Amina om by AmmeonclyarS 7” AS Ps ») General Discurion a> Clarification, ef, Peaches i!) Ammin e King fyb NHa aa a: qe NHs NH3 Kis Ny Exel? ap a Sel” eee From dasa? gee « ‘Spind 6% 2 poe se he a omit Borme salts . Soleeth 5 ~ Catal ~ ee amcinalny - 7, P. Cond. ay Say prerren unw D RAL Reacher cx Say clualypss, See: anwilto. aks. . Some properties arin bg age fay Awinahon Leachins . € tt) Server} ) Conversion th hhalegore Compoorels, _— ae i, Sem 1 i) peplacmrent th — 5a £ OSCR qtorsps . th) hovel te Pe en sy) Cmverh on Carbenyl Grpe rato (Ht drvamment y=) w ey —* “8 as ‘wal en _— NA) padifien Peseler- jpugen. piserenbornet fe ceganenn BY Vi) pancho th frwmness © Hyd Carbon A) buseattangena. fepe bens - ears VES ¢ geinetite ak armoreryr’ aa Root t ce + —TheArmimatien toy Mmmendly 5s means formation oh amines by ymen a. gx) Ni (Ammone!¥sis) fo RNH, / PNA Caminolysis ) | iw) wees hy drogimalion (ndaeanrens) y pyamammonelysis ws ts used to convert Gar armpavn de tp aminer witrought He forms Nite les _ > RCN CHAO Me) AS Ritts eg. REHOT NMS 7 _ “i > Loy niles) Hi Ammonolysi the acho Oh am o-9t H. Lod-teo +87 Or te» Hg NHe Mi “Due to behave oh NHS Ammonol¥5iS involves NHs, sli a) poubk deamposion ’ with ~ Cl. _sash, Noa ot ral po NH2 tH ups - H. i hak 1S gubshtured 2) Dobycaahion | weatir & asin anal BOP ‘@mmone! os 6 aleahe!’S phorsis an of Caroor¥ npounels velyeo addin oh es pe, & i rahi alamime ole®D _Nubtine ach vity _ Jeol ammes compe Gmanis nacenkor recy! fant 2 proctts bh ammonia ana @ wi gaare QmiTONGRS. Jur Sec bak aniner. bey Arrmeanchyiie reacions mow be clanrifisal broadly a follows? age? Replace ment cs fra / Atel heloyn pe) Aryl Sos & pike 688M L» jn b akohwls & fumch all i) Cone alcohols. ° ‘t by WN) Hydae grmmons ys of Cabal Gmpounds wAddi on Peachong | LY) Peach of Rimmonia AHS lnydav Carbors | Wi) prrscellaneeuwr yeachions Gnveation Hh prunes / beg leeon amy pibe ge & parymengaen wile foymatotery de: ;wnt is nos Nig. Jf yong Bee A minating ag forms an Follows: “employed 2m yanicws 1) Lig i As a iv) NH3sih W)9n Vv) From NHs Solu ay. wc vapowt solid solvent pot A hile Selec ng, porkeatan agents due ne considenation's ganeme 7, remckrgpe b compound balalyst be ave its golubil ty, Sayp Th shots aenetions S38 fay oteol oye viytusl eek a pws 2 ere, Jan WM as : ania mony be Supa! gant & ammon oly Combet So pation SNH eh fram Lad penperstejm) Aqueous Ammema’ — Greatet neo eu opin! ms dn Lig. phar ammo nolyns —sathas adver \nge ray handli ny —> at disselver sulphonic ards, Aad Cu salts on deduction yhibo bey KC lOg (Used > clalpeankrogut Gimiteel sehbiuty Oo chlue —> psodvantn te | a ry daa ly Sis Campane @ anol ar alent with amment lysis Selabo ry oh Nis jy wale ‘Cat pated yf jo 2c Zo 4A Se ane Fewpe | : ; % sony AT 4 AL 7 441 29 2S 22) 193 113. (o- —> usually os se 4. gous FI vag unickes pew & Tey? In > Ammons # baeugt abow! “4 Why € ret NHgOH. NH3 4 Hoo = ow ene = Hy ton” —> The Prcwen& Sh ley dase ew on Bem dissec) sation th ame hy dwaels er i reoporsihy ey wie mate th sinul fore oe? hye Aoah Conger —peg Amnarion ob Cie bewyone/ Chlerea ntnessine pramel/ Ley deny | antoaquim ato que ky prod beri ler ALIPE eHve aenune+s- ao Nias . CsHs- NHet cH rent NM, au mol 7 , oe fel © solid sous ia - See, bert quis expemsire Separation. aie ale for wed, af depensls on wench ok qnuin produncedt Zz KH vate, oH ror Gn Hove mo Con ballad key « reweat by prod Jernext bata, lorerry pnb a Aram Sas .poorertce vh_ age Ammonia; Show jirak eater Ho yt th sewtion Th 7 purer OF heap i i 2 | 3 § ty 3 = iy € gz x > Stu dire of Manachor niga fa 8 ce t e & b is. UF do eCrxanples- Shows ti Mane janie ¥ > & 8 pries of ag. Ammonia : Pde LU | . studies show that paatial pressur- tf tt tt | af wates-vopousy ane nok oper Honal tothe water content dma ielrd pre hence. kelow cultcal temp of NMs, Solutions S armenia ata nol cam pletely: teal admixtures of two component. 3m genera, alight eve dewatio is showy ponttsdpressee(welie) | om He + Ammonolysis ky aqvesi? ammonia and Hs gas ian dissolved 1 Detati jmnesd- pol vent (agave) is Similak. However pH. shuctien show thal wala ofr inet Bivens mauad play imvporteunt 20! jn, ammonelytic wen pce above Caiheel temp iste. Hh Aa Ns (287 decreases tom pes te B2 Buk wits Bite Heel jp falls more Disp dy > gn a Snalost deer expt. snopondedd pactcals af 2et Anthraguinen® aid net undrge Gaversion. bout compouncl De 4g. Ammon % undergoe? Conversion - 47 ? (AS gag" wen tour valerate * [ome ae beet | co ae 7 < eis} . enitan a : Aq. partial pressure 8 Ho — Altes ——volwea june te obser tion Syne | Caleutates! oe we, Bt make A Shoes rey * bo gnthes Sie a hd ty Whaeneh'e 2 Oimstraneerunerrm gunk COMP een Sve 12 Theoret values ptt tre ieee ka oy, were o ether Salve ‘83, Tory of ainixtre appliad tome tensions of amnoninnater mires, Lin 3 np absorbed In 7 aly fo vey absorb fe SN Aide srutt ors amd +e absorbed Ee ke range 5 wee Mole cali Ny sPCHB 10:1 if eee 4 ef BOS, 167 Herm 22 FF py Layne pooperten rh wrta, 4 Pt a iinet Dimer ammania mary tn wike wale Fio, 8:4, Effect af Ny conceutrstion: conversion of p-chlorositrobeazene to pnitro- (92) tole , ae wires mony be (Hy FRE) Be enable r ine form ionic Comper witha compound underreirA aminahon, (Cm otra words iba duwto more, Iniuuma sf mars aclon be fore one Tani Gmp!exe? favouring aramen yes ager ef ommeniaeat solstions eh eaniaus motives Guverato of pat presres HEB) etove anmanral soto) Padre Pooporiton oh NMg vapors dnt & wiz % yapos on amon! errutton Jmcreasss asi He TH crease Gone: Hy. Bul ao “he tempos fu in Crease, popation $ alien Vvapowrs aloo rises. Thue to mer tier sila SE 1 Fat toe emma sateen Fe 6 ati PoP fr possible weal” possi flrs ES Pri mara tA aynivies, enemy sintenstae Am . . / ii) Aro monia Dissolved in an Snment —— x > Seme eyenic aarveorts Compaumdla OM “ Slab wv Lg. aym mia / gases WHS Sp\ub le sm Sore 0795, Jovem ts > bse ae ynnwl sejvenh qteect Ye wwohusvere tare cxvyarhonce OH day days wns jue hwo mets yen rants. ae HHente —— ne Jyyod he aheonn 49% moh — neat. | soi hy tt Wie in O1% cajun 0 — lerY sewenh sono de nore gents il Sebi tke, ah YS kar eee } dugdTe Gy crigeH.) * me thm HY (qaben|naleg © \o Ze se * 24 2% \o (4 % oy do a - jee ye Liq. BH hte Vases ory Sa Sp\ve L betes Haar bw ans & Sz\ver Bowie thaaeoee RMB. dees as Sorry Q prs at wales ® The bo lackinge _Conversion of Nalegeme Compound . on ee aluprialic (alka pati Leo Compares umdurge Gnversi om enaly than Aromolic Chlore Compownels protien fev ocemor Pans cmpanele for pecs ak Feit coe Cotohigshs Ysed ore oxi Copper anermakic. Wale comporndl: (cope? pu pe 4) ey Witmphanet, & artim new atid, con do with » Cabal » Caprice galts and oniden ane. uaest tr’ parvernt- yeouchom ot Kelome quoeh yu Chine antragul nemo .ele- Replacement th Holegen ae aa , ‘ (a * Rens (el CA hes Nite iy Bacerp bier alan on.) rh calor 5 oe ct | We \ fet eS 5 a> Front ely chlorate ov —hovsyounkeraq none Nihobenyzerne . ct He is) NH3 , A Noz“6 cHpnta, ORM 8 jaa ON 4-chios Ne matin aniline > Clecly Chy NH2. ebngtonecti croriele. ae ePaylmectiaeine, NR, -che chy-NH Die ey Ce” Diebyhene ps andre. CH, Cho > 0” ac byH3 Jon ste 5 NH. Chrcret Liq phone N\engsene’ Dichtrodretydt oH Q Bs yk cl. ch,- CDOH Nig. NM Ce COOH. eit giacine + wel (Gere) (hace. bu entre Chloe cule Che + 2Nwad Ake Beguine . Cliz ¢00h cam + SMNECI Cha (doh Tr giny —_ » 8 _ Repleermont oh —SQH & OSQH Gromp ‘ “) SQW %, 1 sits, WHs age a Eee ent “am ae : P dypeatotes Germain ied Saal [erbet in day 1 + Ketone sok pase T oh oxi iting age =a aA = Nibobengent -Setphee® ac ~ MnO , k Br02, Kel 03, fe Cre OP, Ky Cr pita - C20 . . ase of 100— 12° i) ondant/Calelom is foyorn ble J Ht Fy one chacha SBM. RES phy ete che= SOxh, * Ne 805 4 seal tegen Sabpdaale ° Nee tre A ii) NHy= Cho Che OSOaH foet.ch - wn, Nett, Pree eee u e \ a Che < NaH ete Mich “ol Ch. ch: i ; ee . + Sie Sanaen, an Crhg NHp + surgi boychargon eHytonw Lianne NQn Sere +2? Hear Excem odpott 6Vy — > Hon pm 4 z : rr wher ses . —s on 2 "aheimal in frmt i tanto OsH a |a Cite ) pwede bor yene « —> Use ob Ceiads ainrGni a jo ricerca ' Jr Commercial production. a1 pon accoucl | vyieldo oh pamny anne. lesser guantsy aywmewa tendo on ty QUO Chom ca! fr vey sempen 4, Sat ote Lepend? ™ From Wha ch Aa melicral a mans Faeroe prokics ey.) Senger 26s gle tl ts Avi lihe ) Bewyere Aten” HiFi frien as o/s a y = Ps <> } DM Efrat Jeary (cotabyhyCrpres Gren “oe qacate quantchy is bot Alepebel be Grrmanoe ongarr0 Ld Com} Ye | : => pow anne tages coin opricarionw jm- emuldi Frey, jomencha pean aopralt additives, Corrosion ile bi few. de Pepteemed ob Promo Farter, Dronek coun Arcreserer Dues ry , fa ger watie PMG Fou satel... Higho Tey Dunner . bok gucararee chrantes b SOL: tert, Iw bory @aapord formato, IER u iy Sg GAY vuah Aicoholes bo Amines ‘ 5 hia Conversion sind alley pie feastbl. ynebreds. Aung alcohel anges - Choice ob rasqonk alee! —____# depends m Camry renee nm plan J etonromy. «aldeby de Hy droamons ae = Canboxttic ae oe Gere oles) eesey Wn igen’ gy - SPO . ot yo-se® MNS wail fallog oheshsls (cot ) formation ob — foley ; . [See | bet gd Conn, . fr mahe amy on ee aiech,ok bth cap? ORT MS > anomidin —_—_ OH che-c + cor Ranh Fro 7 pyrene PB +2NHy HN Che Bascre N\ Dba + Cente % 2 Hay-cha con. t Gy ene Traces | Ut OH- My He $3 NA MB yyy Cha Ore SOM) . Nake . Tenn Hy aren Daiphonis anid,Conversion of Carbonyl compounds : ‘ Aldslydes H, : 3 ae Avwneo. ’ tye ene neva )28. Cala NS. ev. Neeser WoS2 ov — lower alselyales — Vapomr plane Mos2. a Hig Ao Lrg. proce Typical rsachio, hr : " eects CH3-c=0 MHS, Chg ¢-oh “> Clg H=NH Excey NHe or. Wes, Ov Klose CHa-Cha-NHo -s for unsabinalact al.dehyder:. Nat Mz. Chia Clte=CHy Nie. yy) CHy=Ch-CHO Cation ‘one N Acrotein Cabal: map = cs H: ii) Ch, CHECH -ChO ie CHa che cHe-Citg No Cease ‘ai Rubylamdne - any ok (owerTonp 125-108 Karta n-eo — r Hoi ee, te CH= ¢=e5 CHa Ga He | hydawgenahen de 3 catalyar . By yt ] 50 prepytarni ne Vapi ; pl. lower C2~-& Pillow HasAddition Raachions ) IB go some Hythe we’ SS Addition \s possi Bie Neat Seay, ke form Vand oo ami noo, WF" ogee cyelire Com SPO. i. ea Re tees : Cha Fe . See CReeeee Hot cox QHecn. aot fs bow vente! “sim © yn moni fas “ > fermahm she's oo | 2NHs + Cea = | " : aa aommanismn arbererts: => re =O + NHg on Cantosnaic a (oh eng [iw se vm e pe pte a ho- 6 = OX Lets San . Qyanicaricl si a saluheh , faclor (fo pret), why dre ws Krmation of woke to Gm rY amuse onele < wal. yielding gr sey. Ut= : ‘ \48 2 NHa + CS2 FD HAN -CS+s NHy . Pnmoniium Littte carbamate Na-SEs-NCtb, +0 (Clg), ~ WHT C524 Noon > Ma: Sett Cam ee comesk> BS i laagtun motel Cn 3 . _ AatSF Ne ] enela woot ote eo Cis e bh No eat o-ch,~ cH + ———— Dretnane) en Gali Nitz Governs. poud. Ho—Ch, Cn. Ta trail amine C=C + Nh, —> Ho, Uopome. Coc---Gon+ KHg + *X cHe---e + NHy > Hew divear oolaliben & xe clan ron, B pore a pena ad fer Cagagation de double bend, Ny & atteehadl to Avmmater < akon x. Oy From Kept ebeelum PN, attecko on rex ewl- —_>-14@) CHg )=n-n e 63 on . (o ¥3 om He CSE ENON wacenGisa may Hs in 3 on) Jane. a easange ace ne , ze Netes ont vet ramiginy eyed | Pi fimngeta ote 7 § ony @ . : / fame. —NHs Gg x ha = ie 3 Se ys 1 a Siew PS matheaccly Aysle\ OCA, sia pe Mal 7 NB“ byin h readers its ohne | R-H+ My, " wo nee # they when eng eon a meses | Rinay wit bag cypghe > oon eb SE ister . ; oridayy yt hal) aber oe chek Ce & hiew Ciba hatin I ek eerste iy 2. 9 dena earn e feet? Aarls nek Lademenly aapbrarih boy 7 pally eat @ paar fram Mone pakeeaen TS ere ckn eaten ates vn Gondy Si fr — SOS ansLoe pete G pee a ss bend dn entegee? eS en, FB 1 oe" i @ Ths ny | my | \ Sqr” \ Se ; ‘ ©Guanietine from Cyanide * HN CEN. + KH - zo Han “c= NH 4 Guantdi ne Ado Him ; Amma nib prevents Sy peer ate yee inl) formes Cnc Gorm palewant yk v WN-cEN. + NH : the es Cyanawres— quant NH Nets - : wa WH. HyA- <— NENT HN-CEN AS ~ y s ; Nee nue’ Se Ca Noh z Ne” Yo f ; — a, Bit flumeres as Wome ram \ Sie fen canted GmediHond, melamine. Sua veer, (eee hayes© wet ee © Rochon Ch Nig with hyde Covbma NN Angers, Vanesa / Ba Reackivm. ohn ommadelly ) Misceflam ecto Ha overs ety Mit wig ry ae fo- t- pn Aniline Ti prorom> be crsral Met BA Pen yo Y Nha prov ibs Autre - aes ch, — om 68 ! vy bits —? | \ 1 — oe ety de done”, ne “Ye Bubslectme _254ethn oy, stuidime 2 La ect Ys, ae han )iass Pexamatrylonetetratecs exe pethraanch We ZEN ANHgt €HCKO A 8 . y 30), yet é Heo ah ane ne Sy ersten c Conterrbusd te got SlumsPhysical & chemi cab fenton —= cee Aram onolyns, Iz }) Sotubiliby Ek r * bx Favarsble rc aa hom Sa phett ans aa Setckis Halegere ghee Come: Bra & a ee ” Payrera Whe fregtatem in wets te mle jremeqitcly, 1k ensiiee pooyee trea. 2, Be chi ation TA tuts 1 Sette down, see R i tare place ovdy at paket enews it) Fine ated 7 wate i) Effecrethytation, oct Prt ey Rig kes 4 Boom dineh Ser yeten i, 4, Nite ~ Chiaraben * Poly Gave Mp als ” ye i) oleh Pe ein wd ot 6 oie Tee p- | N02 /c0H (favors), for replat 9K a- ct wy NHo V) Nig conc ~ a wrt C Prrmary eG moma gy whelety te pne neko Oi Hera fr 9) 2 Motor Ceuta. i $ Cee pet Ey pho) = Machen ts foe wc Khe Qo et amine ney, re mH coves oh CHarabengine a« , Catalyse vers tn Auinalon feachions, Amonel p. 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