PRE-MEDICAL 2023

ALLEN CLASS
CAREER INSTITUTE ENTHUSIAST COURSE
KOTA (RAJASTHAN) PRACTICE TEST
CHEMISTRY DATE 17-11-2022
ELECTROCHEMISTRY, SOLUTION & CHEMICAL KINETICS

1. A metal rod is dipped in a solution of its ions. Its electrode potential is independent of
(1) temperature of the solution (2) concentration of the solution
(3) area of the metal exposed (4) nature of the metal

2. The position ofsome metals in the electrochemical series in decreasing Mg > Al> Zn > Cu > Ag. What will
happen if a copper spoon is used to stir a solution of aluminium nitrate?
(1) The spoon will get coated with aluminium. (2) An alloy of copper and aluminium is formed.
(3) The solution becomes blue. (4) No chemical change will take place.

3. A standard hydrogen electrode has zero electrode potential because

(1) hydrogen is easiest to oxidize (2) this electrode potential is assumed to be zero
(3) hydrogen atom has only one electron (4) hydrogen is the lightest element

4. A gas X at 1 atrn is bubbled through a solution containing a mixture of 1 M-Y and 1 M -Z" at 25°C. If
the reduction potential of Z > Y > X, then,
(1) Y will oxidize X and not Z (2) Y will oxidize Z and not X
(3) Y will oxidize both X and Z (4) Y will reduce both X and Z

5. In salt bridge, normally KCl is used because

(1) it is a strong electrolyte. (2) it is good conductor or electricity.
(3) K and C ions have nearly same ionic mobility. (4) it is an ionic compound

6. The solution of CuSO,4. in which copper rod is immersed. is diluted to 10 times. The reduction electrode
potential
(1) increases by 0.0295 V (2) decreases by 0.0295V
(3) increases by 0.095V (4) decreases by 0.095 V

7. Electrode potential will be more for hydrogen electrode at pH (at the same temperature)
(1) 4 (2) 3 (3) 2 4) 5

8. The standard reduction potentials ofPt | Cr,0,, Cr*3,Pt| MnO, , Mn, Pt|Ce*, Ce* in the presence of
acid are 1.33 V, 1.51 V and 1.61 V, respectively, at 25°C. The decreasing order of oxidizing power is
Cet4 (2) MnO > Cr,0,> Ce+4
(1)Cr,0,> MnO,>
(3) Ce*> MnO, > Cr0, (4)MnO4 > Ce**> Cr,O,2

9. Some standard electrode potential are given:

Fe2 +2e >Fe; E°= -0.440V

Fes+3e >Fe; E°= -0.036V

The standard electrode potential for: Fe* +e Fe4", is

(1)-0.476V (2)-0.404V (3) +0.988V (4) +0.772 V

CHEMISTRY
 at 298 K. Ihe electrode potential for the half oi
10. The dissociation constant for
is 1.8 x 10
CH,COOH
0.48; 2.303 RT/F 0 06 -cell
K is (log 2 0.3; log 3
=
= =

0.5 M- CH,COOH, at 298

Pt H, (1 bar)| 3) +0.3024V (4) +0.1512 V
(2)-0.1512V
(1)-0.3024V

and ECiCuCICu is 0.128 V. The value of E

11. At 25°C, the solubility product of CuCI is 2.0 x10 Cu'Cu is

(log 2 0.3; 2.303 RT/F =

0.06)
(3) +0.53V (4) +0.402 V
(1)-0.2744V (2)-0.402V
12.
The standard reduction potential of oxygen in acidic solution is 1.23 V (O, +4H,0+ 4e>6H,0). The
standard reduction potential of oxygen in basic solution is (2.303 RT/F 0.06)
=

(2)-0.39 VV (3) +0.39V (4) +2.07v

(1)-1.23 V

13. The corect diagram for the following reaction and E° for tha cell is

2AgBr(s)+ H2lg) 2Agls)+ 2H* +2Er; E = +0.10V

AgBrlAglBr
(1) (P)H |H" || Br|AgBr | Br(Pt); E°= 0.10V 2) (Pt)H2 |H*|| Br | AgBr | Br2(Pt); E°--0.10V
3) Pt)BrzAgBr | Br" ii H* |H2(Pt); E°=0.10V4) (Pt)Br2 |AgBr| Br || H* |H2(Pt); E°=-0.10V

14. In an experimental set-up for the measurement of EMF of a half-cell using a reference electrode and a salt
bridge, when the salt bridge is removed, the voltage
(1) remains the same (2) increases to maximum
(3) decreases half the value (4) drops to zero

15. After some time, the voltage of an electrochemical cell becomes zero. This is because
(1) their electrode potential becomes zero.
(2) their reduction potential become equal but have opposite sign.
(3) their reductioni potential become equal and have the same sign.
(4) the ions of the lectrolyte in the salt bridge stop moving.

16. Mole fraction of CH(OH), in a solution of 36 g of water and 46

gof glycerine is-
(1) 0.46 (2) 0.36 (3) 0.20 (4) 0.40
17. If 'A contains 2% NaCl and is separated by a
semipermeable membrane from B which contains 10% NaCl,
which event will ocur?
(1) NaCI ill flow from A to 'B
(2) NaCl will flow from B to 'A
(3) Water will flow from A to 'B'
4) Water will flow from 'B to 'A
18. A solution of a non electrolite substance containing 1.05
g per 100 mL. was found to be isotonic with 3%
glucose solution. The molecular mass of the substance is:
(1) 31.5 (2) 6.3 (3) 630 (4) 63

19. Osmotic pressure of 30% solution of glucoses is 1.20 atm

and that of 3.42% solution of cane sugar is 2.5 atm.
The osmotic pressure of the mixture
containing equal volumes of the two solutions will be
(1) 2.5 atm (2) 3.7 atm (3) 1.85 atm (4) 1.3 atm

20. A solution of glucose (CH,0,) is isotonic with 4gof urea (NH,-CO-NH,) per liter of solution. The concentration
of glucose is
(1) 4 g/l (2) 8g/ (3) 12 g/l (4) 14 g/l

CHEMISTRY
-2-
21. In which case van't Hofffactor are equal?
(a) KCI, 50% ionised (b) KSO,,40% ionised (c) FeCl, 30%ionised (d) SnCl, 20% ionised

Code:
(1) (a), (b) (2) (b), (d) (3) (a), (c), (d) (4) (a). (b), c)

22. The osmotic pressure of equimolar solutions of BaCl, NaCl and glucose will be in the order
(1) Glucose > NaCl » BaClh (2) BaCl, NaCl >Glucose
(3) NaCl > BaCl,> Glucose (4) NaCl Glucose> BaClh

23. The van't Hoff factor i for an infinity dilute solution of NaHSO, is:
(1) 1/2 (2) 1/3 (3) 3 (4) 2

24. fP arnd Pare the vapourpressure of a solvent and its solution respectively and N, and N, are the mole fractions
of the solvent and non-volatile solute respectively, then corect relation is:

(1) P PN2 (2) P = PN (3) Po = PN, (4) P PoN,N)

25. The vapour pressure of pure liquid solvent A is 0,80 atm. When a non-volatile substance Bis added to the
solvent, its vapour pressure drops to 0.60 atm. Mole fraction of the component B in the solution is:
(1) 0.50 (2) 0.25 (3) 0.75 (4) 0.40

Moles of K,So, to be dissolved in 12 mol water to lower its vapour pressure by 10 mmHg at a temperature at
26.
which vapour pressure of pure water is 50 mm is:
(1) 3 mol (2) 2 mol (3) 1 mol (4) 0.5 mol

27. The vapour pressure of a dilute aqueous solution of glucose is 750 mm of mercury at 373 K. The mole fraction
of solute is-

1 1
(1 10 2) 76 35 (4)
28. 1 mol each of following solutes are taken in 5 mol water,
A. NaCl, B. KSO4: C. Na,PO, D. Glucose
will be in order:
Assuming 100% ionisation of the electrolyte, relative decrease in vapour pressure
B <C <D (2)D <C <B <A (3)D < A < B <C (4) Equal
(1)A <

Aluminium phosphate is 100% ionised in 0.01 molal aqueous solution. Hence, AT,/K is:
29.
(2) 0.015 (3) 0.0175 (4) 0.02
(1) 0.01

30. 1.0 molal aqueous solution of an electrolyte X,Y, is 25% ionized. The boiling point of the solution is (K, for H,O

= 0.52 K kg/mol)
(2) 374.04 K (3) 377.12K (4) 373.25K
(1) 375.5 KK
correct
31. Which of the following statement is more

chemical reaction
(1) Catalyst only accelerates the rate of a
can retard the rate
of a chemical reaction
(2) A catalyst
of a reaction
(3) A catalyst can control the speed
A catalyst alters the speed of a
reaction
(4)
be slowed down by the addition of a small amount of acetanilide.
The decomposition of hydrogen peroxide
can
32.
The latter act as -
(2) Promoter
(3) Moderator (4) Poison
(1) Inhibitor
its
Efficiency ofthe catalyst depends
on
33.
(2) Number of free valencies
(1) Molecularweight (4) Amount used
(3) Physical state

CHEMISTRY
34. In the reaction KMnO +H,SO, + HC,O,> products
Mn** ions act as
(1) Positive catalyst (2) Negative catalyst (3) Auto catalyst (4) Enzyme catalyst
35. Platinized asbestos is used as a catalyst in the manufacture of H,SO, It is an example of
(1) Homogeneous catalyst (2) Heterogeneous catalyst
(3) Auto-catalyst (4) Induced catalyst
36.
In(1)the
Fe
ostwald's process for the manufacturing of HINO, the catalyst used is -

(2) Pt (3) V,O (4) Mo

37. In reversible reaction a catalyst-
a

(1) Increase the rate of forward reaction only

(2) Increases the rate of forward reaction to a greater extent than that of the backward reaction
(3) Increases the rate of forward reaction and decreases that of the backward reaction
(4) Increases the rate of forward and backward reaction equally
38. In the manufacture of H,SO, by contact process the presence of As,O, acts as -
(1) Catalytic promoter (2) Catalytic poison (3) Induced catalyst (4) Auto catalysis
39. Which statement is wrong-
(1) Haber's process of NH, requires iron as catalyst (2) Friedel-craft's reaction requires anhydrous AlCl,
(3) Hydrogenation of oils requires iron as catalyst (4) Oxidation of SO, to SO, requires V,O
40. Which is false for catalyst-
(1) A catalyst can initiate a reaction
(2) It does not alter the position of equilibrium in a reversible reaction
(3) A catalyst remains unchanged in quality and composition at the end of reaction
(4) Catalysts are sometimes very specific in respect of a reaction
41. Which acts as a promoter for nickel in the hydrogenation of oils -
(1) Cu (2) Mo (3) Fe (4) Pt
42. Enzymes are known to increase the rate of reaction by -
(1) 10 time (2) 102 times (3) 105 times (4) 1012 times
43. Zeolites are used as catalyst in -

(1) Petrochemicai industries during crackingg (2) In the preparation of H,SO,

(3) In the hydrolysis of ester (4) All

44. Which is not the corect statement for a catalyst:

(1) It does not alter Ea
(2) It provides an altemate mechanism with a lower energy of activation
(3) Catalyst may form intermediates with the reactants
(4) Action of enzyme catalyst is always specific

45 Shape selective catalysts are so called because of-

(1) The shape of the catalysts
(2) The specificity of the catalysts
(3) The size of the pores of the catalysts which can trap only selective molecules
(4) Their use for only some selected reactions