Answer Phase 1 Test 11th

FIITJEE Page 1 of 13 PHASE TEST
ANSWER- KEY
PHYSICS CHEMISTRY MATHEMATICS

PART-A PART-A PART-A
Ans1. C Ans1. D Ans1. A
Ans2. C Ans2. A Ans2. A
Ans3. A Ans3. D Ans3. C
Ans4. A Ans4. A Ans4. A
Ans5. C Ans5. A Ans5. C
Ans6. B Ans6. A Ans6. B
Ans7. B Ans7. D Ans7. C
Ans8. B Ans8. D Ans8. D
Ans9. D Ans9. A Ans9. C
Ans10. A Ans10. D Ans10. D
Ans11. A Ans11. B Ans11. C
Ans12. B Ans12. C Ans12. C
Ans13. D Ans13. A Ans13. B
Ans14. C Ans14. D Ans14. B
Ans15. A Ans15. C Ans15. A
Ans16. D Ans16. C Ans16. D
Ans17. A Ans17. A Ans17. B
Ans18. B Ans18. B Ans18. A
Ans19. D Ans19. A Ans19. A
Ans20. D Ans20. B Ans20. A
PART-B PART-B PART-B
Ans1. 8 Ans1. 4 Ans1. 3
Ans2. 2 Ans2. 0 Ans2. 1
Ans3. 3 Ans3. 3 Ans3. 0
Ans4. 0 Ans4. 6 Ans4. 6
Ans5. 2 Ans5. 2 Ans5. 6
Ans6. 5 Ans6. 5 Ans6. 3
Ans7. 5 Ans7. 2 Ans7. 5
Ans8. 2 Ans8. 4 Ans8. 2
Ans9. 4 Ans9. 1 Ans9. 1
Ans10. 6 Ans10. 9 Ans10. 5
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Ranchi (SOP, Doranda): Samriddhi Complex, Ground Floor, Near St. Xavier’s School, South Office Para Doranda, Ranchi.
Jamshedpur : Om Plaza, 3rd Floor, Thakurbari Road, Aam Bagan, Sakchi, Jamshedpur
.
SOLUTION
CHEMSITRY
PART-A
Sol1. Although charge density of Li is maximum, so it is extensively hydrated and its ionic
mobility is least and that of Cs is highest.
Sol2. I  H2O2  2H  I2  2H2O

(-1) oxidation (0)
 H2O2 behaves like oxidizing agent
Sol3. Radial node = n –  –1 (5d)

= 5 –2 – 1 = 2
Angular node =  =2
Sol4. PV = nRT PV = constant (at constant T)
PV
P
Pressure increases & volume decreases , PV remains constant at constant T.
an2
Sol5. Unit of 2  atm
V
atm  unit of V 2
Unit of a 
unit of n2
2


atm  dm3 
mol2
 atmdm6mol2 .
Sol6. Compound Oxidation state of P
H4P2O7  5
H4P2O5  3
H4P2O6  4
e
Sol 7. Anions have larger radii than atoms. Also, higher the ratio higher the ionic radii. So,
p
rN  3  rO2  rF 
Sol8. In BrO 4 ,Br has +7 O.S, therefore it only acts as a oxidizing reagent, does not undergo
disproportionation reaction
Sol9. According to Bohr’s theory,

z2 z2
K.E  13.6 2 frequencies () of revolution of electron  3
n n
6 z
v  2.18  10
n
kq1q2
F 2
r
.
Kze2  n2 
=  r  
r2  z 
z3
F 4
n
Sol10. In both reactions H 2O2 act as reducing agent
In reaction (A) HOCl – O. A
H2O2 – R.A
In reaction (B) I2 – O.A
H2O2 – R.A
Sol11. Meq of Base = Meq of Acid
For H3PO3 ; 1  V = 50  1  2  V = 100ml of NaOH
For H3PO2 ; 1  V = 100  2  1  V = 200ml of NaOH
Sol12. Divalent metal ion of atomic Number (Z) = 25 is Mn2(25)


2
Mn(25)  ..............3d5 4so
(n=5, five unpaired electron)
  n  n  2   5   5  2   35  5.92 BM
Sol13. First ionization enthaly of Mg is smaller than Ar and Cl but higher than Na.
N
Sol14. Structure of HNO2 is HO O and it contains only covalent bond.
Sol15.
electron
+
Na 10
2+
Mg 10 isoelectronic
3+
Al 10
But Zeff value Al3   Mg2  Na
+ 2+ 3+
Ionic Radius Na > Mg > Al
0.72 0.54
1 1 1
Sol16.  
 1  2
1 1 1
  
300 450  2
1 1 1 450  300 150 1
     
 2 300 450 450  300 450  300 900
h h h h
Sol17.    , He  , Ne 
2mKE 2mT 2  4  400 2  20  300
Ne 2  4  400 16 4
    1: 1.94
He 2  20  300 60 15
.
Sol18. The balanced equation is:

3 MnO 4  5 FeC 2O 4  24 H  3 Mn2  5Fe3   10 CO2  12H2O
Meq. of KMnO4 or MnO4 = 200  0.5 = 100
Meq. of FeC2O4= 300  0.6 = 180
100
Eq. of MnO 4 = = 0.1
1000
0.1 0.1
Moles of MnO4 =  = 0.02
n  factor 5
180
Eq. of FeC2O4 = = 0.18
1000
0.18 0.18
Moles of FeC2O4 =  = 0.06
n  factor 3
MnO4 is the limiting reactant
3 moles of MnO4 produces 10 moles of CO2
10
0.02 moles of MnO4 produces =  0.02 = 0.066 moles of CO2
3
Volume of CO2 at NTP = 0.066  22.4 = 1.478  1.48 L
Sol19. Ammonia decomposes into N 2 and H2 completely when a spark is passed through it.
1 3
NH3 (g) 
 N2 (g)  H2 (g)
2 2
Initial pressure in atm. 1 0 0
1 3
Finial pressure 0
2 2
The total pressure of N2 and H2 after complete decomposition is given by
PT  PN2  PH2  0.5  1.5  2 atm.
Sol20.
P4
P3
V P2
P1
–273ºC 1ºC
TºC
(P1<P2<P3<P4)
1
V
p
p1  p 2  p3  p 4
.
PART-B
Sol1.
NaOH + Na 2CO 3
(1) When Hph is added

1 1
m.e NaOH + m.eNa2 CO3  m.eHCl = 17.5   1.75
2 10
(2) When MeOH is added after Hph

1 1
m.eNa2CO3  m.eHCl  1.5   0.15
2 10
 m.eNaOH = 1.75 – 0.15 = 1.6
. m.eNa2 CO3 = 0.15  2 = 0.3
WNa2CO3
 1000 = 0.3
ENa2CO3
0.3  53 ENa CO  53 
WNa2CO3   2 3 
1000
 0.3  53 
Weight % of Na2CO3=  1000   100 =  0.3  53  15.9  3.975%  4 %.
  10  0.4 4
 0.4   
 
2 2 6 2 6 2 10
Sol2. Zn(30)  1s 2s 2p 3s 3p 4s 3d
Zn   Ar  4s13d10
Outermost electron is 4s electron,
n  4,   0,m  0,s  1/ 2
Sol3. KCl solution has molality (m) = 3.3, [ Means 3.3 mol of KCl dissolved in 1 kg of solvent]
Total mass of solution = mass of solute + mass of solvent
= 3.3  74.5  1000gm
= 1245.85gm
Mass 1245.85
Volume of solution = =   1038.20ml
density 1.2
moles  1000 3.3  1000
M   3.17M
V(ml) 1038.2
Ans. = 3 (Nearest integer)
Sol4. Na +, Mg2+, F, A  +3, O, K+, N3
Sol5. Power = 50 watt = 50 J / sec

Energy emitted per second = 50 J
Wavelength ;   795nm
hc
Energy of one photon =

6.63  10 34  3  10 8
 J
795  10 9
 0.025  10 17 J
50
Number of photons emitted per second =
0.025  1017
= 2  10 20
.
Sol6. Melamine is a heterocyclic compound.

H2N N NH2
N N
NH2
Each nitrogen atom has one pair of lone pair. Thus in all lone pairs
Sol7. In 10 sec provides 1000 J energy

In 1 sec provides 100 J energy
 E = E0 + K.E
 = 400 nm is sufficient for ejection of e
hc 6.626  10 34  3  108
 E  E0  
 400  10 9
6.626  3
  10 34 15
4
6.626  3
  1019 J
4
 4.965  10 19 J
100
Number of e ejected   20.14  1019
4.965  1019
 2.01 1020
Sol8. Strength = 0.72 g/ L
Using;
Strength
Molarity =
Molar massof solute
0.72
M M
180
= 4  103 M
Ans is 4.
Sol9. Total wt  4 gm  WNaOH  WNa2 CO3

Let us suppose moles are ‘ m ’ for each.
4 = 40m + 106 m
 4 
m  mole of NaOH and Na2 CO3 each.
 146 
 Mass of NaOH (x gm)  4  40  1.095  1.0
146
Sol10. NH3  3
N2H4  2
NH2OH  1
N2  0
N2 O  1
NO  2
N2 O3  3
NO2  4
N2 O5  5
Sum of 0.5 = 9
.
MATHEMATICS
PART – A
Sol1. cos 250  sin 250  k


cos 250  cos 90  250  k 
2cos 45 .cos  20   k
0
 2
Sol2.  , 
2n  1  2n  1
 2   2 
sin  n . .cos    n  1 . 
 2  2n  1   2n  1.2  
  2n  1
 2 
sin 
  2n  1 2 
 
 n   n 
sin  .cos 
 2n  1   2n  1 


  
sin  
 2n  1 
 2n    
sin   sin  
  2n  1    2n  1   1
      2
2sin   2 sin  
 2n  1   2n  1 
Sol3. cosx varies from -1 to 1 for all real x.

Thus cos(cosx) varies from cos1 to cos0.
 minimum value of cos(cosx) is cos1.
1
Sol4. a
5cos x  12 sin x
13  5 cos x  12 sin x  13
1
 least positive value of a is
13
1 10
Sol5. We have log 8 b  3  log23/2 b  .
3 3
2 10
log2 b   log2 b  5  b  25  32
3 3
Hence (C) is the correct answer.
3x  4
Sol6. Here 184 x 3  54 2  .
Taking log on both sides, we get
3/ 2
 4x  3  log18  3x  4  log54 2   4x  3  log18   3x  4  log 18 
  4x  3    3x  4  . 3 / 2  x  6 .
Hence (B) is the correct answer.
.
Sol7. A is the set of children like Milk

B is the set of children like Apple
n  A   63 n B   76 n  A  B  x
76  n  A  B   100
76  76  63  x  100
39  x  63
Sol8. x2  x  x 2  x
x  x if x  0
x2  x  0
x  x  1  0
x   ,  1   0,  
Sol9.
 
x 3 x  1  x  1
0
4
 x  3  x  2

for x  0, 3 x  1  0 
2
x  x  1
 4
0
 x  3 x  2

for x  0; 3 x  1  0 
2
x   x  1
4
0
 x  3  x  2
Sol10. x 3  48  4x  3x  11
x 3  48  12x 2  44x
x 3  12x 2  44x  48  0
 x  2  x  4  x  6  0
log10  x  3  1
Sol11. 

log10 x  21 2
 2
2log10  x  3   log10 x 2  21  
2
 x  3 2
 x  21
9  6x  21
x 5
2 2
2  1  3
Sol12. Now,  A 0 A1    1     0  
 2   2 
2 2
 1  3  1 3
  
     1  A 0 A1  1
2
   2  4 4
.
2 2
2  1  3
 0 2   2    0  2 
A A  1 
   
2 2
3  3 9 3 12
 2     2   4  4  4  3
   
 A0 A 2  3
2 2
2  1  3
and  A 0 A 4    1     0  
 2   2 
2
 3   3  9 3 12
       3
2 4 4 4 4
 A0 A 4  3
Thus,  A 0 A1  A 0 A 2  A 0 A 4   3
OR
A3
A2 A4
O 0
60
A1 A5
P
A0
In A 1OP
A1P
sin300 
A1 0
1 A1P

2 1
1
A1P 
2
Similarly,
A0A4  3
& A0A3  3
 A 0 A1 .  A 0 A 3  A 0 A 4   3
Sol13. T1 

1  sin 46  45
0 0
   1
cot 450  cot 460 
sin10  sin 450 sin 460  sin10 
 
T2 

1  sin 48  47 
0 0

sin10  sin 480 sin 470 
 
1
 cot 470  cot 480 
sin1 
.
T 

1  sin 133  134 
0 0

sin10  sin133 0 sin1340 
 
1
 cot1330  cot1340 
sin10 

1 
On adding  Tr 
r 1 sin10 

cot 450  cot 470  cot 490  ...  cot1330 
 
 cot 460  cot 480  cot 500  ...  cot1340   cos ec10

0
[all terms cancelled except cot45 remains]
Sol14. The equation of any line parallel to the line 3x  2y  5  0 is

3x  2y    0 ………..(i)
This passes through  5, 6  . Therefore, we get
3  5  2  6    0
or   27
Putting   27 in (i), we get
3x  2y  27  0
which is the required equation.
Sol15. sin x  2sin2 x

 
 sin x 2 sin x  1  0
1
 0  sin x 
2
    5   7    11 
 x   0,    ,     ,  , 2 
 6  6   6   6 
Sol16. cos ec 2 x  25 sec 2 x  26  cot 2 x  25 tan2 x

2
 25  10   cot x  5 tan x   36
Sol17. We can write k1  tan 27  tan9  tan9  tan3  tan3  tan 
sin3 cos   cos3 sin
But tan3  tan  
cos3 cos 
sin 2 2sin 
 
cos3 cos  cos3
 sin9 sin3 sin  
 k1  2     2k 2
 cos 27  cos9  cos3  
x
1  tan2  
Sol18. 674  a2  2a  2  1
x
1  tan2  
2
1  49
 a 2  2a  1
1  49
.
48
 a 2  2a  1
50
 25a 2  48a  673  25  0
  a  25  25a  673   0
 a  25 (taking the integral value of a).
Ans19. lim

tan  1  sin2 
 0
sin  2 . sin   2
 tan   sin   2
 lim
sin  2 sin  
 0 2
 tan  .sin   2
2.sin2  1
 lim . .
 0 2
.sin   2
sin 2.sin  2 
1

2
Sol20. f  x   cos  2  x  cos  2  x
f  x   cos9x  cos  10  x     9

2
 2   10
 
 9
f    cos  cos  5    1
2
  2
PART – B
Sol1. Let 5 sin   3cos   k …………(i)
and 3 sin   5cos   5 ………..(ii)
squaring and adding (1) and (2),
25 sin2   9cos2   30 sin  cos   9 sin2   25 cos2   30 sin  cos   k 2  25
k3
Sol2. 
cos2 x 1  cos2 x 
2 4
 cos x  cos x
 cos2 x  sin2 x  1
Sol3. sin x  sin2 x  1  sin x  cos2 x

cos12 x  3 cos10 x  3 cos8 x  cos6 x  1
sin6 x  3 sin5 x  3 sin4 x  sin3 x  1
3
 sin 2
x  sin x  1
=0
Sol4. sin3 x . sin3x

 3 sin x  sin3x 
4
 sin3x 
1
 3 sin x .sin3x  sin2 3x 
4
.
1 3 
 cos 4x  cos2x   sin2 3x 
4  2  
1
 3 cos 4x  3 cos 2x  2cos6x  2 
8
1
  23 cos2x  3cos 4x  2cos 6x 
8
Sol5. 3 sin2 x  7 sin x  2  0

3 sin2 x  6 sin x  sin x  2  0
3sinx  sin x  2   1 sin x  2  0
 3 sin x  1 sin x  2
1
sin x 
3
Sol6. Given points (1, 2), (-3, 4) and (h, k) are lies on lone L1, so slope of line L1 is
42 k 2
m1  
3  1 h  1
1 k  2
 m1   ……….(i)
2 h 1
 2  k  2   1 h  1
 2k, 4  h  1
 h  2k  5 ……..(ii)
and slope of line L2 joining points (h, k) and
3k
 4,3  , is m2  4  h ……..(ii)
Since lines L 1 and L2 are perpendicular to each other.
 m1m2  1
 1   3  k 
     1 [from Eqs. (i) and (iii)]
 2  4  h 
 3  k  8  2h
 2h  k  5
On solving Eqs. (ii) and (iv), we get
 h, k    3,1
k 3
So,  3
h 1
Sol7. lim

sin x 2  5x   lim sin  x 2
 5x x 2
 5x
5.
2
x 0 x x 0 x  5x x
5
Sol8. On solving equation 3x  4y  9 and y  mx  1 , we get x 
3  4m
Now, for x to be an integer,
3  4m   5 or  1
The integral values of m satisfying these conditions are -2 and -1.
1  sin 2  cos 2
Sol9. f   
2cos 2
.
2
 cos   sin     cos2   sin2  

2  cos   sin   cos   sin  
 cos   sin     cos  sin  

2  cos   sin  
2cos  1
 
2  cos   sin   1  tan 
1 1
  
f 110 . f 340   .
1  tan11  1  tan34 
0 0
1 1
 .
1  tan11  1  tan  45
0 0
 110 
1 1
 .

1  tan11 1  0
1 tan110
1  tan110
1 1  tan110 1
 . 

1  tan110 2 2
Sol10. Slope of the line 2x  3y  17  0 is
2
 m1 (let) and the slope of line joining the points (7, 17) and 15,  is
3
  17   17
  m2 (let)
15  7 8
According to the question, m1m2  1
2   17
   1    17  12    5
3 8
.

Answer Phase 1 Test 11th

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Answer Phase 1 Test 11th

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FIITJEE Page 1 of 13 PHASE TEST

PHYSICS CHEMISTRY MATHEMATICS

Sol2. I  H2O2  2H  I2  2H2O

Sol3. Radial node = n –  –1 (5d)

Sol4. PV = nRT PV = constant (at constant T)

Sol9. According to Bohr’s theory,

Sol12. Divalent metal ion of atomic Number (Z) = 25 is Mn2(25)

Sol18. The balanced equation is:

(1) When Hph is added

(2) When MeOH is added after Hph

Sol5. Power = 50 watt = 50 J / sec

Sol6. Melamine is a heterocyclic compound.

Sol7. In 10 sec provides 1000 J energy

Sol9. Total wt  4 gm  WNaOH  WNa2 CO3

Sol1. cos 250  sin 250  k

Sol3. cosx varies from -1 to 1 for all real x.

Sol7. A is the set of children like Milk

Sol14. The equation of any line parallel to the line 3x  2y  5  0 is

Sol15. sin x  2sin2 x

Sol16. cos ec 2 x  25 sec 2 x  26  cot 2 x  25 tan2 x

Sol20. f  x   cos  2  x  cos  2  x

f  x   cos9x  cos  10  x     9

Sol3. sin x  sin2 x  1  sin x  cos2 x

Sol4. sin3 x . sin3x

Sol5. 3 sin2 x  7 sin x  2  0

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