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Precambrian Research 162 (2008) 102–127

Thermo-tectonic evolution of the North Singhbhum Mobile Belt


(eastern India): A view from the western part of the belt
S. Mahato a,1 , S. Goon a,2 , A. Bhattacharya a,∗ , B. Mishra a , Heinz-J. Bernhardt b
a Department of Geology and Geophysics, Indian Institute of Technology,
Kharagpur 721302, West Bengal, India
b Institute für Mineralogie, Ruhr Universität,

D-44780 Bochum, Germany


Received 9 June 2006; received in revised form 20 March 2007; accepted 4 July 2007

Abstract
The arcuate North Singhbhum Mobile Belt (NSMB) comprises multiply-deformed greenschist–amphibolite facies phyllites and schists flanking
the centrally-located belt of the Dalma meta-igneous suite of rocks. The NSMB is separated from the Archaean Singhbhum Craton in the south, and
the suite of granulite–amphibolite facies gneisses and foliated granites of the Chotanagpur Gneissic Complex to the north, by ductile shear zones.
Three fabrics (S1S , S2S , and S3S ) formed due to D1S , D2S and D3S deformation events and three metamorphic stages (M1S : pre-S2S ; M2S : syn-S2S ;
and M3S : syn/post-S3S ) were identified in phyllites and schists to the south of the Dalma meta-igneous in the NSMB. Reverse-sense transport along
north-dipping imbricate thrusts (S3S ) emplaced the high-grade garnet–kyanite–staurolite schists centrally located in the orogen over low-grade
muscovite–biotite–chlorite schists in the foreland. The M1S stage (∼1.5 Ga; EPMA monazite date) in the high-grade gneisses characterized by high
P/T prograde metamorphism (P > 10 kbar) was followed sequentially by post-loading prograde heating (Tmax ∼650 ◦ C) and exhumation – cooling
at amphibolite facies (M2S ) and greenschist facies (M3S : ∼1.3 Ga; EPMA monazite date) conditions.
In the northern part of the NSMB, mica schists fringing the CGC document a northward increase in strain (sequential cleavage formation)
and temperature (greenschist to amphibolite facies). The strain–temperature spatial gradient is correlated with crustal shortening and heating (T
∼620 ◦ C, P ∼7 kbar) synchronously with reverse-sense transport of schists along southerly-dipping thrust planes.
The structural framework and thermal structure across the mobile belt is correlated with (a) collisional thickening of the orogen (>1.5 Ga), followed
by convective removal of the lithospheric root resulting in post-burial heating and (b) syn-collision and exhumation of the orogen (∼1.3 Ga). The
exhumation was caused by outward-directed extrusion of the crustal slices along imbricate foreland-vergent thrusts dipping towards the centre of
the orogen.
© 2007 Elsevier B.V. All rights reserved.

Keywords: North Singhbhum Mobile Belt; Syn-collision exhumation; Mesoproterozoic; Lithospheric thickening; Mantle convection

1. Introduction of sedimentation, magmatism, deformation and metamorphism,


the details of which vary depending on the tectonic setting of the
Orogenic processes in mobile belts (Condie, 1997) operate in geologic area. Typically, mobile belts bear evidence of multiple
cycles beginning with basin formation, progressing to collisional metamorphic episodes that may relate to a single orogeny or mul-
thickening of the crust, and culminating with tectonic exhuma- tiple orogenies (cf. Goscombe and Hand, 2000; Willner et al.,
tion (Dewey, 1988; Nelson, 1992; Platt, 1993; Grujic et al., 1996; 2000; Regnier et al., 2003; Vogl, 2003; Raith and Harley, 1998;
Ernst et al., 1997; Knapp et al., 1998; Leech, 2001; Beaumont et Jamieson et al., 1992; Begin, 1992; Dusel-Bacon et al., 1995;
al., 2001). Consequently, mobile belts inherit a complex history Nishimura, 1998) that may vary in thrust bound longitudinal
sections. The time–space evolutionary histories of metamorphic
rocks in mobile belts are, therefore, important tools for decoding
∗ Corresponding author. syn- and post-orogenic processes.
E-mail address: abbhat55@yahoo.com (A. Bhattacharya).
1 Present address: Department of Geological Sciences, Jadavpur University, The North Singhbhum Mobile Belt (NSMB) is a geological
Kolkata 700032, India. term specific to the ensemble of multiply folded, low to medium
2 Present address: Purbachal, Sripalli, Burdwan 713103, India. grade meta-sedimentary and meta-igneous rocks of Proterozoic

0301-9268/$ – see front matter © 2007 Elsevier B.V. All rights reserved.
doi:10.1016/j.precamres.2007.07.015
S. Mahato et al. / Precambrian Research 162 (2008) 102–127 103

Fig. 1. Geological map of the North Singhbhum Mobile Belt (NSMB). The NSMB is separated from the Archaean Singhbhum Craton (SC) in the south and the
Chottanagpur Gneissic Complex (CGC) in the north by two north-dipping shear zones (bold line with filled triangles). The boxes with numbers correspond to the
location and extent of the areas studied by earlier workers. (1) Bhattacharya et al. (1976); (2) Chakrabarty and Sen (1967); (3) Lal and Singh (1978); Lal and
Ackermand (1979); (4) Roy (1966); (5) Bhattacharya (1966); (6) Sarkar and Bhattacharya (1978); (7) Pasayat and Bhattacharya (1977); (8) Sanyal (1985); (9)
Bose (1954); (10) Gangopadhyay (1959); (11) Banerji (1985); (12) Bhattacharya (1992); (13) Bhattacharya and Chatterjee (1992); (14) Bhattacharya (1989); (15)
Bhattacharya (1978); (16) Bhattacharya and Sarkar (1970); (17) Mukhopadhyay et al. (2004). Naha (1965) and Mukhopadhyay and Sengupta (1971) studied the
superposed fold structures in mica schists/quartzites and metamorphic mineral paragenesis in and around the town of Ghatsila. Located in the western part of the
NSMB, Kolomda, Hesadi, Tebo and Nakti constitute the areas investigated in this study.

age (1.0–2.4 Ga) sandwiched between the Archaean (>2.4 Ga) two corridors transverse to the NSMB in the western part of the
Singhbhum Craton in the south, and the Meso/Neo-Proterozoic belt (corridors A and B; Fig. 2).
(0.9–1.7 Ga) Chotanagpur Gneissic Complex (CGC) in the north
by north-dipping ductile shear zones (Fig. 1). The NSMB and 2. The northern corridor: results and discussion
the CGC are separated by the Tamar–Porapahar–Khatra–Fault
(TPKF), sometimes referred to as the Northern Shear Zone 2.1. The structural setting
(NSZ; adopted in this study). Further to the south, the NSMB and
the Singhbhum Craton is separated by the Copper Belt Thrust The spatial variations in mesoscopic structural elements
(CBT), sometimes referred as the Southern Shear Zone (SSZ; and metamorphic minerals in muscovite schists (muscovite,
adopted in this study). biotite, quartz, ilmenite, tourmaline ± garnet ± staurolite, and
Various tectonic models have been proposed for the mobile rare plagioclase) from the northern corridor around Kolomda
belt; e.g. intraplate subduction (Sarkar and Saha, 1977), micro- are depicted in Fig. 3. Mineral abbreviations used subse-
continental subduction (Sarkar, 1982), back-arc marginal setting quently are adopted from Kretz (1983). In the mapped area,
(Bose and Chakrabarty, 1981; Bose et al., 1989), intra-cratonic garnet and staurolite porphyroblasts are absent in the mus-
extension, rifting and ensialic orogenesis (Gupta et al., 1980; covite > biotite ± chlorite schists from the southern part of
Mukhopadhyay, 1984; Sarkar et al., 1992). The proposed the corridor. Garnet porphyroblasts start to appear ∼1000 m
tectonic models are based on stratigraphic correlation, sedi- south of the NSZ. Staurolite porphyroblasts begin to appear
mentological information, available data on magma genesis, from ∼200 m south of the NSZ. The sizes of staurolite
and chronologic information available from rocks within and and garnet porphyroblasts increase northwards. Proximal to
flanking the NSMB. However, the input of metamorphic P–T the CGC, garnet porphyroblasts measure in excess of 1 cm
evolutionary history to the models is totally lacking. This study in diameter; the largest of the staurolite porphyroblasts is
addresses the gap based on a critical appraisal of the structural smaller (<500 ␮m). Chlorite is rare in the porphyroblast bear-
setting and time–space evolution of metamorphic variables (e.g. ing zone; the modal abundance of biotite decreases dramatically
P and T) in meta-sedimentary phyllites, schists and gneisses in northwards.
104 S. Mahato et al. / Precambrian Research 162 (2008) 102–127

Fig. 2. Lithologic map (simplified after Dunn, 1929) between Kolomda (in the north) and Nakti (in the south) in the western part of the NSMB. The National
Highway is shown by gray line for reference. The northern corridor (designated A) lies to the south of Kolomda. The southern corridor (designated B) extends from
Hesadi, along the road through Tebo, to Nakti. The areas within boxes designated A (see Fig. 3) and B (see Fig. 9) were geologically mapped during the course
of this study. The three domains 1, 2 and 3 in the southern corridor are separated by four north-dipping ductile shear zones indicated by filled triangles secured to
thick lines. The chlorite-out zone in muscovite–biotite schists in the southern corridor is also shown. Southern hemisphere projections of structural elements (see
text for discussion) for domains 1 and 2 are shown. Domain 1: ␲S2S girdle (n = 190) contoured at intervals of 1%, 2%, 4% and 8% (in increasing shades of gray;
max 16.32%). The calculated β-axis corresponding to the girdle is 03◦ → 070N. ␲S3S (n = 40) are shown as filled circles; the dip of the mean orientation of S3S is
73◦ /166N. Filled triangles are measured F3S fold axis (n = 68). Domain 2: Southern hemispheric plots showing the ␲S2S girdle (n = 126) contoured at intervals of
1%, 2%, 4%, 8% and 16% (in increasing shades of gray; max 22.22%). The calculated β-axis corresponding to the girdle is 10◦ → 072N. ␲S3S (n = 70) are shown
as filled circles; the mean dip orientation of S3S is 84◦ /158N. Filled triangles are measured F3S fold axis (n = 18). The southern hemispheric plots of the orientations
of F2S (open triangle) fold axes (n = 9) are shown.

The prominent schistosity in mica schists is a crenulation constant orientation of S3N is attributed to top-to-the-north slip
cleavage (S2N ; subscript N refers to the northern corridor) of and shearing (Fig. 4a) during D3N deformation, apparently in a
alternate muscovite > biotite rich layers (M-domain) and quartz- transpressive regime.
rich layers (Q-domain). With increasing grade of metamorphism
northwards, the spacing between adjacent S2N M-domains 2.2. Porphyroblast–matrix relationship
decreases. The increase in intensity of deformation is associ-
ated with northward tightening of F3N folds, and a correlated In zones neighboring their first appearance, garnet porphy-
prominence of axial planar S3N fabric associated with top-to- roblasts are typically post-S2N , but pre-S3N . However, garnet
the-north thrusting (Fig. 4a). The F3N folds are asymmetric, in most parts of the staurolite and garnet-bearing zones is pre-
northerly overturned and characterized by curved easterly plung- S2N . In zones proximal to the NSZ, post-S3N overgrowths on
ing axes (Fig. 3) that are steeper at the NSMB–CGC contact. The pre-S2N garnet nuclei commonly protrude into and truncate the
F3N fold axes and the stretching lineations in the L > S granite wrapping M-domains. The protrusions are lacking in garnet at its
mylonites in the CGC are broadly coincident. The F2N fold axes first appearance. At their first appearances, garnet and staurolite
broadly straddle the average orientation of the S3N cleavage. are restricted to M-domains, but at the highest-grade and most
The variable orientation of the F2N fold axes lying on near- intensely-deformed schists neighboring the NSZ, both minerals,
S. Mahato et al. / Precambrian Research 162 (2008) 102–127 105

Fig. 3. Structural-metamorphic map of the northern corridor (box A; Fig. 2) showing the planar and linear structural elements in the NSMB muscovite schists at the
southern fringe of the CGC (gray colour). First appearances of garnet and staurolite in muscovite schists are shown. Stereographic projections of ␲S2N (contoured),
␲S3N (filled circle) and F2N (open triangle) and F3N (filled triangle) fold axes for zones 1, 2 and 3 are shown. Contour intervals for ␲S2N are in multiples of 2.
Number (n) of measured ␲S2N data are 23 for Zone 1, 91 for Zone 2 and 47 for Zone 3.

wrapped by M-domains, are restricted exclusively to quartz-rich als formed independent of each other from muscovite, biotite,
domains. Staurolite occurs as inclusions within garnet (staurolite ilmenite ± chlorite ± plagioclase assemblage.
hosted garnet was not observed), but staurolites also occur exclu- Shapes, sizes and Si–Se relationships (‘Si’ stands for mineral
sive of garnet in garnet-bearing mica schists (Fig. 5). Garnet and inclusion trails within porphyroblasts, and ‘Se’ is designated for
staurolite do not share a reaction relationship, i.e. both miner- schistosity external to the porphyroblasts) in garnet porphyrob-

Fig. 4. (a) Top to the north sense of shearing in zone 3 mica schists in the northern corridor (corridor A in Fig. 2). Width of the photograph = 18 cm. (b) S–C fabric
in granite mylonite in the southernmost shear zone in the southern corridor (corridor B in Fig. 2). Length of pencil = 15 cm. Photomicrographs (c) plane polar and
(d) crossed polars images of sheared mica schists showing S–C fabric in quartz-rich domains in the northernmost shear zone in the southern corridor.
106 S. Mahato et al. / Precambrian Research 162 (2008) 102–127

Fig. 5. Line drawing (top set) and plane polarized light image (bottom set) showing the relationship between garnet (light gray in drawings) and staurolite (deeper
gray shade in drawing) in mica schists from the northern corridor. White and dark lines within porphyroblasts correspond to quartz and ilmenite inclusion trails. In
(a) and (b), staurolite occurs wholly within muscovite-rich layers (S2N ) both as inclusions within garnet as well as discrete grains exclusive of garnet. Garnets, on
the other hand, occur in quartz rich portions, and are wrapped by micaceous layers. The marginal parts in garnet (PPL image of b) are dark because of extensive
leaching. Note the closed loop nature of quartz inclusion trails in garnet in b.

lasts in muscovite schists varied systematically from south to (2) sub-vertical section (‘ZY’ plan) parallel to the cleavage and
north. The spatial variations summarized in Fig. 6 were based on the fold axis, and (3) sub-horizontal section (‘XZ’ plan) perpen-
examination of oriented thin sections in (1) sub-vertical section dicular to the cleavage and parallel to the fold axis. The X, Y and
(‘XY’ plane) perpendicular to S3N cleavage and F3N fold-axis, Z directions do not correspond to the axes of the strain ellipsoid.

Fig. 6. Three-dimensional line sketches of garnet shapes and inclusion trail patterns in muscovite schists (drawn from transmitted plane polarized light images) from
muscovite schists in the northern corridor in YZ, XZ and XY sections. X, Y and Z do not correspond with the axes with the strain ellipsoid. In (c), the garnet grains are
schematically drawn. The block diagram at the top shows the geographic orientation of the YZ, XZ and XY sections (see text for discussion). Garnet porphyroblasts
are in light gray, staurolite in darker shades of gray, ilmenite inclusions are in black, and quartz inclusions are in white. The external schistosity in each case is S2N .
(a) Fringe of the CGC; (b) within the staurolite/garnet porphyroblast bearing zone; and (c) at to the first appearance of garnet further to the south.
S. Mahato et al. / Precambrian Research 162 (2008) 102–127 107

The length of garnet porphyroblasts in XY sections decreases


from ∼9 mm neighboring the NSZ to <400 ␮m where garnet
first appears (a distance of ∼1000 m), with a correlated decrease
in the aspect ratio from >8 to ∼1. Garnet porphyroblasts are
disc-shaped close to the CGC (flattened parallel to the S3N schis-
tosity; Fig. 6a), kidney-shaped for most of the staurolite and
garnet-bearing zones; Fig. 6b), and of dodecahedral shape with
well-developed rational faces neighboring the zone where gar-
net first appears (Fig. 6c). Disc-shaped garnets contain straight
to mildly curved Si in XY and XZ sections (radial Si in YZ
section); kidney-shaped garnets contain sigmoidal Si trails in
XY and XZ sections (closed loop Si trails in YZ section). Fur-
ther towards the hinterland, in zones where garnet first appears,
garnet porphyroblasts are inclusion-free.

2.3. Metamorphic P–T conditions

The mineralogy of muscovite schists provides limited options


to estimate pressure, because plagioclase and biotite were lack- Fig. 7. Estimate of metamorphic P–T conditions (shaded box) for the sample
GO-286 (analytical data provided in Table 1). The P–T locations of thermo-
ing in most garnet-bearing schists. Only one sample (GO-286) barometric formulations (see text for discussion) applied to the assemblage
with plagioclase was found suitable for P–T estimation. Temper- garnet–plagioclase–muscovite–biotite in mica schists from the northern cor-
atures were obtained using the biotite-garnet Fe–Mg exchange ridor are shown. Continuous lines sub-parallel to the pressure axis correspond
thermometric formulation (Bhattacharya et al., 1992; Ferry and to the P–T loci of biotite-garnet thermometric formulations; broken lines are the
Spear, 1978; Hodges and Spear, 1982; Perchuk and Lavrent’eva, P–T loci for muscovite–biotite thermometers. Other set of lines refers to the P–T
loci for the barometric formulations discussed in the text. The Al2 SiO5 phase
1983; Thompson, 1976 and Holdaway and Lee, 1977). Tem- relations (gray broken lines) shown for reference are computed using thermo-
peratures were also estimated using the muscovite-biotite dynamic data in Thermocalc program (version 3.21) after Holland and Powell
thermometers of Wu et al. (2000, cited in the GTB program of (1998). Mineral abbreviations are after Kretz (1983).
Spear and Kohn; http://ees2.geo.rpi.edu/MetaPetaRen/Frame-
software.html/) and Hoisch (1989) based on Tschermak’s FeO(total) = 25.69, K2 O = 13.31, Na2 O = 3.27, MnO = 0.33) was
substitution. The garnet-plagioclase-muscovite-biotite equilib- calculated on a H2 O-free, silica-free and FeO(total) basis. Mus-
rium (Ghent and Stout, 1981; Hodges and Crowley, 1985; Powell covite, quartz and H2 O were considered to be in excess for
and Holland, 1988; Hoisch, 1990) and garnet-plagioclase- constructing the pseudosection for a six-component KFMASH
muscovite-quartz equilibrium (Hodges and Crowley, 1985; system using the thermodynamic data set of THERMO-
Hoisch, 1990) were used as geobarometer. CALC program (version 3.21) of Holland and Powell (1998).
P–T conditions for the sample were estimated using the rim The fields for stable mineral assemblages in the P–T win-
composition of garnet and the nearest neighbor muscovite, pla- dow between 4 and 10 kbar and 500–700 ◦ C are shown
gioclase and biotite, but with biotite not in grain contact with in Fig. 8c. The XGrt (= Fe/Fe + Mg) isopleths are shown
garnet (Table 1). The thermometric estimate form the different for the garnet-bearing assemblages. For the assemblage
biotite-garnet formulations converge at 620 ± 20 ◦ C. Intersec- garnet + staurolite + muscovite + biotite + quartz, XGrt decreases
tions of the P–T locations of the thermobarometers yield the with increasing temperature. This, combined with the core to rim
mean equilibrium T and P value ∼620 ± 20 ◦ C and 7 ± 1 kbar, decrease in XGrt (Fig. 8b, right), suggests that garnet growth syn-
within the kyanite field (Fig. 7). The P–T loci of the muscovite- kinematic with sequential cleavage re-generation in the northern
biotite thermometers after Hoisch (1989) and Wu et al. (2000; corridor was prograde in nature involving heating, with or with-
cited in the GTB program) pass through the P–T box. Although out loading.
kyanite was not observed in the northern sector, kyanite has been
reported from the highest-grade NSMB schists at the fringes of 3. The southern corridor: Results and discussion
the CGC, e.g. near Beldi (Ray and Gangopadhyay, 1971) and
Barabhum-Banduan (Bose, 1954). Sillimanite and andalusite 3.1. The structural setting
have not been reported from the NSMB schists fringing the CGC.
The garnet porphyroblasts are typically zoned (Fig. 8a). The 40 km long southern corridor extending from Hesadi in
While almandine and pyrope components increase towards the the NW to within 6 km from Nakti in the SE is composed of
porphyroblast margin, grossular and spessartine components in several lithologic units, e.g. phyllites, mica schists, quartzites,
garnet show a complementary decrease (Fig. 8b; left) and XGrt mafic schists/amphibolites, quartzofeldspathic gneisses, and
(= Fe/Fe + Mg) decreases rim ward (Fig. 8b; right). A P–T pseu- gabbroic rocks (Fig. 2). The area was divided into three domains
dosection was constructed using the whole rock composition of on the basis of four bounding northerly-dipping ductile shear
the muscovite schist, GO-284 (Fig. 8c). The mole-proportion zones (Fig. 2). The southernmost part of the corridor (domain 1)
of the bulk rock (Al2 O3 = 53.80, CaO = 0.76, MgO = 2.83, is dominated by muscovite–biotite–chlorite bearing phyllites;
108
Table 1
Electronprobe microanalysis and structural formulae (computed using the a-X program of Holland and Powell, 1998) of minerals in Grt-bearing St-Ky gneiss from domain 3 in the southern corridor and Grt-St
bearing muscovite schist of the northern corridor
Sample no. Biotite Muscovite

South North South North

M1 M2 Matrix M1 M2 M3 Matrix

GO-462a GO-159a GO-588a GO-462 GO-159 GO-588 GO-286a GO-286 GO-462a GO-159a GO-588a GO-462 GO-159 GO-159 GO-286a GO-286

S. Mahato et al. / Precambrian Research 162 (2008) 102–127


Weight percent
SiO2 34.56 34.64 33.69 35.51 35.02 34.27 35.67 36.10 45.83 45.23 46.23 45.50 46.00 44.57 46.37 46.08
TiO2 1.68 1.74 1.65 1.69 1.85 1.68 1.74 1.59 0.30 0.32 0.56 0.57 0.44 0.51 0.54 0.53
Al2 O3 18.40 17.98 17.56 18.46 18.32 17.89 18.62 18.36 35.53 35.42 35.22 34.37 35.49 37.23 35.72 35.37
Cr2 O3 0.00 0.00 0.00 0.00 0.00 0.00 0.00 0.00 0.00 0.00 0.00 0.00 0.00 0.00 0.00 0.00
Fe2 O3 b 0.00 1.46 3.92 0.00 0.43 1.01 0.00 0.00 0.00 0.00 0.00 0.00 0.00 0.00 0.00 0.00
FeO 19.64 22.19 20.00 19.20 20.39 22.66 18.98 19.28 2.03 2.23 2.05 2.33 2.23 1.55 1.24 1.13
MnO 0.05 0.02 0.05 0.01 0.05 0.00 0.01 0.02 0.00 0.05 0.00 0.02 0.00 0.00 0.05 0.03
MgO 10.18 9.77 8.50 10.33 9.87 8.50 7.54 7.52 0.52 0.41 0.55 0.64 0.54 0.38 0.59 0.67
CaO 0.00 0.02 0.00 0.00 0.01 0.01 0.04 0.06 0.00 0.02 0.00 0.00 0.00 0.96 0.00 0.01
Na2 O 0.27 0.00 0.12 0.12 0.11 0.05 0.16 0.29 0.96 1.76 1.27 1.50 1.73 0.38 0.94 1.01
K2 O 9.60 8.67 8.51 9.91 9.52 9.15 9.00 9.00 10.30 8.97 8.94 9.56 9.05 9.37 9.92 9.79
Totals 94.39 96.50 94.01 95.24 95.58 95.23 91.77 92.23 95.48 94.42 94.83 94.50 95.49 94.96 95.38 94.63
Cations
Si 2.67 2.65 2.64 2.71 2.68 2.67 2.80 2.83 3.06 3.04 3.08 3.07 3.06 2.97 3.07 3.08
Ti 0.10 0.10 0.10 0.10 0.11 0.10 0.10 0.09 0.02 0.02 0.03 0.03 0.02 0.03 0.03 0.03
Al 1.68 1.62 1.62 1.66 1.65 1.64 1.73 1.70 2.79 2.81 2.77 2.73 2.78 2.93 2.79 2.79
Cr 0.00 0.00 0.00 0.00 0.00 0.00 0.00 0.00 0.00 0.00 0.00 0.00 0.00 0.00 0.00 0.00
Fe3 0.00 0.08 0.23 0.00 0.03 0.06 0.00 0.00 0.00 0.00 0.00 0.00 0.00 0.00 0.00 0.00
Fe2 1.27 1.42 1.31 1.23 1.31 1.48 1.25 1.26 0.11 0.13 0.11 0.13 0.12 0.09 0.07 0.06
Mn 0.00 0.00 0.00 0.00 0.00 0.00 0.00 0.00 0.00 0.00 0.00 0.00 0.00 0.00 0.00 0.00
Mg 1.17 1.11 0.99 1.18 1.13 0.99 0.88 0.88 0.05 0.04 0.06 0.06 0.05 0.04 0.06 0.07
Ca 0.00 0.00 0.00 0.00 0.00 0.00 0.00 0.01 0.00 0.00 0.00 0.00 0.00 0.07 0.00 0.00
Na 0.04 0.00 0.02 0.02 0.02 0.01 0.02 0.04 0.12 0.23 0.16 0.20 0.22 0.05 0.12 0.13
K 0.95 0.85 0.85 0.97 0.93 0.91 0.90 0.90 0.88 0.77 0.76 0.82 0.77 0.80 0.84 0.84

Cation 7.89 7.83 7.77 7.85 7.85 7.84 7.70 7.71 7.03 7.04 6.97 7.05 7.03 6.96 6.98 6.99
Table 1 (Continued)
Sample no. Garnet Chlorite

South North South

M1 (rim) M1 (core) Rim Core M3 M1


GO-462a GO-159a GO-588a GO-462 GO-159 GO-588 GO-286a GO-286 GO-286 GO-286 GO-462a GO-588a GO-159a

Weight percent

S. Mahato et al. / Precambrian Research 162 (2008) 102–127


SiO2 37.41 37.98 37.51 36.92 36.68 37.18 37.32 36.96 36.99 36.89 24.85 25.17 24.50
TiO2 0.07 0.00 0.03 0.08 0.00 0.05 0.00 0.00 0.10 0.00 0.02 0.08 0.05
Al2 O3 21.39 21.34 20.99 21.00 20.86 20.88 21.13 21.08 20.70 20.70 23.38 23.31 21.50
Cr2 O3 0.00 0.00 0.00 0.00 0.00 0.00 0.00 0.00 0.00 0.00 0.00 0.00 0.00
Fe2 O3 b 1.33 0.68 0.00 2.21 2.00 0.23 1.65 3.02 1.56 1.53 0.00 0.00 0.00
FeO 31.54 34.31 34.84 30.37 33.73 34.06 36.37 35.54 34.03 33.78 21.86 22.97 24.62
MnO 0.29 1.17 0.35 1.17 1.34 0.82 0.19 0.18 3.09 2.90 0.00 0.00 0.04
MgO 3.57 2.72 2.65 2.67 2.74 1.76 2.79 2.82 1.45 1.57 17.09 15.14 14.36
CaO 5.15 3.91 3.61 6.00 2.96 5.05 2.10 2.06 3.32 3.38 0.00 0.03 0.21
Na2 O 0.00 0.00 0.00 0.04 0.02 0.00 0.06 0.16 0.05 0.05 0.03 0.00 0.09
K2 O 0.00 0.02 0.00 0.01 0.00 0.00 0.04 0.02 0.03 0.01 0.00 0.06 0.17
Totals 100.76 102.13 99.98 100.47 100.33 100.04 101.64 101.84 101.32 100.81 87.23 86.76 85.54
Cations
Si 2.96 2.99 3.01 2.95 2.95 3.00 2.97 2.94 2.97 2.97 2.58 2.64 2.65
Ti 0.00 0.00 0.00 0.01 0.00 0.00 0.00 0.00 0.01 0.00 0.00 0.01 0.00
Al 1.99 1.98 1.99 1.98 1.98 1.99 1.98 1.97 1.96 1.97 2.86 2.88 2.74
Cr 0.00 0.00 0.00 0.00 0.00 0.00 0.00 0.00 0.00 0.00 0.00 0.00 0.00
Fe3 0.08 0.04 0.00 0.13 0.12 0.01 0.10 0.18 0.09 0.09 0.00 0.00 0.00
Fe2 2.09 2.26 2.34 2.03 2.27 2.30 2.42 2.36 2.29 2.28 1.90 2.01 2.22
Mn 0.02 0.08 0.02 0.08 0.09 0.06 0.01 0.01 0.21 0.20 0.00 0.00 0.00
Mg 0.42 0.32 0.32 0.32 0.33 0.21 0.33 0.33 0.17 0.19 2.64 2.37 2.31
Ca 0.44 0.33 0.31 0.51 0.26 0.44 0.18 0.18 0.29 0.29 0.00 0.00 0.02
Na 0.00 0.00 0.00 0.01 0.00 0.00 0.01 0.03 0.01 0.01 0.01 0.00 0.02
K 0.00 0.00 0.00 0.00 0.00 0.00 0.00 0.00 0.00 0.00 0.00 0.01 0.02

Cation 8.00 8.00 7.99 8.00 8.00 8.00 8.00 8.00 8.00 8.00 9.99 9.92 10.00

109
110
Table 1 (Continued)
Sample no. Plagioclase Staurolite

South North South North

M1 M2 Core Rim M2 Inc. Grt Matrix

GO-462a GO-159a GO-588a GO-462 GO-159 GO-286 GO-286a GO-462 GO-159 GO-588 GO-286 GO-286 GO-286 GO-286

Weight percent

S. Mahato et al. / Precambrian Research 162 (2008) 102–127


SiO2 59.64 61.23 61.51 59.67 59.59 62.75 62.89 27.53 27.21 27.97 26.95 27.16 27.03 26.78
TiO2 0.01 0.00 0.00 0.00 0.01 0.00 0.00 0.35 0.36 0.46 0.52 0.53 0.50 0.48
Al2 O3 25.17 24.32 24.51 25.18 24.10 23.02 22.85 54.17 53.87 53.91 53.62 53.33 53.81 54.10
Cr2 O3 0.00 0.00 0.00 0.00 0.00 0.00 0.00 0.00 0.00 0.00 0.00 0.00 0.00 0.00
Fe2 O3 b 0.18 0.20 0.02 0.04 0.02 0.01 0.11 0.00 0.00 0.00 0.00 0.00 0.00 0.00
FeO 0.00 0.00 0.00 0.00 0.00 0.00 0.00 13.92 13.37 14.23 14.99 15.01 15.10 15.28
MnO 0.00 0.02 0.07 0.05 0.00 0.00 0.01 0.12 0.12 0.02 0.15 0.15 0.01 0.05
MgO 0.02 0.01 0.05 0.01 0.00 0.01 0.00 1.60 1.36 1.08 1.51 1.52 0.91 0.85
CaO 6.34 5.80 5.70 6.68 5.82 4.41 4.22 0.00 0.00 0.02 0.02 0.00 0.01 0.00
Na2 O 8.36 8.54 8.10 8.16 8.31 9.08 9.14 0.00 0.01 0.00 0.01 0.02 0.00 0.05
K2 O 0.06 0.05 0.04 0.01 0.05 0.25 0.21 0.00 0.02 0.02 0.00 0.01 0.02 0.01
Totals 99.78 100.17 100.00 99.80 97.90 99.53 99.43 97.69 96.32 97.71 97.77 97.73 97.39 97.60
Cations
Si 2.67 2.72 2.73 2.67 2.71 2.79 2.80 7.65 7.65 7.77 7.54 7.60 7.58 7.51
Ti 0.00 0.00 0.00 0.00 0.00 0.00 0.00 0.07 0.08 0.10 0.11 0.11 0.11 0.10
Al 1.33 1.27 1.28 1.33 1.29 1.21 1.20 17.75 17.86 17.66 17.68 17.59 17.80 17.88
Cr 0.00 0.00 0.00 0.00 0.00 0.00 0.00 0.00 0.00 0.00 0.00 0.00 0.00 0.00
Fe3 0.01 0.01 0.00 0.00 0.00 0.00 0.00 0.00 0.00 0.00 0.00 0.00 0.00 0.00
Fe2 0.00 0.00 0.00 0.00 0.00 0.00 0.00 3.24 3.15 3.31 3.51 3.51 3.54 3.58
Mn 0.00 0.00 0.00 0.00 0.00 0.00 0.00 0.03 0.03 0.01 0.04 0.04 0.00 0.01
Mg 0.00 0.00 0.00 0.00 0.00 0.00 0.00 0.66 0.57 0.45 0.63 0.63 0.38 0.36
Ca 0.30 0.28 0.27 0.32 0.28 0.21 0.20 0.00 0.00 0.01 0.01 0.00 0.00 0.00
Na 0.73 0.74 0.70 0.71 0.73 0.78 0.79 0.00 0.01 0.00 0.01 0.01 0.00 0.03
K 0.00 0.00 0.00 0.00 0.00 0.01 0.01 0.00 0.01 0.01 0.00 0.00 0.01 0.00

Cation 5.03 5.01 4.98 5.02 5.02 5.01 5.00 29.40 29.35 29.30 29.51 29.50 29.42 29.47
Table 1 (Continued)
Sample no Ilmenite

South North

M1 Inc. St Matrix

GO-462a GO-462a GO-588 GO-122 GO-122 GO-122

Weight percent
SiO2 0.00 0.02 0.01 0.03 0.06 0.10

S. Mahato et al. / Precambrian Research 162 (2008) 102–127


TiO2 50.09 52.20 50.83 51.13 51.59 51.45
Al2 O3 0.00 0.00 0.00 0.09 0.09 0.05
Cr2 O3 0.00 0.00 0.00 0.00 0.00 0.00
Fe2 O3 b 4.95 1.94 2.10 1.97 1.34 1.70
FeO 44.30 46.07 45.53 45.52 45.84 45.28
MnO 0.58 0.47 0.10 0.16 0.21 0.20
MgO 0.09 0.08 0.05 0.06 0.06 0.12
CaO 0.00 0.00 0.00 0.02 0.03 0.00
Na2 O 0.00 0.06 0.00 0.03 0.03 0.11
K2 O 0.00 0.00 0.00 0.02 0.04 0.06
Totals 100.01 100.83 98.62 99.03 99.29 99.07
Cations
Si 0.00 0.00 0.00 0.00 0.00 0.00
Ti 0.95 0.98 0.98 0.98 0.99 0.98
Al 0.00 0.00 0.00 0.00 0.00 0.00
Cr 0.00 0.00 0.00 0.00 0.00 0.00
Fe3 0.09 0.04 0.04 0.04 0.03 0.03
Fe2 0.94 0.96 0.98 0.97 0.97 0.96
Mn 0.01 0.01 0.00 0.00 0.01 0.00
Mg 0.00 0.00 0.00 0.00 0.00 0.01
Ca 0.00 0.00 0.00 0.00 0.00 0.00
Na 0.00 0.00 0.00 0.00 0.00 0.01
K 0.00 0.00 0.00 0.00 0.00 0.00

Cation 2.00 2.00 2.00 2.00 2.00 2.00
a Data used in P–T calculation.
b Re-calculated from stoichiometry.

111
112 S. Mahato et al. / Precambrian Research 162 (2008) 102–127

Fig. 8. (a) EPMA X-ray images (top set photos) of garnet showing Ca and Fe variations in garnet in muscovite schist (GO-284) from the northern corridor. Lighter to
darker shades indicate decrease in element abundance. (b) Core to rim variations in XAlm (Fe/Fe + Mg + Ca + Mn) and similarly for XPrp , XGrs and XSps are shown (b,
left). Also shown are the variations in ZGrt (=Ca/Ca + Mg + Fe) and XGrt (Fe/Fe + Mg). (c) P–T KFMASH pseudosection (left) constructed with quartz, muscovite and
H2 O in excess for the garnet–staurolite-bearing mica schist. Bi-variant fields are in darker shades. The dotted box is the P–T field obtained from the thermobarometers.
The mole proportions of the KFMASH components recalculated to 100 are (K2 O = 13.85; Al2 O3 = 56.00; FeO = 26.67; MgO = 3.40). The broken lines show XGrt
isopleths (=Fe/Fe + Mg) in the garnet-bearing assemblages. The core → rim decrease in XGrt is consistent with increase in T and/or P. The box (dotted line) is the
P–T condition obtained from the thermobarometers using garnet (rim) and nearest-neighbor muscovite, biotite and plagioclase.

muscovite schists are dominant northwards in domains 2 and quartzofeldspathic gneisses (near Tebo). The mafic/ultramafic
3. The northernmost domain (domain 3; Fig. 9) is structurally rocks may be grouped into two structural varieties. The
and lithologically the most complex. While quartzites and first variety comprises multiply folded hornblende schists
mica schists/gneisses, with minor proportions of calc-schists, (chlorite–hornblende–clinozoisite–plagioclase ± quartz); the
are by far the most profuse lithologic components, the area rocks are characterized by multiple diastrophic fabrics and do
in parts is dominated by mafic and ultramafic rocks, and not preserve igneous texture. The second variety comprises
S. Mahato et al. / Precambrian Research 162 (2008) 102–127 113

Fig. 9. Lithologic map of domain 3 (between Hesadi and Tebo) in the southern corridor B (Fig. 2) showing the planar and the linear structural elements. Only
representative data are shown in the map; the complete data set is provided in the south hemispheric projections. The bold lines with filled triangles are the bounding
shear zones. Continuous and broken lines are proven and inferred lithologic boundaries, respectively. Short dashes demarcating lithologic margins of the amphibolites
are after Dunn (1929). The highway connecting Hesadi and Tebo is shown in gray line. Numbers in boxes refer to samples analyzed by EPMA and/or XRF. Each
sample number is prefixed by “GO-”. Southern hemispheric plots: left, showing the ␲S2S girdle (n = 319) contoured at intervals of 1%, 2%, 4%, 8% and 16% (in
increasing shades of gray; max 20.69%). The calculated β-axis corresponding to the girdle (broken line) is 02◦ → 078N. Centre, ␲S3S distribution (n = 53) in domain
3 shown as filled circles; the dip of the mean S3S is 77◦ /328N. Filled triangles are measured F3S fold axis (n = 32). Right, orientations of F2S fold axes (unfilled
triangles) in domain 3 (n = 22).

undeformed gabbros and peridotites (clinopyoxene, plagio- of S3S , the domal structure of S2S is correlated with non-plane
clase ± olivine ± orthopyroxene) that are barely deformed and non-cylindrical shear-related F3S folding.
typically unmetamorphosed. Apparently, the mafic/ultra-mafic
rocks were emplaced at different time with respect to defor- 3.2. Reaction textures
mational episodes. The mafic/ultramafic units are aerially
inconspicuous in domains 1 and 2. Mineral assemblages in the lower grade mica schists/phyllites
Mineral parageneises in metapelites from the three domains from domains 1 and 2 (Table 2) are not amenable to
are summarized in Table 2. As in the northern corridor, the quantitative P–T estimation. In domain 3, metamorphic
prominent schistosity in metapelitic rocks from the southern P–T conditions were determined by thermobarometry on
corridor is a crenulation cleavage (S2S ; subscript S refers to the garnet-bearing staurolite–kyanite gneisses and garnet-bearing
southern corridor); the earlier S1S schistosity is preserved in staurolite–kyanite free mica schists. Chemically, the rocks cor-
S2S inter-folial domains as rootless hinges or as inclusion trails respond to high-Al pelites, with staurolite–kyanite gneisses
in pre-S2S porphyroblasts. The prominent fold form is a set of being the most aluminous group (Fig. 10). In staurolite–kyanite
gentle to moderate plunging south-vergent folds on S2S (Fig. 9). gneisses, garnet is absent in the most mg-rich varieties (Fig. 10).
The F3S folds are non-planar and non-cylindrical. The associated This indicates that the appearance of garnet is compositionally
S3S axial plane cleavage is either absent or weakly developed. controlled.
In zones of high D3S strain, the southerly-overturned F3S folds In garnet-bearing staurolite–kyanite gneisses (analytical data
evolve into northerly dipping ENE-WSW trending S3S mylonite provided in Table 1), the earliest assemblage (M1S metamorphic
zones characterized by top-to-the-south shear sense. The top-to stage) comprises muscovite, biotite, garnet, kyanite, plagioclase
the-south thrust sense is indicated by stretching lineations at and chlorite. Garnet and kyanite typically occur as pre-S2S por-
high angles to the F3S fold axis. In domains 1 and 2, small (pre- phyroblasts (Fig. 11a, b). Straight and curved quartz inclusion
S3S ) garnet porphyroblasts in highly decomposed state occur trails within garnet (and kyanite) are terminated at high angle
in and neighboring the S3S shear zones. In domain 3 com- to the warping S2S schistosity (Fig. 11b). This implies garnet
prising the highest-grade rocks, including staurolite–kyanite and kyanite to be syn–post-S1S , but clearly pre-S2S . In a few
gneisses and garnet-bearing muscovite schists, S2S schistos- instances (Fig. 11c), pre-S2S garnet appears to be mantled by
ity in staurolite–kyanite gneisses and garnet-bearing muscovite staurolite porphyroblasts, but due to subsequent replacement of
schists describes a domal structure (Fig. 9), although the ori- staurolite by fine-grained muscovite + chlorite intergrowths the
entation of the S3S cleavage is identical to those in domains 1 textural relations are not unequivocal. Some of the pre-S2 gar-
and 2. Since the F2S fold axes lie on the average orientation net porphyroblasts are mineralogically and chemically zoned
114 S. Mahato et al. / Precambrian Research 162 (2008) 102–127

Table 2
Mineral paragenesis in the domains 1, 2 and 3 from the Nakti–Hesadi southern corridor (B in Fig. 2)

(Fig. 12a, b). The central parts of garnets are poor in inclusions in the garnets across the core–overgrowth interface is constant
(quartz  ilmenite  plagioclase), while the inclusion (quartz)- (Fig. 12c).
rich marginal parts are sieve textured. The inclusion-poor parts The continuous S2S schistosity is defined by muscovite,
are richer in grossular and poorer in almandine (and pyrope) biotite, staurolite and kyanite. The syn-S2S assemblage con-
compared to the sieve-textured marginal parts (Fig. 12b); the stitutes the M2S metamorphic stage. The interfaces between
compositional changes are abrupt across a boundary separating porphyroblasts of garnet, staurolite and kyanite on one hand,
the central and the sieve-textured parts. However, Fe/(Fe + Mg) and S2S muscovite-biotite aggregates on the other, are often

Fig. 10. AFM projections of whole rock composition of metapelites from (a) the southern corridor and (b) the northern corridor. The fields for low- and high-Al
pelite are taken from Spear (1993). The metapelites from the northern corridor are richer in Fe/Mg compared to their counterparts in the southern corridor. In the
southern corridor, the staurolite–kyanite ± garnet gneisses are more aluminous than in domains 1 and 2. The garnet-free staurolite–kyanite gneisses are among the
most Mg-rich samples.
S. Mahato et al. / Precambrian Research 162 (2008) 102–127 115

Fig. 11. Textural relations in metapelites from the southern corridor. (a, b) In garnet-bearing staurolite–kyanite gneisses, pre-S2S garnet–kyanite–biotite–muscovite
assemblage wrapped by staurolite–muscovite–biotite defines S2S fabric. In both figures, staurolite is absent in pre-S2S assemblage. In (a), the M1S kyanite porphyroblast
overgrows the S2S fabric (within circle). Shape-preferred alignment of pre-S2S kyanite in (a) and pre-S2S garnet-hosted inclusion trails of quartz (in b) defining the
S1S schistosity, are truncated at high angles by the S2S fabric. Image was taken in plane polarized light. (c) In garnet-bearing staurolite–kyanite gneiss neighboring
S3S mylonite zone, a central garnet grain is mantled by optically continuous and physically separated staurolite grains. The staurolite is decomposed to a fine-grained
muscovite + chlorite intergrowth. (d) Staurolite (in higher relief) and garnet porphyroblasts in staurolite–kyanite gneisses neighboring D3 high strain zone are partially
altered (some are pseudomorphed) by chlorite + muscovite intergrowth that overgrow the chlorite–muscovite–biotite-defined S3S mylonite fabric. The earlier S1S
and S2S fabrics are either obliterated or transposed parallel to S3S . (e) In garnet-free staurolite–kyanite gneisses, coarse sieve-textured staurolite porphyroblasts
and coarse plates of kyanite are wrapped by S2S schistosity. Note the pressure shadows (partially shown) around the sieve-textured staurolite porphyroblast. Relict
sigmoidally curved S1S schistosity (broken line) defined by muscovite and biotite, and inclusion trails in staurolite and kyanite can be observed within the pressure
shadow. The quartz inclusions in the staurolite are approximately parallel to the S1S schistosity. Parts of the staurolite and kyanite porphyroblasts extend into and
appear to overgrow the S2S fabric (arrow). Note the persistence of chlorite syn-tectonic with S2S .

blurred by fine-grained intergrowths of muscovite and chlo- typically syn- to post-tectonic with respect to S3S mylonite
rite (Fig. 11c, d)). The intergrowths typically overgrow the S2S fabric (Fig. 11d). The textural relations suggest widespread
cleavage. The decomposition of the porphyroblasts to muscovite syn- to post-S3S retrogression (M3S stage) of staurolite-bearing
and chlorite is most intense within and in zones neighbor- assemblages that could be related to the reaction stauro-
ing the S3S shears. In the shear zones, the intergrowths are lite + biotite → chlorite + muscovite.
116 S. Mahato et al. / Precambrian Research 162 (2008) 102–127

Fig. 11. (Continued ).

Fig. 12. (a) PPL image showing two-stage growth of pre-S2S M1S garnet porphyroblast, with an inclusion-poor core mantled by inclusion-rich sieve-textured rim
in a staurolite–kyanite gneiss (GO-462). Staurolite occurs only in the S2S M-domain. (b) EPMA X-ray images show variation of Ca, Mg, Fe and Mn in the part of
garnet shown by box in (a). (c) Compositional variations of XGrt (=Fe/(Fe + Mg) and ZGrt (=Ca/Ca + Fe + Mg) along line A-B (box in (a)) are shown.
S. Mahato et al. / Precambrian Research 162 (2008) 102–127 117

In garnet-free staurolite–kyanite gneisses, with higher mg# bor phases (muscovite, biotite, plagioclase, kyanite). To ensure
(Fig. 10b), the pre-S2S porphyroblasts are typically staurolite that the estimated temperatures were not locked-in on cooling
and kyanite (Fig. 11e). The minerals and muscovite, chlorite and through diffusive exchange across the garnet–biotite/chlorite
biotite constitute the M1S metamorphic assemblage. Since the interface, compositions of biotite in contact with garnet were
garnet-free and the garnet-bearing variants of staurolite–kyanite not considered.
gneisses are intimately associated in the Tebo-Hesadi area, P–T estimate for M1S metamorphic stage were obtained from
the metamorphic P–T conditions for the stabilization of M1S three garnet-bearing staurolite–kyanite gneisses from domain 3
garnet–kyanite assemblage in mg-poor variety are expected to (Fig. 13). The P–T conditions obtained from the intersections of
be similar to those obtained from M1S staurolite–kyanite assem- mineralogical thermobarometers varied in the range 8–12 kbar
blage in higher mg# gneisses. In other words, the stability of and 550–700 ◦ C, with the preferred mean at 10 ± 1.5 kbar and
garnet + kyanite assemblage with respect to staurolite–kyanite 625 ± 50 ◦ C. Thermobarometrically constrained P–T estimates
assemblage is extended to higher temperature and pressure from the NSMB exist only for three areas, e.g. Surda and
with increasing mg#. In fact, the staurolite–kyanite assem- Sini (near Tatanagar; Fig. 1). In the Sini area, the highest P–T
blage in mg-richer gneisses continues to persist during S2S , conditions reported by Lal et al. (1987) are 450–580 ◦ C and
i.e. through the M2S stage, and only starts to decompose to 4.4–5.3 kbar for M1 metamorphism. Sengupta et al. (2005)
chlorite + muscovite intergrowths post-dating S3S (M3S stage). estimated Pmax and Tmax values ∼480 ± 40 ◦ C, 6.4 ± 0.4 kbar
Mica schists associated with staurolite–kyanite gneisses from the Surda mica schists. Ghosh et al. (2006) retrieved a
occur as bands of varying width and extent intimately associated peak pressure of ∼550 ◦ C and 5.5 kbar for the Ghatsila mica
with quartzites. The schists are characterized by a simple miner- schists. The mean M1S metamorphic pressure estimated in this
alogy comprising quartz, muscovite, biotite, garnet, ilmenite and study is, therefore, about twice the known estimates from the
plagioclase, with tourmaline and apatite as the accessory phases. NSMB.
Chlorite is absent in the rocks, except in zones neighboring the
bounding shear zones. S2S is the regional schistosity in domains 3.4. P–T path for staurolite–garnet–kyanite gneisses
distal from the shear zones. Both S1S and S2S fabrics are defined
by the parallelism of muscovite and biotite (±ilmenite). Gar- P–T pseudosection (Fig. 14a) was constructed for a
net porphyroblasts are typically wrapped by the S2S schistosity garnet-bearing staurolite–kyanite gneiss (GO-462) using mole-
with prominent pressure shadows, and garnet-hosted inclusion proportion of oxides in NCKFMASH system calculated on
trails, if present, are generally straight and oriented at high H2 O-free, silica-free and FeO(total) basis from XRF whole rock
angles to the schistosity. Post-S2S garnets occurring as dis- data. Quartz, plagioclase and H2 O were considered to be in
crete grains or overgrowths on pre-existing garnets are absent. excess in constructing the pseudosection. The P–T pseudo-
The garnet margins are often corroded and replaced by thin section was constructed using the thermodynamic data set of
mantles of randomly-oriented fine-grained muscovite–chlorite THERMOCALC program (version 3.21) of Holland and Powell
intergrowths post-dating S2S schistosity. The textural relations (1998). Fig. 14b is an amplified portion of Fig. 14a showing the
suggest that garnet porphyroblasts were pre- to syn-tectonic with variation of XGrt (=Fe/Fe + Mg) and ZGrt (=Ca/Ca + Fe + Mg)
S2S , while its decomposition to muscovite + chlorite was post- isopleths in garnet-bearing phase fields. The XGrt and ZGrt values
S2S . Proximal to the S3S shear zones, the alteration of garnet to were computed for P–T windows of 10 ◦ C and 200 bar. There-
muscovite + chlorite is prolific. fore, the uncertainties in P and T of the XGrt and ZGrt values are
±100 bar and ±5 ◦ C.
3.3. Thermobarometry The minerals commonly hosted within M1S garnet are mus-
covite, chlorite, plagioclase and ilmenite. Garnet-hosted kyanite
Temperatures were estimated using biotite garnet ther- was not observed. This, coupled with the absence of chlori-
mometer (Thompson, 1976; Holdaway and Lee, 1977; Ferry toid and staurolite within garnet, suggests that the prograde
and Spear, 1978; Hodges and Spear, 1982; Perchuk and P–T path that produced M1S garnet ± kyanite was for the
Lavrent’eva, 1983; Bhattacharya et al., 1992), muscovite–biotite most part restricted to chlorite + garnet + muscovite (+plagio-
thermometers based on Mg-Tschermak’s substitution (Wu clase + quartz + H2 O) phase field. In this field, the isopleths
et al., 2000, cited in GTB program; Hoisch, 1989), of XGrt and ZGrt are sub-parallel to the pressure axis and
and the garnet–chlorite thermometer of Dickenson and decrease with increasing temperature (Fig. 14b). The theoret-
Hewitt (1986). The geobarometric equilibria that could be ically determined composition may be compared with core
applied were garnet–plagioclase–quartz–kyanite (Newton and to rim compositional variations in GO-462 pre-S2S garnet in
Haselton, 1981; Hodges and Spear, 1982; Ganguly and Fig. 12. Since XGrt is constant and ZGrt decreases from core to
Saxena, 1984; Hodges and Crowley, 1985; Koziol, 1989), rim (Fig. 12), the compositional variations can be explained by
garnet–plagioclase–muscovite–biotite (Ghent and Stout, 1981; growth of garnet within the garnet + chlorite + muscovite (+pla-
Hodges and Crowley, 1985; Powell and Holland, 1988; Hoisch, gioclase + quartz + H2 O) field due to decrease in pressure and
1990) and garnet–plagioclase–muscovite–quartz (Hodges and increase in temperature (Fig. 14b). Alternatively, if the garnet
Crowley, 1985; Hoisch, 1990). In the thermobarometric reac- formed within the garnet + kyanite + muscovite + biotite (+pla-
tions that involve garnet, rim composition of garnet rim was gioclase + quartz + H2 O) field, the chemical variations suggest
used in combination with the compositions of nearest neigh- that garnet growth was promoted by a P–T path parallel to XGrt
118 S. Mahato et al. / Precambrian Research 162 (2008) 102–127

Fig. 13. M1S P–T estimates (shaded boxes) obtained from garnet–kyanite–plagioclase–muscovite–biotite–quartz assemblages in staurolite–kyanite gneisses GO-462,
-159 and -588. The top set of images shows the P–T loci of biotite–garnet thermomteric formulations and barometers involving garnet, plagioclase, kyanite, biotite,
muscovite and quartz (see text for discussion). In the bottom-set figures, the P–T locations for the muscovite–biotite and garnet–chlorite thermometers are shown.
Continuous lines are for Ms–Bt thermometers (M1S assemblage) and the broken lines for Grt–Chl thermometers (M3S assemblage). The shaded boxes are the same
as in the corresponding top-set figures.

contours and in a direction of decreasing ZGrt . Since the XGrt 3.5. EPMA monazite dating
contours are sub-parallel to the T-axis, and the ZGrt contours
are characterized by high dP/dT slopes in the field, the forma- EPMA monazite dating by Th–U-total Pb isochron method
tion of garnet was promoted by near-isobaric heating. In both (Suzuki et al., 1991) was undertaken to constrain the key events
cases, the estimated M1S temperature was attained following in the southern corridor. Three samples were analyzed for the
heating along the prograde arm of a clockwise P–T path. How- purpose, e.g. a staurolite–kyanite bearing paragneiss (GO-159)
ever, if garnet grew within the chlorite + muscovite + garnet field, and a staurolite–kyanite free mica schist GO-430) from domain
the estimated M1S temperature obtained from the garnet rim 3, and a chlorite–muscovite–biotite schist (GO-442) contain-
was attained through heating following the attainment of peak ing unusually large monazite grains from domain 1. GO-159
pressure. And, the M1S peak-pressure should lie at P values is a sheared paragneiss located adjacent to a locally developed
higher than the (>8.5 kbar) stability field of Grt–St–Chl–Ms S3S shear zone in domain 3, whereas GO-442 lies proximal to
(+Pl + Qtz + H2 O), because garnet and staurolite are mutu- the southernmost shear zone in domain 1. Quantitative micro-
ally exclusive in the paragneisses. The available evidence, probe analyses of monazites were carried out at the University
when considered together, suggests that the post-peak P–T of Bochum with a Cameca SX50 Electron probe Micro ana-
path passed through the left of the P/T box (broken line) in lyzer. The operating conditions were 20 kV acceleration voltage,
Fig. 14a. 100 nA beam current, and beam diameter of 6 ␮m. Th, Y, Pb,
Thermobarometric estimates for M2S and M3S metamorphic P and U were measured in each spot. REE’s were taken to be
stages could not be determined due to the lack of adequate min- Ce as difference to a total of 100. The raw analytical data were
eral assemblages. Instead, the stability relations shown in the corrected for matrix effects following the procedure outlined in
P–T pseudosection (Fig. 14a) were combined with the syn-S2S Armstrong (1995), and the chemical age for each spot analysis
(M2S ) and syn- to post-S3S (M3S ) decomposition reactions to was calculated using the decay equation (Montel et al., 1996) and
constrain the retrograde P–T path. The net transfer reaction, gar- the least-square fit model of York (1966) using the MINCALC v.
net + kyanite + muscovite → biotite + plagioclase + staurolite, 5 programs. The analytical data and the computed ages are pre-
that led to the formation of M2S staurolite from M1S garnet– sented in Table 3. Linear background corrections were employed
kyanite assemblage occurred at ∼7–8 kbar and 625–650 ◦ C, for the analytical conditions. However, the curvature of back-
while the stabilization of M3S chlorite–muscovite overgrowths ground particularly under the Pb peak is a significant analytical
replacing staurolite (staurolite + biotite → chlorite + muscovite) consideration (Dahl et al., 2005a,b; and references therein). The
is likely to have occurred at lower P–T conditions, e.g. use of linear background correction may have led to somewhat
4.5–7.0 kbar and 550–580 ◦ C. erroneous and usually anomalously younger computed dates. In
S. Mahato et al. / Precambrian Research 162 (2008) 102–127 119

Table 3 Table 3 (Continued )


Concentrations (wt%) of Y, Pb, Th and U and calculated chemical ages of
monazite in mica schists from the southern corridor wY wPb wTh wU Age (Ma)

wY wPb wTh wU Age (Ma) 0.616 0.3245 5.112 0.257 1187


0.641 0.2394 3.591 0.249 1180
GO-159 (monazites in matrix) 0.628 0.3253 4.125 0.284 1385
0.791 0.2738 4.043 0.1923 1272 0.638 0.3134 5.02 0.252 1168
0.872 0.311 4.799 0.2548 1201 0.651 0.3631 5.209 0.269 1293
0.887 0.2738 3.951 0.2614 1235 0.651 0.3871 5.297 0.267 1357
0.913 0.5566 8.457 0.3324 1268 0.621 0.3144 3.952 0.281 1388
0.898 0.5434 8.517 0.3088 1242 0.613 0.3465 4.193 0.262 1473
0.899 0.3649 6.467 0.2369 1103 0.611 0.3225 4.154 0.266 1383
0.955 0.3501 5.421 0.2887 1196 0.594 0.3719 4.886 0.235 1419
0.91 0.2394 4.784 0.2339 948 0.615 0.3044 4.249 0.283 1273
0.911 0.3914 7.06 0.2372 1094 0.622 0.2652 3.93 0.311 1163
0.961 0.4859 8.155 0.2558 1181 0.595 0.2948 4.133 0.255 1284
0.901 0.4352 7.25 0.2431 1181 0.619 0.2536 3.887 0.245 1176
0.91 0.4665 7.82 0.2256 1191 0.958 0.404 5.317 0.292 1390
0.873 0.4326 7.525 0.224 1146 0.945 0.3894 5.578 0.275 1303
0.868 0.5229 8.461 0.2314 1238 1.046 0.527 7.566 0.371 1301
0.916 0.5025 8.221 0.2481 1214 0.617 0.3404 5.776 0.222 1144
0.852 0.5696 8.607 0.2087 1335 0.943 0.4512 6.26 0.34 1324
0.799 0.4988 7.919 0.2375 1251 1.041 0.5091 7.423 0.363 1283
0.905 0.5254 8.877 0.2767 1174 1.031 0.4404 6.239 0.342 1296
0.825 0.4901 7.719 0.2048 1273 1.087 0.3952 5.232 0.331 1350
0.889 0.6309 10.034 0.2906 1252 1.047 0.4011 5.462 0.33 1325
0.771 0.4696 7.407 0.2263 1256 0.962 0.3849 5.382 0.321 1295
0.949 0.5677 9.116 0.319 1218 0.997 0.3432 4.608 0.311 1317
0.819 0.5091 8.432 0.2387 1207 1.04 0.4152 5.645 0.319 1342
0.942 0.4116 5.553 0.396 1298 1.035 0.4833 7.106 0.318 1288
0.795 0.2696 3.999 0.294 1179 0.99 0.3244 4.876 0.282 1215
0.891 0.4939 7.115 0.425 1259 1.268 0.5201 7.08 0.423 1328
0.815 0.3502 4.854 0.325 1280 1.077 0.5883 8.171 0.365 1360
0.781 0.3376 4.844 0.312 1247 0.9 0.6891 12.823 0.351 1082
0.82 0.3343 4.683 0.299 1278 1.062 0.8306 12.114 0.373 1353
0.804 0.4479 6.358 0.391 1270 1.019 0.7725 17.505 0.395 907
0.842 0.4249 6.086 0.334 1283 1.037 0.4493 6.394 0.334 1300
0.845 0.3707 5.26 0.36 1247 0.835 1.5608 23.849 0.565 1323
0.758 0.3369 4.746 0.309 1267 0.959 0.4191 6.114 0.259 1307
0.808 0.4105 5.932 0.291 1293 1.033 0.4583 6.523 0.333 1305
0.788 0.3906 5.591 0.311 1281 0.881 0.3087 4.028 0.263 1362
0.799 0.4393 6.263 0.331 1296 0.911 0.3261 4.603 0.272 1285
0.802 0.5162 7.642 0.354 1274 1.217 0.3436 3.621 0.633 1287
0.819 0.5281 7.9 0.341 1273 0.95 0.3252 4.502 0.308 1276
0.861 0.4748 6.86 0.315 1305 0.92 0.5398 2.838 0.307 2760
0.798 0.5132 7.539 0.362 1277 1.051 0.2997 3.88 0.436 1217
0.831 0.5018 7.556 0.367 1245 0.903 0.1941 2.069 0.326 1320
0.874 0.5742 8.206 0.404 1306 1.298 0.2892 3.012 0.516 1311
0.836 0.5217 7.589 0.376 1283 0.96 0.2652 3.987 0.557 993
0.849 0.5605 8.261 0.392 1275 1.23 0.2945 2.84 0.584 1315
0.669 0.4169 5.566 0.284 1386 1.142 0.3394 4.134 0.912 1029
0.586 0.2699 3.425 0.242 1378 0.954 0.3612 5.195 0.275 1285
0.605 0.3206 4.616 0.26 1271 0.909 0.2972 4.395 0.25 1237
0.664 0.3283 4.437 0.224 1372 0.954 0.1688 1.522 0.408 1253
0.669 0.288 4.332 0.099 1346 0.933 0.3777 5.467 0.248 1305
0.631 0.3071 4.5 0.309 1209 0.947 0.2391 2.833 0.333 1307
0.702 0.3332 5.023 0.337 1182 0.745 0.3445 6.26 0.294 1045
0.61 0.4306 6.025 0.25 1363 1.058 0.3468 4.678 0.348 1288
0.621 0.2566 4.373 0.248 1081 0.936 0.2225 2.729 0.291 1298
0.638 0.2364 3.726 0.25 1132 0.924 0.4087 5.556 0.308 1346
0.642 0.2816 3.723 0.372 1230 0.973 0.3796 5.372 0.348 1262
0.642 0.5318 7.165 0.339 1389 0.99 0.4372 6.063 0.333 1323
0.623 0.5043 7.114 0.283 1359 0.97 0.3137 4.158 0.311 1308
0.611 0.5153 6.84 0.312 1416 0.971 0.3778 5.202 0.296 1324
0.665 0.4548 6.418 0.3 1332 1 0.493 7.082 0.359 1294
0.669 0.4635 6.723 0.35 1278 0.992 0.5022 6.892 0.339 1358
0.646 0.4358 6.336 0.334 1272 0.998 0.4471 6.66 0.333 1253
0.796 0.4667 6.438 0.451 1275
120 S. Mahato et al. / Precambrian Research 162 (2008) 102–127

Table 3 (Continued ) Table 3 (Continued )


wY wPb wTh wU Age (Ma) wY wPb wTh wU Age (Ma)

0.989 0.3514 5.028 0.288 1275 1.321 0.089 0.887 0.097 1564
0.972 0.4546 6.377 0.332 1319 0.745 0.1071 1.189 0.105 1491
0.945 0.3463 4.743 0.28 1323 0.678 0.0286 0.086 0.06 1967
0.97 0.4866 6.993 0.341 1301 0.426 0.0228 0 0.103 1362
1.02 0.4047 5.395 0.309 1364 0.389 0.0167 0 0.039 2316
0.956 0.3851 5.252 0.282 1348 0.466 0.0161 0.171 0.025 1360
0.998 0.3741 5.11 0.319 1314 0.648 0.0203 0.143 0.037 1591
0.971 0.4037 5.302 0.307 1381 0.454 0.0203 0.01 0.057 1944
1.006 0.4219 6.014 0.322 1294 0.678 0.0455 0.279 0.082 1702
1.051 0.4089 5.524 0.341 1331 0.438 0.0187 0.067 0.048 1669
1.062 0.3958 5.482 0.304 1322 1.404 0.0837 0.412 0.271 1336
1.042 0.4321 7.183 0.353 1131 1.483 0.1011 0.594 0.26 1448
0.963 0.4239 6.155 0.296 1291 1.131 0.0897 0.51 0.177 1681
1.011 0.3949 5.676 0.299 1286 1.185 0.0596 0.365 0.177 1318
1.204 0.4108 6.675 0.306 1167 1.354 0.0838 0.382 0.268 1373
1.042 0.5581 7.974 0.364 1320 1.069 0.0501 0.111 0.159 1584
1.03 0.3915 5.61 0.285 1297 1.517 0.1061 0.344 0.372 1390
1.152 0.4617 6.556 0.37 1288 1.363 0.0846 0.353 0.27 1405
1.186 0.5529 7.874 0.424 1293 1.2 0.0712 0.262 0.205 1546
0.921 0.3599 5.503 0.273 1223 1.365 0.0966 0.398 0.251 1603
1.515 0.1161 0.381 0.361 1506
GO-430 (monazites in porphyroblast)
1.546 0.1225 0.529 0.349 1497
0 2.0668 26.052 0.749 1564
1.239 0.0832 0.168 0.275 1557
0.68 1.1326 14.613 0.392 1539
1.442 0.1178 0.252 0.313 1802
0.64 0.8317 10.797 0.291 1530
1.303 0.0989 0.165 0.243 1965
0.308 2.4764 29.708 1.094 1599
1.268 0.0877 0.139 0.246 1802
0.392 2.1472 26.499 0.895 1571
1.245 0.0971 0.127 0.25 1953
0.491 1.7819 21.593 0.966 1547
1.222 0.0896 0.131 0.241 1873
0.346 1.0527 13.428 0.35 1560
1.485 0.1039 0.18 0.326 1646
0.178 0.8566 11.2 0.241 1546
1.385 0.0892 0.167 0.236 1841
0.05 1.0372 13.567 0.274 1552
1.205 0.0761 0.158 0.21 1763
1.142 1.2435 15.9 0.514 1526
0.348 1.4057 18.669 0.359 1534
0.308 1.1237 14.818 0.299 1540
0.422 1.1742 15.153 0.316 1568
view of this, the standard errors of the chemical dates are not
GO-430 (monazites in matrix) presented in Table 3, and the chemical dates may be considered
0.21 0.5843 7.524 0.805 1239
0.003 1.7221 23.591 2.011 1234
to be cursory in nature.
In mica schist of domain 3 (GO-430), monazites were few
GO-442 (monazites in matrix)
in number, but were present both within garnet porphyroblast
1.306 0.0968 0.204 0.271 1742
1.187 0.0735 0.152 0.196 1806 (Fig. 15a) and in the matrix. The garnet-hosted monazites were
1.168 0.0719 0.132 0.19 1847 unzoned, small (25–30 ␮m diameter), elliptical to circular in
1.346 0.0919 0.168 0.278 1681 shape, and contained 0.93–2.61% of PbO, 0.27–1.24% UO2
1.317 0.0986 0.155 0.25 1937 and 12.24–33.81% ThO2 . Monazites in the matrix were also
1.199 0.0772 0.126 0.213 1818
unzoned, somewhat larger (∼100 ␮m in maximum length) and
1.193 0.0734 0.115 0.205 1809
1.193 0.0892 0.454 0.251 1441 contained 0.63–1.86% of PbO, 0.91–2.28% UO2 , 8.56–26.84%
1.406 0.1195 0.543 0.352 1447 ThO2 . In sheared and retrogressed staurolite–kyanite gneiss
1.24 0.0873 0.35 0.228 1609 (GO-159), monazites were rare in the relict porphyroblasts, but
1.389 0.1159 0.452 0.326 1548 were abundant in the matrix (Fig. 15b). The monazites were
1.234 0.0764 0.252 0.221 1579
somewhat irregular in shape and size (max. length: 180 ␮m),
1.367 0.0925 0.39 0.288 1424
1.39 0.1069 0.482 0.299 1497 weakly zoned, and contained 0.25–1.68% of PbO, 0.11–1.03%
1.443 0.1147 0.503 0.333 1474 UO2 , 1.73–27.13% ThO2 . Compositional zoning in the mon-
1.136 0.0755 0.15 0.219 1713 azite grains in the samples GO-430 and GO-159 were checked
1.456 0.1035 0.21 0.316 1648 using BSE imagery, but elemental X-ray imaging was not per-
1.211 0.082 0.15 0.207 1906
formed. Therefore, delicate element zoning unresolved with
0.588 0.0404 0.13 0.082 1976
0.572 0.0486 0.1 0.129 1814 BSE imagery may have escaped attention. However, chemical
0.095 0.02 0.164 0.007 2235 ages determined in single grains did not show systematic core
0.059 0.0337 0.25 0.02 2202 to rim younging trend.
0.504 0.0392 0.089 0.082 2085 The most prominent peak occurs at ∼1280 Ma with consider-
0.694 0.0372 0.145 0.065 2038
able scatter, and a less prominent peak at ∼1520 Ma (Fig. 16a, b).
0.571 0.0398 0.052 0.081 2291
0.902 0.0759 0.715 0.068 1705 The well defined peak at ∼1520 Ma is obtained from monazites
S. Mahato et al. / Precambrian Research 162 (2008) 102–127 121

words, the age provides a minimum estimate for M1S garnet


growth. This age coincides with the age of uranium mineral-
ization at the SSZ determined by Rao et al. (1979) based on
U–Pb isotope ratios in uraninite. A somewhat comparable K–Ar
date (∼1550 Ma) in tholeiites was obtained by Saha (1994).
Roy et al. (2002) determined a somewhat older Rb–Sr isochron
age (∼1619 ± 38 Ma) for gabbro–pyroxenite intrusives prox-
imally located to the Dalma metaigneous. The younger age
cluster at ∼1280 Ma was obtained from monazites in sheared
S3S matrix minerals. Two lines of evidence suggest that the age
may correspond to the S3S shearing–exhumation event. First,
the monazites in the sheared matrix are anhedral with mar-
gins that overgrows the S3S fabric (cf. Fig. 15b). Second, the
matrix monazite grains are typically homogeneous with rare
older (∼1.55 Ga) spot ages. This may imply that either the
older ages were largely re-set at 1.3 Ga or the 1.3 Ga monazites
may have grown broadly synchronous with S3S shearing. This
appears to be a reasonable assumption in the absence of subse-
quent amphibolite facies diastrophic events affecting the rocks.
The age data of 1.3 Ga coincides with K–Ar ages reported from
several areas in the NSMB (Misra and Johnson, 2005).
The chlorite–muscovite schist (GO-442) from domain 1 is
unusual in more than one way. First, the schist is unusually rich in
CaO (24.78 wt%) and P2 O5 (25.26 wt%) compared to the schists
and paragneisses from the southern sector. Second, the mon-
azites (>100 ␮m, and up to 300 ␮m in length) are botryoidally
shaped chemically zoned grains, with light gray margins around
darker-shaded interior (Fig. 15c, d). The lighter-shaded margins
are continuous and symmetrically disposed adjacent to grain
boundaries or cracks forming a hexagonal or honeycomb-like
network (Fig. 15c, d). And finally, the cores of monazite grains
(0.02–0.13% of PbO, 0.01–0.42% UO2 , 0.00–0.67% ThO2 ) are
characterized by extremely low thorium contents. The histogram
(Fig. 16c) based on spot age data retrieved from core portions in
monazites in GO-442 shows a wide scatter (1300–2400 Ma), and
Fig. 14. (a) NCKFMASH P–T pseudosection showing the stability fields of
the majority of computed dates are older than 1500 Ma. The old-
mineral assemblages in the range 500–750 ◦ C and 4–16 kbar calculated using
the bulk composition of garnet–staurolite–kyanite gneiss GO-462. Pl, Qtz and est dates (2.2–2.4 Ga) coincides with the depositional age of the
H2 O were in excess. The darkest shade corresponds to low variance fields; pro- Singhbhum Group of metasediments suggested by Sarkar and
gressively lighter shades are for higher variance fields. The mole proportions Saha (1983) and Saha et al. (1988), and the age of intercalated
of the system components (recalculated to 100) are Na2 O = 7.54; CaO = 5.80; Dalma (meta-) volcanics (Misra and Johnson, 2005).
K2 O = 7.43; Al2 O3 = 49.98; FeO = 12.97; MgO = 16.27. The box outlined by
Available evidence (Copeland et al., 1988; Suzuki and
broken line highlights the P and T conditions (Fig. 13) obtained for the rock
using rim composition of M1S garnet and neighboring phases. The bold line with Adachi, 1994; Cherniak et al., 2004) indicates Pb loss in
arrowhead shows the reconstructed P–T path. The prograde P increase shown as monazites does not occur at temperature below 600 ◦ C;
broken line is purely conjectural. The question mark between the loading related higher closure temperature (700 ◦ C) has been indepen-
P–T path and the exhumation-related P–T path is inserted to suggest a possible dently postulated by Dahl (1997). The greenschist facies
break in the P–T evolutionary history (refer to text). (b) An enlarged portion of
chlorite–muscovite ± biotite schist (GO-442) arguably did not
the NCKFMASH P–T pseudosection in A showing XGrt [=Fe/Fe + Mg)] (bro-
ken line) and XGrt [=Ca/(Ca + Mg + Fe)] (dotted line) contours in phase fields experience metamorphic temperature in excess of 550 ◦ C at
involving garnet (unshaded). The shaded fields are for garnet-free assemblages. any stage of their evolutionary history. Therefore, the oldest
Details of contour construction are discussed in the text. The contour intervals ∼2400 Ma CHIME dates in GO-442 monazites are unlikely to
are not constant. correspond with the metamorphic recrystallization events sug-
gested in this study. Instead, the chemical age (2.2–2.4 Ga) of the
hosted within M1S garnet porphyroblasts (Fig. 15a), whereas monazite grains may correspond with the age of deposition of the
monazites in the matrix (Fig. 15b) yielded younger dates, with sedimentary precursors to para-schists in the southern corridor.
∼1280 Ma being most prominent (Fig. 16). The older age clus- However, as the very low concentrations of Th, U and Pb may
ter ∼1520 Ma in M1S garnet-hosted monazites corresponds to also induce large error in the chemical ages, the assumption that
the age of entrapment of monazite in the garnet during M1S the 2.2–2.4 Ga represents the age of sedimentation is specula-
prograde loading and heating of the crustal domain. In other tive. It is in-built in the inference that the 2.4 Ga monazites once
122 S. Mahato et al. / Precambrian Research 162 (2008) 102–127

Fig. 15. Back-scattered-electron image of monazite grains in metpelites from the southern corridor. (a) Occurrence of garnet-hosted monazite in mica schist GO-430A
(domain 3); blown-up image of the monazite to the right shows its unzoned nature. (b) Anhedral monazite grains in mylonitized (D3S ) staurolite–kyanite gneiss
GO-159 (domain 3) apparently overgrowing the S3S fabric. Close-up views in the right show lack of apparent zoning in the monazite grains. (c, d) Back-scattered-
electron images showing the occurrence of monazite in chlorite-muscovite schist GO-442 in domain 1. The botryoidal monazite grains show darker-shaded cores
mantled by lighter-shaded rims symmetrically developed along grain margins. The rims form a continuous network around the cores. (+) marks show the analyzed
spots in the monazite grains.

existed in the higher-grade gneisses of domain 3, but were all The near peak P–T minerals experienced exhumation and cool-
reset at ∼1.5 Ga by either thermally-driven Pb diffusion or fluid- ing at amphibolite facies conditions (M2S metamorphic stage;
driven processes of dissolution and recrystallization operating syn-S2S ) and at greenschist facies conditions corresponding to
below the Pb diffusional closure temperature. the M3S stage (syn- to post-S3S ). The chemical dates in mon-
azites from the matrix of S3S mylonitized staurolite–kyanite
3.6. The composite P–T path; the southern corridor gneisses are inferred to indicate the last exhumation event to
have occurred at ∼1.3 Ga (Fig. 17a). By implication, the Meso-
The composite P–T path retrieved from textural-petrogenetic proterozoic exhumation of the crustal segment occurred over a
considerations in the highest-grade para-gneisses (and schists) protracted time.
from the west-central part of the North Singhbhum Mobile Belt The Tmax value in the reconstructed P–T path for the NSMB
is shown in Fig. 17a. Earlier estimates (Ghosh et al., 2006; high-grade gneisses is considerably higher (>200 ◦ C; Fig. 17b)
Sengupta et al., 2005; Lal et al., 1987) of Pmax and Tmax compared to the documented peak temperature of subduction
values are lower than 6 kbar and 550 ◦ C, respectively. These zone settings (Ernst, 1988; Ernst et al., 1997). By implication,
values were retrieved from the Ghatsila–Sini areas. The high- the subducting crust in the North Singhbhum Mobile Belt was
est Pmax and Tmax values retrieved in this study indicate that likely to have been characterized by higher geothermal gradient
the more deeply buried parts of the NSMB are located closer compared to the cold slab subduction model.
to the Dalma meta-igneous suite and in the centrally-located
domains within the orogen. The Tmax value was attained fol- 4. Concluding remarks: tectonothermal evolution of the
lowing loading, and by implication the thermobarometrically mobile belt
constrained P value is likely to be comparable or lower com-
pared with Pmax experienced by the rocks. Cursory chemical Summarizing, in the northern corridor, prograde heating syn-
dates obtained from monazites within M1S garnet indicate the chronous with crustal shortening (syn-tectonic with S2S and S3S )
prograde metamorphism to have occurred >1.5 Ga (Fig. 17). in highest-grade rocks (T ∼620 ◦ C, P ∼7 kbar) occurs towards
S. Mahato et al. / Precambrian Research 162 (2008) 102–127 123

Fig. 16. Frequency plots of CHIME dates obtained from spot analyses in monazites grains in mica-schist from the southern corridor. CHIME dates obtained in
multiple monazite grains from (a) sheared garnet-bearing staurolite–kyanite gneiss GO-159 (domain 3), (b) garnet-bearing mica schist GO-430 (domain 3), and
(c) chlorite–muscovite schist GO-442 in domain 1. ‘n’ indicates total number of spots analyzed. Darker-shaded bars in (b) are for CHIME dates obtained from
garnet-hosted monazite; the lighter-shaded bars in (a) and (b) are for monazites occurring in the matrix.

the foreland and at a deeper structural level with respect to S3N . prograde arm of a possible clockwise P–T path (Pmax ≥ 10 kbar;
By contrast, the highest-grade metamorphic rocks in domain 3 Tmax ∼650 ◦ C) followed by post-loading heating prior to S2S ,
flanked by lower-grade rocks in the southern corridor occur in a and finally cooling–exhumation synchronous with S2S and S3S in
narrow zone towards the hinterland and at shallower structural the retrograde sector. Cursory chemical dates in monazites sug-
(S3S ) levels. The highest-grade rocks evolved along a high P/T gest that the prograde metamorphism in the southern corridor

Fig. 17. (a) The composite P–T path (bold line with arrowhead) was reconstructed from garnet-bearing staurolite–kyanite gneisses (Fig. 14a) in domain 3. The P–T
boxes are mineral thermobarometric estimates of pre-S2S metamorphic conditions in metapelites from domain 3. The gray lines are metamorphic facies boundaries
after Spear (1993). The P–T boxes in broken lines are for previously inferred P–T estimates. Box A: Ghosh et al. (2006); box B: Sengupta et al. (2005); box C:
Lal et al. (1987). (b) The P–T in (a) (shown in bold line with arrow) is compared with documented P–T paths in subduction zones (after Ernst, 1988), excluding
ultra-high-P rocks (Ernst et al., 1997). The peak temperature of NSMB paragneisses is higher by 200 ◦ C from peak T known for cold slab subduction.
124 S. Mahato et al. / Precambrian Research 162 (2008) 102–127

Fig. 18. A schematic view of the structural-metamorphic setting along a section transverse to the elongation of the NSMB. The reverse-sense shear zones correspond
to S3 in both the northern and southern corridors. The P–T paths correspond to those reconstructed for staurolite–kyanite gneisses in domain 3 of the southern corridor
and garnet–staurolite-bearing muscovite schists at the fringe of the CGC in the northern corridor.

was ≥1.5 Ga. The S3S exhumation at greenschist facies condi- The episodic nature of mafic magmatism in the NSMB sug-
tions, on the other hand, possibly occurred later, ∼1.3 Ga. The gests that the sub-crustal mantle was thermally active during
depositional age of sedimentary precursors to para-gneisses and the early stages of collisional thickening (pre-S2S ) and the ther-
schists in the southern corridor is suggested to be <2.4 Ga. The mal anomaly (assuming that T at the base of a normal 40 km
hinterland-dipping reverse-sense S3S thrust imbrications in the thick crust is <500 ◦ C; Fowler, 1998) outlasted the Pmax stage.
southern and northern corridors led to syn-collisional extrusion The thermal anomaly is supported by (a) the higher (>200 ◦ C)
of the crustal slices from the central parts of the orogen out- Tmax value recorded by the staurolite–kyanite gneisses com-
wards, e.g. syn-contractional expansion of the orogen (Fig. 18). pared to those known for cold slab subduction, and (b) M1S Tmax
The deformation plan for the D3 deformation event – associ- value attained after the Pmax value or even during decompres-
ated with M3S cooling–exhumation in the southern corridor and sion. Clearly, a tectonic model applicable for the NSMB should
prograde heating–loading in the northern sector – was similar, account for the existence of thermally active sub-continental
e.g. the mean trend of S3 and the attitude of axes of the non- mantle prior to and out-lasting collision-related crustal thicken-
cylindrical non-planar flexural slip shear-related F3 folds are ing.
conformal. Since monazites in the northern corridor could not All considered any tectonic model for the NSMB should
be dated, it is unclear if the D3 deformation event in the two account for prograde heating post-dating loading. Convec-
corridors were coeval. tive removal of lithospheric root beneath a collisional orogen
(England and Houseman, 1989) and consequent crustal exten-
4.1. Convective removal of collision thickened lithospheric sion induced by surface elevation controlled crustal extrusion
root: the preferred model (Vissers et al., 1995) is a plausible mechanism for rapid heating
of the lithosphere. Heating during extension may be accompa-
Mafic and utramafic rocks comprise key lithological units nied by emplacement of mantle-derived melts (Gans, 1989). This
within the NSMB. Based on field examination and textu- may explain the observed mafic emplacements post-dating the
ral characterization made in this study (not discussed), the collisional fabrics in the NSMB. The mafic emplacements are
rocks can be classified into three petrographic varieties, e.g. expected to be abundant directly above the zone of maximum
(a) multiply-deformed and metamorphosed hornblende schists, thickening (e.g. the Dalma meta-igneous suite). Yet, another
chlorite schists and talc schists (cf. Dunn, 1929; Dunn and consequence of convective removal of a lithospheric root is that
Dey, 1942), (b) undeformed, unmetamorphosed mafic intru- high temperature is likely to post-date the collisional phase.
sives like gabbro and pyroxenites (cf. Dunn, 1929; Gupta et However, calculations by Houseman and Molnar (1997) indi-
al., 1977, 1980, 1982; Bhattacharya and Sanyal, 1988) that pre- cate that the onset of heating may be initiated several tens of
serve igneous textures, and (c) tuffs and pyroclastic rocks in the millions of years after thickening depending upon the crustal
northern sector (cf. Dunn, 1929). The meta-igneous rocks are thickness, the external forces and the viscosity structure of the
overwhelmingly dominant in the central part of the NSMB (the crust. Recently, Platt et al. (2003) demonstrated for the Albo-
Dalma meta-igneous suite; Dunn, 1929), whereas the pyroclas- ran Basin in the Betic Cordillera that the heating phase initiated
tic and tuffaceous rocks are the least dominant. Although field ∼30 myr after crustal thickening.
documentation of the inter-relationship between the intrusives The time gap between high-P subduction and heating
and fabrics in mafic rocks is lacking, there is little doubt that the due to slab-break-off is of the order of 30–50 Ma. This
intrusive and extrusive mafic rocks were emplaced at different value does not account for the >200 Ma time gap inferred
stages during the evolution of the NSMB. between subduction (>1.5 Ga) and syn-collisional exhumation
S. Mahato et al. / Precambrian Research 162 (2008) 102–127 125

(∼1.3 Ga) documented in this study. Seemingly, therefore, the on Mg-Fe partitioning and a reformulation of the biotite-garnet geother-
1.3 Ga collision–exhumation and the >1.5 Ga subduction events mometer. Contrib. Mineral. Petrol. 111, 87–93.
may not constitute a continuum. In other words, the recon- Bhattacharya, D.S., Payasat, S., Sarkar, A.N., 1976. Zones of metamorphism in
western Singhbhum, Eastern India. Ind. J. Earth Sci. 3, 26–36.
structed P–T path (Fig. 17) may not represent a single cycle Bhattacharya, D.S., Sanyal, P., 1988. The Singhbhum orogeny – its structure
of subduction-related metamorphism, and instead may be a and stratigraphy. Mem. Geol. Soc. India 8, 85–111.
composite of two temporally disparate events, e.g. a subduction- Bhattacharya, D.S., Sarkar, A.N., 1970. Structure of the rocks around Lapsa,
related orogeny older than 1.5 Ga, and a later syn-collisional Singhbhum District, Bihar. Quart. J. Geol. Min. Met. Soc. India XLII,
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Bose, R.N., 1954. The metamorphic rocks around Barabhum and Bunduan,
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Bose, M.K., Chakrabarty, M.K., Saunders, A.D., 1989. Petrochemistry of lavas
S.M. in the Indian Institute of Technology, Kharagpur, 2007. from Proterozoic volcanic belt, Singhbhum, eastern India. Geol. Rundschau
The authors acknowledge the financial support (grant-in-aid) 78, 633–648.
provided by the Department of Science and Technology, New Chakrabarty, K.R., Sen, S.K., 1967. Regional metamorphism of pelitic rocks
Delhi (India). Electron probe microanalyses of mineral were car- around Kandra, Singhbhum. Bihar Contrib. Mineral. Petrol. 16, 210–232.
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Kolkata and Faridabad of the Geological Survey of India, and 829–840.
in the Ruhr Universitat Bochum, Germany. We thank Dr. N.C. Condie, K.C., 1997. Plate tectonics and Crustal Evolution, fourth ed. Butterworth
Pant and Dr. A. Ghosh (GSI, Faridabad) and Mr. B. Chattopad- – Heinemann, Oxford, UK.
hyay, Mr. S. Sanyal and Mr. S. Som (GSI, Kolkata) for helping Copeland, P., Parrish, R.R., Harrison, T.M., 1988. Identification of inherited
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logistic support during fieldwork under difficult circumstances. geochronology. Earth Planet. Sci. Lett. 150, 277–290.
We are especially grateful to Sukhram Bodhra (Tebo), Avinash Dahl, P.C., Hamilton, M.A., Jercinovic, M.J., Terry, M.P., Williams, M.L., Frei,
Purtu (Kolomda) and Hiralal (Charkradharpur) for their assis- R., 2005a. Comparative isotopic and chemical geochronometry of monazite,
with implications for U–Th–Pb dating by electron microprobe: an example
tance during fieldwork. The authors appreciate the constructive from metamorphic rocks of the eastern Wyoming Craton (USA). Am. Min.
comments by P.S. Dahl and an anonymous reviewer that led to 90, 619–638.
substantive modifications in the manuscript. A.B. thanks Prof. Dahl, P.C., Terry, M.P., Jercinovic, M.J., Williams, M.L., Hamilton, M.A.,
S. Dasgupta (Editor) for inviting to contribute in the special Foland, K.A., Clement, S.M., Freiberg, L.M., 2005b. Electron probe (Ultra-
volume. chron) microchronometry of metamorphic monazite: unraveling the timing
of polyphase thermotectonism in the easternmost Wyoming Craton (Black
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