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  • Organic Chemistry

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    Dhyey Patel
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    The document discusses several chemical reactions and syntheses. It involves the reduction of compounds using sodium nitrite, hydrogen gas over a palladium catalyst, lithium aluminum hydride, zinc dust, and electrolytic reduction. Some reactions occur with heating to temperatures like 300°C or 623K under pressure. Products include alcohols, amines, halides, and other organic compounds.

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    Organic chemistry

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    The document discusses several chemical reactions and syntheses. It involves the reduction of compounds using sodium nitrite, hydrogen gas over a palladium catalyst, lithium aluminum hydride, zinc dust, and electrolytic reduction. Some reactions occur with heating to temperatures like 300°C or 623K under pressure. Products include alcohols, amines, halides, and other organic compounds.

    Copyright:

    © All Rights Reserved
    Download as PDF, TXT or read online from Scribd
    Flag for inappropriate content
    78 views1 page

    Organic Chemistry

    Uploaded by

    Dhyey Patel
    The document discusses several chemical reactions and syntheses. It involves the reduction of compounds using sodium nitrite, hydrogen gas over a palladium catalyst, lithium aluminum hydride, zinc dust, and electrolytic reduction. Some reactions occur with heating to temperatures like 300°C or 623K under pressure. Products include alcohols, amines, halides, and other organic compounds.

    Copyright:

    © All Rights Reserved
    Download as PDF, TXT or read online from Scribd
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    of 1

    44

    NaNO2 + HCl
    dil.H2SO4
    39 24
    Electrolytic
    H3PO2/H2O 43 reduction conc.H2SO4
    59 40 C2H5I Zn dust
    V2O5 5
    CH3CH2OH 25 Na
    60 57 58 LiAlH4 Zn 300 C 23
    38 Na2Cr2O7
    NH4Cl 6
    NaNO2,Cu HBF4 CH3COCl
    61 oleum NaOH
    62 PhOH PhNH2 42 20 21 22 dil. HNO3
    H2/Pd 350 C 7
    Ph 10-11 Ph 5-6
    HBF4 37 (ii) H
    63
    Br2
    CHCl3 + KOH 8
    CS2
    KI
    64 Sn HNO3 + H2SO4 HNO3 + H2SO4 NaNO2 + HCl Br2
    NaNO2 + HCl Sn + H2O
    56 41 36 1 2 3 4 9
    Cu/HCl 273-278K HCl HCl 273-278K H2O
    65
    conc.H2SO4
    10
    Cu/HBr 25 C
    66
    Cl2 / AlCl3 NaOH NaOH CH3I conc.H2SO4
    26 27 28 29 11
    Cu2Cl2/HCl 623K,300atm 100 C
    67 Br2 CS2 Br2 H2O Ac2O Pyridine HNO3 +
    CH3COCl Pyridine (ii) H CHCl3 + NaOH
    H2SO4 12
    Cl conc.HI
    Cu2Br2/HBr O2 H/H2O (ii) H
    68 32 33 34 35
    45 46 47 50 (51 ) 53 AlCl3 CCl4 + NaOH
    13
    + 30 31 (ii) H
    CuCN/HCN
    69 Br2 CH3CO2H HNO3
    51 (47 ) CO2 + NaOH
    H2SO4 14
    125 C, 5atm
    +
    H/H2O (ii) H
    48 52 (2 ) 54

    70
    H/H2O H/H2O
    Ac2O Br2 H2O CH3OH H PhOH H NaOH +
    CaO
    49 55

    NaOH + Cl2/AlCl3
    CH3OH H SOCl2 PCl3 NH3 88 15 16 17 18 19
    CaO
    Cl2/AlCl3
    excess 89
    71 72 74 77 87
    3Cl2/UV
    P2O5 90
    H2/Pd/BaSO4 NH3 NaOH + Br2 500K
    Br2 Mg/ether CO2
    91 92 93
    Fe (ii) H
    73 75 78 79
    I2 Na
    95 94
    HNO3 dry ether
    KOBr (CH3CO)2O Zn-Hg/HCl
    96 97
    DIBAL-H H2/Ni AlCl3
    (ii)H2O CO + HCl
    76 98
    AlCl3
    80 83 HCN + HCl/AlCl3
    99 CrO2Cl2/CS2
    (ii) H/H2O 101
    50%KOH HNO2 (ii) H/H2O
    CH3Cl CrO3 + Ac2O
    100
    AlCl3 102
    (ii) H/H2O
    81 82 84
    KMnO4/H
    103
    PCl3 NaCN
    85 86
    DMSO

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