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1610512022, 1337 ALLEN Digital LLEN Digita QUESTION PAPER OF BURN TEST 01 ENTHUSE PHASE-1 & 2 (CHE-BOT) / 15 MAY 2022 ?APER NO : -BURN TE! HEM+BOT Question No. - 1 Void fraction af ARC ABC in three dimensional packing is- (6% (2) 22% (3) 47.6% (4) 26% Answer :4 Question No. - 2 A solid ‘AB’ having Rock salt structure has edge length 320 pm. if radius of cation A+ is 60 pm. then the radius of anion Bo is (1) 144.92 pm. (2) 81.96pm. (3) 100pm. (4) 200pm Answer :3 Question No. - 3 Which of the followingis not the characteristics of crystalline solids? (1). They are isotropic (2). They exhibit plymorphism (8). After meting, they become nen erystaliine (4) They have thermodynamicdeiecs Answer :1 Question No. - 4 htpssstudent allencigitalin.JAIPUR print paper/2022.-20234JAI9980D45/Paarh-Goyalid=diyysSKM%2O]U%3d ea 1610512022, 1337 ALLEN Digital A.compound famed from elements A and B has a cubic structure in which atoms A are present at the comers as well as face centres whereas atom Bare present on the edge centresas well as body centre. The formula of compound will be () AB 2) AB, (@) AB (4) ApBs Answer : 3 Question No. - 5 ‘An ionic compound is expected to have tetrahedral structure if r+) lies in the range of ()) 0.41410 0.732 (2) 0.782t01 8) 0.15510 0.225 (4) 0.225100.414 Answer : 4 Question No. - 6 ‘The minimum distance between anions in rock salt type structure is aw 5 2 B 8 Be @ ce Answer:2 Question No. - 7 ‘Which f the follouing are the comect axial distances and axial angles for Yhembahedal system ? (Q) a=b=ce= B= 7490 Q) a=bseqa Q) aeb=c2=p=y=9 (4) axbecaspry290° Answer :1 Question No. - 8 htpssstudent allencigitalin.JAIPUR print paper/2022.-20234JAI9980D45/Paarh-Goyalid=diyysSKM%2O]U%3d 209 1610512022, 1337 ALLEN Digital The ratio of co-ordination No. of cation : anion in calcium fluoride (CaF) type structure is: (yy 1:2 Q 4:4 @) 4:8 (@) 8:4 Answer : 4 Question No. - 9 Inwhich of the following defect holes are not responsible for electrical conduction? (1) Schottiy detect (2) Metal excess defect through anion migration (8) Frenkel defect (4) Allof these ‘Answer : 2 Question No. - 10 ‘Number of alternate facesin cube will be~ a 3 2) 8) (4) oo Answer :3 Question No. - 11 ‘The evailable space occupied by spheres of equal size in three dimensional packing in both hep and cep arrangement is- () 14% (2) 70% (3) 604% (4) 52.4% Answer :1 Question No. - 12 ‘Analysis shows that Nihas the formula Nig 930. the pereentage by mole of Ni presentas Ni*2 and Ni*? respectively will be- (1) 96.% 4%, 2) 97%, 3% 8) 98%,2% (4) 99%, 1% htpssstudent allencigitalin.JAIPUR print paper/2022.-20234JAI9980D45/Paarh-Goyalid=diyysSKM%2O]U%3d 1610512022, 1337 ALLEN Digital Answer :1 Question No. - 13 Which of the following type of cubic lattice has maximum number of atomsper unit call? (1). Simple cubic (2) Body centred cubic (8). face centred cubic (4) Allhave same ‘Answer :3 Question No. - 14 ‘Which is correct relation for BCC ? ay (2) @) = nis (4) Allof these Answer :1 Question No. - 15 Consider following statements 3) Coordination number of each sphere in CCP and in HCP is (i) Coordination number of each sphere in SCCis 6. (ii) Han element cwstalisesin BCC & FOC unit cell then edge lenath of both unit cellis same. (i) In NaCl, 8 Cl and 6 Na* Ions ate present per unit cell Correct statements isvare~ (1) fi) & (i) (2), (i) & fii @) Gi) & fi) (4) i) & (wv) Answer :1 Question No, - 16 htpssstudent allencigitalin.JAIPUR print paper/2022.-20234JAI9980D45/Paarh-Goyalid=diyysSKM%2O]U%3d 423 1610512022, 1337 ALLEN Digital ‘The number of atoms present in a unit cell of a mono atomic substance of a simple cubic lattice. body centred cubic and face centred cubic respectively are— (Q 8.9814 2) 1284 @) 4,586 @) 2,385 ‘Answer : 2 Question No. - 17 ZrO is white when cold and yellow when heated, (1) Frenkel defect (2) Schottiy detect (8) metal excess defect (4) Metal deficiency defect is due ta the development of Answer :3 Question No. - 18 How many types of unit colls are possible in orthorhombic crystal a 2 3 4 (4) only Answer :3 Question No. - 19 Alattice consist of elements A, Band C which occupy comers, face centres and edge centres respectively. What would be formula of lattice if particles along a diagonal plane of symmetry are removed? (1) ABC, (2) ABC, (3) ABC. (4) BC, Answer : 3 Question No. - 20 htpssstudent allencigitalin.JAIPUR print paper/2022.-20234JAI9980D45/Paarh-Goyalid=diyysSKM%2O]U%3d 1610512022, 1337 ALLEN Digital If elements X, Y and Z crystallizes in SC, BCC and FCC unit calls with same edge length then, correct order of radii of X, Y and Zspheresin, ( X=v=z @ X>v>z @) Kz ‘Answer : 2 Question No. - 21 Solid CO, is an example of - (1) onic erystal (2) Covalent erystal 8) Metalic crystal (4) Molecular crystal Answer : 4 Question No. - 22 Total number of Brvais lattice in 3D. a7 @ 5 @ 4 (4) 12 Answer :3 Question No. - 23 ‘Which kind of exystel aystems ate most aymmetrical end unsymmebical respectively ? (1) Cubicand Tretnie (2) Orthothombic and Tetragonal (3) Monodtinic and cubic (4) Hexagonal end Trigonal Answer :1 Question No. - 24 htpssstudent allencigitalin.JAIPUR print paper/2022.-20234JAI9980D45/Paarh-Goyalid=diyysSKM%2O]U%3d 1610512022, 1337 ALLEN Digital ‘Which is possible distance between tetrahedral voidin f.c.c. unit cell ? 8 (4) Allare comect Answer : 4 Question No. - 25 If Ag(Atomic mass = 108) is erystalised in b.c.c. type unit cell with edge length 100 A® then its density will be Q) 19% 104 gee. Q) 36x 10490. @) 1.996. (4) 3.69% ‘Answer : 2 Question No. - 26 Which of the following is nota molecular solid’? (1) Solid CO, (2) Solid Helium 8) SiO, (4) Polyurethane Answer :3 Question No. - 27 ‘Arrange following inincreasing order of their packingefficiency— (I) Simple cubic (ll) Body centred cubic (1) Face centred cubie (IV) Hexagonal closepacked (Ql)

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