DPP - Daily Practice Problems Chapter-wise Sheets CHEMISTRY (cc20 ‘SYLLABUS : General Principles and Processes of Isolation of Elements ‘Max. Marks : 100 Time : 60 min. INSTRUCTIONS : This Daly Practice Problem Sheet contains 25 questions, For each question only one option i correct, Darken the caect cll the Repose i rovied on each ep. ‘Marking Scheme : (+4) for correct & (—1) for incorrect answer and zero for unattempted. 1. Identity x, y, z for the following metallurgical process. Metal sulphide __*_, Metal oxide», Impure metal Pure metal. x, y and z are respectively (a) roasting, smelting, electrolysis (b) roasting, calcination, smelting, (©) calcination, auto-reduction, bassemerisation (d) none of the above is correct 2. Bronze is a mixture of (a) Pb+Sn (b+) Cu+Sn (Q CutZn (@ Pb+Zn 3. Which reagent is used in Bayer’s process? (a) Na,CO, (b) Carbon (©) NaOH (@ Silica 4. Which of the following fluxes is used to remove acidic impurities in@ (>) © @ @ (b) © @ @ () © @ (>) © metallurgical process? Silica Lime stone Sodium chloride Sodium carbonate A basic lining is given to a furnace by using Calcined dolomite Lime stone Haematite Silica Extraction of gold and silver involves leaching with CN“ ion. Silver is later recovered by distillation zone refining displacement with Zn liquation Which of the following reactions is an example for calcination process 2 2Ag + 2HC1+[0] —> 2AgC1+H,0 2Zn +0, > 2Zn0 2Zn$+307 > 2Zn0 +2805 MgCO; + Mg0+CO5 AG? vs T plot in the Ellingham’s diagram slopes downward for the reaction 1 Mg +O, + MgO 1 2Ag +09 > Ag,0 C450, co@) CO+ $0, > C07 9. Which of the following elements is present as the impurity to the maximum extent in the pig iron ? (a) Manganese (b) Carbon (© Silicon (@_ Phosphorus 10. Among the following statements the incorrect one is (a) o (c (@) Malachite and azurite are ores of copper. 11, Match list I with list II and select the correct answer given below the Calamine and siderite are carbonates Argentite and cuprite are oxides Zinc blende and iron pyrites are sulphides lists: List I List 11 I. Cyanide process A. Ultrapure Ge II. Floatation process B. Pine oil Ill. Electrolytic reduction C. Extraction of Al IV. Zone refining D. Extraction of Au (a) I-C, I-A, II-D, IV-B (b) I-D,I-B,UI-C,IV-A (©) FC\I-B,II-D, IV-A (d) I-D,II-A,II-C,IV-B 12. A coupled reaction is takes place as follow— A+B——+C+D, AG?=+xkj D+E——+F AG°=-ykj for the spontaneity of reaction A + B + E ——+ C+F, which of the following is correct?(b) © @ 13. @ ) © (d) 14. @ (b) © (@ © @ (b) 2x=y xy x= (y)x TAS Aluminium is extracted from alumina (Al,O, ) by electrolysis of a molten mixture of Al,O, + HF + NaAlF, ALO, + CaF, + NaAIF, Al,O, + Na, AIF, + CaF, ALO, + KF + Na,AIF, Which of the following statements, about the advantage of roasting of sulphide ore before reduction is not true? The AGP of the sulphide is greater than those for CS, and H,S. The AG is negative for roasting of sulphide ore to oxide. Roasting of the sulphide to the oxide is thermodynamically feasible. Carbon and hydrogen are suitable reducing agents for reduction of metal sulphides. In the extraction of copper from its sulphide ore, the metal is finally obtained by the reduction of cuprous oxide with : Copper (1) sulphide (Cu,S) Sulphur dioxide (SO,) Iron sulphide (FeS) Carbon monoxide (CO) The method of zone refining of metals is based on the principle of Greater solubility of the impurity in the molten state than in the solid. Greater mobility of the pure metal than that of the impurity.(c) Higher melting point of the impurity than that of the pure metal. (d) Greater noble character of the solid metal than that of the impurity. 17. In the cyanide extraction process of silver from argentite ore, the oxidising and reducing agents used are (a) O,and CO respectively (b) O, and Zn dust respectively (©) HNO, and Zn dust respectively (@ HNO, and CO respectively 18. The metal oxide which cannot be reduced to metal by carbon is (a) Fe,0, (b) ALO, (© PbO (@ ZnO 19. Which process represents the change, Ti+2I) > Tily > Ti+21 (a) Cupellation (b) Van Arkel (©) Polling (@ Zone Refining 20. Among the following groups of oxides, the group containing oxides that cannot be reduced by carbon to give the respective metals is (a) Cu,0,Sn0 (b) Fe ,03,ZnO (0 Ca0,K,0 (@) PbO, Fe;04 21. Which of the following pairs of metals is purified by van Arkel method 2 (a) Gaand In (b) Zrand Ti (© Agand Au (d) Niand Fe 22. Which of the following pair is incorrectly matched ?@ (b) © @ @ (b) © @ 24. @ () © @ @ (b) © (d) Magnetite— Fe,O, Copper glance —Cu,S Calamine — ZnCO, Zincite— ZnS Before introducing FeO in blast furnace, it is converted to Fe,O by roasting so that it may not be removed as slag with silica. it may not evaporate in the furnace. presence of it may increase the m.pt. of charge. None of these Which of the following statements is correct ? Gangues are carefully chosen to combine with the slag present in the ore to produce easily fusible flux to carry away the impurities. Slags are carefully chosen to combine with the flux present in the ore to produce easily fusible gangue to carry away the impurities. Gangues are carefully chosen to combine with the flux present in the ore to produce easily fusible slag to carry away the impurities. Fluxes are carefully chosen to combine with the gangue present in the ore to produce easily fusible slag to carry away the impurities. The value of A, G° for formation of Cr, O, is — 540 kJmol" and that of Al,O, is — 827 kJ mol“, What is the value of A,G’ for the reaction? * aus) +2.c40,(8) a1,05(5)+ 4 cxG) s 1,0;(s) + = s) += Cr(s). 3 3 23 3 M3 3 —574 kJ mol" 287k) mol +574 kJ molt +287kJ mol*Dey Meditate A ak a a GN 4 ela Total Questions 25 __ [Total Marks 100 [Attempted Correct Incorrect Net Score [Cut-off Score 38___ [Qualifying Score 52 Success Gap = Net Score — Qualifying Score Net Score = [(Correct x 4) ~ (Incorrect x 1)]DPP - Daily Practice Problems Chapter-wise Sheets CHEMISTRY (cc21) ‘SYLLABUS : The p-Block Elements (Group 18, 18, 17 and 18) ‘Max. Marks : 100 Time : 60 min. INSTRUCTIONS : This Day Practice Problem Sheet contains 25 question, For each question ony one option i correct, Darken the correct crcl bubble inthe Response Grid provided an each pape. Marking Schome : (+4) for correct 8 (-1) for incorrect ancwer and zero for unatempted 1. The oxyacid of phosphorous in which phosphorous has the lowest oxidation state is (a) hypophosphorous acid (b)_orthophosphoric acid (©) pyrophosphoric acid (@_ metaphosphoric acid 2. The decreasing values of bond angles from NH, (106°) to SbH, (101°) down groups15 of the periodic table is due to (a) decreasing Ip-bp repulsion (b) decreasing electronegativity (©) increasing bp-bp repulsion (d) increasing p-orbital character in sp? 3. The deep blue colour produced on adding excess of ammonia to copper sulphate is due to presence of @ cu*() © @ @ ) © @ @ o « @ @ (b IG @ Cu(NH3);* Cu(NH3)2* ~, 2+ Cu(NH3)3 In nitroprusside ion, the iron and NO exist as Fe"* and NO* rather than Fe’ and NO. These forms can be _ differentiated by estimating the concentration of iron measuring the concentration of C\y~ measuring the solid state magnetic moment thermally decomposing the compound The brown ring test for NOQz and NQ3 is due to the formation of complex ion with a formula [Fe(H,0),}* [Fe(NO)(CN),]* [Fe(H,0),NO}* [Fe(H,0)(NO),}* Concentrated hydrochloric acid when kept in open air sometimes produces a cloud of white fumes. The explanation for it is that oxygen in air reacts with the emitted HCl gas to form a cloud of chlorine gas strong affinity of HCI gas for moisture in air results in forming of droplets of liquid solution which appears like a cloudy smoke, due to strong affinity for water, concentrated hydrochloric acid pulls moisture of air towards itself. This moisture forms droplets of water and hence the cloud. concentrated hydrochloric acid emits strongly smelling HCI gas all thetion in ICI, is The compound of sulphur that can be used as refrigerant is sO, SO, S,Cl, H,S0, Which of the following is a saline oxide ? Na,O, BaO, Na,O Fe,O, Which one of the following substances has the highest proton affinity ? H,S (b) NH, PH, (@ 1,0 Which one of the following statement regarding helium is incorrect ? It is used to produce and sustain powerful superconducting magnets It is used as a cryogenic agent for carrying out experiments at low temperatures Its used to fill gas balloons instead of hydrogen because it is lighter andqd) 12. @ (b) © @ 13. @ (>) © @ 14. non-inflammable It is used in gas-cooled nuclear reactors The acid which forms two series of salts is H,PO, H,PO, H,BO, H3PO3 Gaseous HCI is a poor conductor of electricity while its aqueous solution is a good conductor this is because H0is a good conductor of electricity a gas cannot conduct electricity but a liquid can HCI gas does not obey Ohm’s law, whereas the solution does HCl ionises in aqueous solution The number of hydrogen atom(s) attached to phosphorus atom in hypophosphorous acid is three one two zero What products are expected from the disproportionation reaction of hypochlorous acid? HCl and Cl, HCl and HClO, HCIO, and C1,0@ 16. @ (>) © @ 17. @ (b) © @ 18. 0) © (@ 19. @ ) © @ 20. HCIO, and HClO, Shape of XeOF, is octahedral square pyramidal pyramidal T-shaped Yellow ammonium sulphide is (NH4)2Sg (NH4)2S (NH4)2Sx (NH4)2S4 The correct order of increasing bond angles in the following species are Cl,0< ClO, < C10; C10) 2Xe+ XeO3 +12HF+1.50) 2XeF, + 2H,0—>2 Xe+ 4HF + Oy XeFy + RbF —>Rb[XeF,] Xe03 +6HF —> XeF, +3H,0 Trigonal bipyramidal geometry is shown by :@ ) © @ 21. @ (>) oO @ 22. @) (b) @ 23. @ (b) © @ 24. @ (>) © XeO,F, XeO,F, FXeOSO,F [XeF, > Oxidation of thiosulphate by iodine gives tetrathionate ion sulphide ion sulphate ion sulphite ion The crystals of ferrous sulphate on heating give : Fe0+SO, +H 0 FeO +$03 +H,$04 +H 0 Fe,03 +80) +H3$804+H,0 Fe,03 +H,804+H,0 Which one of the following orders correctly represents the increasing acid strengths of the given acids? HOCIO < HOC! < HOCIO, < HOCIO, HOCIO, < HOCIO, < HOCIO < HOC! HOCIO, < HOCIO, < HOCIO < HOCI HOCI < HOCIO < HOCIO, < HOCIO, Shapes of certain interhalogen compounds are stated below. Which one of them is not correctly stated? IF, : pentagonal bipyramid BrF, : trigonal bipyramid BrF, : planar T-shaped(@)_ ICI, : planar dimeric 25. The nitrogen oxides that contain(s) N-N bond(s) is /are @ NO (i) N,O, (iii) N,O, (iv) NO, @ @, (i) ©) Gi), Git), Gv) © Gil), Gv) (@_@), Gil) and (iii) DAILY PRACTICE PROBLEM DPP CHAPTERWISE 21 - CHEMISTRY Total Questions 25 |Total Marks 100 [Attempted Correct Incorrect Net Score [Cut-off Score 38___ [Qualifying Score 52 Success Gap = Net Score — Qualifying Score Net Score = [(Correct x 4) - (Incorrect x 1)]