PIANO Calibration Standards Certifications and Chromatograms Customer : ACCUSTANDARD INC P.O. Number : 260950 Date : 10/22/07 Product ; PIANO NAPHTHENES Lot number: $3600-1PIANO Calibration Standards All chromatograms generate under the following conditions: Detector: Injector: Split Ratio: Column Temperature Program: ‘Sample Size: Varian CP3800 Capillary FID Hetlum Inlet pressure 44 psig (Methane elutes at §.50 min) FID. at Range x 10 “* Temperature at 300 °C Fuel: Hydrogen at 30 comin Oxidart: Air at 300 ecimin Makeup: Helium at 30 cctmin Temperature at 300 °C 450: 4 (vent Flow 6.78 cc/min) ‘Supelco Capillary SPB-1 100m x 0.25 mm 1D (0.5 micron film) Initial temp: 35° Cfor 15min Ramp 1: 1 deg/minto 60 ° C Hold 1: 20 min Ramp 2:2 degimin to 200 ° C Hold 2: 0 min Total Run Time: 130 min Syringe injection Individuals: 0.3 uL plus 0.2 uL Air PIANO mix: 0.4 ul. plus 0.2 ul Air IMPORTANT NOTE: Retention order and times are valid for these conditions only.CERTIFICATION OF MIXTURE TYPE: PIANO NAPHTHENES. To $3600 DATE 102207 PEAK RET LINEAR PEAK NAPHTHENIC WT MOLE% = LV®% — SPGR MOLWT APH 4 TIME INDEX TYPE ‘COMPONENTS 1 1062 $49.9 NS Cyelopentane 4.970% 5.17% 07505 7013 12067 2 M81 ITT NG Methyleyelopentare 3.269% 338% 07536 $4.16 15125 31795 6473. NG Cyclohexane $400) 538% O78 $415 17729 4 1949 561.7 NT 1,-Dimetisleyelopentane 3.483% 358% 0739398819012 S 2078 S73B_N7 _cis.3-Dimethyleyelopertane 0.601% 0.430% 07495 ORR S39 6 2113 S77L_NT — transi.3-Dimethykeyelopertne 2.749% 284% 07537 9818 197.10 7 M147 6803. NT trane-l.2-Dimethylyelopertane 1.46895 15160 07862 RIB 197.35 8 2589 TMA NT Methyleyciohexane suit 3.368% 07740 98:18 204.82 9 27627281 N7_—_Bihyleyelopentane 457505 3% 0770 9RIR 21824 10282) 7292 NB — etel,24-Trimethyleyclopentane 1.673% 1.738% O7SI8 1221-22872 11 YOU 7407 NB — cee 2 3-Trimetiglevelopentane 1 $86 163% 0788) — 1122128040 123429 7663 NB etei2,4Trimethykyelopentane 3.760% 3925% 0768) 11221-24212 13 3812-7714 NR transl dsDimethyleyebherane 3.557% 302% 0767 11221-24693 M3758 7867 NB LhylL-Metiyleydopentine L076 1.070% 0.7854 11221 25074 IS 38OS 7806 N® — trans-,2-Dimetiykycloherase 1.669% 1.671% 07803 11221 254.15 16 39017955 NB ecel.23-Trimethyleyclopentire 0.808% 0.805% 0783511221 253.40 IT 4048 803.1 NB Tssprepylevelopenase 3.511% 3.513% 07808 11221 259.52 18 43438157 NB civ 2Dimethyleyslohoxane 3.73806 3.635% 0800511221 255.51 19 4455 8202 NB — mPropyieyelopeatane 3.677% 3.679% 07808 11221. 257.71 20 M453 8202 NO ceoL3.5Trimothyeyetohexane 3.55896 3goie 0773712628 281.14 21 4613-8268 NI 1.1,4-Tnmethvleyelobexane 3.080% 3.103% 0760 126.23 273.00 22 ARSE BIBI NO ohl.2/-Trimethylyeloherane 3.638% 3557% 07089 12628 286.23 23 S478 8030 NO cle 24-Trimetiyleyetohexene 3.541% 393% 07929 126.28. 298.00, 24 $892 B78 NO 1,12-Trinethyleyechexane 3376 4279% 08% 12623 29480 233993 884.7 NO Isobulylyelopentne 26 56.18 9139 NO Ieopropsleyelohexane 27 69659326 NO nButyleyelopenaze 3.724% 28 79059833 N10 eohuiyleyelohexane 5.630% 07997 14025 34032 29 sas! 9917 NiO Propyleyelohexane 3.289% 08150 14025 350.00 30987511469 NI2_ tl-Methyi2-GMPyyelopeniane 3.795% 2.483% 3.615% 0820015833 40.00, 309% 0783012623 29840 Sov, gna 12628. 31028 07888 12623. 31381 TOTAL 100,000% 100.0008 100,000%%-T.ALN.O. - Naphthenes 18.00PIANO Calibration Standards STANDARD STORAGE Refrigeration is strongly recommended when standards are not in use. Replace worn septa to avoid loss of components. TERMS AND DEFINITIONS PEAK # - An identifying number which corresponds to a numbered peak on the accompanying chromatogram. The elution order is correct for the specified conditions only. RET TIME - Retention time in minutes. Times are valid for the specified conditions only. LINEAR INDEX - A number which indicates the retention of a compound relative to the n-alkanes on a linear scale. ‘The equation used to calculate the Linear Retention Index (LI,) of a compound "AY is given by: = Ma| trineny ~ fro where: tea) = actual xetention time of the compound of interest treo - actual retention time of the n-alkane smaller than tra tian = actual retention time of the n-alkane larger than tray PEAK TYPE - A designation consisting of the first letter of the group name and the carbon number Naphthene) e. N@ indicates a C fpPIANO Calibration Standards NOTICE OF LIABILITY Every reasonable effort has been made to assure that all information contained herein is correct and that the products herein concerned conform to advertised specifications. Retention times and elution order is valid for the specified conditions only. Physical constants are taken from a variety of sources and are subject to revision. The seller reserves the right to make improvements and/or changes to the product contained herein at any time and without notice. The seller shall not be liable to buyer or any other person or entity with respect to any liability, loss, or damage caused or alleged to be caused directly or indirectly by the products and information contained herein. This includes, but is not limited to interruption of service, loss of data, loss of business or anticipatory profits, or consequential damages resulting from the use of these products. The seller further shall not be liable for any loss of product caused by buyer's mishandling or misuse of same. Under no circumstances shall seller's obligation exceed the cost of replacement of product. There are no warranties by seller other than those specified in this paragraph. No warranties by seller (other than warranty of title as provided under the Uniform Commercial Code) shall be implied or otherwise created under the Uniform Commercial Code, including, but not limited to, warranty of merchantability and warranty of fitness for a particular use. TRADEMARK ACKNOWLEDGEMENTS “Varian CP 3800 is a registered trademark of Varian Instrument Group. “Supelco SPB-1 is a trademark of Supelco, Inc. “P.LA.N.O. is a trademark of Analytical Automation Specialists.cugnsampco REVISED 1/1/08 4880 RYAN ROAD DALLAS Tx 75220 Tel (609) 656-2440 FAK (609) 655-2446 MATERIAL SAFETY DATA SHEET wea ae awa Ae} AAG ® IDENTIFICATION © 8 hb AAO RT A RAD Name: Napthene Fraction of PIANO Blend PRODUCT $+ $3600 wee ee ee eee HEALTH HAZARD DATA FA EE ee ACUTE EFFECTS MAY BE HARMFUL BY INHALATION, INGESTION, OR SKIN ABSORPTION ANESTHETIC EFFECT RESULTING IN DROWSINESS, DIZZINESS AND HEADACHE. MAY CAUSE EYE AND SEIN IRRITATION FROM OVEREXPOSURE. FIRST AID IN CASE OF CONTACT, IMMEDIATELY WASH SKIN WITH SOAP AND COPIOUS AMOUNTS OF WATER. IN CASE OF CONTACT, IMMEDIATELY FLUSH EYES WITH COPIOUS AMOUNTS OF WATER FOR AT LEAST 15 NINUTES. IF INHALED, REMOVE TO FRESH AIR. IF NOT BREATHING GIVE ARTIFICIAL RESPIRATION, PREFERABLY MOUTH-TO MOUTH. IF BREATEING IS DIFFICULT, GIVE OXYGEN. SEE A PHYSICIAN IF THERE IS PAIN OR IRRITATION. EXPOSURE LIMIT 2000 ng/M3 OSHA THA ARR RR AE RRR PHYSICAL DATA FERRER RR INTIAL BOILING POINT: 90 F FLASH POINT : LESS THAN 0 F SPECIFIC GRAVITY 0.60 VAPOR PRESSURE 30 mm Hy @ 100 F VAPOR DENSITY HEAVIER THAN AIR EVAPORATION RATE SLOWER THAN ETHER ODOR THRESHOLD Spom +t 44 0 nee 4 8 # ® PIRE AND EXPLOSION HAZARD DATA #4 4 et AR EXTINGUISHING MEDIA CAREON DICKIDE, DRY CHEMICAL POKDER, ALCOHOL OR POLYMER FOAN. SPECIAL FIRE FIGHTING PROCEDURES WEAR SELF-CONTAINED BREATHING APPARATUS AND PROTECTIVE CLOTHING TO PREVENT CONTACT WITH SKIN AND EYES. STOP THE FLOW OF LIQUID OR GAS(IF I? CAN BE ACCOMPLISHED SAFELY) USE WATER SPRAY TO COOL FIRE EXPOSED CONTAINERS KBEP AWAY FROM HEAT, SPARKS AND OPEN FLAME, UNUSUAL FIRE AND EXPLOSION’ HAZARDS EXTREMELY FLANMABLE - CONTAINER EXPLOSION MAY OCCUR UNDER FIRE CONDITIONS. AR A RH RERCIIVITY DATA FRE RR INCONPATIBILITIES STRONG OXIDIZING AGENTS. HAZARDOUS DECOMPOSITION OR EY PRODUCTS: CARBON OXIDES MAY RESULT FROM THERMAL OXIDATIVE DEGRADATION eA © 8 8 REBELS ORSTBAKS PROCEDURES <#FWie 6 8 8 ne eeeSTEPS TO BE TAKEN IF MATERIAL IS RELEASED OR SPILLED EVACUATE AREA. SHUT OFF ALL SOURCES OF IGNITION. WEAR RESPIRATOR, CHEMICAL SAFETY GOGGLES, RUBBER BOOTS AND HEAVY RUBBER GLOVES. COVER WITH DRY LIME, SAND, OR SODA ASH. PLACE IN COVERED CONTAINERS USING NONSPARKING TOOLS AND TRANSPORT CUTDOORS. VENTILATE ARSA AND WASH SPILL SITE AFTER MATERIAL PICKUP [5 COMPLETE WASTE DISPOSAL METHOD BURN IN A CHSNICAL INCINERATOR EQUIPPED WITH AN AFTERBURNER AND SCRUBBER BUT EXERT BXTRA CARE IN IGNITING AS THIS MATERIAL IS HIGHLY FLAMMABLE. PRECAUTIONS TO BE TAKEN IN HANDLING AND STORAGE AVOID CONTACT WITH EYES, SKIN AND CLOTHING. AVOID PROLONGED OR REPEATED EXPOSURE. MECHANICAL ZIKAUST REQUIRED. SAFETY SHOWER AND EYE EATH.KEEP AWAY FROM IGNITION SOURCES, KEEP CONTAINERS TIGHTLY CLOSED. WEAR APPROPRIATE OSHA\MSHA APPROVED RESPIRATOR, CHEMICAL RESISTANT GLOVES, SAFETY GOGSLES, OTHER PROTECTIVE CLOTHING DO NOT BREATHE VAPOR USE NONSPARKING TOOLS. FLANMABLE LIQUID. ee eee ORANSPORT DATA HHH ER PETROLEUM DISTILLATSS, N.0.S Uy #: UNLZ68 CLASS: 3 PG: IZ THE ABOVE INFORMATION IS BELIEVED TO BE CORRECT BUT DOES NOT FURPORT TO BE ALL INCLUSIVE AND SHALL BE USED ONLY AS A GUIDE. CHENSAMPCO SHALL NOT BE HELD LIABLE FOR ANY DAMAGE RESULTING FROM HANDLING OR FROM CONTACT WITH THE ABOVE PRODUCT.