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Environ Earth Sci (2015) 73:5891–5904

DOI 10.1007/s12665-015-4341-7

THEMATIC ISSUE

The role of surface and subsurface integration in the development


of a high-pressure and low-production gas field
Yang Liu1 • Jiexun Li2 • Zhihua Wang1,2 • Shanzhe Wang1 • Yingchun Dong2

Received: 13 November 2014 / Accepted: 22 March 2015 / Published online: 3 April 2015
Ó Springer-Verlag Berlin Heidelberg 2015

Abstract Against a background of gradual changes in the be necessary to design a simplified production process for
global energy consumption structure, clean natural gas still multi-well gathering and single-well rotation. Meanwhile,
plays an indispensable role in satisfying energy needs. the role of surface and subsurface integration would be
Xushen gas field in Songliao Basin has held the balance in better played by improving the key production units such
gas-producing areas in China since its exploitation in 2004, as wellbore throttling, gathering pipe heat tracing, corro-
especially by ‘‘using a gas to supply oil output’’ strategy in sion inhibitor injection and gas purification disposal. This
Daqing oilfield. However, the difficulties and beneficial study will contribute to obtaining the maximum benefits in
results of development in the field are challenged by the green gas field development.
very cold climate, poor reservoir property and high
amounts of CO2 in natural gas. An investigation of the Keywords Clean energy  Natural gas  Production
heat-tracing measures for preventing the formation of process  Operation parameter  Hydrate prevention 
natural gas hydrates and selection of stainless steel pipes Xushen gas field
and a high-pressure equipment to restrain CO2 corrosion in
Xushen gas field operation was carried out recently. In this List of symbols
paper, the hydraulic and thermal characteristics of gas A Flow area (m2)
gathering pipelines is studied, including a discussion on the c Specific heat (J kg-1 °C-1)
effect of high pressure and low production on the formation D External diameter of gas gathering pipeline (m)
of natural gas hydrates during transportation and the de- F Friction impulse (kg m s-1)
termination of technical limits for inhibiting the formation g Gravity constant (m s-2)
of hydrates under different conditions. Subsequently, the Hl Liquid holdup (%)
gas production process, including purification and de- K Heat transfer coefficient (W m-2 °C-1)
foaming parameters in a high-pressure and low-production L Length of gas gathering pipeline (m)
field, is optimized. The results indicate that the surface Dm_ Mass flow (kg s-1)
engineering construction would take up more than 30 % of P Pressure (Pa)
the total investment in gas field development, especially in q Calorific value of gas (kJ Nm-3)
high-pressure and low-production areas, and that it would R Gas constant (8314 kJ kmol-1 K-1)
Swc Water saturation (%)
T Temperature (K)
& Zhihua Wang q Density (kg m-3)
zhihua_wang@126.com t Velocity (m/s)
1 u Void fraction (%)
Key Laboratory of Enhanced Oil and Gas Recovery Under
Ministry of Education, Northeast Petroleum University, g Efficiency (%)
Daqing 163318, Heilongjiang, People’s Republic of China k Heat transfer coefficient (W m-1 °C-1)
2
Daqing Oilfield Company Limited, d Wall thickness of the pipeline (m)
Daqing 163002, Heilongjiang, People’s Republic of China RF Resistance coefficient (–)

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5892 Environ Earth Sci (2015) 73:5891–5904

Subscript 2014). Bagheri et al. (2014) investigated the origin of brine


l Liquid phase in Kangan gas field. The saline produced water in the gas
g Gas phase field is a counterproductive issue, and it causes corrosion in
the pipelines and wellhead facilities. They came to the
conclusion that understanding the causes of salinity of the
Introduction aquifer water has important implications for overcoming
this problem and for long-term reservoir management.
In recent years, the global energy sector has undergone In this paper, specific treatment measures for preventing
significant changes, including the global financial crisis the formation of natural gas hydrates and restraining CO2
that was accompanied by high price volatility for hydro- corrosion of Xushen gas field in Daqing (China) are pre-
carbons, international hydrocarbons trade redrawn by new sented. Subsequently, the hydraulic and thermal charac-
exploratory development technologies, and a noticeable teristics of gas gathering pipelines were studied, including
slowdown in requirement and increasing competition from a discussion on the formation of natural gas hydrates dur-
the traditional energy markets (Bildirici and Bakirtas 2014; ing transportation and gathering of technical limits to in-
Bloch et al. 2012; Shahbas and Lean 2012). hibit the formation of gas hydrates under different
According to a detailed analysis and forecasts of the conditions. Furthermore, the gas production process, the
development trend in the global energy sector, the world’s purification and the defoaming parameters in high-pressure
consumption of primary energy will increase by only 40 % and low-production field were optimized. This is sig-
(approximately 1.1 % annually) from 2010 to 2040, which nificant for taking advantage of the role of surface and
is threefold lower than the average annual gross domestic subsurface integration, and will contribute to realizing the
product (GDP) growth and significantly slower than the efficient development of clean energy.
energy consumption growth observed over the past
30 years (Behmiri and Pires Manso 2013; Mitrova 2014;
Zheng and Luo 2013). Undoubtedly, hydrocarbons will Development background of Xushen gas field
remain the basis of the world’s energy over this period. At
the same time, the structure of the world’s energy con- The Xushen gas field, located in the north of Songliao
sumption will become more diversified and balanced. As is Basin, has been a giant potential source of gas for China
known, in the next 30 years, the share of fossil fuels will from the 1990s onwards (Xu et al. 2011). It was developed
gradually level off, oil consumption will drop to 27 % and and went into production in 2004. It is an example of a
coal to 25 %, while gas consumption will increase to 25 %, typical dry gas field with low sulfur and high pressure. This
and the percentage of fossil fuels will be approached by gas field is located in a cold region, in which the annual
that of other non-fossil sources (Makarov et al. 2013; minimum temperature is -36 °C, and the depth of frozen
Payne 2011). In terms of sustainable energy, natural gas ground can reach 2 m. The shut-in pressure for most gas
has advantages in combustion efficiency and low CO2 wells ranges from 2900 to 4350 psi, downhole flowing
emissions. Its lower emission impact, price advantages and pressure is about 2900 psi and the operation pressure of the
alternative ways of production have made natural gas be- gathering pipeline after throttling ranges from 725 to
come an important source of clean energy, and it will be 1015 psi. The sulfur content of the gas produced is lower
the most popular type of fuel in decades to come in (Pao than 10 mg L-1. However, some blocks have a high content
and Tsai 2011; Gurgul and Lach 2011). Against this of CO2, sometimes higher than 20 %, with a partial pressure
background, efficient exploration and development of of about 145 psi, as described in the previous study by De
condensate gas and other unconventional gas are urgent Lucia et al. (2012), which causes serious corrosion to the
and promising. Also, the future development of natural gas equipment. In addition, several gas wells may attain high
will inevitably have impact on other fossil fuel industries. water production rates up to 30 m3 d-1. With the con-
However, the development of natural gas will encounter tinuous exploitation of the gas field, a gradual decline in gas
challenges of technical bottlenecks and beneficial results production rates has been registered due to poor reservoir
similar to the development of oil, especially in areas with properties (Dai et al. 2014). This kind of reservoir has an
very cold climate and poor reservoir properties. These average porosity of 7.65 % and a mean permeability of
challenges can be addressed by preventing the formation of 0.15 9 10-3 lm2, and the lithological character of its ma-
hydrates, restraining the CO2 corrosion and optimizing the trix is compact and going against fluids driving. The natural
production process and operation parameters. low-production capacity wells are about 80 % of the total,
Previous studies showed that environmental hazards and fracturing technology is necessary for achieving com-
caused by oil and gas reservoirs’ exploitation activities are mercial levels (Yang et al. 2008). Currently, the gas pro-
one of the most serious problems worldwide (Jia et al. duction of this field is approaching 15 9 108 m3 a-1. The

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Environ Earth Sci (2015) 73:5891–5904 5893

development practice of this field indicates that the in- phase and the gas phase, kg m s-1; tg is the velocity of the
vestment in surface engineering is about 35.8 % of the total, gas phase, m s-1; tl is the velocity of the liquid phase,
and the sum invested in the surface gas production system, m s-1; Hl is the liquid holdup, %; hg is the elevation head
surface gas gathering pipeline and station is about 80 % of of the gas phase (m); hl is the elevation head of the liquid
the total surface engineering budget (Xu et al. 2008). It is phase (m); z is the elevation head of the flow area, m; u is
therefore necessary to put surface and subsurface integra- the void fraction, %; A is the flow area (m2); Al is the liquid
tion into practice to reduce and control the investment costs, phase in the flow area (m2); Ag is the gas phase in the flow
as this is also beneficial for realizing the efficient devel- area (m2); D is the external diameter of the gas gathering
opment of high-pressure and low-production gas fields. pipeline (m); K is the heat transfer coefficient, W m-2 °C);
T is the temperature, K; T0 is the environmental tem-
perature, K; g is the gravity constant, m s-2.
Hydraulic and thermal characteristic models
Thermodynamic model
Hydraulic model
During the process of natural gas transportation, each node
When calculating the average velocity corresponding to varied with the relevant physical parameters such as flow
each cross-sectional area, it was assumed that the gas rate, temperature, pressure, component of gas and liquid.
gathering pipeline is isothermal transportation and that the Therefore, establishment of phase equilibrium and state
gas and liquid phases are in thermodynamic equilibrium equations, and the determination of the physical parameters
(Beggs 1973; Martinez 1997). The influence of time on are significant for the thermodynamic property analyses of
other parameters is neglected during the calculation pro- the gas gathering system. The widely used SHBWR
cess. Thus, the gas phase continuity equation: equation, which is the foundation of the gas–liquid equi-
dqg dtg du librium model, was proposed by Starling and Han (1972).
Atg u þ Aqg u þ Aqg tg ¼ Dm_ gl ð1Þ At present, it is one of the most widely used models for
dx dx dx
thermal analysis of the gas gathering pipeline.
The liquid phase continuity equation:
SHBWR is normalized as:
dql dtl dHl  
Atl Hl þ Aql Hl þ Aql tl ¼ Dm_ lg ð2Þ C0 D0 E0
dx dx dx P ¼ qRT þ B0 RT  A0  2 þ 3  4 q2
T T T
   
The momentum equation: d 3 d 6 cq3 ð1 þ cq2 Þ expðcq2 Þ
þ bRT  a  q þa aþ q þ
T T T2
dP dtg dtl
A þ qg tg uA þ q l tl H l A ð5Þ
dx dx dx ð3Þ XX 1 1  
¼ Fgw  Flw  ðqg u þ ql Hl ÞgA sin h A0 ¼ Xi Xj A20i A20j 1  kij ð6Þ
X
The mixture energy conservation equation: B0 ¼ Xi B0i ð7Þ
dhg dhl dtg dtl XX 1  3
qg tg uA þ ql tl Hl A þ qg t2g uA þ ql t2l Hl A 1

dx dx dx dx C0 ¼ 2
Xi Xj C0i 2
C0j 1  kij ð8Þ
dz XX  4
¼ ðqg gtg uA þ ql gtl Hl AÞ  KpDðT  T0 Þ D0 ¼
1 1
Xi Xj D0i D0j 1  kij
2 2
ð9Þ
dx!
t2g  t2l XX 1 1  5
 Dm_ gl hg  hl þ ð4Þ E0 ¼ 2
Xi Xj E0i 2
E0j 1  kij ð10Þ
2
hX 1 i3
where, in the formula, P is the pressure of the flow area, Pa; a¼ xi a3i ð11Þ
Dm_ gl is the mass flow of the liquid phase transit into the gas hX 1
i3
phase, kg s-1; Dm_ lg is the mass flow of the gas phase transit b¼ xi b3i ð12Þ
into the liquid phase, kg s-1; qg is the density of the gas hX i3
1
phase, kg m-3; ql is the density of the liquid phase, kg m-3; C¼ xi c3i ð13Þ
Fgw is the friction impulse between the gas phase and the hX i3
1
pipe wall, kg m s-1; Flw is the friction impulse between the d¼ xi di3 ð14Þ
liquid phase and the pipe wall, kg m s-1; Fgi is the friction
hX i3
impulse between the gas phase and the liquid phase, 1
a¼ xi a3i ð15Þ
kg m s-1; Fli is the friction impulse between the liquid

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hX 1
i2
c¼ xi c3i ð16Þ Table 1 Composition of natural gas
Composition Mole fraction (%)
where P is the system pressure, Pa; q is the density
(k mol m-3); T is the temperature, K; R is the gas constant, CH4 92.33
8314 kJ (k mol K)-1; xi represents the mole fraction of i C2H6 2.41
component (in the mixture of gas or liquid phases); Kij is C3H8 0.39
the transfer coefficient between i and j, Kij ¼ Kji ; A0 , B0 , C4H10 0.18
C0 , D0 , E0 , a, b, c, d, a, c are the mixture state equation C5H12 0.03
coefficients, whose values are determined by Starling’s iC6H14 0.02
normal paraffin correlations. CO2 2.91
Based on the above methods, temperature drop along the N2 1.73
gas gathering pipeline can be determined. This can reveal
the universal pattern that temperature decreases with the
increase in the gas transportation rate. When the gas Taking one gas well in Xushen gas field as an example,
transportation rate and distance remain unchanged, the final the gas production rate of this well is 50,000 m3 d-1 and
temperatures are increased with an increase in the wellhead the water production rate is 10 m3 d-1. The composition of
temperature. By keeping the wellhead temperature and natural gas is summarized in Table 1. The overall length of
distance unchanged, the final temperature will be increased the surface gas gathering pipeline is 1289 m, the tem-
with the increasing gas transportation rate. perature of wellhead is 24 °C, the transportation pressure is
870 psi, the buried depth of pipeline is 2 m and the
thickness of silicate insulating layer is 40 mm. So the
The formation and inhibition of gas hydrates formation limits relationship between the temperature and
pressure of gas hydrates in this gas gathering pipeline can
The gas hydrates are considered as undesirable solids be established.
when they form in gas transportation and processing By combining the hydraulic and thermal analyses of this
equipment. They can cause detrimental obstacles to the pipeline, the formation temperature and location of gas
flow of gas and serious damage to instruments because of hydrates can be predicted. As shown in Fig. 1, the hy-
high-pressure pipeline explosions (Ghavipour et al. 2013; draulic and thermal characteristics’ curve intersects with
Li et al. 2013). In these cases, hydrate formation can be the curve for the relationship between pressure and tem-
prevented by dehydrating the water, maintaining tem- perature, which reveals that the formation temperature
perature and pressure outside the hydrate formation re- limit of the gas hydrates under this condition is 19.1 °C.
gion and injecting thermodynamic inhibitors or low- Furthermore, according to the thermal characteristic, the
dosage hydrate inhibitors. location of gas hydrate formation can be found about
819 m away from the wellhead. In other words, the re-
The formation limits of gas hydrates maining 470 m is the key area of gas hydrate inhibition in
this pipeline.
The importance of accurate hydrate formation prediction is
evidenced by its wide applications, such as the determi-
nation of the limits for natural gas expansion during
throttling in valves, chokes and restrictions, the amount of 1000
inhibitor to be injected. Temperature and pressure are the formation limits of gas
key parameters which determine the formation of gas hy- 800 hydrates 19.1 ,
drates. The free water model, which is based on phase 853.7psi
Pressure(psi)

hydraulic and thermal


equilibrium, contains the following phases: the water-rich 600 characteristics
phase of mixed hydrates, which forms in the pipeline, the
400
gas and water-rich phase, the hydrocarbon–water-rich
phase, and gas phase with hydrocarbon–water-rich phase 200
(Nguyen et al. 2008). Therefore, it is possible to use
PIPESYS (multiphase flow pipeline simulation software) 0
0 5 10 15 20 25
with a free water model for predicting the gas hydrate
Temperature( )
formation limits for the gas gathering pipeline under dif-
ferent conditions. Fig. 1 Determination of gas hydrate formation limits

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Comparison and selection of the methods


where Pc is the total operating cost ($); T is the heat-
for hydrates inhibition
tracing cycle (h); D is the external diameter of the gas
gathering pipeline (m); L is the total length of the gas
The electrical heat-tracing technology and hot-water-trac-
gathering pipeline (m); / is the correction coefficient for
ing technology are both feasible for inhibiting hydrate
the electrical heat-tracing band; k is the heat transfer co-
formation as indicated above, but it is necessary to have a
efficient of the gas gathering pipeline, W (m °C)-1; d is the
further comparison and selection for saving the operating
wall thickness of the gas gathering pipeline (m); xe is the
costs and investment.
electrovalence, $ (kw h)-1; Mg is the mass flow rate of
the gas gathering pipeline, kg h-1; cg is the specific heat of
Investment
the gas, J (kg °C)-1; g is the efficiency of electrical heat
tracing (%); xr1 is the maintenance cost per unit length
Electrical heat tracing provide stable electric heating to the
($ m-1); t is the operating temperature (°C); tc is the cri-
gas gathering pipeline with the aid of a surface power
tical temperature for hydrate formation (°C); t0 is the soil
supply and distribution system (Brazil et al. 2013; Liu et al.
temperature of the buried pipeline (°C).
2000). Thus:
Except for the daily maintenance costs, heat consump-
It ¼ L  /  Ue þ Ps þ El þ Ec ð17Þ tion accounts for most of the operating costs in the hot-
where It is the total investment ($); L is the total length of water-tracing technology (Liu et al. 2013; Cheng et al.
gas gathering pipeline (m); / is the correction coefficient 2013). So the following calculation model established by
for the electrical heat-tracing band; Ue is the price of the heat transfer is used:
electrical heat-tracing band ($ m-1); Ps is the cost of the Mg cg dðtw2  tc Þ þ kpDLðt  t0 Þ
Pc ¼ ½xg cg Tðtw2  tw1 Þ
power supply ($); El is the labor cost ($); Ec is the cost of cw dqgðtw2  tÞ
the installation and trial run ($). þ 3600  xw Tqg þ L  w  xr2 ð20Þ
In contrast, the hot-water-tracing technology provides
heating by laying parallel pipelines, and the water in the where Pc is the total operating cost ($); T is the heat-
pipeline is circulation heating (Liu et al. 2012). tracing cycle (h); D is the external diameter of the gas
gathering pipeline (m); L is the total length of the gas
It ¼ L  w  Up þ Vg þ El þ Ec ð18Þ gathering pipeline (m); w is the correction coefficient for
where It is the total investment ($); L is the total length of the circulation heating pipeline; k is heat transfer coeffi-
gas gathering pipeline (m); w is the correction coefficient cient of the gas gathering pipeline, W (m °C)-1; d is wall
for the circulation heating pipeline; Up is the price of thickness of the gas gathering pipeline (m); q is the
heating the pipeline ($ m-1); Vg is the price of the valves calorific value of gas (kJ Nm-3); xg is the price of gas, $/
and accessories ($); El is the labor cost ($); and Ec is the Nm3; Mg is the mass flow rate of the gas gathering pipeline,
cost of installation and trial run ($). kg/h; cg is the specific heat of the gas, J (kg °C)-1; cw is
the specific heat of the water, J (kg °C)-1; g is the effi-
Operating costs ciency of gas (%); xw is the price of tracing hot water, $/
kg; xr2 is the maintenance cost per unit length, $/m; t is the
Except for daily maintenance, electric energy consumption operating temperature (°C); tc is the critical temperature of
accounts for most of the operating costs in the electrical hydrate formation (°C); t0 is the soil temperature of the
heat-tracing technology (Thomas and Baen 2000; Huang buried pipeline (°C); tw1 is the temperature of the tracing
et al. 2012). So the calculation model is established. water before heating (°C); and tw2 is the temperature of the
tracing water after heating (°C).
pDLðt  t0 ÞkTxe Mg cg ðt  tc ÞTxe
Pc ¼ þ þ L  /  xr1 Table 2 compares the investment and operation costs for
gd g
the two gas hydrates inhibiting technologies, i.e., electrical
ð19Þ heat tracing and hot-water tracing in terms of materials,

Table 2 Comparison of investment and operation costs of gas hydrates inhibiting technologies
Inhibiting technologies Investment ($) Operation cost ($/a)
Materials Installation Labor Total Energy consumption Maintenance Total

Electrical heat tracing 3799.5 1864.7 481.5 6145.7 6627.7 198.9 6826.6
Hot-water tracing 2230.5 2221.9 222.7 4675.1 55,956.3 652.0 56,608.3

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installation, labor, energy consumption and maintenance the gas gathering pressure is also decreased. By reducing
under the same pipeline conditions as mentioned above. investment and operation costs, the safety of the trans-
The heat-tracing cycle was calculated as 200 days per year. portation system can be improved, and the surface process
This reveals that the electrical heat-tracing technology can be simplified. Furthermore, the downhole throttle
needs high investment, 1.3 times higher than the hot-water- technology has better applicability to a gas well with a
tracing technology, but its operation cost is lower, about higher wellhead pressure and a lower liquid production
1/8 of the latter. The need for extra time which is equal to capacity.
the costs saved over the investment period can be defined The parameters for two typical gas wells before and
as an additional investment return period (Munoz et al. after throttling are shown in Table 3, and those parameters
2009; Beal et al. 2012; Zambujal-Oliveira 2013), and the with which wellbore temperatures and pressure distribu-
method for determining this period can be established us- tions are compared are shown in Fig. 2. These provenly
ing the following equation: reveal that the downhole throttle technology can effectively
Tp ¼ ½lg C  lgðC  K  iÞ= lgð1 þ iÞ ð21Þ prevent the formation of gas hydrates. This is also benefi-
cial for maintaining the safety of downhole operations and
where Tp is the additional investment return period, a; C is reducing the wellhead pressure.
the years of operational cost saving ($); K is the investment
difference ($); i is the annual interest rate, 0.75 %.
Simplification and optimization of gas gathering
As indicated above, Tp = 0.03 can be calculated from
process
Table 2. This demonstrates that the investment difference
between electrical heat tracing and hot-water tracing could
Simplified gas gathering processes have been widely ap-
be balanced in 0.03 years or about 11 days, while the
plied in the Xushen gas field in recent years. They include
comparison results reveal that the electrical heat-tracing
rotation metering, differential pressure gathering and
technology has better economic benefits than hot water in
transportation and centralized disposal (Chase et al. 1988;
the process of inhibiting gas hydrates.
Fu and Chao 2011). Among them, differential pressure
gathering and transportation produce gas and heat exchange
Optimization of production process and operation under higher pressure and separate, meter and dehydrate gas
parameters under moderate pressure. The centralized disposal system
brings together the processes of heat exchange, separation
Downhole throttle technology and dehydration, as shown in Fig. 3. Simplification and
optimization of the gas gathering process is significant for
During the development of a high-pressure and low-pro- the surface and subsurface integration in the development of
duction gas field, formation of gas hydrates, pressure a high-pressure and low-production gas field.
fluctuations and temperature drop caused by throttle are
all challenges to the traditional technology of pressure Simplification of pipeline network layout
control valves. The downhole throttle technology has
gradually come to maturity and will be of great advantage Single gas wells connected to a station is the traditional
for surface and subsurface integration (Wang et al. 2013a; process for gathering gas. The layout of the connections is
Wu et al. 2005). This technology realizes the effect of limited by gas well locations, and the level of investment in
throttling and pressure dropping through the installation the pipeline network is noticeable.
of a choke downhole. After throttling the gas using this Simplification of the pipeline network layout and
technology, heat can be preserved as reservoir energy, the economizing on the length of the gas gathering pipeline are
formation temperature of the gas hydrates is reduced, and efficient ways to reduce the investment costs. An example

Table 3 Production parameters of gas well before and after downhole throttling
Well Before downhole throttling After downhole throttling
Oil Gas production Water Temperature Oil Gas production Water Temperature
pressure (m3 d-1) production (°C) pressure (m3 d-1) production (°C)
(psi) (m3 d-1) (psi) (m3 d-1)

Xs-209 2001 4.80 4.20 20.3 798 3.60 1.50 17.1


Xs-104 3814 10.30 1.60 21.6 2233 9.60 1.30 18.8
Average 2908 7.55 2.90 20.9 1523 6.60 1.40 18.4

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Fig. 4 Example of pipeline network layout simplification

Fig. 2 Wellbore temperature and pressure distribution before and


after downhole throttling
with a tandem type meets the design of a gas gathering
pipeline, and a band with a parallel type is used in the
of simplification case for a detailed pipeline network layout station design, as shown in Fig. 6.
is illustrated in Fig. 4. Traditional designs for managing electrical heat tracing
use a centralized control. This means that each process area
Integration of production facility has one or two control points for managing the operation of
the electrical heat-tracing band. The statistical data from
Compared with the traditional method of block design and the gas gathering station power load show that the energy
installation in situ, the integration method has desirable consumption for the electrical heat band accounts for 50 %
advantages for industrial production. The various process- of the total. However, such a control method has short-
ing units including the inlet valve block, heating furnace, comings, especially when several gas wells are shut-in as it
production valve block, separator and metering valve block would cause other electrical heat bands to join into the no-
are each modularized and prefabricated into a skid- load run. Electricity would be wasted, and the service life
mounted equipment (see Fig. 5). So the surface process of the pipeline coatings, insulation layers and bands
layout is simplified to enable savings in the area occupied weakened. To improve this situation, some necessary op-
and the level of investment. The management and main- timization methods should be carried out. On the one hand,
tenance levels are also increased. the control of each well should be guaranteed, the rule that
each control point should be responsible for one well only
Electrical heat tracing and freeze-proofing technology should be followed and each loop in the pipeline should be
set at a different operating temperature. Spontaneously, one
Electrical heat tracing and freeze-proofing technology are multiloop distribution box should be set up in every pro-
efficient for inhibiting the formation of gas hydrates as cess area and several loops separated out for controlling the
indicated above. Generally, an electrical heat-tracing band band of each well. On the other hand, the installation

Fig. 3 Schematic illustration of


gas gathering process

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Fig. 5 Integration of
production facility

Fig. 6 Structure of electrical


heat-tracing bands

location of the temperature sensor probe should be opti- tracing band to realize accurate monitoring and control of
mized. The temperature measurement on gathering pipeli- the temperature data. Furthermore, the layout method of
nes can be canceled, and the temperatures registered in the the electrical heat band should involve the thermal char-
inlet valve block. In the station, a temperature sensor probe acteristics of a Christmas tree, meters, valves and
can be installed on the initial and terminal ends of the heat- separators.

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Optimization of separation and dehydration gathering system to the dew point is investigated. From
systems Fig. 8, it can be seen that dehydration effect deteriorated
when the disposal capacity decreased. It can be deduced
A cyclone separator which belongs to the first stage of that the dehydration device is operating in conditions of
separation is widely used for removing droplets above ultra-low load, leading to low velocity of gas in the de-
5 lm (Hreiz et al. 2014). But when coalesce is plugged by hydration tower, and the dispersity of lean glycol is
the impurity from the gas, the natural gas would channel weakened, while the dew point rises spontaneously. Fur-
into the second stage because of its structural limitations thermore, the quantity of triethylene glycol circulating is
and the separation effect deteriorates. As shown in Fig. 7, a decreased with the drop in the operating pressure, which is
division plate is installed on the fluid cylinder to improve responsible for the undesirable dehydration effect. In this
the effect of separation. Then, the two cyclone separation experimental investigation, the dew point is above -10 °C
parts are mutually independent, the channel is prevented when the operating pressure is lower than 725 psi. So it is
and the separation effect is improved. After optimized, the available to enhance the operating pressure by means of the
effect of droplet separation is enhanced by seven percent- pressure control valve which is installed on the exit of the
age points, and the separation efficiency achieved up to dehydration device. The design of defoaming process be-
97.05 % in production practices. fore separating can play a role in reducing the dehydration
When the operating of the dehydration process is un- load, preventing the losses of triethylene glycol and
stable, the dew point of natural gas would rise, and the avoiding foaming in the dehydration tower. Again, mea-
transportation safety will be under threat. Taking one block sures for injecting the pH regulator to revive the triethylene
of Xushen gas field as an example, the influence of the glycol also contribute to promoting the production of a
disposal capacity and operation pressure on the gas high-pressure and low-production gas field.

Anti-corrosion measure

According to Lee et al. (2015), Cl- ion concentration can


be used to estimate the mixing of seawater in cavern

15

10

5
Dew point( )

0
35 50 65 80 95 110 125 140
-5 Daily dispoal capacity(×104 m3 )

-10

-15

-20
dispoal capacity

Operation pressure(psi)
490 540 590 640 690 740 790
0

-5
Dew point( )

-10

-15
operation pressure

Fig. 7 Optimization of separator structure Fig. 8 Influence of dehydration parameters on dew point

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5900 Environ Earth Sci (2015) 73:5891–5904

Fig. 9 Corrosion condition of


facilities

Several targeted field practices are carried out to prevent


corrosion. In high-pressure and normal-temperature areas
(e.g., 2900–3625 psi, \30 °C) in which the pipeline ex-
tends from the wellhead to the station, the differential
pressure of CO2 is 2.9–29 psi, 20 carbon steels are still
selected for the pipeline, but the wall thickness is intensi-
fied by 1–2 mm, and an anti-corrosive agent is injected into
it. During this process, the inhibition efficiency of corro-
sion is above 80 %, and the corrosion rate is controlled to
below 0.02 mm a-1. When the differential pressure of CO2
Fig. 10 Energy spectrum of corrosion product is above 29 psi, the steel pipeline must be exchanged with
a 316-L corrosion-resistant material. As shown in Fig. 11,
the corrosion will be effectively relieved.
seepage water and assess the seawater intrusion into un- In a high-pressure and high-temperature area (e.g.,
derground oil storage cavern. A natural gas gathering 2900–3625 psi, 50 °C) in which the pipeline extends from
system always encounters the challenge of corrosion. If the the heating furnace to the outlet throttle valve, except for
causes of this corrosion are CO2 from the gas and Cl- in areas where the corrosion rate of CO2 has reached its
the produced water, then the safety and operational costs of maximum value, the corrosion resulting from Cl- cannot
the field will be seriously affected. The corrosion due to be ignored at this moment. So, the use of comprehensive
CO2 is influenced by temperature, differential pressure and and effective methods should be taken into consideration in
material quality. However, the solubility of CO2, which this situation.
depends on pressure, is the key to the corrosion. As Huq
et al. (2014) presented, dissolution of alkali feldspar might Selection of defoaming agent
be promoted by the lowering of pH due to the formation of
carbonic acid in the presence of high CO2 partial pressure. Foam drainage gas recovery consists of a combination of
The primarily mechanism of corrosion is electrochemical foaming, dispersing, friction-reducing and deterging effects
which results from the physicochemical reaction between in one process (Li et al. 2005). When a foaming agent is
CO2 and metallic matrix. These factors may cause a injected into the wellbore, it will mix with the liquid which
mitigation or promotion effect on the corrosion through had already accumulated. After agitating by natural gas flow,
their action on the formation of the corrosion product a large amount of low-density hydrous foam is produced. By
(Fatah and Ismail 2011). means of this process, liquid density and slippage loss along
Analyzing the corrosion conditions of the facilities from the wall of the production tubing would be reduced, and the
the Xushen gas field, it was revealed that corrosive pitting, vertical lifting capacity of the gas flow could be increased.
which would cause crippling, is the main pattern. As shown Therefore, the productivity of a water-producing gas well
in Fig. 9, it is fatally destructive to metals, whose products can be improved. In this study, however, difficulties emerged
are soft and easy to strip. The black corrosion product on after performing the process of foam drainage gas recovery.
the surface is FeCO3, as shown in Fig. 10, whose elemental The separation effect of natural gas and water was weakened.
composition includes Fe, O, Ca, Cl and Na, and the amount Especially during the operation of the dehydration process,
of Fe, O and Ca is much higher. when challenges from the crystallization in the high-salinity

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Environ Earth Sci (2015) 73:5891–5904 5901

Fig. 11 Corrosion conditions


of test blocks in gas gathering
system

foaming water were encountered. Therefore, the selection of cores. The results indicate that water quality had a sig-
a defoaming agent plays an important role in the develop- nificant improvement with the intensity of the disposal.
ment of a gas field. When the oil content shows little change, suspended solid
The experimental results indicate that the process in which content is lower than 3 mg L-1 and median diameter is less
organic silicon combines with polyether at a volume ratio of than 2 lm, core permeability will reduce negligibly with
3:2, adding an essential addictive, plays a favorable role in increasing volume of the re-injected water (see Fig. 12).
defoaming technology in the development of a high-pressure
and low-production gas field. It offers favorable com- Prediction of invalid re-injection ability
patibleness with a corrosion inhibitor, antifreezer (methanol),
dehydrant (triethylene glycol) and decarburizer (methyl- As Wang et al. (2013b), resistance coefficient parameter is
diethanolamine). Furthermore, it is well known that low introduced by the equation:
temperature and high concentration of foam can improve the
kp Kp =lp
foaming velocity while high temperature and high concen- RF ¼ ¼ ð22Þ
tration of the defoaming agent can save the defoaming time, kc Kc =lc
so the best time for defoaming is late in the foaming process. According to the published relevant literatures (Al-
Rumhy and Kalam 1996; Zhong et al. 2013), it is assumed
Treatment to the produced water that the length of porous medium and velocity of flow are
constants. Hence,
Gas fields with water-producing wells have the following
DPp
properties: dispersed well location, poor water quality and RF ¼ ð23Þ
DPc
uneven distribution of wells. Combination of pipeline and
tank truck transport, re-injection and discharge are the In the two formulas, RF is the resistance coefficient;
basic treatment for the produced water. DPp the re-injection pressure of the produced water, psi;
DPc the injection pressure of clear water, psi.
Evaluation of re-injection ability Then, according to the evaluation results of re-injection
ability into cores from the pilot well, the constraint pa-
Four kinds of water (I, II, III, IV) were obtained after un- rameters of injection velocity and pressure are considered,
dergoing different disposal methods, including physical and the field injection threshold pressure (2030 psi) and the
sedimentation, filter, chemical flocculation and steriliza- maximum allowable wellhead injection pressure (3625 psi)
tion. The properties of the produced water after disposal were defined. So, the maximum resistance coefficient can
are given in Table 4. Subsequently, experiments were be determined as being below 1.8, and the variation of
carried out to re-inject the disposed water into natural injection volume with the resistance coefficient in the

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5902 Environ Earth Sci (2015) 73:5891–5904

Table 4 Properties of produced Kinds of water Oil content (mg L-1) Suspended solid content (mg L-1) Median diameter (lm)
water after undergoing different
disposal methods I 3.578 15.031 4.12
II 0.894 6.527 3.61
III 0.560 3.291 2.08
IV 0.308 1.004 0.75

0.15 2500
water water
2

Re-injection pressure(psi)
Effective permeability(×10 μm

water water 2300


0.12
-3

2100
0.09
1900

0.06
1700

0.03 1500
0 50 100 150 200 250

0.00 Re-injection rate(m3 /d)


0 5 10 15 20
Pore volume of cumulative injection Fig. 13 Injection index curve of pilot well for re-injection

Fig. 12 Relation between permeability and re-injection volume


re-injection cycles are significantly prolonged with dis-
Table 5 Prediction of invalid re-injection ability of the disposed posal intensity. This result is in agreement with the stable
water water injectivity of the pilot well (see Fig. 13).
Kinds of re- Maximum re- Injection Re-
injection injection volume allocation rate injection
water (m3) (m3 d-1) cycle (d) Conclusions
I 21,354 60 356
30 712
1. Although the consumption of energy from renewable
energy sources is showing a higher growth rate, hy-
II 37,370 60 623
drocarbons will remain the basis of the world’s energy
30 1246
source over the next 30 years. As a clean energy,
III 48,047 60 800
natural gas will be applied extensively in the energy
30 1600
consumption structure. It is important to take advan-
IV 53,385 60 890
tage of the role of surface and subsurface integration,
so that the efficient development of gas reservoirs will
be promoted.
process of re-injection can be established as indicated 2. Taking a high-pressure and low-production field of the
above. Xushen gas field as an example, the analytical method
When the pore volume of re-injection unit is considered, of hydraulic and thermal characteristics is established,
the following expression by Hosseini and Nicot (2012) and and the formation limits of gas hydrates determined.
Al-Homadhi (2013) is used: By comparing the magnitude of investment and
operational costs for two inhibiting technologies (i.e.,
Q ¼ pR2 h/Swc ð24Þ
electrical heat-tracing and hot-water tracing), electrical
where Q is the pore volume of the re-injection unit (m3); R heat-tracing technology has finally been selected as the
is the effective radius of re-injection (m); h is the perfo- most economical process of gas hydrate inhibition.
rated gas reservoir thickness (m); / is the porosity (%); and 3. The downhole throttle technology has a significant role
Swc is the water saturation (%). in the development of a high-pressure and low-
The invalid re-injection ability for the different kinds of production gas field. It contributes to the inhibiting
disposed water can be predicted, and the results for a of hydrate formation, simplifying surface processes
typical gas well in the field are given in Table 5. This and reducing operational and investment costs. Sim-
indicates that, with a constant injection allocation rate, the plification of pipeline network layout, integration of

123
Environ Earth Sci (2015) 73:5891–5904 5903

the production facility and optimization of the separa- experimental data to a reference geochemical model. Environ
tor structure are all beneficial to the running of the gas Earth Sci 67:563–572
Fatah MC, Ismail MC (2011) Empirical equation of CO2 corrosion
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Acknowledgments This work presented in this paper was finan- 2:172–184
cially supported by the National Natural Science Funds for Young Hreiz R, Lainé R, Wu J, Lemaitre C, Gentric C, Fünfschilling D
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