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a r t i c l e i n f o a b s t r a c t
Article history: This study is to evaluate the potential for development of a cellulosic ethanol facility in Vietnam. Rice
Received 10 October 2013 straw is abundant in Vietnam and highly concentrated in the Mekong Delta, where about 26 Mt year1 of
Accepted 20 August 2014 rice straw has been yearly produced. To minimize the overall production cost (PC) of ethanol from rice
Available online 13 September 2014
straw, it is crucial to choose the optimal facility size. The delivered cost of rice straw varied from 20.5 to
65.4 $ dry t1 depending on transportation distance. The Mekong Delta has much lower rice straw prices
Keywords:
compared with other regions in Vietnam because of high density and quantity of rice straw supply. Thus,
Ethanol
this region has been considered as the most suitable location for deploying ethanol production in
Optimal facility size
Production cost
Vietnam. The optimal plant size of ethanol production in the region was estimated up to 200 ML year1.
Rice straw The improvement in solid concentration of material in the hydrothermal pre-treatment step and using
residues for power generation could substantially reduce the PC in Vietnam, where energy costs account
for the second largest contribution to the PC, following only enzyme costs. The potential for building
larger ethanol plants with low rice straw costs can reduce ethanol production costs in Vietnam. The
current estimated production cost for an optimal plant size of 200 ML year1 was 1.19 $ L1. For the
future scenario, considering improvements in pre-treatment, enzyme hydrolysis steps, specific enzyme
activity, and applying residues for energy generation, the ethanol production cost could reduce to
0.45 $ L1 for a plant size of 200 ML year1 in Vietnam. These data indicated that the cost-
competitiveness of ethanol production could be realized in Vietnam with future improvements in pro-
duction technologies.
© 2014 Elsevier Ltd. All rights reserved.
http://dx.doi.org/10.1016/j.renene.2014.08.051
0960-1481/© 2014 Elsevier Ltd. All rights reserved.
N.Q. Diep et al. / Renewable Energy 74 (2015) 456e463 457
small to medium scales. Many other types of biomass have not been farmers selling the material; and ‘Fa’ is the accessibility and/or
used. We have seen bioethanol from agricultural residues as an weather inhibiting factors. In Vietnam, there are two or three rice
appropriate renewable energy for Vietnam to be developed. As Viet- harvest seasons per year, depending on the region. In this study, we
nam has strongly depended on imported gasoline, and this situation is assumed that the values of Fc, Fp and Fa were 0.7, 0.8, and 0.3,
not changed as long as oil refinery industry in Vietnam is incapable. respectively, for all of the regions.
Ethanol is a good additive to gasoline, partially reduces gasoline
import and is widely used in transport sector. According to the sta- 2.2. Estimation of the delivered rice straw cost in Vietnam
tistical data of 2010 [3], Vietnamese transport sector accounted for
was 22% total energy consumption and produced 16.4% of the country The delivered cost of rice straw was broken down into farmer
CO2 emission. Bioethanol production from agricultural residues can payments, baling costs, handling costs (e.g., staking on the field
significantly reduce gasoline import, CO2 emission, increase income edge and loading and unloading the trucks), and transportation
for farmers, create jobs, and especially provide an environmentally costs. Approximately 80e90% of the amount of rice straw generated
friendly way to deposit biomass in rural areas. was disposed of by open-field burning, but, in some periods of the
Vietnam is an agriculture-based economy, and rice is the major year, rice straw has a market value (in the field) of around 7 USD ($)
product. The Mekong Delta region is called 'a rice bowl' and dry t1 for cattle feed and mushroom cultivation [9]. This price was
recognized as the most intensively agriculture-activity region of applied as the cost of farmer payments.
Vietnam, with huge amount of agricultural products and labour In Vietnam, rice straw is transported in a loose condition. To use
force (more than 80% of its population engaging in farming). The rice straw as a feedstock for bioenergy industries, it must be baled
intensive agricultural activities in this region demand high energy to reduce the transportation costs. We applied the baling and
consumption and create environmental problems related to agri- handling cost data from Thailand, where the fuel and labour costs
cultural wastes [4]. are similar to those in Vietnam. The rice straw is baled to achieve a
In 2009, Vietnam has cooperated with University of Tokyo to size of 1.2 0.4 0.5 m (m) e 40 kg for a wet, basic, moisture
develop the JST (Japan Science Technology)/JICA (Japan Interna- content of 11%. The baling cost and handling costs were $9 t1 and
tional Cooperation Agency) joint project titled “Sustainable Inte- $4.5 t1, respectively [10]. The transportation costs depend on such
gration of Local Agriculture and Biomass Industries” in 5 years variables as the transportation distance, feedstock moisture, bale
which designate outputs as developing the key technologies for density, and road quality. The technical standard for design of rural
bio-refinery processes including production technologies of bio- roads on connecting rural district-commune-village-hamlet-fields
ethanol from lignocellulosic biomass. Within the project, a pilot in Vietnam was referred [11], such as road width, weight and
plant supported by JICA for producing ethanol from rice straw was speed limit of vehicles for transportation, etc. as well as the opin-
built in the South of Vietnam for promoting research and devel- ions from experts in transportation sector to assume the type of
oping technologies for cellulosic ethanol production using the truck that can be applicable for delivering rice straw from fields to
abundant biomass supplies from the Mekong Delta area [5]. the facility's gate. As such, we assumed that each truck has a vol-
Nevertheless, to promote cellulosic ethanol production in Vietnam, ume capacity of 78 m3 and a loading weight of 6 tons, for the
additional concerns other than conversion technologies should be transport of feedstock to an ethanol facility at a cost of $2 km-1 [12].
addressed. As mentioned above, the rice straw bale density was 40 kg bale1
To promote the implementation of bioethanol production from (0.24 m3), for a wet, basic, moisture content of 11%. Thus, this type
rice straw in the Delta, this research aims to assess the potential of of truck can carry 150 bales with the weight of 6 tons, volume of
ethanol production from rice straw in this region on the basis of 36 m3. Therefore, the hauling cost per-unit weightedistance (Hc)
quantity, distribution and farm-plant's gate costs of rice straw, was given by the following equation:
optimum facility's capacity for minimizing the production cost
.h i
(PC), and PCs at different scenarios via techno-economic analysis. Hc ¼ 2 $ km1 6 ton 1 0:11 ¼ $0:375 dry t 1 km1
where ‘Y’ is the ethanol yield (L dry t1). In this study, we applied an Japan were applied for setting the process conditions of the base
ethanol yield of 250 L dry t1. case to estimate current ethanol production cost [20,21]. The pro-
cess conditions for the future case were set based on ethanol pro-
2.3. Calculation of optimal plant size duction cost reduction targets [22,23]. The detailed conditions of
the process are shown in Table 1. The process flow, mass balance
In the bioenergy industry, selection of the optimal facility size and energy consumption were used to calculate operating costs.
must consider the effect of a number of tradeoffs. The savings
resulting from the “economics of scale” are offset by the increased 2.4.2. Cost analysis
cost of transportation of the feedstock [15,16]. The determination of Net ethanol production costs were estimated that included in-
optimum facility size is independent of the other logistics of vestment costs (depreciation or fixed cost), rice straw costs, fixed
feedstock cost, such as payments to farmers and the baling, operating costs (labour and maintenance costs), and variable
handling, and storage costs of the straw (distance fixed cost, DFC) operating costs (other materials and energy costs).
[17]. For this study, our approach was that an optimal facility size The assumptions made for the economic evaluation are:
exists when the total of the capital investment (fixed cost) and the
transportation cost of the feedstock per unit ethanol production is - Total capital investment (equipment costs þ installation
minimal. An equation for calculation the optimal plan size pro- costs þ site development þ home office þ construction
duced in our previous study was applied [18]: fee þ other costs) was estimated based on the equation shown
nh i. o½1=ð32aÞ in a previous study [18]: Y ¼ 20.695X0.49 where “Y” is the total
Ropt ¼ 3$ 1 a $a$ðp$DÞða1Þ $Y a Hc$t$T capital investment (millions of US $); “X” is plant size (in meg-
alitres (ML) of ethanol/year). When residues are used for energy
here; 3 2a 1 generation, this capital cost will be increased by 34.2% to ac-
(5) count for added equipment costs [24].
- Rice straw cost (including transportation cost): 40 US $/dry ton
where ‘a’ is scale factor; ‘a’ is coefficient, has the value of 20.695; ‘T’ for plant sizes of 200 ML/year, in the Delta area.
is payback period (year). - Maintenance cost per year: 3% of total capital investment (TCI).
- Plant life: 20 years, with a straight-line depreciation cost per
2.4. Production process design and specific conditions for techno- year ¼ TCI/20.
economic analysis - Rice straw cost (including transportation cost): 40 US $/dry ton
for plant sizes of 200 ML/year, in the Delta area.
A process model of ethanol production from rice straw was - Variable operating costs (Table 2): chemicals, enzyme, yeast
designed as shown in Fig. 1, by considering the economic efficiency costs were from global market meanwhile heavy oil, electricity,
and environmental sustainability of lignocellulosic ethanol pro- and running water costs were market prices in Vietnam. All
duction technologies that have been researched and developed in costs were updated to years 2011e2012, with an exchange rate
Japan. of 1 US $ ¼ 21,000 VND.
- Raw material: rice straw with a moisture content of 15 wt%. 3.1. Annual rice straw generation in Vietnam
Composition of rice straw (on a dry basis) was: glucan 34.4 wt%,
xylan 13.6 wt%, lignin 24.1 wt%, and ash 17.7 wt%. The theoretical Vietnam was divided into six administrative regions, designated
yields of glucose (Glu) and xylose (Xyl) were 382.2 and regions 1, 2, 3, 4, 5, and 6, respectively. The total rice straw gener-
154.5 mg/g of dry rice straw, respectively [19]. ated in Vietnam was estimated to be approximately
- Plant size: 200 ML/year. The plants were operated for 24 h/day 50 dry million tons (Mt) (see Table 3). This amount is much more
and 300 days/year. than that in other countries, such as Thailand (32.9 Mt) or Myanmar
(34.4 Mt) [30]. Region 6, the Mekong River Delta, accounts for 52%
Process conditions: data from experiments at laboratories and of the total rice straw generation and is followed by the Red River
bench plants at the Biomass Technology Research Center, AIST, Delta (region 1), accounting for 17% of the total. The rice straw
Table 1
Process conditions.
Hydrothermal pre-treatment 180 C, 3 MPa, initial solid concentration 10 wt%; heat Initial solid concentration 20%
recovery as heat rejection temperature is 50 C
Enzymatic hydrolysis Cellular enzyme 28 mg/g-dry rice straw, equal to 2 efold increasing in specific enzyme
10 FPU/g-dry straw. Reaction time of 72 h, at 45 C activity, (10 FPU/g-dry rice straw).
% fraction converted to product after hydrolysis: Glucose yield: 95%
Glucan to glucose: 86% (glucose yield) Xylose yield: 75%
Xylan to xylose: 66% (xylose yield)
Co-fermentation Seed solution (KH2PO4, (NH4)2SO4, MgSO4.7H2O, and e
C5 and C6 sugars recombinant yeast at 0.10, 0.10, 0.05, and 4.00 wt%, respectively)
accounts for 10% of total fermentation solution. Fermentation at 30 C, 24 h.
Fermentation rate: Glucose to ethanol: 90%
Xylose to ethanol: 90%
Distillation Ethanol distillation yield 99% e
Product: ethanol 92.5 wt%
Residues for energy generation Not included The residues: solid cake and syrup with a
moisture content of 40 wt% and 60 wt%,
respectively. The total energy gain from
residues includes: power 10% (efficiency 95%),
and heat 90% (efficiency 80%)
amount is high in the two deltas because of the higher rice-planted growing area in Vietnam, with an average yield of more than 5 tons
area and rice yield compared to the other regions. ha1. This region is divided into 12 provinces and one municipality
This result showed an abundant rice straw supply and density (Can Tho) or 13 sub-regions (Fig. 2).
for ethanol production in the Mekong Delta of Vietnam. A high The amount of rice straw is different in each sub-region. An
density of feedstock could reduce the total cost of the feedstock, via Giang, Kien Giang, Dong Thap, and Long An have more rice straw
a reduced transportation cost. than do the other sub-regions, and they account for 16%, 15%, 13%,
In the Mekong delta, most of rice straw generated has been and 10% of the total rice straw in the Delta, respectively. The
ploughed in or burned directly on the fields, just small amount has quantity of available rice straw in An Giang alone is 2.1 Mt year1,
been used for cattle feeding or mushroom cultivation, and com- which corresponds to almost the same as the total rice straw
posting. It was stated that 87% of generated rice straw is burned on generated in Malaysia (2.2 Mt year1) [30]. To consider the high
the fields and cause air pollution during harvest season [4]. This potential of rice straw as a feedstock supply for ethanol production,
huge amount of unused residue could be available for energy assessment of the rice straw density by location (sub-region) and
production. season is essential for the proper planning of activities that precede
actual utilization. Such activities include locating ethanol plant
building sites, as well as collection, transport, and storage.
3.2. Density of rice straw and its distribution in Mekong Delta, The distribution of rice straw is represented by the sub-regional
Vietnam rice straw densities (mass/area/year, Fig. 3). Rice straw generation is
in high density in Can Tho, An Giang, Dong Thap, Hau Giang, Vinh
The Mekong Delta is located in the southern tip of the country, Long, and Tien Giang, ranging from approx. 6.6 to
where the Mekong River approaches and empties into the sea 11.8 tons ha1 year1. Because these sub-regions have high per-
through a network of distributaries. Thus, the Delta is endowed centages of land use and good soil for rice cultivation, rice yields are
with important natural resources: fertile soil and water. Rice pro- more than 6 tons ha1 [33]. However, the contribution of rice straw
duced in this region accounts for nearly 60% of the total Vietnamese amounts from each sub-region varies because of the disparity in
rice output and is more than that produced in other countries such their total areas. Can Tho is the municipality in the Delta, with the
as the Philippines (15.97 Mt) or Japan (10 Mt) [31,32]. The Delta highest density of rice straw (11.8 tons ha1 year1), but it has a
possesses a favourable equatorial climate for agricultural produc- lower amount of rice straw than other sub-regions. An Giang could
tion, especially for rice cultivation. About 1.7 million ha of the re-
gion is under rice cultivation, and most of this area uses the triple
rice crop system.
Therefore, the total rice-planted area in the Mekong Delta is Table 3
3.872 million ha, which corresponds to more than 50% of the rice- Rice straw generation and regional distribution in Vietnam.
be considered as the best site in terms of the total amount as well as There are three rice seasons in the Mekong Delta: winter,
the high density of rice straw for ethanol production. autumn, and spring. The seasonal distribution of rice straw is shown
In summary, large rice-planted areas with high potential for rice via rice production by season (Fig. 4). The winter, autumn, and spring
straw collection are located along the upper and mid-banks of the rice seasons represent about 7%, 45%, and 48%, respectively, of the
two main rivers, the Tien River and the Hau River (see the dash- total annual rice output in the Delta [33]. Winter rice season starts in
circle areas in Fig. 2). These areas belong to sub-regions: An the rainy season, in July or August, and ends at the close of the rainy
Giang, Can Tho, Hau Giang, Kien Giang, Dong Thap, Vinh Long, Long season in November or December. Local rice varieties with low yields
An, and Tien Giang. These sub-regions have fertile soil and water (4 tons ha1) that are adapted to deep water are grown in this sea-
from the rivers and are less affected by seawater intrusion due to son. The spring rice season starts at the end of rainy season
high tides, floods, and inundation. The annual flooding season in (NoveDec) and yields the first harvest in February or March. The
the Mekong Delta lasts for five months, between July and autumn rice season starts in May or June and is harvested in mid-
November, primarily in the lower parts of the Delta. August or September. Rice straw generated in the winter season
accounts for just 7% of the total supply and is less efficiently collected
Fig. 3. Density of generated rice straw by sub-region. Fig. 4. Rice production by season in the Mekong Delta.
N.Q. Diep et al. / Renewable Energy 74 (2015) 456e463 461
the result of high density, low labour costs for collection, handling
of biomass.
Table 4
Optimal plant size for different regions in Vietnam.
Region Optimal plant size Ropt (km) Number of optimal Delivered cost of rice straw Total of fixed cost þ delivered Yearly ethanol
(ML year1) plant by region rice straw cost ($L1 EtOH) production (ML year1)
($ dry t1) ($L1 EtOH)
Red River Delta (1) 112.5 45.5 1 37.6 0.150 0.244 112.5
Northern Midlands and 52.5 98.8 2 57.5 0.230 0.368 105
Mountain Areas (2)
North Central and Central 7.5 26.2 6 30.3 0.121 0.492 45
Costal Areas (3)
Central Highlands (4) 15 70 2 46.7 0.187 0.448 30
South East (5) 45 69.1 1 46.4 0.186 0.335 45
Mekong River Delta (6) 195 48 2 38.7 0.154 0.224 390
Whole country 727.5
462 N.Q. Diep et al. / Renewable Energy 74 (2015) 456e463
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