Printing date 18.06.2008 Version: 1 Revision: 18.08.2008 Meneses - Product details Trade name DMD-40 ~ Article number: 205430 - Application of the substance / the preparation Fuel additive -Manufacturer/Supplier: IMCD Benelux 8.V. Withelminaplein 32 - 3072 DE Rotterdam - The Netherlands Phone: +31 10 290 86 00 - Fax: +31 10.290 86 11 IMCD Benelux B.V. Waterstreat 5 - 7201 HM Zutphen - The Netherlands Phone: +31 575 58 58 90 - Fax: +31 575 51 54 96 IMCD Benelux B.V. Hardwareweg 2k - 3821 BM Amersfoort - The Netherlands Phone: +31 33 456 04 65 - Fax: +31 33 456 08 42 IMCD Benelux NV. Industrieterrein Noord A Biarenberglaan 21 - 2800 Mechelen - Belgium Phone: +32 15 29 49 50 - Fax: +32 15 29.49 99 - Informing department: Quality Department : sds@imedgroup.com - Emergency information: +32(0)479 99 20 77 (24h) pee ones - Hazard designation: | Xn Harmful gj N. Dangerous for the environment = Information pertaining to particular dangers for man and environment The product has to be labelled due to the calculation procedure of the "General Classification guideline for preparations of the EU" in the latest valid version Has a narcotizing effect. R22 Harmful if swallowed R 36/36 Inritating to eyes and skin R40 Limited evidence of a carcinogenic effect. R43_ May cause sensitisation by skin contact. R 51/83 Toxic to aquatic organisms, may cause long-term adverse effects in the aquatic environment. R65 Harmful: may cause lung damage if swallowed R67 Vapours may cause drowsiness and dizziness. Additional information: Inhalation of aerosol spray may damage health 3. Composition/information on ingredients - Chemical characterization - Description: Mixture consisting of the following components, Dangerous components: [cas earaz-9a5 |SoWvent naphtha (peiroteum), heavy arom. 300% EINECS: 265-198-5 BQ Xn, RIN; R51/53-65-66-67 Indexnumber: 649-424-00-3 CAS: 94-81-7 'a,c°-propylenedinitriiodi-o-cresol EINECS: 202-374-2 bel Xn. Xi: R 22-36/38-43-52/53 (Coad on page 2)Printing date 18.06.2008 Version: 1 Revision: 18.06.2008 Trade name DMD-40 i (Conte. of pape 1 CAS: 95-63-6 7.2.4-tiimethylbenzene 15% EINECS: 202-436-9 (Be Xn, BB Xi, EN; R 10-20-36 /37/98-561/53 [__Indexnumber: 601-043-00-3 CAS: 97-20-3 EINECS: 202-049-5 | Care. Cat. 3; 8] Xn, ff] N; R 22-40-50/53 Indexnurber: 601-052-00-2| “Additional information For tha wording of the listed rick phrases refer fo Se 13% on 16, ~ General information Instantly remove any clothing soiled by the product. ‘Symptoms of poisoning may even occur after several hours; therefore medical observation for at least 48 hours after the accident. - After inhalation ‘Supply fresh air or oxygen; call for doctor. IFnot breathing, give erifcial respiration, ‘Administer oxygen in case of breathing diffcuttes. WARNING: It may be hazardous to the person providing aid to give mouth-to-mouth resuscitation when the inhaled material is toxic, infectious or corrosive. In case of unconsciousness bring patient into stable side position for transpor. After skin contact Instantly wash with water and soap end rinse thoroughly, Call a doctor immediately, Wash contaminated and soaked clothes before reuse. Clean shoes thorougly before reuse. - After eye contact Check for and remove any contact lenses Rinse opened eye for several minutes under running water. Then consult docter. Keep eyelids well open to rinse the whole eye surface and eyelids with water Continue to rinse the eyes for at least 15 minutes. Continue to bathe eyes during transport to medical practitioner. - After swallowing Remove dentures if any. If conscious, give several small portions of water to drink. Stop if the exposed person feels sick as vomiting may be dangerous Do not induce vomiting unless directed to do so by medical personel. Keep head below hips to prevent aspiration of material into the lungs. It may cause chemical pneumonitis which can be fatal Never give anything by mouth to an unconscious person, Maintain open airway. Loosen tight clothing such as a collar, tie, belt or waistband - Information for doctor -Danger Repeated exposure to an highly toxic material may produce general deteriation of health by an ‘accumulation in one or many human organs fume - Suitable extinguishing agents Fire-extinguishing powder Carbon dioxide (CO2) Water haze Foam -For safety reasons unsuitable extinguishing agents Weter with 2 full waterjet. - Special hazards caused by the material, its products of combustion or flue gases: Can be released in case of fire: (Contd. on page 3)Printing date 18.06.2008 Version: 1 Revision: 18.08.2008 Trade name DMD-40 (Contd. of page 2) Nitrogen oxides (NOx) Carbon monoxide (CO) Carbon dioxide (C02) Under certain fre conditions, traces of other toxic gases cannot be excluded. - Protective equipment: Wear self-contained breathing apparatus. | Weer full protective suit | Additional information Cool endangered containers with water spray jet. | Collect contaminated firefighting water separately. It must not enter drains. Dispose of fire debris and contaminated fire fighting water in accordance with official regulations. | Cea one cone nies | -Person-related safety precaution: Wear protective equipment. Keep unprotected persons away. Avoid contact with the eyes and skin. ‘Avoid inhaling mists and vapours Use breathing protection against the effects of fumes/dust/aerosol Ensure adequate ventilation - Measures for environmental protection: Do not allow to enter drainage system, surface or ground water. Stop leak if possible without risk Prevent from spreading (e.g. by damming-in or oil barriers). Inform respective authorities in case product reaches water or sewage system. - Measures for cleaningicollecting: Absorb with liquid-binding material (sand, diatomite, acid binders, universal binders, sawdust) ‘Send for recovery or disposal in suitable containers. Dispose of the material collected according to regulations. Ensure adequate ventilation - Additional information: | See Section 7 for information on safe handling See Section 8 for information on personel protection equipment. See Section 13 for information on isposel ‘At accidents andior spillage on the public highway or public surroundings, it is compulsory always to notify! warn the authorities concerned (police, firebrigade) about the dangerous properties of the product. Pelee J - Handling - Information for safe handling: Take note of emission threshold, ‘Open and handle container with care. Ensure good ventilation/exhaustion ai the workplace. Avoid formation of aerosols. In case of aerosol formation special protective measures are required (exhausting by suction, respiratory protection), ‘Avoid contact with skin and eyes. Do not breathe vapour. Keep away from heat and direct sunlight. ‘Store in cool, dry place in tightly closed containers. Information about protection against explosions and fires: | Keep ignition sources away - Do not smoke. Protect against electrostatic charges. Storage i - Requirements to be met by storerooms and container: | “Store only in the original container. | Provide floor trough without outlet. (Conta on page #)Printing date 18.06.2008 Version: 4 Revision: 18.06.2008 | Trade name DMD-40 (Conta. of page 3) Prevent any penetration into the ground -Information about storage in one common storage facility: Do not store together with oxidizing and acidic materials. -Further information about storage conditions: Keep container tightly sealed, Dai ce - Additional information about design of technical systems: No further data; see section 7. =Components with critical values that require monitoring at the workplace” 96-63-6 1,2,4-trimethyibenzene ; | WEL | Long-term vaiue: 125 mg/m*, 25 ppm: iv '—Raditional information: The Wats tat were valid during the compilation were used as basis - Personal protective equipment ~ General protective and hygienic measures Keep away from foodstufis, beverages and food. instantly remove any soiled and impregnated garments. | Wash hands during breaks and at the end of the work Avoid coniact with the eyes and skin. Do not inhale gases / fumes / aerosols, Breathing equipment: In case of brief exposure or low pollution use breathing filter apparatus. In case of intensive or longer exposure use breathing apparatus that is independent of circulating air. Recommended filter device for short term use: Filter A - Protection of hand: ‘The glove material has to be impermeable and resistant to the producl/ the substance/ the preparation Due to missing tests no recommendation to the glove material can be given for the product/ the preparation’ the chemical mixture Selection of the glove material on consideration of the penetration times, rates of diffusion and the degradation - Material of gloves Nitrile rubber, NBR Fluorocarbon rubber (Viton) The selection of the suitable gloves does not only depend on the material, but also on further marks of quality and varies from manufacturer to manufacturer. As the product is a preparation of several substances, the resistance of the glove material can not be calculated in advance and has therefore to be checked prior to the application «Penetration time of glove material ‘The exact break-through time has to be found aut by the manufacturer of the protective gloves and has to be observed. - Eye protection: ) Safely glasses Tightly sealed safety glasses. Provide work station with eye bathing equipment. Body protection: Solvent resistant protective clothing (Contd on page 5) |Printing date 18.06.2008 Version: 1 Revision: 18.06.2008, Trade name DMD-40 J (Contd of page 4) |< Limitation and supervision of exposure into the environment Only introduce into water purification plants in diluted state. Fluid Amber coloured Characteristic = Change in condition Melting pointiMelting range: <-29"C Bolling point/Bolling range: _168-195°C -Flash point: 70°C (Pensky Martens CC) Product is not selfigniting. - Danger of explosion: Product is not explosive. However, formation of explosive air/vapor mixtures are possible, ~ Critical values for explosion: 0.6 Vol % 7Vol % |_:Vapour pressure at 20°C: 1hPa -Density at 20°C 0.986 giem* + Solubility in / Miscibility with Not miscible or difficult to mix 3cSt 4.9% - Organic solvents: MUSA uvenencceany = Conditions to be avoided: No decomposition if used according to specifications. - Materials to be avoided: Strong oxidizing agents Strong acids - Dangerous reactions No dangerous reactions known - Dangerous products of decomposition: None | pes HB 41 Toxicological information: -Acute toxicity: = LDILC50 values that are relevant for classification: 64742-94-5 Solvent naphtha (petroleum), heavy arom. rat JLOS0 52000 mark (raty 7 - Dermal |LDS0 > 2000 mgikg (rabbit) | Inhatative| LC50/4 h|>5 mall (rat) | 94-91-7 o,c’-propylenedinitrilodi-o-cresol Oral [LD50_[4560 mark (rat) '95-63-6 1,2,4-trimethylbenzene [Grail [L560 ]>2000 magjkg (rat) (Cason pee)Printing date 18.06.2008 Version: 1 Revision: 18.06.2008 ‘Trade name DMD-40 _{Conts. of page 5) | Inhalative [LC50/4 h [18 mall (rat) |__91-20-3 naphthalene “Oral |LD80-—_ 14200 mglkg (Guinea pig) 316 mglkg (mouse) '490 mgjkg (rat) LDio 400 mgtkg (Dog) | 100 mgikg (Homo Sapiens Sapiens (child)) Dermal |LDS0 — |>2500 mglkg (rat) >20000 mg/kg (rabbit) Inhalative |LC5O/1h |> 340 maf (rat) ~ Primary irritant effect: ~on the skin: Iritant for skin and mucous membranes. ‘on the eye: Irritant effect - Sensitization: Sensitization possible by skin contact. - Additional toxicological inform: Contains material that may cause cancer, according to animal test data. Risk of cancer depend on time and level of exposure. The product shows the following dangers according to the calculation method of the General EC Classification Guidelines for Preparations as issued in the latest version: Harmful Irritant Limited evidence of a carcinogenic effect - Sensitisation May cause sensitisation by skin contact. re Ecological informati - Information about elimination (persistence and degradability): - Other information: Biologically not degradable. -Ecotoxical effects: Aquatic toxicity: pe of test Effective concentration Method Assess! 4-10 mgfl (Daphnia magna) 4-10 mg/l (fish) | 95-63-6 1,2,4-trimethylbenzene | LC80/96h [7.72 mah (fish) | 91-20-3 naphthalene ECSO/8h] 1.6 mall (Daphnia magna) ~ LC50/96h | 1 mail (Daphnie pulex) 1.37-3.8 mall (fish) -General notes: Do not allow product to reach ground water, water bodies or sewage system. Danger to drinking water if even small quantities leak into soil Also poisonous for fish and plankton in water bodies. | Toxic for aquatic organisms (Conta, on pege 7)Printing date 18.06.2008 Version: 4 Revision: 18.08.2008 Trade name DMD~40 (Contd of page 6) ine oes 5 5 Ae - Product: = Recommendation Observe local/state/federal regulations, Must not be disposed of together with household garbage. Do not allow product to reach sewage system, Alter prior treatment product has to be disposed of in an incinerator for hazerdous waste under adherence to the regulations pertaining to the disposal of particularly hazardous waste. - Uncleaned packagings: | -Recommendation: Disposal must be made according to official regulations. Packagings must not be cleaned of reused (dangerous restproduct) and are to be disposed of in the same manner as the product. Wiieae nels | - Land transport ADRIRID and GGVS/GGVE (cross-border/domestic) ath || - ADRIRID-GGVSIE Class: 9 (M6) Miscellaneous dangerous substances and articles. - Kemler Number: 90 | - UN-Numbé 3082 | -Packaging group: il -Label 9 -Designation of goods: 3082 ENVIRONMENTALLY HAZARDOUS SUBSTANCE, LIQUID, N.O.S. (Solvent naphtha (petroleum), heavy arom., 1,2,4-trimethylbenzene) laritime transport IMDG/GGVSea: ath, | |] -tociocvsea cass: 9 | _ -UN Number: 3082 “Label ° | ~ Packaging group: a - EMS Number: FASE ~ Marine pollutant: Yes - Correct technical name: ENVIRONMENTALLY HAZARDOUS SUBSTANCE, LIQUID. N.O.S. Air transport ICAO-TI and IATA-DGR: abn, a -ICAO/IATA Class: 9 “UNIID Number: 3082 - Label 9 | - Packaging group: MW ~ Correct technical name: ENVIRONMENTALLY HAZARDOUS SUBSTANCE, LIQUID, N.O.S. (Solvent naphtha (petroleum), heavy arom., 1,2,4-trimethylbenzene) (Conta. on gage 8)Printing date 18.06.2008 Version: 1 Revision: 18.08.2008 Trade name DMD-40 (Contd of page 7) cue nce - Designation according to EC guideline: The product has been classified and labelled in accordance with EC Directives / Ordinance on Hazardous Materials (GefStoffV) - Code letter and hazard designation of product: . Xn Harmfut a NN. Dangerous for the environment - Hazard-determining components of labelling: .a’-propylenedinitrilodi-o-cresol Raphthalene ~ Risk phrases: 22 ‘Harmful if swallowed, 36/38 Irritating to eyes and skin. 40 Limited evidence of a carcinogenic effect. 43 May cause sensitisation by skin contact. 51/53 Toxic to aquatic organisms, may cause long-term adverse effects in the aquatic environment. 65. Harmful: may cause lung damage if swallowed. 67 Vapours may cause drowsiness and dizziness. - Safety phrases: 36/97 Wear suitable protective clothing and gloves. 61 Avoid release to the environment. Refer to special instructionsisafely data sheets. - National regulations | ~Technical instructions (air): ae in% NK eee ‘These data are based on our present knowledge. However, they shall not constitute a guarantee for any specific product features and shall not establish a legally valid contractual relationship. - Relevant R-phrases 10 Flammable. 20 Harmful by inhalation. 22 Harmful if swellowed. 36/37/98 Irritating to eyes, respiratory system and skin 36/38 Iritating to eyes and skin. 40 Limited evidence of a carcinogenic effect, 43 May cause sensitisation by skin contact 50/53 Very toxic to aquatic organisms, may cause long-term adverse effects in the aquatic environment. 51/53 Toxic to aquatic organisms, may cause long-term adverse effects in the aquatic environment. 52/53 Harmful to aquatic organisms, may cause long-term adverse effects in the aquatic environment. 65 Harmful: may cause lung damage if swallowed. 66 Repeated exposure may cause skin dryness or cracking. 67 —_Vapours may cause drowsiness and dizziness. - Department issuing data specification sheet: Quality Department