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ABSTRACT. Bulk density is a major physical property in designing the logistic system for biomass handling. The size, shape,
moisture content, individual particle density, and surface characteristics are few factors affecting the bulk density. This
research investigates the effects of true particle lengths ranging from 6 to 50 mm and moisture contents ranging from 8% to
60% wet basis (wb) on the bulk density of wheat straw and switchgrass. Three types of particle densities of straw and
switchgrass measured were: a hollow particle density assuming a hollow cylindrical geometry, a solid particle density
assuming a solid cylindrical geometry, and a particle density measured using a gas pycnometer at a gas pressure of 40 kPa.
The bulk density of both loose‐fill and packed‐fill biomass samples was examined. The calculated wet and dry bulk density
ranged from 24 to 111 kg m ‐3 for straw and from 49 to 266 kg m ‐3 for switchgrass. The corresponding tapped bulk density
ranged from 34 to 130 kg m ‐3 for straw and 68 to 323 kg m ‐3 for switchgrass. The increase in bulk density due to tapping the
container was from 10% for short 6‐mm particles to more than 50% for long 50‐mm particles. An equation relating the bulk
density of stems as a function of moisture content, dry bulk density, and particle size was developed. After the validation of
this bulk density equation, the relationship would be highly useful in designing the logistics system for large‐scale transport
of biomass to a biorefinery. The bulk density and particle density data of uniform particles would be important, if straw and
switchgrass is used for pulping and paper making.
Keywords. Bulk density, Particle density, Straw, Switchgrass, Packing, Porosity, Fibrous biomass.
B
ulk density is an important characteristic of depends on bulk density and flow characteristics of feedstock
biomass that influences directly the cost of (Woodcock and Mason, 1987). A recent study by Ryu et al.
feedstock delivered to a biorefinery and storage (2006) investigated the effect of bulk density on the
cost (Sokhansanj and Fenton, 2006). It also combustion characteristics of biomass. They found that the
impacts storage requirements, the sizing of the material ignition front speed was inversely proportional to bulk
handling system and how the material behaves during density, while the burning rate tends to decrease linearly. As
subsequent thermo‐chemical and biological processes. a physical property, bulk density (rb ) depends on material
(McKendry, 2002). The engineering design and operation of composition (c), particle shape (f) and size (l, d), orientation
transport equipment, storages, and conversion processes of particles (s), specific density of individual particles (rp ),
particle size distribution (PSD), moisture content (mc), and
applied axial pressure (p) (Peleg, 1983; Lang et al., 1993;
Submitted for review in November 2007 as manuscript number FPE Sokhansanj and Lang, 1996).
7262; approved for publication by Food & Process Engineering Institute ò = f ( c , ò , l , d , f , s , PSD , mc , p ) (1)
Division of ASABE in April 2008. Presented at the 2007 ASABE Annual b p
Meeting as Paper No. 076058.
The authors are Pak Sui Lam, ASABE Member, Graduate Research where l and d are length and diameter of particles. The
Associate, Department of Chemical and Biological Engineering, variables in the right side of equation 1 are not all
University of British Columbia, Vancouver, British Columbia, Canada; independent of each other. For example, moisture content has
Shahab Sokhansanj, ASABE Member, Adjunct professor, Department of
Chemical and Biological Engineering, University of British Columbia, an effect on particle density and surface characteristics.
Vancouver, British Columbia, Canada and Distinguished Research Similarly, particle size and distribution depends on upstream
Scientist Oak Ridge National Laboratory, Environmental Sciences processes such as chopping, drying, grinding, sieving, etc.
Division, Oak Ridge, Tennessee; Xiaotao Bi, Professor, C. Jim Lim, Length (l) and diameter (d) define a shape factor (f) for the
Professor, Ladan J. Naimi, ASABE Member, Graduate Research
Associate, Mozammel Hoque, ASABE Member, Posdoctoral Associate
particle. Other factors such as surface characteristics also
Department of Chemical and Biological Engineering, University of British affect the bulk density and flow characteristics of biomass.
Columbia, Vancouver, British Columbia, Canada,; Sudhagar Mani, The agricultural biomass particles are usually cylindrical
Assistant Professor, Faculty of Engineering, Driftmier Engineering Center, or disk shape depending upon the part of the plant they
University of Georgia, Athens Georgia; Alvin Ray Womac, ASABE originate. The long particles with aspect ratio (l/d) of greater
Member, Professor, X. Philip Ye, Assistant Professor, Department of
Biosystems Engineering and Soil Science, The University of Tennessee, than one are classified as cylindrical while the short particles
Knoxville, Tennessee; Sundar Narayan, Professor, Lambton College, (l/d<1) are classified as disk. The packing behavior of these
Sarnia, Ontario, Canada. Corresponding author: Pak Sui Lam, non‐spherical shapes usually starts from studying the
Department of Chemical and Biological Engineering, University of British mono‐sized particles (Zou and Yu, 1996a; Zhang et al., 2006)
Columbia, Vancouver, British Columbia, Canada, V6T1Z3; phone:
604‐827‐3413; fax: 604‐802‐6003; e‐mail: plam@chml.ubc.ca.
and then gradually moves to the particle mixtures with
Gas Displacement
A gas multipycnometer (Quantachrome Corp., Boynton
Beach, Fla.) that measures the volume of a group of particles
was used. The measurement is based on the pressure
difference between a known reference volume (VR ) and the
volume of the instrument's sample cell (Vc ). Nitrogen is used
as the gas to fill the reference and sample cells. The pressure
is set at around 40 kPa (near maximum as specified by the
instrument specifications). The pycnometer volume of the
sample (Vp) is calculated from
⎛P ⎞ (6)
V p = Vc − V R ⎢⎢ 1 − 1⎟⎟
⎝ P2 ⎠
where P1 is the pressure reading after pressurizing the
reference cell (kPa), P2 is the pressure after connecting the
Figure 1. A container filled with 14.7‐mm Switchgrass particles for bulk reference cell to the sample cell. The particle density (ρs ) of
density measurement.
the sample is its mass mp divided by the pycnometer particle
volume (Vpvc )
Dimensional Measurement
mp (7)
The length (l), diameter (Dout ), and the thickness (t) of ò =
10 particles in each size group were measured using a s
V pvc
150‐mm Mastercraft digital caliper with a precision of
0.01 mm. The weight (mp ) of each particle was measured The instrument readings on each sample were repeated three
using A&D GR200 digital balance with a precision of 0.1 mg. times.
The average diameter of the samples was taken as the average
value of the diameter in both ends and the middle of the WET AND DRY BULK DENSITY RELATIONSHIPS
samples along the length of the sample. The particle density The relationship between the wet (w) and dry (d) bulk
measurement of each sample was determined from the density of the samples is represented as a mixture equation in
following equations: two forms of equation 8 (Peleg, 1983) and equation 9
mp (2) (Hollenbach et al., 1982)
òp =
V p , hollow 1 1− Mw Mw (8)
= +
ò ò ò
b d w
Dout − Din (3)
t=
2 ò = ò (1 + M ) (9)
b d w
where ρb is the wet bulk density of the samples (kg m‐3) at
V p , hollow = (2rt + t 2 )pl (4)
moisture content of Mw, ρd is the bulk density (kg m‐3)
measured using a bone dried sample. Mw is the moisture
V p , solid = pr 2 l (5) content of the wet samples (decimal wet basis), ρw is the bulk
density of water (1000 kg m‐3).
where rp is the particle density of the samples (kg/m3), mp is
the mass of the samples (kg), t is the thickness of the wall of
the tube (m), Din is the inner diameter of the samples (m),
Dout is the outer diameter of the samples (m), r is the inner RESULTS
PARTICLE VOLUME AND DENSITY
L Table 1 lists the length, diameter, tube thickness, and the
mass of each of the cut stems of straw and switchgrass. The
t average lengths deviated from the target lengths by a few
millimeters. In most cases, the coefficient of variations
(standard deviation divided by average) among 10 samples
in each length group were around 0.10 to 0.15 (10% to 15%).
Dout
Outside diameter of the particles ranged from 2.4 to 2.9 mm
Din except the 9‐mm wheat straw. Switchgrass stems were more
than twice in thickness than the straw and that reflected in the
Figure 2. Dimensions of a stem assuming cylindrical shape (L: length,
Dout: outer diameter, t: wall thickness, Din: inner diameter of the hollow mass of most of the individual particles.
stem).
Table 2 lists the calculated volumes from dimensional tub ground wheat straw using 50.8‐mm screen size was about
measurements and gas displacement (pycnometer). The 56 kg m‐3 and was highly varied with particle size
volumes calculated from a hollow cylinder was less than that distribution of the sample. Ebeling and Jenkins (1985)
calculated from a solid cylinder. Single particle volumes reported that loose bulk density of wheat straw was about
measured by pycnometer showed switchgrass have more 20 kg m‐3 and was increased to 65 kg m‐3 when the sample
solids than the straw. The volumes of individual particles was chopped into smaller sizes( 10% moisture content).
measured using pycnometer were generally less than the Switchgrass had a higher bulk density (on average 125 kg m‐3
volumes calculated from dimensional measurements for loose‐fill and 147 kg m‐3 for tapped) than straw (50 kg m‐3
indicating that the gas in pycnometer had filled some of the for loose‐fill and 65 kg m‐3 for tapped). Bulk density
cellular voids. The last column lists the particle density of increased with moisture content of particles. The tapped bulk
powdered switchgrass and straw. The particle density for densities of wheat straws and switchgrass ranged from 34 to
wheat straw appears to be nearer to the particle density of 130 kg m‐3 and 68 to 323 kg m‐3, respectively, for the
finely ground sample. But for switchgrass, the particle moisture content of 8% to 60% for four different particle
density of finely ground sample was almost twice the particle sizes. The percent increase in bulk density due to tapping was
size of the large particles. The applied pressure of 40 kPa on the highest for longer biomass particles than for shorter
gas was not adequate to penetrate all of the voids in the particles. For most tests, tapping switchgrass produced a
switchgrass particle. larger percentage increase in bulk density than wheat straw.
Visually, we could not detect any influence of moisture
BULK VOLUME AND DENSITY content on bulk density change due to tapping.
Table 3 lists the results of mass and bulk volume of dry and
wet biomass and the calculated bulk density for each size RELATIONSHIP BETWEEN WET AND DRY BULK DENSITY
group. The ratio of the container diameter to the length of the Equations 8 and 9 were used for predicting the wet bulk
particles ranged from 5.38 to 24. Zou and Yu (1996b) states density from the dry bulk density. We assumed the measured
that the diameter of the column should be at least 20 times the bulk density at 8% moisture content to be the dry bulk
equivalent volume diameter of cylindrical particle in order to density. We then calculated bulk density of switchgrass and
minimize the edge effect. We noticed larger variations in straw for moisture contents at 20%, 40%, and 60% wb.
measured bulk mass of larger particles than in measured bulk Figure 3 shows sum of square of errors (SSE) between the
mass of smaller particles and this may be due to the edge predicted and measured values. For switchgrass, the SSE for
effect. This needs to be verified by constructing a larger equation 9 was higher than the SSE for equation 8. The SSE
diameter container for measuring the bulk density of larger values were small for larger particles. The SSE values
particles (i.e. to have the ratio of container diameter over the increased for the smaller particles. For wheat straw, the SSE
largest particle length more than 20). If we assume a diameter for equation 9 was slightly lower than the SSE for equation 8,
to particle length ratio of 20 for the 50‐mm length particle, but the SSE increased at high moisture of 60%. For
the container diameter should be at least a meter. equation 8, the SSE values appeared to be more random than
The wet bulk density increases as the particle size those for equation 9. We recommend equation 8 for further
decreases and moisture content increases. The least bulk analysis.
density was 24 kg m‐3 for 8% moisture content of 56.6‐mm The relationship between the dry bulk density and particle
straw particle in a loose fill and that increased to a maximum size can best be described by power law equations in the
of 111 kg m‐3 for 61.2% moisture content with the 9.1‐mm following form,
particle. The tapped density of the straw increased from
ò = ax −b (10)
34 kg m‐3 for 8.5% moisture content to 130 kg m‐3 for 61.2% b
moisture content. The least bulk density of switchgrass for where rb is the dry bulk density and x is the nominal particle
loose fill was 49 kg m‐3 for 8% moisture content of 51.8‐mm size. Table 4 lists constants a and b and R2 for equation 10.
particle and increased to the maximum density of 323 kg m‐3 The estimated values for a and b in table 4 were averaged and
for 59.4% moisture content of 8‐mm particles when tapped. it was observed that the constant a did not change much
Arthur et al. (1982) reported that the average bulk density of
between loose and tapped fill for straw and switchgrass. DISCUSSION
Overall estimates for a and b were found by trial and error Biomass samples used in this research had several
procedure as a = 166.24, b = 0.41 for straw, and a = 574.5 and characteristics that would influence the applicability of the
b = 0.54 for switchgrass. For estimating the tapped density, results to real situations: (1) samples were clean and made up
the values of b decreased to 0.33 for straw and 0.46 for solely of stems, (2) samples were cut to exact lengths and the
switchgrass. bulk density of each size groups were measured separately,
Figure 4 is the plot of wet bulk density of biomass and (3) samples were artificially wetted by spraying water on
calculated by combining equations 8 and 10, and using the the sample in order to attain high moisture conditions. The
values of a and b from table 4. lengths studied were limited to a range between 6 mm to just
1 1− M w MW (11) over 50 mm. Uniform size of straw and switchgrass particles
= + results in low bulk density due to large pore spaces among
òb ax −b òw
particles. The higher bulk density due to reorientation of the
Visually, the equation represents the wet bulk density of particles was achieved by tapping the container five times on
biomass reasonably good. As it was shown in figure 3, the the work bench. In practice, this kind of tapping is not
predictions become less accurate for smaller size particles. practical and needs to be replaced by vibration. The
direction, amplitude, and frequency of vibrations to achieve
1000
500
0
20% 20% 20% 20% 40% 40% 40% 40% 60% 60% 60% 60%
50 mm 25 mm 12 mm 6 mm 50 mm 25 mm 12 mm 6 mm 50 mm 25 mm 12 mm 6 mm
Figure 3. The square of errors of the values obtained from series and parallel equation for the prediction of wet based bulk density from dry based bulk
density at different moisture content and particle sizes of wheat straw (WS) and switchgrass (SG).
Table 4. Relationship between biomass particle size and bulk and tapped densities.
Bulk Density, ρb (kg/m3) Tapped Density, ρtb (kg/m3)
Moisture
Biomass Content a b R2 RMSE[a] a b R2 RMSE
8 113.79 0.39 0.98 5.08 150.95 0.37 0.99 9.00
20 98.80 0.32 0.97 3.08 97.88 0.25 1.00 3.03
Wheat straw
40 161.64 0.43 0.99 6.63 155.20 0.31 1.00 6.39
60 290.71 0.51 0.99 14.51 261.04 0.37 1.00 14.34
8 502.10 0.57 0.98 11.04 494.82 0.49 0.96 14.45
20 378.10 0.49 0.96 10.58 397.28 0.43 0.94 16.40
Switchgrass
40 479.77 0.52 0.94 16.50 448.51 0.40 0.92 17.37
60 938.03 0.61 0.93 26.18 938.67 0.52 0.93 28.84
[a] The root mean square error.
WS 8% mc WS 20% mc
300
WS 40% mc WS 60% mc
SG 40% mc SG 60% mc
200
150
100
50
0
0 10 20 30 40 50 60
Nominal particle size (mm)
Figure 4. Measured (symbols) and calculated wet bulk density (solid lines) of switchgrass (SG) and wheat straw (WS) at different sizes and moisture
contents for the loose packing using equation 11 and constants from table 4.
4 Individual particle density was dependent upon the way ASABE Standards. 2007. S269.4. Cubes, pellets and crumbles -
we calculated or measured the volume of the particles. Definitions and methods for determining density, durability and
Assuming that a particle was a solid cylinder, the particle moisture content. St. Joseph, Mich.: ASABE.
density of wheat straw was about 90 kg m‐3, assuming it Ebeling, J. M., and B. M. Jenkins. 1985. Physical and chemical
properties of biomass fuels. Transactions of the ASAE 28(3):
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898‐901.
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particle density was roughly 1100 kg m‐3. The peanut hull and poultry litter. Transactions of the ASABE 49(3):
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400 for hollow, and 650 kg m‐3 for pycnometer Hollenbach, A. M., M. Peleg, and R. Rufner. 1982. Effect of four
measurements. We concluded that the biomass needs to be anticaking agents on the bulk characteristics of ground sugar. J.
pulverized in order to have an accurate particle density Food Sci. 47(2): 538‐544.
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ACKNOWLEDGEMENT Physical Properties of Food, 293‐321. Westport, Conn.: AVI
This research is made possible through a USDA/DOE Publishing Co., Inc.
Grant to the University of Tennessee and a sub contract to the Ryu, C., Y. B. Yang, A. Bhor, N. E. Yates, V. N. Sharifi, and J.
University of British Columbia. The financial assistance Switenbank. 2006. Effect of fuel properties on biomass
combustion: Part 1. Experiments‐fuel type, equivalence ratio and
from the Oak Ridge National Laboratory in support of the
particle size. Fuel 85(7‐8): 1039‐1046.
logistics project is acknowledged. NSERC's Discovery and Sokhansanj, S., and W. Lang. 1996. Prediction of kernel and bulk
Strategic Grants supported the work of graduate students on volume of wheat and canola during adsorption and desorption.
this and related projects. J. Agr. Eng. Res. 63(2): 129‐136.
Sokhansanj, S., and J. Fenton. 2006. Cost benefit of biomass supply
and pre‐processing, BIOCAP research integration program
synthesis paper. Ottawa, Canada: BIOCAP Canada Foundation.
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