CÁLCULOS

t(min) CA(ml)
10 33.4
20 48.7
30 100
40 53.3
50 45.4

1. Graficar 1/CA contra tiempo en segundos. Determine la constante cinética

en cada caso.
t (seg) 1/CA(ml)
600 0.02994012
1200 0.020533881
1800 0.01
2400 0.018761726
3000 0.022026432

t vs 1/CA
0.035

0.03

0.025
f(x) = − 2.93325515158768E-06 x + 0.025532290965024
R² = 0.151528903846469
0.02
CA

0.015

0.01

0.005

0
500 1000 1500 2000 2500 3000
t

2. Graficar ln k contra 1/T. Calcular la energía de activación de Arrhenius.

Con el método de vida media:

t(s) CA(ml) k 1/t ln(k)

600 33.4 17.96407186 0.001666667 2.888373755
1200 48.7 24.64065708 0.000833333 3.204397806
1800 100 18 0.000555556 2.890371758
2400 53.3 45.02814259 0.000416667 3.807287685
3000 45.4 66.07929515 0.000333333 4.190855463
 1/t vs ln(K)
4.5

f(x) = − 728.122659499434 x + 3.95043953971367

3.5 R² = 0.458792258786295
ln(K)

2.5

2
0 0.0002 0.0004 0.0006 0.0008 0.001 0.0012 0.0014 0.0016 0.0018

1/t

3. Graficar ln(k/T) contra 1/T, calcular ΔH* y ΔS*.

1/t ln(k/t)
0.001666667 -3.5085559
0.000833333 -3.88567903
0.000555556 -4.605170186
0.000416667 -3.975936331
0.000333333 -3.815512105
 1/t vs ln(k/t)
0
0.0002 0.0004 0.0006 0.0008 0.001 0.0012 0.0014 0.0016 0.0018
-0.5

-1

-1.5

-2
ln(k/t)

-2.5

-3

-3.5
f(x) = 419.518522561124 x − 4.27747091929387
-4 R² = 0.318181677380404

-4.5

-5
1/t

kT
ln(k) S *  R ln k  R ln( )R
h

2.888373755 474.9622327

3.204397806 474.9622327

2.890371758 474.9622327

3.807287685 474.9622327

4.190855463 474.9622327