OXIDATION Oxydatio is one tthe powerhul tools wedi @aqanic Chomicat Bn dirs Drtes far pra Ayntors oh variate) Of Conmpoumels . Maintypes ob oxidations Gre Ge Loos. |) Dehydragimation_ Cahson + 402-> Mt gCHO + H20 cy GH eS EO eng THs + H20 Oo oH Secondary 2) Addition th Oxyaer aiom. CHache + %02 — Cgc OCH , pidshy de feid- 1 Ph. (ces) zoo Os > He E-0H i Rh Hyducarbon oteshol , 3) Dehydw gemahon ond inkeduchon of OX4927 - chy + 02 —> CH20 + M20. Hydavcasbon aldehyde, Cehs Chon + Ses Ces COOH +H20. Bens alcohol. Bengoic add. 4) Dehy diogenatim poly mote csLar Condensation, mcg, OS 41,0,» Sey cely es Lops OH yo San ES orm — ClgoH + CO > Chg COOH, 7) oxidation oh olefins with amild [Stronger agents CH, CH. De “CH= CH(cH.y COOH Cote c Rad) Wa, th0: kenya ES CHa(ciy) = GH -en (CH); COH, cHs for com 3 € He oH pod. Dihy dacyy Skevic Kev pone-(chi)s COOH. nyebic B) Poeroyidation. CSame peackons occu title sick, on. pus Shae hh Does eee ce. » OV) puadiat ose Q come pa * ) =e a H-c-8 AS ' each S richeenpiemers _‘sopreny? bemyene”3) é Amine Compounds _umder xe oxidations { La eee: Nor i J ee. es te a | Ayobengemne y que i , 1°) su und S. Subghade st ovidigcdte “subg Compounds. Salt ee emcee fad Cy 4 ek Ue : x men te 3), €-S-Cary Jacans cist for ersse Clans ae fren Captars hohave, dabhernentty fran Meohi cHo + Heo -oH — > CHa paldohyde wo i) ch. cHe ; 3 . + 2 SO,0H. NcH. cH2-SH Cig CH, 2 OF ery) frccepken. chivgf omtproni’ +e i) fameved ro lwyde gn . - we Ne aemov. wy any dagen gnc vatan ey % s oxidixin fegen's S The, Paine: pa problem jm oxidation poe jnduction ob desired yeaction ond ix | atisfactory Control, to 16 extent,4 Variow Salts th per vmonganats, mee t. \) Na Mx 04, > deleqursant not prebbersol it) Ca-( A > for-oxidaton oh Complex potcing it) Ba Te fo sso lbs Compiler \ Cao. M02 pr et ae Siw ep DLavery, oe Cetin ont kate) Fusion) ucts iw) Kg Mn0l- por ny popermnane agent (useel Gv pi. see: alcohsts) W) Kem Ody ak mony be jee yea Semel ponent? " galttiong Aikabine — MYYssde,t 20 TF 2 MnO ZO. 30 2K Mnd4, S227 soy Aromatic diy deo Grbors Shriac first “tess Qeachiom fh greet CHO CH ome Cee eis a cs, Osteen. Fin " iaat's ren < FTO} -atack only foc Garber CH,~Chy~ CH, en. To) aa = &. Benge acal, 5 Dhow sabt Avot ruck oy saat ore ail. | potasium sobt sabe 1 i int cite Ger real de sl", ong opt pent] in wales pressor iguwets its eek oppe Hens. SS Crown eS pe -Etsy forme Cow tenth. feos £ be cone yen “Lee “2 apaet® fOr a3 rey ae (oe , : co ch 6 . ney we) ot pcntis3 Cormn 7 ae ¢3) ee ym jf “Tstomn-! me Chale. @ lenge ans Ge" che eon @ Gig chee a 3 particles tes * Ow oxidation ob Gacebe cor OUP: ees arpa ANG Conse CoHoe ws oom et when ssl” sa: “titty get poh oH Fase, HO y i am ly, c —_ pare cH3-¢ CHa Get ecg, Speech Coty ie res = . @® teat aleakats corel pees ols Canter als, coieh with CrWD «6 a on dis sid on peed Sak “ au nate Sieiwlrhe JonesDirehenmab es. A > Show moar poner Fad ecoeekh Bs action fn presen te Ce Reacts, — © enCryOz 4 4 H2S04-> K2S04 Cay + F20 — Na Salt is more Soluble + find moreusre. | —=s Chromic add getubion C choanie Saigo) C03 in gtercr al ontick aes is ussal 4 ondigi Le T addition is ridiging agenb— Ts qd One. 0 Cy —> “203 +30 pease They AL formahon Selaffs bared mK ipo Sas aldehydes and Sub Sequin el pasedon wile pamony| Gr03 Grek). \) -cH,oh — > bai-> 5 12 Ketoatee adit. ii) [ae hydanny Seat ¢ aud —F oh a . vsorttneies it bok B pigs gana hed 3 fyratere Ioartirn qeavee < crs ~ aloo found bh eee weetMechanism (Sec oieohel ——7 cokers): f [skp — involves acid cabal gest Auplacerrant of, wali Ae Chaeitgae typerteh te grunt oe lene. ; : Rae oF Eke amorsoina Hat nS Ro yoo + owt AA wy Ron 6 gor i ° chien , i step — patinansin patna ar ba PTD Com Canker pile Cr? ‘pened breaks. aM 0 f_* is te + chy -oF 1 RY, R Q { s Ho Zo ger on See NF ag or chowiteion Sp FO a v! West HH? Meet. ( Daiwa aleohel sadd. { » oa 7 . OH nen C63 / Hott ¥ HoH, 34 \ eset Re CHOW Fy, Say, fe cH Bethe Reet =F cation Lo = ast ry eH 1 ‘ e p Soren seme R= Gro UG > fe 4 peleon + Grom ‘ nh o Add. o- nD i ms Lselation ahdolydes sm aifttort in geod fll fem. Pronany sLeehel! hence Vari ows CylVE) oni deaths oo qnivydaaus med a Sh Py aida mi ere chlove chyemake (yee JE RAT Aine dicremate (PACD gin Vek te Ho Clo Cros + 7 Seer oy CrO3cI . x poe aiconels bx 35 mby drous indi on Cam at aldehyde een, lt ra Cr PCE Mn bs re aad ‘: pet, cam abse we yted Ff Sam siBve graces er tee c= © W ener, 4 gaz paosent ee CON, =cn-eHe) OH pec/ Glade, erie ‘ goad - alos oxidise pr ala) Dd 2 {epee 1?) cot phe oe He, alehuy ctos.in good Gchiy = Le ag ta aren on msCHLORATES > © LEhbaAie aerat Hels 15 poverty ot at - Shelete wp to 40'e (Conc dot, is Visrok) | — payer ignites who diped init. aS — ondizer.. Citson —y cHacan. VHB, + Chi on chim, = Grduiba af visteb ren 1S Undtesl. 3 . Salts a é hy 32 Gq) lary, of PC ne 7 Kelde - serbi sos glee ph le < — 3 vred oder wile ARAL agevt ay Sek prtr + eolLukes+ - eke. Carica, REGAN —> 2 KCl\O, heat 5 aket +302 eae > Watilg te wre’ galubte, Leas endp eave — oN PEROXIDES. ( weanly pred OAR Pb O2, Mn02 HO, 1) PbO, - Useet to He peste | Hast | Hel? . 4 2CHe,Coor —F EH2CO\ pp x 0 PbOo 3 Ooo pb > Op be "erinablye *- = Finely daridod parts Ye from. - Pb (NO 4 Wa Cle 7 Chet Pho Papers fae ? é 23 esa tates aes Bot! ei = Cla are = i) Wide yead wit M284, Mn Opt He SH AF MRS tad + 7Q,x, Hypochlowiws Acid. : | as ee rad | mpfowden CC 0Cle,) * | 7ST Ng, Ca Salis. ey Bleachi CaH), + Cl, > Cadtlea. “pagan noni Hoe ae Orn MoS aanve Bot a GAR aS odie ? “for. enn op preparation > Ge Salt = Compt is woe Usaal 20 poper/ferctile Ro lyaan peal daa ate HSyreerev 7 Tp ene peceptens sah he Sisitptader - pon oe Soe bess M 5, Sadium ctloaite- onal Chava Dion Syn 10 9; Golabe don wali» powertyat oxida: ager Peencly | x) NaclOa. a Ne ee > For & iG ; ws aes ort nee werden chen po BSB Bren les it © HA > Sol’ Solve ee genes t mm. = a ya duel yal parrancl & HST, ae cHs0H +H > 2C\0,+ CHgCOOM. Nalhooe, Nalct COO yw. : Bod H20 ENarsen —> Oli: Mats te S02 oy Ha SO.. fo 7% yee. stenaly ierseee Sry, > Morksled + sad as 09-32 dasignat : snierr? & VK Sy OS™ HBL ORM aguav abewts (Ge Bday Has Per yooce) of 205% ee We : > dyorxbort=® Tao Gh 7 OY edits aes ple 0"), Wee Lee yee pexhle S07.; paper iA Seti ee choca oof. H % CHg AFzS Ha, Page Chg y0% Ha, 160% vidal . pe stun carbons (24078 Lrarypation. vty Aromatic hy:_OXIDATION mn -iquid_preseonidation with Omar onyapr from cin 18 chsapent adie erent foconbal. Os Combines with 4¥ coda, at normal Teme bul foo slow e wer As Ccommensial rlewibit saroter® eal TEnf: com ance eA ns an Liq phere Calalnt i» stravied [Sucpenseen Ow Conta willy bubbles sb 402: Tospend up He pee vised4 poorp amst thers 2% Gh anction beak 1288 Sng == Formation % Acébie Aad foiling te rovker + AcOH Sitter Sy [ose : > Olen hese ee * heatshalabade eno +0 Reet te KG =a ula | quire Maye ph wi], Kewcone @\h- Eta! | Mycodneme Red [BPE ~ MOH lore 2, BRN addition sf edhamel 12 Sauoted duterndttantt se yiad Camb @96)- inbeb: A Smdaaial prose. acitaly solulion + 2525 heetatdohyte fg etaamel (120) + AY. cacrd & @balt Gr ceRvahen« g54 “Fennp so alow J4S%E abe AAPETET s Carentan otran betel acctsie “oT otady? AcOH E27 © Et-Oke~ 2Dy Umnchogek 3°57,Liquit : Acetaletelyde 5 Aeskic Al. yrvides good soos ds Lig prow oxidation using move Cubes OM gers ern eh, &pemsts cone. AcOH. Gor makin. Swlet Ferd - “Pres NpVemt 42 SteamOK * wate. Blunt nium lined skeel versed Gils br heating £ lolig Munir $ £ a ; is; og i ah > > > > 6 > ? > > > > > 2 b > > > fo ahr = 28-30 € > mentee A ee, > Ramction Cott ant hy lone: d > > > > t b t Ny vented ae Hhroagh Series sf Condens, scrubbers > My disbibuter, fe peret bait, t kettle + bash Gmc. Acette atid pith excerding, Arrestch Uy 96. shungith & 88-957. yield Bate liquid phase 4 As 4 te 60 fons 4 397- sid pocrunt- in forced Condition OR BO- |d fons 2 js possible Serie “uy dotion Hh Hi. febstetnn Hrd Oxidation Set cae te item aap aiget and idaeg auf orn gonad 160: cbc bemp- ans an Lig phe on dation oh ei aagom bens I Heat Ces eye rs pede ily acay wht chow Te lien fy Seay, Fs dehexgonts. lamenting 5 Heali: caling - Yror. 6, spsalved Cabelyst: or Solid cat * * Sith race sith Fiutd posinxor™ \ 3 J Apmalasfe, liquid” ae be wed is isp Mite typ ductor Pa ation Set fe Gntinusw” H 135 Used fo.canbol. TeneVi OWL h a ning Av 3 myersien Fh Napirelin te Pave lace emthyetaiele - 2 Ke) + ite” + ACd, + AHae Ate ges kos] g Cie . Vas [sila {30 ae We ie e 5x 35BC Cs Ks Wri liowing + vaphous Fr oxidation. Heatit [+p prevent clishuction oh. ¢ ones ab, ™ E gxidahen 5S ane, apple NE younaved is f-sq ul 2 ye many C24? ne cheatin oF pcHon Femsponstes Lb wee UR: Lower pepen ts rh ay Db jnovynet Fig A providesa Sethion EN sing fake ane . al & temper “aopects Hh bei Ling, dia. he ssa A ccmueshbr i | Boing Haut tataiyst ore = > ‘Frc, 0-9, Section of single-tube reactor with : bec rca co 4 Speen ate Pg “ona ty aa ene oat eof nae a oi 7 Bry alm Ax Tarcuned ode ov ov mnOe Tem fafa an death] an aaa: more anand S50 ° pA Asceh an hd ye ok eg erent- wD slaw Ge Bian apo oe aq mixta) Am R Jb byt ane! “Ln Hy Vike ade vel Aw eal Bim For. mani, nono zeit ts 7 Jame al Lat aft pra “ke Mm ec andy? one t re aa one a ote dk wood fey palais evar » Flower, cresting high pus aivteho, lew te mp af tess labs - oud ela fo osu ee oeke : —s