Thermo Calc (ZnS)

REACCIÓN ZnS+1.5O2(g)=ZnO + SO2(g)

1/T T deltaH deltaS deltaG K'' Log(K'')
1/K K kJ J/K kJ
0.00335402 298.15 -442.077 -73.4598 -420.175
0.00333333 300 -442.094 -73.5169 -420.039
0.0025 400 -442.76 -75.4623 -412.575
0.002 500 -443.089 -76.2074 -404.985
0.00166667 600 -443.221 -76.4527 -397.349
0.00142857 700 -443.232 -76.4715 -389.702
0.00125 800 -443.174 -76.3948 -382.058
0.00111111 900 -443.076 -76.28 -374.424
0.001 1000 -442.948 -76.1449 -366.803
0.00090909 1100 -442.8 -76.0039 -359.195
0.00083333 1200 -442.642 -75.8666 -351.602
0.00076923 1300 -455.446 -85.7647 -343.952
0.00071429 1400 -455.198 -85.581 -335.384
Promedio -444.751 -77.201
Desvest 4.70730803 3.89508435
%error 1.058% 5.045%

FACT WEB (ZnS)

REACCIÓN ZnS+1.5O2(g)=ZnO + SO2(g)
1/T T °K ∆H KJ/mol ∆G KJ/mol ∆S Jmol/°K K Log(K)
1/K °K KJ/mol KJ/mol Jmol/K
0.00333333 300 -442.1346 -420.0777 -73.523 1.381E+073 73.1401937
0.0025 400 -442.8078 -412.6152 -75.481 7.5973E+53 53.8806593
0.002 500 -443.2263 -405.0145 -76.424 2.0441E+42 42.3105021
0.00166667 600 -443.485 -397.3458 -76.899 3.9007E+34 34.5911426
0.00142857 700 -443.6431 -389.6423 -77.144 1.1878E+29 29.0747433
0.00125 800 -443.7348 -381.9209 -77.267 8.6348E+24 24.9362523
0.00111111 900 -443.7782 -374.1912 -77.319 5.2112E+21 21.7169377
0.001 1000 -443.7802 -366.4588 -77.321 1.3847E+19 19.1413557
0.00090909 1100 -443.7489 -358.7279 -77.292 1.0818E+17 17.034147
0.00083333 1200 -443.6895 -351.0012 -77.24 1.898E+15 15.2782962
0.00077373 1292.44 -443.6107 -343.864 -77.177 7.8905E+13 13.8971045
 0.00077373 1292.44 -456.6335 -343.864 -87.253 7.8905E+13 13.8971045
0.00076923 1300 -456.6197 -343.2043 -87.243 6.1627E+13 13.789771
0.00071429 1400 -456.4211 -334.4873 -87.096 3.0169E+12 12.4795609
POMEDIO= -446.236671 -373.02965 -78.9056429
DESVEST= 5.61234364 27.4649484 4.61053572
% ERROR= 1.25771% 7.36267% 5.84310%

ZnS+1.5O2(g)=ZnO + SO2(g) ZnS+1.5O2

0 80
-50 200 400 600 800 1000 1200 1400 1600 70 f(x) = 23155.6939761
60 R² = 0.999999160588
-100
50

Log K eq (1,T)
-150
∆G KJ/mol

-200 40

-250 30

-300 20

-350 10
f(x) = 0.0773349891577424 x − 443.652404013074
-400 R² = 0.999891943088576 0
0.0005 0.001 0.001
-450
T °K
 Log(K') %Error

1000 2.303 8.314 4.184

Log(K') %Error Log(K'') %Error

73.1677062 0.037616% 73.131488762 0.01190%

53.8712945 0.017381% 53.976541251 0.17795%
42.2934475 0.040308% 42.456968251 0.34617%
34.5748829 0.047005% 34.763343097 0.49782% ∆G=A+B*T
29.0616224 0.045128% 29.260390775 0.63852% A B
24.9266771 0.038399% 25.128841683 0.77233% -443.652404 0.07733499
21.7106084 0.029144% 21.912611756 0.90102% 0.07733499 -443.652404
19.1377536 0.018819% 19.337465612 1.02454% 0.00023208 0.22739647
17.0326905 0.008550% 17.228946801 1.14358% 0.99989194 0.3083745
15.2784712 0.001146% 15.470624807 1.25884% 111040.591 12
13.8983218 0.008759% 14.086282109 1.36127% 10559.3863 1.14113798
 13.8983218 0.008759% 14.61252958 5.14802%
13.7941319 0.031624% 14.504667228 5.18425% ∆H KJ/mol -443.652404
12.521841 0.338795% 13.18693262 5.66824% ∆S Jmol/°K 0.07733499
PROMEDIO= 0.00047960 27.78983102 1.723889%
DESVEST= 0.00085067 17.83483188 0.01998328 Log(k')=A'+B'*(1/T)
%ERROR= 177.373207% 64.177547% 115.919759% A' B'
-4.01794041 23155.694
23155.694 -4.01794041
6.12427558 0.00951545
ZnS+1.5O2(g)=ZnO + SO2(g) 0.99999916 0.01714762
80 14295723.9 12
70 f(x) = 23155.6939761376 x − 4.01794041247597 4203.52519 0.00352849
60 R² = 0.999999160588859

50 A' -4.01794041
Log K eq (1,T)

40 B' 23155.694
30
20
10
0
0.0005 0.001 0.0015 0.002 0.0025 0.003 0.0035

1/T°K
R^2= 0.99989194
R^2= 0.99999916