FACT

REACCION 3CuO(s)+2CO2(g)+1H2O(l) + 1Cu3(CO3)2(OH)2(g)

1/T T ∆H J/mol ∆S j/mol*K ∆G kj/mol DCp°(J/mol*°K) K logK
0.00333333 300 -128026.4 -329.21 -29263.3 5.626 124470 5.09506469
0.00307692 325 -127903 -328.815 -21038.3 4.2016 2405.6 3.38122342
0.00285714 350 -127817.5 -328.56 -12821.4 2.6272 81.928 1.91343235
0.00267738 373.5 -127773.7 -328.439 -5100.6 1.0907 5.1677 0.71329729
0.00267738 373.5 -168629.5 -437.824 -5100.6 43.04 5.1677 0.71329729
0.00266667 375 -168565.2 -437.652 -4445.6 42.964 4.1613 0.61922903
0.0025 400 -167506.4 -434.918 6461 41.761 0.14332 -0.8436932
0.00235294 425 -166476.2 -432.42 17302.2 40.675 0.0074735 -2.12647596
0.00222222 450 -165471.7 -430.123 28083.6 39.697 0.00054982 -3.25977947
0.00210526 475 -164490.5 -428.001 38809.8 38.82 0.000053986 -4.26771885
0.002 500 -163530 -426.03 49484.9 38.036 0.0000067682 -5.16952682
0.00190476 525 -162588 -424.191 60112.4 37.337 0.0000010454 -5.9807175
0.00181818 550 -161662.5 -422.469 70695.5 36.718 1.9323E-07 -6.71392545
0.00173913 575 -160751.6 -420.849 81236.7 35.996 4.1726E-08 -7.37959325
0.00166667 600 -159885 -419.374 91739.1 33.356 1.0318E-08 -7.98640448
0.0016 625 -159082.8 -418.063 102206.8 30.84 2.8724E-09 -8.54175508
0.00153846 650 -158342.1 -416.901 112643.5 28.434 8.8732E-10 -9.05191973
0.00148148 675 -157660.3 -415.871 123052.9 26.127 3.0049E-10 -9.52216998
0.00142857 700 -157035 -414.962 133438.1 23.91 1.104E-10 -9.95703093
0.00137931 725 -156464.1 -414.16 143801.9 21.774 4.3617E-11 -10.3603442
0.00133333 750 -155945.7 -413.457 154146.9 19.712 1.8388E-11 -10.7354655
0.00129032 775 -155477.9 -412.843 164475.5 17.718 8.2169E-12 -11.085292
0.00125 800 -155059.3 -412.311 174789.8 15.786 3.8698E-12 -11.4123115
0.00121212 825 -154688.2 -411.854 185091.7 13.911 1.911E-12 -11.7187393
0.00117647 850 -154363.3 -411.466 195383.1 12.089 9.8519E-13 -12.00648
0.00114286 875 -154083.3 -411.142 205665.5 10.316 5.2814E-13 -12.2772509
0.00111111 900 -153847.1 -410.875 215940.6 8.5889 2.9339E-13 -12.5325547
0.00108108 925 -153653.5 -410.663 226209.8 6.9042 1.6838E-13 -12.7737095
0.00105263 950 -153501.5 -410.501 236474.2 5.2592 9.9557E-14 -13.0019282
0.00102564 975 -153390.2 -410.385 246735.2 3.6514 6.0499E-14 -13.2182518
0.001 1000 -153318.7 -410.312 256993.8 2.0785 3.7702E-14 -13.4236356
Promedio -155064.2 -407.569065 -6.86810096
Desvest 11669.932 31.9652104 5.58832811
%error 7.526% 7.843% 81.366%

ESTADOS
T(K) ALOTRÓPICOS
 273.15 ------ CuO(s) CO2(g) H2O(s) Cu3(CO3)2(OH)2(s) ------
373.5 ------ CuO(s) CO2(g) H2O(g) Cu3(CO3)2(OH)2(s) ------
H2O(1 mol): DH° = 40855.8 DG° = 0 ------ DS° = 109.385
 l𝑜𝑔⁡〖𝐾 _(𝑇_2 ) 〗 =log⁡〖𝐾 _(𝑇_1 ) 〗− (Δ_𝑟 𝐻^0)/(2.303∗𝑅) (1/𝑇_2 −1/𝑇_1 )
-(dDG°/dT)P
%Error
∆H°/R
∆S° Jmol/°K
Log K´ %Error Log K´´
5.09462733 0.009% 5.09462733307967 0.01% -329.21
3.3818207 0.018% 1.30526790093548 61.40% -328.873693
1.91370073 0.014% 0.133798327912397 93.01% -328.805015
0.71286899 0.060% -0.742981561235728 204.16% -328.970989
0.59121429 17.115% 0.591214285435154 17.12% -319.778407
0.50114053 19.070% 0.414409008080177 17.31% -319.62286
-0.90063228 6.749% -2.25039159829555 166.73% -317.196109
-2.13749064 0.518% -3.32845474661524 56.52% -315.042625
-3.2369203 0.701% -4.29555505700595 31.77% -313.114252
-4.22062052 1.104% -5.16782003708878 21.09% -311.370955
-5.10595071 1.230% -5.95843028105517 15.26% -309.780237
-5.90696375 1.233% -6.67825478522293 11.66% -308.315625
-6.63515741 1.173% -7.33633108584926 9.27% -306.953906
-7.30002989 1.078% -7.9402319415161 7.60% -305.79145
-7.90949633 0.963% -8.49634821019565 6.39% -306.089383
-8.47020546 0.838% -9.01010918420819 5.48% -306.574391
-8.98778311 0.709% -9.48615578138137 4.80% -307.225119
-9.46702168 0.579% -9.92847785491017 4.27% -308.022826
-9.91202892 0.452% -10.340523940836 3.85% -308.951108
-10.326346 0.328% -10.7252896468882 3.52% -309.996858
-10.713042 0.209% -11.0853893518971 3.26% -311.148077
-11.0747898 0.095% -11.4231147611868 3.05% -312.394191
-11.4139284 0.014% -11.7404830327954 2.88% -313.726629
-11.7325131 0.118% -12.0392765701122 2.74% -315.13762
-12.0323575 0.216% -12.3210761108913 2.62% -316.619864
-12.315068 0.308% -12.587288389645 2.53% -318.167326
-12.5820724 0.395% -12.8391693808025 2.45% -319.774129
-12.834644 0.477% -13.0778439225381 2.38% -321.435793
-13.0739225 0.554% -13.3043223603887 2.33% -323.147828
-13.3009302 0.625% -13.5195147243376 2.28% -324.906259
-13.5165876 0.692% -13.7242428545552 2.24% -326.707543
-6.86810096 -7.47766968761327 -315.898421
5.58800579 5.31647466949556 7.670789791
81.362% 71.098% 2.428%
 (d(DG°/T)/d(1
/T)P ∆Gsimp + aporte
%Error %Error ∆G°simplificado(J) %Error %Error
∆Cp
∆H° KJ/mol

0.0000% -128026.4 0.00% -29263.3 0.00% -29263.3 0.00%

0.0178% -127921.36 0.01% -21033.05 0.02% -20982.6308 0.26%
0.0746% -127895.04 0.06% -12802.8 0.15% -12689.8304 1.03%
0.1620% -127946.234 0.14% -5066.365 0.67% -4991.7410867 2.13%
26.9619% -124862.96 25.95% -5066.365 0.67% -2121.6384694 58.40%
26.9687% -124804.1 25.96% -4572.55 2.86% -1565.07 64.80%
27.0676% -123850.3 26.06% 3657.7 43.39% 7666.756 18.66%
27.1443% -122942.025 26.15% 11887.95 31.29% 16834.03 2.71%
27.2036% -122071.85 26.23% 20118.2 28.36% 25953.659 7.58%
27.2499% -121232.9 26.30% 28348.45 26.96% 35036.5814286 9.72%
27.2868% -120419.2 26.36% 36578.7 26.08% 44090.81 10.90%
27.3168% -119625.575 26.42% 44808.95 25.46% 53122.6553333 11.63%
27.3429% -118846.9 26.48% 53039.2 24.98% 62137.9204 12.10%
27.3394% -118127.5 26.52% 61269.45 24.58% 71093.0856364 12.49%
27.0128% -118019.6 26.18% 69499.7 24.24% 79439.788 13.41%
26.6679% -118003.4 25.82% 77729.95 23.95% 87693.6423077 14.20%
26.3074% -118074.5 25.43% 85960.2 23.69% 95859.294 14.90%
25.9331% -118228.775 25.01% 94190.45 23.46% 103941.0464 15.53%
25.5471% -118462.4 24.56% 102420.7 23.24% 111942.8575 16.11%
25.1505% -118772.45 24.09% 110650.95 23.05% 119867.756118 16.64%
24.7448% -119156 23.59% 118881.2 22.88% 127718.746667 17.14%
24.3310% -119610.35 23.07% 127111.45 22.72% 135498.591684 17.62%
23.9102% -120133.4 22.52% 135341.7 22.57% 143209.4424 18.07%
23.4832% -120723.125 21.96% 143571.95 22.43% 150853.364857 18.50%
23.0508% -121377.45 21.37% 151802.2 22.31% 158432.467 18.91%
22.6138% -122094.7 20.76% 160032.45 22.19% 165948.451739 19.31%
22.1724% -122873.06 20.13% 168262.7 22.08% 173403.15665 19.70%
21.7276% -123711.275 19.49% 176492.95 21.98% 180797.856784 20.08%
21.2796% -124607.92 18.82% 184723.2 21.88% 188133.993477 20.44%
20.8289% -125561.705 18.14% 192953.45 21.80% 195412.870756 20.80%
20.3758% -126571.45 17.45% 201183.7 21.72% 202635.680714 21.15%
-122082.384 80087.518387097 85971.2998095
3381.73315 71416.308030018 72378.6277088
2.770% 89.173% 84.189%
de 273.15 a 373.5

DG = A + B*T DG = DH - DS*T
A B
-127881.8749 328.7385241 Hallando el valor de DH y DS
328.73852406 -127881.875 DH kj/mol -127881.875
0.0729355485 24.66977545 DS j/mol*K -328738.524
0.9999999016 4.004279519
20315274.498 2
325740280.79 32.06850893 R^2 = 0.9999999

de 373.5.15 a 1000

DG = A + B*T DG = DH - DS*T
A B
-159722.6282 417.784435 Hallando el valor de DH y DS
417.78443502 -159722.628 DH kj/mol -159722.628
0.7249746402 509.6377735 DS j/mol*K -417784.435
0.9999247254 728.2321711
332092.35772 25
176115914906 13258052.38 R^2 = 0.9999247

CONSTANTES
1000
2.303
8.314
 3CuO(s)+2
1Cu3(C
0
logK= A' + B' *(1/T) 𝐥𝐧⁡(𝑲)=(−𝑯)/𝑹∗(𝟏/𝑻)+ 290 300 310 3
-5000
A' B' (𝑺)/𝑹 f(x) = 328.7
-10000
R² = 0.9999

G kj/mol
-17.17185892 6679.9458756 -15000
6679.9458756 -17.17185892 Hallando el valor de DH y D -20000
1.2917649854 0.0038704572 DH kj/mol -127.901872 -25000
0.9999999252 0.0006338344 DS j/mol*K -328.792021 -30000
26741075.517 2 -35000
10.743120772 8.03492E-07 R^2 = 0.9999999

logK= A' + B' *(1/T) 𝐥𝐧⁡(𝑲)=(−𝑯)/𝑹∗(𝟏/𝑻)+ 3CuO(s)+2

A' B' (𝑺)/𝑹 1Cu3(C
-21.92722444 8410.6368632
300000
8410.6368632 -21.92722444 Hallando el valor de DH y D 250000
24.757209569 0.0420698152 DH kj/mol -161.039658 f(x) = 417.78
200000 R² = 0.99992

G kj/mol
0.9997834334 0.0657476737 DS j/mol*K -419.84368 150000
115412.90663 25 100000
498.90190334 0.1080689149 R^2 = 0.9997834 50000
0
300 400 500
-50000
 3CuO(s)+2CO2(g)+1H2O(l) +
1Cu3(CO3)2(OH)2(g) 3CuO(s)+2CO2(g)+1H2O(l) +
0
1Cu3(CO3)2(OH)2(g)
290 300 310 320 330 340 350 360 370 380
-5000 6
-10000 f(x) = 328.738524063284 x − 127881.874924835 5
f(x) = 6679.94587555607 x − 17.17185

Log k eq(1,t)
R² = 0.999999901551918 4
-15000
3
R² = 0.999999925208698
-20000 2
-25000 1
-30000 0
0.0026 0.0027 0.0028 0.0029 0.003 0.0031 0.0032
-35000
1/T° K
T° K

3CuO(s)+2CO2(g)+1H2O(l) +
3CuO(s)+2CO2(g)+1H2O(l) +
1Cu3(CO3)2(OH)2(g)
1Cu3(CO3)2(OH)2(g)
300000 0
0.0008 0.001f(x) = 8410.63686321474
0.00120.00140.00160.0018 x −0.00220.0024
0.002 21.927224
250000
Log k eq(1,t) -4 R² = 0.999783433356256
f(x) = 417.784435022067 x − 159722.628240748
200000 R² = 0.999924725403781 -8
150000
100000 -12
50000 -16
0 1/T° K
300 400 500 600 700 800 900 1000 1100
-50000
T° K
(s)+2CO2(g)+1H2O(l) +
u3(CO3)2(OH)2(g)

79.94587555607 x − 17.1718589187739
99999925208698

28 0.0029 0.003 0.0031 0.0032 0.0033 0.0034

1/T° K

)+2CO2(g)+1H2O(l) +
3(CO3)2(OH)2(g)

0.63686321474
0140.00160.0018 x −0.00220.00240.00260.0028
0.002 21.9272244380314
9783433356256

1/T° K
3 CuO + 2 CO2 + H2O = Cu 3(CO3)2(OH)2
(T) (T) (T) (T ,s)
______ _ __ ____ _ ___ _ _ ____________

T(K) Delta_H°(J) Delta_S°(J/K) Delta_G°(J) Delta_Cp(J/K)Keq T

_________________________________________________________________ _

------ CuO(s) Cu3(CO3)2(OH CO2(g) ------

300 -128026.4 -329.21 -29263.3 5.63E+00 1.24E+05
325 -127903 -328.815 -21038.3 4.20E+00 2.41E+03
350 -127817.5 -328.56 -12821.4 2.63E+00 8.19E+01
373.5 -127773.7 -328.439 -5100.6 1.09E+00 5.17E+00
------ CuO(s) Cu3(CO3)2(OH CO2(g) ------
H2O(1 mol): DH° = 40855.DS° = 109.38 DG° = 0
373.5 -168629.5 -437.824 -5100.6 4.30E+01 5.17E+00
375 -168565.2 -437.652 -4445.6 4.30E+01 4.16E+00
400 -167506.4 -434.918 6461 4.18E+01 1.43E-01
425 -166476.2 -432.42 17302.2 4.07E+01 7.47E-03
450 -165471.7 -430.123 28083.6 3.97E+01 5.50E-04
475 -164490.5 -428.001 38809.8 3.88E+01 5.40E-05
500 -163530 -426.03 49484.9 3.80E+01 6.77E-06
525 -162588 -424.191 60112.4 3.73E+01 1.05E-06
550 -161662.5 -422.469 70695.5 3.67E+01 1.93E-07
575 -160751.6 -420.849 81236.7 3.60E+01 4.17E-08
600 -159885 -419.374 91739.1 3.34E+01 1.03E-08 T
625 -159082.8 -418.063 102206.8 3.08E+01 2.87E-09 T
650 -158342.1 -416.901 112643.5 2.84E+01 8.87E-10 T
675 -157660.3 -415.871 123052.9 2.61E+01 3.00E-10 T
700 -157035 -414.962 133438.1 2.39E+01 1.10E-10 T
725 -156464.1 -414.16 143801.9 2.18E+01 4.36E-11 T
750 -155945.7 -413.457 154146.9 1.97E+01 1.84E-11 T
775 -155477.9 -412.843 164475.5 1.77E+01 8.22E-12 T
800 -155059.3 -412.311 174789.8 1.58E+01 3.87E-12 T
825 -154688.2 -411.854 185091.7 1.39E+01 1.91E-12 T
850 -154363.3 -411.466 195383.1 1.21E+01 9.85E-13 T
875 -154083.3 -411.142 205665.5 1.03E+01 5.28E-13 T
900 -153847.1 -410.875 215940.6 8.59E+00 2.93E-13 T
925 -153653.5 -410.663 226209.8 6.90E+00 1.68E-13 T
950 -153501.5 -410.501 236474.2 5.26E+00 9.96E-14 T
975 -153390.2 -410.385 246735.2 3.65E+00 6.05E-14 T
1000 -153318.7 -410.312 256993.8 2.08E+00 3.77E-14 T
_________________________________________________________________ _
_

Delta_Vol(litre)
________________

H2O(l)
-4.92E+01
-5.33E+01
-5.74E+01
-6.13E+01
H2O(g)
------
-9.19E+01
-9.23E+01
-9.85E+01
-1.05E+02
-1.11E+02
-1.17E+02
-1.23E+02
-1.29E+02
-1.35E+02
-1.42E+02
-1.48E+02
-1.54E+02
-1.60E+02
-1.66E+02
-1.72E+02
-1.78E+02
-1.85E+02
-1.91E+02
-1.97E+02
-2.03E+02
-2.09E+02
-2.15E+02
-2.22E+02
-2.28E+02
-2.34E+02
-2.40E+02
-2.46E+02
________________
 FACT

REACCION 3CuO(s)+2CO2(g)+1H2O(l) + 1Cu3(CO3)2(OH)2(g)

1/T T ∆H J/mol ∆S j/mol*K ∆G kj/mol DCp°(J/mol*°K) K logK
0.00333333 300 -827710.8 -141.542 -785248.2 -14.626 5.2531E+136 136.720416
0.00307692 325 -828049.1 -142.626 -781695.6 -12.544 4.2903E+125 125.632488
0.00285714 350 -828342.5 -143.497 -778118.7 -11.006 1.3333E+116 116.124928
0.00266667 375 -828603 -144.216 -774522 -9.8979 7.6259E+107 107.882291
0.0025 400 -828840.2 -144.829 -770908.8 -9.1329 4.6539E+100 100.667817
0.00235294 425 -829061.9 -145.366 -767281.2 -8.6431 1.9969E+094 94.3003563
0.00222222 450 -829274.2 -145.852 -763640.9 -8.3752 4.3541E+088 88.6388984
0.00210526 475 -829482.2 -146.302 -759988.9 -8.2869 3.7334E+083 83.5721045
0.002 500 -829689.8 -146.728 -756326 -8.3444 1.0253E+079 79.010851
0.00190476 525 -829900.4 -147.138 -752652.7 -8.5203 7.6375E+074 74.8829512
0.00181818 550 -830116.6 -147.541 -748969.2 -8.7922 1.347E+071 71.1293676
0.00173913 575 -830340.6 -147.939 -745275.7 -9.142 5.0264E+067 67.701257
0.00166667 600 -830574.2 -148.337 -741572.2 -9.5544 3.6138E+064 64.5579641
0.0016 625 -830818.8 -148.736 -737858.8 -10.017 4.6271E+061 61.6653089
0.00153846 650 -831075.4 -149.138 -734135.4 -10.519 9.8709E+058 58.9943568
0.00148148 675 -831345 -149.545 -730401.9 -11.051 3.3149E+056 56.5204704
0.00142857 700 -831628.1 -149.957 -726658.1 -11.606 1.6693E+054 54.2225344
0.00137931 725 -831925.4 -150.374 -722904 -12.179 1.2087E+052 52.0823185
0.00133333 750 -832237.2 -150.797 -719139.3 -12.762 1.2135E+050 50.0840398
0.00129032 775 -832563.6 -151.225 -715364.1 -13.352 1.6368E+048 48.2139956
0.00125 800 -832904.8 -151.658 -711578 -13.944 2.8847E+046 46.4601007
0.00121212 825 -833260.8 -152.097 -707781.1 -14.535 6.4838E+044 44.8118296
0.00117647 850 -833622.4 -152.528 -703973.2 -14.216 1.819E+043 43.2598327
0.00114286 875 -833971 -152.933 -700154.9 -13.667 6.2504E+041 41.7959078
0.00111111 900 -834305.7 -153.31 -696326.8 -13.114 2.5866E+040 40.4127293
0.00108108 925 -834626.6 -153.662 -692489.6 -12.554 1.2701E+039 39.1038379
0.00105263 950 -834933.4 -153.989 -688644 -11.984 7.3001E+037 37.8633288
0.00102564 975 -835225.7 -154.293 -684790.4 -11.404 4.8532E+036 36.6860282
0.001 1000 -835503.4 -154.574 -680929.5 -10.81 3.6916E+035 35.5672146
Promedio -831377 -148.990655 67.5367422
Desvest 2343.3355 3.73094605 28.5406019
%error 0.282% 2.504% 42.259%

ESTADOS
T(K) ALOTRÓPICOS

273.15 ------ CuO(s) CO2(g) H2O(s) Cu3(CO3)2(OH)2(s) ------

373.5 ------ CuO(s) CO2(g) H2O(g) Cu3(CO3)2(OH)2(s) ------
H2O(1 mol): DH° = 40855.8 DG° = 0 ------ DS° = 109.385
 l𝑜𝑔⁡〖𝐾 _(𝑇_2 ) 〗 =log⁡〖𝐾 _(𝑇_1 ) 〗− (Δ_𝑟 𝐻^0)/(2.303∗𝑅) (1/𝑇_2 −1/𝑇_1 )
-(dDG°/dT)P
%Error
∆H°/R
∆S° Jmol/°K
Log K´ %Error Log K´´
136.78953 0.051% 136.789529912914 0.05% -141.542
125.672168 0.032% 114.538726571491 8.83% -142.546056
116.143001 0.016% 106.60005105885 8.20% -143.238582
107.884389 0.002% 99.6138328370656 7.66% -143.750653
100.658104 0.010% 93.4213673098814 7.20% -144.169372
94.2819705 0.019% 87.8966142223311 6.77% -144.55245
88.6142959 0.028% 82.9384236538932 6.43% -144.937851
83.5432186 0.035% 78.4648066176121 6.11% -145.350098
78.9792491 0.040% 74.4086782733424 5.82% -145.804533
74.8499433 0.044% 70.7146649524563 5.57% -146.310094
71.0960289 0.047% 67.3366850036969 5.33% -146.871267
67.6685419 0.048% 64.2360974681798 5.12% -147.489672
64.5266788 0.048% 61.3802714159507 4.92% -148.164605
61.6361648 0.047% 58.7414699663756 4.74% -148.894169
58.967998 0.045% 56.2959719900933 4.57% -149.675184
56.4974732 0.041% 54.0233750182489 4.42% -150.50359
54.2034144 0.035% 51.9060375497031 4.27% -151.375739
52.0675666 0.028% 49.9286295170629 4.14% -152.288618
50.0741086 0.020% 48.0777673605166 4.01% -153.235702
48.2092608 0.010% 46.3417158010307 3.88% -154.214124
46.4609661 0.002% 44.7101425824419 3.77% -155.218683
44.8186285 0.015% 43.1739155720843 3.66% -156.245619
43.2728991 0.030% 41.7249339589789 3.55% -156.347308
41.8154971 0.047% 40.3559870717163 3.45% -156.171723
40.4390618 0.065% 39.0606357017661 3.35% -155.949202
39.1370285 0.085% 37.8331118683355 3.25% -155.677945
37.9035232 0.106% 36.6682337756296 3.16% -155.355711
36.7332746 0.129% 35.5613333495023 3.07% -154.983382
35.6215384 0.153% 34.5081942403233 2.98% -154.556946
67.5367422 64.0431449869474 -149.842099
28.5405857 26.5928160357224 4.986482706
42.259% 41.523% 3.328%
 (d(DG°/T)/d(1
/T)P ∆Gsimp + aporte
%Error %Error ∆G°simplificado(J) %Error %Error
∆Cp
∆H° KJ/mol

0.0000% -827710.8 0.00% -785248.2 0.00% -785248.2 0.00%

0.0561% -828024.4 0.00% -781709.65 0.00% -781860.178 0.02%
0.1801% -828261.1 0.01% -778171.1 0.01% -778644.358 0.07%
0.3227% -828453.143 0.02% -774632.55 0.01% -775325.403 0.10%
0.4555% -828624.09 0.03% -771094 0.02% -771970.7584 0.14%
0.5597% -828791.188 0.03% -767555.45 0.04% -768606.45096 0.17%
0.6268% -828967.08 0.04% -764016.9 0.05% -765248.0544 0.21%
0.6506% -829161.008 0.04% -760478.35 0.06% -761906.06449 0.25%
0.6294% -829379.68 0.04% -756939.8 0.08% -758587.819 0.30%
0.5627% -829627.868 0.03% -753401.25 0.10% -755298.4368 0.35%
0.4539% -829908.85 0.03% -749862.7 0.12% -752041.40716 0.41%
0.3037% -830224.85 0.01% -746324.15 0.14% -748819.08491 0.48%
0.1162% -830577.12 0.00% -742785.6 0.16% -745632.8112 0.55%
0.1063% -830966.325 0.02% -739247.05 0.19% -742483.31154 0.63%
0.3602% -831392.45 0.04% -735708.5 0.21% -739370.61471 0.71%
0.6410% -831854.925 0.06% -732169.95 0.24% -736294.1832 0.81%
0.9461% -832353.2 0.09% -728631.4 0.27% -733253.4895 0.91%
1.2732% -832886.875 0.12% -725092.85 0.30% -730248.14906 1.02%
1.6172% -833453.7 0.15% -721554.3 0.34% -727275.93 1.13%
1.9766% -834053 0.18% -718015.75 0.37% -724336.16516 1.25%
2.3478% -834682.8 0.21% -714477.2 0.41% -721426.8896 1.38%
2.7276% -835341.675 0.25% -710938.65 0.45% -718546.68429 1.52%
2.5040% -835529.6 0.23% -707400.1 0.49% -715196.92982 1.59%
2.1177% -835569.325 0.19% -703861.55 0.53% -711699.27739 1.65%
1.7215% -835579.2 0.15% -700323 0.57% -708171.729 1.70%
1.3119% -835557.05 0.11% -696784.45 0.62% -704612.12008 1.75%
0.8875% -835500.4 0.07% -693245.9 0.67% -701017.98492 1.80%
0.4474% -835408.5 0.02% -689707.35 0.72% -697388.57756 1.84%
0.0110% -835277.8 0.03% -686168.8 0.77% -693720.35714 1.88%
-831831.655 -735708.5 -739801.08342
2886.37254 30129.667562575 27297.055123
0.347% 4.095% 3.690%
de 373.5.15 a 1000

DG = A + B*T DG = DH - DS*T
A B
-830695.9987 149.1169635 Hallando el valor de DH y DS
149.11696355 -830695.999 DH kj/mol -830696
0.3050185704 208.2743096 DS j/mol*K -149116.964
0.999887043 343.5692674
239002.00312 27
28211758562 3187075.72

CONSTANTES
1000 ∆G kj/mol vs T
2.303 -620000
8.314 200 300 400 500 600 700 800 900 1000 1100
-640000
-660000
-680000
G kj/mol

-700000 f(x) = 149.116963546798 x − 830695.998719212

-720000 R² = 0.999887042996258
-740000
-760000
-780000
-800000
T° K
 logK= A' + B' *(1/T) 𝐥𝐧⁡(𝑲)=(−𝑯)/𝑹∗(𝟏/𝑻)+
A' B' (𝑺)/𝑹
-7.73617224 43357.710647
43357.710647 -7.736172243 Hallando el valor de DH y D
8.8705041051 0.0164340865 DH kj/mol -830.176243
0.9999988699 0.0308975366 DS j/mol*K -148.125588
23891096.53 27
22807.82096 0.0257757598 R^2 = 0.9999989

vs T
700 800 900 1000 1100
LogK vs 1/T
160
140
120 f(x) = 43357.7106466608 x − 7.73617224262247
6798 x − 830695.998719212
Log k eq(1,t)

100 R² = 0.999998869873157
6258 80
60
40
20
0
0.0005 0.001 0.0015 0.002 0.0025 0.003 0.0035
K 1/T° K
CuFeS2 + 3 O2 = 2 2 + CuO + Fe O
(T,s) (T) ( (T) (T )
______ _ ____ _ __ _ ___ _ _ __

T(K) Delta_H°( Delta_S°(J/K) Delta_G°(J) Delta_Cp(J/K)Keq Delta_Vol(litr

_______ _________ ____________________________________________ ___________

------ CuFeS2(s) CuO(s) O2(g) FeO(s) ------ SO2(g)

300 -827710.8 -141.542 -785248.2 -1.46E+01 5.25E+136 -2.46E+01
325 -828049.1 -142.626 -781695.6 -1.25E+01 4.29E+125 -2.67E+01
350 -828342.5 -143.497 -778118.7 -1.10E+01 1.33E+116 -2.87E+01
375 -828603 -144.216 -774522 -9.90E+00 7.63E+107 -3.08E+01
400 -828840.2 -144.829 -770908.8 -9.13E+00 4.65E+100 -3.28E+01
425 -829061.9 -145.366 -767281.2 -8.64E+00 2.00E+94 -3.49E+01
450 -829274.2 -145.852 -763640.9 -8.38E+00 4.35E+88 -3.69E+01
475 -829482.2 -146.302 -759988.9 -8.29E+00 3.73E+83 -3.90E+01
500 -829689.8 -146.728 -756326 -8.34E+00 1.03E+79 -4.10E+01
525 -829900.4 -147.138 -752652.7 -8.52E+00 7.64E+74 -4.31E+01
550 -830116.6 -147.541 -748969.2 -8.79E+00 1.35E+71 -4.51E+01
575 -830340.6 -147.939 -745275.7 -9.14E+00 5.03E+67 -4.72E+01
600 -830574.2 -148.337 -741572.2 -9.55E+00 3.61E+64 -4.92E+01
625 -830818.8 -148.736 -737858.8 -1.00E+01 4.63E+61 -5.13E+01
650 -831075.4 -149.138 -734135.4 -1.05E+01 9.87E+58 -5.33E+01
675 -831345 -149.545 -730401.9 -1.11E+01 3.31E+56 -5.54E+01
700 -831628.1 -149.957 -726658.1 -1.16E+01 1.67E+54 -5.74E+01
725 -831925.4 -150.374 -722904 -1.22E+01 1.21E+52 -5.95E+01
750 -832237.2 -150.797 -719139.3 -1.28E+01 1.21E+50 -6.15E+01
775 -832563.6 -151.225 -715364.1 -1.34E+01 1.64E+48 -6.36E+01
800 -832904.8 -151.658 -711578 -1.39E+01 2.88E+46 -6.56E+01
825 -833260.8 -152.097 -707781.1 -1.45E+01 6.48E+44 -6.77E+01
850 -833622.4 -152.528 -703973.2 -1.42E+01 1.82E+43 -6.97E+01
875 -833971 -152.933 -700154.9 -1.37E+01 6.25E+41 -7.18E+01
900 -834305.7 -153.31 -696326.8 -1.31E+01 2.59E+40 -7.39E+01
925 -834626.6 -153.662 -692489.6 -1.26E+01 1.27E+39 -7.59E+01
950 -834933.4 -153.989 -688644 -1.20E+01 7.30E+37 -7.80E+01
975 -835225.7 -154.293 -684790.4 -1.14E+01 4.85E+36 -8.00E+01
1000 -835503.4 -154.574 -680929.5 -1.08E+01 3.69E+35 -8.21E+01
_______ _________ ____________________________________________ ___________
T
_

T
T
T
T
T
T
T
_