramic preforms
type of pore former used in the system. Raddatz et al. [21] created [33]. Contreras et al. successfully infiltrated liquid magnesium into
hollow channels in the ceramic preform by integrating cylindrical TiC preforms by pressure-less technique [34]. Previous studies
shaped polymer fibers as pore forming agent. The binding agent in suggest that the wettability can be improved by adding 3 - 4.7
the preform plays a dual role, which imparts strength to the green mass percent of magnesium to the melt and also by using 100%
body as well as the sintered porous structure by bridging between nitrogen atmosphere in the furnace.
the particles.
4. Processing Techniques
The liquid infiltration processes can be broadly classified into two
categories: a) spontaneous infiltration and b) forced infiltration
(Figure 1). When capillary action of the reinforcement phase acts
as a driving force for infiltration, the category of processes is
termed as spontaneous infiltration. In forced infiltration an external
pressure such as gaseous, mechanical, squeeze, electromagnetic
etc. are applied to the liquid matrix phase which accelerates the
infiltration of molten metal through the preforms. The processing
details are briefly discussed here.
the interface. The reaction results in attenuating the oxide layer 4.2. Forced Infiltration
and act as driving force to promote wetting [35]. Schiroky et al. The infiltration process in which the aid of an external pressure
reported the PRIMEX™ pressure less infiltration process of SiC or mechanical force governs the infiltration of liquid metal into
and alumina infiltration by Al-Mg alloy. During the pressure-less the porous reinforcement is called forced infiltration. Poor wetting
infiltration process the Mg in the Al-Mg alloy at 800oC vaporizes between the molten metal and porous structure can be overcome
by endowing mechanical energy to force the metal in to the porous
and react with the nitrogen gas used as atmosphere for the process
preform. There are various types of forced infiltration methods and
to form Mg3N2 and deposits on the reinforcement surface. During
these are described below.
aluminum alloy infiltration Al react with Mg3N2 to form AlN and Mg
which promotes better wetting with the reinforcement [36]. Even 4.2a. Gas Pressure Infiltration
though, the primary motive for the use of nitrogen during infiltration An infiltration process in which pressurized gas (Figure 3) is used
is prevention of Al alloy oxidation it aids in reinforcement wetting as driving force for the penetration of molten metal into the porous
body. Gas infiltration process is normally carried out in combination
also. The effective chemical reaction between the constituents in
with vacuum at other end of the preform to get rid of entrapped
the molten metal and trapped gases in the porous preform cause
air to facilitate easy penetration at lower gas pressures [45]. Qi et
pressure drop in the preform and thereby improves the ease of al. suggests that the anti-pressure of gas in the porous preform
molten metal penetration. Nake et al. studies the spontaneous significantly slowdown the rate of infiltration, which increases with
infiltration mechanism of Al-Si-Mg alloy on SiC preform with the increase in infiltration depth and the temperature. As a result high
addition of Fe2O3 in the preform as additives to improve wettability. pressure is needed for complete infiltration of molten metal, hence,
The pressure reduction in the preform improves the suction of the anti-pressure of gases is to be considered during the analysis of
molten metal which helps to break the oxide film present at the threshold pressure. With the ideal gas equation PV = nRT, the anti
interface between the metal and the preform formed due to the pressure of gas can be expressed as [46]
reaction between the molten metal and the adsorbed moisture at
the infiltration front [37]. (4)
Generally, the wetting system of solid by a liquid is stipulated by where, p0 is the pressure of gas at initial time, T0 is the initial
contact angle and the contact angle, θ, at the solid, liquid and gas/ time temperature, L is the preform total length and Tz is the
vapour is related by the Young-Dupre’s equation [38]. temperature of the gas when the infiltration attains a height z.
Enhance in the infiltration temperature and pressure during gas
(2) pressure infiltration process improves the relative density of the
where, are the liquid metal surface tension, component, which shows an effect on the mechanical properties
surface energies of solid/vapour and solid/liquid respectively. The of the final composite [47]. Joseph Blucher concluded that the
molten metal will wet the solid preform, if that is, when fabrication of MMC by hydrostatic gas pressure infiltration holds
θ < 900. Similarly, if the above process is reverse in the case of non- certain advantages like low acquisition cost, high operational
wetting system a minimum pressure (threshold pressure) is to be flexibility for research purposes etc [48]. Al alloys reinforced with
exerted for infiltration. As stated by Darcy’s law, the infiltration rate Ni and Cu coated chopped, unidirectional carbon fibres and porous
of molten metal into porous preform is [39] graphite preforms were successfully fabricated using gas pressure
infiltration technique [49-51]. Non coated fibres can also be used in
(3) gas pressure infiltration technique due to the short contact time of
where, ν is the flow rate, k is the permeability which depends upon the matrix with the reinforcement. Drawback of the gas infiltration
the shape and sizes of the interconnected channels through which technique is the added cost of pressurized gas which usually is an
the molten metal flows, µ is the viscosity of the molten metal, p is inert gas.
the pressure (capillary pressure for spontaneous) correlated with
the size and shape of the pores that are in contact with the molten
metal and x is the infiltration distance. Surface modification of
reinforcements is also an effective method to circumvent interfacial
reactions and enhance wetting. Treatments include metallic
coatings like Cu, Ni, Zn, Ag, Si etc and high temperature treatment,
for example, of SiC leads to the formation of very stable surface
layer of amorphous silica [40, 41]. It has also been reported that
the coating of K2ZrF6, ZrO2 and Na2O in the fillers helps pressure-
less infiltration [42-44]. Continual investment and further process
optimization can ensure spontaneous infiltration techniques to
remain an attractive technique to synthesize composites in the time
to come.
Fig. 3. Schematic illustrations of gas pressure infiltration process Where, ρ is the density of molten metal, is the rotational
for the fabrication of MMCs: (a) infiltration process carried out with speed in rpm and L2 and L1 are the outer and the inner molten
vacuum to remove the entrapped air in the preform to facilitate metal's level from the rotation axis. To develop the near net
easy molten metal penetration, (b) applying pressurized gas as a shape components and to avoid the material wastage typical
driving force for metal infiltration and (c) final composite. centrifugal infiltration technique is adopted. In order to achieve high
4.2b. Pressure Die Infiltration pressure centrifugal infiltration, a slight modification within the
Pressure die infiltration process involves placing a porous same centrifugal system used for conventional process is made
preform inside a solid die and applying pressure with the help of a by extending the inner molten metal level L1 from the rotational
movable piston to allow penetration of liquid metal in the porous axis (Figure 7b). In such cases liquid metal pressure acting on the
preform (Figure 4 (a and b)). Process parameters that are optimized preform will be given by
include speed, die temperature and pressure of the piston. Main
advantages of this process are low cost and ability to fabricate (6)
components of high complexity and precision. The deformation Surface coated and non-coated carbon short fiber preforms were
of preform due to the pressure of the molten metal before and successfully infiltrated by centrifugal process and the optimum
during infiltration will be high for pressure die casting compared preform preheating temperature for non coated fiber for the
to squeeze casting owing to high compression rate of preform smooth penetration of molten metal is above 873 K (6000C),
during infiltration. Rasmussen et al. suggests that by increasing whereas for nickel coated carbon fiber preform is 673 K (4000C)
the volume fraction of the reinforcement leads to stronger preform [54]. In addition, surface pressure of the porous preform is reduced
which can prevent preform deformation, but at the same time it will perceptibly as the molten metal starts to infiltrate and once when
prohibit the ease of infiltration [52]. the metal gets penetrated into the preform the pressure of the
infiltrated region falls under the threshold pressure. The adhesion
between the molten metal and the reinforcement will not get
separated due to the fall of pressure in the infiltrated zone below
the threshold pressure. However, to achieve a complete infiltration
of molten metal throughout the porous preform, the pressure on the
infiltration front should exceed the threshold pressure [55].
4.2d. Lorentz Force Infiltration
Lorentz force infiltration process is a novel infiltration process in
which electromagnetic force is used to propel the molten metal
into the ceramic preforms. During the process, the preform gets
immersed in a liquid molten metal which is subjected to an high
frequency magnetic pulse. Simultaneously, eddy current persuaded
in the liquid metal gets interact with the magnetic pulse and develop
a Lorentz body force in the liquid molten metal causing the liquid
metal to enter into the ceramic preform at a high speed. Richard M.
Andrews and Andreas Mortensen had successfully fabricated void
Fig.4. Schematic diagrams of pressure die infiltration process for
free aluminum/Al2O3 fiber composite by Lorentz force infiltration
the fabrication of MMCs: (a) before applying pressure to molten
technique. They suggested that the infiltration depth depends upon
metal using plunger and (b) after applying pressure to molten metal
the nature and number of discharges [56].
using plunger to form the composite.
4.2e. Ultrasonic Infiltration
4.2c. Centrifugal Infiltration
In ultrasonic infiltration process, pressure waves generated by
In centrifugal infiltration process, rotational / centrifugal force is
the ultrasonic vibration assists in the penetration of the molten
used to infiltrate porous preform with liquid molten metal. During
matrix material in the ceramic preform. When ultrasonic vibration
the fabrication of composites porous reinforcement material is
is actuated through a horn in the liquid molten metal acoustic
positioned inside a mould (at the end) having an elongated runner,
cavitations (bubbles) are originated. The air entrapped in the porous
which was filled with molten metal. Large rotational velocities of the
preform and the dissolved gas in the molten metal can become the
runner initiate centrifugal force with required drive for infiltration to
cavitations nuclei. When a bubble collapses shock wave originate
overcome the threshold pressure for melt penetration and viscous
close to the molten metal resulting in infiltration process [57, 58].
forces of the molten metal to flow in the preform. The molten metal
pressure exerted on the porous preform during centrifugal force is The important process parameters considered for the ultrasonic
given by [53] infiltration is ultrasonic power, hole in the horn and fabrication
speed. Increase in the diameter of the hole in the horn decrease
(5) the infiltration ratio due to the depletion in the formation of acoustic
4.2f. Vacuum Infiltration In light of the above, the application of higher squeeze pressure
accelerates the infiltration process but leads to crumpling or
Vacuum infiltration involves a negative pressure infiltration in which
cracking of the porous preform. Numerous studies regarding
matrix metal gets penetrated into the evacuated preform due to the infiltration pressure have been done by many researchers. Guan et
application of suction pressure. Process parameters like infiltration al. [73] investigated the threshold pressure and infiltration behaviour
temperature, infiltration time and applied vacuum (~300-500 of liquid metal into the porous preform. The infiltration rate can be
mm Hg) plays a crucial role in this process [62]. Infiltration rate improved effectively by raising infiltration pressure, but the effect
gets increased with increasing the molten metal temperature and will gradually diminish with the advancement in time. Increase in
by applying coating on the reinforcement, thereby reducing the infiltration pressure minimizes porosity, reduces the heat loss and
hinders the solidification of liquid metal front effectively. According
infiltration incubation period to avoid brittle interfacial reactions [63].
to Darcy’s law the expression for the square of infiltration height as
Low solidification rate of the final component during processing can
a function of infiltration time and difference in infiltration pressure
be stepped up as one of the disadvantage of vacuum infiltration of the liquid metal is [74]
which enhances the grain growth of the matrix metal and interfacial
(7)
reaction between matrix and the reinforcement [64]. To avoid the
liquid molten metal getting into the vacuum pump by chance during where p is the applied pressure, p0 is the threshold pressure for the
infiltration process one portion of the connection pipe is filled with initiation of infiltration, infiltration time t, µ is the viscosity of molten
metal, vs is the volume fraction of solid and k is the permeability of
metal chips, so that the molten metal entering in to the pipe gets
the porous solid. The threshold pressure p0 for infiltration can be
solidified in that particular area without damaging the vacuum pump. obtained as [75]
Studies have shown that Al and Mg based composite materials with
(8)
more than 50 vol. % reinforcement can be successfully fabricated
using vacuum infiltration technique [65]. Where λ is a geometrical factor represent the deviations from
particle/fiber shape, surface roughness and actual particle/
4.2g. Squeeze Infiltration fiber size distribution. The basic governing phenomenon for the
Squeeze infiltration is one of the widely used methods for the infiltration of metals, ceramics and polymers into the porous
production of near net shape metal matrix composites with close preforms are fluid flow, capillarity and the behaviour of preform
control over shape, volume fraction, chemistry and distribution of deformation, which in turn are decided by preform permeability,
reinforcement [66-72]. This process offers advantages over other volume fraction of reinforcement, preform stress-strain behaviour,
pressure-dependant saturation of melt in the porous preform and
conventional methods for fabricating composite components which
the melt viscosity.
are difficult to be machined. The process involves the formation of
porous preform as the reinforcement and its infiltration with the The strength and stability of preform during infiltration depends
molten matrix material under pressure (Figure 5) typically in the upon the mode of fabrication of preform, type of binder and the
reinforcement used. Reinforcements having lubrication nature
range of 50-100 MPa [22]. The appropriate magnitude of applied
enhance the tendency of sliding over one another thereby
pressure ensures eradication of porosities, refined microstructure, increasing the chance for deformation of the preform. Similarly
enhanced processing speed and termination of chemical reactions. during the fabrication of layered preform equality in the stacked
For the development of quality composites processing parameters layers reduces the preform compliance [76]. A new technique for
of squeeze infiltration have to be optimized. the direct measurement of capillary force is by drainage curve
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2
Aditya Birla Science & Technology Company Pvt. Ltd, MIDC Taloja, Maharashtra, India
3
Veer Surendra Sai University of Technology, University of Burla, Odisha, India
Corresponding author: sahoo.mahesh@adityabirla.com
Abstract
Primary aluminium production process poses a threat to the environment due to generation of hazardous waste like the spent pot lining
(SPL). This has led the researchers to focus on 4R (Reduce, Recycle, Recover, Reuse) approaches to minimize the impact of SPL on the
environment. Worldwide aluminium smelters have been looking into ways to reduce the SPL generation per tonne of Al produced, such
as enhancing cell / pot operational life, as well as by reusing and recovering value from SPL by its utilization in both cement and ferrous
industries as well as coal-fired power plants. Hindalco’s Hirakud smelter has also been utilizing the 4R approaches with a goal to minimize
the SPL impact on the environment. This paper highlights the redesign approach adopted by Hirakud smelter, which has led to reduce the
SPL generation significantly. The paper describes the modification in the cell lining design and materials to enhance pot performance and
pot life, thereby reduce the SPL generation from 20.41 kg/t Al to about 15.55 kg/t Al. To enhance the energy efficiency of pot, copper-insert
collector bars have also been utilized, which are reported to enhance the pot life, thereby further potential of reducing the SPL generation
to the level of 14.14 kg/t Al. Apart from the redesign, other approaches such as recycle, recover and reuse have also been looked upon for
effective SPL management.
Keywords: 4R approach, Pot life, Cell lining, Spent pot lining (SPL), Aluminium smelter.
1.INTRODUCTION frost heave damage and a freezing isotherm too far down into the
Primary aluminium is produced using an electrolytic process, also insulation refractory layer results in damage of the insulation layer,
known as Hall-Héroult process, from the alumina dissolved in to the which is usually less dense and less salt resistant then the upper
molten cryolitic bath. The electrolytic process occurs in a steel pot, refractory layer. The thermal conductance of the sidewalls should
which is lined with refractories, to offers mechanical and chemical result in a proper ledge shape and thickness.
stability. The lining refractory is typically made of two layers, an
insulating refractory, which house a carbon cathode along with
collector bar to allow the current flow. The cell usually operates for
about 4 to 8 years before it fails. The life of the cell usually varies
from plant to plant based on the cell technology & operational
amperage. There are various factors, which affect cell operational
life, e.g., cell design, quality of lining materials, preheating, start-
up procedures and thermal disturbance during cell operational life.
Precise start-up procedures and efficient operation play key role in
attaining a satisfactory life of a cell. The thermal, mechanical and
chemical properties of cathode and lining materials may also lead
to failure, if the cell is not designed correctly to ensure isotherms
in proper locations. Figure 1 shows a typical cross-section of a
Hall-Héroult cell, highlighting cell-lining materials such as carbon
cathode, refectory and insulation materials. The cell lining design
should ensure that the electrolyte freezing isotherm in the lining
(~780 °C) should be just below the cathode blocks into the high Figure 1. Cross-sectional view of Hall Héroult cell.
dense refractory brick, made of silica and alumina. Due to capillary There are certain phenomena related to cathode and its properties
action, bath impregnation takes place after the sodium front has that may lead to pot failures, for instance, wear of cathode surface,
moved through the carbon and only through the porous network Na diffusion and intercalation, pothole formation etc. Wear rate of
formed by the volatilization & shrinkage of the binder during baking cathode is also dependent of current density [2]. Most of the current
[1]. A freezing isotherm inside the carbon blocks may result in tries to concentrate towards the end of cathode block due to the
least resistant path of electrical current, in such a way that the 2 SPL Management at Hirakud Smelter
cathode top surface acquires a W-shape pattern after completion of Hirakud smelter had taken several strategic & sustainable initiatives
its normal life. To avoid this, the collector bar assembly-to-cathode adopting the 4R approach for SPL management. The practices
block electrical resistances ratio may be modified by means of followed at Hirakud smelter focus on protecting human health and
altering both materials and design. Copper-insert collector bar the environment from impacts associated with generation, storage,
(CuCB) tends to provide (a nearly) uniform current distribution, handling, transportation and disposal of SPL. Following section
which aids in enhancing the pot life [3]. explains the modification in cell lining design, which resulted in
The Hirakud potline has end-to-end cells with upstream risers, improving the pot life and reduction in SPL generation.
which offer uncompensated magnetic field, leading to higher metal 2.1 Redesign of Cell Lining
velocities and MHD instability [4]. These pots utilize semi-graphitic While redesigning the lining of a cell or pot, its thermal balance
cathodes (30% graphite) and old lining design with a tendency to needs to be analyzed critically with respect to isotherm location
form a ledge toe extension under anode shadow, which increases in the refractory. Ledge toe extension underneath anode or hard
the chance for pothole formation. There were also operational deposits on the cathode surface enhances the wear rate and chance
disturbances like anode spikes, bottom sludge and muck, which of pothole formation, thus affecting pot life. Presence of extensive
may aggravate the pothole formation. These are the some of the ledge and sludge can lead to an uneven current distribution in the
factors which have adversely affected the life of Hirakud pots, cell, resulting in MHD instability, which adversely affects the cell
resulting in higher SPL generation. In this study, these aspects operation and, consequently, requires higher anode-to-cathode
have also been looked upon carefully, while redesigning the cell distance (ACD) [8]. Hence, for efficient cell operation at minimum
lining to enhance the performance and pot life thereby reducing ACD, the cell lining design should ensure a nearly vertical ledge
the SPL generation. These modifications have been discussed in profile along with the isotherm location at an appropriate position
subsequent sections. in the refractory lining of the cell. This would not only prolong the
1.1 SPL Management life of the cell but also improve its performance. A new lining design
After the completion of cell operational life, the used lining of was developed to reduce the SPL generation by means of reducing
the pot is classified as spent pot lining. The SPL is composed of the mass of lining materials used in a pot along with improving the
a first-cut (the carbon lining) and a second-cut (the remaining thermal balance of pot.
refractory lining). During the production of one ton of aluminium, For this purpose, a thermo-electric model has been utilized to
a smelter produces about 25 kg of SPL waste with high content of analyze the cell lining design and material modification. Additional
carbon fluorine compounds, alumina, various cyanides, aluminium information regarding thermo-electric model development for
nitride, aluminium carbide, etc. [5]. In general, fluoride is present Hirakud 85 kA cell and its validation with industrial measurements
in both carbon and refractory layers at around 1–2 wt. % whereas can be found in literature [9]. In this study, simulations have been
cyanide (CN) content in SPL is low and varies across cuts, though performed for analyzing changes in cell lining materials, lining
on average CN is around 60 ppm by weight [6]. The hierarchy of design and CuCB. Desired thermal balance of the new cell was
SPL management focus first on reducing the generation itself, by obtained after performing multiple simulations where the results
means of redesigning and enhancing the pot life. Subsequently, yielded by proposed changes in design and materials were analyzed.
the preference should be given in descending order to recycle, The cell lining design has been modified around the cathode block,
recover and reuse. The last option is responsible disposal, in which as shown in Figure 5, to alter the heat loss distribution from the
care must be taken on adoption of appropriate storage, handling, cell for improving the thermal balance of the cell and electrolyte
treatment, transportation and disposal processes. Hence, the 4R freezing isotherm placement in the refractory.
approach is adopted worldwide for SPL management to minimize
the impact on environment, which are described as follows:
a) Reduce or minimizing SPL generation through redesign of pot
and optimization of the process;
b) Recycle by using the part of the old pot lining material in a
new pot [7] or restarting a stopped or shunted pot by means of
patchwork, to utilize the same pot lining material;
c) Recover by conversion of carbonaceous part of SPL into useable
heat, electricity or alternate fuel, e.g., use of first-cut material in Figure 2. Cell lining modification. Left: old lining design, Right: new
coal-fired power plant; lining design with CuCB.
d) Reuse by utilizing SPL waste into ferrous, non-ferrous and The new lining design helped in attaining uniform current
cement industry. Example of using SPL in cement and ferrous distribution, a nearly vertical freeze profile with a smaller toe and
industry has been discussed in the following section. a thicker ledge at metal-bath interface, thereby providing energy
saving as well as potential for improvement in pot life. This design
modification was associated with changes in the quantities of lining found that the erosion rate of cathodes is much smaller when
materials. Table 2 shows the changes in the quantities of different compared to the old design pot. Based on this result, pot life is
lining materials for new cell lining design as compared to the old expected to exceed 2200 days, which would help in attaining a
one, excluding the collector bars. SPL generation of about 14.14 kg/t Al or a 30.7 % reduction with
respect to the original figure.
Table 2. Modification in cell lining materials quantities (in tonnes).
3. Conclusion
Cell Lining Materials Old Lining New Lining
Spent pot lining is a hazardous waste and a major threat to the
design (t) design (t)
environment. It is being managed by Hirakud smelter by adopting
First Cut Material Total = 8.60 Total = 7.80 4R (Reduce, Recycle, Recover & Reuse) approach. This work majorly
1. Cathode & Tamping Mix A 1. 6.20 1. 6.20 focuses on the first “R”, i.e., redesign of pot lining to reduce the
2. Carbonaceous Groove Mix-B 2. 0.40 2. 0.00 SPL generation. Pot lining was redesigned to improve the thermal
3. Carbonaceous Seam Mix 3. 2.00 3. 1.60 balance, ledge profile and isotherm location in the refractory by
Second Cut Material Total = 12.47 Total = 10.41 modifying the lining design and materials along with Cu-insert
collector bar. This has not only improved the pot performance
1. Dry Barrier Mix 1. 6.50 1. 5.50
with respect to the energy efficiency, but also improved the pot
2. High Strength Insulation Bricks 2. 1.73 2. 0.16
life. The new design pots are already running for the last 5.5 years
3. Low Strength Insulation Bricks 3. 0.12 3. 0.00
and offering an extended pot life of more than 200 days along with
4. High Strength Impervious 4. 1.40 4. 0.40
reduction in lining material quantity by about 3 tonne as compared
(Castable)
to old design. The new cell lining design reduces the SPL generation
5. Refractory Brick 5. 0.27 5. 1.35
from 20.41 kg/t Al to about 15.55 kg/t Al, or 23.8 %. Based on
6. Insulation Board 6. 0.27 6. 0.82
cathode surface measurement, the pot life is expected to exceed
7. Remaining Material Unchanged 7. 2.18 7. 2.18
2200 days, which provides further reduction potential in SPL
The simulation analysis incorporating the CuCB helped improving generation to about 14.14 kg/t Al or 30.7 % with respect to the
the current distribution in cathode block, hinting towards a positive original figure.
influence on pot life [3]. The simulation results also show that 4 References
cell lining modification has improved the ledge profile as well 1. M. Sorlie and H. A. Øye, Evaluation of cathode material properties
as cathode temperature profile, which would improve the cell relevant to the life of Hall-Héroult cells, Journal of Applied
operating condition. Table 3 shows the performance comparison Electrochemistry, Vol 19, (1989), 580-588.
between old and new lining designs, where both a 2.1 % reduction
2. Pretesh Patel, Margaret Hyland and Frank Hiltmann, Influence of
in specific energy consumption as well as a 13.6 % increase in pot
internal cathode structure on behaviour during electrolysis part III:
life have been effectively achieved. Wear behaviour in graphitic materials, Light Metals 2006, 633-638.
Table 3. Comparison of pot performance. 3. Amit Gupta et al., Energy Reduction Initiatives to Improve Low
Old Lining New Lining Amperage Cell Performance, Proceedings of 35th International
Design Design ICSOBA Conference, Hamburg, Germany, 2-5 October 2017, Paper
AL35, Travaux 46, 1135-1142.
Current (kA) 85 85
4. Amit Gupta et al., Electromagnetic and MHD Study to Improve Cell
Pot Voltage ex. Line Loss (V) 4.38 4.31 Performance of an End-to-End 86 kA Potline,” Light Metals 2012,
Current Efficiency (%) 93.0 93.5 853-858.
Cathode Voltage Drop (mV) 350 270 5. Rudolf P. Pawlek, Spent Pot lining: An Update, Light Metals
Pot Specific Energy 14 035 13 734 2012,1313-1317.
Consumption (kW.h/t Al) 6. Mohammad Al Jawi, et al., Environmental Benefits of Using Spent
Pot Lining (SPL) in Cement Production, Light Metals 2020, 1251-
Pot Life (Days) ~ 1760 ~ 2000
1259.
New design pots have been running efficiently over the period of 7. Aleksandr V. Proshkin et al., New Resource-Saving Technologies for
last 5.5 years. The new lining design offers a reduction of about Lining the Cathode with Un-shaped Lining Materials, Light Metals
3 tonne in the virgin lining materials (both carbon & non-carbon 2019, 573-581.
parts). However, the actual reduction in SPL quantity will be known
8. Amit Gupta and Biswajit Basu, Sustainable Primary Aluminium
only after completion of its operational life. Autopsy of an old design
Production – Technology Status and Future Opportunities,
pot revealed that SPL quantity was increased by about 8–9 % Transactions of the Indian Institute of Metals, Volume 72, Issue 8,
compared to virgin material. Therefore, a similar increase in weight (2019), 2135–2150.
has been assumed for the new cell lining design in such a way that
9. Amit Gupta et al., Investigation of Cathode & Collector Bar
the new design potentially offers a reduction in the SPL generation
Modification on Thermal Balance of Low Amperage Cell, Light
from 20.41 kg/t Al to about 15.55 kg/t Al, or 23.8 %. Measurement
Metals 2015, 747-752.
of cathode surface wear was performed in new design pots and
Abstract
Overhead line systems are dependent on a multitude of different factors. The lines must be capable of operating reliably in all environmental
conditions and should have as low an impact as possible on the environment. There are modifications, extensions and developments from
time to time in existing networks to manage & accommodate the continuous increase in power demand. River crossing involved in any
transmission line is most critical link of the line. It must be safe & sound from design considerations to be able to withstand field conditions
and any unexpected changes in climate resulting in cyclones/ storms, speedy winds, floods & changes in the course of rivers.
Keywords— HPC, High temperature low sag, AACSR, GZTACSR, ACCC, Sag-Tension, Ampacity, Electrical clearance.
1.INTRODUCTION
This paper is on the details of solution provided to a long river
crossing span 1099 mtr (i.e without intermediate tower) in the 400
kV DC- river crossing - Purina Bihar Sharif line. Due to change in
course of the river Ganga & high velocity water flow, pile foundations
were damaged on the towers of the 400 kV DC line in the middle
of Ganga river. As a result, the line was in a de-energized condition
for a prolonged period. This is non-navigable river where small
boats etc can’t be used. And waters were at the highest level due
to floods. To revamp the line, the feasibility of various technology
(AACSR, GZTACSR & ACCC-[1]) of High Peformance Condutor (HPC)
products were analysed. Post detailed deliberation, a new and Fig 1 : Existing line profile shows tower with either side of middle
permanent solution was provided - newly designed conductor & tower (intermediate tower) with 550 span & 549 span
earth-wire, considering all the key requirements like ampacity, sag
tension, RIV – Corona, phase & electrical clearance. 3. CHALLENGES IN RESTORATION
The possibility of line restoration was analysed by line diversion,
The product solution circumvents the need for intermediate towers/ enhancement of water level & other condition. In connection with
foundations and also there is no need to increase height of the this, if the fallen tower is bypassed, the total span would increase
tower. to 1099 mtr (i.e by connecting either side of the tower).
2. DESCRIPTIONS OF RIVER CROSSING Further, increase of the span challenged the sag clearance from
400kV Purnia-Bihar Sharif D/C line was out of service from 10th highest flood level (HFL). To cater to the present load demand, line
Aug 2018 due to the change in the course of the river Ganga and could be restored using special High Peformance Conductor (HPC),
heavy velocity of flow of water which led to tower collapse (pile which meets the sag with increased span without compromising the
foundation). Post flooding when water started receding, various power transfer requirements. These special conductor meets the
emergency restoration plans were proposed to ERPC[2] to charge high capacity needs & performance testing on some applications.
the line temporarily. The existing line conductor, quad AAAC 525 However, it’s the first case where such solution was provided for
mm2, in a double circuit tower can transfer 1600 MW per circuit. river crossing.
A unique solution with new design & development of both conductor 4.SOLUTON
& earthwire for a critical long river crossing span, revamped the Planning for the permanent restoration of the line using special
EHV - 400 KV Purina Bihar Sharif line by the end of 2019. high-performance low sag conductor ( i.e ACCC[1] Conductor)
Accomplishment Of Resolution between tower AP46/9A and AP47/1 as single long span of 1099
Initially the plan was to restore the line temporarily. It was with mtr. The critical sag requirement & power transfer for double circuit
single long span having not intermediate tower, single circuit configuration has been meet in newly designed conductor & earth
configuration. Various conductor technology & earth wire for with respect to limitations as per below table 4.
suitability were analysed. This imposed the challenge of meeting the
sag requirement in single circuit with long span. Sag requirement
fixed as 38 mtrs to ensure the 10 mtrs extra clearance from HFL.
Detailed mentioned below table 1.
7.IMPACT 9.REFERENCE
a. Social Impact – Eliminating the requirement of prolonged [1] CORE – CTC F-730-532-F www.ctcglobal.com Date Produced:
shutdown of the line and faster power transmission and permanent 3/29/2019.
solution
b. Cost & Time reduction – [2] - Agenda for 162nd OCC Meeting date 22.10.2019, Eastern
Regional Power Committee.
i. No intermediate tower and its foundation (pile type).
ii. No need of any special tower type (i.e increased heights) [3] - Relevant standards are as mentioned below,
resulted into substantial cost & time saving. ASTMB609-Specification for Aluminium 1350 round wire, annealed
c. Benefits – No derating of the line and 100% Power transfer and intermediate tempers, for electrical purpose.
(1600 MW/Ckt) ASTMB857-Standard Specification for Shaped Wire Compact
8.CONCLUSION Concentric-Lay-Stranded Aluminum Conductors Coated-Steel
The summary of outcome & benefit with these new developments Supported (ACSS/TW.
are as follows
ASTM B987 Standard Specification for Carbon Fiber Thermoset
1. Special characteristics of ACCC[1] conductor such as low thermal Polymer Matrix Composite Core (CFC) for use in Overhead
expansion, high strength to weight ratio addressed the critical Electrical Conductors.
challenges of sag & ampacity.
2. Newly Designed Earthwire with special steel results in less sag EN 50540- Aluminium Conductors Steel Supported (ACSS) for
& meets the electrical clearance whereas normal Earthwire & overhead lines.
OPGW cause electrical clearance issues. [4] - HPC specification in line with current test protocol of PGCIL
3. Without reducing the power transfer for single long span, double tender (CC-CS/912-NR1/TW-3957/3/G3.
circuit solution provided by meeting critical clearance. [5] - core validation report No. 54264 , Qct 18, 2019.
4. Need for intermediate tower & pile foundation eliminated
[6] – Complete Conductor validation report No. CT/102/ 19-20 vide
resulting in huge time & cost saving with implementation of
dated Jan 01, 2020.
single long span.
5. Re-energizing the line will impact to social lives by quick transfer
of power
6. Application of ACCC[1] Technology first time in long single span.
7. Application of special high strength earthwire in long single span.
8. The line consists of two technology I,e. AAAC & ACCC conductor
connected by suitable jumpers have 75% DC Resistance of
conductor.
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About the author: Shankhadeep is based in CRU's Mumbai office as team leader of CRU’s India office and works across the aluminium
and steel team and has over 12 years of experience in the metals and mining industry. He has worked in many countries across different
functions including strategy, market research, working capital management and corporate finance. He has a bachelor's degree in chemical
engineering from Jadavpur University, Kolkata and an MBA in finance and operations from Xavier Institute of Management, Bhubaneswar.
India’s coal-dependent power infrastructure gives the country a When we see Scope 1 and Scope 2 emissions in aluminium from
high-carbon intensity for metal production. CRU’s Global Carbon CRU’s Global Carbon emissions service (figure 2), we see that
Emissions Service will help to solve this complex power puzzle emissions from power generation used in aluminium is the most
Data from CRU’s Global Carbon Emissions Service shows the average significant source of aluminium carbon emissions. Elsewhere,
intensity of CO2 emissions from Indian aluminium production is 48% carbon emissions have been low where hydropower is available
higher than the global average. This is unsurprising as a significant for smelting.
proportion of India’s power production is coal-based. Hydropower generation is independent of market variations and
Indeed, India’s environmental and developmental context is visible provides relatively constant power tariffs, making it an attractive
in the country’s power mix. For example, hydropower, which power source for smelters. However, generation capacity can
globally reduces carbon emissions in aluminium production, is a vary largely with local meteorological conditions, like with other
power source which brings its own share of problems in India. And renewable energies. Hydropower may also provide significant cost
while India does not have a carbon tax as defined in the rest of the advantages. For example, smelters in Canada have the lowest
world, there are other ways in which India does tax carbon in coal. power cost partly due to Rio Tinto’s six smelters which benefit from
the world’s cheapest electricity rates from hydropower plants with
Indian aluminium producers can reduce their emissions, but the
long-term amortised capital charges.
approach may be very different to other parts of the world. In this
Insight, CRU explores the challenges and seeks to answer some of Figure 2: Hydropower and renewable energy helps reduce emissions
the most pressing questions.
Indian power generation growth will be primarily coal-based
The growth in power generation in India is expected to be primarily
driven by coal. While there is competition expected to come from
renewables – particularly from solar and wind – the share of coal
is expected to remain high. Though the share of power from coal
is expected to reduce only to 59% by 2030 (compared to 70% in
2019), actual power production from coal is expected to increase
from 1,166 TWhr in 2019 to 1,492 TWhr in 2030.
Figure 1: Coal will continue to be a major contributor to Indian
power production
is government-owned (93% of installed capacity). Nearly half of at INR400 /t of coal. Any user of coal (thermal power plants or
the present installed capacity (40GW) is in Northern India (19GW) captive power plants) needs to pay this price over and above the
and almost 65% of the total hydro potential (94GW) is yet to be notified prices of Coal India Limited along with other royalties. This
developed and not under construction. is included in the cost of coal procurement in our cost models. With
As far as potential hydro projects in India are concerned, they are India switching over to a uniform goods and service tax regime
based on the Brahmaputra river route which flows from China from July 2017, this is now known as the compensation cess.
into the North Indian state of Arunachal Pradesh. However, since Renewable purchase obligation (RPO): Each state specifies
1962, this area has been mired in border disputes between the some obligated entities who need to procure part of their power
two countries. There are also occasional insurgent-related issues requirement in the form of renewable power – and this is split by
in the region which can potentially disrupt project executions and
solar power and non-solar power. This percentage is specified for
operations. This makes the region fraught with significant geo-
the year the captive plant was established. In the state of Odisha,
political risks, making it unattractive for private players in India (see
where most of Indian aluminium smelters are based, captive power
figure 3).
plants are designated as obligated entities. There are two ways a
For this reason, we do not expect hydropower generation to become company in India can meet RPO levels:
an important share of India power supply. If Indian power emission
intensity in metal production is to be reduced, we think it must a. Produce their own renewable power
be through other changes, and on incentives to do so. The other b. Procure renewable energy certificates (REC) on the Indian
important point for investors to understand is how CO2 emissions Energy Exchange
costs are reflected in Indian power.
How are Indian aluminium producers handling this?
Figure 3: While most hydro potential is in the North East, aluminium The source of power is a complex issue that the aluminium industry
smelting is in the East. faces in general: smelters cannot shift power source easily. In
India, this is even more complicated. Globally, 41 smelters produce
aluminium from 100% hydropower. However, only nine of them
have their own hydro production units. In fact, of the 180 smelters
in CRU’s aluminium cost model, 107 smelters operate on 100%
purchased power.
The situation in India is starkly different. All three aluminium
producers in India have captive power plants which can meet
100% of their power requirements, though a certain portion of grid
purchase is necessary to meet RPO obligations (alongside purchase
of REC). Along with captive power plants, all three primary producers
also have access to captive coal sources as well as assured coal
supply in the form of supply agreements with Coal India Limited,
though the extent of assurance is varied by company.
In fact, as we write this insight, coal block auctions for commercial
purposes are underway in India and both Hindalco and Vedanta have
won coal blocks in these auctions. As these blocks are auctioned
for commercial purposes without any end-use restrictions, both
the producers will get additional flexibility in sourcing coal for their
captive power plants. NALCO already has 100% captive / assured
DATA: CRU, CEA coal supply.
How is coal taxed in India? It might also be worth noting that the Indian aluminium producers
While there is no separate ‘carbon tax’ on power production in India, could reduce their emissions by around 20% if they sourced
there are a couple of ways where the cost of carbon is introduced in electricity from the grid (comparable to the 2020 mix shown in
the cost of thermal power production. figure 1), but that would result in an increase in power costs of
Clean energy cess: Purchase of coal in India (including imported three to four times and expose the smelters to the instability of
coal) as well as coal mined by captive producers attracts a cess the grid, which is an unacceptable compromise. The chart below
which is used to fund the development of cleaner power projects shows the performance of the grid in the state of Odisha over the
in India. When introduced this was at INR50 /t of coal now it is last few years.
Figure 4: Performance of the state grid makes it risky for smelter from parties for developing 100MW solar power plant beside their
operations Aluminium smelter at Jharsuguda.
Alongside investments in renewable power, Indian producers
are also investing in recycling facilities which also help reduce
emissions as well as undertake regular internal projects to reduce
power consumption. In 2018, Hindalco signed a Memorandum of
Understanding with the State of Gujarat to invest in 300,000 t/y
scrap recycling facility (read here).
During FY2019-20, NALCO utilised graphitised cathode block in their
pot line and achieved the lowest power consumption (13.367Mwh
/t) in smelting operations since they started operations. Vedanta
also undertook similar process which resulting in power savings
DATA: CRU, SLDC-Odisha for the company. The renewable power projects of Hindalco helped
reduce CO2 emissions by 0.25Mn tonnes during this period.
However, producers in India need to pay both the clean energy
cess as well as comply with RPO obligations as explained above. All countries utilise the natural resources present within their
Along with paying the charges, all three producers have invested respective borders and being abundant in coal, it is unlikely that
in renewable sources of power. NALCO has 198.4MW of installed India’s dependence on coal will go away in the medium term.
wind capacity and is in the process of expanding this further by an However, Indian producers are taking various steps to reduce the
additional 25.5MW. environmental impact of using this resource.
Hindalco’s current renewable power generation capacity stands
at 45.2MW and the company intends to expand this by another
100MW by adding a solar power plant. In March 2020, just before
the lockdown in India, Vedanta floated a tender inviting interest
Aluminium not alloyed 7601-10 1,418.5 -11.2 376.6 329.3 324.3 246.4 73.3 -31.8 900.0 1,041.9 -13.6
Aluminium alloyed 7601-20 1,169.7 -8.8 282.2 258.6 216.1 148.3 67.0 -24.0 623.0 887.4 -29.8
Wrought aluminium
Plates, sheets & strip 7606 142.5 31.9 35.6 36.1 35.1 26.9 9.5 -23.2 98.2 106.9 -8.2
Bars, rods & profiles 7604 31.1 15.7 8.3 8.4 7.6 4.9 1.3 -56.9 21.0 22.9 -8.5
Tubes & pipes 7608 4.4 13.1 1.0 1.0 0.9 0.7 0.3 -24.3 2.6 3.3 -21.2
Wire 7605 12.8 42.9 3.4 3.0 3.5 2.4 0.8 -38.7 8.9 9.4 -5.8
Foil 7607 60.3 5.5 13.8 12.3 15.2 13.8 4.2 -9.0 41.3 46.6 -11.3
Rolled prod. sub total 251.1 22.5 62.0 60.9 62.4 48.7 16.2 -25.8 171.9 189.1 -9.1
EXPORTS
Unwrought aluminium 7601
Not alloyed, alloyed -10,-20 18.1 -14.9 5.4 6.9 4.9 4.1 1.7 -12.3 15.9 12.7 25.5
Plates, sheets & strip 7606 179.9 -8.0 42.1 31.3 31.3 33.6 11.4 -21.3 96.2 137.8 -30.1
Bars, rods & profiles 7604 16.4 -22.3 4.4 4.2 3.5 2.9 1.0 -17.7 10.6 12.0 -11.7
Tubes & pipes 7608 4.8 -11.7 1.1 1.1 0.8 0.9 0.3 -18.4 2.8 3.7 -24.6
Wire 7605 6.2 -21.4 1.7 1.5 1.4 1.5 0.4 0.8 4.3 4.5 -4.4
Foil 7607 66.1 -0.3 19.1 16.5 14.5 13.5 3.8 -32.9 44.5 47.0 -5.2
1. Detail may not add to the each quarter and year totals due to rounding
2. The figures of ‘Total 2019’ are final ones of 2019. It might be different from the total figure of each quarter of 2019, because the data of
each quarter is based on temporary statistics for preliminary release.
However, the outlook for the presidential election and vaccine hope remains unclear and may be a factor hindering price increase.
The three-month LME price was $1,934.5 on November 13 and Japan’s spot price was ¥233,000/ton. According to data from The
Daily Light Metals News, aluminum stocks at the three major Japanese ports at the end of October 2020 totaled 286,1000 tons,
32,500 tons less than a month earlier, marking a decline for 4 months in a row.
Selling prices of secondary aluminum alloys shipped in small lots in October 2020 rose ¥7-11/kg from the previous month. This
may have been reflected by the tight supply and demand as well as the shortage of the raw scrap ingredients. Prices of ADC12
sold in small lots in the Tokyo area were between ¥284~289/kg as of November 10, up ¥10/ kg from the previous month, according
to the Japan Metal Bulletin.
Shipments of Secondary Aluminum and Secondary Aluminum Alloys by Market in September 2020 (tons)
Castings Die Castings Rolled Products Extruded Products Steel Alloys Exports Others Total
15,891 37,575 4,363 1,357 2,742 1,983 32 89 64,032
Y-on-Y% Chg 85.6 100.1 96.2 74.2 75.5 79.1 32.3 46.8 93.0
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