9. Coordination Compounds EXERCISE Question - Answer Chemistry (eoww tiwariacademy.com) (Chapter 9)(Coordination compounds) *** xi ‘Question 9: Explain the Bonding In coordination compounds in terms of Wemer’s postiates. ‘answer ‘Wiemer’s postulates explain the Bonding in coordination compounds 2s follows: (1) Ametalextibits two types of volencies namely, primary and secondary valecie Primary valencies are satisied by negative ions while secondary valences a1 ‘sisted by both negative and neutral ons (in modern termincogy, the primary valency corresponds tothe oxation number of tr ‘mata on, whereas the secondary valoncy refers tothe coordination number ofthe met (8) Arve on hs» atte muro secondary vlc wun he can wot) ‘Also, these valencis project ina sped direction nthe space assigned tothe dent geometry of the coraination compound (4) Primary valencles are usualy cnzable, whe Secondary valences are non~ionzabe, Question 9.2 FS soldion mixed wth (W.):S0s solution in 1:1 moar ri ves he testo Fein bt cuSOe scion mic with aqueous ammonia in 1:4 molar ato doesnt ve thetest fC". Eeain wy? Aosmer (Nt,),50, + FeS0, 64,0 —+FeS0, (NH), $0,-611,0 Motes 6180, +4NH, 51,0 —+[Cu(MH) J80, 5840 teraamminccoppe( i) pate FeSO, (NH,),S0, 61,0, [Ca(NH),]80,-s11,0 Bath the compouns i, $9 an ‘ou under the category a adlton compounds with enly ene major diference Le, the former ‘5 an example of couble sale, whe the latter i @cooreinaton compound. ‘Acouble ste i an adason compound that stable in the soli state Bu hat which breaks ‘Up into ts constituent fons inthe cissoved sate. These cmpounes exhibit9. Coordination Compounds EXERCISE Question - Answer 4 Chemistry (wow. tiwariacademy.com) (Chapter 9)(Coordination compounds) xi Inciviuat properties of their constituents. Far e.g. F&504"(NH,),S0,-6H0, Fe, Ne and S00. Hence, ves # postive et for Fe ons | ccordination compoune ian adton compound which ean ts tty nthe sodas vel a inthe csv tate. However, the idol properties ofthe constituents [ca(nt,)]s0,-s1,0 breaks into are lost This happens because oes aot show the test for Cu ne tone present in the (CHlNH),J80.8140,. [eu(NH).)" 80," Shion of Explain wth two examples exch fhe flowing: coriation erty, and ccordnaton -_l))) number, condnaten pete, help od hte = {coordination ey: Acomdaton ety on decay ged rte spes cing poste o ncjotte chen cnnation enty, tent stam or an seat © tater te mateo nse e(ald ged) Fr rae: [i007 [FCN] econ trcip. [asten),] [Ni(Co),]. feo(t),cL] = anionic complex = neutral complex (0) Uganes ‘The neutral molecules or negatively charged fons that surround the metal atom in a ‘coordination entity ora coorinal complex are known a ligands. For example, NH 120 cx, -on. Ligands are usualy polar in nature and possess atleast one ‘unshared par of valence electrons (it) Coordination number:9. Coordination Compounds EXERCISE Question - Answer Chemistry (eco tiwariacademy.com) (Chapter 9)(Coordination compounds) xi “Tne total numberof igands (ether neutral molacules or nagative ions) that get atached ‘tw the central metal atom inthe coordination sphere is calle the coordination number of ‘the central metal atom, Iti also referred to as its igancy. For example: {@) Inthe complex, Ks[Ptle, there as sx chloride ions attached to tin the coordinate ‘phere. Therefore, the coordination number of Pi 6. (8) Simaty, inthe complex [Ni(Hs}]C, the coordination numberof the central ‘tor (ws (vi) Coordination polyhedron: Cocrdination polyhedrons about the central atom can be defined as the spatial ‘errengement ofthe ligands that ore directly attaches to the central metal ion in the ‘oorcination sphere. For example: (¥) Homoteptic complex “These are those complexes in which the metal lon is Boune to only one kind of @ donor ‘group. For eg: [COCNM)] [CLP a (ul) Heteroleptic complexes:9. Coordination Compounds EXERCISE Question - Answer Chemistry Cooww,tiwariacademy.com) (Chapter 9)(Coordination compounds) xil eterolepticcompaxes ae those complexes where the central metal ion is bound te more than one typeof a donor group. For eg.: [COUNH), C1] «[Co(nt,), cr)” Question 9.4 let is meant by unidertate,eidentate anc ambidentate iganct? Give two examples for [Aigané may contain one or more unshares pairs of electrons which are called the conor ‘ites of igands. Now, depending on the number ofthese donor sites, ligands can be asses a8 fllons: {@) Unidentate ligand: Ligands with only one donor sites are calle unidentate Naands. Foreg., NMS, crete. (@) Didentate igands: Ligands that have two donor sites recalled aidentate hgands. Fores, (@) Ethane, 2-tiamine non, ako 0) ontaan ee (© Ante toe Uw co ta ere ce ml aon rh rt oe seca ensue ar fe pe o9. Coordination Compounds EXERCISE Question - Answer 6 Chemistry (woww tiwariacademy.com) (Chapter 9)(Coordination compounds) xi tn oor toma CDH 0 ewe Cine or stom onsen) © ne (the enor some) QBs — betes (The donor atom is) (question 9.5: ‘Specity the axdation numbers ofthe metal inthe flowing coordination entities: © (euaeon ence?” (49 teasexensr (eA (KAKO oo te00ms.241 eo [£2tH,V(EN)on) Let he xitaon number of Co be Te charge on the compris +2. [eo (#0) (en) (en),]” + so 4 re OF) +3 22 fetes re on Onl Lat the oxidation numberof Pt be x ‘Te enarge onthe complex is 29. Coordination Compounds EXERCISE Question - Answer Chemistry ‘(ervow tiwariacademy.com) (Chapter 9)(Coordination compounds) xi (i) [eo (ae), (eo) beg x +24) + 20)=41 so2e4l x43 on BFE] te[Fe (cx).) () [er (NH), 4] baod +30) +30 Question 9.6 Using 1UPAC norms waite the formulas forthe folowing: (0) Tetranyeronocineate(a) (U) Potassium ttraclondopaiaate(t) (Gi) Diamminecienlereoplatnum(a) (iu). Potassium ttracyanonickalate()9. Coordination Compounds EXERCISE Question - Answer Chemistry ‘(eeww.tiwarlacademy.com) (Chapter 9)(Coordination compounds) xi (0) Pentaarminentte-o-cobatit) (1) Hexaamminecoban() suipate (al) Potassium tr(oxalato)eromate( tt) {ul Hexaamminepltinumav) (00) Teteabromidocuprate(t) ()Pentaamminentrto-N-cobat at) ) (2o(oKP- a) theo) (G,(Preur) 1 ey) atracene) (2) (Co(ONO) (wH)s7* (oa) [Cowspls (S00). (at) 6f0C20.)3) ay (Peery (6 (Cul@na™ (4) (CaINOS}(NHYEF* Question 9.7: Using TUPAC norms writ the systematic names ofthe following: 0) co(nwes cts (4) (Puen-creMcrEyIC {G9 (THO}6* Gu) [cott}-CkNO2)}C1 (9 [nc0)69"* (9 (mCP (WA CHENHIEIC (uy (coen)* (0) (NCO) Answer (0) Hexaamminecobatil) cblende9. Coordination Compounds EXERCISE Question - Answer 6 Chemistry ‘(Ceoww,tiwariacademy.com) (Chapter 9)(Coordination compounds) xil (4) Diamminecnlondo(metnyiamine) patium(i)chionge (i) Hexacuataniom@t) ton (iv) Tetraamminichlondonitto-N-Cobat{i) cence (¥)Hexacuamanganese(t) ion (ot) Tetrachorsonickeite( ion (uit) Hexaamminenickel(t) chore {uit Tasfetnane-1, 2- can crete snr 1) [C(C2O4j2)°—9. Coordination Compounds EXERCISE Question - Answer 4 Chemistry ‘(wow tiwariacademy.com) (Chapter 9)(Coordination compounds) xi Question 9.11: Draw all the isomers (geometrical and optical) of (0) {ocisen)I* a) feoqnteycen) {a (Coon -C1(€n))" ‘nower (0) (Coenen9. Coordination Compounds EXERCISE Question - Answer 6 Chemistry (eevew tiwariacademy.com) (Chapter 9)(Coordination compounds) (aC ered i ‘Conapenmpnie rime) In total, thee comers are possible. oi ° rye irk waniutiwariacademecon ‘Free web support in Education9. Coordination Compounds EXERCISE Question - Answer 6 Chemistry Cow, tiwariacademy.com) (Chapter 9)(Coordination compounds) xi ‘Trans-somers are optically inactive. Cisisomers are optically active {a [C00 te eo amet ENC now ay ew son tnt ne trwsxencven 7 ON LONI - nove tcmers, none wil ext optical omer. Tetrahecral complexes rarely show optical isomerization. They do so only inthe presence of unsymmetrical chelating certs.9. Coordination Compounds EXERCISE Question - Answer Chemistry (oeww,.tiwariacademy.com) (Chapter 9)(Coordination compounds) xi uention 933: fauna copper shite ston (i clos gies: (4 ree preciate wth agnou potas te, and (0) beghe green set with aquecus pease chee tiga thee experinena esut never evans CSOs ents a6 [CH(K0})80u It ble n cour due to the presace of {eutheoy tons (9 When xr sates [cufi.o),}" +47 —s[cu(e),J”+n.0 eo) (8) ven ec ae [cut }" 4cr —s feucy f+ 4,0 (beight green) In both these cases, the me el gtd water ela byte Fa Cn Question 9.14: Wat i the cordnaton enty formed when exces of aqueous KCN is added to an aqueous ston of copper sulphate? Why i & that no precintte of copper sulphice ie cbtanes when H:S() pases trough ts luton? Answer 618044) +4KCN,,, — K.[CU(CN), se, [Co(t.0),"+4en" —s [ea(en),]" +480 "Tus, he cordon ety farmed in the proces teen. 2LEMEN Dg very stable complex, which éoes not ionize to give Cu ions when added to water. Hence, Cu fans are not preciptated when HS ls passed through the solution9. Coordination Compounds EXERCISE Question - Answer 6 Chemistry (eowwtiwariacademy.com) (Chapter 9)(Coordination compounds) xi Question 9.15: Discuss the nature of Bonding inthe following coordination entities on the basis of valence bond theory: (Fea (wef a [eoco437- (9 (CoFa™ trea In the above cooréination comp, ion exists in the +l oxidation state, et: Electronic configuration is 38 Oritals (ot Fe on am OOO wwe [As CN ts strong fed Agand, lt causes the paring of the unpaired 3d electrons. ee Oo ‘ince thre ae sx ganes around the central metal on, the most feasible hybrcestion ke 50% 5p! hybridized orttals of Fe are: ae 6 electron pais trom CN ions occupy the sx hybrid esporbtas. Then, GT) ‘om 669. Coordination Compounds EXERCISE Question - Answer 6 Chemistry (eeonw.tiwarlacademy.com) (Chapter 9)(Coordination compounds) xi Hence, the geometry of the complex is cctahedral and the complex i dlamagnetic (35 ‘there ate no unpaired electrons) were In this complex, the oxidation state of Fe is +3. teas of Fe" on: Gam O OO OT) we ® w ‘There are 6 F ions. Thus, it wil undergo 5p or spc hybrtization. As Fis a weak id ligand, t oes nat cause the pairing ofthe electrons inthe 3d orbital. Hence the most Feasible hybeceaton i 23% pane ss a tf i Ton) @ 3 we Hence, the geometry ofthe complox is found tobe octahedra. {a (C0(C2097~ (Cobalt exists inthe +3 oxidation state inthe given complex. Cralate 16 a weak field ligand, Therefore, cannot cause the paring ef the 3¢ orbtal ‘electrons. As there ae 6 ligands, hybridization has tobe ether sp or dsp? hybiaton ‘5p hybritaton of Co9. Coordination Compounds EXERCISE Question - Answer 6 Chemistry (eoww.tiwariacademy.com) (Chapter 9)(Coordination compounds) xi fini) O C1 CLIT) me ‘he eet param the'3 oxen (oat aon sa bette Han) ecipy thee i ta, a) vanes tegen of tree fund bead (9) (C0F CCobat exists in the 43 oxcation state Orbital of Co?” hn: fn) O OO OT) w we w ‘ain, fuoce on is 2 weak fed ligand It cannot cause the paring of the 34 electrons. ‘Asa resi, the Co ion wil undergo sp2a"hybridvation. spi? hybridiza orbitals of Coon are: am) O OO OTM Pe ee ence the geometry ofthe comple is ecahedtal and paramagnetic Question 9.16: ‘raw figure to show the spliting of d orbital in an octahedral crystal9. Coordination Compounds EXERCISE Question - Answer 6 Chemistry (weww.tiwariacademy.com) (Chapter 9)(Coordination compounds) ‘The spting of the d orbtals in an octahedral eld takes pala in such a way that oqxperiance a risen energy ané frm the 61a, wile day cane du experience 3 fattin energy and form thet lve Question 9.17: What is spectrochemical series? Explain the diference between a weak fel ligand and a strong fe gand. | spectrochemical sens isthe arrangement of cameron Ngands in the increasing ore of hie crystal spiting eneray (CFSE) values. The Heands present on the RH-S of the sees are strong flldgands whe that on the LMS are weak flld ligands. ls strong field toands couse higher spiting in the derbitals than weak ted ligands. TH € BF «SP «SCH ¢ Ce NI «F< OH «COE WHO € NCS” WH < EN < NH << on ~S0r™ < NOs" < phen « CO Question 9.18: hat i crystal fed spiting energy? How does the magnitude of de decide the actual configuration of d-orttals in a coordination entity?9. Coordination Compounds EXERCISE Question - Answer Chemistry (eco tiwariacademy.com) (Chapter 9)(Coordination compounds) xi “Tne degenerate drobtals (in a spherical field environment) sit into two levels Le, ‘and ty inthe presence igands. The spiting ofthe degenerate levels cue tothe presence ‘of ligands is called the crysal-ele spitting wile the energy ciflerence between the two levels (ey and a) called the crystl-telesplting energy. Its denote by _Atter the orttals have spl, the fing of the electrons takes pace. Aer 1 electron (each) has been filed inthe three t eras, the fling of the fourth electron takes place two ays. I can enter the ey orbital (iving se to ta? ay ke electronic configuration) oe the ainng ofthe electrons can take place inthe fora (eng Seto ty ike electronic ‘configuration. Ifthe de value of a ligand ists than the paring eneray (P) then the ‘electrons enter theo, orbital. On the other hand, W the value af 2 igané Is more than the pairing eneray(P), then the electrons enter thet rtital. Question 9.19: [crtrs})* is paramagnetic while N(CN)P~ is ciamagnetic, Explain why? ‘Anoner Cris im he +3 oxation state Le, configuration. Abo, Nis s @ weak fea hgand that doesnot cause the pang of the electrons in the 34 ort. CP* gat) O OO OT) ™ sw w “Therfore, it undergoes op? hybritizaton and the electrons inthe 3d orbitals romain unaired. Hence, tis paramagnetic in nature, In (N(CH), M ens inthe +2 oxcation state, configuration. ee mmm 0 OT) 7% (isa strong fled Hgand. It causes the pairing ofthe 3d orbital electrons. Then, Ne undergoes csp? hybnizatin.9. Coordination Compounds EXERCISE Question - Answer Chemistry (eevew tiwariacademy.com) (Chapter 9)(Coordination compounds) xi fbaAO O OT) oP [As thre are no unpre electrons, it is clamacnetc Question 9.20: [solution of [N(H0)s)* Is gran but 2 solution of {N(CN}]~ fs colourless, Explain. an ructooyer, HO a weaktelsigand. Merefore, there are unpaired electrons a M2 Inthis compley, the electrons from the lower ener level can be exced to the higher ‘energy level, the possiblity of d=d transtion is present. Mence,Ni(H:0}," is cloured. In (W(CR), the electrons are all pared as CN is 2 strong fee lgsnd. Theelore, dd transition snot possible in [M(CN)¢P~. Hence, Its eolouess. Question 9.21: UFe(CN)e}* and UFe(Hs0}e}* are of diferent colours in dute solitons. Why? Answer ‘The colour af a portelarcoorination compound depends on the magnitude ofthe crystal fle sping energy, A. This CFSE in turn depends onthe nature ofthe gang. In case ot {Fo(CN)e}- and {Fo(H20}e*, the colour cifers becuse there is a ference the CFSE. om, CN isa strong fildigand having a higher CFSE value as compared to the CFSE value of water. This means that the absorption of eneray forthe Intra ded transition also ters. Hence, the transmit colour ao ier Question 9.22: Discuss the nature of bending in metal carbon Answer ‘The meta-carbon bonds in metal carbonyls have both o anc a characters. A @ bond is formed winen the carbonyl carbon donates 8 lone pair f electrons to the vacant orbital of9. Coordination Compounds EXERCISE Question - Answer Chemistry (Chapter 9)(Coordination compounds) xi terme An bon oma by he donate of pa of eens ram he ed meta Gera to the vacant ston ral a known a EH Dvn oe Caron sou. The © bond Srengten hem and and wce-verse Thus# yer cetec Ic created due to this metal-igand bonding, This synerge effect strengthens the ‘bond between CO andthe metal. Q Same ag el atom question 9.23: Give the oxidation tate, ¢-orital occupation and coordination number ofthe central metal Jon in the foioming complexes: (0) KC0(C204)), (i) ais{er(en).ct}ct (a (we fo.) (v9 DagHioyes04 (0) K{CoC:0031 “Tre central metal fon is Co. Ite coordination number 1s 6, The ‘oxidation state can be given as: ax a3 ‘The d otal occupation for Co™ Is tet (G0 es {erfen.c1c1 ‘The central metal fn is Ce9. Coordination Compounds EXERCISE Question - Answer Chemistry (oewrey siwariacademy,com) (Chapter 9)(Coordination compounds) xi ‘The ccordnation number ie 6. The oxidation state can be given as: e+ 2(0) + 2(-1) « 41 wa Desdee sd ‘The d orttl ocupation for CP 67 up (ney CoFa ‘The central metal ln s Co. ‘Tha oxidation state can be given as: 42 The d ortatal ecupation for Co* I et? {0 [Ht0}150+ ‘The central metal ln eM. ‘The coordination number is 6. The ‘oxidation state can be given as: x + Om s2x= 42 “The d orbital occupation for Mn st? Question 9.24: \Wirte down the IUPAC name foreach ofthe fllowing complexes an¢ indicate the ‘vddation state, electronic configuration and coorcnation number. Also glve stereochemistry and magnetic moment ofthe comple (9 KIcx(:033(6:003}.3440 a (CofnHs} 1c} (cu cxci¢oy)s (iv) catfeci) (9) Kamera) Answer (0) Potassium eiacuadionaatochromate (1) tihyerate,9. Coordination Compounds EXERCISE Question - Answer 6 Chemistry ‘(Conww,tiwariacademy.com) (Chapter 9)(Coordination compounds) xt osten tt oen #3 fcc: 30) Coordination number = 6 ‘Shope: octahedral Stereochemistry: be os te AT CQ oO napa aie = Yon) Magnetic moment,9. Coordination Compounds EXERCISE Question - Answer Chemistry (eeow tiwariacademy.com) (Chapter 9)(Coordination compounds) xi = 3043) W) [co(nee).C}02 TUPAC name: Pentaamminechioncocobalt() odd (uation state of Co = +3 Coordination numbar = 6 Shape octahedral ectronic configuration: ot ‘stereochemistry: “les OS we Mi Magnetic Moment = 0 a) CCHKOWDs TUPAC name: Trichlordotipyriinechromium (1) nication state of chromium = +3, Electronic configuration for d= ti Coordination number = 6 Shape: ‘octahedra ‘stereochemistry:9. Coordination Compounds EXERCISE Question - Answer 6 Chemistry (ooww,tiwariacademy.com) (Chapter 9)(Coordination compounds) Xxil ° ° Le os Beth isomers are optically active. Therofore, a total of 4 isomers exist. rage ove) = 83) =Vi8 (6) CatFect) IUPAC name: i Electronic configuration of = et ‘Shape: tetrahedral Stereochemstry: opteally inactive Magnetic inte) $e) VB ~ oa (0) Ka (CN) Potassium hexacyanomanganate(t) Owieation state of manganese = +2 lectronic configuration: °° Carnation numbar =9. Coordination Compounds EXERCISE Question - Answer Chemistry (wow. tiwariacademy.com) (Chapter 9)(Coordination compounds) xi ‘Streochemistry: optically nacive tagetic ment,» “¥2) = ite) 6 sim aM Question 9.25: ‘nat is meant by stabity of 2 coordination compound i solution? State the factors which ‘gover stabilty of complexes, Answer ‘The stability of» complex in solution refers othe degree of association betwoen the two species invlved ina state of equilibrium. Stabity can be express quantitatively in terms of stability constant or formation constant. Mose ML, silty constant, p= Mt) Sabi 8~ aa For thie reacuon, the greater the value of the stabity constant, the greater ts the proportion of Mis inthe solution. Stabity can be of two types: (2) Thermodynamic stab ‘The extent to which the complex willbe formed or willbe transformed into another species {atthe point of eculrum is determines by thermodynamic stilt. (©) Kinetic stability: This heps in determining the speed with which the transformation will occur to attain the state of equilibrium, Factors that affect the stability of a complex are: (@) Charge on the central metal lon: Thegreater the charge on the central metal io, the greater is the stabity ofthe complex 2. Basic nature ofthe ligand: A more basic lgand wil form a more stable complex.9. Coordination Compounds EXERCISE Question - Answer 6 Chemistry (erww,tiwariacademy.com) (Chapter 9)(Coordination compounds) xi 2. Presence of chelate rings: Chelaton increases the stabity of complexes. question 9.26: hat meat by the cbf eet Give an example oower ‘When gan ataces tothe metal on in manner hat foms 2 ing, then the metal ‘gan axons found tobe more abe Inthe eres, we can say th complexes containing chalatevings are more stable than complnes without ings This sKoown a8 the chelate et. Fer snags Ney FNM, [NN J, lo =799 Ni #363 Nilen),T Question 9.27: Discuss brey giving an example in each case the role of coordination compounds in: (0) icogial system (0) mesiinl chemistry (i) anayticat chemistry () extraction/metaturgy of metals9. Coordination Compounds EXERCISE Question - Answer 6 Chemistry ‘(Ceoww,tiwariacademy.com) (Chapter 9)(Coordination compounds) xil We know that photosynthesis is made possible by the presence o the chlorophyll pigment. “This pigment is 2 coorcination compound of magnesium. Inthe human biological system, Several coordination compounds play important roles. For example, the oxygen-carrier of blood, le, aemoglobin, i coordination compound of ron. (\) Rote of coordination compounds in medicinal chemist Certain coordination compounds of platinum (for example, cisplatin) are used for Inisiting the growth of tumours. (i) Role of coordination compounds in analytical chemistry: During sa analyse, a number of basic racicals are cetecec withthe help of te colour ‘changes they exhib wih diferent reagents. These eslour changes are a result of the ‘ooreinationcompounes or complexes tat the basic raicals form with ferent igands (i) Rote of coordination compounds in extraction or metallurgy of metal: ‘The process of extraction of some ofthe metas trom thelr ores involves the formation of “complexes. For example, i aqueous olution, golé combines with cyanide ions to form [Au(CN)s) From this Slution, olds later extracts by the adcition of zinc metal Question 9.28: ow many lon are procuced from the complex Co(NHs)sl in seution? os aya cay wm? {G) The given complex can be writen as {CO{NHSJaJCls “Thus [Co{NH)]* along with two CI-lons are produced ‘question 9.29: ‘Amongst the fllowing ions which one has the highest magnetic moment value? (0 [x03 (ay (Feo)9. Coordination Compounds EXERCISE Question - Answer 6 Chemistry (wow tiwariacademy.com) (Chapter 9)(Coordination compounds) xi ca tznoionr> Answer (No, of unpaired electrons in {Cr(Hs0}eP* = 3 = Yt) Ten,» (1) No, of unpatred electrons in (Fe(Hs0}]* = 4 ren y AE) (0 No, of unpaired electrons a 2n(HiOV* = 0 Hence, (F(Hs0)s* has the highest magnetic moment valve. Question 9.30: ‘The oxidation numberof cobalt in K{CO{CO)] on as cay ws Answer We know that CO is a neutral ligand and K caries a charge of +3. ‘Therefore, the complex can be written as K*[Co(CO)l". Therefor, the oxidation number of Coin the given complex is =1. Hence, option (a) is correct. question 9.31: ‘Amongst the following, the most stable complex is € (Fege0yeP*9. Coordination Compounds EXERCISE Question - Answer Chemistry (ecorw tiwariacademy.com) (Chapter 9)(Coordination compounds) xi (0) trsn0 (a faC:0557- (9 eo none We know thatthe stability of 9 complex increases by chelation. Therefore, the most ‘stable complex is [Fe(CsO0P* oe sal ae Question 9.32: What will be the correct order for the wavelengths of absorption inthe visible region for te folloning mi(nO.)I, ICME, ERHLOD Aner “The central metal ion in al the thre complexes the same. Therefore, absorption in the sible region depends on the igancs. The order in which the CFSE values ofthe ligands Increases in the spectrochemicl seis isa fotows: Who < Ni < NO “Thus, the amount of crystal-eld spitting observe wil be in the falling orer: agog tran) > tNK(NODII