003504 KAFFIR LIME FLAVOUR

The Product Makers (Australia) Pty Ltd Chemwatch Hazard Alert Code: 2
Version No: 1.1 Issue Date: 02/11/2017
Safety Data Sheet according to WHS and ADG requirements Print Date: 02/11/2017
S.GHS.AUS.EN

SECTION 1 IDENTIFICATION OF THE SUBSTANCE / MIXTURE AND OF THE COMPANY / UNDERTAKING

Product Identifier
Product name: 003504 KAFFIR LIME FLAVOUR
Proper shipping name: ENVIRONMENTALLY HAZARDOUS SUBSTANCE, LIQUID, N.O.S. (contains dl-limonene and lime oil)
Other means of identification: Not Available

Relevant identified uses of the substance or mixture and uses advised against
Relevant identified uses: Personal care product.

Details of the supplier of the safety data sheet Emergency telephone number
Registered company name The Product Makers (Australia) Pty Ltd Association / Organisation Not Available
Address 50 - 60 Popes Road Keysborough 3173 Australia Emergency telephone numbers 61 3 9771 0300
Telephone 61 3 9771 0300 Other emergency telephone numbers Not Available
Fax 61 3 9771 0301
Website www.theproductmakers.com
Email Not Available

SECTION 2 HAZARDS IDENTIFICATION

Classification of the substance or mixture

HAZARDOUS CHEMICAL. DANGEROUS GOODS. According to the WHS Regulations and the ADG Code.
COMBUSTIBLE LIQUID, regulated for storage purposes only

ChemWatch Hazard Ratings

Flammability 1
Toxicity 1 0 = Minimum
1 = Low
Body Contact 2 2 = Moderate
Reactivity 2 3 = High
Chronic 2 4 = Extreme

Poisons
Not Applicable
Schedule
Skin Corrosion/Irritation Category 2, Skin Sensitizer Category 1, Eye Irritation Category 2A, Respiratory Sensitizer Category 1, Specific target organ toxicity - single
Classification
exposure Category 3 (respiratory tract irritation), Reproductive Toxicity Category 2, Acute Aquatic Hazard Category 2, Chronic Aquatic Hazard Category 2, Flammable
[1]
Liquid Category 4
Legend: 1. Classified by Chemwatch; 2. Classification drawn from HSIS ; 3. Classification drawn from EC Directive 1272/2008 - Annex VI

Label elements
Hazard pictogram(s)

SIGNAL WORD : DANGER

Hazard statement(s)
H315: Causes skin irritation.
H317: May cause an allergic skin reaction.
H319: Causes serious eye irritation.
H334: May cause allergy or asthma symptoms or breathing difficulties if inhaled.

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003504 KAFFIR LIME FLAVOUR

H335: May cause respiratory irritation.

H361: Suspected of damaging fertility or the unborn child.
H411: Toxic to aquatic life with long lasting effects.
H227: Combustible liquid

Precautionary statement(s) Prevention

P201: Obtain special instructions before use.
P210: Keep away from heat/sparks/open flames/hot surfaces. - No smoking.
P261: Avoid breathing mist/vapours/spray.
P271: Use in a well-ventilated area.
P280: Wear protective gloves/protective clothing/eye protection/face protection.
P281: Use personal protective equipment as required.
P285: In case of inadequate ventilation wear respiratory protection.
P273: Avoid release to the environment.
P272: Contaminated work clothing should not be allowed out of the workplace.

Precautionary statement(s) Response

P304+P340: IF INHALED: Remove victim to fresh air and keep at rest in a position comfortable for breathing.
P308+P313: IF exposed or concerned: Get medical advice/attention.
P342+P311: If experiencing respiratory symptoms: Call a POISON CENTER or doctor/physician.
P362: Take off contaminated clothing and wash before reuse.
P370+P378: In case of fire: Use alcohol resistant foam or normal protein foam for extinction.
P302+P352: IF ON SKIN: Wash with plenty of soap and water.
P305+P351+P338: IF IN EYES: Rinse cautiously with water for several minutes. Remove contact lenses, if present and easy to do. Continue rinsing.
P312: Call a POISON CENTER or doctor/physician if you feel unwell.
P333+P313: If skin irritation or rash occurs: Get medical advice/attention.
P337+P313: If eye irritation persists: Get medical advice/attention.
P391: Collect spillage.

Precautionary statement(s) Storage

P403+P235: Store in a well-ventilated place. Keep cool.
P405: Store locked up.

Precautionary statement(s) Disposal

P501: Dispose of contents/container in accordance with local regulations.

SECTION 3 COMPOSITION / INFORMATION ON INGREDIENTS

Substances
See section below for composition of Mixtures

Mixtures
CAS No %[weight] Name
8002-75-3 60-90 palm oil
106-24-1 1-10 geraniol
138-86-3 1-10 dl-limonene
8008-26-2 1-10 lime oil
78-70-6 10-30 linalool

SECTION 4 FIRST AID MEASURES

Description of first aid measures

Eye Contact
If this product comes in contact with the eyes:
- Wash out immediately with fresh running water.
- Ensure complete irrigation of the eye by keeping eyelids apart and away from eye and moving the eyelids by occasionally lifting the upper and lower lids.
- Seek medical attention without delay; if pain persists or recurs seek medical attention.
- Removal of contact lenses after an eye injury should only be undertaken by skilled personnel.

Skin Contact
If skin contact occurs:
- Immediately remove all contaminated clothing, including footwear.
- Flush skin and hair with running water (and soap if available).
- Seek medical attention in event of irritation.
For thermal burns:
- Decontaminate area around burn.
- Consider the use of cold packs and topical antibiotics.
For first-degree burns (affecting top layer of skin)
- Hold burned skin under cool (not cold) running water or immerse in cool water until pain subsides.
- Use compresses if running water is not available.
- Cover with sterile non-adhesive bandage or clean cloth.
- Do NOT apply butter or ointments; this may cause infection.
- Give over-the counter pain relievers if pain increases or swelling, redness, fever occur.
For second-degree burns (affecting top two layers of skin)
- Cool the burn by immerse in cold running water for 10-15 minutes.
- Use compresses if running water is not available.
- Do NOT apply ice as this may lower body temperature and cause further damage.

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003504 KAFFIR LIME FLAVOUR

- Do NOT break blisters or apply butter or ointments; this may cause infection.
- Protect burn by cover loosely with sterile, nonstick bandage and secure in place with gauze or tape.
To prevent shock: (unless the person has a head, neck, or leg injury, or it would cause discomfort):
- Lay the person flat.
- Elevate feet about 12 inches.
- Elevate burn area above heart level, if possible.
- Cover the person with coat or blanket.
- Seek medical assistance.
For third-degree burns
Seek immediate medical or emergency assistance.
In the mean time:
- Protect burn area cover loosely with sterile, nonstick bandage or, for large areas, a sheet or other material that will not leave lint in wound.
- Separate burned toes and fingers with dry, sterile dressings.
- Do not soak burn in water or apply ointments or butter; this may cause infection.
- To prevent shock see above.
- For an airway burn, do not place pillow under the person's head when the person is lying down. This can close the airway.
- Have a person with a facial burn sit up.
- Check pulse and breathing to monitor for shock until emergency help arrives.

In case of burns:
- Immediately apply cold water to burn either by immersion or wrapping with saturated clean cloth.
- DO NOT remove or cut away clothing over burnt areas. DO NOT pull away clothing which has adhered to the skin as this can cause further injury.
- DO NOT break blister or remove solidified material.
- Quickly cover wound with dressing or clean cloth to help prevent infection and to ease pain.
- For large burns, sheets, towels or pillow slips are ideal; leave holes for eyes, nose and mouth.
- DO NOT apply ointments, oils, butter, etc. to a burn under any circumstances.
- Water may be given in small quantities if the person is conscious.
- Alcohol is not to be given under any circumstances.
- Reassure.
- Treat for shock by keeping the person warm and in a lying position.
- Seek medical aid and advise medical personnel in advance of the cause and extent of the injury and the estimated time of arrival of the patient.

Inhalation
- If fumes or combustion products are inhaled remove from contaminated area.
- Lay patient down. Keep warm and rested.
- Prostheses such as false teeth, which may block airway, should be removed, where possible, prior to initiating first aid procedures.
- Apply artificial respiration if not breathing, preferably with a demand valve resuscitator, bag-valve mask device, or pocket mask as trained. Perform CPR if necessary.
- Transport to hospital, or doctor, without delay.

Ingestion
- If swallowed do NOT induce vomiting.
- If vomiting occurs, lean patient forward or place on left side (head-down position, if possible) to maintain open airway and prevent aspiration.
- Observe the patient carefully.
- Never give liquid to a person showing signs of being sleepy or with reduced awareness; i.e. becoming unconscious.
- Give water to rinse out mouth, then provide liquid slowly and as much as casualty can comfortably drink.
- Seek medical advice.

Indication of any immediate medical attention and special treatment needed

Treat symptomatically.

SECTION 5 FIREFIGHTING MEASURES

Extinguishing media
- Do NOT direct a solid stream of water or foam into burning molten material; this may cause spattering and spread the fire.
- Foam.

Special hazards arising from the substrate or mixture

Fire Incompatibility
- Avoid contamination with oxidising agents i.e. nitrates, oxidising acids, chlorine bleaches, pool chlorine etc. as ignition may result

Advice for firefighters

Fire Fighting
- Alert Fire Brigade and tell them location and nature of hazard.

Fire/Explosion Hazard
- Combustible.
Combustion products include:
carbon dioxide (CO2)
acrolein
other pyrolysis products typical of burning organic material.
CARE: Water in contact with hot liquid may cause foaming and a steam explosion with wide scattering of hot oil and possible severe burns.

HAZCHEM
•3Z

SECTION 6 ACCIDENTAL RELEASE MEASURES

Personal precautions, protective equipment and emergency procedures

See section 8

Environmental precautions
See section 12

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003504 KAFFIR LIME FLAVOUR

Methods and material for containment and cleaning up

Minor Spills
Environmental hazard - contain spillage.
Slippery when spilt.
- Clean up all spills immediately.

Major Spills
Environmental hazard - contain spillage.
Slippery when spilt.
CARE: Absorbent materials wetted with occluded oil must be moistened with water as they may auto-oxidize, become self heating and ignite.
Some oils slowly oxidise when spread in a film and oil on cloths, mops, absorbents may autoxidise and generate heat, smoulder, ignite and burn.
Moderate hazard.

Personal Protective Equipment advice is contained in Section 8 of the SDS.

SECTION 7 HANDLING AND STORAGE

Precautions for safe handling

Safe handling
Rags wet / soaked with unsaturated hydrocarbons / drying oils may auto-oxidise; generate heat and, in-time, smoulder and ignite.
The 38th Amendment to the IFRA Standard (Nov 2003) states that 'linalool and natural products known to be rich in linalool should only be used when the level of peroxides is kept to the lowest
practical value.
- Avoid all personal contact, including inhalation.
- DO NOT allow clothing wet with material to stay in contact with skin

Other information
Store tightly closed under cool, dry conditions in an approved storage area. Avoid exposure to light.
Shelf life: 12 months according to specified storage conditions.

Conditions for safe storage, including any incompatibilities

Suitable container
- Glass container is suitable for laboratory quantities
- DO NOT use aluminium or galvanised containers
- Metal can or drum
- Packaging as recommended by manufacturer.

Storage incompatibility
d-Limonene:
- forms unstable peroxides in storage, unless inhibited; may polymerise
- reacts with strong oxidisers and may explode or combust
- is incompatible with strong acids, including acidic clays, peroxides, halogens, vinyl chloride and iodine pentafluoride
- flow or agitation may generate electrostatic charges due to low conductivity
- The various oxides of nitrogen and peroxyacids may be dangerously reactive in the presence of alkenes.
Acetic acid:
- vapours forms explosive mixtures with air (above 39 C.)
- reacts violently with bases such as carbonates and hydroxides (giving off large quantities of heat), oxidisers, organic amines, acetaldehyde, potassium tert-butoxide
- reacts (sometimes violently), with strong acids, aliphatic amines, alkanolamines, alkylene oxides, epichlorohydrin, acetic anhydride, 2-aminoethanol, ammonia, ammonium nitrate, bromine
pentafluoride, chlorosulfonic acid, chromic acid, chromium trioxide, ethylenediamine, ethyleneimine, hydrogen peroxide, isocyanates, oleum, perchloric acid, permanganates, phosphorus
isocyanate, phosphorus trichloride, sodium peroxide, xylene
- attacks cast iron, stainless steel and other metals, forming flammable hydrogen gas
- attacks many forms of rubber, plastics and coatings
The very feature which confers the important properties on carotenoids (antioxidants) also makes
them unstable.
HAZARD:
- Although anti-oxidants may be present, in the original formulation, these may deplete over time as they come into contact with air.
· Materials soaked with plant/ vegetable derived (and rarely, animal) oils may undergo spontaneous combustion
· Many vegetable and animal oils absorb oxygen from the air to form oxidation products.
Terpenoids and terpenes, are generally unsaturated, are thermolabile, are often volatile and may be easily oxidised or hydrolysed depending on their respective structure.
· The interaction of alkenes and alkynes with nitrogen oxides and oxygen may produce explosive addition products; these may form at very low temperatures and explode on heating to
higher temperatures (the addition products from 1,3-butadiene and cyclopentadiene form rapidly at -150 C and ignite or explode on warming to -35 to -15 C).
- Avoid reaction with oxidising agents

SECTION 8 EXPOSURE CONTROLS / PERSONAL PROTECTION

Control parameters

Occupational Exposure Limits (OEL)

INGREDIENT DATA
Not Available

Exposure controls
Appropriate engineering controls
Engineering controls are used to remove a hazard or place a barrier between the worker and the hazard.
For molten materials:
Provide mechanical ventilation; in general such ventilation should be provided at compounding/ converting areas and at fabricating/ filling work stations where the material is heated.
Keep dry!!
Processing temperatures may be well above boiling point of water, so wet or damp material may cause a serious steam explosion if used in unvented equipment.
Care: Atmospheres in bulk storages and even apparently empty tanks may be hazardous by oxygen depletion.

Requirements of State Authorities concerning conditions for tank entry must be met.

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003504 KAFFIR LIME FLAVOUR

Personal protection

Eye and face protection

- Safety glasses with side shields.

Skin protection
See Hand protection below

Hands/feet protection
- Wear chemical protective gloves, e.g. PVC.
NOTE:
- The material may produce skin sensitisation in predisposed individuals.
The selection of suitable gloves does not only depend on the material, but also on further marks of quality which vary from manufacturer to manufacturer.
- When handling hot materials wear heat resistant, elbow length gloves.
- Protective gloves eg. Leather gloves or gloves with Leather facing
- Neoprene rubber gloves

Body protection
See Other protection below

Other protection
- When handling hot or molten liquids, wear trousers or overalls outside of boots, to avoid spills entering boots.
- Usually handled as molten liquid which requires worker thermal protection and increases hazard of vapour exposure.
- Overalls.

Thermal hazards
Not Available

SECTION 9 PHYSICAL AND CHEMICAL PROPERTIES

Information on basic physical and chemical properties

Appearance: Clear pale yellow to pale green liquid

Physical state Liquid Relative density (Water = 1) 0.9

Odour Characteristic Partition coefficient n-octanol / water Not Available
Odour threshold Characteristic of kaffir lime Auto-ignition temperature (°C) Not Available
pH (as supplied) Not Available Decomposition temperature Not Available
Melting point / freezing point (°C) Not Available Viscosity (cSt) Not Available
Initial boiling point and boiling range (°C) Not Available Molecular weight (g/mol) Not Available
Flash point (°C) >60 Taste Not Available
Evaporation rate Not Available Explosive properties Not Available
Flammability Combustible. Oxidising properties Not Available
Refractive Index 1.467 Surface Tension (dyn/cm or mN/m) Not Available
Lower Explosive Limit (%) Not Available Volatile Component (%vol) Not Available
Vapour pressure (kPa) Not Available Gas group Not Available
Solubility in water (g/L) Not Available pH as a solution (1%) Not Available
Vapour density (Air = 1) Not Available VOC g/L Not Available

SECTION 10 STABILITY AND REACTIVITY

Reactivity:
See section 7
Chemical stability:
- Unstable in the presence of incompatible materials.
Possibility of hazardous reactions:
See section 7
Conditions to avoid:
See section 7
Incompatible materials:
See section 7
Hazardous decomposition products:
See section 5

SECTION 11 TOXICOLOGICAL INFORMATION

Information on toxicological effects

Inhaled
The material can cause respiratory irritation in some persons.
Inhalation hazard is increased at higher temperatures.
Inhalation of vapours may cause drowsiness and dizziness.
Not normally a hazard due to non-volatile nature of product
Inhalation of oil droplets or aerosols may cause discomfort and may produce chemical inflammation of the lungs.
Fine mists generated from plant/ vegetable (or more rarely from animal) oils may be hazardous.

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003504 KAFFIR LIME FLAVOUR

- Usually handled as molten liquid which requires worker thermal protection and increases hazard of vapour exposure.

Ingestion
Accidental ingestion of the material may be damaging to the health of the individual.
Retinoid poisoning from Vitamin A intoxication may occur at high doses and is characterised by sedation, headache, irritability, swelling of the disc in the eye, and a generalised peeling of the skin.
The retinoids occur widely naturally.
Terpenes and their oxygen-containing counterparts, the terpenoids, produce a variety of effects.
Central nervous system (CNS) depression may include general discomfort, symptoms of giddiness, headache, dizziness, nausea, anaesthetic effects, slowed reaction time, slurred speech and
may progress to unconsciousness.

Skin Contact
The material may accentuate any pre-existing dermatitis condition
Skin contact is not thought to have harmful health effects (as classified under EC Directives); the material may still produce health damage following entry through wounds, lesions or abrasions.
Following contact with plants that produce furocoumarins and direct sunlight, a severe, painful reaction can occur, with blisters.
Open cuts, abraded or irritated skin should not be exposed to this material
Entry into the blood-stream, through, for example, cuts, abrasions or lesions, may produce systemic injury with harmful effects.
The material may cause moderate inflammation of the skin either following direct contact or after a delay of some time.

Eye
Evidence exists, or practical experience predicts, that the material may cause eye irritation in a substantial number of individuals.

Chronic
Long-term exposure to respiratory irritants may result in airways disease, involving difficulty breathing and related whole-body problems.
Inhaling this product is more likely to cause a sensitisation reaction in some persons compared to the general population.
Skin contact with the material is more likely to cause a sensitisation reaction in some persons compared to the general population.
Based on experience with animal studies, exposure to the material may result in toxic effects to the development of the foetus, at levels which do not cause significant toxic effects to the mother.
There has been some concern that this material can cause cancer or mutations but there is not enough data to make an assessment.
Substance accumulation, in the human body, may occur and may cause some concern following repeated or long-term occupational exposure.
Glyceryl triesters (triglycerides) undergo metabolism to become free fatty acids and glycerol.
Certain substances, commonly found in perfumes or perfumed products, produce hypersensitivity.
Repeated swallowing of linoleic acid may alter platelet function.
A number of common flavor and fragrance chemicals can form peroxides surprisingly fast in air.
d-Limonene may cause damage to and growths in the kidney.
Linalool (a terpinoid) is an unsaturated tertiary alcohol.
Peroxidisable terpenes and terpenoids should only be used when the level of peroxides is kept to the lowest practicable level, for instance by adding antioxidants at the time of production.

TOXICITY IRRITATION
003504 KAFFIR LIME FLAVOUR
Not Available Not Available

TOXICITY IRRITATION
palm oil
Not Available Not Available

TOXICITY IRRITATION
[2] Skin (guinea pig):100mg/24hSEVERE
Dermal (rabbit) LD50: >5000 mg/kg
geraniol
Oral (rat) LD50: 2100 mg/kg [1] Skin (man): 16 mg/24h - SEVERE

Skin (rabbit): 100 mg/24h-SEVERE

TOXICITY IRRITATION

dl-limonene Oral (rat) LD50: 5300 mg/kg [2] Eye : Moderate

Skin : Moderate

TOXICITY IRRITATION
[2] Skin (rabbit): 500 mg/24h - mild
lime oil dermal (rat) LD50: >5000 mg/kg

Oral (rat) LD50: >5000 mg/kg [2]

TOXICITY
dermal (rat) LD50: 5610 mg/kg
linalool
Oral (rat) LD50: 2790 mg/kg
IRRITATION
[2] Skin (guinea pig):100mg/24h-mild
[2] Skin (man): 16 mg/48h-mild
Skin (rabbit): 100 mg/24h-SEVERE
Skin (rabbit): 500 mg/24h - mild

Legend: 1. Value obtained from Europe ECHA Registered Substances - Acute toxicity 2.* Value obtained from manufacturer's SDS. Unless otherwise specified data extracted from RTECS -
Register of Toxic Effect of chemical Substances

PALM OIL
For group E aliphatic esters (polyol esters):
The polyol esters, including trimethylolpropane (TMP).
The material may be irritating to the eye, with prolonged contact causing inflammation.

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003504 KAFFIR LIME FLAVOUR

GERANIOL
Allergic reactions involving the respiratory tract are usually due to interactions between IgE antibodies and allergens and occur rapidly.
Attention should be paid to atopic diathesis, characterised by increased susceptibility to nasal inflammation, asthma and eczema.
Exogenous allergic alveolitis is induced essentially by allergen specific immune-complexes of the IgG type; cell-mediated reactions (T lymphocytes) may be involved.
Geraniol does have sensitising properties, but the response it exhibits tends to be weak and variable.
Citronellol, geraniol, nerol, and geranyl acetate are currently generally regarded as safe by the US FDA for their intended use as flavouring substances.

LIME OIL
The essential oils, oleoresins (solvent-free), and natural extractives (including distillates) derived from citrus fruits are generally recognized as safe (GRAS) for their intended use in foods for
human consumption.
NOTE: Substance has been shown to be mutagenic in at least one assay, or belongs to a family of chemicals producing damage or change to cellular DNA.
The material may produce severe irritation to the eye causing pronounced inflammation.
Gastrointestinal tumours recorded Equivocal tumorigen by RTECS criteria

LINALOOL
The terpenoid hydrocarbons are found in needle trees and deciduous plants.
Inhalational exposure of mice and man to linalool caused slight sedative effects but a dose dependent response characteristic could not be determined.
Opinion holds that there are no safety concerns for linalool and the linalyl esters, as fragrance ingredients, under the present declared levels of use and exposure for the following reasons:
· Linalool and the linalyl esters have a low order of acute toxicity.
A member or analogue of a group of aliphatic and alicyclic terpenoid tertiary alcohols and structurally related substances generally regarded as safe.
For terpenoid tertiary alcohols and their related esters:
These substances are metabolised in the liver and excreted primarily in the urine and faeces.
Alkyl alcohols of chain length C6-13 are absorbed from skin, when inhaled or swallowed but show evidence of little harm.

PALM OIL & GERANIOL

Asthma-like symptoms may continue for months or even years after exposure to the material ends.

PALM OIL & LIME OIL

No significant acute toxicological data identified in literature search.

PALM OIL & LIME OIL

The material may cause skin irritation after prolonged or repeated exposure and may produce on contact skin redness, swelling, the production of vesicles, scaling and thickening of the skin.

GERANIOL & DL-LIMONENE & LIME OIL & LINALOOL

The following information refers to contact allergens as a group and may not be specific to this product.

GERANIOL & DL-LIMONENE & LIME OIL & LINALOOL

Adverse reactions to fragrances in perfumes and fragranced cosmetic products include allergic contact dermatitis, irritant contact dermatitis, sensitivity to light, immediate contact reactions, and
pigmented contact dermatitis.

GERANIOL & DL-LIMONENE & LIME OIL & LINALOOL

Fragrance allergens act as haptens, which are small molecules that cause an immune reaction only when attached to a carrier protein.

GERANIOL & LINALOOL

With few exceptions* (see below), there are no safety concerns regarding certain cyclic and non-cyclic terpene alcohols **, as fragrance ingredients, under present declared levels of use and
exposure, because
- They have low acute toxicity
- No significant toxicity was observed in repeat dose toxicity tests
- They were not found to cause mutations or genetic toxicity
- Substances in this group are processed similarly in the body
- There is no indication of persistent breakdown products causing severe toxicity
- They practically do not irritate the skin
- They have a generally low potential for sensitization
- The margin of safety is more than 100 times the maximum daily exposure.

GERANIOL & LINALOOL

Current opinion holds that there are no safety concerns regarding the branched chain unsaturated non-cyclic alcohols, as fragrance ingredients, at current declared levels of use and exposure;
however, use of these materials at higher maximum levels of skin or whole-body exposure requires re-evaluation.

GERANIOL & LINALOOL

The material may cause severe skin irritation after prolonged or repeated exposure and may produce on contact skin redness, swelling, the production of vesicles, scaling and thickening of the
skin.

DL-LIMONENE & LIME OIL

d-Limonene is readily absorbed by inhalation and swallowing.

Acute Toxicity Carcinogenicity

Skin Irritation/Corrosion Reproductivity
Serious Eye Damage/Irritation STOT - Single Exposure
Respiratory or Skin sensitisation STOT - Repeated Exposure
Mutagenicity Aspiration Hazard

Legend: – Data available but does not fill the criteria for classification
– Data available to make classification
– Data Not Available to make classification

SECTION 12 ECOLOGICAL INFORMATION

Toxicity

ENDPOINT TEST DURATION (HR) SPECIES VALUE SOURCE

003504 KAFFIR LIME FLAVOUR
Not Available Not Available Not Available Not Available Not Available

palm oil ENDPOINT TEST DURATION (HR) SPECIES VALUE SOURCE

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Not Available Not Available Not Available Not Available Not Available

ENDPOINT TEST DURATION (HR) SPECIES VALUE SOURCE

geraniol LC50 96 Fish 2.6mg/L 4
EC50 48 Crustacea 10.8mg/L 2

ENDPOINT TEST DURATION (HR) SPECIES VALUE SOURCE

dl-limonene LC50 96 Fish 0.0385mg/L 4
EC50 48 Crustacea 0.0282mg/L 4

ENDPOINT TEST DURATION (HR) SPECIES VALUE SOURCE

lime oil
Not Available Not Available Not Available Not Available Not Available

ENDPOINT TEST DURATION (HR) SPECIES VALUE SOURCE

LC50 96 Fish <19.9mg/L 1
linalool EC50 48 Crustacea =20mg/L 1
EC50 96 Algae or other aquatic plants =88.3mg/L 1
NOEC 96 Fish <3.5mg/L 1

Legend: Extracted from 1. IUCLID Toxicity Data 2. Europe ECHA Registered Substances - Ecotoxicological Information - Aquatic Toxicity 3. EPIWIN Suite V3.12 (QSAR) - Aquatic Toxicity
Data (Estimated) 4. US EPA, Ecotox database - Aquatic Toxicity Data 5. ECETOC Aquatic Hazard Assessment Data 6. NITE (Japan) - Bioconcentration Data 7. METI (Japan) -
Bioconcentration Data 8. Vendor Data
Toxic to aquatic organisms, may cause long-term adverse effects in the aquatic environment.
Do NOT allow product to come in contact with surface waters or to intertidal areas below the mean high water mark.
For fatty acids and fatty alcohols:
Environmental fate:
Saturated fatty acids are very stable in air, whereas unsaturated (C=C bonds) fatty acids are susceptible to oxidation.
For Terpenes such as Limonene and Isoprene:
Atmospheric Fate: Contribute to aerosol and photochemical smog formation.
Substances containing unsaturated carbons are ubiquitous in indoor environments.
For Retinoids:
Environmental Fate: Retinoids are naturally occurring derivatives of vitamin A which have profound effects upon the development of various embryonic systems, especially amphibians.
For Limonenes:
Atmospheric Fate: Due to the high volatility of limonene, the atmosphere is expected to be the major environmental sink for this chemical.
For Linalool: Vapor Pressure: ~0.2 hPa (at 23.5 C); Water Solubility: 1589 mg/L.
For Unsaturated Vegetable Oils:
Environmental Fate: The application of vegetable oils for industrial purposes has been in practice for many years.
DO NOT discharge into sewer or waterways.

Persistence and degradability

Ingredient Persistence: Water/Soil Persistence: Air
geraniol LOW LOW
dl-limonene HIGH HIGH
linalool HIGH HIGH

Bioaccumulative potential
Ingredient Bioaccumulation
geraniol LOW (LogKOW = 3.47)
dl-limonene HIGH (LogKOW = 4.8275)
linalool LOW (LogKOW = 2.97)

Mobility in soil
Ingredient Mobility
geraniol LOW (KOC = 70.79)
dl-limonene LOW (KOC = 1324)
linalool LOW (KOC = 56.32)

SECTION 13 DISPOSAL CONSIDERATIONS

Waste treatment methods

Product / Packaging disposal
- Containers may still present a chemical hazard/ danger when empty.
Legislation addressing waste disposal requirements may differ by country, state and/ or territory.
- DO NOT allow wash water from cleaning or process equipment to enter drains.
- Recycle wherever possible or consult manufacturer for recycling options.

Continued...
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003504 KAFFIR LIME FLAVOUR

SECTION 14 TRANSPORT INFORMATION

Labels Required

Marine Pollutant

HAZCHEM
•3Z

Land transport (ADG) Air transport (ICAO-IATA / DGR) Sea transport

(IMDG-Code / GGVSee)

UN number: 3082 Environmental hazard: Environmental hazard: Environmental hazard: Marine

Pollutant
UN proper shipping name: ENVIRONMENTALLY HAZARDOUS Environmentally Environmentally hazardous
SUBSTANCE, LIQUID, N.O.S. (contains dl-limonene and lime oil) hazardous EMS Number: F-A , S-F
ERG Code: 9L
Transport hazard class(es): 9 Special provisions: 274 331 Special provisions: 274 335
Special provisions: A97 A158 A197
335 375 AU01 969
Subrisk: Not Applicable
Cargo Only Packing Instructions: 964
Limited quantity: 5 L Limited Quantities: 5 L
Packing group: III
Cargo Only Maximum Qty / Pack: 450 L
Passenger and Cargo Packing
Instructions: 964
Passenger and Cargo Maximum Qty /
Pack: 450 L
Passenger and Cargo Limited Quantity
Packing Instructions: Y964
Passenger and Cargo Limited Maximum
Qty / Pack: 30 kg G

Environmentally Hazardous Substances meeting the descriptions of UN 3077 or UN 3082

are not subject to this Code when transported by road or rail in;
(a) packagings;
(b) IBCs; or
(c) any other receptacle not exceeding 500 kg(L).
- Australian Special Provisions (SP AU01) - ADG Code 7th Ed.

SECTION 15 REGULATORY INFORMATION

Safety, health and environmental regulations / legislation specific for the substance or mixture

palm oil(8002-75-3) is found on the following regulatory lists

- Australia Inventory of Chemical Substances (AICS)

geraniol(106-24-1) is found on the following regulatory lists

- Australia Inventory of Chemical Substances (AICS)

dl-limonene(138-86-3) is found on the following regulatory lists

- Australia Hazardous Substances Information System - Consolidated Lists - International Agency for Research on Cancer (IARC) - Agents Classified by the IARC
- Australia Inventory of Chemical Substances (AICS) Monographs

lime oil(8008-26-2) is found on the following regulatory lists

- Australia Inventory of Chemical Substances (AICS)

linalool(78-70-6) is found on the following regulatory lists

- Australia Inventory of Chemical Substances (AICS)

National Inventory Status

Australia - AICS Y
Canada - DSL Y
Canada - NDSL N (dl-limonene; linalool; lime oil; palm oil; geraniol)
China - IECSC Y
Europe - EINEC / ELINCS / NLP N (lime oil)
Japan - ENCS N (lime oil; palm oil)
Korea - KECI Y
New Zealand - NZIoC Y

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003504 KAFFIR LIME FLAVOUR

Philippines - PICCS Y
USA - TSCA Y
Y = All ingredients are on the inventory
Legend:
N = Not determined or one or more ingredients are not on the inventory and are not exempt from listing(see specific ingredients in brackets)

SECTION 16 OTHER INFORMATION

Other information

Ingredients with multiple cas numbers

Name CAS No
linalool 78-70-6, 126-91-0, 126-90-9

Classification of the preparation and its individual components has drawn on official and authoritative sources as well as independent review by the Chemwatch Classification committee using
available literature references.
The SDS is a Hazard Communication tool and should be used to assist in the Risk Assessment.

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end of SDS