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The manuscript was received on 26 November 2010 and was accepted after revision for publication on 1 February 2011.
DOI: 10.1177/1350650111401282
Abstract: Polymer nanocomposites have received considerable research attention in the past
decade due to its remarkable improvement in tensile, fatigue, and tribological characteristics.
This article reports the wear characteristics of pristine polyamide 6 and polyamide 6 nanocom-
posite (PA6NC) spur gears. The nanocomposite was made by melt intercalation method and
injection moulded into gears. Molecular level interaction of nano-size reinforcement enhances
the mechanical properties of polymer nanocomposite. The performance of gears at different
torque levels were studied using a power absorption type gear test rig. The gear tooth surface
temperature affects the wear rate and service life. The enhanced mechanical properties of PA6NC
results in reduced frictional and hysteresis heat generation associated with less wear and
increased life.
prone to severe wear. Moreover, the orientation of the Table 2 Test conditions
reinforcement governs the degree of enhancement in Rotation speed (r/min) 800
mechanical properties of PMC, and it is difficult to Applied torque (Nm) 1.5, 2, 2.5, and 3
Pitch-line velocity (m/s) 0.974
keep the orientation in the most effective direction Lubrication No
throughout the gear tooth geometry. Thus, only a Room temperature (K) 300 2
fraction of micron-size reinforcement is effectively Relative humidity (%) 550 4
used to enhance the performance of gear. In gear
application, an ideal reinforcement is one which
can enhance the material property independent of The PPA6 and PA6NC pellets were dried at 333 K for
its orientation and without affecting the surface 8 h in an oven to remove the moisture. The dried pel-
roughness and tooth shape. lets were injection moulded to test gear at a pressure
Recent studies on the polymer composites with of 125 MPa and at a temperature of 513 K. Separate
nano-size (109 m) reinforcement, known as polymer test specimens were made as per ASTM standard to
nanocomposite, showed a tremendous improvement measure the mechanical properties of the materials,
in mechanical properties [7–11]. The improvement in and the properties are presented in the Table 1. The
mechanical properties is observed only if proper hardness of polymer is measured using Shore
combination and composition of ingredients are Durometer and reported in Shore D scale. The tensile
selected [12]. The polymer nanocomposites derive strength and modulus are obtained from tensile test.
their superior properties even at the low volume of The test gear has 17 teeth, 2-mm module, 20 pres-
reinforcement addition due to their high surface area sure angle, and 6-mm face width. A stainless steel
to volume ratio and strong adhesion with the polymer (AISI 304) gear with a similar nomenclature was
[13, 14]. Uniform dispersion of nano-size clay rein- made by hobbing process and used as mating gear.
forcement in polyamide 6 significantly increases the The centre-line average surface roughness values
strength and elastic modulus [11]. Polyamide 6 nano- measured using the surface profilometer of the
composites (PA6NCs) are also found to exhibit better moulded polymer and stainless steel gears are
fatigue properties [15]. Presence of nano-size clay nearly the same (2–3 mm). The hardness and rough-
reinforcement reduces the coefficient of friction ness of the surface can also be measured using sur-
under dry sliding conditions [10]. PA6NC has higher face force microscopy and atomic force microscopy
glass transition temperature and thermal stability [16, 17]. Before conducting the test, the gears were
compared to pristine polyamide and it retains the cleaned using ethanol in an ultrasonic cleaner and
material property for a long duration [11]. These dried for 12 h to eliminate the effect of surface con-
desirable characteristics of PA6NC attract the authors tamination on the gear performance. The tooth thick-
to investigate its performance as a gear material. In ness was measured over the marked four teeth using
this investigation, pristine polyamide 6 (PPA6) and the gear tooth micrometer with an accuracy of 1 mm.
PA6NC gears were developed and their performance The weight of the gear before and after the test was
and failure modes are reported. measured using an electronic weighing balance with
an accuracy of 0.1 mg. The gears were tested under
2 MATERIALS AND EXPERIMENTAL DETAILS dry conditions in a power absorption type gear test rig
[3], wherein the required torque is applied by adjust-
The nanocomposite was produced from commer- ing the rheostat connected to the generator. In this
cially available extrusion grade polyamide 6 granules investigation, the test gear was used as driver gear and
and organically modified layered silicate hectorite. stainless steel gear as driven gear. To understand the
The nanocomposite pellets with 5% clay content (by effect of applied torque on the wear of PPA6 and
weight) were produced by dispersing the nano-size PA6NC gears, experiments were conducted at dif-
clay into the polymer matrix using melt intercalation ferent torque levels and at a constant speed under
method. The details are reported elsewhere [12]. laboratory atmosphere (Table 2). The surface
Accelerometer
Test gear
Sound-level meter
10 mm
Fig. 1 (a) Photograph of PA6NC gear; (b) close-up view of the gear test rig
temperature of the test gear was measured using a stabilization, the surface temperature is within a
non-contact type infrared absorption sensor with an short range till the final fracture. At 3-Nm torque
accuracy of 0.01 C. Sound level, torque on shafts, and level, PA6NC gear exhibited no thermal stabilization
vibration were monitored through sound level meter, and the rate of increase in surface temperature was
torque transducer, and accelerometer, respectively. high compared to other torque levels. The surface
Figure 1(b) shows the close view of the gear test temperature of PA6NC gear is less than that of PPA6
unit. All the data were continuously recorded using gear at all torque levels tested.
a computerized data acquisition system. The experi- Thermal softening is a major issue in the compo-
ment was run till the fracture of the gear tooth or 1 nents made of polymer and polymer composites. The
million revolutions of gear, whichever is earlier. The rise in temperature weakens the hydrogen bonds that
sound level and accelerometer readings indicate the exist between the polymer chains and result in deg-
condition of the gear tooth. Failure of gear tooth radation of mechanical properties. During meshing,
causes a sudden rise in vibration. Images of the gear polymer gear generates heat at the tooth surface and
tooth were captured using a video microscope. within the bulk material due to friction and hysteresis
effect, respectively. At low torque level, frictional
3 RESULTS AND DISCUSSION heating dominates the gear tooth temperature and
at high torque level, frictional and hysteresis heating.
3.1 Gear temperature Gear undergoes non-conformal contact and expe-
riences high contact pressure. The contact pressure
During meshing, polymer gear generates heat, result- (P) can be calculated using the Hertizian equation
ing in temperature rise. Figures 2(a) and (b) shows the
rise in surface temperature of PPA6 and PA6NC gears 2Fn
P¼ ð1Þ
at different torque levels, respectively. In PPA6 and bL
sffiffiffiffiffiffiffiffiffiffiffiffiffiffiffiffiffiffiffiffiffiffiffiffiffiffiffiffiffiffiffiffiffiffiffiffiffiffiffiffiffiffiffiffiffiffiffiffiffiffiffiffiffiffiffiffiffiffiffiffiffiffi
PA6NC gears, the increase in applied torque raises
2Fn 1 21 =E1 þ 1 22 =E2
the surface temperature and it increases rapidly b¼ ð2Þ
L ð1=d1 Þ þ ð1=d2 Þ
during the initial stages at all torque levels tested.
At low torque level (1.5 Nm), the surface temperature Equation (1) can be written in terms of gear speci-
of PPA6 gear reaches around 342–344 K and, after a fications as below [19]
large number of cycles, it increases slowly. At 2-Nm sffiffiffiffiffiffiffiffiffiffiffiffiffiffiffiffiffiffiffiffiffiffiffiffiffiffiffiffiffiffiffiffiffiffiffiffiffiffiffiffiffiffiffiffiffiffiffiffiffiffiffiffiffiffiffiffiffiffiffiffiffiffiffiffiffiffiffiffiffiffiffiffiffiffiffiffiffiffiffiffiffiffiffiffiffiffiffiffiffiffiffiffiffiffi
torque level, the rate of increase in surface tempera- Fn uþ1 2
P¼
ture is 1.2 103 K/cycle and remains unaltered till Ld1 sin u 1 1 =E1 þ 1 22 =E2
2
380
PPA6
PA6NC
360
320
300
1 1.5 2 2.5 3
Applied torque (Nm)
3.4 PA6NC 7.5 104 and 10 104 cycles. In addition, the surface
3.3 temperature directly influences the wear rate [5, 6,
11]. The increase in surface temperature at the later
3.2
stages is also a reason for the increased rate of reduc-
3.1 tion in tooth thickness.
3
3.3 Gear life and failure mode
2.9
0 25000 50000 75000 100000 Figure 6 shows the lives of PPA6 and PA6NC gears at
Number of cycles different test conditions. The enhanced mechanical
Fig. 5 Tooth thickness of PPA6 and PA6NC gears at property results in a higher life in PA6NC gear com-
specific cycles tested at 1.5 Nm torque level and pared to pristine polymer gear at all test conditions.
at 800 r/min At low stress level (15 MPa), the life of PA6NC gear is
about 3.8 times higher and at high stress level
(30 MPa), it is about 2.6 times higher than that of
PPA6 gear. In polymer gear, the mode of use (driver
35
PPA6
or driven) also affects the life [26]. As discussed ear-
30 PA6NC
lier, gear tooth slides during meshing and the direc-
tion is reversed at the pitch point. The driver gear
Bending stress (MPa)
1 mm 1 mm (f) 1 mm
(d) (e)
Fig. 7 Images of damaged gear tooth after test: (a) PPA6 gear at 1.5 Nm; (b) PPA6 gear at 2.5 Nm;
(c) PPA6 gear at 3 Nm; (d) PA6NC gear at 1.5 Nm; (e) PA6NC gear at 2.5 Nm; and (f) PA6NC
gear at 3 Nm
single-tooth contact region. The reduction in tooth 2. reduced tooth deflection in PA6NC gear reduces
thickness causes a stress concentration at the severe the abnormal wear at the flank side;
wear region and the tooth deflects about that region 3. the increased hardness and crystallinity reduce the
instead of root fillet. This causes an excessive hyster- wear rate in PA6NC gear; and
esis heat generation at the wear region and acceler- 4. the enhanced thermal property allows the PA6NC
ates the wear. A crack is generated at the severe wear to retain the strength for a long duration and result
region and grows at a rapid rate due to tooth bending in higher gear life.
(Fig. 7(b)). At high torque level (3 Nm), severe tooth
deformation occurs due to large deflection of tooth ß Authors 2011
(Fig. 7(c)). In PA6NC gear, root cracking is observed in
all test conditions and no tooth fails by the crack at
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